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By B. Dubreuil, J. -M. Lalancette, D. Lemieux

A gold bearing pyrite concentrate was treated at the pilot scale for the extraction of gold. Mineralogical analysis of the concentrates identified gold to be mainly present in the form of a solid solution in pyrite. Gold distribution resulted in a poor extraction yield of 55 % by direct cyanidation. A piloting campaign including an oxidative pre-treatment by roasting in a fluid bed was followed by treatment with halogens for gold extraction and has led to a gold extraction yield of 94%. Sulphur removal during the oxidation was very efficient at >99.5% and gold extraction by the halogens was completed within a 1 hour contact time. The piloting was performed on a 300 kg sample and used a diluted solution of hypohalites as the oxidizing agent for gold extraction. Sulphuric acid was injected in the reactor during the halogens treatment to lower pH to 2. The diluted solution of hypohalites (1-3%) was generated by electrolysis during the piloting campaign in a diaphragm-less electrolysis cell. The extracted gold was recovered via adsorption over silica and the gold depleted brine was treated for impurities removal. This brine was recycled for further gold extraction. With the recycling of water and brine, the regeneration of hypohalites and with a barren solid that is inert and stable, the Nichromet Extraction technology is a green process where the protection of the environment does not preclude profitability.

Jan 1, 2014

By J. -F. Blais, M. -O. Simonnot, P. Charbonnier, J. Mocellin, Université de Lorraine INRA, G. Mercier

"Huge amounts of air pollution scrubber sludge have been generated during ferromanganese production using blast furnace. These residues have been historically deposited in ponds near steel making plants. They are very rich in zinc, manganese and lead (5 to 40 %) and also contain aluminum and iron. Considering the market value of these metals, brownfield sites can now be used as secondary resources. These ponds also have to be cleaned up to meet the environmental regulations.We have developed a hydrometallurgical process to recover Zn, Mn and Pb in order to produce valuable compounds of Mn and Zn and recover the final Pb residue by pyrometallurgy. The Zn and Mn compounds need to be pure enough to be economically valuable. Batch laboratory tests were carried out to determine suitable selective leaching conditions. The investigated operating conditions were acid concentration, pulp density and temperature. Optimal conditions to maximize zinc extraction (100 %) and manganese extraction (95.9 %) were found using sulfuric acid and sodium metabisulfide. The final residue contained 14.8 to 23.8 % of Pb. Then, Zn was recovered in the form of ZnO or ZnS by precipitation and Zn metal by electrowinning, while Mn was recovered as MnCO3 with a fairly acceptable concentration of impurities.INTRODUCTIONFerromanganese has been produced by pyrometallurgy in much of Western Europe for centuries. Use of wet scrubber to remove pollutant and dust particles from gas stream was common for most of these operations. Those residues contain high concentration of Zn, Mn and Pb. They have been left to decant in settling ponds installed close to the steel production plants. They now constitute heavily contaminated artificial soils. Those sludges are so contaminated with Zn, Mn and Pb that they can be used for metal production. Currently, no method is available to decontaminate these residues and recover Zn, Mn and Pb. Therefore, an approach considering these brownfield sites as secondary resource is in development. Doing so would achieve two goals, decontaminate the site and produce metals.. (Huot, Faure, Biache, Lorgeoux, Simonnot, & Morel, 2014a; Huot, Simonnot, Marion, Yvon, De Donato, & Morel, 2012; Huot, Simonnot, Watteau, Marion, Yvon, De Donato, & Morel, 2014b)."

