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During the first five years of operation, the Lihir gold mine has steadily increased plant throughput rate to over 4 Mtpa, well above the original design capacity of 2.8 Mtpa. Understanding how future variations in ore type impact on plant performance has been an integral part of LihirÆs development program. This paper discusses the key drivers for significant improvements to the plant, including a second oxygen plant, a pilot flotation plant, an autoclave heat recovery circuit, a pebble crushing circuit and additional autoclave feed pumping capacity. The result is a process plant with the flexibility to accommodate variations in ore type without significant loss of throughput.

Jan 1, 2003

By Blair J. R, Barrett J. R

In many underground mining applications where-dry fill is used, only a token acknowl- edgement of the fill properties is given. It is the aim of this paper to induce mining engineers to consider dry fill as an engineer- ing material rather than a mass to place in unwanted voids. Dry fill is generally cheap, inert and readily available, but it can still contribute to mining performance. In particular, the choice of the dry fill becomes more critical as stope sizes increase, controlled choked draws are used or pillar recovery introduced. Selection must be initiated from an evaluation of the role of the fill in the mining operation. In most cases the fill must be chosen before quarrying begins and an investigation must be made of available sources and appropriate quarrying methods. Some of the properties of fill are described together with evaluation techniques. A com- parison of placement conditions is limited by the complexities of material flow and degrada- tion: However, field and model tests can aid interpretation in these cases. Examples are given of aspects of dry fill selection and their incorporation in mining design.

Jan 1, 1973

By S Porter

The Melbourne City Link Project is a privately funded road infrastructure project linking three significant existing freeways in the vicinity of the Central Business District. The State Government, through the Melbourne City Link Authority, has contracted Transurban to build, own and operate City Link for a concession period of 34 years before the road network is transferred to the State. Transurban has a contract with Transfield Obayashi Joint Venture (TOJV) to design and construct the works. The project is divided into the southern and western sections and the tunnel works comprised the significant component of the Southern Link. Outside of the cut and cover tunnels at the portals, the driven tunnels component was constructed by TOJV direct labour. TOJV subcontracted all design work to a joint venture of Hyder Consulting and CMPS&F (Hyder/CMP). The geology in the tunnel corridor and generally below the city of Melbourne is highly variable and constantly changing. The tunnels were driven, for the most part, in siltstone and sandstone of the Silurian age, but also intersected overlying basalts and clays. The Silurian bedrock is a fractured aquifer that is connected to overlying alluvial aquifers. Consequently, the construction of the tunnels was a complex engineering task. This paper details the operational relationships and procedures developed to deliver a design that was aligned to the construction constraints and delivered an end product that met all technical, quality, cost and program goals.

Jan 1, 1999

By J Lombardi

OZ Minerals' Prominent Hill copper-gold concentrator is located 130 kilometres south east of the town of Coober Pedy in the Gawler Craton of South Australia. The concentrator was built in 2008 and commenced commercial production in early 2009. The Prominent Hill concentrator is comprised of a conventional grinding and flotation processing plant with a 9.6Mtpa ore throughput capacity. The flotation circuit includes six rougher cells, an IsaMill for regrinding the rougher concentrate and a Jameson cell heading up the three stage conventional cell cleaner circuit. In total there are four level controllers in the rougher train and ten level controllers in the cleaning circuit for eighteen cells.Generic proportional – integral and derivative (PID) control used on the level controllers alone propagated any disturbances downstream in the circuit that were generated from the grinding circuit, hoppers, between cells and interconnected banks of cells, having a negative impact on plant performance. To better control such disturbances, FloatStar level stabiliser was selected for installation on the flotation circuit to account for the interaction between the cells. Multivariable control was also installed on the five concentrate hoppers to maintain consistent feed to the cells and to the IsaMill. An additional area identified for optimisation in the flotation circuit was the mass pull rate from the rougher cells. FloatStar flow optimiser was selected to be installed subsequent to the FloatStar level stabiliser. This allowed for a unified, consistent and optimal approach to running the rougher circuit. This paper describes the improvement in the stabilisation of the circuit achieved by the FloatStar level stabiliser by using the interaction matrix between cell level controllers and the results and benefits of implementing the FloatStar flow optimiser on the rougher train.

