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By Fatemeh Pourakbari, Mohammad Reza Yarahmadi, Abbas Sam

Pyrite is the most abundant sulfide gangue mineral in copper porphyry ores. In spite of addition of lime in large quantities to depress pyrite in flotation, considerable amount of this mineral is reported to concentrate, particularly in rougher and scavenger stages. With the Sarcheshmeh pit advancing to a greater depth and reaching to the hypogene zone, the amounts of pyrite and chalcopyrite in the feed are increased. Hence, a reduction in the copper grade and increase in the sulfur content of the concentrate are observed. In this study the effective factors on the pyrite floatability at the circuit flotation was considered at Sarcheshmeh Mine. Mineralization zones in the pit were firstly identified. Then, sampling points were located using GPS system. On the basis of mineralogical composition and morphology, the ore was categorized into five main classes. In this classification the amount of lead and zinc and also pyrite locking with other minerals were analyzed. The study of polished section indicated that inclusion in pyrite was very frequent in all classes, mostly composed of the floatability of pyrite. Flotation tests were performed on the samples of different classes at pH of 11.8 after conditioning time. It was shown that, pyrite floatability was decreased with a decrease in the lead content of the feed samples except for the second class, while for all classes an increase in zinc content contributed to a decrease in pyrite floatability and recovery. It was found that, the lowest pyrite recovery (1.89%) was corresponding to pyrite–molybdenite dominant mineralization with Zn of 0.33% and the highest recovery (86.89%) corresponding to pyrite vein dominant mineralization with Zn equals to 0.9%.

Jan 1, 2016

By Stuart J. Schofield

Introduction The study of the ore deposits of British Columbia is one of fascinating interest not only from a scientific but also from a commercial standpoint and certain wide problems in connection therewith have interested me for some years. Several of these problems have been set forth in papers presented before this Institute on previous occasions. In 1918 it was pointed out that the commercial ore deposits of British Columbia, with one exception, were associated with the granodiorite batholiths of upper Jurassic age. This was followed, in 1922, by a discussion of the ore deposits of British Columbia in which the mineral belts of the province were defined and named, showing a zonal arrangement of ores in which the Pacific coast deposits are characterized by the presence of copper, while the interior belt is marked by the presence of silver, lead, and gold. Methods Of Investigation In reading various reports on the economic geology of British Columbia one is struck with the fact that the mineral veins may be arranged as a system and further examination will show that such a system follows two main directions, one northeasterly and the other northwesterly, both related in origin to the same force.

Jan 1, 1925

By Balmer Neilly

FOR some reason or other, Mine Taxation has never been a popular subject for discussion in meetings of this kind, and it has never received the study and consideration its importance demanded. By way of explanation, two reasons may be suggested. In the first place, the computation, adjustment, and final payment of taxes, have been looked upon in most cases as a Head Office chore. Secondly, since taxes represent an uncontrollable cost item, they have been treated as an added rather than an inclusive factor in calculating unit costs. Perhaps because I am half Irish, and therefore resent taxation of all kinds, perhaps because I am half Scotch, and am therefore concerned with the results, I have always taken a keen interest in this subject. Moreover, by some peculiar set of circumstances, I have been a participating party in many, perhaps I can say most, of the discussions on this subject that have taken place between the Governments and the representatives of this industry during the past thirty years. Looking backward, certain very definite impressions remain. Political considerations have never had any part in these discussions. Views have been exchanged upon the frankest possible basis, and, when we disagreed on some particular detail, we agreed to disagree, and followed through in harmony and? good faith. We, as an industry, have refrained from importuning and fault finding in ways that might be considered as petty or selfish, and it is only upon occasions such as this, where conditions necessitate action, that we lay our troubles before the powers that be. The Ontario Mining Tax Act was drafted by men who were earnest and practical as to purpose, and that Act has stood the test of time. It is, in. truth, a mode! Act, for it has been copied in its general clauses by both Quebec and the Dominion of Canada. We all know that, when a machine is running smoothly, we should leave it alone. The same is true of a well designed, easily applicable, taxation measure, and our present difficulty with respect to this Act arises out of an amendment made in 1916. In that year, you will remember, the Dominion imposed a wartime Income Tax Act. It was described as a wartime necessity and it was intimated t:1 at with the end of hostilities its application would be restricted and finally cancelled. The rate of taxation was modest, and when the Ontario Government was asked that the Dominion Income Tax be allowed as a deductible item, they readily acquiesced. This was looked upon as a temporary arrangement.

