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By T. Abu Leil

A new class of ternary Mg-Sn-Ca alloys is being developed to address the dual demands of corrosion and creep resistance at service temperatures. While tin has proven to enhance the corrosion resistance, calcium is expected to significantly increase their creep resistance of binary magnesium alloys. Their effects in ternary magnesium alloys are not yet known. The series of alloys studied has Sn and Ca in the ranges 3-6% and 1¬2%, respectively. The results indicate that these alloys have two-phase structures with CaMgSn phase dispersed in a matrix that is predominantly a solid solution of magnesium. The corrosion behavior of these alloys has been investigated by means of salt spray tests and potentio-dynamic measurements. Creep behavior of these alloys was measured at a temperature of 135 C under an applied compressive stress of 85 MPa. Scanning Electron Microscopy with Energy Dispersive X-ray facility and X-ray Diffraction techniques were used to characterize the microstructures. The results indicate the prospect of designing alloys that can provide optimum combinations of corrosion and creep resistance by adjusting the relative compositions of Sn and Ca in the system.

Jan 1, 2006

By M. Timmins

Campbell Mine operates a 100 tpd gold autoclave that treats sulphide concentrates at 305 psi and 200 °C. Autoclave feed consists of fresh pretreated concentrate, an acidic oxide slurry recycle as well as other high arsenic sources. The brickwork that is used to construct the five compartments of the vessel must be inspected and repaired periodically. Shutdowns are scheduled to inspect this brickwork and at times replace entire sections of the brick walls or lining. It also provides an opportunity to repair or replace other internal features such as agitator blades or oxygen spargers. Mechanics and contractors are scheduled around the clock to perform the maintenance requirements. There are many safety considerations and precautions that must be taken in order to protect the well-being of the workers and minimize damage to sensitive pieces of equipment. Heat, arsenic and lead contamination and confined space issues are just a few of the hazards involved. The following paper will describe how these safety concerns are addressed and will serve as a guide for future autoclave shutdowns.

Jan 1, 2004

By R. P. Hackl, P. G. West-Sells

Carbonaceous gold ores are particularly attractive for leaching by ammonium thiosulfate as the gold thiosulfate complex is not significantly adsorbed by the organic carbon present in the ore. A technically and economically feasible process for treating these ores with ammonium thiosulfate has been developed. In this process, gold is extracted by leaching the ore with ammonium thiosulfate, the solution is separated from the ore by counter - current decantation, the gold is recovered by precipitation with ammonium sulfide, and finally the gold containing product is upgraded by reacting the elemental sulfur present in the precipitate with ammonium sulfite. The precipitation filtrate is recycled back to the grinding step to close the solution balance. Reagent consumption is not excessive. Besides precipitating gold, the precipitation step removes most deleterious solution impurities and converts a portion of the polythionates back to thiosulfate. This paper discusses the optimization of the leaching, precipitation, and upgrading steps. The results of a 10 kg/h pilot plant campaign are also discussed.

Jan 1, 2005

By M. Kawahara, H. Sunayama

Oxidation rates of the cubic specimens, which were prepared by cutting the shaped magnesia-carbon bricks, were measured continuously with a thermo balance in the temperature range from 1273 to 1 823 K in N2-02 and Ar-02 mixed gas with 2.1 x 104 and 3.7x 102 Pa of oxygen partial pressure respectively. The effect of the graphite content, the maximum grain size of magnesia clinker and the oxygen concentration in the atmospheric gas on the oxidation rate for the MgO-C refractory has been investigated. The value of effective diffusion coefficient of O2, which diffuses through the porous decarburized layer, decreased with the decreasing of the porosity and the oxygen concentration in the external gas phase. It was speculated that the dense layer formed easily due to the high tortuosity of pores and the low recession speed of the carbon interface in the MgO-C bricks.

