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By S. Makni, S. Koppalkar, A. Bouajila

This paper reviews briefly the gravity recovery involving conventional gravity separators and centrifugal gravity separators. The advantages of semi-continuous gravity separators will be discussed. Techniques for upgrading the gravity concentrates will be addressed briefly. The research efforts in optimizing semi-continuous gravity separators will be recalled. Innovative gravity circuit for eliminating or minimizing the use of complex processing schemes will be reviewed. On-going gold gravity research at COREM has revealed that gold particle shape transformation is the main factor explaining the lower recoveries of the plant units. Efforts to devise possible remedies for improving gravity recovery at plant will be discussed.

Jan 1, 2011

By William Petruk, Donald Leroux, Michael Cooper

"Brunswick's primary flotation circuit (CuPb) produces a low grade concentrate containing considerable amounts of undesirable sphalerite and pyrite. To determine the cause of the poor selectivity, a series of Quantitative Mineralogical Analyses (QMA) were performed on several CuPb circuit streams. It was observed that significant fractions of sphalerite and pyrite reporting to the concentrate was liberated, meaning that their depression was not complete. The study highlighted the need for some R&D efforts to be spent in sulphide flotation fundamentals.IntroductionThe viability of many mining projects strongly depends on the performance of their concentrators. More than ever, competitive grade concentrate and high metal recoveries are criteria of paramount economic importance. The selectivity of solid/solid separation processes used in concentrators must be maintained at high levels or continuously improved.Flotation is the solid/solid separation process used by most base metal producers. In spite of its low operating cost, flotation remains a very complex process. To make it selective, precise reagent dosages and electrochemical conditions must be maintained. The difficulty in controlling flotation lies in the numerous heterogeneous reactions that can take place between the different solid, liquid and gaseous phases involved. This complex chemistry makes flotation selectivity difficult to understand and, therefore, to improve from a theoretical point of view.Brunswick Mining and Smelting, near Bathurst N.B., operates a 10500 tpd concentrator which produces four concentrates through five stages of sequential flotation (Figure I). Various reagents are added at key process stages while the ore undergoes different electrochemical conditions. Although the selectivity is important at all stages, the performance of the very first separation, the CuPb circuit, is the most critical. It is here where mineral misplacement to the wrong stream has the greatest economic consequences."

Jan 1, 1996

By M. Cossette, V. H. Tran

"How can the durability of asphalt pavement be doubled without increasing highway budgets? Asphalt containing asbestos can provide the desired performance with additional costs being made up by longer life. The addition of a low percentage of asbestos to an asphalt mix permits a higher asphalt content without any consequent loss in stability. It is mainly the higher asphalt content that provides improved performance and durability, although the fibrous reinforcement plays a key role in preventing the propagation of micro-fissures. As well, several international studies show that, thanks to the latest production techniques, no environmental hazards need be incurred.RésuméComment doubler la durée des chaussées d'asphalte sans augmenter les budgets de voirie? L’asphalte contenant de l'amiante peut offrir les performances souhaitées et l'augmentation des couts initiaux peut être rapidement compensée par une durée prolongée. L’addition d'une faible teneur en amiante courte il l'enrobe de bitume permet des teneurs en bitume plus élevées sans subir une perte de stabilité en conséquence. C'est principalement la teneur accrue en bitume qui assure un améliorations propriétés physiques et une augmentation des performances mécaniques, ainsi qu'on prolongement de la durée. Cependant, le renforcement fibreux joue un rôle clef en prévenant la propagation éventuelles micro-fissures. Les nouvelles techniques évitent tous risques environnementaux"

