Search Documents

By Upfold RW, Velzeboer MD

An underground mine fire will influence the ventilation equilibrium in several ways which results in a redistribution of the ventilating quantities and pressures throughout the whole mine. The ventilation carries the combustion products which constitute the greatest danger of mine fires through the mine and provides the oxygen on which the intensity of the fire depends. However, as a result of the ventilat- ion disturbances created by the fire, changes in airflow patterns can take place which are not always obvious, especially when the mine is being served by several fans. The use of com- puter simulation techniques allow for the likely effects to be tested and the different ventilation options to be evaluated as an integral part of the overall emergency/rescue planning and control procedures.

Jan 1, 1981

By P Dare-Bryan

Many mines have an interest in improving fragmentation at their sublevel caving operations in order to produce better ore recovery, lower dilution and less overbreak. The primary requirement for the extraction phase is to understand and optimise the flow of the fragmented rock in the rings including interactions with the caved material. Rock fragment formation is critically controlled by the blasting phase and can potentially be improved by optimising the dynamic energy distribution throughout the ring through the crafting of explosive charging, priming position and initiation timing. The modelling of fragmentation and damage due to explosive loading of complete rings is inherently and irrevocably a three dimensional problem that is difficult to address. We have therefore initially utilised an analytical code to predict vector peak particle velocities and energies that are restricted to the plane of a ring. Dynamic energy distributions based on common timing and priming practice have been compared with other possibilities using conventional pyrotechnic detonators as well as initiation designs based on accurate electronic detonators. The energy distribution can be quite subtly tailored to increase energy in appropriate regions or to decrease energy in the brow region for example to potentially reduce instability and the probability of misfires. We have also recently developed the capability to efficiently model particle flow using four-sided polygonal elements. Despite the 2D limitations of such a model this results in more realistic fragment interaction and stacking than can be achieved using conventional rigid circular elements. Modelling of a typical sublevel caving ring utilising these elements activated by the correct dynamics offers considerable potential for understanding the influence of the blasting energetics and timing on the complex flow and extraction process.

Jan 1, 2005

By D M. Brady

Underground coal mines in Australia have embraced the use of various inertisation techniques both proactively and reactively. The use of such techniques can have a significant influence on ratios and trends used to monitor the status of the underground environment. Whilst control strategies should never be ignored in favour of preserving the integrity of ratios, the influence and significance of the changes likely to be seen should be anticipated and understood for reliable interpretation of the situation. This paper looks at the influence inertisation techniques can have on results and subsequent interpretation.CITATION:Brady, D M, 2013. The influence of inertisation techniques on gas interpretation, in Proceedings The Australian Mine Ventilation Conference , pp 259-264 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013

By G Brewster

The Eagle on the Hill tunnels form part of an upgrade of Mt Barker Road, 15 km to the southeast of Adelaide. The upgrade significantly improves safety and reduces delays on this major road, which winds steeply through mountainous terrain. The twin tunnels each spanning 15 metres run in parallel for a length of 480 metres. The tunnels are excavated in slightly weathered high strength slates and very high strength quartzites of the Saddleworth Formation on the western margin of the Mount Lofty Ranges. Steeply dipping slate cleavages and the high fracture ratio result in many slope stability problems in the project area. The level of geotechnical investigation undertaken prior to the calling of tenders for the project was extensive. This included the excavation of a pilot tunnel along one of the tunnel alignments, which allowed accurate mapping and rating of the rock, resulting in an increased level of confidence during the tender process. One of the features of the winning alternative tender design was the use of canopy tubes, flexible steel ribs and shotcrete to replace up to 40 metres of deep portal cuts in unstable rock with driven tunnels. Slope stability issues were overcome with the use of rock dowels and shotcrete. The support concept allowed the safe driving of the tunnel portals with as little as two metres of overburden. The design incorporated lining drainage and criteria for fireproofing based on European experience to ensure the ability of the tunnels to remain stable in the case of a severe fire incident. The support design allowed for maximum flexibility with a range of support types able to deal with the varying ground conditions. Design development and support refinement continued throughout the tunnel construction phase with close liaison between the designer and the constructor. Monitoring and review of feedback from the construction site by the Sydney based design team was easily achieved by means of electronic transfer of photographic and survey information, telephone and fax communication and regular site visits. The contractor for this project is Macmahon Concrete Constructions Joint Venture (MCCJV) and the designer is Connell Wagner. Excavation commenced in January 1998 with tunnel breakthrough having been achieved in early-August 1998 and mid-September 1998 respectively. Concrete lining construction is scheduled for completion in April 1999.

