Search Documents

By L. Byszynski

The results of a three month evaluation of the application of EMEW® technology at the KGHM Glogów II Smelter tank house bleed stream are presented. The current, conven¬tional electrolyte decopperization process has some limitations, including: only a fraction of its production is commercial grade cathode copper, significant operating costs, low current efficiency, low current densities resulting in low copper depletion rate, and arsine gas and sulphuric acid emission. The EMEW® cell technology developed by Electrometals Technologies Ltd. can overcome many of these limitations. Tests were performed on a pilot EMEW® installation comprising 30 cells at ambient temperature on electrolyte bleed, using current densities between 100 and 600 A/m2 , with copper concentrations between 45 and <1g/dm3. Results showed that a high grade copper can be obtained to the level of 7 g/dm3 of copper concentration in electrolyte. The use of EMEW® technology allows the direct and efficient recovery of over 85% of the copper contained in the bleed electrolyte. Glue & thiourea addition were tested in order to improve the parameters of the copper depletion process. The behavior of Arsenic and Bismuth was observed and a means for their elimination from the system proposed. On-line copper concentration monitoring is proposed to improve control and performance.

Jan 1, 2007

By H. Groeneveld, C. A. Connally, P. J. Hoenmans, W. L. Mason, John J. Justen

"A miscible displacement pilot, using a slug of LPG driven by separator gas, was conducted in the Cardium Reservoir of the Pembina Field. The injection pattern was a 10-acre, inverted, isolated five-spot. Upon completion of the LPG-gas phase, an .experiment was conducted using a slug of water followed by gas. Calculated performance of the pilot is compared with actual performance. Equations are developed to cakulate the distribution of LPG into zones of varying permeability, to estimate the progress of the flood at different times in the various zones, and to estimate gas rates after breakthrough. The analysis indicates that permeability stratification was a dominant factor in con-trolling oil recovery and that oil was completely displaced from the swept pore volume. The results of the pilot indicated that miscible flooding is a practical means of pressure maintenance in this reservoir. The total recovery from the pilot area was good in spite of the early breakthrough of LPG. The effects of stratification were reduced by injecting a slug of water into the partially swept reservoir."

Jan 1, 1960

By Marko Lampi, Ross Andrews, Jouni Pihlasalo, Robert Matusewicz

With widespread discussion on reducing carbon, sulphur and other emissions, use of sustainable energy sources and the pivotal circular economy theme, consideration needs to be given to pyrometallurgical operations broadly and more specifically, non-ferrous metallurgy. These themes present a number of challenges in terms of current operations and the view of processing the metals which are largely taken for granted in day to day living. This paper considers how these themes will impact pyrometallurgical flowsheets using the non-ferrous base metals as an example. It will examine the flowsheet chain to offer views on the boundaries of flowsheet optimization and the application of available tools to meet these future goals and challenges. INTRODUCTION The themes of reducing footprint through lowered CO2, S and other emissions, together with process sustainability (e.g. lowered energy) and links to the circular economy are well known to everyone in the metals industries. Whether it is reducing greenhouse gas emissions or analysing the importance of metals recycling in the circular economy, all these themes carry with them the fundamental premise of any change being considered; how can you best optimize a system to meet your aims? Of course, this depends on the available tools and the approach used for optimisation.

Jan 1, 2019

By Helmut Lerchs

An open-pit mining operation can be viewed as a process by which the open surface of a mine is continuously deformed. The planning of a mining program involves the design of the final shape of this open surface. The approach developed in this paper is based on the following assumptions: 1. the type of material its mine value and its extraction cost is given for each point; 2. restrictions on the geometry of the pit are specified (surface boundaries and maximum allowable wall slopes); 3. The objective is to maximize total profit-total mine value of material extracted minus total extraction cost. Two numeric methods are proposed: A simple dynamic programming algorithm for the two-dimensional pit (or a single vertical section of a mine), and. a more elaborate graph algorithm for the general three-dimensional pit. ASURFACE mining program is a complex operation that may extend over many years, and Involve huge capital expenditures and risk. Before undertaking such an operation, it must be known what ore there is to be mined

Jan 1, 1965

By S. B. Kang

Magnesium has poor ductility at temperatures lower than 225°C and, as a result, Mg alloy sheets are produced via fairly complex thermomechanical processes consisting of numerous sequential steps of hot (warm) rolling with low reduction and intermediate recrystallization annealing operations. In context of the present study, a simple technology for the fabrication of magnesium sheets by hot (warm) rolling was applied to various magnesium alloys. The misch metal addition in those AZ alloys was done to evaluate the deformation behavior. Tensile tests were carried out for those AZ alloys after applying different heat treatments. The precipitation of ß phase (Mg17Al12 phase) induced different microstructures with various cooling method from solution treatment temperature, and also with various annealing treatment temperatures.

