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By V. G. Papangelakis, J. E. Dutrizac, G. Azimi

A new model capable of predicting the solubility of calcium sulphate solid phases in zinc sulphate processing solutions from 25 to 95°C was developed. The model uses the Mixed Solvent Electrolyte (MSE) model of the OLI systems software to calculate the mean activity coefficients of the electrolyte species. The model was tested using recently developed experimental measurements. It was shown to predict accurately the solubility behaviour of calcium sulphate in multi-component zinc processing solutions containing ZnSO4, H2SO4, MgSO4, MnSO4, Fe2(SO4)3, Na2SO4 and (NH4)2SO4. The model can also explain the complex effect of coexisting metal sulphates on the solubility of the CaSO4 phases. The model is a practical tool for assessing the process chemistry of a wide variety of complex aqueous processing streams.

Jan 1, 2008

By D. H. Ryan, J. T. Graham, A. Navarra, J. A. Finch, S. Somot

Pyrrhotite (Po) is widely considered to be the most significant mineral in the self-heating of sulphides. It is therefore desirable to determine the amount of Po in mineral samples. This is commonly accomplished through x-ray diffraction (XRD) or quantitative evaluation of materials by scanning electron microscopy (QEM-SEM). This paper introduces another quantitative method based on Mossbauer analysis that requires limited sample preparation and has the additional potential to detect the sulphur/iron ratio within Po. The technique is explored using pentlandite/pyrrhotite mixtures.

Jan 1, 2009

By R. A. Nemchek

ABSTRACT Concentrator plant design has evolved from large numbers of small grinding mills to small numbers of large mills. Consequently, plant performance often hinges on the productivity of a single large semi-autogenous grinding mill. Industry attempts to address the grinding mills’ critical nature frequently result in specifications that can be made simpler, more economical, and better focused on the project’s goals. This paper surveys current specification writing practices and proposes an improved approach recognizing that product design, procurement, manufacturing, and quality are interrelated in a successful project. The lessons learned here can apply to all types of machinery specifications.

Jan 1, 2014

By Jamie N. Burdeski, Susan E. Hartfield-Wünsch

Aluminum sheet use has been steadily increasing in the automotive industry to achieve mass reduction and improve fuel economy. One significant manufacturing challenge for aluminum sheet implementation is the reduced formability compared to the steel alloys it replaces. This paper includes friction results from the draw bead simulator (DBS), twist compression (TCT) and strip draw (SDT) tests, for two oil based lubricants and four hot melt lubricants. Formability testing was done with the same lubricants and materials, testing in pure stretch with a hemispherical punch, and in draw with a breadpan shaped die.

Jan 1, 2015

By N. R. Andrade-Gonzalez

In this paper, the effect of magnesium and strontium additions on the heat treatment behaviour of cast A319,2 alloy was investigated, Permanent mold samples were heat treated at 495 °C for 4 and 24 h, then quenched in hot water and aged at 180 °C and 220 °C for different temperatures, It is found that multiple aging peaks are present in the age-hardening curves of Al-Si-Cu alloys, mainly when Mg and Mg-Sr are added, The results of electron probe microanalysis (EPMA) observations reveal that the age-hardening behaviour is related to the precipitation sequence of alloys, For the Al-Si-Cu alloy, the first aging peak is the result of the high-density GP zones, while the subsequent peaks arise from metastable phases, Obvious intervals during the transition from GP zones to metastable phases may be the main reason of the formation of multiple aging peaks, It is seen that addition of Mg (-0,40 wt %) leads to the precipitation of coarse Al5Mg8SioCu2 particles. When modifying the high Mg alloys, Cu-intermetallics segregate in areas away from the growing Al-Si eutectic regions, Modification with strontium retards the precipitation of the silicon out of the matrix.