Jan 1, 1999

By S Bailey

In-field sampling programs generally take time, equating to money, and unless you have an onsite laboratory, you have the issue of having to wait long periods for your data. Until recently, field portable X-ray fl uorescence (FPXRF) analysers, which can help provide instant indicative results, were not able to detect penalty elements, such as Al and Si, or do so reliably enough to act upon.The purpose then of this field test then was to show that the latest FPXRF devices are capable of producing reliable readings on field samples of variable grain size, in particular for Al and Si, such that the readings still correlate well with the assay for those samples and thus be reliable for an iron ore grade control application.We tested RC chip samples on-site in the Pilbara, Western Australia, with the Niton, analysing for a range of elements including Fe, Mn, Al and Si and then compared the results for those elements against assay data for the same. A strong correlation would tell us that the FPXRF results were reliable. Furthermore, to show the effect of simple sample preparation, we also analysed pulps of the same samples in the same way.The correlations were good for the all of the four elements of interest for the RC chip samples (R2 values between 0.82 and 0.9), and excellent for the pulps (R2 values between 0.89 and 0.998).The results also showed a direct correlation between sample preparation and improved quality of results with the FPXRF.The data showed allowed for two conclusions:1. the FPXRF can produce data from unprepared RC chips for Al and Si that, when compared with assay, is reliable for a fi eld application in drilling and grade control; and2. the greatest limitation to data quality is sample preparation.

Jul 11, 2011

By H Y. Niu

The coal left in the goaf is easily submerged by groundwater damage. During the mining process of the underlying coal seam, it is necessary to drain the water in the overlying goaf. The coal sample is prone to spontaneous combustion after being soaked in water and air-dried. To explore the effect of micro-functional group transformation of water-immersed coal samples on the spontaneous combustion characteristics of coal samples during the low-temperature oxidation process. Using the experimental method of infrared spectroscopy, the migration law of special functional groups under different oxygen concentrations of water-soaked coal samples was analysed. By means of thermal analysis, the endothermic and exothermic properties of the functional groups in the water-soaked coal samples were studied. The results show that: the higher the oxygen concentration, the more oxygen-containing functional groups in the water-soaked coal sample, compared with the 18 per cent oxygen concentration, the 14 per cent oxygen concentration has a small increase, and the chain length is shortened. The temperature increase together with the oxygen concentration content determines the functional group content, the pyrolysis process produces some functional groups. The lower the oxygen concentration, endothermic rate decreases and endothermic temperature increases, the higher the ignition temperature of coal oxy-combustion, the lower the total heat release, the higher the burnout temperature, and the faster the oxygen-absorbing weight gain and the conversion of functional groups. Below 14 per cent oxygen concentration, the oxidative combustion process will be greatly reduced. The results provide a theoretical basis for preventing long-term water-soaked coal body oxidative spontaneous combustion in shallow buried coal seams.

Oct 12, 2022

Land is of extreme importance to citizens of Papua New Guinea and is fundamental to most of their customs and values. Because of this, matters to do with land cannot easily be separated from other matters to do with the community. Good relation-ships with landowners and the community surrounding a development are, indispensable ingredients that -must flavour and colour the entire ;operati on .

Jan 1, 1994

By Wong KY, Woodcock JT

Previous results have shown how con- trolled-potential sulphidization (CPS) can give improved metallurgy during rougher flo- tation of mixed oxide-sulphide copper ores. Results in this paper, using different samples and different equipment, confirm the previous results and extend the application of CPS to cleaner flotation. By using CPS, faster flotation of copper minerals (chalcocite and malachite) from clay was obtained in roughing and cleaning, and improved concentrate grades and recoveries were achieved over those by conventional manual control. The optimum sulphidizing potential (i.e. the potential of a sulphide ion-selective electrode versus a saturated calomel electrode) was -500 mV, and could be controlled to ¦5 mV, during four rougher- scavenger and three cleaner-re cleaner stages. This optimum gives the best balance between copper recovery, concentrate grade, and sodium sulphide consumption. Five cleaning circuits and five ore com- posites of different composition (0.55-1.50 per cent Cu) were examined as well as the effect of feed size and pulp density. Better results were obtained at 20 per cent solids in a Denver cell than at 33 per cent solids in an Agitair cell; this may have been related to the high clay content of the ore. Commercial equipment for pilot plant or full-scale plant application of CPS is cur- rently being developed.

