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By C. Sorel

The solvent extraction systems devoted to uranium purification from crude ore to spent fuel involve concentrated solutions in which deviation from ideality can not be neglected. The Simple Solution Concept based on the behaviour of isopiestic solutions has been applied to quantify activity coefficients of metals and acids in the aqueous phase in equilibrium with the solvent. This approach has been validated on various solvent extraction systems such as trialkylphosphates, malonamides or acidic extracting agents both on batch experiments and counter-current flowsheets. Moreover, this concept has been successfully used to estimate the aqueous density which is useful to quantify the variation of volume and to assess criticality parameters such as number density of nuclides.

Aug 1, 2010

By Chen Feng

Compared to widespread successful deployment of robotic manipulators for repetitive and hazardous tasks in related industries such as manufacturing, the construction industry has achieved relatively limited benefits from robotics and soft automation. Unlike manufacturing, where robotic solutions benefit from the structured layout of the environment (e.g., factory assembly line), construction robots face unique challenges that arise from the rugged, dynamic, and unstructured environment of the work site, as well as the uncertainty and evolving sequence of occurring on-site events. This challenges any intended construction robots to not only replicate basic human motion, but also be capable of sensing and adapting to environmental changes, and making decisions based on the evolving state of the environment. Building upon recent advancements in robotic mapping, computer vision, and object recognition, the authors propose to introduce autonomous behavior at the basic task level for on-site construction robots to address these challenges in a flexible and extensible manner. This paper reports the outcome of the first phase of this research - a structured methodology for improved design and development of basic task automations - and focuses on algorithms developed for mobile robot navigation and relative pose estimation. The algorithms are implemented on a prototype mobile robotic platform, and evaluated in several experimental scenarios.

Aug 1, 2013

By Vincent H. Hartung

The process of estimating tailings deposition for a given basin is a relatively tedious process without dedicated software tools. The amount of time required to generate a tailings surface for a given set of conditions tends to limit the number of design alternatives that can be considered for a particular project. Recent innovations in the Surpac Vision mining software include the widely used scripting language TCL (Tool Command Language) that brings with it the ability for non-programmers to extend the software functionality beyond mining applications alone. A software tool was developed using the Surpac Vision scripting language to take advantage of 3D visualization and create a flexible tailings modeling solution. The result is an application that removes much of the drafting overhead required to produce a tailings surface. It provides the means for reviewing alternatives and performing sensitivity analysis with variables such as pond elevation, dam or spigot location and height without a significant increase in overall time for a project.

May 1, 2001

Commercial SOFC systems will likely utilize hydrocarbons or hydrogen produced from hydrocarbon fuels and therefore will likely be exposed to sulfur impurities. Conducting-Atomic Force Microscopy (C-AFM) is a scanning probe microscopy technique which maps both sample topography and conductivity with tens of nanometers resolution. In Ni-YSZ, C-AFM measures the resistance of the metallic network at scanned locations, with the ability to differentiate between interconnected and isolated metallic particles. We have applied C-AFM to Ni-YSZ SOFC anode materials, with the goal of monitoring changes in the conductivity of the Ni anode network resulting from SOFC degradation processes, such as H2S poisoning.