Jan 1, 2004

By S. P. Cashin, D. Kashuba, W. Esplin

Barrick has had 6 autoclaves in operation at the Goldstrike Mine, North of Carlin Nevada, since 1993. The 6 autoclaves operate in parallel, processing slurry of gold ore. The gold in the ore is predominantly associated with, and encapsulated by, sulphide minerals. It is necessary to oxidize at least 90% of the sulphide mineral before the gold can be concentrated using a cyanide/carbon-in-leach (CIL) circuit. Sulphide oxidation chemical reactions occurring in the autoclaves are exothermic; however, the sulphide content in the ore is not high enough to operate the autoclaves in an auto-thermal mode. Heat from steam is added to the first 2 of 5 autoclave compartments to initiate the sulphide oxidation reactions. The steam used to heat the autoclaves is supplied by three boilers, which are fuelled with propane gas. The completion of a few operations and maintenance projects in the last 2 years has resulted in a 50% reduction in propane energy requirements. The autoclave operating temperatures were minimized. Excess oxygen addition was held as low as possible. The material of construction for the compartment walls inside the autoclaves was changed from brick to Titanium metal. And, the speed of the autoclave slurry agitators was increased. All of these activities had an impact on the propane energy requirements of the autoclaves. Presented below is a description of the autoclave systems, and a discussion of how the energy needs were reduced, resulting in significant operating cost savings.

Jan 1, 2004

By Yongteng Dong, John P. Quinn, Bradford Wesstrom, Guikuan Yue

With increasingly low-grade copper ores being mined, it is difficult to handle growing concentrations of As, Sb, Bi and/or Fe in the whole flowsheet, especially during copper electrorefining. To better elucidate the effects of those impurities on the quality of cathode deposit and/or current efficiency, a detailed speciation study of the electrolyte under industrial conditions is required to quantitatively describe their distribution in the solution, thereby facilitating their effective control and removal. In the present study, a thermodynamic model of complicated iron-arsenic-copper-sulfuric acid electrolyte under industrial conditions was developed. The main species of those elements involved in the electrolyte were first identified, and their thermodynamic data were collected and critically assessed. Those data were then used to estimate the activity coefficients of species, and to calculate the equilibrium constants from 25°C to 70°C. The developed model provides a mathematical tool that is capable of quantifying the concentrations of free ions and complexes in terms of temperature and solution composition. Finally, oxidation-reduction potential measurements were employed to validate the model. INTRODUCTION In copper electrorefining, impurities like arsenic, antimony, bismuth and/or iron can partially dissolve in the electrolyte and accumulate gradually, and eventually cause problems such as bad cathode deposit (co-deposition with copper or mechanical inclusion from the floating slime), lower current efficiency, etc., which eventually increases the operating costs. The presence of impurities may substantially reduce properties of copper products such as conductivity, corrosion resistance, mechanical properties, and leads to more energy consumption (Schlesinger et al., 2011; Jafari et al., 2017). To remove these impurities, various methods have already been proposed and applied in industrial copper production, such as solvent extraction, ion exchange, chemical precipitation, absorption by activated carbon, etc. (Cunningham et al., 1997; Navarro et al., 1999; Toyabe et al., 1987). In addition, adding reducing agents such as sulfur dioxide and trivalent arsenic could also precipitate arsenic, antimony and bismuth from copper electrolyte, by changing the distribution of impurities with various valence (Braun et al., 1976; Xiao et al., 2007). The disadvantages of those methods include high energy consumption, serious contamination, lower selectivity and efficiency, and so on.

Jan 1, 2019

By C. J. Hall

This paper presents a basic motive column analysis of natural ventilation and shaft resistance, using the density depth diagram. The method makes use of tables showing the state of the air as determined by thermodynamic analysis. Several theoretical examples are given.

Jan 1, 1968

By E. R. Dixon

Copper SX/EW plants often bleed part of their electrowinning electrolyte to control impurities and maintain consistent cathode quality. Depending on the specific situation at each site, the bleed is either returned to raffinate, to an SX extraction stage, to an SX wash stage, or to the PLS pond, to avoid losing the copper in the bleed. This practice can have undesirable effects on the overall process. An alternative is to electrowin all or most of the copper in the bleed, thus avoiding the recirculation of the copper in the bleed. In this manner, the bleed is converted to metallic copper without interfering with the SX circuit. This in turn reduces the copper concentration in the raffinate, improving global copper recovery because of improved leaching conditions.