Jan 1, 1986

As this district is so far distant from the other mining centres and its mode of approach so circuitous, I am afraid that many residents of other portions of the Commonwealth never think of paying this" Australia's Silver City" a visit, to learn personally the many and various lessons everywhere available, and to become familiar with the really wonderful and interesting features and deposits (which pature has so lavishly bestowed in the mineralogical world) yet seemed to almost ignore or overlook when disposing of topogr,aphical beauties of landscape and vegetation) unless professional or business duties require their presence here. So it is to those whose life is necessarily spent in other parts of the States where they answer their call of duty, and yet feel an interest, either for business or other reasons, that my paper is specially addressed and prepared, and for that reason I witl endeavour to make my remarks more of an explanatory than a dictatorial nature. I feel sure that there. are many members of our Institute who are much more familiar, and have had many more years' experience in the various methods of timbering, filling, and ore extraction, etc., than myself, but I hope that over I6 years' experience in connection with mines and engineering works, the last six of which have been spent in Broken Hill, where, I have been very closely connected.

Jan 1, 1903

By R Schlueter, H Mischo

The mining industry is facing a variety of geological, technological and social challenges. Future deposits show a general tendency towards increasing depth with complex ores and decreasing grades. One promising approach to deal with low-grade ores is bioleaching in the form of heap and dump operations. Bioleaching is already a state-of-the-art technique, especially for the extraction of copper from sulfide ores. The next step in the development of this technology will be its application as an in situ technology. First attempts to adapt this technology in underground mining in the form of stoping and block caving have already been made. Both methods have to be carried out adjacent to conventional mining operations and therefore require much effort regarding drift development as well as extraction and transport. The adaption of bioleaching as a borehole mining method is the next step to establish an innovative in situ technique to meet future challenges.The Freiberg University of Mining and Technology established the Biohydrometallurgical Centre for Strategic Elements (BHMZ) to foster interdisciplinary research along the whole biohydrometallurgical process chain. In general, 13 different university institutes and several associated groups with about 30 PhD students are mainly focusing on the extraction of indium and germanium from deposits, tailings and recycling material. One of the core projects within the BHMZ is the design and implementation of an underground in situ bioleaching testing facility.This paper demonstrates the potential of in situ bioleaching under technological aspects. Furthermore, different conditioning methods to increase the permeability of the orebody will be explained, and the BHMZ’s underground testing facility will be presented.CITATION:Schlueter, R and Mischo, H, 2015. Potential and applications of underground in situ bioleaching, in Proceedings Third International Future Mining Conference, pp 205–212 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 4, 2015

By A Vakili, F Harvey, H Greaves

Mine seismicity is one of the most difficult geotechnical risks to manage in seismically active mines. There are currently some established empirical and statistical methods that provide quantitative measures for seismic hazard assessment in operating mines. However, these methods are mostly suitable for quantifying the current or historical seismic hazard and often cannot be directly used to forecast the future hazards. Numerical modelling is the only analytical tool that can capture the level of complexities required for a meaningful analysis of mine seismicity and therefore to facilitate a reliable forecast of future hazards. However, there is currently no widely accepted and established guideline and methodology for analysing and forecasting mine seismicity using numerical modelling. This paper first provides a background on previous published studies on this subject and then outlines the key aspects that can affect the reliability of the forecasting for mine seismicity. These aspects include a) processing of historical seismic data, b) selection of suitable numerical modelling approach, c) Post-processing and interpretation of the model outputs. A case study is then presented for the Gwalia Deeps Mine where a new framework was developed to forecast future mine seismicity. High-quality seismic data for a period of five years was used for back-analysis and comparisons with the numerical modelling outputs. After development of the method, the future seismicity was forecast for the next 12 months and the actual seismicity was monitored against the forecast during this period. Results of this study shows promising potential for the proposed framework to be applied more routinely and at other mine sites. However, more validations are required at Gwalia Deeps mine as the mine proceeds to deeper levels. In addition, the method needs more improvements and should be tested and validated at other mining operations before it can be established as a proven method. CITATION:Vakili, A, Harvey, F and Greaves, H, 2018. Forecasting mine seismicity – towards a more established methodology, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 207–222 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

