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Infrared spectroscopic data collected using HyloggerTM technology is being used to assess the mineral composition of Archean iron ore bedrock and Cenozoic detrital units in Western Australia’s Pilbara region. Analysis of infrared spectra enables quantification of: (1) composite iron mineralogy, (2) composite clay mineralogy, (3) hydrous silicates and (4) carbonate mineral abundances. Stratigraphic and rock mass unit logging of core has identified several detrital and bedrock units recognisable across the Pilbara. However, due to alteration related to mineralisation, weathering and later stage precipitate overprinting, it can often be difficult to assess the detrital-bedrock boundary and the occurrences of specific geotechnical units in the detritals and bedrock, particularly when using non-core drilling techniques and traditional geochemical assays. Infrared spectroscopic data collected concurrently on core from several sites has shown distinct correlation against existing unit subdivisions and associated geochemical parameters. Where infrared spectroscopic data have also been collected on rock chips recovered from reverse circulation infill drilling, these correlations allow robust geological and geotechnical models to be developed based on the typical mineralogical-geochemical signatures. The geotechnical sub-units identified in core can be readily distinguished using the various iron and clay minerals captured by the HyloggerTM technology as opposed to total iron, potassium, and alumina captured by geochemical assays. Further, some of the minerals targeted by infrared spectroscopic analysis (eg gibbsite, white mica, vitreous goethite) and their ubiquitous presence as the products of weathering, assist in recognition of various ancient weathering surfaces and help to define the origin of the material, whether bedrock or detrital. Overall, HyLogging of core and chips allows important mineralogy focussed data to be captured at minimal additional financial outlay. Correlations against geochemical unit identifiers are robust both within deposits and between deposits. Significant improvements in the confidence of geological and geotechnical models are attained.

Jan 1, 2015

By B. Arsenault

Aluminum coatings can provide galvanic cathodic protection for several metals and alloys, In order to be a suitable protective solution on structural components, the mechanical integrity of the component must be preserved, In particular, fatigue properties are a challenge for thermal-spray protective coatings on mechanical structures, To address the issue of the fatigue integrity of 7075 aluminum alloy with an arc-sprayed protective coating, different surface preparations prior to arc spraying were considered, In the present work, a feasibility study was performed using laser ablation as a surface-preparation technique before or during arc spraying of coatings, This was collaborative effort between the LERMPS laboratory in France, the National Research Council Canada and the Royal Military College of Canada, Both fatigue and adhesive properties of aluminum coatings were evaluated in relation to substrate-surface-preparation techniques including laser ablation (Protal® process), grit blasting and shot peening. Results indicate that a combination of key conditions, including the use of nitrogen as the arc spray gas, shot peening, and proper laser energy density for ablation, provide high fatigue resistance of metallic coated 7075 alloy substrates. Specimens prepared under these conditions show a similar fatigue resistance to uncoated substrates.

Jan 1, 2005

By Sh. Karimidorabati

In the construction industry, project changes constitute a major cause of delay, disruption, cost increases, poor quality and unsatisfying performance. They are also known as a main factor of litigation between the owners and constructors. Construction projects are essentially process-based, and with the critical role of Information Technology (IT) in this industry, projects, especially mega projects, are being managed remotely. The volume of data and documents, such as Requests For Information (RFIs), different types of Change Requests (CRs) and Project Change Notices (PCNs), being transferred and exchanged amongst the stakeholders of a project is considerable. The circulation of these documents amongst project stakeholders still heavily relies on two methods or levels for management of change process; Conventional (fully paper-based, Faxes, Snail mails) and Electronic or semi-automated (Email, Internet, PDF files). These two methods are dependent on human discipline to follow specified processes which often break down because of human nature. This creates serious compliance problems. It is hypothesized here that fully that automated process-based management of change can lead to better compliance, more efficient management of change, and reduction of time and cost of data exchange. An approach of doing this is presented in this paper. Ultimately, its impact should improve project performance. Conclusions are presented on time savings and improved compliance.

