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By F. Parada Torres

Xstrata Tintaya S.A. opera el yacimiento a tajo abierto y procesa el mineral en dos plantas: Planta Concentradora de Sulfuros y Planta de Lixiviación de Óxidos, donde anteriormente consideraba al mineral mixto complejo como intratable en la planta concentradora, por lo que se le destinó a ser tratado como óxido marginal en la planta de lixiviación. En este sentido, el presente texto describe el nuevo tratamiento al mineral complejo en la planta concentradora. De forma que se busca definir las variables geometalúrgicas del mineral de Chabuca Norte, optimizar los procesos metalúrgicos del mineral mixto mediante la investigación geometalúrgica, así como correlacionar el entendimiento de la geología y alteraciones del yacimiento con los procesos metalúrgicos y crear valor mediante la optimización de la tasa de tonelaje de tratamiento y el incremento del porcentaje de recuperación de cobre en el proceso.

Sep 12, 2011

By S. Vongpaisal, T. R. Yu

"A set of new blast damage criteria has been developed, with special reference to blasthole mining operations, for assessing damage by incorporating the vibration level, rock properties, site characteristics and the effects of ground support systems. The main objective of this work was to provide a database with reasonable accuracy for use in optimizing blast design, numerical analysis and ground control expert system module development.The new damage criteria allow one to estimate the degree of damage to rock structures in terms of a dimensionless parameter defined as Blast Damage Index (BDI). This allows for the description of blast damage in a unified form, and facilitates the development of codes for numerical modelling to express the degree of blast damage universally. A number of field investigations from several stope production and slot opening blasts at a large underground base metal mine were carried out to verify the developed index. The results show a good correlation between the observed damage and the type of damage predicted from the BDI values.Practical measures are also provided for minimizing blast damage in large underground blasthole mining operations"

Jan 1, 1996

By Jan A. Nilsen

This paper describes a key element in the construction of a major project undertaken by Harbourfront Corporation in its efforts to rejuvenate the central Toronto waterfront. The Spadina Pier forms one of the two major structures of the $10 million marina complex. Completed in early 1986, the 150 metre(490 ft.) long by 43 metre(140 ft.) wide pier structure will contain a 320 car parking garage as well as providing the foundation of a 17-story residential tower and a two-story retail/commercial complex. However, the pier structure posed a considerable challenge to its developers due to the the many restrictions imposed on the site by the environmental authorities which ruled out the construction of dykes or the placing of other fill materials on the highly contaminated bottom sediments. In addition, access at the site was restricted by its proximity to the main harbour navigation channel and a grain elevator berth. The original design called for a cofferdam to form an integral part of the finished structure. However, the contractor chose to regard the cofferdam as a temporary structure and proposed to construct the pier in the dry by enclosing the 10,000 square metre(107,600 sf) site with a 450 metre(1480 ft.) long single wall steel sheet pile cofferdom 7.5 metres(25 ft.) from the final pier structure. This paper will describes the design and construction of the cofferdam. Prior to finalizing the pier design, a geotechnical investigation of the shale bedrock was undertaken as well as a small sheet pile test cell program to evaluate the feasibility of driving a Canadian manufactured cold-rolled sheet pile into the bedrock. Relying on the design parameters for the shale bedrock, Foundation designed the cofferdam utilizing a post-tensioned bipod bracing system to resist a 7 metre(23 ft.) hydrostatic head as well as the maximum wind and wave forces expected at the site. The bipod bracing system consists of diagonal H-pile raker piles and verticle pipe piles anchored to bedrock with post-tensioned anchors grouted into bedrock.

Jan 1, 1987

By Jun Wang, Bo Zhang, Wenqing Qin, Guanzhou Qiu, Xiaozhen Ma, Key Lab of Biohydrometallurgy of Ministry of Education, Fen Jiao, Central South University, Yansheng Zhang