Jan 1, 1991

By B. Nanthakumar

The impact of stockpile oxidation on chalcopyrite was studied through collectorless and collector-induced flotation conditions. In both cases, the Cu grade-recovery performance of stockpiled ore showed relatively poor concentrate grades with respect to that of a fresh sample. However, the oxidation had a minor effect on chalcopyrite recovery itself. The poor concentrate grades resulted from dilution effect primarily by excessive flotation of pyrrhotite. Size-by-size analyses indicated that for the collectorless flotation, the recoveries in the coarse and fine particle-size regions, were higher for fresh ore than for stockpile sample. A greater impact was seen in the coarse size regions for both types of sample, compared to the collector-induced case. The Cu recoveries showed a remarkable increase in the coarse size range for both samples when a collector was used. However, the case for stockpile sample was a marginally higher compared to the fresh sample. This difference has been offset by an opposite trend that was observed between these two samples in the fine size region. It is concluded that in contrast to the case with nickel-bearing sulphides, stockpiling conditions do not show a significant adverse effect on behaviour of chalcopyrite due to its strong floatability, regardless of oxidation.

Jan 1, 2007

By Stavros A. Argyropoulos, Radhakrishna Valiveti, Bernard Closset

"The use of microprocessors in metallurgy is currently increasing at a very fast rate. A large number of companies are offering systems ""off the shelf"" which are aimed at the data acquisition and process control market. There are two main drawbacks to these systems: first, they are usually quite expensive, and second, they are not completely compatible with the target metallurgical application. An alternative is to develop a microcomputer-based system "" in lab "".A dedicated microcomputer system has proved to be very useful in many metallurgical research applications(1,2)). However, in this system the analog input signals had to be transferred over long distances , and significant noise was introduced despite the use of shielded cables. In order to overcome this problem a network of low pass-filter s was designed and built. The usage of the abovementioned system brought the need to digitize the analog signals in-situ and transfer the digital signals, which are much less susceptible to noise over very long distances. This distinctly different design philosophy has become a reality with the evolution of microprocessor technology over the last few years. This design philosophy is utilized in this development."

Jan 1, 1984

By F. Lambert

"Amok Ltd./Cluff Mining operates a uranium mine at Cluff Lake in northern Saskatchewan. The project consists of one open pit and one underground mining operation along with a full-scale milling installation.The underground stoping operations are of the narrow vein type and are done between two levels 50 m apart. The mining method is undercut with concrete backfilling. Cuts are 3.5 m in height and can be as narrow as 1.4 m in width.Stoping operations are mechanized utilizing a CT-500E electric Microscoop marketed in Canada by Teledyne. The machine is only 85 cm in width and does all the mucking in stopes. Ore passes are provided in stope roughly every 40 m to 50 m.This paper describes the utilization of the CT-500E Microscoop in the company's underground operations and provides performance data related to the experience.IntroductionThe Amok Ltd ./Cluff Mining operation is located in the northwestern corner of Saskatchewan. The project started in 1980 with open pit mining and milling operations. In 1983, an underground mining operation began production . Today, the Amok Ltd./Cluff Mining installation produces 800 tonnes of uranium per year , which originates from both the open pit and the underground mine at about the same proportion."