Aug 1, 2013

By J. Drenda

The model for methane removal from the workings directly behind an advancing longwall as presented in this paper may be used for U-ventilated cross or length-wise systems of longwall advance, starting from the boundaries of the extraction field. In mines with high methane concentrations, Uventilated longwall extraction from the boundary of the extraction field produces a methane risk. The risk is manifested by a higher methane concentration at the end of the longwall, upper gate and incline. The methane in increasing concentrations, which is emitted mainly from the workings with caved areas, appears towards the end of the longwall and in the upper gate. The graphical model of the longwall provided includes both the workspace of the longwall and the caved area. Based upon a model of the rock distribution in the cave, a ventilation model comprising two standard air splits and large number of crosswise air splits has been constructed. Simulations indicate that if the shearer is not present in the longwall, the air distribution in the caved area is symmetrical. The presence of the shearer, both at the bottom and the top of the longwall, causes an asymmetrical air distribution in the cave, that is the asymmetrical flows in the goaf and longwall workspace and in the inflows and outflow between those regions. This phenomenon causes an increase in methane concentration at the end of the wall and at the upper gate. The methane removal method proposed for workings with a caved area directly behind the advancing U-ventilated longwall, starting from the boundary of the field, consists of the removal of methane-air mixtures from the caved area with the boom pipes. These booms may be of several meters long and may be extended if necessary. The insertion of the boom pipes into the cave towards the end of the longwall and connecting them with the general methane removal system creates negative pressure causing a change in the depression field, which is the aerodynamic potential field in the goaf area around the ends of the boom pipes. This will promote the extraction of the methane-air mixture from voids and the goaf cracks, and the area from which methane is being extracted may extend to the side of the cave. This is a positive phenomenon, which could result in the methane flow from the goaf into the airflow in the longwall workspace decreasing or even stopping. A reduction in the methane flow into the longwall workspace with extractions booms will be advantageous for the production continuity. Based on the floor load model for the rocks in the cave and the methane-removal boom load model, the value of the force required to move the boom behind the advancing wall has been calculated. Strength calculations for the pipe were performed using a finite elements method. The analysis results, as well as the comparison of the pipe material effort to the strength parameters of steel, which can serve as piping material (for the assumed load conditions), lead to a belief that the proposed boom construction satisfies the strength requirements.

Aug 1, 2013

By W G. Brese

The attention of the world is being focused on the spectacular rise of elemental sulphur production in Alberta. In the short space of a decade, production has increased from less than 10,000 long tons, in 1952, to al-most 1,000,000 long tons in 1962. Moreover, 1963 sulphur production is expected to rise by 50 per cent to approximately 1,500,000 long tons, and further increases are forecast for ensuing years. The reason for this dramatic in-crease in elemental sulphur production, particularly in the last year or two, is that Alberta elemental sulphur is recovered in association with the production of sour natural gas. When very large volumes of natural gas began moving to U.S. markets in the latter part of 1961, the resultant increase in sour gas production led to a marked increase in the production of sulphur. Consequently, Canada, mainly on the strength of sulphur produced in Alberta, will soon become the second largest producer of sulphur in the Free World

Jan 1, 1963

By Jose Alberto Gonzalez, Said Sharif Mahboob, Jeffrey L. Shepherd

"During the industrial electrowinning of zinc, uneven growth can cause short-circuits and make the deposits more sensitive to the presence of impurities that can significantly impact current efficiency. To produce levelled zinc deposits, additives such as glue, licorice and sodium silicate are often added to the electrolyte. Even in the presence of additives, uneven zinc growth still takes place because of the combination of hydrodynamic and electrolysis conditions in the cell house. Recent advancements in imaging spectroscopy and scaling analysis have opened an avenue to further study the effects of additives on zinc growth morphology. In this study, Atomic Force Microscopy (AFM) and scaling analysis have been used to monitor zinc growth characteristics including roughness, periodicity, aspect ratios and growth mechanisms as a function of electrolyte composition as well as deposition time. Zinc was electrodeposited from an industrial electrolyte containing a host of additives onto an aluminum cathode with a platinum wire serving as the anode. AFM images of the samples were collected to obtain 3D topographical information on which scaling analysis was performed to extract details on root-mean-squared (rms) roughness, periodicity (grain size), aspect ratio of surface features and growth mechanism. This analysis provided information on the mechanism by which the previously mentioned variables can impact short term growth and also provided a prediction of expected growth at long deposition times.INTRODUCTIONElectrowinning is one of the final stages in the industrial production of zinc metal. It is during this process where dissolved zinc ions undergo electro-reduction from an acidic electrolyte onto an aluminum cathode and are later recovered by stripping the zinc metal from the substrate. However, due to the nature of zinc growth as well as the various operating conditions, zinc deposition may occur unevenly, sometimes causing short-circuits that can cause electrode damage and reduced zinc production."