Jan 1, 2006

By W. A. Jankola

Teck Cominco Metals Ltd. operates an integrated zinc-lead smelter at Trail, British Columbia, Canada. The zinc circuit comprises three parallel operations: conventional fluid-bed roasting, direct zinc pressure leaching of concentrates and atmospheric leaching of zinc oxide fume recycled from the lead smelter. The products from these three areas are combined in the main leaching plant where they undergo iron purification. Unlike most leaching circuits, the leach process in Trail begins with an acid leach and is followed by a neutral leach. An evaluation was undertaken to determine if the process at Trail could be improved by converting to the conventional neutral leaching process with a subsequent acid leach of the residues. This paper explores the results of these tests and the implications for Trail Operations.

Jan 1, 2006

By J. Defreyne

CESL has developed a proprietary hydrometallurgical process for base metal concentrates, notably those of copper and nickel. The process is based on pressure oxidation (PO) of the sulphide minerals, which is done at elevated temperatures in mixed sulphate-chloride liquor at about pH 2 ? 3. The process achieves maximum oxidation of the metals whilst minimizing sulphur oxidation to sulphate. Almost all base metal sulphide minerals are efficiently treated under these conditions. In the case of copper minerals, pressure oxidation does not generally put the copper into solution, because of the relatively high pH prevailing in this process. Therefore, PO is followed by an acidic leaching stage, which specifically aims at maximum copper dissolution with minimal leaching of iron. The overall copper recovery is largely determined by the efficiency of this stage. The process has low capital and operating costs, partly because there is minimal use of acid or neutralizing agents for iron dissolution or precipitation, respectively; this is achieved by minimizing iron leaching during both the oxidation and leaching stages. Iron sulphides in the feed concentrate deport almost entirely to the solid leach residue as hematite, which has superior handling characteristics for filtering and washing. Iron minerals play a key role in the process, with pyrrhotite and pyrite having very different responses to the oxidation process. Acid management for the whole process is affected by the iron mineralogy, and the flowsheet is therefore tuned to the specific concentrate.

Jan 1, 2006

By J. Janeson

Wall control at the Pipe Open Pit is of primary importance in ensuring the long-term stability of the operation, while keeping costs to a minimum. Blasting techniques have been adapted to the variations in competence and structure of the wall rocks. A portion of the perimeter wall is being developed in incompetent peridotite . A recent change in pit slope design provides a wide safety berm on alternate benches. A support program which consists of pinning the crests of wide berms with vertical reinforced concrete dowels and horizontal bolting of walls shows evidence of increasing the stability of the pit walls. This paper describes the blasting and support techniques which are contributing to successful wall control in the Pipe operation.