Jan 1, 2016

By C. Tissot, R. Palmer

"Due to the low concentrations of gold, direct measurement of gold concentration in ore on belt has not been seriously considered to now. Pre-concentration or sorting strategies have largely consisted of particle sorting based on secondary characteristics such as colour, which can be successful in select cases. CSIRO has produced sample measurement results using gamma activation analysis of ~300 gm samples with accuracies of around 30 ppb at best. With this encouragement, a feasibility study into gold ore measurement on belt for the purpose of sorting pods of gold ore has been undertaken. The study described here included, prototype design options with existing industrial Linacs, extensive Monte Carlo modelling of measurement sensitivity and shielding, further sample measurement, a study of the interaction of target measurement accuracy and sorting efficiency, and a rough estimation of potential economic benefit. The projected model sensitivity of around 0.1-0.15 ppm (1 standard deviation) in 10 seconds for 1 ppm average feed result in good bulk sorting performance and intriguing economic potential.INTRODUCTION Pre-concentration or sorting strategies for gold ores have largely consisted of particle sorting based on secondary characteristics such as colour or density, which can be successful in select cases (Klein, 2010). No method is available to measure gold content for sorting in particles or even in bulk on belt, principally due to the low concentrations of gold present. In fact, in many cases it is difficult to do rapid bulk grade measurements of base metal ores with concentrations many orders of magnitude higher. By a fortunate quirk of nature gold is particularly amenable to gamma activation analysis (GAA). CSIRO has performed extensive work in GAA of samples of crushed ore (Tickner, 2017). This has resulted in the Photon AssayTM technique that is currently being commercialised through the CSIRO spinoff company Chrysos. The technique relies on the recent availability of industrial high intensity X-ray sources such as Linacs which are currently being used in industry for security, medical and sterilisation applications. This development has led to CRC ORE funding a feasibility study to determine whether on-belt measurement of gold concentration is possible at a rate and accuracy sufficient to be useful for bulk sorting, where pods of ore are diverted rather than individual rocks. The study in the first instance is based on Monte Carlo modelling that has successfully predicted the performance of the sample based gold measurements. As well as the measurement feasibility consideration was also given to the likely heterogeneity of gold ores and hence the degree to which useful separation could be achieved. This is then tied to a back of the envelope evaluation of the order of magnitude economics of bulk sorting in an example deposit."

Jan 1, 2017

By Ian Orford, Ken L. Boyd

"Can the ever-increasing tonnages of ore and waste being mined today be accommodated simply by using bigger and better crushers? This paper updates the principal author’s earlier publication, “Crushing Plant Design and Layout Considerations” (SME Mineral Processing Plant Design, Practise, and Control, 2002). It reviews the latest primary crushing and large cone crusher designs. Its goal is to help consultants and operators select the optimal equipment and custom-designed items in the material handling flowsheet from the mine to the mill, maximizing operating hours per year.INTRODUCTIONAre larger crushers the answer to meeting the demands of existing or new mining projects for increased tonnage? The principal author’s previous paper in the year 2002 on ""Crushing Plant Design and Layout Considerations"" provided a detailed design and layout review for the design of primary and fine crushing (Secondary, Tertiary, Quaternary) mineral processing facilities. Some of the conclusions in this previous paper had predicted that larger crushers for primary and fine crushing would be beneficial and contribute to the further development of mineral processing. Larger crushers for primary and fine crushing applications are now available.The rock size reduction process, from the mine to the selected milling process facility has not changed since man first broke a rock to get at the interesting mineralization within. The rock size reduction process circuit from the mine to the mill can be summarized into four (4) stages:• Stage 1: Mining ( Rock Breakage and Fragmentation)• Stage 2: Pre-Screening (Scalping)• Stage 3: Primary Crushing• Stage 4: Fine Crushing (Secondary, Tertiary and Quaternary; the crushers used in this stage are identified by the titles which usage has conferred on them)Plant throughput and ore delivery schedule will form the basis for flowsheet design and equipment selection. Once a project's design criteria and the mine plan has been established, the actual circuit's utilization percentage (percentage of hours when the circuit is being utilized) can be optimized for each of the four stages. The mining and process departments are the key stake holders in the selection of the final comminution circuit and both departments should be familiar with and contribute to the design of the circuit."