Jan 1, 2016

By Marek Mika

This Paper has been prepared to be presented at the 23rd World Mining Congress & Expo ? Montreal 2013. It presents the idea how to carry out the shaft sinking operation, going through highly water-bearing and very weak rock strata, giving as an example one specific shaft sinking project which is being executed for one of the Polish collieries by our Shaft Sinking Company Content 1. Introduction. 2. Hydrogeological conditions within the area of the shaft. 2.1. Hydrogeological conditions assumed at the stage of designing. 2.2. Hydrogeological conditions encountered in the course of sinking. 3. Designed shaft lining. 4. Procedures for the shaft sinking. 4.1. Designed procedures of the shaft sinking. 4.2. Procedures for preservation and strengthening of the shaft lining and the surrounding rock strata. 5. Technological guidelines for proceeding with the shaft sinking ? selection of special methods. 6. Options for mechanization of work for the selected method. 7. Conclusions.

Aug 1, 2013

By G. Danha, S. Wabula, D. Glasser, D. Hildebrandt, N. Hlabangana

"Impact tests on single particles or a bed of particles are used to determine the fracture characteristics of particles. Many different techniques have been adopted in comminution in order to find ways of optimizing energy consumption in the size reduction process. In this paper, we apply one such method called the Attainable Region (AR) analysis technique to optimize the impact energy on a bed of silica particles. The attainable region is a fundamental approach that is equipment-independent and can be used to analyze breakage processes. The AR is defined as a set of all possible outcomes, for the system under consideration that can be achieved using fundamental processes operating within the system.INTRODUCTIONThe energy crisis in Southern African has reached such critical levels, that most cities in countries like Zambia, Zimbabwe, Lesotho, Swaziland and even South Africa are experiencing load shedding challenges lasting sometimes up to 18 hrs a day. Southern Africa is well known for its riches in mineral resources, and the economies of most states in this region are driven by the mining & mineral processing sector. With the emergence of small scale miners due to government empowerment policies, national energy providers have had to resort to power cuts mainly to domestic users in a bid to cope up with the huge industrial electricity demands.It has been estimated that about 4% of the total energy used in the world is consumed by the mineral processing sector (Fuerstenau & Lutch, 1999). Tomanec and Milovanovic (1994) estimated that milling alone accounts for more than 50% of the total power used in mineral processing, but this can rise to as high as 70% for hard or finely dispersed and inter-grown ores. Today, the greatest challenge in mineral processing is how to optimize energy input to the size reduction process (Dey & Das, 2013; Nomura & Tanaka, 2011), where it has been observed that only a small percentage (1.5%) of the total energy input really does the breaking (Khumalo et al., 2008) while the rest is consumed by the equipment concerned and lost to contacts that do not result in breakage. The immediate benefits of focusing research on the optimization of energy in size reduction operations in the mineral processing sector lies in potential savings on industrial electricity usage that may then be directed towards domestic users."

Jan 1, 2016

By T. S. Smith, C. C. Rennie

"THE LEAD-ZINC and tungsten mines of Canadian Exploration Ltd are on Iron Mountain, 8 miles south of Salmo, B.C., in the Nelson mining division. Relative location of the mines is shown on the general plan.First recorded lead production was in 1908 from surface outcrops. Small amounts of high lead ore were mined intermittently until 1926. No major lead-zinc production occurred until 1949 when outcroppings on the south side of the mountain were mined and diamond drilling began to prove the existence of a large replacement orebody. Lead-zinc ore has been mined continuously from the Jersey orebodies since March 1949, with monthly tonnage as high as 50,000 tons per month, but currently averaging 30,000 tons per month.Schee1ite-bearing tungsten ore was found in 1942 by H. Lakes in an old adit and open cuts at the north end of the Emerald tungsten orebody. The Emerald tungsten mine was developed by the Federal Government as a Wartime Metals project and operated for eight weeks in the fall of 1943, when the poor demand for tungsten closed the mine. Canadian Exploration Ltd. purchased the mine in 1947 and mined in excess of 100,000 tons in 1947-48 until the demand for tungsten dropped again and interest was centred on lead-zinc. The Federal Government repurchased and reopened the Emerald Mine in 195 L and built a new concentrator. The mine and mill were sold back to Canadian Exploration Ltd. in 1952.Regional Geology and IntrusivesThe host rock for both the lead-zinc and tungsten mineralization is the Laib formation of Lower Cambrian age, which consists of 400 feet of crystalline limestone underlain by beds of argillite, and argillaceous limestone locally altered to ""skarn"" or ""tactite"". The Laib limestone is overlain by black argillite and underlain by the Reno quartzite of Pre- cambrian age. Repetition of folded beds has allowed the interpretation of the large isoclinal fold which repeats the limestone (see general cross-section). Dolomitization and the associated lead-zinc ore have been found only in the right-side-up limestone and are not known in the overturned limestone.Two elongated stocks of granite cut the sediments. The Emerald stock outcrops along the east side of the Emerald tungsten mine and again west of the Jersey workings, while the Dodger stock outcrops only at the north end of the Iron Mountain. The shape and attitude of these bodies are believed to have been governed partly by pre-granite faulting and partly by pre-granite folding of the sediments. Although some forceful intrusion may have occurred the detailed granite surface indicates a gentle stoping emplacement."