Jan 1, 1979

By B. Lafrance, C. J. Beaumont-Smith, L. R. Jones

"Abstract - The Burnt Timber gold deposit is located in the Paleoproterozoic Lynn Lake greenstone belt of the Trans-Hudson Orogen, Manitoba. The deposit occurs along the Johnson shear zone, and is hosted by enriched and depleted tholeiitic volcanic arc basalts cut by feldspar porphyry dikes. The Johnson shear zone is a regional, belt-parallel structure characterized by the intensification of the regional S2 foliation. At the Burnt Timber deposit, S2 is folded by centimeter- to meter-scale, Z-shaped, F3 chevron folds that have an axial planar S3 crenulation cleavage. Within the 20 to 30 m-wide core zone of the shear zone, S2 and F3 are transposed parallel to S3 and the volcanic rocks are strongly sheared parallel to S3. The presence of a steeply plunging stretching lineation, together with dextral shear sense indicators along both S2 and S3 on horizontal surfaces, suggest that the Johnson shear zone is a dextral transpression zone. Gold was introduced in pyritic, biotitic, and carbonatized mafic volcanic rocks along the core of the shear zone. Mylonitic mafic volcanic rocks contain localized high-grade zones (=10 g/t Au) that differ from wider carbonatized, low-grade zones (<3 g/t Au) by the presence of deformed gold-bearing quartz-pyrite veins. High-grade zones are also associated with swarms of quartz-pyrite veins that cut across sericitized and carbonatized feldspar porphyry dikes, which acted as brittle, competent bodies during shearing. Gold deposition in the high-grade zones was controlled by the channeling of hydrothermal fluid along the core of the shear zone during shearing of the volcanic rocks, and brittle fracturing of the porphyry dikes. Sommaire - Le gîte aurifère de Burnt Timber est situé dans la ceinture de roches vertes Paléoprotérozoïque de Lynn Lake dans l’orogène Trans-Hudsonien, au Manitoba. Ce gîte est situé le long de la zone de cisaillement de Johnson et est encaissé dans des basaltes tholéiitiques d’arc enrichis et appauvris recoupés par des dykes porphyriques. La zone de cisaillement de Johnson est une structure régionale parallèle à la ceinture de Lynn Lake caractérisée par une intensité accrue de la foliation régionale S2. Au gîte de Burnt Timber, S2 est affectée par un plissement F3 en chevrons en Z d’échelle centimétrique à métrique associé à un clivage de crénulation de plan axial S3. Dans la zone centrale de 20 à 30 m de largeur au sein de la zone de cisaillement, S2 et F3 sont transposés parallèlement à S3 et les roches volcaniques sont fortement cisaillées le long de S3. La présence conjointe d’une linéation d’étirement à forte plongée et d’indicateurs cinématiques dextres sur les surfaces horizontales S2 et S3 suggère que la zone de cisaillement de Johnson est une zone transpressive dextre. L’or a été mis en place dans des volcanites mafiques altérées en pyrite, en biotite, et en carbonate au coeur de la zone de cisaillement. Les roches volcaniques mylonitiques présentent des zones aurifères locales à haute teneur (=10 g/t Au) qui diffèrent des zones à basse teneur (<3 g/t Au) par la présence de veines de quartz et de pyrite aurifère. Des zones à haute teneur associées à des essaims de veinules de quartz et de pyrite sont aussi notées dans des dykes porphyriques à plagioclase altérés en séricite et en carbonates; ces dykes se sont comportés comme des corps compétents durant le cisaillement. La déposition de l’or dans le zones à haute teneur a été contrôlée par la circulation du fluide hydrothermal au coeur de la zone de cisaillement durant la déformation des roches volcaniques et la fracturation des dykes porphyriques."

Jan 1, 2006

By Ed McConaghy, P. LaRochelle

The Ambatovy Nickel Project comprises the development of mine, hydrometallurgical processing facilities and necessary infrastructure in Madagascar, positioning Ambatovy as one of the world’s largest producers of nickel and cobalt from lateritic ore. SNC-Lavalin successfully provided comprehensive Engineering, Procurement, Construction Management (EPCM) services for this major capital project which, apart from its sheer size, scope, and engineering design, represented significant location, infrastructure, labour, environmental and climatic challenges. Today, the project has reached 90% of its nameplate capacity and is in its final performance optimization stage. This paper will discuss the significant project management effort that was required to successfully address the complexity of this major project. It will cover the main project management control systems and the engineering tools and processes used during the detail engineering, procurement, and construction phases to achieve optimum project execution.