Jan 1, 1943

By N. R. Thornton

This paper discusses the rapid growth in the application of instrumentation for metallurgical process control. It covers such methods as ultrasonics, pulp density measurements, on-stream X-ray analysis and reagent control, as well as the expanding use of computer control and data acquisition.

Jan 1, 1971

By J. Lu, D. B. Dreisinger, G. Houlachi

"Zinc metal is primarily produced by electrowinning from sulfate solution. Zinc electrowinning is very sensitive to impurities such as Co and Ni. These impurities have to be removed to produce high-quality zinc and maintain a high zinc current efficiency. Zinc dusts are used to remove these impurities by cementation. However cobalt cementation is extremely slow and it is typically activated by the addition of Cu and Sb. Even with the use of Cu-Sb activation, cobalt is still difficult to remove. The zinc dust used for cobalt cementation is negligible compared to that consumed for hydrogen evolution. In some plants up to 6-7% of electrolytic zinc is used for cementation. This is a great waste of energy. Cu-Sb activation is not well understood. The objective of this study was to further understand the Cu-Sb activation and then find a way to reduce hydrogen evolution and promote cobalt cementation. The investigation reveals how hydrogen evolution (or zinc dissolution) and cobalt cementation and re-dissolution change with temperature, zinc dust dosage, the concentrations of copper and antimony and time. In the Cu-Sb activation, copper is deposited on a zinc particle to produce a porous shell. The zinc particle as an anode dissolves while the shell as a cathode provides a place where cobalt cementation and hydrogen evolution occur and they are catalyzed by antimony. A certain level of antimony (around 0.1 mg/L) is a key to maintain the catalytic effect of the shell. At a higher antimony concentration, cobalt cementation is accelerated slightly while hydrogen evolution is increased greatly. When a zinc particle dissolves to a certain degree, cobalt loses its cathodic protection and starts to re-dissolve. The change in cobalt concentration is determined by the rates of cobalt cementation and re-dissolution. The operation conditions can be optimized to maximize the cobalt removal and minimize the zinc dust dosage.INTRODUCTIONMost of the world’s zinc metal is produced by electrowinning from sulfate media. Many impurities such as iron, copper, cobalt and nickel are co-extracted into solution with zinc. Iron, mercury, indium, lead and tin are removed by co-precipitation as hydroxides. Copper, nickel, cobalt, aluminum, arsenic and germanium are partially co-precipitated with iron while cadmium, magnesium and chloride remain in solution. Cobalt, copper, cadmium, nickel and etc. are subsequently removed by cementation with zinc dust to achieve an acceptable current efficiency and high purity metal product for the economical production of zinc. Zinc provides a strong thermodynamic driving force for the cobalt cementation:"

Jan 1, 2016

By C. J. Sullivan

Many metalliferous ?provinces are co-extensive with particular groups of sedimentary, volcanic, or :basic plutonic rocks. Deposits may be truly syngenetic (Rand, Rhodesia-Katanga, Mans-field, Blind River, White Pine); re-. concentrated by circulating waters (Colorado Plateau, Red Bed Coppers) ; or re-concentrated thermally during metamorphism and granitization (most uranium and lead-zinc provinces ?and some copper and gold provinces). Basalts may yield important cop-per provinces when folded and re-heated. Granitization of basalts which have not reached the chlorite-carbon-ate phase of metamorphism may produce copper provinces. If they reach ?the chlorite-carbonate stage, granitization may result in a gold province. Copper and copper-nickel provinces may result if gabbros are granitized, and a ?similar alteration of per-idotite may result in asbestos or nickel ores. Many similar associations are known. Granite is not a source of ore, but a result of heat. A classification of ?ore with respect to source rocks is of greater prospecting value than are classifications based on magmatic differentiation and hydrother-mal solution theories. Volcanic centres are important ore foci because the thermally unstable metallic sulphides may be concentrated here by a distillation process. The ores found in the hot spring deposits, viz., mercury, mercury sulphide, sulphur, and the compounds of ?antimony and arsenic, are not those which are soluble in water at low temperature (epithermal sub-division of hydrothermal class), abrut those which are unstable thermally at comparatively low temperatures . Water is one of the most common thermally unstable minerals, and generally accompanies the thermally activated ore-forming sulphides.