Jan 1, 1990

By P. Homola, M. Karlík, M. Slámová

"Aluminum sheets (AA1199, AA8006, and AA5754) were processed by accumulative roll-bonding (ARB) in the temperature range from 20 to 350°C. The microstructure of the sheets was characterized by means of scanning and transmission electron microscopy and electron backscattered diffraction. Mechanical properties were monitored by hardness measurements and tensile tests. Increasing strain (number of ARB cycles) led to incremental development of lamellar microstructure with a decrease of the spacing between high-angle grain boundaries in the normal direction of sheets. ARB process produced an important increase of strength while maintaining thickness and relatively high ductility, without accenting of the anisotropy of mechanical properties of sheets. The level of hardening decreased with the processing temperature and at 300 and 350°C ARB caused even the softening of the material due to the recovery of the deformed microstructure or partial recrystallization during heating to ARB processing temperature.INTRODUCTION Accumulative Roll Bonding (ARB) is a technique of grain refinement by severe plastic deformation (SPD) proposed by Saito et al. (1999). One ARB cycle consists in sheet cutting, surface treatment, stacking of two pieces, heating (optional), and rolling with 50% reduction in thickness. Since the sheet thickness remains unchanged by this cycle, ARB processing can be repeated as many times as desired. The goal of ARB is to impose an extremely high plastic strain on the material, resulting in structural refinement and strength increase without changing specimen dimensions. After several cycles, ultra-fine grained (UFG) materials with high strength and relatively high ductility are produced. An advantage of this method is that it does not require any special equipment as other SPD methods such as equal channel angular pressing (ECAP) (Valiev & Langdon, 2006), high pressure torsion (HPT) (Valiev et al., 2000), or cyclic extrusion and compression (CEC) (Richert et al., 1999), but only a conventional rolling mill and so it is seen as an economically viable and industrially scalable processing route. ARB processing has been successfully applied to various kinds of metallic materials at room or elevated temperatures (Tsuji, 2005). Besides processing single metals and alloys, ARB has also been used for creating ultra-fine grained and nanograined metallic composites (Wu et al., 2010; Qu et al., 2014)."

Jan 1, 2018

By Christopher Riley

A relatively unexplored lead zinc deposit lies about 12 miles northwest of Revelstoke, B.C., in the highly metamorphosed Monashee Group of rocks of the Shuswap Terrane, Precambrian in age. Host rocks are of sedimentary origin and consist of gneisses, schists, marbles and quartzites with intermediary types. The marbles and quartzites provide good horizon markers. Using these it is possible to interpret the controlling structure which is a syncline overturned to the north, dipping south at about 45°, and plunging east at about 12°. The syncline is truncated at about halfway of its length on a peak on the west side of which a partial cross section together with superimposed minor folds may be seen. The quartzites and the two marble beds may be traced over much of the structure. There are two lodes, above the marble and below the quartzite, which converge eastward and which are the exposed edges of the same host bed -an impure limestone.

Jan 1, 1961

By M. Imamura

Sumitomo Metal Mining Co., Ltd. has developed a novel hydrometallurgical process for producing not only copper metal but also iron metal from copper concentrates. Because copper concentrates generally contains the same amount of iron as copper, cost-effective rejection of the iron is a key issue for the development of the process. Conventional hydrometallurgical processes produce a large volume of goethite or hematite for disposal and the residues are not environmentally friendly. In the novel Sumitomo hydrometallurgical process, copper is leached effectively from chalcopyrite concentrates using chlorine gas, followed by purification through solvent extraction and electrowinning for copper and iron recovery. This process has many advantages such as the minimization of the volume of solid waste by the recovery of metallic iron and the production of high purity copper. Iron metal with a purity of more than 98% can be recovered from the purified raffinate. This paper presents the results of the batch and continuous tests of the process flowsheet.

Jan 1, 2006

By A. W. Chan

"An interactive computer simulation model of conveyor systems used in oil sands mining has been developed to aid in the selection of mining equipment and the evaluation of operating policies. The materials handling links between supply points, such as bucket-wheel excavators and draglines, and demand points such as bins and extraction plants are modelled in such a way that the conveyor model can be interfaced with any combination of these equipment submodels. Detailed calculations of the power demand of each conveyor section based on operating characteristics and conveyor design parameters are included to permit the close monitoring of energy requirements. Various interactive features are incorporated so that an operator can not only monitor, but also control, the mining operations in the model and experiment with different operating strategies.IntroductionThe interactive simulation model of conveyor systems described in this paper is one of a number of detailed computer models being jointly developed by the National Research Council and Canstar Oil Sands Ltd. on the mining equipment and operations used in oil sands mining. Reference I presents an overview of this whole series of models, their interrelationships and the underlying motivation for their development.A network of conveyors constitutes one of the practical ways for transporting mined material in an oil sands plant. The materials handling links between supply points, such as bucket-wheel excavators, bucket-wheel reclaimers and bins, and demand points such as dumps, bins and extraction plants can be represented by a series of interconnected conveyor sections. For example, the fluctuations of the feed rate at the bucket-wheel excavator, the flow of ore material through the conveyor network and the arrival of this material at the extraction plant can be simulated."