Jan 1, 2016

By Richard D. Moffett

The MineSight® Implicit Modeler arms geologists, engineers and surveyors with a better approach to 3D modeling. Use the tool to quickly retrieve a 3D wireframe from drillhole data and onscreen interpretation. Generate faster and more informed decisions to guide future work and improve reproducibility of results. Implicit Modeling is a mathematical surface fitting method that interpolates points to give a smooth and realistic fit. Control results by mixing planar, sectional and non-orthogonal polygons or polylines, as well as drillhole information to create solids or surfaces. The outcomes are particularly valuable to identify ore body trends, generate 3D contours of drillhole intercepts, or produce cut-off 3D maps. MineSight Implicit Modeler (MSIM) is fully integrated in MineSight?s robust and versatile suite of products, allowing you to interpret, interpolate and calculate while moving between applications. It connects seamlessly with the MineSight Torque SQL database, offering access to extensive filtering options. MSIM makes modeling much faster, allowing geologists more time to analyze data and test theories. The presentation will reveal how MSIM complements MineSight?s geomodeling workflow.

May 1, 2013

By J. E. Hawley

Abstract Spectrographic methods for the analysis of minor constituents such as platinum-group metals, gold, silver, and silica in palladium and platinum refinery sponge are described. These involve the conversion of the sponge metals to the black form by reduction with high purity aluminum filings in either acid or alkaline media. Standards of known composition are prepared in the same manner from either refinery or spectrographically standardized sponge metals. Samples of the black metals are mounted in pellet form and a multisource spark discharge used for excitation. The range of concentrations of impurities studied are those common to refinery samples. Excellent reproducibility of intensity ratios using major constituents as internal standards, is demonstrated and two methods have noted by which the accuracy of the procedures are shown to be of the order of 3 per cent, on the basis of synthetic preparations. Introduction During the past two years an investigation has been carried out in the Spectrographic Laboratory, Queen's University, to determine the suitability of modern spectrographic techniques for the precise analysis of the platinum-group metals palladium, platinum, rhodium, iridium, and ruthenium in the form of refinery sponge analyzing about 99 per cent of the major constituent.

Jan 1, 1951

By T. T. Ni

FOR MORE THAN 200 years, the Kochiu district of Yunnan province has been, and it still is, the hub of China's tin industry. The district produces annually from 80 to 90 per cent of that country's out-put of tin, which averages about 9,300 tons a year and places China fifth among the tin producing nations of the world. The tin ore reserves of the country are estimated (1) at 1,873,370 metric tons, of which 1,500,000 tons are in the Kochiu district. The mill of the Yunnan Consolidated Tin Corporation, described in this paper, is the only one of its kind in China. MINING AND SMELTING There are only two tin mines in the Kochiu district operating with modern equipment -the Hsin-Chang and the Lao-Chang, both owned by the Yunnan Consolidated Tin Corporation, a government company. The Hsin-Chang mine has four working levels with cross-cuts 6 ft. by 6 ft. and is equipped with steel mine cars and trucks to haul the ore. The ore is hoisted to surface in a three-compartment shaft and transferred to the mill by a 4-kilometer aerial tram. The Lao-Chang mine has two circular shafts 656 feet apart, each equipped with two cages. Haulage-ways 1,600 meters and 1,000 meters long, respectively, have been driven to the southwest from these shafts and are connected by three cross-cuts.

Jan 1, 1951

By R. H. Duthie

As at any other mine in Canada, grade control procedures are used at Steep Rock Iron Mines (1) in order to ensure that concentrator and pellet-plant operator s have a uniform feed so that they can manufacture a pellet to suit buyers' specifications and (2) to maximize ore recovery so that as little as possible finds its way to the waste dump or is downgraded by contamination. At Steep Rock, material grading 40% to 66 % Fe is considered ore. The ore may contain up to 10% sulphur. These ranges create six different stock pile types, with the possibility of more if large concentrations of arsenic are encountered. Although grading and mining techniques used to accomplish these ends are fairly standard, there is an appreciation and willingness by hourly and staff pit personnel to make grade control effective. This produces vertical and horizontal communication, which is necessary for success in this field. At Steep Rock, the waste-to-ore ratio is greater than at any other iron ore mine in Canada. Also, a high percentage of the ore mined is direct pellet feed. For these reasons, .grade control is very important.