Jan 1, 1957

By L. Heber Cole

In making this plea for a better and more sympathetic understanding of the non-metallic industry, I do not for one minute wish to give the impression that I in any way belittle the wonderful strides that have been made in the exploitation of our metallics. We in Canada can be justly proud of our Sudburys, Norandas, Flin Fions, and of the remarkable growth of the Consolidated in British Columbia, and at the same time, without in the !east detracting from these worthy undertakings, be equally as proud of our asbestos, gypsum, salt, and coal deposits, as well as of our building-stone and limestone industries. If, in my remarks, I have occasion to compare the metallic with the non-metallic industry, I do so, not with any idea of dimming the glory which the metallics of Canada have gained- not only in our own country, but in the world at large-but for the purpose? of bringing to your attention the fact, perhaps not very well recognized, that Canada contains deposits of non-metallics well worth y of your serious consideration. In the past 33 years, namely, since 1895, the value of non-metallics produced in Canada has exceeded the value of metallics in 19 of the years, and for the last three years has been increasing rapidly. The war years (1915-1918 inclusive) naturally saw an intensive metallic production, but since that time, with the exception of 1925, when there was a general depression throughout the whole country, the non-metallics have been in the ascendency.

Jan 1, 1929

By P. Hansman

"Place Dome Canada's Detour Lake Mine is a low-grade gold producer located in northeastern Ontario. Production is targeted for 2850 tonnes of ore per day. As reserves and mining areas continued to be found below and far to the west of the shaft (Fig. 1), it became necessary to review and upgrade the materials handling facilities. This paper deals with the selection, design and construction of an underground crusher and conveyor system capable of handling up to 450 tonnes per hour from the lowest existing level in the mine.BackgroundThe Detour Lake mine site is accessed via secondary Highway 652 which runs northeast out of Cochrane, Ontario. The road consists of 200 Ian of hard top followed by 100 Ian of well maintained gravel to the mine site. A 1500 m airstrip is maintained at the mine site for emergency use. Prior to 1991, the workforce was flown to and from the mine site. Crews were now bused to the site from Timmins. Remnants of a winter road exist to the southeast which at one time ended in La Sarre, Quebec. This was the route used to haul bulk items during the construction period and early production years.A town site has not been established at the site for the current operations. Instead, a rotational scheme is being utilized whereby most personnel will work seven days on site followed by seven days off site. For some employees, however, the work week is termed as a four/three schedule where they work 42 hours between Monday at 10:00 a.m. and Thursday at 4:00 p.m. with the following three days off. All surface employees and maintenance employees underground work 12-hour shifts. All underground employees work a lOV2-hour shift. Supervisors work a similar schedule as their crews, however, other staff may overlap their rotation during the week.A five-compartment shaft was sunk in 1984 from surface to the 610 m elevation. Shaft stations were established at the 120 m, 260 m, 360 m, 460 m, and 560 m levels. The cage compartment consists of a single deck, 4O-man cage in balance with a counterweight. The cage hoist is an Ingersoll-Rand 10H and is regulated to travel at 4.1 m/s. Two 9 t skips operate in balance at a travel speed of 7.1 mls. The skip hoist is a 3.05 m drum Nordberg. Both hoists are automated to function without a hoistman during normal skipping and cage service runs."