Jan 1, 1949

By G. Russo

During the construction of the S.Martin La Porte access adit, 9m in diameter, extreme squeezing conditions occurred while crossing Carboniferous schistose formations, with diametric convergence up to 2m. Back-analysis of monitoring results shows that an acceptable simulation of the observed excavation behaviour can be derived using a combined analytical and numerical approach, with simple elasto-plastic laws but a progressive reduction of residual parameters and a relevant increase of dilatancy.

May 1, 2009

By H. Hejny

Given the current status of political discussion in Europe about raw materials issues, the sustainable development of the extractive industry and the reduction of its environmental and societal footprint are among the key topics in this discussion. In this context, the European Commission approved the EO-MINERS project (Earth Observation for Monitoring and Observing Environmental and Societal Impacts of Mineral Resources Exploration and Exploitation). The overall aim of EO-MINERS is to bring into play EO-based methods and tools to facilitate and improve interaction between the mineral extractive industry, authorities, and the society in view of its sustainable development while improving its societal acceptability. Developing generic, standardised and reliable EO-based products to monitor the environmental and societal footprint of mining projects is the way chosen by EO-MINERS to improve this interaction, along with the organisation of tripartite meetings gathering all relevant stakeholders. The project uses existing EO knowledge and carries out new developments on three demonstration sites (Sokolov lignite mining area, Czech Republic, Witbank coal field, South Africa, Makmal gold mine, Kyrgyzstan) to further evaluate and demonstrate the capabilities of integrated EObased methods and tools in monitoring the environmental and societal footprints of the extractive industry during all phases of a mining project, from the exploration to the exploitation and closure stages. It contributes providing reliable and objective information about affected ecosystems, populations and societies, to serve as a basis for a sound ?trialogue? between corporate stakeholders, governmental organisations and societal stakeholders. The project already developed a set of consolidated indicators based upon previous knowledge about mining-related issues along with interviews of national, regional, and local stakeholders. These indicators reflect known environmental and societal issues at mining sites as well as the interest of various relevant stakeholder groups. The process described in the EO-MINERS project ? policy assessment > indicator identification > choice of suitable EO tools able to serve monitoring task > monitoring by EO tools > making available objective information for fair dialogue among stakeholders ? is generally applicable to all stages of a mining project. The key to success will be the right choice of indicators addressing the problem and subsequently the right choice of suitable EO tools and finally the willingness of all stakeholders to find a common solution. To this end, the EO-MINERS project organises site-specific ?trialogue? workshops at each demonstrations site, which aim to provide relevant information in adequate quality to the stakeholders as common ground for discussions. Local stakeholders, including mining companies, regulatory bodies, and community representatives are invited to participate in these workshops where the relevance of the developed EO-based products to environmental and societal impact assessment will be discussed. The presentation will discuss results obtained during these trialogue workshops, as well as the success and difficulties and reluctances encountered. The project will further indicate ways and means how the EO products and other project results may be used for monitoring purposes in all phases of a mine.

Aug 1, 2013

By W. J. D. Stone

"For several years, the existence of a deposit of barite (BaS04) near Brookfield, Nova Scotia, has been known. A very large deposit of strontium (SrS04) near Sydney, Cape Breton, is a more recent discovery. Cape Chemical Syndicate has been formed to work the deposits. A five-million-dollar integrated mineral processing and chemical plant is planned for Sydney to produce various compounds of barium and strontium. The mineral processing plant includes the Jones Wet Magnetic Separator and will produce high-purity barite and celestite. These products will be processed further in the fine grinding plant and the chemical plant. The general project is described, covering the deposits, processing and markets."