Jan 1, 1982

By Waldbillig. D.

A baseline of the poisoning effect of hydrogen sulfide (H2S) fuel impurities on solid oxide fuel cell (SOFC) anodes was developed using polarization testing. After the baseline behaviour was characterized, tests to study the effect of various H2S concentrations on the rate and amount of cell voltage degradation and recovery were performed. Attempts were made to improve the rate and amount of recovery by various methods. Testing was very reproducible, but significant electrochemical performance degradation was seen after all H2S poisoning tests even at an H2S concentration of 0.1 ppm. Degradation is initially quite rapid, but after a period of time the rate of degradation levels off. After poisoning was complete, the H2S flow was stopped and the cells were allowed to recover. Some recovery was seen after poisoning, but cell performance was never fully recovered.

Jan 1, 2005

By Randy Billing, J. Fraser Wilson

"IntroductionThe job of designing and implementing effective environmental management sounds like what one executive, assuming responsibility for a very sick organization with lots of potential described as, ""an insurmountable opportunity"".Effective environmental management is an opportunity, no doubt. Its an unusual, if not unique opportunity. Insurmountable? Maybe not! Indeed, in the authors' experience, the keys to unlocking this opportunity are not in new or complicated technicalities; they are in the existing strengths and successful experience that one has in managing other complex and exacting management issues.To begin, it is necessary to understand what these issues of sustainable development mean to business. What is the nature of this opportunity? What makes it look unsurmountable?New Games: New RulesLawyers have described some of the new rules companies are facing and there is a new game being played; a game characterized by unique challenges.Take two, for example: • The ecological problems to be faced are Mother Nature's business, the political solutions required are our business. This combination of natural problems and political solutions requires the development of new management mechanisms, to bridge the gaps among us, as individuals, as professions, as interest groups and so on; indeed, even as countries;• and gaps there are : about as many gaps as the people involved : many of them with new and changing expectations, often mutually exclusive and not negotiable.The challenge of these relationships and communications among so many different interests is one of the keys to effective environmental management.Like any game, this one has rules and they are new, too. These rules are evident not just in new legislation - tough legislation with draconian penalties; they are also evident in new and exacting business policies, value driven and just as unforgiving of poor performance. Senior management of many companies are speaking about the role of enlightened corporate policies and how important it is for everyone involved that these policies drive and reflect business practices. Absence of day to- day behaviour which evidences the words in action, the policy on the wall of a corporate office or published in an Annual Report is first evidence for the prosecution , not the defence.The challenge of practical policies is another key to effective environmental management.This is a new game, with new rules: the challenge of change."

Jan 1, 1991

By Gordon Thompson

"Development of the unique Mine Games exhibition at Science World British Columbia is the largest ever collaboration of many interests to present the story of mining and the issues of mineral development delivered to the public by a science education centre.IntroductionMineral education programs have long been a major focus of the British Columbia mining community. Mine Games and its tremendous potential to enhance industries image and the public's awareness of mining is unequalled in the field of Issue Based Education Exhibits.The main goal of the exhibition is to look at the future of resource industries in a rapidly changing world of economic activities, new technologies, and growing public concern for the environment. Three challenges were the aim of the exhibition: to increase participation, to serve as a tool to increase interest in science and technology, and to draw an increasing number of school students to the interests of geology and the earth sciences. Mine Games is to serve as a meeting place for discussion of issues and where reliable information can be shared and new ideas explored.The exhibition is designed to develop new approaches to hands on learning that encourages visitors to explore and generate discussion and thinking with respect to resource development activities.The role of author, beginning in 1993, was, with senior industry leaders, to coordinate the raising of $1.3 million to complete the funding of the $1.6 million project total. The second and most interesting challenge was to work with the many minds that were collaborating to create the exhibition and to assure that the facts and science were correct. This involved the coordination of ""expert groups"" that verified the science and technology and the issues that the creative design team at Science World planned to use in development of each exhibit module."