Jan 1, 1977

By A. J. Faulds, K. C. Westaway, Z. Waszczylo

"PAH compounds have been found in the exhaust from all types of engines burning hydrocarbon fuels . They have also been found in the air over cities and in water. The authors report on a study to assess the concentrations of twelve different PAH compounds in several different environments in dieselized underground mines. In addition, the differences in the PAH levels and distributions in different mines will be demonstrated. Finally, the influence of blasting and the type of diesel engine used as well as the effect of catalytic converters in the exhaust system on the PAH concentration in the mine will be discussed.IntroductionMining methods have been altered significantly in the last 25 years; i.e ., the tools and machinery used underground have changed from electrically operated trains and other equipment to diesel-powered equipment. This has been done for several reasons: 1) economics, 2) convenience and 3) safety. Today, most mines are heavily committed to using diesel equipment.Although the introduction of diesel equipment has revolutionized mining methods and has been a tremendous boon to the mining industry, it has also created new problems. These problems arise because the exhaust from diesel engines contains several pollutants which can be hazardous to the health of the miners. These pollutants are CO2, CO, NO., SO2, oxygenated hydrocarbons produced during the buring process and unburned hydrocarbons. There are two classes of hydrocarbons, of which polynuclear aromatic hydrocarbons (PAHs or PNAs) are a part."

Jan 1, 1981

By N. W. Hendry

ABSTRACT Exploration by geophysical methods and diamond drilling of an occurrence of chrysotile asbestos, located ten miles east of Matheson, Ontario, was commenced on March 25th, 1949, by the Canadian Johns-Manville Company, Limited. The asbestos is associated with a narrow sill-like body of basic and ultrabasic rocks which strikes northwesterly across portions of Munro and Beatty townships. To date, asbestos zones of commercial interest, many hundreds of feet in length, width, and depth, have been outlined by diamond drilling along a 2-mile length of serpentine. The fractures occupied by the asbestos veins are closely associated with the regional faulting in the area. The mining of the first occurrence, or A orebody, will be by open-pit methods. Milling will commence at a rate of 50 tons an hour. INTRODUCTION OCCURRENCES of chrysotile asbestos in Munro township have been known at least since 1914 and references to them appear in reports published by the Ontario Department of Mines in 1915 (1) and 1919 (2). J. G. Ross (3) in his excellent publication on Chrysotile Asbestos in Canada, mentions an occurrence in Munro township. The area was first mapped in detail by J. Satterly, of the Ontario Department of Mines, in 1944, and brief mention is made of chrysotile asbestos in Satterly's preliminary report (4), which was published the following year.

Jan 1, 1951

By J. B. Mawdsley

"AbstractThe uraninite-bearing deposits in the Charlebois Lake area of northeastern Saskatchewan are unusual and important concentrations of uranium. They were first discovered in 1949 and preliminary development work to the end of the 1951 field season indicates the probability that this will become •another uranium producing district. The deposits are in zones bordering granite masses. These zones are of migmatite (mixed rocks) composed of calcium-rich meta-sediments intruded and replaced by a fine-grained white pegmatite. Locally this pegmatite is replaced by an end fraction which is relatively rich in fine-grained disseminated uraninite; it is these occurrences that constitute the bodies of economic interest.The fine-grained white pegmatite contains plagioclase feldspar more lime-rich than that in the granites of which it is an end differentiate. This extra lime, evidently derived from the intruded sediments, would result in the raising of the temperature of crystallization of the pegmatite-forming magma, thus consolidating it rapidly near the granite contacts as a fine-grained pegmatite. The end liquor containing uranium was evidently locally concentrated in minor fracture zones in these pegmatites. Where no lime sediments were present. the coarse-grained alkaline pegmatites were formed. Their crystallization would not be accelerated and the uranium would tend not to be localized in the pegmatite but to migrate and consolidate at lower temperatures with the end products, possibly in some instances as pitchblende veins."