Jan 1, 2015

By J. P. Grau, J. Z. Lu

"Thickeners/clarifiers are widely used in coal preparation plants, potash processing and other mineral processing facilities. Thickeners play a very important role in slurry treatment systems to accomplish solid/liquid separation. The demand for larger plants and the increased thickener handling capacities sometime require thickener diameters as large as 200m. The development and use of high capacity thickeners makes it possible to increase the handling capacity of these thickeners by several to more than 10 times compared to conventional thickeners. Hence, for a given slurry rate, selection of a high capacity thickener will significantly reduce the footprint of the thickener. Much higher handling rate, higher concentration of underflow, clearer overflow and lower capital cost are obvious advantages of high capacity thickeners; however, some process requirements and the concerns of operational cost, especially the flocculant cost of a high capacity thickener operation, keep some engineers selecting conventional thickeners and staying away from the high capacity thickeners. Forty years after the first high capacity thickener was developed, there are still arguments in the selection of conventional thickeners or high capacity thickeners in mineral processing. The arguments will continue unless there is a clear picture of capital cost vs. operational cost for each of the thickener types. The purpose of this paper is to analyze these costs and to provide guidelines for selection of thickeners. INTRODUCTIONThickeners/clarifiers are widely used in various slurry treatment systems. For mining and mineral processing, thickeners are an integral part of the solid/liquid separation system. The feed to the thickeners are processing slurries. The fundamental mechanism for the solids/liquid separation is for the solid particles in the slurry to gravity settle inside the thickener tank. The clear water overflows from the top of the thickener tank and is typically reused in the processing circuit, and the concentrated underflow is discharged to different downstream process systems depending on the application of the thickeners. The general requirements for a thickener operation include high density of underflow and clear overflow. Since thickener operation consists of continuous feeding, overflow and discharge of underflow, the solid particles will gravity settle against an upward flow with its velocity dependent on the feed rate and the underflow discharge rate. Higher feed rates to a given thickener produce higher upward velocities. Underflow discharge is typically relatively small compared to the amount of overflow. The upward flow tends to take particles up to the overflow. Only those particles having a settling velocity greater than the upward flow velocity will possibly settle out. Hence, thickener feed rate has to be controlled so that the required overflow water clarity can be achieved."

Jan 1, 2012

By K. Himbeault, D. Campbell, N. C. Garisto, D. A. Orava, A. Rosaasen

"The level of scientific knowledge about the effects of contaminants is increasing and changes in environmental monitoring are likely to allow for the assessment of environment effects particularly to the aquatic environment. This paper provides an overview of recent developments in this area which include the environmental effects monitoring program for pulp and paper operations, the assessment of the Aquatic Effects of Mining (AQUAMIN) program, the Aquatic Effects Technology Evaluation (AETE) program, and the review of the federal Metal Mining Liquid Effluent Regulations (MMLER). The paper also provides a look forward at the direction of environmental monitoring of mine projects in Canada. IntroductionEnvironmental monitoring programs provide a wide range of data to environmental management systems, regulatory authorities, and stakeholders. The data obtained are used to demonstrate that operations are in compliance with regulatory environmental protection requirements, and provide the scientific basis for assessing the effectiveness of environmental protection measures. Environmental monitoring requirements for mine projects are established based on the type of operation, site specific issues and concerns, and the requirements of regulators and mine proponents.The level of scientific knowledge regarding the potential effects of contaminants on the receiving environment is increasing, and in particular with regards to the receiving aquatic environment. Regulatory controls regarding the protection of fish, fish habitat, and fishery resources are being reviewed with regards to their adequacy, and the environmental effects monitoring program on the pulp and paper industry is expected to provide useful data relevant to those types of operations. These developments are of interest to mine proponents as it is presently expected that an environment effects monitoring program will be developed specifically for the metal mining industry under a regulated environmental effects monitoring program as part of the Fisheries Act. This paper reviews recent developments in this area, and provides a look forward on the future directions of environmental monitoring programs."