"Arsenic contained in minerals sulphides such as enargite and tennantite can represent not only a significant penalty element in base metals production, but also a disadvantage to the environment through producing the toxic emissions to the atmosphere. The achieving separation of arsenic bearing minerals either at an early stage in floatation or from the floatation concentration is significantly beneficial to the economic. However, there was no feasible commercial method of separation at the flotation stage because of its similar flotation properties with many other copper sulphides. In this work, the selective floatation of enargite from copper sulphide concentrate containing maily covllite, chalcoctie, bornite and enargite was investigated. A low arsenic concentrate with As 0.2%, Cu 22% and a high arsenic bulk concentrate with As 7.65%,Cu 33.65% were obtained. It was indicated that Ca(ClO)2 is the effective depressor and the optimum floatation condition was obtained. Most enargite could be floated at pH 11 and controlling the pulp potential at 290 mV SHE. Furthermore, the arsenic removal from the high arsenic bulk concentrate by hydrometallurgy methods was study. The results showed that the reaction temperature and the concentrations of NaOH were the most important variables affecting the rate of arsenic removal. A low arsenic concentrate with As 0.24%, Cu 37.80% was obtained in the optimum leaching condition.INTRODUCTIONArsenic is mainly produced as a by-product of base metals smelting, in particular copper concentrate. China has imposed an upper limit of 0.50% arsenic for concentrates entering (Long et al., 2012). Arsenic amount of copper concentrate within 0.40% has also been imposed in China, and above which will be introduced about 50 RMB penalties per ton for each 0.10% increasing by smelters now. Therefore, it is necessary to remove arsenic from the copper concentrate.In copper concentrate, arsenic is mainly in the form of arsenopyrite (FeAsS), enargite (Cu3AsS4) or tennantite (Cu12As4S13). There are two types of arsenic in the separation of copper and arsenic: arsenopyrite and arsenic bearing copper mineral. It is easier to separate arsenopyrite from the copper sulphide by flotation in comparsion with the separation of enargite or tennantite from non-arsenic copper minerals (Pineda et al., 2015). The main difficulty in the separation of arsenic copper mineral from non-arsenic copper sulphides is their extremely similar floatability, which depends on the fact that tennantite and enargite contain high copper content (Pineda et al., 2015)."

Jan 1, 2016

By F. Baerhold, S. Mitterecker

"Acid recovery is an important process step in pickling and leaching processes. Pyrohydrolysis in spray roasters and fluidized beds is a well-established technology to recover hydrochloric acid, but the hydrolysis in the liquid phase is more and more considered as an alternative new process route. The characteristic features of these three processes will be discussed along with select industry trends. For example, hydrochloric acid based leaching processes for ilmenite and nickel laterite ores produce far larger volumes of waste acid streams than the steel industry. Scaling-up of the spray roasting technology to the highest possible capacity is necessary in order to become more cost effective. In addition, process routes based on ferric chloride pyrohydrolysis allow the production of super-azeotropic HCl (up to 30 wt.%). Finally, the new ECOmode concept optimizes the operation of both pickling lines and the spray roast acid recovery plant. Long term results from industrial applications show that fuel savings in the spray roaster of 25% are easily achieved without additional process steps. An attractive feature is also to upgrade existing installations to higher plant capacities.INTRODUCTION Pyrohydrolysis is the conversion of metal halides into metal oxides at elevated temperatures in the presence of water vapor. Reaction products are a hydrogen halide gas and a metal oxide. The process was originally developed and introduced into the market by ANDRITZ Ruthner in the 1960’s. It has found wide technical application in the field of acid recovery and oxide production. The introduction of this process has revolutionized pickling technology. The use of hydrochloric acid has strongly increased over the last decades, since pyrohydrolysis is available for the total recovery of waste pickle liquors from mild steel pickling, as illustrated in Figure 1.Chloride media are also used increasingly in the metallurgical industry. Oxide production processes for Mg, Co, Ni, and Al have been installed. Processes using hydrochloric acid are known for the leaching of ores as well as for the re-extraction of metals from organic solvents. In both cases the recycling of HCl is of substantial importance to achieve highly economic processes and to reduce waste."