Aug 8, 2011

By A C. Robertson

World urban expansion puts constraints on the available land surface area of our major cities both for accommodating people as well as providing infrastructure and services whilst at the same time attempting to preserve the remaining natural environment. Whilst consideration is often given to underground planning for private and public transport infrastructure, the author is of the opinion that the current lack of underground planning of our cities that are suitable for underground development will have major long implications when finally the need for underground space planning is critical and ultimately recognised. This paper identifies the need for our city planners to integrate surface planning and underground planning as a ‘total planning solution’ where the city plan incorporates the elements of underground space planning as identified in this paper. Investigations by the author reveal that there are very few cities in the world that actually incorporate underground space planning in their city plans. The author uses the City of Brisbane as a case study for the potential introduction of underground space planning as part of the city plan. Despite efforts by the author to include the planning concept of underground commercial development in the latest Brisbane City Plan 2014 as well as four underground space workshops in Brisbane over the past 20 year through the Australasian Tunnelling Society (ATS), underground space planning for the City of Brisbane, apart from infrastructure projects, is not considered of significance to the City of Brisbane.CITATION:Robertson, A C, 2014. Commercial underground space – planned development for the future, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 513–518 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By A E. Annels, M D. Raine, I M. Platten

Lode-gold systems are often characterised by a high to extreme nugget effect (>50 per cent), and the presence of coarse gold particles (>100 ¦m in size). They rank amongst the most difficult of ore deposits types, in terms of producing an accurate and precise resource estimate. Their effective sampling is generally difficult because of the relatively low concentrations involved and erratic nature of the gold particles. Grade continuity is usually less consistent than gross geological continuity, and is typified by the localisation of grades within discrete oreshoots. In most cases drilling, particularly diamond drilling is an effective measure of global geological continuity, whereas grade can only be reliably resolved from underground development. Depending upon drill density and geology, it is unlikely that anything above an Inferred Mineral Resource can be estimated from surface drilling alone. Underground development, in-fill drilling and, potentially, bulk sampling or trial mining will be required to delineate Indicated and Measured Mineral Resources and subsequent Ore Reserves. Grade estimation will have to account for highly skewed and often multi-modal populations, extreme values, a high nugget effect and low geostatistical ranges. A clear geological model that honours both geological and grade continuity must drive the resource estimation process.

Jan 1, 2003

By L Terrusi

The Bungaroo Valley hosts a concealed Tertiary channel iron deposit (CID) along a 17 km stretch of its length. Bungaroo Valley is approximately 0.5 km wide upstream at its easternmost extent, and 3.5 km wide downstream where it joins the Jimmawarrada Creek. The valley follows the axial trace of an anticline that plunges gently to the southeast, and the CID infills the valley. Mineralisation extends to a depth of 230 m below the surface, and almost the entire deposit occurs below the water table. Bungaroo Valley cuts through the Buckland Hills and is bounded to the north and south by steep scarps capped with the resistant Dales Gorge Member of the Brockman Iron Formation. Basement rocks are believed to be mostly Wittenoom Formation shales and dolomites, with Mount McRae Shale and Mount Sylvia Formation also present. Deep, localised depressions appear at the base of the CID sequence towards the north edge of the upstream section of the valley, while downstream the basal CID contact is relatively flat and shallow. In both cases the profile of the CID surface closely mirrors that of the basal contact. The localised depressions seen in the upstream basal CID contact produce significant variations in CID thickness of up to 100 m over short strike distances. This uneven palaeotopography is most likely due to eddying and waterfalls forming within the riverbed prior to CID deposition during a time when the water table was much lower than at present. It may also be associated with possible karsting in an underlying dolomite unit and subsequent syn- or post-depositional collapse of the overlying CID. The irregular basal contact of the Bungaroo CID sequence has implications for mining in terms of pit design and resource accessibility.