Jan 1, 2007

By William A. Price

The objective of this paper is to outline the approaches used in British Columbia to address the challenges posed by metal leaching and acid rock drainage (ML/ARD). Challenges include the large financial costs, the need for site-specific assessments, the large information requirements, the need for mitigation measures to be designed and financed in a manner that permits long-term performance, the lack of long-term operating experience, the ongoing changes in many important processes, the need for pro-active detection and resolution of concerns, difficulties in predicting the potential for ARD or significant metal leaching, the need for new tools, and the multidisciplinary, highly specialized nature of the work. Consequently, mines must be planned, operated and closed in a manner that permits regular review, detailed monitoring and adaptive management. Proper consideration of the challenges involved, including a plan of how all outstanding concerns will be addressed, studies to address areas of significant uncertainty and caution in the absence of the required understanding, should ensure environmentally safe practices in the future.

Nov 1, 2002

By Janice Zinck, Ian London

In recent years, the secure supply of critical and technology metals has become increasingly important tomajor industrialized economies that seek to sustain their industrial base and develop advanced technologies, such as clean energy. Canada, with its significant reserves of rare earth element (REE) and other metals, has an opportunity to supply some of the global demand for these materials. However, to transition from promising mineral deposits to marketable products, investment in strategic research and development (R&D) and expertise is needed to address the complex technological challenges around the production, separation and processing of these metals, and to better understand the global market for these key commodities. To this end, in its April 2015 budget, the Government of Canada committed to invest $23M over 5 years to accelerate production of REE and chromite/ferrochrome. The goal of this program, developed in close association with industry, is that Canada contributes a sustainable supply of REE to the global market. The research and development program will provide the technological capacity to establish a Canadian REE industry. This paper will discuss REE R&D advances achieved in the first year of the program in areas of mineral characterization, beneficiation, leaching, separation and environmental management and will highlight the Canadian model of collaboration where industry (e.g. prospective producers, technology companies), government, academia and other stakeholders work closely to ensure that the R&D is targeted, innovative and effectively deployed and commercialized.

Jan 1, 2016

The mechanism of thiosulfate decomposition and the products formed were investigated in the presence of pyrite or pyrrhotite in copper-ammonia solutions used for leaching gold. The presence of the sulfides significantly increased the decomposition of thiosulfate. The sulfide-surface-catalyzed oxidation of thiosulfate to tetrathionate by dissolved oxygen or the cupric tetra-ammine complex was proposed to be the dominant thiosulfate decomposition mechanism. The catalysis of the sulfides in this reaction could originate from their strong affinity for aqueous sulfur species and their semiconducting properties. Oxygen was found to be the initial driving force for thiosulfate decomposition in the absence of cupric ions and the driving force for the continuous decomposition of thiosulfate in the presence of cupric ions. Under an oxygen free atmosphere, the decomposition of thiosulfate was limited to reduce the cupric ions and the catalytic effect of the sulfides was also marginal. The dominant oxidative product of thiosulfate was trithionate in alkaline solutions especially in an oxygen rich or cupric ion rich environment. Tetrathionate was found in relatively smaller amounts in an oxygen and cupric ion deficient environment. Tetrathionate was not stable and would further decompose after extended periods. Trithionate concentrations increased almost linearly with time.

Jan 1, 2005

By George P. Demopoulos

In a departure from the traditional domain of hydrometallurgical extraction processes we consider new R&D opportunities for innovative application of solution processing into the advanced green energy and clean technology fields. It would not be an exaggeration if we state that protection of the environment via advancement of clean technologies on the one hand, and harvesting and utilizing renewable energy in a sustainable and cost-effective way on the other hand are clearly among the top pressing global priorities. When hydrometallurgy is approached on the basis of its aqueous chemistry and reactive processing fundamentals, it can indeed provide a highly fertile ground for innovation outside the "box". In this context therefore we will present highlights from our recent research that is directed towards the development of new generation HCl recycling, environmental, and solar energy conversion/storage technologies. In all systems the research is approached via the innovative integration of aqueous process engineering and material chemistry principles. The presentation will include discussion of (i) the development of crystallization-based HCl regeneration technologies; (ii) the supersaturation-controlled production and encapsulation of scorodite that was recently commercialized; (iii) the aqueous synthesis of nano-TiO2 and its electrophoretic deposition into solar cell electrodes; and (iv) the hydrothermal synthesis of nanostructured lithium titanate and lithium iron phosphate materials to make lithium-ion batteries destined for electric cars.