A research and testing facility has been developed at Simtars to allow the spontaneous combustion testing of coal on a large scale. In this adiabatic reactor, the coal particle sizing is closer to that which could be found in the goaf and therefore the reaction is more likely to simulate the underground situation. This allows aspects of the spontaneous combustion process and methods for detecting a heating to be investigated which cannot be done in an operational mine. Up to 18 tonnes of run of mine or crushed coal is loaded into the reactor and allowed to self-heat while the temperature and gas profiles within the coal pile are monitored. The gases evolved from the coal are analysed using a fixed gas monitor system and gas chromatography to determine which of the common mine fire indicators and ratios can be used to predict the onset and progress of coal heatings. Benchmarking of the inherent propensity of a coal to spontaneously combust at both the large- and laboratory-scale is also possible by comparing the sample against previously tested samples. It has been found that the coal particle size affects both the time it takes for the coal to react and the location of the developing heating. The heatings generate approximately one metre from the inlet but in the crushed coal case do not progress to an advanced heating stage until the æhot spotÆ migrates towards the coal surface where there is an increased oxygen supply. Physical properties such as the compressive strength of the coal also affect the heating size and the time it takes for a heating to develop. Higher strength coals appear to oxidise more slowly and therefore take longer to self-heat as oxidation of the coal is the heat-generating step in the spontaneous combustion process. The best indicators of the state of the heating were found to be CO make and GrahamÆs ratio which are independent of air flow. Investigation of a potential spontaneous combustion should begin as soon as the CO make or GrahamÆs ratio exceed the background levels. The results from the tests undertaken on a number of Queensland and NSW coals are reported here together with the implications for the mining industry.

Jan 1, 2005

By Nott M. C

The oxidation of xanthate collectors to xanthate/dixanthogen results in a higher hydrophobicity of sulphide minerals surfaces due to the action of dixanthogen. This higher hydrophobicity can be proved on a fundamental level by examining the st

Jan 1, 1994

By D Kent

"There has been a revolution occurring in underground mining over the last several years, where big headline items such as the Internet of Things (IoT), optimisation, managing data, data mining etc – the list of current catchphrases, goes on. In the end these are nothing new; but the ‘things’ (sensors) are becoming smaller, cheaper and easier to deploy, and the analysis much more powerful as computer processing speeds increase. However, to take advantage of the myriad of devices out there and gain the processing power to analyse and use the data, a reliable ‘conduit’ is needed for that information to be delivered where it can actually be used. That is, a high quality data network.Modern mining is like any other industry in the information age: the access to reliable data is the first, critical step in improving productivity (Stevens, 2015). The convergence of communications onto an IP (Internet Protocol) backbone has been the driving force in enabling the productivity gains in general industry over the last two decades.This paper overviews how this technology has developed as an enabler in accessing productivity and safety benefits, and how it has used access to large amounts of data to manage mining processes underground. Reams of data are useless, but with the reliable receipt, analysis, processing and feedback system in place to use that data, benefits can be realised.Automated mining systems are increasingly being seen as a key requirement for a productive mining operation, and the importance of an integrated communication network infrastructure to support such systems is growing. Another emerging driver is the much talked about IoT and data analytics, both dependant on reliable, accurate, high volume data.The author will outline how communication infrastructure is fundamental to the operation of such systems, and explain why the resultant communication networks require much more than just increased bandwidth (data capacity) to properly support the automation and other data hungry systems within the overall mine operation.Mining operations embarking down this road are discovering that the required network must be based on a true enterprise level architecture to, not only enable the mine’s current plans for remote or automated mining, but also to provide a scalable and integrated platform for future developments. The emerging issues for the communication network to truly support automation systems include: increased complexities of operating and maintaining multiple networks integration issues with disparate systems problems with reporting, particularly as demands for corporate reporting and compatibility with enterprise systems become the norm ongoing management challenges, which will only increase with the proliferation of new technologies.How certain mining operations lay the necessary foundations to meet their current requirements, while supporting their visions for a more automated and proactively managed mine, will be explored.CITATION:Kent, D, 2017. Modern mining – why bandwidth matters, in Proceedings 13th AusIMM Underground Operators’ Conference 2017, pp 123–128 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 16, 2017