Jan 1, 2000

By T. Imgrund, A. Bischoff, S. Spürk

"Specific conditions of underground coal mines at great depth, such as high temperatures, high rates of methane inflow and natural ventilation pressure provide considerable challenges for the reliable design of appropriate mine ventilation systems. For decades coal mining in Germany has coped with these extreme circumstances. Based on these experiences appropriate software tools for simulating mine ventilation networks have been developed and continuously enhanced. This paper examines differences in the simulation results and underlying calculation methods of two software solutions. The analysis is based on the comparison of FlowNetTM and VentSim DesignTM (Version 5.1) regarding the accurate prediction of fluid mechanical quantities and their validation with real measurements. A special focus lies on exceptional ventilation scenarios typical for deep coal mines, like gas inflows, fire events and buoyancy effects. The purpose of the comparison is the future utilization of the experiences gained during mining at up to 1,500 m depth for state of the art ventilation design. INTRODUCTION Ventilation is an essential component of mine operations—as providing fresh air to workplaces, diluting and removing explosive, toxic or asphyxiating pollutants and assuring sufficient climate conditions. On the other hand, the costs of ventilation contribute to a large extend to the overall operating costs of a mine, as the share in the energy consumption of a mine may be in the range of 25–50% (Belle, 2008). Accordingly, proper design of ventilation systems has been a task since early times. Consequently software for modelling of ventilation networks has been developed in order to improve efficiency and accuracy of calculations (Maleki, 2018). Compressible flow has not been considered by initial ventilation modelling software tools. In Germany, the consideration of changes in airflow density—depending on pressure and temperature—in the algorithms of ventilation simulation software has been started in 1974 by Duepre & Hofbauer. This development had been continued by the Pruefstelle fuer Grubenbewetterung (Test Centre for Mine Ventilation) and resulted in the release of a computer ventilation software named “Wetter”. The mine inspectorate of the German state of North Rhine-Westphalia, which supervises the major coal mining district in Germany, declared ventilation simulation based on compressible flow being “state of the art” in 1985 (Pollak, 1985). This pronouncement made allowance for assessing the consequences of underground fires and downtimes of main fans based on advanced software solutions."

Jan 1, 2019

By M. R. Hudec, M. A. Nikolinakou, P. B. Flemings

"We model the shale response to the large deformations associated with salt bodies, and we identify the implications of the stress changes for hydrocarbon exploration. We employ both the static and evolutionary approach, and show that while the static one can model actual geologic geometries, only the evolutionary approach can provide a detailed description of the stress history of shales, which is essential for predicting stress, porosity, and pore pressure and, more generally, for understanding Earth processes related to salt-hydrocarbon systems.INTRODUCTIONDuring the last two decades, understanding the stress, material behavior, and pore pressure in shales around salt bodies has become increasingly important. The energy industry routinely drills near salt (Beltrão, Sombra, Lage, Fagundes Netto, & Henriques, 2009; Meyer, Zarra, Rains, Meltz, & Hall, 2005; Seymour, Rae, Peden, & Ormston, 1993), because a significant number of hydrocarbon reservoirs around the world are found in layers dipping away from salt diapirs.Salt is a viscous material that cannot sustain deviatoric stresses. Under differential loading it flows, changes shape, and eventually relaxes to an isostatic stress state (Urai & Spiers, 2007). Therefore, emplacement of a salt body and its viscous relaxation process may cause significant deformation of the surrounding sediments, perturb their state of stress and create local overpressures (Dusseault, Maury, Sanfilippo, & Santarelli, 2004; Seymour et al., 1993). As a result, drilling near salt is particularly challenging, and problems leading to additional expense or even abandonment are common (Bradley, 1978; Dusseault et al., 2004; Meyer et al., 2005; Seymour et al., 1993; Willson et al., 2003).Historically, salt and the evolution of its cross section to the present day geometry have been studied using kinematic restorations (Rowan & Ratliff, 2012). This approach aims to explain the present geologic section through a sequence of plausible past sections; however, it does not model the constitutive response of the wall rocks, hence it cannot provide any prediction on their state of stress. Similarly, largestrain numerical studies (Albertz & Beaumont, 2010; Chemia, Schmeling, & Koyi, 2009; Goteti, Ings, & Beaumont, 2012; Gradmann, Beaumont, & Albertz, 2009) have focused on the rheological evolution of salt systems without modeling the geomechanical response of the sediments."