Jan 1, 1969

By H. Salamanca

HighService has developed different equipment using wireless technology and machine vision systems that were specially designed to allow 1) the online determination of the SAG mills liner's service life, 2) the automatic detection of a missing dipper tooth in mineral extraction shovels, 3) the reduction of accident risk potential in the mineral transportation within the mine, and 4) the reduction of collision risk potential between shovels and wheel dozers during mineral extraction. For the development of all these systems at HighService, extensive research has been done in radio frequency and image processing fields. The integration of both technologies with the expert knowledge of the company on the typical harsh environment conditions of the mining industry has led to the development of heavy duty equipment that tolerate the extreme mechanical requirements of SAG mills and electrical mining shovels.

Jan 1, 2007

By M. J. Latva-Kokko, T. J. Riihimäki

"Oxidation autoclaves are normally operated at elevated temperature and pressure. The improvement in kinetics is due to combined effect of temperature and partial pressure of oxygen. In this paper exclusive effect of pressure has been studied with a low grade sulphide ore at below 100 °C temperature. These studies are related to development of a novel tower-like reactor that utilizes hydrostatic pressure. Technology is designed to generate high amount of effective fluid volume for high solid content slurries with lower energy consumption and improved kinetics compared to normal atmospheric operation.INTRODUCTIONEconomical utilization of low-grade ores requires handling of enormous amount of material. This sets new requirements for process equipment in terms of size and energy efficiency. For example on the field of mineral processing this has lead to a six fold increase in the operating volume of mechanical flotation cells over the past two decades. Ore beneficiation methods like flotation greatly reduce amount of material that needs to be further processed in smelters or hydrometallurgical refineries. However with some ore types, such as nickel laterites and refractory gold ores, traditional concentration technologies cannot be utilized. Thus direct leaching of ground ore could be an attractive option. In many cases normal atmospheric tank leaching has traditionally been a non-feasible option mainly due to high capital and operational expenses induced by large amount of stirred reactors required. Main restriction for increasing reactor size to beyond 500 m3 has been mechanical load and power requirements set by mixing in cases when high dispersion efficiency of gas is required. THEORETICAL BACKGROUNDIn hydrometallurgical industry autoclaves are typically operated at elevated temperature and pressure. In many cases increase in operating temperature is the desired phenomena and improvements in kinetics are strongly related to that. Thus increase in pressure might be induced solely by water vapor pressure. However when gaseous feed is present, pressure itself has a strong effect on leaching kinetics for various reasons and its role should not be neglected."

Jan 1, 2012

By G. W. H. Norman

INTEREST in the mineral possibilities (gold, copper) of northern Quebec, north of the Quebec-Cochrane branch of the Canadian National railway, has centred for many years in the Chibougamau district (see Figure 1). Since 1934, however, promising gold discoveries in the Rose Lake-Florence River section, 115 miles southwest of Chibougamau lake, have widened the interest, and prospectors have examined other parts of the country between Chibougamau lake and Bell river and the surrounding districts. The object of this paper is to !resent an outline of the geology, and to describe the mineral deposits, o part of this region, or, more specifically, of the part embraced by the Opawica-Chibougamau and Waswanipi map-areas(l), which include the districts about Chibougamau lake and Rose lake-Florence river, where mineral deposits are now in course of development either by surface or underground work. Early discoveries, developments, and explorations in the Chibougamau district are well summarized in the report of the Chibougamau Commission, published in 1911(2). The Commission discredited previous optimistic accounts of mineral discoveries in the area, made initially in 1903, but at the same time they expressed the opinion that, from a geological standpoint, the district promised a reward to diligent and intelligent prospecting. Their general conclusion-that prospecting in the area was not then (1911) commercially advisable in view of its inaccessibility and other handicaps shifted interest from the district until, some years later, valuable discoveries were made in the Rouyn area, and aircraft widened the field of successful exploration. During the past ten years or so, considerable energy has been spent in promoting the development of the district. The net result has been the discovery of a number of prospects, the majority of which have been explored only by trenching and, in most cases, diamond drilling.

Jan 1, 1936

By G. Goodlad

This paper describes some of the main aspects involved in implementing the European “Equipment and Protective Systems for Use in Potentially Explosive Atmospheres” (ATEX) Directive (No.94/9/EC) in the British mining industry by the year 2003. It provides a brief background to the Directive and considers its main objective of removing all barriers to trade in Europe. It outlines the need for the European Standards making bodies to write new editions of the ’explosion protection concept standards’ and for manufacturers to adopt new quality management procedures and develop new versions of equipment in conformity with the ATEX categories of “M1” or “M2.” Finally, it assesses the possible future relationship between the European enforcing authorities, manufacturers and users of explosion protected equipment.