Jan 1, 2007

By D Connelly

Quartz deposits are common in nature but the presence of quartz suitable for yielding high purity quartz is exceedingly rare. This paper describes a test work study on producing high purity quartz (HPQ) product to meet the tight product specifications of greater than 99.97per cent, including four and even five nines, for uses including, lighting and fibre optics and modern-day high efficiency solar panels. Due to demand in renewable energy applications the market for high purity silica solar panels known for their increasing efficiency and durability is rapidly growing. Demand continues to rise for the use of high purity quartz in semiconductors, electronics, imaging and sensor markets. Microelectronic components are created by chemically fabricating wafers of semiconductors such as silicon to obtain the desired transport of electrical charge and control of the current. The production of silicon metal from high purity quartz has been designated a Strategic Mineral by the European Commission and by the US Department of Justice due to the growing significance of this metal in various industries. The subsequent processing of quartz is the key step to adding value and aiding technological advances. Overall, the high purity quartz market is a highly secretive, specialised market with increasing opportunities for stakeholders. The attempt to produce HPQ in this work was carried out using an Australian quartz ore following a typical HPQ process flow sheet. The unit processes included primary crushing, scrubbing, magnetic separation, flotation, acid leaching followed by hot chlorination. The results indicate that grinding of quartz requires specialist equipment due to the hardness and extreme abrasiveness of the ore leading to additional iron contamination in the ground ore. The critical impurities were aluminium, iron, sodium, potassium, lithium, titanium, zircon, calcium and magnesium. The chemical refining was found effective. The hot chlorination process needed to be done at 1200°C in a chlorine – hydrogen chloride gas atmosphere. The risk of any gas being released during this stage is very serious and only specialist companies should and can carry out this step. More recent studies reported many new options that appear to facilitate the production of HPQ with the requisite purities more easily, but costly equipment along with highly trained operators are required and hence unlikely to become available in standard metallurgical laboratories any time soon.

Sep 1, 2024

By M K. C Roberts, M G. Magwaza, J W. L Hanekom, P Piper, R Lousteau

Due to the perceived potential to extract the second economic manganese seam at its Black Rock Operations in the Northern Cape Province, South Africa, Assmang commissioned an investigation with respect to mining method and sequencing of the two orebodies in 2007. Based on this initial study into multiseam potential, conditions and impacts, the rock engineering aspect was expanded to determine conceptual rules to govern the extraction of both manganese seams using the normal bord-and-pillar layout implemented at this operation. This work included the theoretical analysis using basic pillar design practices and numerical modelling, including the use of Map3D, UDEC and Phase2 codes.In 2013, Assmang launched a large-scale investigation into the potential to increase mine output from all possible manganese sources at the operation. Included in this investigation was the requirement to confirm or modify the conceptual multiseam extraction rules to implementation. As part of this confirmation process, stress measurements, borehole camera audits and additional numerical modelling were performed at a particular site on the operation where a limited extraction of both seams had been undertaken. The results obtained from this process provided confidence in the conceptual extraction rules and allowed the derivation of final extraction rules that will be implemented at the operation as the multiseam mining process becomes more widespread.CITATION:Hanekom, J W L, Roberts, M K C, Magwaza, M G, Lousteau, R and Piper, P, 2014. Confirmation of multiseam extraction rules for Black Rock Manganese Operations, Assmang, Northern Cape, South Africa, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 107–116 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

The Pilbara region, located in the north-west of Western Australia, is significant as the second-largest source of iron ore on the planet. Iron ore mines owned and operated by Pilbara Iron are located within the Hamersley Basin. This paper refers to the Greater Paraburdoo mines, the 4WEST and 4EAST pits, located on the southern margin of the Hamersley Basin. The groundwater model refers to ephemeral watercourses: Seven Mile and Pirraburdoo creeks, which are adjacent to the two pits, and Ratty Springs, located upstream from 4WEST and within Pirraburdoo creek. The spring and creeks hold cultural heritage significance for local Aboriginal communities. Two of these, the Gobawarrah Minduarra Yinhawanga (GMY) and Innawonga native title claim groups, initiated hydrological work on the two creeks and Ratty Springs, with the aim of determining the affects of dewatering on the natural water flows of these systems. The numerical model used to simulate drawdown in the Pirraburdoo and Seven Mile Creeks was derived from PMWIN Pro software and covered an area of 77 km2. The modelling period was from January 1998 to December 2004, and the prediction period was from January 2005 to December 2015. The model has four layers and incorporated effects caused by mining voids, 4WEST and 4EAST pits, creek bed material, weathered bedrock below creeks and surrounding banded iron formations (BIF). The model has been calibrated using the trial-and-error method set down by Middelmis et al (2001). The current dewatering schedule (12 ML/day) in the 4WEST and 4EAST mining areas does not affect the water table levels in the adjacent creeks significantly or for any considerable periods of time. However, changes to mine plans may occur, for example, in response to changed commodity price and may lead to significant increase in rates of vertical advancement. This, in turn, affects dewatering schedules, as greater vertical advancement requires increased dewatering effort. When an accelerated mine plan is applied to the model and dewatering rates increased to 18 ML/day, drawdowns in the creeks are more noticeable. The model has therefore helped to indicate the extent to which increased dewatering rates may be acceptable, especially in terms of immediate and longer-term damage to riparian species, ie Melaleuca and Eucalypt. Predictions from the model may also allow mine planners to schedule decreased rates of vertical advancement, where these are required to meet environmental constraints.

