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By X. F. Liu, O. Buzzi, Y. Sieffert

This study falls in the context of underground coal fires (UCF) where burning coal can elevate the temperature of a rock mass in excess of thousand degrees. The objective of the research was to experimentally investigate the change in mechanical behavior of a rock when subjected to temperatures up to 900 °C. Several blocks of an Australian mudstone were collected from a mining site in New South Wales, Australia. X-ray diffraction and thermal-gravimetric analysis were conducted on powdered rock in order to determine the critical temperatures at which the main mineralogical changes occur. Then, cylindrical specimens were prepared from intact rock blocks for unconfined compression tests. These rock specimens were then treated by heating in a temperature-controlled furnace at temperatures varying from 100 °C to 900 °C. The heating process consisted of two stages: raising temperature with very slow rate of 1 °C per hour followed by a holding period of 24 hours and then a slow cooling process to room temperature. The compression tests were carried out on treated rock specimens to characterize the change in compressive strength. The macroscopical study was complemented by microstructural investigations via optical microscope, scanning electron microscope (SEM) and mercury intrusion porosimetry (MIP). Results show that the unconfined compressive strength of mudstone decreases with increasing heating temperature up to 450 °C, beyond which it increases. This can be explained by the combined effects of micro cracks and mineral thermal reactions caused by heating process.

Jan 1, 2015

By Pura Alfonso, Sarbast Hamid, Hernan Anticoi, Eduard Guasch, Josep Oliva

"Av. Bases de Manresa 61-63, Manresa (08242) Barcelona, SpainTantalum is a strategic metal and an improvement of the mineral processing is an important issue. The main objective of this work is to optimize the grinding technologies for tantalum ores with high pressure grinding rolls. The selected ore for this study was an altered leucogranite from the Penouta Open Pit Mine (NW Spain). In the present work mono-size experiments have been carried out using grinding rolls with controlled pressure. The particle size distribution has been monitored in the input and output of the high pressure grinding rolls for each experiment. The cylinder pressure that is transmitted to the particles has been determined. New population balance models are presented for high pressure grinding rolls with parameter adjust for tantalum ore. The obtained model uses the physical description of particles under the comminution action of the grinding rolls. The obtained results are in agreement with other models and the errors in the adjustment are low. The selection function proposed for this model describes adequately the breakage probability of the particles inside the high pressure grinding rolls. The presented model can be a good alternative for simulating a high pressure grinding roll process. INTRODUCTIONTechnology for grinding have been improved for many years, introducing new variables and parameters involving energy consumption, mechanical stress analysis of the compression particles or pressure application for optimizing the comminution (Morrell et al, 1997). High pressure grinding rolls is a modern technology that is proven to reduce the operating costs in full scale plants when compared with other milling technologies. Its benefits on energy saving and simplicity in the process have been studied and applied, first in the cement clinker industry (Abouzeid & Fuerstenau, 2009) and after in mining activities, especially in metallic ore deposits (Austin et al, 1991; Guevara & Menacho, 1992; Morrel et al, 1997; Torres & Casali 2009; Numbi & Xia, 2015). Many author structures of the High Pressure Grinding Rolls modelling in three main branches; (a) throughput modelling, (b) Power and energy model and (c) particle size distribution modelling (Austin et al, 1991; Guevara & Menacho, 1992; Austin & Trubelja, 1994; Morrel et al, 1997; Torres & Casali, 2009)."

Jan 1, 2016

By T. G. Joseph, M. Welz

ABSTRACT: Joseph (2002) introduced passive seismic monitoring to measure mining equipment performance. This paper evaluates the potential of passive seismic monitoring to correlate mining equipment operation with oil sands surface response, with a mining hauler as the seismic source. When applied to moving haulers, this action–reaction approach is complex. Vibrations from on-board equipment, such as pumps and tires, dirty the signal with noise. To facilitate any correlation, the signal must be cleaned up. Existing geophysical analytical techniques were manipulated to evaluate the noise problem and to filter sufficiently to permit an evaluation of whether a mining equipment action–ground response relationships in fact discernable.