Jan 1, 1995

By Neil Schofield

"The estimation of recoverable ore reserves for feasibility in precious metal deposits such as Pine Creek must account not only f or the extreme variability of the ore grade but also for the complexity of the geology. Compatible models f or both must be adopted. Further, very selective mining demands reserve estimates be based on small selection units whose individual grades cannot be estimated reliably from the exploration drilling data.Multigaussian kriging is one method based on a multivariate normal model for estimating recoverable reserves under such conditions. In this paper, a non-mathematical description of the multigaussian model is presented together with its application to the Pine Creek Gold Deposit. The results, when compared to the first year of production, are encouraging for the model but not without surprises.Together, Part 1 and Part 2 of this study combine a detailed and geologically conditioned variogram analysis with an appropriate estimation method for a highly variable low-grade gold deposit. This and other studies of gold deposits familiar to the author show convincingly both that while the appropriate geostatistical skills and techniques are necessary to tackle the question of reserves, equally important but often discounted is the need for an appropriate and compatible geological model. IntroductionThe Pine Creek gold mineralization is associated with saddle reefs, and quartz and quartz- sulphide veining within the Enterprise Anti cline. The anticlinal structure is complex and, prior to mining, the mineralization was considered to be mainly strata controlled. Grades vary up to 160 grams in l .5rn core samples with coefficients of variation in excess of three.The estimation of the recoverable reserves for such a depo sit must account for both the geological complexity and the extreme variability of the gold grade.Part 1 of this work presented the geological model for the deposit and summary statistics 0 f the gold data. A detailed structural and variogram analysis considered both gold grades and the normal score (or gaussian transform) of these gold grades for different composite sizes."

Jan 1, 1988

By Robert B. Parsons

"Recent amendments to the so-called ""flow-through share"" rules in our income tax legislation have given a new lease on life to this once popular investment vehicle.The original ""Dome funds"" for exploration in the Beaufort sea recognized the usefulness of flow-through share arrangements, but, by and large, flow-through shares have until recently not been able to compete effectively with other tax shelter instruments-mainly , limited partnership interests.This month, Tax Notes examines the new tax rules for investing in flow-through shares.IntroductionRecent income tax amendments have helped to rekindle investor and industry interest in so-called ""flow-through shares"" as a mechanism for mobilizing funds toward mineral exploration and development activities. In competing for investment funds, flow-through shares have historically placed a distant second in terms of investor popularity, being unable to compete with the more attractive features of limited partnership arrangements. However, primarily as a result of favourable changes to the income tax law, flow-through shares may be well poised for a comeback.This article examines the income tax considerations pertaining to issuing and investing in flow-through shares, and compares the former and the new income tax rules relating thereto. Of course, inasmuch as a flow-through share issue can involve various contractual arrangements between the investor and the issuer, there is a wide range of legal and business factors that generally have to be taken into account. A discussion of these matter s is beyond the scope of this paper, which is restricted to a summary of the special income tax factors attributable to flow-through shares."