Jan 1, 2016

By K. K. Murray, D. G. Gelderland

"The pressure oxidation autoclave at the Goldcorp’s Red Lake Gold Mines (RLGM) was commissioned in 1991. Since commissioning, the circuit has been well maintained and its capacity increased to mechanical and gaseous oxygen limitations. With advances in available technology, opportunities to produce more sulphide concentrate and a changing business environment, an optimization project has been initiated at RLGM. A multi-phase approach has been developed to optimize both the operations and economics of the circuit. This paper describes the history and future of the autoclave circuit at RLGM.AcknowledmentsWe would like to thank the operations and maintenance staff at Red Lake Gold Mines for their support and openness of mind to enact changes to enhance the operation. We would also like to acknowledge the members of the integrated team from Red Lake maintence, metallurgy, operations and corporate technical services that did the hard work to push past the status quo in order to advance productivity.OpportunityThe Red Lake Gold Mines (RLGM) pressure oxidation (POx) circuit has been in operation for over 25 years processing the high sulphide content gold bearing minerals. Increased sulphide concentrate production from improved flotation recovery and increasing gold sulphide association at depth has led to the POx circuit becoming a throughput bottleneck. The opportunity exists to process increased tonnages of sulphide concentrates and increase gold production. In order to realize this value, it will be necessary to increase the throughput capacity of the POx circuit.BackgroundThe POx autoclave at the RLGM, commissioned in 1991, was Canada’s first gold autoclave. It was installed to replace the two-stage fluid bed roaster that was built when the Campbell mine and mill were constructed in the late Forties. The circuit was originally designed to process 12.5 t/d sulphide sulphur in about 50 t/d of Campbell flotation concentrate. Following the merger of the Campbell and Red Lake Mines in 2006, the POx circuit started processing flotation concentrate from both Campbell and Red Lake Mills. In recent years, the circuit has been processing about 18 t/d sulphide sulphur in 75-85 t/d flotation concentrate."

Jan 1, 2017

By M. K. McCarter

The history of mining education, like the history of the mining industry, is typified by “boom and bust” cycles. In academia, the perpetual problem can be stated as “too many graduates for the jobs or too many jobs for the graduates.” The deep “bust cycle” that spanned the 1990s through 2003 spawned renewed efforts to eliminate, consolidate, restructure, rename, reinvent or otherwise change mining education to make it (for some) more fiscally or socially acceptable. During this period, a number of mining programs were eliminated, and by the late 1990s senior people in academia and their counter-parts in industry became increasing concerned about the very real possibility that strategic disciplines may disappear altogether. As a result, the Mining and Metallurgy Society of America (MMSA) created an educational committee to explore how industry could help preserve key programs necessary to provide future professionals. Several meetings were held to assess the problems and look for solutions. In 2004, this effort culminated in the first of the “Engineering Education” sessions to be held at the SME Annual Meetings. In response to the information presented in this first meeting, Marc LeVier (then president of MMSA) invited a number of the participants to reconvene the following day. An action plan was formulated and a task force was organized. To more fully represent all industry sectors, SME later that year assumed the sponsorship role for the task force.

Jan 1, 2007

By Blott S. F

The smelting plant and equipment at Mount Isa, as originally designed and built, was described by J. M. Callow (1) *.F. A. Forward (2) described alterations and additions to the plant and discussed the metallurgy of mixed carbonate-sulphide concentrates at Mount Isa, prior to 1933, in the Proceedings of this Institute.In 1933, A. F. McAskill (3) gave full mechanical details of the plant in a paper presented to the Institution of Engineers, Aust.FLOW SHEETSFig. No. 1 represents the present general flow sheet. Forward's (2) flow sheet is reproduced here as Fig. lA, and will serve for comparison in depicting subsequent deletions from, and alterations and additions to, the plant.Fig. No. 2 presents the daily tonnage flow sheet of 1939 practice.ALTERATIONS SINCE 1933General. Many changes in metallurgy and operation have taken place, particularly subsequent to March, 1935, when the treatment of a mixture of carbonate and sulphide ores was discontinued and the mill commenced operating on all-sulphide ore. This alteration brought about the elimination of gravity concentration-Jigs and Tables and resulted in the production of all-floatation concentrates of a very fine sizing. Refer Table No. 2, page?) Radical changes in the analyses and physical nature of concentrates also followed (see Table Nos. 1 & 2, page ?) and, similarly, radical changes in the smelting plant have been slowly brought about.