Jan 1, 2011

By P. E. Weidmark

Allard, M., Hucka, V.J., Das, B., and Borchtch-Komponietz, V.I., "Investigation of seismic vibration due to large blasts in Gaspe Copper Mines"; (in Russ); The Industry of Chemical Raw Materials; Referativnyi sbornik; 5:18-20: 1978. Askew, J., McCarthy, P.L. , and Fitzgerald, D.J ., "Backfill research for pillar extraction at ZC/NBHC"; Mining with Backfill; Proc 12th Cdn Rock Mech Symp; May 23-25, 1978; Sudbury; CIM Spec Vol 19:100-lJO; 1978. Barrett, J.R., Coulthard, M.A., and Dight, P.M., "Determination of fill stability" ; Mining with Backfill; Proc 12th Cdn Rock Symp; May 23-25, 1978; Sudbury; CIM Spec Vol 19:85-91; 1978.

Jan 1, 1979

By I. Paredes, R. Díaz, H. Henao

Smelting of copper concentrate generates a significant amount of dusts which are collected in electrostatic precipitators. This material, which is a complex oxide of Cu, Fe, S, As, Sb, Bi and others, is difficult to recirculate into the smelting process due to the reported high concentration of arsenic. However, the dust also has concentration of copper above 10wt %, aside from reported contents of silver corresponding as much as 25wt% of the total inventories of this element in the smelters. Thus, it is of economic and environmental interest the development of a process able to reduce the concentration of arsenic in the dust and produce a material suitable to be recirculated into the smelting process. The present experimental work shows the results of a process of dust sulfidization-oxidition able to remove more than 65wt% of the arsenic present. INTRODUCTION Copper sulfide deposits worldwide exhibit increasing concentrations of arsenic. One case of interest would be the copper ores from the northern zone of Chile, which report high concentrations of enargite (Cu3AsS4) (Revista química, 2015) (Latinominería, 2014). The obtained concentrate from this ore is treated in a Fluidized Bed Roaster, producing calcines with low concentration of arsenic (<0.5 wt% As). This material is suitable to be treated in a Flash Furnace. At the roasting process, the arsenic is volatilized and then precipitated as fine particles of complex oxides. Most of this particulate material is removed from the gas stream through a device called Electrostatic Precipitator (Minería chilena, 2014). The experimental results reported in the literature indicate that arsenic present in these particulate materials (or dusts) cannot be eliminated in oxidizing atmospheres (air) or with inert gases (N2) in a Fluidized Bed Roaster even at temperatures as high as 700°C. There is also information that even the recovery of valuable metals from the dust is difficult through hydrometallurgical processes (private communication). This is how in some foundries these dusts are considered environmental liabilities. Regarding the decomposition of enargite (Cu3AsS4) in neutral atmosphere, it is reported in the literature (Padilla, 2001) that the main chemical reactions are:

Jan 1, 2019

By S Romanchuk, V N. Macvkiw, D. J. I. Evans

The paper describes the processes developed and piloted by Sherritt Gordon Mines Limited for recovering copper, in the form of specification copper powders, from Lynn Lake sulphidic copper concentrates and Fort Saskatchewan Refinery by-product copper sulphides. The process includes ammonia pressure leaching and hydrogen reduction from solution. Nickel and cobalt present in the con-centrates dissolve in the leach solution and a method was developed for separating these metals from the cop-per. Methods are described for con-trolling the physical properties of the copper powder produced in the reduction vessel. The chemistry of the process is briefly discussed and the effects of some of the more important process variables are described. SHERRITT Gordon Mines Limited have developed and proven on a pilot plant scale, a process (I) for the production of copper powder