Jan 1, 2005

By Gae On Kim, Ki Baik Kim, Suk Hoon Kang, Tae Kyu Kim, Sanghoon Noh

"Advanced radiation resistant oxide dispersion strengthened steel (ARROS) is being developed as a fuel cladding tube material for future nuclear reactor system applications. The research activities consist of advanced radiation resistant ODS steel development and fabrication technology development of ODS steel structural components. One candidate material with a chemical composition of (in wt%) Fe-10Cr-1Mo-0.5Mn-0.1V-0.25Ti-0.35Y2O3and was selected as representative materials, and this material was named as the advanced radiation resistant ODS steel (ARROSTM).On the basis of this ODS steel composition, an optimized fabrication process of structural components such as plates, sheets and tubes has been established through various process conditions in mechanical alloying, hot/cold working, and heat treatment processes. These R&D activities are expected to contribute to the realization of ODS materials in the future.INTRODUCTIONA sodium-cooled fast reactor (SFR) is being developed at the Korea Atomic Energy Research Institute (KAERI) with a view to economics, safety, reliability, and sustainability. The prototype Gen-IV SFR with a capacity of 150 MWe is under design, and this prototype reactor is scheduled to operate from 2028. For a commercial SFR system application, it is necessary to develop an advanced structural material having both high creep strength and irradiation resistance at high temperatures (Jeong, 2014). Oxide dispersion strengthened (ODS)steel is one of the most promising structural materials because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density, which is extremely stable at high temperatures under a neutron irradiation environment for a prolonged operating period(Kim, 2016). As the first step, several batches of ODS steel were designed and the candidate samples with a 2 kg scale each were fabricated by mechanical alloying, hot isostatic pressing and hot rolling processes. The mechanical properties of these samples were evaluated. Up to now, two candidate materials with chemical compositions of (in wt%) Fe-10Cr-1Mo-0.5Mn-0.1V-0.25Ti-0.35Y2O3 was selected as representative materials, and these materials were named as the advanced radiation resistant ODS steel (ARROSTM).The next step was to optimize the fabrication process of the ARROS compositions for in-core structural components such as the fuel cladding tubes of a SFR. An optimized fabrication process of fuel cladding tube with a composition of ARROS has been established through various process conditions in mechanical alloying, hot consolidation, hot/cold working and heat treatment processes. Joining technologies of the ODS steel tubes is being developed using solid-state welding such as magnetic pulse welding, friction stir welding and diffusion boding. It is expected that the development of ARROS will contribute to the realization of a commercial SFR with high economics and sufficient safety in the future. In this paper, the study of fabrication process of ARROS structural components is introduced."

Jan 1, 2017

By Z. Xie

Gas diffusion electrodes (GDEs) for high temperature polymer electrolyte fuel cells (PEFCs) have been prepared using ZrP-modified Nafion ionomer. The performances of these GDEs as cathodes and anodes were evaluated and compared with conventional Nafion ionomer GDEs using Nafion 112 as the PEM under elevated temperature and reduced relative humidity. ZrP-modified Nafion ionomer was incorporated into the catalyst layer to enhance water retention and/or increase the protonic conductivity. The fabrication of ZrP-GDEs was implemented by the ion exchange of Nafion solution with zirconyl chloride, followed by the impregnation of GDEs in H3PO4 solution. The composite electrolytes in the catalyst layer possessed a ZrP content of 20% by weight. GDEs were characterized by TGA, SEM, XRD, and CV. Scanning electron microscopy (SEM) indicated evenly distributed elemental Zr and P within the catalyst layer. Cyclic voltammetry shows a reduced electrochemically-active surface area when the ZrP is incorporated into GDEs. Polarization and impedance analyses indicate the cathode with ZrP-modified Nafion ionomer did not show an enhanced or decreased performance, compared with conventional Nafion ionomer GDEs under elevated temperature and decreased humidity. However, when GDEs with ZrP¬Nafion ionomer were used as the anode, an improved performance was observed. Preliminary experiments show that the anode is more sensitive to dehydration than the cathode under elevated temperature and/or low humidity. Improving the anode water retention capability will help to reduce losses at the anode. However, the incorporation of hygroscopic agents in the cathode catalyst layer is not essential because it is self-humidified by electrochemically-produced water even under elevated operating temperature and lower humidity.