Jan 1, 2006

The difficulty in creating and obtaining a competitive edge in the mineral industry is rapidly increasing. The Kiruna Iron Ore Mine in the far north of Sweden is currently thriving on the world market through firm managerial strategy. LKAB believes in upgrading its raw material to produce a high quality iron ore product for sale to steelworks throughout the world. It is vital that this product is also of uniform quality and quantity to provide quality assurance to customers. The first link in meeting these product requirements starts in the underground workings. Mining methods and operations are of large-scale. Automation and continuous production streamline operations and reduce operating costs. These factors have built Kiruna Iron Ore Mine into the world's biggest, most modern, underground iron ore mine. To remain competitive on the world market, LKAB relies heavily on research and development. The mine is currently in a phase of upgrading its operations. A 25-tonne Toro electric loader is being tested to improve the rate of output of ore from the mine. Long hole drills are being improved to increase accuracy and efficiency. An electronic detonating system will improve detonator delay precision. Projects are underway to better understand ore flow mechanisms from a caving orebody. Benefits include improved ore recovery along with better rock quality control at the caving front. The continued updating of mining operations at Kiruna will enable LKAB to continue to maintain its competitive advantage on the world market in the production of high quality iron ore products.

Jan 1, 1997

The Emmaville district is located in the northern part of the New England region of New South Wales some 400 miles north of Sypney. Better known for its substantial production of tin and tungsten ores, the Emmaville district has also been the centre of a small and somewhat sporadic production of copper, arsenic, silver, lead and zinc. This production has come principally from three mines-Webb's Silver Mine, Webb's Consols and, to a lesser extent, Pye's Creek Silver Mine.The ores from these mixed sulphide deposits are texturally and mineralogically complex and the problems of beneficiation are rather formidable.GENERAL GEOLOGYThe main rock type of the Emmanville district is a dark, brown to blackish massive siltstone of Permian age which overlies acid volcanics possibly also of Permian age. In places the siltstone gives way to conglomerates and standstones with discontinuous lenses of calcareous sediments (David, 1887).The whole series is folded but because of the massive character of the more expansive siltstone, detailed structure is difficult to delineate.Toward the close of Permian time the area was intruded by a series of intermediate to acid plutonic and hypabyssal rocks. Mineralization within the region is ascribed to the more acid of these intrusives-granodiorite, granite, and quartz-felspar porphyry (Lawrence, 1957, 1960).No intrusive rocks outcrop in the immediate neighbourhood of Webb's Silver Mine though granite occurs two miles...

Jan 1, 1961

The underground mining of a narrow vein hard rock orebody is a capital and labour intensive method of extraction. Due to the nature of underground mining it is difficult for higher level managers to physically see the efficiencies and inefficiencies of a particular method. Extraction methods and sequencing often need to be altered from the original planned methods as a result of mine developent, providing more in depth information as it progresses. As a result of these issues contract mining of these orebodies is common practice. There are several types of contract structures for the purpose of underground contract mining with many complex permutations of them that reflect the different needs of each individual company and orebody. The different contracts are arranged dependent on the mining companyÆs desire to transfer or, alternatively, embrace risk. This presentation gives a brief overview on these different methods and their various advantages and limitations with regard to small scale and narrow vein underground mining. With respect to these different contracting methods, the presenter reviews the mutual growth benefits of emerging partnering opportunities, specifically with regard to smaller explorers exploring and developing prospective mining tenements. The specific advantages to small explorers include the resource flexibility and speed of project development that private mining contractors can provide. Given the contracting methods that are available, there is potential for small private mining companies to gain minor stakes in major projects and major stakes in medium sized projects by employing innovative contracting solutions to provide mutual benefits to the parties. Some potential scenarios to this effect are suggested in the presentation. This paper is available as a PowerPoint presentation only.