The Kidston breccia pipe is situated approximately 280 km west northwest of Townsville, north Queensland. It is currently Australia's largest gold producer with production varying between 8,000 and 16,000 tonnes of ore per day. Current reserves are estimated at 36.2 million tonnes averaging 1.74 C/t Au and 2.21 g/t Ag. Alluvial gold in the gullies surrounding the deposit was first discovered in the 1880's and between 1907 and 1948 small scale open cut and underground mining was undertaken. Advances in extractive metallurgy and an increase in the gold price were major factors influencing the recent exploration and development of large scale mining of the deposit by Placer Pacific and Kidston Gold Mines. The breccia pipe is trapezoid in shape with surface dimensions of 1100 m by 900 m. Clasts show only limited evidence of mixing during brecciation, with the pre-breccia stratigraphy still discernible on the basis of clast types. This lack of mixing together with the intimate association with intrusive activity, suggests that the brecia formed by collapse, probably associated with the escape of a large volume of irothermal fluid from a crystallising hatholith. Mineralisation and alteration are also sratially and temporally associated with rhyolite emplacement and brecciation. Pre-breccia mineralisation consists of laminated stockwork quartz veins associated with muscovite, quartz and orthoclase-epidote alteration. Stockwork veins contain either anomalous molybdenite or gold. Uneconomic early stage post-breccia mineralisation and alteration consists of cavity infill quartz-epidote and calcite associated with potassic and propylitic alteration respectively. Economic late stage post-breccia cavity infill and sheeted veining consists of quartz-carbonate-sulphide infill associated with phyllic alteration. The grade of gold mineralisation generally decreases downwards in the system with an increase in the amount of pyrrhotite relative to pyrite. Pre-breccia stockwork quartz veins mineralisation is genetically related to the

Jan 1, 1987

By Real F, Carvalho P

During the development of the Neves-Corvo Underground Copper Mine, since 1981, inflow of water has been encountered in the mine workings, which consist of a ramp from surface 5 km long, a shaft 575 m deep and access crosscuts through the massive sulphide orebodies of Neves, Corvo and Graga, which are three of the four known deposits up today. Mine-hydrological studies have established the main characteristics of the hydrological system and its evolution in space and time. In a geological setting of low permeability rocks of Paleozoic age, tectonically affected by thrusts and faults, this has involved consideration of the relation with surface and ground water as a result of mine dewatering processes. The hydrological systems are described and summarized in this paper together with the techniques employed to study their origin and evolution, namely hydrochemistry, thermometry, piezometry and isotopic tracers.

Jan 1, 1988

By L Cooper, J Sharma, M J. Hendry

Thick clay tills below potash mine tailings and brine ponds are important natural barriers protecting fresh water aquifers in Saskatchewan. Centrifuge modelling was applied to assess geochemical processes and impacts of dilute brine (0.1 M NaCl) migration through clay till core samples obtained from non saline, unoxidised clay till at a mine site. At accelerated gravity of 876 + g, during each day of centrifuge modelling, flow driven through a 52 mm length core simulated transport through a 45 m thick clay over ~2100 years. Hydraulic conductivity, monitored continuously before and during brine permeation, was low and relatively constant (8.5 + 10-12 m/s), confirming that confining stresses prevent permeability increase. Core density and porosity measurements confirmed that reactive transport occurred under realistic in situ conditions. Breakthrough (defined by C/C0 = 0.5) of non-reactive Cl- occurred at 25 days. The slight delay for Na+ breakthrough, associated with small increases in Ca2+ and Mg2+ concentrations in the effluent were attributed to ion exchange, but carbonate reactions were relatively unimportant. Cation exchange analysis of core samples was inconclusive without corrections for porewater Na+ and carbonate dissolution. Geochemical processes that were observed during centrifuge modelling were successfully simulated using the 1D geochemical transport code PHREEQC. Solute transport was dominated by diffusion with limited ion exchange to delay Na+ migration. Brine would not break through a 45 m thick clay for tens of thousands of years. Based on these findings, the thick clay till at this site, if laterally extensive and undisturbed by drilling activity, is likely to act as an effective natural barrier to vertical brine migration over the long term.