Jan 1, 1995

By K. Heid

"Although concentrated efforts have been made to deplete PCB transformers from the Canadian environment, numerous transformers (as well as ballasts, capacitors and magnets) continue to exist throughout the Canadian mining industry. The existing installed base is slowly being phased out as environmental issues come under increasingly high profile. The following article identifies the potential problems of owning PCB transformers and offers some solutions for their removal, disposal and replacement. IntroductionPolychlorinated Biphenyls (PCB) are synthetic chemical compounds consisting of chlorine, carbon and hydrogen. PCB was widely used in transformers due to its physical properties, including stability, low flammability and non-conductivity. Use of PCB in electrical equipment has been banned since 1977 when the extent of environmental contamination was discovered.Although PCB’s have been outlawed for use in electrical equipment since the late 1970s, safe storage regulations were not addressed until 1988 when a major spill prompted the federal government eventually to issue the storage of PCB Material Regulations in 1992. These regulations replaced the Interim order of 1988 under the Canadian Environmental Protection Act.PCB transformers are usually referred to as askarel filled transformers or as PCB contaminated mineral oil transformers. Askeral transformers were designed to contain high concentration PCB fluids, referred to as askarel. Mineral oil transformers were not designed to have PCB concentrations but were inadvertently contaminated during manufacture or maintenance activities."

Jan 1, 1998

By F. McGravie, S. T. Solinski, W. W. Robertson

During this, the Centennial year of the discovery of the Hall-Heroult process, it seems appropriate to review some of the developments which have taken place in Canada and to explain why it has become an important world centre for the production of primary aluminum. For many years after it was recognized that the element aluminum existed, scientists were frustrated in their efforts to isolate it. In the early 1800s H. C. Oersted and Frederick Woehler prepared small quantities sufficient to measure some of the physical properties. A quasi-commercial process involving reduction with metallic sodium was developed by the French scientist H. St. Claire Deville in 1855 but the cost was very high ($30. 00 per kg). It was not until 1886 that Charles Martin Hall in the United States and P.L.T. Heroult in France, more or less simultaneously but completely independently, discovered the process which is essentially that in use today. Some of the early pioneers in the industry quickly recognized the potential of the hydro-electric resources in Canada as economic energy suppliers for aluminum production. The first commercial production in Canada was in Shawinigan, Quebec in 1901, only 15 years after the process was discovered. Subsequently operating plants were established at nine different locations in Canada (Quebec and British Columbia) (Table 1). Operations continue today in all locations except one (La Tuque). The table shows present plant capacity which for the older plants was reached in an evolutionary manner including replacement of obsolete capacity or upgrading and modernization of existing designs.

Jan 1, 1999

By W. Petruk

"D. Doyle How large is the beam to which you referred? Are we considering Watts, Griffis the probe of a 1 micron sized particle?& McOuatReply Yes. The beam would be about 1 micron. We could enlarge or reduce it depending on the current in-put.D. Doyle Then chemically bound material we might not see. If you are restricted to 1 micron then you would not be able to separate things smaller than this. Is this not so?Reply We won't be able to analyse it but we will see it as the scanning electron microscope has a resolution down to about 0.1 microns. We should be able to get the general composition of such a grain plus its surrounding grains. We feel we can then make a reasonable estimate if it were as small as 0.1 microns. An accurate analysis would be achieved with grains of 3 and 4 microns.D. Doyle Would this have an application in the hydrocarbon field?Reply The lowest atomic number would be sodium. We wouldn't be able to go below that atomic number. Anything with sodiumor a larger atomic number would enable us to analyse the carbon.M. Fairwether Do you have any policy relating to priorities. For instance areCominco companies going to be limited in the amout of samples permitted to give everyone a chance because quite frankly our company, and I'm sure all base metals companies can hardly wait for the installation of this equipment. I can forsee two years back-log of work in the first month.Reply Quite frankly, I haven't looked at this. At the present time the work is under the START program but I suppose we will have to look at possible changes. Anything under the START program has first line priority.B. Thorndycraft Will the briquetting of samples be automated as well? Pinson MiningReply No, not at this point. Our polish section laboratory is first-class and can turn out 18 polish sections a day which is more thar we can handle.B. Thorndycraft With the capability of this machine to operate in a hands-off manner perhaps it could start to look for the 5 micron gold particle in tailings?Reply I have such a program using a wave-length spectrometer rather than the energy dispersive. The wave-length spectometer is about 10 times as sensitive and would scan the section much faster. A one inch diameter polished section would be scanned in about 7 hours for anything 1 micron or larger."