Jan 1, 2006

Digital computers, by virtue of their capacity for high speed repetitive calculation at low cost, are finding increasing application to routine calcula- tions in the mining industry. In this paper techniques are shown whereby the use of computers can be extended to more complex tasks. The regular calculation of grades and tonnages of material to be extracted from specified areas of an operating open pit is a necessary part of production planning. In this paper it is shown how these calculations can be carried out by computer. thereby freeing planning staff from manual calculation. An operating open-pit mine can be described in terms of drill logs, geological ore boundaries and pit perimeters at various levels. These form the data base which must be suitable for frequent updating to incorporate new information. A suite of computer programmes is described which operates on this data base to calculate tonnages and grades of ore within extensions to the perimeters as indicated to the system by planning staff. Possible future extensions are discussed.

Jan 1, 1971

By D McLaughlin

This paper points to the timely importance of commencing a centrally recognised perpetual collection of mineral specimens in the Northern Territory which has as one of its objectives the collection and preservation of Northern Territory minerals of scientific, educational and heritage value. Currently in the Northern Territory there is no government department or institution that has a resourced coordinated state-wide objective to collect and document collectable mineral specimens. Specimens held in storage by the Department of Mines and Energy and the Museum and Art Galleries of the NT are not catalogued and owe their existence to fortuitous circumstances, not as a result of a planned systematic scientific approach to mineralogy. Northern Territory mineral species and unique specimens have and will continue to be driven to extinction while no central and active, recognised repository exists. This situation persists despite the fact mineral production is the Territory's largest income earner. The paper presents the arguments that hopefully will assist decision-makers to commence development of a state mineral collection lodged within an appropriate institution in the Northern Territory.

Jan 1, 1994

By L Scheunis, A Van den Bulck, E Jak, K Verbeken, M Shevchenko, R Starykh, I Bellemans, P-J Boeykens

As a result of the globally increasing consumer use of electronic devices, it is expected that pressure will increase on the supply chain of precious metals. Hence, recycling of these electronics becomes increasingly important, as well as optimising the current processes. One major issue in metallurgical processes is the amount of metal that is lost into the slag. This metal loss is inherent to the production process and therefore, additional processing steps such as slag cleaning may be required. Slag cleaning can be done in electrical resistance furnaces where heat is produced using the Joule effect, making the slag’s electrical conductivity an important operating parameter. Since slags are ionic liquids, the electrical conduction happens via the movement of ions which is called ionic conductivity. However, within the presence of transition metal oxides, a second mechanism of conductivity occurs as electrons are able to hop from one transition state to another, which is known as electronic conductivity. As ‘FeO’ is a common slag component in the non-ferrous pyrometallurgical industry, both mechanisms are present, but their proportions vary with the respective amounts of the two forms of the multi-valent ions and hence, with the oxygen partial pressure. The goal of the present study is to develop an experimental set-up and methodology for measuring the electrical conductivity of synthetic SiO2 – CaO – AlO1.5 – ‘FeO’ slags at various oxygen partial pressures.

Jun 19, 2024

By A M. Ebbels, D Pratt

The current commodities super-cycle has seen an explosion in the number of mining projects demanding human resources throughout the world. The demand for key personnel currently far outweighs the international talent pool and will take several years to subside. A highly effective project team can be the difference between a successful project and a bad public relations exercise. Building an effective team and retaining the team members has become one of the major influencing factors for successful project development in the mining industry in the last decade.Increasingly, international teams are being established combining skill sets, subject matter experts, unique previous experiences and diverse cultures to deliver mining projects all around the world.This paper explores the characteristics of a highly effective team, the communication and geographic challenges and some potential pitfalls which influence the ability to form effective teams within the mining industry.CITATION:Ebbels, A M and Pratt, D, 2012. A great project team - Bringing together location and culture, in Proceedings Project Evaluation 2012 , pp 197-202 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 24, 2012

By Roe P, Lowell A

This paper outlines software development and design work carried out by Mincom Pty Ltd in collaboration with Capricorn Coal Management (CAPCOAL) for computer based design of rehabilitated strip mine landforms at German Creek Mine. Current developments and future application areas for this software are also discussed in relation to other mines in Central Queensland. The development program was initiated in response to statutory requirements placed on mining companies in 1990 to produce a five year Plan of Operations which was to include a contour plan of the final rehabilitated mine landform at the end of the five year planning period. This plan was to be submitted to the Department of Resource Industries (DRI) by 1 December 1990. Due to the limited time given to prepare the plan, a work program was formulated in collaboration with Mincom Pty Ltd to develop suitable software to carry out the design work and provide the required plans and quantities. The software had to include computer based methods to allow design of the proposed landform in line with the rehabilitation strategy adopted by CAPCOAL at the time.