Jan 1, 1983

By C. A. Biley

"A dedicated iron removal stage was installed at Anglo American Platinum’s Rustenburg Base Metals Refiners (RBMR) during an expansion project which began execution in 2010. The Pressure Iron Removal (PIR) process aims to precipitate iron from a nickel leach solution under medium temperature (145 °C) oxidative conditions using caustic for neutralisation. Since commissioning, the process has been robust in removing iron from the refinery but has shown significant variability in the residues produced. These residues, which are typically comprised of ferrihydrite, hematite or natrojarosite, have varying iron contents and different physical properties which have implications for their filtration and ultimate removal from the refinery. Since over 95% of nickel plated at RBMR passes through the PIR section, volumetric constraints caused by poor filtration performance directly influence nickel production and stabilisation of this process remains central to the continued ramp-up of the refinery to full nameplate capacity. This paper details the development of the PIR process and the journey from concept to implementation. Recent laboratory and plant scale tests have highlighted the importance of the initial phase formed in the autoclave for the ultimate residue requiring filtration and how the feed acid concentration is a critical control parameter. On this basis, a new caustic dosing philosophy was implemented which improved pH control in the autoclave. Further optimisation of the PIR process is on-going.INTRODUCTIONIn 2010, an expansion of Rustenburg Base Metal Refiners (RBMR) to increase nickel production from 21 to 33 ktpa began execution. The management of iron was pivotal in the ultimate configuration in the new circuit and one of the primary differences from the original circuit was the addition of a dedicated iron removal stage: Pressure Iron Removal (PIR). A significant drive for this new unit operation was to facilitate the separation of iron from other leach residues. Not only did this result in a significant decrease in the amount of leach residue but, without the constraints associated with iron precipitation during leaching, has permitted more aggressive leaching conditions and, correspondingly, greater throughput and efficiencies.However, as with many commercial implementations of even mature technologies, the journey from development to implementation has presented challenges for the continued ramp-up of the refinery to full nameplate capacity. Specifically, since all nickel bearing leach solution must pass through the PIR section prior to the nickel purification and recovery circuit, throughput difficulties in the PIR section can directly impact supply of feed to the nickel tank house. Since commissioning, the PIR autoclave has effectively removed iron from the refinery, but has shown significant variation in the solids phases produced in the autoclave. This variation presents difficulties for the filtration of the discharge slurry and represents a key throughput limitation which periodically impacts production. Additionally, the increasing production rates associated with the ramp-up of the refinery have resulted in a significant increase in the required volumetric throughput through the PIR process. This has placed even greater emphasis on improving the stability of the solid phase produced in the autoclave, ultimately targeting an easily filterable residue with high iron content."

Jan 1, 2016

By E. M. De Souza, P. Lausch, D. O. DeGagné, J. F. Archibald

"The potential use of industrial and municipal waste glass as a partial pozzolanic replacement for Normal Portland cement in mine backfill has been investigated. Considerable quantities of glass are currently discarded into landfill sites at high cost to municipal and industrial users with no foreseeable environmental benefits being gained by such disposal. This research study was undertaken to assess the viability of using ground waste glass materials as partial binder replacement of Portland cement fractionswithin consolidated mine backfill materials. The program was implemented to review various factors that could influence successful incorporation of glass waste replacement of cement, these factors being the feasibility of glass waste procurement, determination of process economics and the physical and chemical suitability of ground waste glass materials to generate adequate backfill strength when replacing Normal Portland cement fractions. A series of laboratory assessment trials were established to evaluate backfill component characteristics and mixture strength properties for both standard Portland cement-consolidated and blended Portland cement/ground waste glass-consolidated backfill materials. Side-by-side review of the strength behaviour of various component backfill/cement mixtures was designed to permit comparative evaluation of the capabilities of ground waste glass and Portland cement products as backfill consolidating agents"