Jan 1, 1984

By Ursula M. Franklin

Old iron nails are one of the most common objects which entice the general public to ask questions about the history of metallurgy. There is a lot of history in old nails - history of the manufacturing industry, and social and economic history. Nails, therefore, are fine teaching tools; whether students have to acquire metallurgical skills or explore the structure and properties of wrought iron, whether they want to look into the history of inventions and the development of machinery, studying nails tells a story better than any teacher or any book. I have used this approach often and the following note is based on several student projects, particularly the work of Carmina Herrero and Vicky Marchant. Nails, those essential metallic fasteners, have long been with us. Their size, shape and design is basically a compromise between the makers' ability to control and manipulate material and the demands of the intended application. There were copper and bronze nails in antiquity, but in this paper I want to deal only with iron nails. In Rome, iron nails were common, and Cleere carried out the fine metallographic investigations on a large stock of nails recovered from a Roman fort site in Scotland. Those nails were hand forged; sorting them at the site on the basis of length, shape of head and shape of shank (in cross section) indicated that there seemed to have been some nail standardization. It appears that the Roman smiths used a series of heading dies starting with a 1/s-in. size. Each successive size increased by approximately 1/16-in. The metallographic inspection of the microstructures of the nails showed that the smaller nails were made in the one operation; i.e. both the tapering and the formation were accomplished on the heated rod without reheating. However, in the case of the larger nails, the nail had to be reheated for the tapering after the head had been forged. Most nails were tapered on all four sides of the shank and the shanks were square in cross section; only one group had rounded shanks. Most heads were flat disks, but in one group the heads were pyramids and another group had conic heads. Figure 1 shows the procedure used to produce the pyramidal heads. Obviously, Roman nail making was sophisticated and each nail design was meant for a particular use.

Jan 1, 1999

By M. N. Collison

"In 1960, with the opening of the Chisel Lake mine near Snow Lake, Manitoba, the Hudson Bay Mining and Smelting Co., Limited, commenced a new phase in their mining operation -that of bringing ore to Flin Flon over 100 miles of railroad.The schedule of operations required to accomplish this, together with an outline of some of the problems of handling ore at 40° and 50,0 below zero, are discussed. The facilities required to thaw and unload from twenty to fifty cars per working day are also described."

Jan 1, 1966

By D. L. Millar

The hydraulic air compressor (HAC) is driven only by water, held up by a dam, to create relatively low head (typically 10-20 metres), such that the developed hydropower is used to cause flow in openings deeper underground. Air is entrained in the water at the inlet to the sub-surface openings (an air to water volume ratio of 1:1 is reported to be optimal) and is compressed as it is carried along by the deepening water flow. At depth, and with lower water velocities arising from larger cross sectional area tunnels, air bubbles separate out of the water flow and are collected in a receiver space above the flowing water. Water, free of air, then passes back up a return shaft (up-pipe) and rejoins the river or stream flow. In principle, an HAC can produce any pressure and flow rate required, given large enough shafts and enough water supply with head sufficient to overcome frictional resistance in the sub-surface tunnels. Practically, as air solubility in water increases with pressure, HAC installations with depths greater than 100 metres may lead to higher rates of compressed air loss, without special separation measures. A modern HAC application for mine refrigeration and cooling is presented.