Jan 1, 2005

By G. J. Kipouros, N. Dadvand

"In recent years coatings of alloys have been produced for a wide range of applications including many for wire bonding application. The main characteristic of the baths of electroless plating is the presence of sodium hypophosphite as a reducing agent and also as the supplier of phosphorus. In the electroplating of alloys the Watts bath is predominantly used. This presentation compares the two techniques, electroless plating and electroplating, and discusses the possibilities of cross utilization of sodium hypophosphite in an attempt to formulate baths that eliminate the waste disposal issue related to some components.INTRODUCTIONThe importance of surface characteristics and the linkage of surface coating process to surface characterization has given rise to the evolution of surface engineering. Not only the surface preparation and morphology has become very important to the coating technology but also the knowledge of surface area exposed to the process of coating or corrosion is absolutely essential in ascertaining the behaviour of coatings and their adherence to the substrate. The above concepts are not unknown to researchers involved in the protection of surfaces, particularly metallic, from corrosion and/or erosion corrosion. However, the complexity of the surface defects, roughness, porosity, interconnected porosity and other related factors have contributed to the uncertainty of the true surface area versus the nominal surface area. Therefore critical parameters such as current density and chemical surface intensity although have been studied extensively at the atomistic level by carefully prepared surfaces are very difficult to be determined at the practical scale required during the coating processes.The most pronounced case calling for an understanding the relationship between the surface area and the effective protection is the coating of surfaces of items produced by compression or consolidation of powdery materials. With the advent of nanomaterials and the additive manufacturing through 3D metal printing this issue is becoming more important. Certain experience in this field come from the accumulated knowledge resulted from the attempts to characterize the electrochemical behaviour of powder metallurgy metals and alloys. Powder metallurgy has been a well-established process for half a century on basic metals such as iron, copper and their alloys. Recently the development of powder metallurgy process for aluminum, titanium and attempts to develop powder metallurgy processes for magnesium and its alloys has brought to light another important issue that of the development of coatings on difficult to plate reactive metals such as aluminum and magnesium. Despite of many successes in the development of powder metallurgy alloys the exact characterization of the corrosion behaviour of the coatings and the substrates is difficult to determine because of the unknown morphology of the exposed area i.e. the exact morphology and area of the exposed surface (Samal, 2007)."

Jan 1, 2016

By J. De Geoffroy, T. K. Wignall

The paper describes a statistical method based on regression and classification analysis which is designed to assist exploration management in the selection of prospecting areas and drilling targets in regional programs. The classification is based on three criteria which are formulated from sets of relevant geological, geophysical and geochemical factors: (a) regression estimates of expected ore values, (b) Bayesian probabilities of success and (c) expected utility payoffs. The advantages of the method are: (a) rational and unbiased ratings for areas or targets in a manner consistent with management's goals; (b) calculation of probabilities of success and confidence intervals for the ratings, and (c) rapid and accurate handling of a large amount of data by computer programs.

Jan 1, 1970

By C. Bissue, G. M. Castillo

Newmont’s Phoenix mine started production in March of 2006. Due to the extreme hardness of the ore, the mill has struggled to meet throughput projections. Grinding studies showed that optimizing the existing circuit would not achieve budgeted throughput. These studies also showed that the pebble crusher was being underutilized due to the inability of the SAG mill to break the rock. The concept was developed to supplement the feed to the existing pebble crusher with a secondary crusher. Models of this process looked favorable so a portable crusher was installed to test the process. The temporary crusher was successful at increasing the throughput by 7% and based on the operating data, plans are currently being developed to install a permanent secondary crushing system in front of the SAG mill. This paper will review the results from the test crusher and the flow sheet for the permanent secondary crusher.

Jan 1, 2012

By Guy Brouillard

A bow-tie analysis is a safety review methodology that uses a structured approach that can be qualitative or quantitative to document the potential risk of safety incidents. The bowtie diagram itself provides a powerful graphical representation of the threats barriers, events, and recovery measures which are readily understood by the "non-specialist". This presentation will discuss how mining operations can use this valuable tool within their operations to understand the risks and apply the appropriate safeguards toward reducing these risks to acceptable levels.