Jan 1, 2005

By K. Yamaguchi

"This Precious metals content copper scrap is treated with a copper smelting process, and copper and precious metals are recovered. The precious metal lost in the slag is increasing with increasing of treated scrap amount. To determine the portion of the precious metals chemically dissolved and that associated with the mechanically trapped matte in the slag will be a key factor to improve the recovery of those metals. The distribution of precious metals between copper matte and FeOx-SiO2 slag phases is determined at 1300 oC and a fixed partial pressure of SO2 of 0.1 atm for the matte grades from 40 to 70 mass% of copper. The distribution ratios show a tendency to increase when the grade of matte is increased. In addition, the solubility of platinum and rhodium in the FeOx-SiO2-CaO slag under the air and the solubility of platinum in the FeOx-SiO2 slag equilibrated with a pure platinum or the Pt-Cu alloy were determined at 1300oC in the range of oxygen partial pressure from 10-9 to 10-7. The solubility of platinum and rhodium in the slag tends to increase with increasing content of copper in the slag and oxygen partial pressure. INTRODUCTIONThe stringency of the supply and demand of platinum group metal (PGM) intensifies by localization for resources and increase of the demand for PGM, furthermore, smelting and the recycling of PGM in the nonferrous smelting process take an important role. Scrap containing a precious metal for the purpose of collection of PGM is treated by copper smelting recently. With increase of the treatment amounts, loss of PGM in slags is the serious problem.In considering of PGM loss in slags, knowledge of the distribution behavior for PGM between slag and matte phases or slag and copper phases and the PGM solubility in slags is important. The distribution ratios of silver and gold between the FeOx-SiO2 slag and the Fe-Cu matte were reported by Roghani (Roghani et al., 2000), Shinha (Shinha et al., 1985) and Takeda (Takeda et al., 1993) However, there is no data for the PGM distribution ratio. On the other hand, the PGM solubility in slags was reported by Sano (Sano et al., 1997) However, there is very few report for the solubility of PGM in the nonferrous smelting slags."

Jan 1, 2012

By Xiong Tong, Jiushuai Deng, Yingbo Mao, Lingyun Huang

Ammonium carbamate has been used as a reagent for the leaching of copper from the copper oxide ore found in the Honghe state, Yunnan province, China. In order to find the optimal conditions for the leaching of copper from this copper oxide ore,the effects of several processing parameters, including the concentration, time, temperature, particle size and stirring intensity have been investigated. The results of these optimization experiments showed that the leaching rate of copper reached up to 72.76% under the following conditions: liquid-to-solid ratio of 10:1, ammonium carbamate concentration of 2.5mol/L, leaching temperature of 45 °C, stirring speed of 300rpm, a reaction time of 1.5 h and 85% by weight thereof passes through a sieve having 0.074 mm.

Jan 1, 2015

By A. J. Williams

"IntroductionAN EXCELLENT paper entitled Potash Discoveries in Western Canada (l) was presented to the 1948 Annual Meeting of the C.l.M. by L. Heber Cole, of the Department of Mines and Resources, Ottawa. In the intervening three and a half years, the search for oil and gas in Saskatchewan has added considerably to the information available on the occurrence of potash. It is the purpose of this paper to summarize the additional data. For greater clarity, it may be useful, first, to recapitulate some of the highlights of Mr. Cole's paper.Underlying the western plains of Canada there is a large deposit of sodium chloride, believed to be of early Devonian age. Associated with the sodium chloride are certain potash salts, primarily 'sylvinite,' a mechanical mixture of sodium chloride (halite) and potassium chloride (sylvite) crystals. The potash salts, when present, are usually near the top of the salt formation, though in at least one well they were found near the central part of the deposit. Cole reported on some seven wells in Saskatchewan which had encountered appreciable amounts of potash; these were the Ogema, Radville, Davidson Nos. 1 and 2, Prairie Salt Nos. 1 and 2, and Verbata wells. Depth of potash from surface ranged from 7,653 feet in the Radville well to a minimum of 3,466 feet in the Verbata well. Such depths do not compare favourably with those at which the potash is found in mines in the United States, France, and Germany, where about 1,000 feet is the average. The greatest concentration of sylvite encountered was in the Verbata well, where a bed 11 feet thick carried the equivalent of 21.64 per cent K20."