Aug 1, 2013

By P. Tarassoff

Extractive metallurgy is concerned with the winning of metals from their ores and concentrates. It is therefore not unexpected that extractive metallurgy in Canada has always been closely linked with mining. The discovery and exploitation of new orebodies has provided the impetus for the building of many of our smelters and refineries - past and present - and for the development of new metal extraction processes. The purpose of this paper is to provide a brief overview of those early metallurgical developments, and to highlight the continuing expansion and diversification of the Canadian metallurgical industry.

Jan 1, 1999

By Dan Zou, Ji Chen, Deqian Li

"Bayan Obo mixed RE concentrate is the largest RE source in the world. RE elements occur dominantly in bastnaesite and monazite. This paper describes a clean and green technique for processing Bayan Obo mixed rare earth (RE) concentrate. A two-step oxidation method can lead to the effective recovery of REs, thorium (Th), fluorine (F) and phosphorus (P). Ce has a property of valency change, enabling the separation of it from other RE(III) elements. Making use of the interactions of cerium (IV) (Ce(IV)), F and P, a new extraction system was created to separate Ce(IV) effectively from other RE(III) while recovering F, P and Th by complexing F and P following the oxidation of Ce(III) to Ce(IV). The method includes two parts. Firstly, bastnaesite is oxidized by air roasting and sulfuric acid leaching. And then a first leach liquor containing Ce(IV), F and P is obtained. Secondly, monazite was converted into REhydroxide through alkaline attack and then Ce(III) in the RE-hydroxide was oxidized into Ce(IV) by wetair oxidation. After sulfuric acid leaching the oxidized RE-hydroxide, a second leach liquor is obtained. The two parts of leach liquor containing Ce(IV), F and P are then extracted by Cyanex923 to obtain CeO2, CeF3 and CePO4 based on the complex of Ce(IV) with F and P. The raffinate was further extracted by the primary amine N1923, and Th-product was recovered as ThO2. The RE elements recovery yield during the whole process is greater than 92%. The new technique not only provides a new way for Bayan Obo RE ore utilization, but also avoids resource waste and environment pollution.INTRODUCTIONRare Earths (REs) refer to lanthanides, including scandium and yttrium. Owing to the similar structure and property of RE(III), it is difficult to separate them from each other, especially for the adjacent elements. According to the United States Geological Survey, in 2010, the whole world has about 142 million tonnes of rare earth reserves. In that, China ranks the second with 22% following Brazil which ranks first with 32% (Cheng, 2011). There are three main RE ore types in China with about 80% mixed ores in Bayan Obo, 10% bastnaesite ores in SiChuan and ShanDong province and 2.9% ion adsorption ores in Southern China. Bayan Obo mixed RE concentrate consists of bastnaesite and monazite. The concentrate contains CeO2/_REO of 50% and there are 7–8% F, 4-6% P and 0.2–0.3% Th."

Jan 1, 2016

By W. D. Mulholland

"I ASSUME that any effort on my part to deal with the question of the importance of the mining industry is going to be largely an exercise in preaching to the converted, but there are one or two aspects that I'd like to particularly mention.The first is that, in terms of almost all factors, the mining industry is a very important industry in Canada. It is important in terms of employment in relation to the gross national product of Canada and it is particularly important in the international trade of Canada. So far from being insignificant domestically, it is also an extremely important factor in the international picture. That's an important point to bear in mind, because as we talk about all the other matters we never can lose sight of the fact that mining management always has to be conscious of its international competitive position. It is something that one forgets at one's peril, and to a somewhat greater extent than is true of many other industries, those managements have to compete in an international context for their markets, to some extent for their people for specialized skills and of course for finance. In the evolution of domestic policies it is a very, very perilous step to take to impair that competitive ability of the domestic mining industry."