Jan 1, 2014

By Ernest A. Hodgson

WHEN excavations are made, at depth, in hard brittle rock structures, as in certain mines in India, in South Africa, and in Ontario, the pressure due to overburden, together perhaps with inherent geologic strain, tends to become concentrated in the walls of some of these openings and the rock bursts, often closing the adjacent drifts and scopes and presenting a serious menace to the miners. Where the rock is much fractured and faulted, the danger is greater, since the pressures tend to shift without warning from point to point, sometimes within a few hours. Attempts have been repeatedly made to find some physical property of the rock which will change with pressure, which can be measured for rock 'in place' in the mine, and which will give an indication of the state of strain, thus warning of an approach to bursting conditions. Some of the properties tested have been the speed of propagation of elastic waves in the suspect rock, variations in temperature due to pressure changes, rate of closure of openings or shifts along fault planes, strain gauge measures, and others. Each of these has proved unsatisfactory for the purpose. The most promising method so far proposed has been the study of the very faint, sub-audible snaps (microseismims) which are produced in rocks under pressure. Such a study has been in progress at Lake Shore Mines since May, 1942. Instruments designed to pick up, amplify, and record the microseismims were perfected and a programme of observing, using the microseismic method, has been carried through with persistent diligence and at considerable expense. In 1943, experience with the method in a pillar section on the west side of the Lake Shore mine gave much promise of predicting bursts. A very heavy burst on January 29th of that year occurred in the exact section of the mine covered by the instruments, and the records indicated a measure of prediction. In response to repeated requests for information, a number of reports were given out, among others a radio talk by the writer over CJKL (Kirkland Lake), which was reported in full in the Northern News . Also, a detailed account of the occurrence was given in an illustrated paper by the writer (l).

Jan 1, 1945

By George Booth

In mining operations the cost of timber is an item of much importance, because the life of mine timbers is, in many cases, very short and, as the supply of the better grades becomes depleted, less durable kinds must be used. This, of course, tends to shorten still further the period of service-ability. While it is possible that concrete and steel may, to some extent, take the place of timber in mines, their high initial cost and the difficulty in installation will greatly restrict their use. Moreover, wood, besides being comparatively cheap to handle, possesses other desirable qualities, and for many purposes a satisfactory substitute is hard to find. Both the decreasing supply and the increasing price of timber make its more efficient utilization imperative. AGENCIES DESTRUCTIVE TO MINE TIMBERS Timber used in mines is exposed to destruction from many sources. Wear, breakage, and waste are responsible for much loss. Wood rollers and drum laggings must be frequently replaced on account of the constant wear by ropes. Unprotected timber in chutes and mills is also rapidly worn by abrasion, and track ties in main haulage ways get worn by the feet of mules, cut by ropes, etc. Large amounts of timber are broken by 'crush' and 'squeeze,' and much temporary timber is buried beyond all recovery in pillar workings and in those mines which resort to back filling. Decay and insect attack, however, cause the greatest damage. If not totally destroyed by one or both of these, the timbers frequently become so weakened that they break under the pressure upon them.

Jan 1, 1926

By H. W. Manley

SULPHUR, like the minerals of coal, iron and petroleum, is one of the essential materials in our modern expanding industrial civilization. Before discussing the salient features of the production of sulphur from the Canadian sour gas, it seems appropriate to outline the historical past and probable future utilization of sulphur. The ancient Greek writer Homer spoke of its "pest-averting sulphur" and the "divine purifying fumigation". Ancient alchemists found sulphur to be a fascinating and baffling material. The discovery of gun powder in the year of 1250, and its application to the art of war a, century later, made sulphur an important commodity in the progress of mankind. The initial manufacture of sulphuric acid in the year of 1736 by the Englishman Joshua Ward, established the basis of a chemical industry that today utilizes 80 per cent of the consumption of elemental sulphur. Commercial production of the chemical soda ash ( N a2C03) discovered in 1787 by the famous Leblanc Process, in-creased international demand for the element sulphur and marks the birthday of the Sicilian sulphur industry.

Jan 1, 1961

By R. R. Dickson

Princess colliery, the largest mine operated by the Old Sydney Collieries, Limited, commenced operations in 1877. It was the first mine sunk in the Sydney coal field with the primary object of working submarine coal. Until 1925, coal was won by the room-and-pillar system. By that year, the depth of cover over the workings was 1,300 feet, and physical conditions had become such that it was impossible to extract completely the pillars formed by the working of the rooms. Because of this, the system of work was changed to longwall in the early part of that year. At first, an orthodox hand-pick method was used, with gate roads laid off at 50-foot centres and the mine cars loaded by hand directly on the longwall faces. Later in the year, the first machine-cut conveyor longwall faces were started.