Jan 1, 1961

By P. Reyes

The Codelco Chile El Teniente Division Caletones Smelter has an objective to smelt 1,250,000 tonnes per year of copper concentrate. This is a great challenge for the smelter facilities and particularly for the acid plants. The analysis ensuring that there are no obstacles to achieve the production capacity was of great importance. Therefore a series of activities were undertaken as well as studies dedicated to reach the target. This paper presents work focused on a fluid dynamic study, translated in an operation methodology of integrated handling of the smelting and converting gases with the objective to optimize the gas flow and S02 concentration. The optimization should be done employing the current installations, equipment and instrumentation and/or minor modifications. In the first part of the work the condition of the instrumentation involved in the gas handling was checked, improvements determined and the corresponding corrective actions were carried out. The proposed operation method consists of operation of the Cleaning Gas Plant 2 (TC&apos; s gases) and operation of Gas Cleaning Plant 1 (the remaining gas plus the gases from CPS). The implementation of the operation method involves the modification of the valve of the gas into the duct to plant 1 from On to Off to modulate flow. After modification a three days test was carried out. To evaluate the tests, a "Sulphur Capture" indicator was used. During the test the behaviour of the effluent treatment plants was closely examined. No problems or unusual operating conditions were observed. The reduced flow of gas to Gas Cleaning Plant No. 1 permitted the start up of the 2nd test day treating most of the gas received by Gas Cleaning Plant No. 2. The operation was carried out with the limitation not to increase the effluent pond level, which was maintained constant.

Jan 1, 2007

By Mike D. Riley, Alan V. Bell, Ernest K. Yanful

Acid mine drainage (AMD) research under the MEND program has been ongoing since 1988 at the Heath Steele Mines waste rock piles including sulphide material, outside Newcastle, NB. In 1989 approximately 10,000 mt of waste rock was placed on a prepared sand base with an underlying impermeable membrane. The waste rock pile was heavily instrumented for measuring oxygen concentrations and temperatures. In September 1991, a composite soil cover designed for the Heath Steele climatic conditions, using local soils, was placed over the pile, creating a totally enclosed system. Moisture content and oxygen probes were installed within the composite soil cover to monitor changes within the soils over time, while two large-size lysimeters were installed below the cover to monitor the hydraulic conductivity of the cover. The waste rock site has been monitored on a monthly basis since installation of the cover, for performance of both cover and waste rock. The monitoring shows very clearly that the placement of the composite soil cover has had a major impact on the generation of AMD. Major reductions in temperature and oxygen concentrations within the waste rock pile indicate that the cover has significantly inhibited the oxidation reaction that generates the AMD. Performance data have shown that the cover has maintained its integrity under the climatic conditions of the area.

Jan 1, 1995

By E. C. Roper

THE Britannia Mining & Smelting Company, Limited, have been operating their property at Britannia Beach, B.C., continuously for nearly forty years and have mined over 33,000,000 tons of ore from orebodies within a belt of highly sheared rocks, five miles long by 2,000 feet wide. The property is in the Coast Range mountains, about twenty miles due north of Vancouver. The mountains rise abruptly from sea level to elevations of 4, 500 feet within a horizontal distance of 7,000 feet. The topography has enabled the orebodies to be developed by adit tunnels. The active mining levels are connected to the adits by incline and vertical service shafts. The main service adits are the 2200, 2700, and 4100 levels (see Figure 1). The mine surface shops, three bunk-houses, and over one hundred dwellings form the townsite camp at the portal of the 2200 level adit. A small camp of one bunk-house and a few dwellings is situated at the 2700 level portal. The beach surface shops and camp, adjacent to the 4100 level adit, service the mill, foundry, and other beach installations as well as the mining from the 4100 level. The ore mined from the various orebodies is delivered to the 4100 main haulage level through a system of rock raises and intermediate tramming levels and is hauled on the 4100 level to the mill.

Jan 1, 1945

Agenda 1.Energy consumption and energy costs ?focus and failings 2.Energy efficiency methodologies, people and supporting tools 3.Energy cost saving case studies from three minerals processing plants 4.The operations team and the supporting role of Operations IT 5.Conclusion: Reducing energy consumption and energy costs There are many good Energy Efficiency Methodologies ?Energy and GHG Emissions, Management Guidance Document, The Mining Association of Canada ?Energy Savings Toolbox ?An Energy Audit Manual and Tool, Canadian Industry Program for Energy Conservation (CIPEC) ?Lean and Energy Toolkit, Achieving Process Excellence Using Less Energy, www.epa.gov/lean ?Energy Efficiency Opportunities Assessment Handbook, www.energyefficiencyopportunities.gov.au

May 1, 2010

By Bo-Hyun Kim

Outline ? Strainburst criteria and hypotheses adapted for this study. ? Influence of excavation method on rock mass properties. ? Excavation disturbance factors vs. deformation modulus, etc. ? Estimation of blasting damage zone around excavation. ? Considerations of energy on burst-prone ground. ? Literature review & closed form solution. ? Numerical simulations. ? Summary and future works.