Jan 1, 1995

By S. Yadav, T. G. Murthy, C. Saldana

"An experimental study has been carried out in order to study the deformation of porous brittle materials under plane strain indentation. Gypsum, which is well known model system for understanding the behaviour of soft rocks, is used in this study. The effect of wedge angle is investigated in this research through this series of experiments, using wedges of 3 different apical angles. High-speed, high-resolution images are captured using a CMOS camera during the experiment. The images obtained are analyzed using a Particle Image Velocimetry (PIV) algorithm in order to obtain the evolving velocity, strain-rate and strain fields.INTRODUCTIONThe problem of indentation, which is usually referred to in the context of hardness testing is ubiquitous as a material characterization technique for a large class of solids. Mechanical properties of materials such as yield stress, flow stress, fracture toughness, elastic moduli etc. can be related to the hardness of a given solid. The indentation problem involves a given material or solid (whose properties are to be determined) indented by a relatively harder material (indenter) allowing the solid to undergo plastic deformation, which is then related to the yield stress of the material. The problem of indentation and its variants see many applications ranging from mining and petroleum industry, infrastructure industry, manufacturing, and biomedical sectors. Indentation has been extensively studied in metals, with accurate measurement of deformation parameters, stresses and comparison with analytical solutions. On the other hand, understanding of indentation in other class of solids such as cellular solids, porous solids, rocks, and soft solids is still nascent. In case of rocks, a comprehensive understanding of the indentation problem is very crucial because of the obvious applications in mining, petroleum and infrastructure sectors. The inherent porosity, the brittle nature of the rocks, adds to the complexity of indentation in these porous brittle solids. Various theoretical models with degrees of simplifying assumptions have been proposed to study the indentation in rocks. The most common model used in the study of indentation in rocks is a cavity expansion model, wherein a blunt indenter indenting into a rock is approximated with the expansion of cylindrical or spherical cavity in an elastic-plastic material. Complementary studies in understanding fracture initiation and propagation due to indentation has been largely based on the studies of traditional brittle materials such as glass."

Jan 1, 2015

By L. D. Smith

"Those who submit competing proposals for projects seek to present senior management with complete and fully supported material that will not fail under questioning. Hopefully, misleading notions and omissions will have been minimized and there will have been testing of the assumptions regarding the economic, social and political environments.A capital project evaluation team can do management and itself a service by including a sound approach to the impact of inflation (and its twin problem, interest) on a project and a great disservice with an inappropriate approach to inflation.InflationHandled deftly, inflation can alter a project evaluation to show almost any result the handler desires. It must be a constant source of frustration for design people and cost estimators to spend weeks perfecting the technical aspects of a project in order to minimize costs, only to have all of their efforts set awash in a sea of financial and economic assumptions that submerge all of the detail. In all of this, inflation is perhaps the largest offender, with inflation criteria often being brought to bear at the last minute, almost as an afterthought. Perhaps this tardiness reflects the difficulty of the subject and the belief that senior management will take its own approach to the problems of inflation. Such a belief is unfair to senior management, for it is entitled to not being misled by omission. It is entitled to the full use of the skills of the evaluating team, including reasonable assumptions of the impact of inflation.Working in a consulting context, one has the opportunity to participate in the evaluation of a large number of projects."

Jan 1, 1990

By Takahiko Okura, Chiharu Tokoro, Shunta Shibuya

Copper concentrates bearing arsenic as enargite (Cu3AsS4) or tennantite (Cu12As4S13) have disadvantage on copper smelting environmentally and economically, so those concentrates should be treated decently. In this paper, some experiments of arsenic removal from several kinds of copper concentrates by heat treatment in an inert atmosphere were discussed. In this study, several samples in which arsenic contents varied 0.18 to 8.3 wt % were heated to the temperature range of 400 °C to 700 °C under argon gas flow during 1 hour. The heat residues and volatilized materials (V.M.) were analyzed by XRD, XRF, ICP-AES, XAFS and MLA to analyze residual concentration of arsenic and residual mineral composition. Experimental results showed that arsenic removal from copper concentrates advanced in 2 steps; at the temperature range of 500 ° C to 550 °C and of 550 °C to 650 °C, respectively. MLA analysis showed that a few of arsenic in enargite was removed by 550 °C heating and a majority of it was still combined with copper and sulfur as tennantite. On the other hand, arsenic in tennantite was removed almost completely by 650 °C heating. Furthermore, a particular type of arsenic mineral, such as Cobaltite (CoAsS) still remained after heating at 700 °C.

Jan 1, 2014