Jan 1, 1952

By Rodney A. Cooper

The Mary River iron ore deposits were discovered in the 1960?s. The high quality of the deposits was immediately evident, and drilling programs were successful in defining a resource adequate for supporting a feasibility study. Through a combination of ownership, market and political forces, the deposits were not developed. Having missed the window of opportunity, the project remained dormant for over three decades. Baffinland Iron Mines Corporation, with its 100% ownership of the Mary River deposits, began trading publicly in 2004. Modern exploration and metallurgical test work began in 2004 and has continued in 2005 and 2006, resulting in total expenditures during this period of almost C$60 million. In May 2006, an engineering team lead by Aker Kvaerner E&C, a division of Aker Kvaerner Canada Inc., completed a scoping study based on the first of five identified deposits. Highlights of that study include direct shipping of high quality lump ore to Europe over a 34 year mine life at a production rate of 10 million tonnes per annum, based on an indicated resource of 309 million tonnes at 66.1% Fe and an inferred resource of 28 million tonnes at 65.9% Fe. Capital costs were estimated at C$1.5 billion. Using iron ore prices approximately 36% below that of the 2006 market, a pre-tax internal rate of return of 15% was estimated assuming equity financing. Payback on initial capital was 5.9 years. The pre-tax life-of-mine cash flow was estimated to be C$6.3 billion. As a result of this study, Baffinland initiated a Definitive Feasibility Study, under the management of Aker Kvaerner, which is scheduled for completion in December 2007. This paper touches on the geology of the deposits, the current resource and the outlook for expansion. Project permitting, construction planning, logistical challenges and ocean shipping considerations are discussed, providing a current perspective on the project scale, scope and timeline for commercial production. In addition, an overview of the Company?s bulk sampling program will be provided.

May 1, 2007

By J. J. Denny

IN a preliminary paper (1) it was shown that the addition of small quantities of metallic aluminium powder almost completely inhibited the solubility of siliceous material in the beaker. Six rabbits exposed to quartz dust for six months all showed well developed silicosis. Seven rabbits exposed to quartz dust plus 1 per cent metallic aluminium powder for the same period did not develop silicosis. At that time, we were not in a position to state either the manner in which metallic aluminium reduced the solubility of siliceous material, or, from the animal experiments, whether the aluminium was acting locally or systemically, or for what period after the cessation of dusting it would continue to act. This paper reports the further progress of this investigation. CHEMICAL EXPERIMENTATION The technical details pertaining to the various substances used in the experiments are given in an appendix which is on deposit with the American Documentation Institute, Washington, D.C. For lack of space, it is not printed here. The term 'solubility' is used to indicate the concentration of silica in the solution under the conditions as noted, determined colorimetrically (2), and expressed as parts per million (p.p.m.). The term 'reduction in solubility' indicates the difference between the solubility of the .silica in the presence of the aluminium powder and its solubility in the absence of aluminium powder. It will be noted that the solubility figures for different samples of quartz with no added aluminium vary considerably. The figures do not refer to an equilibrium solubility of silica but to the actual amount of silica dissolved from a given sample in a given time at a given temperature. In view of the fact that quartz dissolves extremely slowly, it is evident that the actual figures in any case will depend upon the surface exposed, i.e., fineness of grinding of the different samples.