Jan 1, 1972

By E. Ghali, A. D. Bas

"Treatment of oxide, e.g. roasted gold ores has received relatively less attention than sulphidic ones and recently, handling of oxide gold ores is becoming essential. In this study, the influence of roasted gold ore (RGO) slurry (at 35% solid ratio) on the electrochemical dissolution of gold has been examined using pure gold and iron oxide minerals (hematite, maghemite, and magnetite) as disc electrodes by zeroresistance ammeter mode either in one or two separate containers. The presence of slurry decreased galvanic currents, i.e. corrosion rates due to the release and increase in the amount of soluble and/or insoluble species that could retard further the anodic behaviour of gold. Higher galvanic currents were observed in two separate containers than that in one container indicating the primary importance of galvanic interactions. SEM-EDS results observed iron hydro/oxide coatings on gold surface in case of magnetite test. However, in case of RGO electrode it is not a perfect passivation, although somewhat decreasing trend was observed on gold dissolution. These findings have revealed that passivation is not only a laboratory phenomenon, but also it could be responsible for the slowdown of gold dissolution in industrial practice.INTRODUCTIONThe cyanidation of gold is an electrochemical corrosion process thus; the dissolution of gold can readily be studied by electrochemical techniques. The outcome/summary of previous electrochemical studies of gold leaching can partially be summarized as follows: Filmer (1982) and Lorenzen and van Deventer (1992) reported the negative effect of pyrite and pyrrhotite on gold leaching due to the galvanic interactions; Aghamirian and Yen (2005) studied gold galvanic corrosion in presence of sulphide mineral electrodes only in one cell using zero-resistance ammeter (ZRA) mode; Dai and Jeffrey (2006) discussed, individually, the anodic and cathodic behaviours between gold and sulphide minerals, and Azizi et al. (2010, 2011) used a bed reactor to examine the influence of sulphide minerals on gold dissolution in one and two separate cells. Accordingly, a slowdown in gold leaching has generally been attributed to the passivation phenomenon, although the indication of this phenomenon is still an undergoing debate. For instance, Mrkusic and Paynter (1970) identified the passivation as the film formation of dissolved species from calcine, Crundwell (2014) explained passivation, in the case of corrosion of metals, as the formation of a layer which is composed of a new chemical species on the mineral surface and this layer inhibits or blocks further reactions. He suggested that passivation is related to the oxidation of the metal, and the formation of a passive layer that retards the rate of dissolution by several orders of magnitude. Consequently, galvanic interactions, passivation phenomena, or combinations of them are considered significant electrochemical factors affecting gold dissolution (van Deventer, Reuter, Lorenzen, & Hoff, 1990; Azizi, Petre, & Larachi, 2012). It is important to note that generalizing the influence of a mineral/metal on gold dissolution may not be correct in all cases, since contrary behaviours/results (for pyrite) have been observed (Aghamirian & Yen, 2005). Therefore, electrochemical study of gold is still a subject of research and need to be examined further in detail."

Jan 1, 2016

By Z. D. Hora

Commercial production of barite commenced in British Columbia in 1940; shipments have been recorded from ten deposits, of which four are particularly significant: The Brisco, Silver Giant, Parson, and Mineral King mines. Parr of the barite production is a by-product of base metal deposits in which barite is a major gangue mineral. About one hundred occurrences are known. COMMERCIAL production of barite in British Columbia dates back to 1940. Production volumes rose and fell and reached 39,900 tonnes in 1972. The main producer is Mountain Minerals Limited . There are two principal areas of barite deposits in British Columbia: ( I) The southeast part of the province along the Rocky Mountain Trench , which is the source of all production to date. (2) Stratabound occurrences in northeast British Columbia in the Gataga-Ketchika rivers and Muncho Lake areas which are not yet developed. Of the approximately one hundred reported barite occurrences, only ten have recorded commercial shipments, some of insignificant amount. So far, four deposits have proved to be important producers: Brisco, Silver Giant, Parson and Mineral King. The Mineral King property is situated near the confluence of Toby and Jumbo Creeks, 35 km southwest of lnvermere. The lead-zinc-copper-iron-barite deposits, as described by Fyles (1959, 1962), replace Proterozoic Mount Nelson dolomites of the Purcell system on the limb in the trough of a complex, tight syncline. The mine operated from 1954 to 1967 and 2,097,900 tonnes of baritic ore that was processed for base metal concentrates and also produced 22,680 tonnes of by-product barite. Since 1970, some 136,000 tonnes of barite have been recovered from the old tailings pond. The deposit is now considered depleted. The Silver Giant mine is located 10 km northwest of Spillimacheen. Barite and lead-zinc sulphides replace Cambrian Jubilee limestone near their contact with the overlying Ordovician McKay slate. Mineralization is located in the nose of an overturned plunging anticline. Between 1951 and 1957 800,000 tonnes of baritic ore were processed for lead and zinc concentrate. After 1959 barite was also produced , first from open pit, and later from reworked tailings. Up to 1979 production of barite totalled approximately 180,000 tonnes. Two other producing mines in the area are descri bed by G.R. Manson (this volume). Large, bedded stratabound barite deposits are reported from northeastern British Columbia. Six major shale-hosted Industrial Minerals in Canada lead-zinc-barite occurrences are known in the Devonian Gunsteel Formation. These are: Driftpi le Creek, Mount Alcock, Cirque, Pie, Fluke and Elf. In addition, numerous occurrences of strati form blebby or nodular barite and locally massive white crystalline barite are known from the Driftpi le Creek and Ak ie River districts in Gunsteel shale and from the Kechika, Road River and Ware map areas from Silurian siltstone . The size of these deposits is impressive; the baritic horizon at Mount Alcock is reported to be 25 to 30 m thick , and dri ll ing results from the Cirque deposit indicate reserves of 30 mi llion tonnes of baritic lead-zi nc-si lver ore. Similar bedded barite deposits are also reported from Midway area, near the Yukon border.