Oct 1, 2010

By Takashi Nakamura, Atsushi Iizuka, Yong Fan, Etsuro Shibata

The level of iron in typical copper slag reaches nearly 40% by mass, in the form of iron silicate. We designed a method to oxidize the nonmagnetic iron silicate to magnetite, permitting the selective recovery of the slag’s iron content by magnetic separation. This would effectively decrease the volume of dumped slag; the reclaimed iron could be used for iron and steel making. The crystallization behaviors of magnetite and hematite were studied as reaction products of the molten oxidation of copper slag. A gas atmosphere of 1% by volume of oxygen was found to effectively precipitate the slag’s iron content as magnetite.

Jan 1, 2015

By Shuo Zhang, Wenying Liu

"In dump leaching, the efficiency of metal extraction from ores is strongly influenced by the mechanisms of fluid flow. Particle size distribution acts as a fundamental parameter in the determination of fluid flow properties in packed ore beds. In this study, we investigated the particle size distribution in dump leaching by using image analysis technique. The results showed that the particles in the dump varied from smaller than 2 cm to larger than 200 cm in diameter. P80 was calculated to be 200 cm, which was significantly higher than the historical data used by the operation. P25, P50 and P80 were found to increase non-linearly with increasing depth towards the toe of the dump, suggesting the segregation of fine and coarse particles. The image analysis results were verified by applying the rock fragmentation models. The model with the Swebrec function was found to be in better agreement with the image analysis results. Future research will investigate the effect of particle size distribution on the behaviour of fluid flow.INTRODUCTION Fluid flow plays an essential role in the extraction of valuable metals using heap/dump leaching (Amos et al., 2009). The rates of the chemical leaching reactions and microbial activities determine metal concentrations in the leachates and therefore the efficiency of the metal extraction. The reaction rates are influenced by two fundamental processes: transport phenomenon and reaction kinetics (Bouffard & Dixon, 2001). The transport phenomenon refers to the percolation of fluids through channels and pores in a packed ore bed, which carries lixiviants and reaction products to/from ore surfaces by convection and diffusion. The percolation rate of the leaching solution is determined by the hydraulic conductivity of the packed ore bed, which is a function of the permeability and the degree of saturation (Guzman et al., 2008). Permeability, an intrinsic property of a packed ore bed, is strongly influenced by the particle size distribution of the ore grains (Bouffard & Dixon, 2001). Hence, the objective of this study was to investigate the particle size distribution in dump leaching."

Jan 1, 2017

By M. H. Govett, G. J. S. Govett

"The current American ""energy crisis"", occurring in the midst of a global debate on the adequacy of mineral supplies to support present and projected levels of world consumption, has focused attention on Canada as a major world producer of minerals. Exports of minerals account for approximately one-third of Canadian foreign earnings; more than half of these exports are to the United States. Although the United States is a net importer of most industrially important metals, with the exception of nickel and zinc, only a small part of American mineral imports are from Canada; these imports are minerals for which geographical proximity and strategic considerations are important. In the short-term, Canada is more dependent on her exports to the U.S. than America is on imports from Canada. It is argued that Canada, far from indulging in economic nationalism to preserve her resources, should expand her exports while the markets are available."