Jan 1, 2014

By A. Pearson, F. A. Auld, S. O. Colbeck

"""The theory of buckling of shafts and Steel tunnel-linings"" was published by E. Amstutz in 1970 and commented on by S. Jacobsen in 1974. The authors have revised and enhanced Amstutz’s work to address Jacobsen's comments on its limitations and to extend its validity over a wider range of pipe/shaft geometries, including those commonly found in deep mine access shafts. The author has looked at Amstutz’s assessment of strengthening with flexible shear anchorages and adapted the theory of non-linear shear deformation response of bolts to develop a method of assessing increased buckling capacity utilising the full plastic shear capacity of studs. INTRODUCTION “Amstutz Buckling” refers to the buckling of pipe embedded in concrete under external uniform pressure. In terms of a mining environment, this relates directly to the design of a watertight shaft. This load case will commonly occur where a main shaft is cast against a geostatically stable primary liner and the only load applied to the final shaft is that of a uniform ground water load. Ernst Amstutz wrote his first paper on buckling of pressure-shaft steel linings in 1950 and subsequently improved his theory (Amstutz, 1970), which was then widely adopted for use within the industry. Years later, an alternative approach (Jacobsen, 1974) was proposed. Within his paper Jacobsen critiques Amstutz work, identifying some mathematical inconsistencies and highlighting limitations of the theory imposed by approximations adopted by Amstutz. Despite these limitations Amstutz work has still been used as the favoured design theory for use in the mining industry. In reviewing this body of work the author realised that with the advent of readily available computing software it was possible to adopt an iterative approach using Amstutz approximate formulae to find a solution to the original precise formulae, thus eliminating the limitations highlighted by Jacobsen The shear deformation to load characteristics of bolts has long been established (Crawford & Kulak 1968) and used for the plastic design of bolted connections in shear. This relationship is directly transferable to the design of shear studs, typical properties are well known, and actual values easily established in simple lab tests. The author has taken this relationship and modified Amstutz theory (Amstutz, 1970) for shear anchored strengthened liner buckling, to give a more efficient solution, using readily available material properties."

Jan 1, 2019

By Hiroyuki Sano, Hiroshi Chida, Katsuya Toda, Takafumi Sasaki

Saganoseki Smelter & Refinery is one of the largest copper producers in Japan to produce 450,000 tons of new copper annually. Saganoseki used to operate six PS converters with "4 Hot-2 Blow" scheme, but managed to change its operation to "3 Hot-2 Blow" scheme with four PS converters, while maintaining the same production capacity. To achieve the operational change, the following improvements have been carried out; 1) Extending service life from 220 to 350 batches, 2) Shortening cycle time by increasing the blowing rate and the matte grade, 3) Reducing environmental impact by applying sophisticated fugitive gas collection system and 4) Saving energy by waste heat boiler’s modifications. The operational change has been successfully executed, and results in drastic productivity increase and cost reduction. Currently, Saganoseki is maintaining the efficient and consistent operation with 4 PS converters. This paper describes the above-mentioned improvements for increasing productivity and the recent operational conditions of the PS converters.