Jan 1, 1939

By M. F. Goudge

Introduction It is only fitting on this occasion of the fiftieth anniversary of the incorporation of the Institute that we should indulge in a bit of retrospection and review the progress that has been made within this period in the various branches of the mining industry- progress that is so closely associated with the members of this Institute. Such a moment of retrospection will enable us better to appreciate the present status of the industry and to perceive more clearly the trends that should guide us in making sound plans for the future. The past half century has been a period of amazing industrial progress in Canada. In this period, the economy of our country has changed from one based chiefly on agriculture and the export of raw materials, to an economy based largely on a well integrated manufacturing industry. In all' o( these major developments, industrial minerals have played an important part and will play an increasingly, important part in the future. By ?industrial minerals? we mean the various non-metallic minerals (exclusive of fuels) as well as the rocks, sands, and clays used for industrial purposes. They are now used so widely and in such large quantities that modern industry could not function without them, and their continued availability at low cost is vital to the industrial future of Canada. The key position occupied by industrial minerals in modern Canadian industry was well illustrated two years ago when a strike occurred in the only Canadian plant producing soda-ash and calcium chloride at a time when those materials were already in short supply and unavailable from other sources. Within a short time of the shutdown of this plant, in which the two principal raw materials are limestone and salt, the great aluminium reduction plants on the Saguenay river were forced to curtail operations because of the lack of soda-ash, essential to the process of extracting aluminium from its ore. Automobile production, already harassed by a shortage of steel, was further hampered when glass for windshields and windows could not be supplied because the glass industry was slowed down almost to a standstill for want of soda-ash. Soap became almost unobtainable both to the housewife and to industrial users, because soda-ash is required in its manufacture. As a consequence of the soap shortage, the production o synthetic rubber at Sarnia was threatened because soap in large quantities is essential to the polymerization process. Motorists on gravelled highways all over Eastern Canada drove through clouds of dust because calcium chloride, used for dust laying, was not to be had. There were other cases of dislocation of industry related to the shutdown of this particular plant, but the above illustrates the wide ramifications of industrial minerals in modern industry. However, it is extremely doubtful if many Canadian citizens realized that these apparently unrelated happenings were connected in any way with limestone and salt.

Jan 1, 1948

By S M. Roscoe

Relationships of Noranda sulphide deposits to volcanic rocks are reviewed and chemical variations within the volcanic sequence are described. The assemblages of minor elements in the pyrites and pyrrhotites of the Noranda and l\llatagami deposits are similar and are characterized by a high content of cobalt, tin and other elements. Isotopic compositions of lead, other geochronological data and stratigraphically disposed zonal distributions of sulphides and minor elements indicate that the deposits were formed prior to folding and metamorphism. Lead isotope data indicate that the Matagami deposits, and several others, were probably formed about 2.95 x 109 years ago and that the Noranda deposits may be about 50 million years younger. The volcanic sequence at Noranda is younger than the thick sequences bordering it on the east and on the west. The relationships are consistent with the hypothesis that these strata-bound sul1>hide de-posits are coeval with their associated volcanic rocks. T HE writer has been engaged in a metallogenic study of the region between Sault Ste. Marie and Chibougamau. An essential objective of this study is the classification of mineral deposits with regard to their composition, form, geological

Jan 1, 1965

By M. D. Lawton, P. Steen

"Drilling results from the established levels at AngloRouyn Mines Limited had indicated inadequate tonnages to meet the planning schedule. It was decided to develop the main zone of the orebody below the bottom working level of the mine. The orebody dips north at an average of 50 degrees and plunges to the west at about 10 degrees. Due to the need for rapid development of this area, a decision was made to use trackless equipment.This paper describes the method used and highlights the use of small 5-ton diesel trucks as carriers for the 2-cu.yd LHD machine. The method achieved advances of about 1,000 feet per month, at a dip of 12 degrees over a length of close to 2,000 feet, using as few as 20 men per day."