Jan 1, 1952

By Lars A. Bergstrom

High-voltage direct -current transmission is a relatively new technology. The successful development and operation of AC/DC converters, capable of handling large power blocks, have made HVDC transmission generally accepted by utility engineer s and planners around the world. HVDC technology still has significant development potential and, as a result, it is expected that equipment costs will escalate at a substantially slower rate than those of conventional AC equipment. This development will also result in still more compact terminal stations. This paper reviews two modern HVDC installations. In Zaire in Africa. a 1700-km overhead DC line rated at 500 kv, will supply power to the copper mining district in the Shaba region. Another HVDC link connects Norway and Denmark through a submarine cable rated at 250 kv. This is the longest HVDC cable in the world, 127 km, and the water depth , maximum 530 m, is also much greater than for any previous similar cable. The reasons for selecting HVDC are discussed, and the design and layouts are presented.

Jan 1, 1978

By Manqiu Xu, Songtao Yang, Zongfu Dai, Robert Pelton

Five years ago, VALE Base Metals (then INCO), approached Pelton's group at McMaster and described a challenging mineral separations problem. The McMaster group has a strong track record in colloids, polymers, and chemical additives for papermaking; however, they had no experience in mineral processing. They proposed employing hydrophobic nanoparticles to replace conventional low molecular weight, water-soluble flotation collectors. Over the last five years, Vale, together with the Ontario Government (OCE) have funded two graduate students at McMaster who have worked closely with flotation experts at Vale. Experiments involving both very clean model mineral suspensions at McMaster and complex ores at Vale, have shown that hydrophobic nanoparticles do indeed function as collectors. Key nanoparticle properties and mechanisms have been identified and the technology has been protected in patent applications. Efforts to commercialize the technology are on-going. We believe that this project is a good case study demonstrating the advantages of industry-university collaboration and the use of outside experts, who may come up with novel solutions to complex problems.

Jan 1, 2011

By C. Riveros, H. Henein

Bulk Metallic Glasses have a high potential as advanced engineering materials due to their various properties including strength and corrosion resistance, to name a few. This paper investigates amorphous phase formation and rapid solidification characteristics of impulse atomized Co-based alloys in order to understand and control the application properties of the final products. Amorphous fraction and kinetic crystallization properties of the atomized Co-based alloy powders were quantified by means of Differential Scanning Calorimetry. In addition, different but complementary characterization tools were used to analyze microstructures of the powders. These include optical microscopy, X-ray diffraction and micro-hardness tests. While the amorphous fraction within the powders is promoted by high cooling rate and smaller powder size as expected, hardness is found to decrease with the fraction of amorphous phase.

Jan 1, 2015

By F W. Irwin

In recent years, a number of significant developments have occurred in the steel industry which are no-table and of general interest. This paper is confined to the steel-melting phase of the business. The development of high production rates on Stelco's Basic Open Hearth furnaces is chronologically summarized. Al-though various aspects of this subject have been presented previously, this paper summarizes the developments in high fuel rates, the usage of basic refractories, low and high oxygen rates and hearth maintenance. Background T HE interest which has been shown in steelmaking techniques in the past few years has been due, primarily, to the extremely high production rates obtained. Upon further study of the facilities and techniques employed to generate this steel at record rates, tonnage oxygen appears as the common factor. It can be stated that tonnage oxy-gen has revolutionized steelmaking techniques to a degree never before encountered. It was only about ten years ago that the use of large amounts of pure oxygen in a steelmaking