Jan 1, 2015

By S. Haggarty, R. Walton

Barrick's growth and development plan will add three major new mines during 2005 including the Lagunas Norte Project in the La Libertad Province of Peru, the Veladero Project in the San Juan province of Argentina, and the Tulawaka Mine in north¬western Tanzania. Lagunas Norte and Veladero are similar in that they are both green-field open pit deposits at elevations over 4,000 meters above sea level, with two stage crushing and heap leaching followed by Merrill Crowe zinc precipitation for precious metal recovery. Operating sites will each generate in excess of 700,000 ozs Au per annum with commissioning and full scale operation planned during the third and fourth quarter of 2005. Details with regards to regional geography, development schedule, production and process specifics for Lagunas Norte and Veladero will be discussed in this presentation providing an overview for the respective properties.

Jan 1, 2005

By L. Bichler

Utilizing thermal analysis techniques, pioneering research into the solidification mechanism of a popular magnesium alloy AZ91E cast by the Lost Foam Casting (LFC) process was carried out, Foam characteristics, section thickness and application of vacuum were seen to have profound effect on the cooling rate, thermal gradients and casting temperature profiles.

Jan 1, 2005

By R. D. Browns

In his Budget Speech on March 31, 1 977, the Honourable Donald S. Macdonald expressed concern about the financing of investments through new equity issues. He mentioned the need to render more attractive participation in the equity market by investors in all in come brackets. One of the measures introduced in the budget to accomplish this goal is the proposal to increase the dividend gross-up and tax credit in respect of most dividends received by an individual from Canadian companies. The following comments and tables serve to illustrate the impact of this particular proposal.

Jan 1, 1977

By H. C. Boydell

Those connected with mining, prospecting, or mining geology in northern Ontario are familiar with the fact that it is a comparatively unusual thing to have assayed a sample for which the assay report shows no gold. Values of 20 cents to 80 cents per ton, or even higher, are extremely common. Whilst contamination by fluxes, faulty manipulation, or a desire, on the part of the assayer, to sugar-coat the pill for the client, may account for 20 to 40 cent values at times, it is un1ikely that they would a1ways do so. Exonerating the assayer from being necessarily at fault, what can be the cause of such a widespread distribution of gold (and silver) in minute quantities- of a dissemination .that, in the writer's experience, and so far as he is? aware, is not met with on a simi1ar scale in other parts of the world? Explanations that suggest themselves are, that the dissemination is due: 1. To a very widespread auriferous minera1ization, post-dating (epigenetic) the formation of the rocks in which it occurs. 2. To a general syngenetic distribution of gold in the volcanic rocks of Keewatin age that form so large a part of the sections of northern Ontario that have been prospected.

Jan 1, 1928

By M. L. Trépanier

"Engineering and technical services are supplied by the Engineering Department, located at Thetford Mines, Quebec, approximately 60 miles southwest of Quebec City. The department serves the three operating mines in the Thetford area, the Asbestos Hill mine at Putuniq, Nouveau Quebec, and the Nordenham plant at Nordenham, West Germany. The Engineering Department is responsible for supplying the following services. 1. Administration and coordination of capital projects. 2. Engineering, design and drafting services for in-plant changes or improvements. 3. Preparation of geological plans for mine planning and ore reserves determinations. 4. Short-, medium- and long-term mining plans. 5. Rock mechanics studies and monitoring. 6. Grade control monitoring. 7. Environmental control engineering and construction. Details of the organization and services rendered will be the basis of the paper."

Jan 1, 1976

By T. A. Lazier, C. S. Longley

"Paymaster Consolidated Mines, Limited, owns several groups of claims in various parts of the Porcupine district. The area in which mining has been carried on includes parts of lots 5, 6, and 7, con. 1, Tisdale township, and twelve adjoining claims in Deloro township to the south. Highway No. 67A between South Porcupine and Timmins crosses the property.The discovery of the Dome mine in 1909 caused a rush of prospectors to the district and in a few weeks practically all territory adjacent to the Dome was staked. At that time work was started on the West Dome, West Dome Lake, Apex, and Standard properties. These were consolidated in 1930 to form the present Company. Gold was produced from the West Dome Lake from 1915 to 1930, and from the Standard-Paymaster from 1922 to 1928. The total production of the previous and present companies from 1915 to November 30, 1946, has been 487,170 oz. gold and 149,342 oz. silver from 2,337,554 tons of ore."

Jan 1, 1954