Jan 1, 1984

By P. C. Holloway, M. J. Collins, K. R. Buban

Historically, there has been little incentive to process copper-arsenic concentrates by leaching, rather than via established smelting operations. However, with ever tightening environmental emission standards and more arseniferous concentrates being produced, increasingly sophisticated and upgraded off- gas handling facilities are required in smelting operations, generating greater quantities of challenging metallurgical dust. In this context, oxidative pressure leaching offers distinct advantages. The current state of pressure leach technology delivers high extractions from copper concentrates, while producing an environmentally stable process residue, without atmospheric emissions of sulphur dioxide or arsenic. However, as was shown in an earlier study, copper extractions and environmental leach residue stability are impacted negatively by arsenic levels above 2.5 to 3.0 wt%. In further studies on pressure leaching of copper concentrates, Sherritt has developed process conditions that allow even highly arseniferous (> 7 wt% As) feed materials to be converted into environmentally stable residues, with excellent copper extractions. At the same time, pressure leach residues can be generated that are amenable to silver recovery via direct cyanidation, without pre-treatment by lime boiling or hot curing. The results of pilot plant test work are discussed. INTRODUCTION As the production of copper has expanded over the years, resource exploitation has extended beyond relatively clean, high grade and easily accessible ores, and copper sulphide concentrates increasingly come with higher levels of contaminants, such as As, Hg, Sb and Bi, and lower copper and sulphide sulphur concentrations. However, as concerns on the impact of the emission of such contaminants into the natural environment have mounted, import/export restrictions have made the trading of copper concentrate more difficult, and, in particular, the export of concentrates with greater than 0.5 wt% As; under ever tightening environmental emission standards, these lower quality concentrates can be a significant strain on the off-gas handling facilities in smelting operations. The processing of arsenic bearing copper concentrates is, therefore, an increasing challenge as copper producers seek to exploit more complex mineralization and to extend the life of their operations. In this environment, processing arsenical copper concentrates with high temperature pressure leaching (>200°C) must be considered as an alternative to pyrometallurgical processing. Leaching kinetics for copper minerals at these temperatures are rapid and acid is generated for potential use in heap leach operations. Pressure leaching of copper concentrates eliminates gaseous emissions of arsenic and sulphur, while generating environmentally stable residues, as measured by the Toxicity Characteristic Leach Procedure (TCLP) (Kalanchey et al., 2007). Both medium and high temperature pressure leaching of copper concentrates have also proven themselves technically on an industrial scale (Marsden et al., 2004) with high copper recoveries.

Jan 1, 2019