Jan 1, 1965

By Allan A. Este, Bruce Arthur

"Rio Algom's Stanleigh Mine and Mill Operation Was' officially started up in August 1983. In September 1982, Rio Algom contracted Estonix International Inc. from Lively, Ontario, to develop and implement two innovative programs: (1) Work Renovation Planning, and (2) Systems Performance Training. This paper deals with the development and implementation of these two concepts relative to the plants technology from start-up to present and the exceptional results achieved. This paper discusses how a small but motivated workforce resulted in the smooth transition from startup to full production. It also deals with how these concepts were applied elsewhere in the organization which permitted a successful transition and downsizing of the over-all operation.IntroductionRio Algom Limited produces uranium in Elliot Lake, Ontario. In the late 1970s Rio Algom entered a contract with Ontario Hydro to supply uranium from its Stanleigh property, which had been idle since 1960. The mine was subsequently upgraded, and a new modem mill was designed and built, commencing operation in 1983.From then until September 1990,Rio Algom had three producing mines and mills in the Elliot Lake area. Quirke mill, with a capacity of 6350 tonnes per day, operated continuously from 1968. The Panel mill with a 3000 tonnes per day capacity, operated since 1979. Stanleigh mill continues to operate under long-term contracts, although at a production rate about 25070 lower than its rated capacity of 5000 tonnes per day.Both the Quirke and Panel mills, although not entirely similar, were conventional uranium mills utilizing crushing, grinding, leaching and ion exchange. As such, and in keeping with the traditional management style, there was a rather large mill operating workforce, which utilized a line-of-progression job classification system."

Jan 1, 1993

By J-P. Rossetti, A. Guerin, M. Jaboyedoff, L. Baillet, A. Mariscal, J. D'Amato, D. Hantz

"The processes leading to the fall of rock compartments from rock walls are poorly known as well as their velocity. It ensues that quantitative prediction of the failure time for a rock compartment which is presently stable, is not possible by a purely geomechanical approach. However a quantitative probabilistic prediction of rockfalls at the scale of a rock wall is possible if the spatial-temporal rockfall frequency can be determined or estimated (Hantz, 2011). For a better knowledge of failure processes and frequency, rockfalls have been detected in several rock walls, using annual terrestrial laser scanning, allowing comparison of the frequencies in different geological conditions. For one of these rock walls, the spatial detection have been completed by a precise dating of the events, using a quasi-continuous photographic survey (one photo every 10 mn), allowing the study of the influence of meteorological factors.The precise dating of rockfalls has been carried out for the Saint-Eynard cliff which towers above a residential area of the town of Grenoble (French Alps). The South-East facing cliff consists in bedded limestone gently dipping North-West and located at an elevation between 850 m and 1100 m. The surveyed zone is about 750 m large and 250 m high. Between 01/02/2013 and 26/11/2013, 65 rockfalls ranging between 0.01 m3 and 20 m3, have been detected by diachronic comparison of laser scanner data and dated by comparison of photographic images. The temperature at the elevation of the cliff has been calculated from the temperature measured (every 5 mn) at a meteorological station located at an elevation of 245 m and 2.5 km away from the cliff, using a temperature gradient of 0.003°C/m (D’Amato et al., 2014). The precipitation were measured 900 m away from the cliff at an elevation of 469 m. Different meteorological conditions have been defined: (a) “freeze” qualifies days with negative mean temperature (but with a thaw period, except for two days); (b) “thaw” qualifies days with positive mean temperature, but following a freeze day; (c) “rain” qualifies days with precipitation.Table 1 shows the rockfall temporal frequency for the different meteorological conditions. It appears that the frequency is about 6 times higher the freeze days, 2.5 higher the thaw days and 3 times higher the rain days than days without freeze, thaw or rain."