Jan 1, 2003

By G R. Ballantyne, B Putland, I Lovatt, M Di Trento

The Tropicana Gold Mine, owned by AngloGold Ashanti Australia Ltd (70% owned and managed) and Independence Group NL (30%) is located 330 kilometres east-northeast of Kalgoorlie, Australia, in the newly developed Albany-Fraser Orogen. Following extensive feasibility studies, a high pressure grinding roll (HPGR)-ball milling circuit was selected based on the reduced power requirements and thus reduced operating expenses. The HPGR-ball mill circuit was estimated to require 75% of the energy of a standard semi-autogenous grinding (SAG) mill circuit. Even with an anticipated greater capital cost, the HPGR-ball mill circuit was found to give significantly better financial returns in all cases investigated in the feasibility study. A comparison between the specific energy requirements of the HPGR, crush and SAG based circuits (SABC) from the feasibility work was conducted and the HPGR circuit was found to be considerably more energy efficient. A survey was conducted and the efficiency of the HPGR was similar to both the overall circuit design and the HPGR laboratory results, reflecting the accuracy that is possible for design and operation of HPGR circuits.Between 2015 to 2016, the Tropicana circuit has achieved a 20% increase in throughput from 780 to 930 t/h, and this increase has been maintained in 2017. This improvement can largely be attributed to upgrades to material handling processes, increased HPGR speed and smaller HPGR screen apertures. The result of these changes has been to increase the ball mill capacity by increasing the breakage conducted by the HPGR.CITATION:Ballantyne, G R, Di Trento, M, Lovatt, I and Putland, B, 2017. Recent improvements in the milling circuit at Tropicana mine, in Proceedings MetPlant 2017, pp 73–83 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 11, 2017

By A Parry, C Fitzmaurice

After conducting laboratory ore sorting testwork on samples of a low grade nickel ore stockpile at Western Areas’ Flying Fox nickel mine, a mobile crushing, screening and ore sorting plant was located adjacent to the stockpile. An initial two month trial of the ore sorter program proved successful and was extended to process the entire Flying Fox low grade stockpile in a further four month campaign. A total of 167 660 t of low grade ore was processed, providing highly upgraded feed trucked 26 km to the Cosmic Boy concentrator. A more than three-fold grade increase was achieved on ore sorter accepts. The moderately upgraded fines that by-passed the mobile ore sorter were also subsequently blended into plant feed. This paper describes the mineralogy of the Flying Fox low grade ore, the mobile ore sorting campaign and provides some commentary on the economic and environmental benefits achieved in the ore sorting campaign. The ore sorting campaign demonstrated the benefits of being able to utilise mobile ore sorting equipment temporarily located adjacent to sub-economic low grade stockpiles in order to effectively treat these stockpiles and produce viable plant feed.CITATION:Parry, A and Fitzmaurice, C, 2018. The upgrading of low-grade nickel ore stockpiles at Western Areas Ltd Forrestania operations, using a mobile ore sorting plant, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 541–550 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By L Klemettinen, J Biswas, W Malan, D Sukhomlinov, D Lindberg

In order to mitigate the effects of climate change, our society must be able to drastically reduce its CO2 emissions. As the metallurgical industry is a considerable contributor to these emissions, new greener technologies must be invented and developed. One option could be the direct production of metals from oxides using renewable electricity. The aim of this study was to investigate the possibility of using high-temperature molten oxide electrolysis (MOE) for iron and ferrochrome production. FactSage™, ver 8.2 (by Thermfact Ltd and GTT-Technologies) was utilised for estimating a feasible equilibrium electrolyte composition, and the experiments were conducted at 1550–1580°C in conical alumina crucibles with iridium wire as the cathode and platinum wire as the anode. The sources of iron and chromium were either pure FeO powder or industrial chromite pellets. Voltage was applied to the electrolysis cell for 6 hrs and the resulting current was measured, along with oxygen concentration in the off-gas line. The electrolyte comprised of SiO2, Al2O3, MgO and CaO. First, the effect of FeO concentration on iron reduction efficiency was investigated using only pure oxide powders as starting materials. The results indicated that 10 wt per cent FeO mixed with the electrolyte resulted in more efficient iron reduction compared to 20 wt per cent. In further experiments, industrial chromite pellets were ground and mixed with the CaO-free electrolyte. Iron and chromium reduction efficiencies were higher when approximately 19 wt per cent of the total sample mass consisted of pellets compared to increasing the pellet amount to 37 wt per cent. Generally, the chromium solubility in the liquid electrolyte was relatively low, and most of the chromium was confined to the spinel solid solution, from where its dissolution to the liquid electrolyte was very slow, resulting in slow reduction kinetics. For larger scale applications, economically more viable electrode materials should be investigated.

Jun 19, 2024