Jan 1, 2015

By K. C. Sole, G. Robinson, M. S. Moats, W. G. Davenport, S. Sandoval

Global practice in hydrometallurgical production of copper cathode by electrowinning is reviewed, based on individual plant operating data for 2018. Data from 29 plants were collected, representing 38% of world cathode copper production. Similar surveys were carried out in 1997, 1999, 2003, 2007, and 2013. This survey includes analysis of historical and current data. Evolving trends in operating conditions and performance, as well as equipment design and process technology choices, are analysed and differences in operating practices with location are assessed. Examples of recent technology and operational choices to increase productivity, improve copper quality, and decrease electrical energy consumption are discussed. Significant project expansions, particularly in Africa, and the consolidation of numerous small Chinese operations are also presented. INTRODUCTION Global trends and operating practices in copper electrowinning (EW) in 2018 are reviewed and evaluated. Similar world and African surveys were carried out in 1997, 1999, 2001, 2002, 2003, 2007, and 2013 (Robinson, Davenport, & Jenkins, 1997; Jenkins, Davenport, Kennedy, & Robinson, 1999; Davenport, Jenkins, Robinson, & Karcas, 2001; Robinson, Garbutt, & Davenport, 2002; Robinson, Davenport, Jenkins, King, & Rasmussen, 2003; Robinson, Davenport, Moats, Karcas, & Demetrio, 2007; Robinson, Sole, Sandoval, Moats, Siegmund, & Davenport, 2013). Contributing operations included sites from the USA and Mexico (9), Chile and Peru (6), Laos (1), Kazakhstan (1), and Africa (9). Despite fewer contributions compared with past experience, this survey nevertheless represents 2018 copper EW cathode production of 1.76 Mt, or about 38% of world production of 4.64 Mt (International Copper Study Group, 2017). This drop in permission to contribute is attributed to the more competitive nature of the industry and unprecedented production pressures; furthermore, several operations in Australia have shut down, while large operations that are currently commissioning or ramping up to full production in Africa and Asia declined to participate. Of the Chinese operations, which represent an increasingly important proportion of global electrowon cathode copper, particularly in Africa, only Tenke Fungurume (Democratic Republic of Congo; DRC) participated in this survey.

Jan 1, 2019

By Zetti Gavelán

Globalization and the search for new ore deposits inevitably lead to investment in foreign markets. Investors need to be aware of the effect of their venture on regional, social and economic issues when they invest. Decades of detailed statistics from various sources can be integrated and analyzed to predict the social-economic impact of investment, thereby mitigating risk. To this end, the correlation among variables such as foreign direct investment into mining (FDIM), reserves, and socio-economic indexes is examined. The investigation focuses on South America from 1992 to 2000. Throughout the past decade, South America has benefited from capital investment from more developed countries. This huge investment by the mining industry has impacted the South American economies and can be measured directly using the FDIM. Other economic variables investigated include mining gross domestic product, direct employment, and human development indexes. The correlation is based on data compiled from the World Bank, international risk assessment agencies, the United States Geological Survey (USGS), and the information agencies of various South American countries. Initial analysis of the economic data suggests various expected outcomes. For example, foreign investors may disregard a measured, highly negative country risk in deference to the quality of its mineral resources. It is important to note that the standard measures of country risk published by investment analysts are not industry or investor-specific. In the case of the investor, the level of accepted risk is based on their managed investment portfolio. It is noted that arguments for level-playing fields may be the antithesis of globalization. The discovery and exploitation of ore bodies in a globalized environment necessitates the development of economic measures that standardize mining-specific risk variables and trends. The latest published information on the security of mineral investments in South America is investigated by integrating databases of economic, geologic, production, human indexes, and risk ranking.

May 1, 2003

By Michael Cullen

The Quinsam Coal Mine is in the process of extracting a panel beneath the mine access road. To prevent damage to the road, and adjacent powerline, it was necessary to establish a ?protection zone? within which the extent of mining would be limited. The protection zone is analogous to the setback limit. For economic reasons it was desirable to make the protective zone as small as possible, and with the greatest extraction ratio possible. The size of the protective zone was established by determining the angle of critical deformation using the numerical model FLAC, coupled with field data on subsidence from the Mine. The angle of critical deformation (defined as the angle, measured from the vertical, at which intolerable damage is sustained by a structure) was determined to be between 0 and 5 degrees. The allowable extraction ratio in the protection zone was established using the ARMPS method of pillar design coupled with field data on pillar stability from the Mine. Excavations spans to prevent caving were determined by historical experience and field data on span stability from the Mine, coupled with numerical modeling. The minimum pillar size was determined to be 7.5m. The maximum pillar height was established at 2.5m. The maximum allowable excavation span was determined to be 8.5m. With these criteria, extraction ratios between 54 and 73% (measured in plan view) were determined to be appropriate for the protection zone.