Jan 1, 2015

By W. Kunda, J P. Warner

SHERRITT GORDON Mines Limited annually produce 300,-000 pounds of pure cobalt by processing a nickel-cobalt-copper-iron sulphide ore which is mined at Lynn Lake, Manitoba. The ore (containing 0.04 per cent Co) is •concentrated to give a concentrate containing l 1-12 per cent nickel, about 2.0 per cent .copper, and 0.25-0.35 per cent cobalt, which is treated at the Refinery in Fort Saskatchewan, Alberta. The concentrate is leached in an ammoniacal solution of ammonium sulphate using compressed air as the oxidant. After filtration the leach solution contains, besides nickel and cobalt, copper ammines, sulpharnates and salts of various thionic acids. The copper is removed by precipitation as sulphide and the sulphur compounds converted to ammonium sulphate by a combined oxidation and hydrolysis treatment. The purified solution •Containing about 45 gpl of nickel and 1 gpl of cobalt is treated with gaseous hydrogen under pressure at 350°F to precipitate metallic nickel powder, the precipitation 'being terminated when the nickel content of the solution is about 0.8-1 gpl. Only about

Jan 1, 1962

By G. G. Bowser

PERUSAL of a list of present-day commercial explosives perhaps does not convey a full realization that there has been a great deal of improvement since the original dynamite was discovered nor that, in recent years, great developments have taken place in specialized explosives. This is true particularly of high-explosives for use in metalliferous mining or what is more commonly termed 'hard-rock' mining. Not many decades ago, only two or three types of explosive were avail-'able for commercial use. One was black blasting powder. Another was ordinary nitro-glycerin dynamite in various strengths. Black blasting powder remains with but very little change. Despite its ancient lineage, it is still with us as perhaps the sole explosive in use today which is almost identical in appearance, physical properties, and working ability or execution co the original. Which dynamite the story is different. Its evolution may be likened to that of the dog, nitro-glycerin as first discovered being the counterpart of the wild dog and, like it, dangerous and hard to control. The original dynamite as made by Nobel might then be considered as representing the first domesticaced species. This original dynamite, however, has been 'crossed with other bloods' until one sees now many distinct 'breeds' in the list. Present-day explosives still have the 'bark' and the 'bite', but with control and research have come many improvements; and types have been created which are specially adapted for particular kinds of work. We still have the direct descendant of Nobel's dynamite in the form of an improved nitro-glycerin dynamite. This C-I-L explosive, Polar Dynamite, is no longer the best type to use in the hunt for gold, silver, iron, and other metals. There have been developed other explosives more suitable for chat work. In Canada, such explosives are accomplishing this work effectively, not only where climatic conditions are moderate but through the rigours of our northern winters, with their sub-zero temperatures.

Jan 1, 1938

By L O. Montpetit

The economics of the asbestos mining industry of Canada, and the physical and chemical characteristics of asbestos fibre, as well as exploration, mining, milling and quality control methods, have been described by several authors in the past few years. The scope of this presentation is to survey the application of asbestos fibres in the major product groups of the construction industry in North America. Principal categories considered include flooring materials, asbestos-cement pipes and building products, high-temperature insulation, textiles, saturated asbestos felts and asphalt com pounds. During 1962, the asbestos mining industry of Canada produced an estimated 1.3 million tons of chrysotile fibre grades, and production capacity is expanding. The market demand for chrysotile fibre, on this continent, has been in the order of 50 per cent of the production volume. The asbestos industry is dependent for growth on the construction industry. Product research is active in finding new uses for asbestos fibre; some of the new developments are presented, including the use of short-fibre asbestos grades for extending the life of asphalt pavement.