Jan 1, 1973

By Jerry Handford

Investing in the Development of our Future Workforce ?Collaborative partnerships with educational institutions, industry associations, governments and other businesses. ?Programs: »Co-op / Discipline Student Program »Trades Development Initiatives »Operator Training Programs »General Student Program »Careers Next Generation / Community Careers Co-operative

May 1, 2006

By Ana Adé

The use of gold compounds in homogeneous catalysed organic reactions has been undervalued for many years due to the preconceived opinion that gold is an expensive and extremely chemically inert metal. However, recent reports have changed this assessment and gold salts in small amounts are known to display high catalytic activity.[1] Thus, it has been reported recently that anhydrous AuCl3 catalyses the formation of C-C and C-O bonds (usually mediated by hydrochloric and other protonic and Lewis acids).[2] Some examples include Michael type additions, selective cross cycloisomerisation/dimerisation of propargyl or allenyl ketones, benzannulation between o-alkynylbenzaldehides and alkynes or cyclisation of alkenyl furans. It is noteworthy that some of these reactions[2a] can be also catalysed by silver salts but with much lower yields. The 1,3-dipolar cycloaddition of nitrones to alkenes is a powerful synthetic method that has found numerous applications in the synthesis of a variety of carbon frameworks.[3] Several laboratories have focused on the development of Lewis acidic reagents to modulate the selectivity of the reaction.[4] Despite the extensive study performed, there are not many examples in which a metallic complex catalyses the dipolar cycloaddition. Most of these reactions require the presence of a metallic complex and nitrone in a 1:1 molar ratio. Recently, we have carried out stoichiometric reactions of the N-benzil-C(2-pyridil)nitrone, 1, with different dipolarophiles in the presence of zinc and silver compounds.[5] Apart from an increase of the reaction rate and the selective formation of one of the possible isomers, we have shown the formation of zinc and silver-nitrone complexes during the reaction, which behave as the intermediates in the cycloaddition process. As suggested by the results obtained with silver complexes, we decided to test gold derivatives (in the oxidation states of I and III). Interestingly, we have found that they can be used not only as stoichiometric reagents but they can also mediate these cycloadditions in catalytic amounts (5 to 10 mol % respect to the nitrone). Here we present the results on the 1,3-dipolar cycloaddition reaction of the N-benzil-C(2-pyridil)nitrone (2-PyBN), 1, and methylacrilate, 2, (Eq. 1) catalysed by gold(III) derivatives.

Oct 1, 2003

By Jacek Paraszczak, Stefan Planeta

"RésuméDans la première partie de cet article on discute Ie contexte technico-économique de l&apos;usage des foreuses à l&apos;eau sur béquille dans des mines sud-africaines. Par la suite on présente les résultats d&apos;une étude comparative du forage avec les foreuses à l&apos;huile et à l&apos;eau par rapport aux foreuses pneumatiques. La performance des foreuses est discutée sous les deux aspects: l&apos;aspect technique concernant Ie taux de pénetration et la quantité d&apos;eau rejetee dans les galeries et l&apos;aspect de fa santé et sécurité au travail, et plus particuliérement, les niveaux de bruit et de vibrations ainsi que Ie brouillard de l&apos;huile. On conclut par l&apos;évaluation du potentiel de forage à I&apos;aide des foreuses hydrauliques dans Ie contexte canadien.AbstractIn the first part of this paper the technical and economical aspects of water-powered drilling are discussed. This technology, originally employed in South Africa, received some interest from Canadian mine operators. In this context a comparative experimental study of pneumatic and hydraulic (oil- and water-powered) jackleg drills has been realized. The performance of the drills is compared and the results reviewed with regards to technical aspects (penetration rate, amount of water spilled) as well as health and safety considerations (noise and vibration level, presence of oil mist). The potential for application of hydraulic jackleg drill is discussed."