Jan 1, 1946

By CRO CRO

Elk Valley Coal?s Cheviot Project is located in the Alberta foothills south of the town of Hinton. The mine has been in operation now for the 3 years. The start up and subsequent operation of the Cheviot project has been directly influenced by the Cardinal River Mine. As the Cardinal River Mine was winding down due to reserve depletion in 2004, the price of seaborne traded metallurgical coal jumped to record levels and customers began aggressively seeking new sources of supply. Several months later, the owners of Elk Valley Coal decided to begin mining at the Cheviot mining area, extending the life of the area?s operations by over 25 years. The Cheviot Project had been delayed by low coal prices, ownership changes and a complicated and lengthy regulatory process fueled in large measure by stiff opposition from a number of major environmental organizations. Chief to the startup of the project was the construction of a 23-kilometer-long haul road that would connect the new coal measures to the existing Cardinal River processing and rail facilities. Construction of this road was completed with the first coal truck making its first trip in October 2004. This paper will look at some of original assumptions, the actual mining experiences and the lessons that were learned while moving from the drawing board to the current development as it exists today.

May 1, 2007

By William James Kempson

This paper discusses ore handling systems in shafts. These are considered from the loading facility at shaft bottom all the way through to the discharge mechanism in the headframe. These systems will be discussed from the following perspective: i. Intrinsic safety of the systems ii. The efficacy of the systems to perform consistently iii. The maintainability of the systems iv. Overall system cycle times Particular emphasis is placed on the following specific areas: 1. The Shaft Bottom Loading Facilities The various shaft loading systems currently in use are discussed, the selection parameters surrounding these are quantified and the specific selection criteria are outlined. 2. The Various Skip Configurations In this section the various skip configurations in use around the world will be described and the specific design details associated with these will be highlighted. The advantages and disadvantages of these systems will be compared and the overall efficacy of these will be discussed. 3. The effect of the loading and skip configurations on the Load Cycle Times. The overall cycle time which can be achieved by a shaft system is strongly dependant by the speed and efficiency with which the ore can be loaded and transported out of the mine. The potential of the various systems to be optimized will be discussed. The emphasis of this paper is to highlight the lessons which have been learned with respect to ore transport system design and provide a common basis against which these can be compared in future applications.

May 1, 2013

By Harry Jomini

Introduction The Wakefield plant of the Aluminum Company of Canada, Limited - a member of the Aluminum, Limited, group of companies - produces magnesia, magnesia fertilizer ingredient, and hydrated lime, from brucitic limestone. Wakefield is on the Gatineau river in Wakefield township, Quebec, some 22 miles north of Ottawa. The plant is near the western bank of the river adjacent to the Ottawa-Maniwaki highway and branch line of the Canadian Pacific railway. The plant is unique in the sense that it is the only place in Canada where brucite is processed. It is also distinguished for its outstanding safety record, as not a single lost-time accident occurred during either 1948 or 1949. The plant is amply provided with safety and comfort provisions in keeping with the standard practice in all of the twelve plants operated in Canada by Alcan and its associated companies. History Following the identification of brucite in the Rutherglen and Bryson districts in Ontario, occurrences of the mineral were discovered in the Wakefield area, Quebec, in 1939. After exploratory work on these deposits and investigation by the Bureau of Mines, Ottawa, on a method of extracting the brucite from the ore, a plant for treating the ore from the Maxwell property was built in 1941 by the Aluminum Company of Canada and commenced operations in early 1942. The process used is more or less in accordance with the method worked out by Mr. M. F. Goudge of the Bureau of Mines.