Jan 1, 1963

By J. R. Kish, J. Dabrowski

"The susceptibility to intergranular corrosion modes is a major technical issue preventing widespread utilization of higher strength welded AA7xxx extruded beam profiles, in the peak-aged T6 condition, in automotive bumper assemblies. A study was undertaken to evaluate the relative exfoliation corrosion resistance (ASTM G85-A2) as a function of joint design parameters, namely the base alloy composition, heat-treated condition and beam orientation after exposure to a cyclic acidified salt spray test. This paper documents the major findings extracted from this study.INTRODUCTIONBumper systems play a predominant role in the passive safety of an automobile, since they are one of the main structures for absorbing the collision energy in the event of an automobile crash. Heattreatable AA6xxx-series (Al-Mg-Si) and AA7xxx-series (Al-Zn-Mg) Al alloys, with relatively high strength, toughness, energy absorption, weldability and formability, make it possible to design costcompetitive bumper systems to crush in a controlled fashion. In this context, Cu-lean AA7xxx extrusions, such as AA7003 and AA7108, which exhibit higher strength than AA6xxx extrusion, such as AA6082, represent an attractive light weight material from which to fabricate bumper assemblies (Clausen et al., 2000; Pedersen et al., 2008; Chen et al., 2009).Arc welding is a key joining process for AA7xxx alloys within the transportation industry. A major technological issue preventing widespread utilization of arc-welded AA7xxx joints is the susceptibility to severe localized corrosion (Kent, 1970, Reboul et al., 1985; Holroyd et al., 1987). It generally occurs as exfoliation corrosion within a heat affected zone (HAZ) a few millimeters from the weld bead, or a type of stress corrosion cracking (weld-toe cracking), which initiates at the weld toe and propagates into the interfacial region between the weld bead and the HAZ (so called “white zone”). In addition to the micro-galvanic cell activity induced by the intermetallic compound constituent and strengthening particles present, there is strong evidence that macro-galvanic cell activity between the weld bead and base AA7xxx alloy may be playing a controlling role. Electrochemical profiles taken across fusion welded joints, in cross-section, during exposure to saline solutions suggest that a significant potential difference exists across the AA7xxx arc-welded joint (Shumaker et al., 1967; Grauer and Wiedmer, 1980; Tuck, 1985, Onoro and Ranninger, 1993). These studies consistently show that the HAZ and base alloy are more electronegative with respect to the weld bead (arc-welded with AA5xxx filler wire). Despite this initial important work, the majority of the recent corrosion research effort on welded AA7xxx alloys has focused on the performance of friction stir welds (Lumsden et al., 1999; Wadeson et al., 2006; Hatamleh et al., 2009)."

Jan 1, 2012

By C. R. Machado

Sossego Mine was the first Vale SAG mill operation to process copper-gold ore. It is located in the state of Para, in the south-eastern Amazon region of Brazil. In the first six years of continuous operation, Vale investigated different alternatives for improving circuit performance by investigating operating conditions, mainly focusing on the SAG mill. Today, after a steady increase over five years the annual production rate seems to have stabilized. It is hoped this work will show how the SAG operating practice have been perfected with time and as new data are collected. Historical data of mill grind-outs and crash stops helped create operation curves depending on the ball charge volume and total charge volume. Also noted were impacts on throughput due to the effect of reducing liner weight and the ore type characteristics.

Jan 1, 2012

By D. R. Murray

"A promising long-term solution to uranium tailings reclamation has been the establishment of vegetation directly on the waste material. The soil profiles of areas vegetated for 0, 3, 8 and 10years are characterized as to the extent of soil development . The characteristics are compared with the visually interpreted soil profile. Organic matter content is presently the best analytical judge of soil development. Vegetation procedures have produced a build-up of organic matter in the top 10cm of tailings where natural microbial populations flourish. The CN ratio is high and the profile depth shallow, suggesting the need for additional fertilizer applications.IntroductionThe reduction of surface erosion and improved aesthetics of uranium tailings has been accomplished by the establishment of a vegetative cover. In 1971 research concentrated on developing methods of plant establishment at minimal cost and soil amendments on uranium tailings in Elliot Lake , Ontario. One process of stabilization used on a large scale was direct seeding of grasses and legumes into the tailings which had received only limestone and fertilizer treatments. Fertilizer additions were made for varying lengths of time in subsequent years to maintain the established cover.Maintenance-free vegetation would be possible once a soil profile developed with sufficient nutrient recycle and plant regeneration capabilities(1). Tailings vegetated in 1971, 1973 and 1978 that had received either 3 or 5 years of maintenance fertilizers were examined for soil development profiles. The extent of soil development and the relative effect of time and fertilizer would provide direction on reaching the goal of a self-sustaining cover.This paper is an abridgment of Division Report MRP /MRL 81-126 of the same title(2)."

Jan 1, 1984