Jan 1, 1995

By James A. Finch, Yue Hua Tan, Wei Zhang

"The paper is part of our study of the frother structure-property relationship using bubble rise velocity. Single bubble rise velocity profiles were determined in a 350 cm column for surfactants from the polypropylene glycol (PPG) family. Using velocity at 300 cm, the concentration to reach minimum velocity (CMV) is determined. The CMV is shown to decrease as alkyl chain length (n, number of carbons) increases and as the number of propylene oxide groups (m) increases. Linear correlations log CMV vs. n and m were observed. Taking literature data for critical coalescence concentration (CCC), linear log CMV vs. log CCC correlations were also noted. Mechanisms are briefly discussed, and prediction of CCC made for a commercial polypropylene glycol.INTRODUCTIONAs one of the great enabling technologies of the 20th century, froth flotation is a highly versatile method for physically separating minerals by exploiting differences in wettability (hydrophobicity). Over the last century, flotation reagents have undergone significant developments (Khoshdast and Sam, 2011). One important group of reagents is frothers which are used to reduce bubble size, slow bubble rise velocity and help stabilize froth (Klimpel and Isherwood, 1991).Frothers, originally derived from natural sources (e.g., pine oil and cresylic acid), are largely replaced today by synthetic products which provide more consistent properties. Polyglycols, based on PEO (polyethylene oxide), PPO (polypropylene oxide), or PBO (polybutylene oxide) groups, were first described by Leja and Nixon (1957) and have attracted wide use since then (Farrokhpay 2011). The chemical structure of polyglycols can be represented by a general formula: R(X)mOH, where R = H, or CnH2n+1 and X stands for EO (-C2H4O-), PO (-C3H6O-), or BO (-C4H8O-). The polypropylene glycol ethers (CnH2n+1(PO)mOH) are the most common of these reagents (Pugh, 2007) and the focus of this study.In general, the chemical structure of frother molecules comprises two parts, a non-polar hydrophobic hydrocarbon (alkyl: CnH2n+1) chain and a polar hydrophilic head. By introducing the ether -Olinkage, which acts as another polar site, the propoxy group (-OC3H6-) in the structure makes the frother readily soluble in water (Somasundaran and Wang, 2006), facilitating the industrial use of these frothers. Available as by-products, Dow Chemicals introduced as series of polyglycols, e.g., Dowfroth (DF) 200, 250, 263, and 1012, the most familiar being DF250 (CH3(PO)4OH), a polypropylene glycol methyl ether. While no longer available from Dow, these and other polyglycols are still widely used."

Jan 1, 2016

By Michael J. Beare

Requirements of both local permitting and international fundraising are forcing increasing numbers of projects in Russia and CIS to carry out dual technical studies. The principal focus of Russian mining project design is to satisfy local regulatory requirements. However, the technical documents are not generally accepted by international banks for project finance outside Russia. Similarly, international study documents are not accepted for permitting in Russia. The purpose of this paper is to compare and contrast Russian and international approaches to mine technical studies and draw conclusions from this. The Russian design and permitting system is centered around two key statutory technical documents termed the TEO Konditsy and the TEO Project. These documents are subject to regulatory approval and are broadly equivalent to the international prefeasibility study and the feasibility study respectively. A comparison of study criteria suggests similar approaches are used for the main technical disciplines in project design by the time projects are at the point of construction, but there is divergence on environmental matters where the OVOS (Russian ESIA equivalent) differs from an ESIA in some significant areas. The key differences relate to project footprint, level of technical detailed required for baseline studies, level of public consultation, consideration and disclosure of information, labour, coverage of community and social issues and the preparation of a Social and Environmental Management System (SEMS). It has been noted that the Russian Design Institutes often leave the detailed economic analysis until after the TEO Konditsy. A common problem is design teams tend to look for ?technological solutions? without due concern for project economics. The end result of this can be mines that are overcapitalized and hence sub-optimal. It can be concluded that Design Institutes have the monopoly on Russian permitting reports and this is likely to continue. Similarly, Russian institutes generally do not prepare feasibility studies to international standards and this is likely to continue to be the case. Therefore to achieve the requirement of dual technical studies, the international consultants and Russian Design Institutes will need to cooperate on a joint work program. Key issues will be to ensure the most appropriate option studies are carried out at the right stages, that project economics are considered throughout the study, and that the environmental work program covers the additional studies necessary for the ESIA.

May 1, 2009

By C. Sorel

The PAREX code has been developed since the nineties by CEA and AREVA to describe the PUREX process implemented in the French fuel reprocessing plants. It enables the calculation, either in steady or transitory states, of the behaviour of the different elements of interest at each process step. The high customized structure of the software allowed the implementation of various phenomenological models describing solvent extraction systems dedicated to uranium purification from crude ore to spent fuel. After qualification of the implemented models, the code was used to perform the design of flowsheets, for safety demonstration analysis or for operational assistance.

Aug 1, 2010