Jan 1, 1950

By B. R. McEwen, A. N. Samis, J. H. Gray

"The Quebrada Blanca Copper Mine is an open pit copper project located at 4200 m elevation in the Chilean Andes. The deposit is a world-class supergene enriched porphyry with a mining reserve of 89 Mt of 1.3% copper. The supergene zone will produce 6.3 Mt of ore per year for more than 15 years to produce 75 000 t of cathode copper per year.This paper will review the project geology the computer model ling of the deposit, the mine planning process and the property production scheduling. With copper production .fixed by the onsite electrowinning capacity, the planning and scheduling aspects to optimize the project NPV will be discussed. Some of the logistics, equipment. personnel and process difficulties of operating a mine at 42()() m elevation will also be described. IntroductionProject DescriptionThe Quebrada Blanca Copper Mine is an open pit copper project located in the northern part of the Chilean Andes. The project is based on the supergene enriched portion of a porphyry deposit which has a mining reserve of 89 million tonnes at 1.3070 copper. Below the enrichment blanket, the protore represents a further resource.All ore will be leached, the higher grade material will be crushed and stacked for thin layer heap leaching, and the lower grade and oxide material will be dump leached as run-of-mine material. Solvent extraction and electrowinning will be used to produce 75 000 tonnes of cathode copper per year. Power will be supplied by a 40 MW on-site diesel generating plant with the waste heat being used for process heating. The leaching operation will operate in excess of 15 years and may be followed by open pit mining and conventional ore concentration of the underlying primary sulphide mineralization.Because of the dry location water will be piped 37 km from a ground water source at the Salar de Michincha. Water requirements will be approximately 1.5 million m3/year. The operation will eventually employ approximately 550 people on a 7-day-on, 7-day-off rotation with two twelve-hour shifts per day with an on-site camp. Busing will be provided to the port city of Iquique."

Jan 1, 1994

By Elaine Ellingham, Francis T. Manns

"The Orostar and Scadding were two small gold mines owned and operated by Orofino Resources Limited. Conventional statistical treatment indicates an identical arithmetic mean grade of 0.22 oz/T Au for both mineable reserves. Further, the deposits are both shown to have cut weighted average reserve grade of 0.21 oz/T. Orostar mined out at 0.206 oz/T and Scadding at 0.156 oz/T Au. The combined exploration and development database contained 1394 fire assays, more than enough for statistical confidence in a normal distribution. Therefore this study was initiated to determine, if possible, why the mill head grades were lower than the averages and to experiment with several methods to determine whether a reliable statistical mill head grade estimation method would emerge. Despite the identical reserve grades, distinct differences in the grade distribution histograms are present. By studying the arithmetic and log-normal grade distributions, with some attention to South African practices, this paper reports on those differences which may account for the considerable divergence in the mill head grades. Furthermore, this study casts considerable doubt on the industry standard method of cut weighted averages.The global mill head grades of the two deposits have been derived from the arithmetic average grades by graphic means. This precise method of mill head grade prediction, if applied to complex orebodies, could permit selective grade control and result in direct cost savings by allowing the operator to detect false value stopes, benches or levels and emphasize reliable regions of not only gold mines, but also uranium or base metal deposits."

Jan 1, 1992

By Samantha A. Beeson, Colin Poole

"A selective flocculation-floe flotation technique is already in use in the Canadian potash industry for the removal of water-insoluble slimes, but the process is currently limited in its application and reagent consumption is high. The work described in this paper details investigations into the separation of sylvite and halite from water-insoluble slimes by selective flocculation utilising other commercially available polymers.Preliminary flocculation performance tests were undertaken on pure sylvite, halite and water-insoluble minerals to establish the importance of a number of experimental parameters. The data from these single mineral tests was then used to establish optimum parameters for the separation of sylvite and halite from a synthetic mixture similar in composition to a typical potash ore. Under optimum conditions, separation was achieved with high recoveries using dispersant and flocculant dosages significantly lower than those currently used in plant practice.IntroductionAlthough solar evaporation and solution mining are used in some operations, most potash is extracted by conventional underground techniques and is then processed by froth flotation, in order to separate the valuable sylvite (KCI) from halite (NaCl) and water-insoluble gangue minerals. Flotation is usually preceded by a desliming stage to remove water-insoluble fines, but this also results in high potash losses and affects process brine requirements. To overcome these problems, one plant operated by Cominco in Saskatchewan uses a selective flocculation -floe flotation process (Banks, 1979/1980), in which a polyacrylamide flocculant is added to produce floes of water-insoluble material with minimal incorporation of halides. A collector is then added to render the floes hydrophobic and suitable for removal by froth flotation.A number of workers have also investigated the use of selective flocculation in potash processing, but these too have been concerned with developments in the removal of water-insoluble slimes (Williams, 1960; Brogiotti et al, 1974; Chan et al, 1986; Thompson et al, 1979; etc.). This paper provides results of novel investigations into the selective flocculation of sylvite and halite from water-insoluble minerals and discusses the possible mechanisms involved."

Jan 1, 1995