May 1, 2001

By V. G. c Papangelakis, M. Huang

A conductivity cell, developed previously, was employed in an effort to investigate the inter-relation between electrical conductivity and acidity of sulphuric acid - metal sulphate solutions at high temperatures. The measured solutions include the H2SO4-H2O, MgSO4-H2O, H2SO4-MgSO4-H2O, H2SO4-MgSO4-Al2(SO4)3-H2O solutions. All solutions reported in this paper were measured from 15 to 250 °C at equilibrium vapour pressure. The maximum measured concentrations of H2SO4, MgSO4 and Al2(SO4)3 were 0.45 m, 0.30 m and 0.10 m, respectively. It was found that, from 15 to 250°C, there is a linear relationship between H2SO4 concentration and electrical conductivities for acid concentration up to 0.45 m. At 250 °C and constant H2SO4 concentration, the solution conductivity drops with the increase of MgSO4 concentration. Lt is suggested that this drop is caused by a decrease in the concentration of H. Finally, an empirical model was developed based on the available measurements. This model has been tested against real laterite leach solutions where sulphuric acid and metal sulphates are dominant electrolytes. The average difference between the estimate acid concentration from this model and the one from titration was less than 5%.

Jan 1, 2004

By N. Ahern, L. Manoukian

"Cyanide is a leaching agent for precious metals commonly used in gold ore processing. Cyanide exists in various forms (including free, complexed as weak or strong complexes, and as ions such as cyanate and thiocyanate), so its detection, speciation and analysis in processing or environmental samples can be complex. This paper will review best practices for cyanide sampling and preservation in the field, interferences and pretreatment methods required prior to sample analysis and analytical methods that are used for cyanide species. Titrimetric, flow injection ligand exchange, spectrophotometric, colorimetric, potentiometric, amperometric, and chromatography techniques will be discussed and their chemistries, detection limits, advantages and limitations will be described.INTRODUCTION Cyanide is well known to be an extremely toxic species. Accurate cyanide measurement in effluent from mines is critical from an environmental perspective. Its measurement is also an important control parameter in the recovery of gold using cyanidation. Cyanide chemistry is diverse and complex, and cyanide analysis can be challenging as a result of and because of limitations in understanding of analytical methods. Various chemical mechanisms can form or destroy cyanide, and the sample matrix or preservation chemicals can also affect analytical results. These interferences make the collection of reliable cyanide measurements challenging and can start as soon as the sample is collected, during laboratory pre-treatment and during analysis. This paper reviews different methods of cyanide measurement. The basic chemistry of cyanide, best practices for sampling and preservation, as well as various methods of analysis will be discussed.CHEMISTRY The complexity of cyanide chemistry is well known (Beck, 1987; Delgado, Botz, Bucknam, Milasovljevic, & Staley, 2008; Botz, Milosavljevic, & Ward, 2013) and is attributed to the ability of cyanide to undergo: •,Volatilization •,Precipitation •,Adsorption •,Complexation with metals •,Oxidation to cyanate, ammonia, or cyanogen chloride •,Reaction with sulfur or sulfide minerals to form thiocyanate •,Redox reactions leading to the formation of cyanogen and cyanate •,Redox reactions (of some cyano complexes) •,Photochemical reactions (of some cyano complexes)"

Jan 1, 2017

By C. Blawert

In spite of various corrosion studies on HPDC AZ91, there is no clear indication which microstructure gives the best corrosion performance. The skin with its fine microstructure is sometimes reported to have the best corrosion resistance, but there is no clear definition of the skin. If the skin is the outermost part of the casting and nothing is removed from it, then it is contaminated and the corrosion resistance is low. If the outermost skin is removed (about 25 µm) then a better corrosion resistance can be obtained. However this does not automatically mean that there is no other region in the bulk of the casting which could have a similar or even better corrosion resistance. Indeed, the corrosion measurements including potentiodynamic polarization and long term electrochemical impedance spectroscopy (EIS) revealed a lower corrosion resistance of the original as-cast skin about 100 pm thick. The thickness of this region is more or less independent from the thickness of the casting section. The surface region is free from any dendritic grain growth which influences the amount and distribution of the 13-phase and therefore the distribution of the most important alloying element Al. This could explain the different corrosion behavior. Further reason can be found in the enrichment of some impurities such as Fe in the near surface.

Jan 1, 2006