Jan 1, 1999

By N. Manopulo, J. Maier, L. Tong, C. Becker, P. Hora

The contribution presents a new finite element approach in which the common updated Lagrangian formulation is replaced by a spatial flow formulation applying a special arbitrary Lagrangian-Eulerian for-mulation (ALE). The description separates spatially the process in a die inside zone and in a profile zone. For the description of the inside zone, where the filling process occurs, a special Euler time independent mesh is applied. By this formulation the mesh has to be generated only once, which simplifies the generation of spatially optimized meshes. For mapping of the material flow during the filling process the method uses a flow surface traction method as applied in casting simulations. A further strength of the new method is the computational efficiency which allows the modelling of extrusion process with the highest complexity with a response time of 12 hours, which is important for the industrial optimization process.

Jan 1, 2015

By J. Drelich

We report structural forces measured for 10 nm silica particles deposited on alumina substrate and 5-80 nm alumina particles on mica using atomic force microscopy technique. For nanoparticles forming clusters, oscillation of structural forces was recorded with a periodicity that is close to the size of the nanoparticles used. Additionally, selected force-separation results indicate that the forces involved between the AFM probe and individual nanoparticles can be studied using the nanoparticle-coated substrates.

Jan 1, 2006

By Yongteng Dong, John P. Quinn, Bradford Wesstrom, Guikuan Yue

With increasingly low-grade copper ores being mined, it is difficult to handle growing concentrations of As, Sb, Bi and/or Fe in the whole flowsheet, especially during copper electrorefining. To better elucidate the effects of those impurities on the quality of cathode deposit and/or current efficiency, a detailed speciation study of the electrolyte under industrial conditions is required to quantitatively describe their distribution in the solution, thereby facilitating their effective control and removal. In the present study, a thermodynamic model of complicated iron-arsenic-copper-sulfuric acid electrolyte under industrial conditions was developed. The main species of those elements involved in the electrolyte were first identified, and their thermodynamic data were collected and critically assessed. Those data were then used to estimate the activity coefficients of species, and to calculate the equilibrium constants from 25°C to 70°C. The developed model provides a mathematical tool that is capable of quantifying the concentrations of free ions and complexes in terms of temperature and solution composition. Finally, oxidation-reduction potential measurements were employed to validate the model. INTRODUCTION In copper electrorefining, impurities like arsenic, antimony, bismuth and/or iron can partially dissolve in the electrolyte and accumulate gradually, and eventually cause problems such as bad cathode deposit (co-deposition with copper or mechanical inclusion from the floating slime), lower current efficiency, etc., which eventually increases the operating costs. The presence of impurities may substantially reduce properties of copper products such as conductivity, corrosion resistance, mechanical properties, and leads to more energy consumption (Schlesinger et al., 2011; Jafari et al., 2017). To remove these impurities, various methods have already been proposed and applied in industrial copper production, such as solvent extraction, ion exchange, chemical precipitation, absorption by activated carbon, etc. (Cunningham et al., 1997; Navarro et al., 1999; Toyabe et al., 1987). In addition, adding reducing agents such as sulfur dioxide and trivalent arsenic could also precipitate arsenic, antimony and bismuth from copper electrolyte, by changing the distribution of impurities with various valence (Braun et al., 1976; Xiao et al., 2007). The disadvantages of those methods include high energy consumption, serious contamination, lower selectivity and efficiency, and so on.

Jan 1, 2019

By M. Kawahara, H. Sunayama

Oxidation rates of the cubic specimens, which were prepared by cutting the shaped magnesia-carbon bricks, were measured continuously with a thermo balance in the temperature range from 1273 to 1 823 K in N2-02 and Ar-02 mixed gas with 2.1 x 104 and 3.7x 102 Pa of oxygen partial pressure respectively. The effect of the graphite content, the maximum grain size of magnesia clinker and the oxygen concentration in the atmospheric gas on the oxidation rate for the MgO-C refractory has been investigated. The value of effective diffusion coefficient of O2, which diffuses through the porous decarburized layer, decreased with the decreasing of the porosity and the oxygen concentration in the external gas phase. It was speculated that the dense layer formed easily due to the high tortuosity of pores and the low recession speed of the carbon interface in the MgO-C bricks.

Jan 1, 2004