Jan 1, 1991

By G Gibson, B Bessen

In coal preparation, large dense medium cyclones (DMC) at low pressure heads (typically 9D where D = cyclone diameter) are the norm. This contrasts with high density mineral applications where, largely for historical reasons, smaller cyclones at high heads are the standard. There are advantages in preferring large diameter cyclones at low heads, assuming that metallurgical performance does not suffer significantly. These include simpler plant layouts, easier maintenance, smaller spares inventories, reduced wear, reduced medium pumping demands, smaller buildings and overall lower capital and operating costs. In 2008, therefore, Xstrata Zinc decided to trial a single DSM-design 800 mm cyclone in one of its four DMC lines at Mt Isa, replacing the four 400 mm cyclones previously installed. Circumstances allowed a low head of 9.5 D to be trialled, compared with the existing 400 mm head of 21.5 D. This paper describes the trial, including tests using painted ore particles as tracers, estimates of yield and metal recovery, and wear monitoring. The larger unit performed well. There was no evidence that metallurgical performance in terms of metal recovery and waste reject rate suffered, and there was some evidence that it may have improved. Cyclone life increased, and preliminary data suggest that the replacement cost of the 800 mm cyclones is less than half that of the 400 mm units, and this is expected to improve. The plant layout and operability have also improved significantly. Xstrata has therefore decided to convert the whole plant to four low head 800 mm units, replacing the original 16 high head 400 mm units. The paper includes an explanation of the effect of static head on DMC separating force. It also reviews earlier research on diamond applications, and applies a general DMC process model to the Xstrata case, both of which confirm that large, low head cyclones are appropriate in mineral applications, contrary to conventional practice. Such units could significantly reduce both the capital and operating costs of DMC plants in mineral applications.

Jan 1, 2009

By C Zschiesche, alam, A Abadias Llamas, A K

An integrated experimental and thermodynamic modelling study of the phase equilibria in the FeOFeO1.5- SbO1.5-SiO2 system in equilibrium with liquid Sb and Sb-Ag metal has been undertaken to develop thermodynamic model of the Na-Si-Fe-O slag system with S-Sn-Sb-Pb-As minor elements based on the experimental investigation of the selected sub-systems. New experimental phase equilibria data at 575–1600°C were obtained for this system using high-temperature equilibration of synthetic mixtures with predetermined compositions in sealed silica ampoules, Fe3O4 basket in sealed silica ampoule, or Re foils, a rapid quenching technique, and electron probe X-ray microanalysis of the equilibrated phase compositions. Experimental results on phase equilibria in the Fe-Sb-Si-O+Sb metal system obtained helped to produce initial set of model parameters in the slag. The primary phase fields of quartz/tridymite/cristobalite (SiO2), 2 high-SiO2 immiscible liquids, olivine (Fe2SiO4), wustite (FeO1+x), spinel (Fe3O4), schafarzikite (FeSb2O4) and valentinite/ senarmontite (Sb2O3) were identified in the binary Sb2O3-FeO, Sb2O3-SiO2 and ternary FeO-Sb2O3- SiO2 systems. Further refinement, particularly the distribution of excess Gibbs energy among the ‘FeO’-Sb2O3-SiO2 and ‘FeO1.5’-Sb2O3-SiO2 interactions, required the study at more oxidising conditions. Oxygen potential was increased using an inert metal (Ag) rather than using the gas flow due to the high volatility of Sb-containing gaseous species. Liquid Ag-Sb alloys with low concentrations of Sb of a few percent were used. At these conditions, the concentration of AgO0.5 in slag was below 1 mol per cent, which had a small effect on observed phase equilibria in the system. In addition, important information on the solubility of silver in slags is produced, which can be valuable when treating electronic recycling materials or primary silver-containing ores through the Pb process. Two main areas were addressed: the spinel-tridymite boundary (40–70 per cent SiO2 in slag) and spinel liquidus near 15 per cent SiO2 in slag. This allowed to deconvolute the separate contributions of the FeO-Sb2O3(-SiO2) and Fe2O3-Sb2O3(-SiO2) systems.

Jun 17, 2024