Jan 1, 1971

By T. W. Wlodek, Zygmunt Kowalczyk

In the period from 1946 to 1964, the annual output of co al from Polish mines increased from 4 7.3 to 117.35 million tons. In this paper, the methods of bringing about this increase in productivity through the building of some twelve new collieries (producing some 15 million tons annually) and the modernization, reconstruction and extension of some thirty-six older collieries are discussed.

Jan 1, 1967

By James S. Redpath

"AbstractThis paper is an attempt. to outline the present status of underground mining contracting in Canada, and to present certain facts concerning the writing and administration of underground mining contracts which, hopefully, may be useful to those intending to engage a mining contractor . The paper is based on the author' s experience as a contractor and also as a consulting engineer advising others in the purchase of contractors' services.HistoryIN THE early days of mining contracting in Canada, the contractor was primarily a labour contractor. He was expected to bring a good crew of men that normally followed him, and to perform certain work under his own direct supervision. The owner usually looked after all other details including financing, payrolls, withholding taxes, etc , computing and paying the contractor his profit. In the pre-World-War II years, most work was done on this basis.Over the years, the contractor was called on to supply more in the way of services, and the present-day situation evolved.Labour contracts are still used, but now the contractor is expected to carry out his own administration. Most contracts now call for the supply of special tooling required to do the work. In most cases, some, if not all, supplies are the contractor 's responsibility and , in a growing number of cases, the contractor is responsible for such items as design and surveying. The ultimate in this direction is the execution of projects on a turnkey basis. Under this system , the contractor carries the project to a stage where it is turned over fully operational to the owner."

Jan 1, 1977

By Matthew D. Meyer

SMART, an association of surface mining companies formed in 1995 to develop a coordinated approach to technology development for the mining industry, has recognized the need for the establishment of a worldwide database that continuously collects mining equipment data and provides metrics related to productivity and cost. Under the auspices of SMART, Syncrude Canada, Suncor Energy and Albian Sands Energy (three oil sands mining operations located in northern Alberta) have established a pilot project for mine benchmarking. This presentation will include a review of the pilot progress including: ???Data gathering techniques: means of collection and storage, proposed practice for data control and normalization, access to data/reports and format for data. ???Reports/analyses for individuals, across groups, within the total industry pool and publicly. ???Security and confidentiality of information belonging to identified parties. ???Sharing of best practices among members. SMART has identified two key deliverables to ensure success of the project. First, data supplied from surface mines must be validated and normalized to common definitions and then analyzed to provide participating companies with regular reports that allow them to understand their position and resultant opportunities to achieve world-class performance. This model maintains granularity of the data for each operation that can then be recombined into standard comparisons or specific indices as required. The general categories of: operating delays, maintenance downtime, standby, and scheduled downtime, have been used to frame comparisons. Second, participating companies are looking to go behind the indices to identify and share best practices that distinguish particular operations. The spirit of cooperation between the companies involved in the pilot project is meant to be a model for future expansion of the benchmarking project.

Apr 1, 2005

Of the many organic impurities present in Bayer liquor, sodium oxalate is known to have one of the most detrimental effects on the Bayer process. Because of its limited solubility, it will co-precipitate with gibbsite during the precipitation stage which results in many operational challenges for the refinery. Despite the importance of this phenomenon, the interaction mechanism between gibbsite and sodium oxalate is not well understood. In this study, the growth of sodium oxalate on three main morphologies (random agglomerates, prims and hexagons) of water-washed and caustic-washed gibbsite was observed under synthetic Bayer conditions using in situ optical microscopy. After a short induction period, oxalate started to nucleate on gibbsite crystals, and grew with a needle-shaped morphology which eventually developed into oxalate bundles. In addition, the results indicated that caustic washing was able to partly decompose gibbsite crystals and thus make the gibbsite surface rougher, which provides more potential sites for oxalate nucleation and growth. The growth rate of oxalate crystals on the basal (001) face of water-washed gibbsite was 1.33 µm/min determined by the time-lapse imaging of in situ optical microscope.

Jan 1, 2014