Jan 1, 1939

By C. Schuffeneger

"The design of SAG milling circuits for mining projects requires the incorporation of the energy consumption considerations and the evaluation between different flexibility-adding options to absorb the time-dependent variation in the ore lithology. In order to expand the focus of the engineering design, a higher level of deepness and quality in the baseline information must be achieved to elucidate all of the constraints on throughput, energy consumption and product quality generating a design optimization consistent with an integrated vision of the process. This paper presents a review of a collection of typical examples of the copper and gold mining project in the Chilean Andes, in which both process and energy efficiency criteria are considered when the focus is to deliver an integral solution that incorporate those areas in the design. The intensive use of energy in the SAG milling, the process continuity and the quality of the product are a function of the proper design and selection of grinding equipment and plant layout, aligned with the mining plan and associated with projected future expansions and production increases.INTRODUCTION Autogenous and Semiautogenous grinding technology, large diameter and short length mills, begins with the Handsel design. During the decade of 1930’s, Handsel-Hardinge studies led to cascade mill development. Nowadays, 80 years later, continuous improvements in design and technology have been conducted to a completely new generation of gearless SAG mills that have led to an increasing capacity at the concentrator plants. Considering the existing alternatives, SAG mills are the most implemented option for the grinding circuit today. This work presents a review of the SAG mill implementation parameters and circuit considerations and its correlations in the most recent projects in Chile with an ore treatment capacity above 50 ktpd since the decade of the 90’s up to now. From this period, the tendencies will be analyzed using project design data. Based on process design information, the recent SAG mill history in relevant projects related to the new generation of commercial SAG mills, technical associated considerations and performance will be discussed. Circuit selection based on energy utilization will be revised to bring up a more holistic perspective on the SAG mill circuit design concepts. As is now well known, the heart of every concentrator plant are the grinding mills. Higher demands on throughput, availability and power consumption optimizations require not only high performance electrical equipment but also a well selected grinding circuit. The energy efficiency issues associated to the circuits design will be reviewed."

Jan 1, 2012

By Abhiram Kumar Verma, Soumya Ranjan Mallick

Generally, waste such as soil and sandstone is used in mines for road construction or haul roads. In many such mines, it is challenging to design haul road pavement to match the dumper capacity. This paper investigates overburden soil to find its utility as a pavement material. It is found that overburden soil is unsuitable pavement material without stabilization; hence, nine composite materials are developed using overburden soil and RBI. Physical, mechanical and microstructural properties of unstabilized and stabilized soil are determined. Statistical analysis is carried out to assess the effect of soil type, RBI and curing period of strength characteristics of unstabilized and stabilized soil. ANOVA tests assess the influence of RBI percentage on soil geotechnical properties, and regression relations are developed. Two-way ANOVA shows the effect of RBI and soil type on soil geotechnical properties, whereas one-way ANOVA shows that the influence of soil type is more than the RBI. The regression relation is developed for CBR, UCS, Poisson’s ratio and modulus of elasticity with a good correlation coefficient. The performance of RBI is more with the finer material and reduces with an increase in the size of soil grains. The performance of the developed composite is better than the earlier developed composite based on overburden with fly ash, lime kiln dust, lime or clinker.

Mar 19, 2024

By S Bright, M J. Masamvu, E K. Chiwandika, S Dandi, S M. Masuka

The depletion of high-grade hard and lumpy chrome ores has forced Zimbabwean ferrochrome producers to resort to low-grade friable ores that have an average of 28 per cent fines against a set limit of 12 per cent. Submerged open arc furnaces currently in use are associated with eruptions within the furnace because of the high amounts of fines, high energy consumption, as well as high SO2 and CO2 emissions. Traditionally employed agglomeration methods such as pelletising and the use of coke in the furnace have been discarded because of the pressure to lower operational costs and to achieve higher profit margins. This research aims to develop a method to incorporate lowgrade friable ore fines and unprocessed coal into production while lowering CO2 and SO2 emissions through a closed direct current (DC) arc furnace. The closed DC arc furnace could incorporate the friable ores and coal while maintaining above 90 per cent reduction rates. Preliminary findings also show that energy consumption could be reduced by up to 35 per cent by incorporating a pre-heating and pre-reduction system using the flue gases from the furnace. In the proposed circuit, the cost of production per ton of ferrochrome might be potentially lowered by an average of 30 per cent.

Jun 19, 2024

By Nicholas Tabor, Norbert Fuegenschuh, Richard Taylor, Jean-Marc Wehrli

The Plymouth Tunnel forms part of the 16-mile long route of the Purple Line Light Rail Project promoted by the Maryland Transit Administration. The tunnel is approximately 1,220 feet in length with a shallow vertical alignment located beneath a residential area. Challenging mixed ground conditions included surficial soils, decomposed Saprolite, and highly weathered to fresh rock requiring the use of the Sequential Excavation Method (SEM) for construction. This paper discusses innovative approaches implemented during construction as well as challenges faced during planning and installation of a spray-applied permanent concrete liner.

Jun 13, 2021

By Y. M. Zhao

Reutilization of waste printed circuit boards (PCB) can not only prevent potential environmental pollution, but also achieve recycling of secondary resources. Study on recycling of discarded PCB belongs to the front edge of environmental pollution prevention and resource recycling. In order to effectively crushing waste PCB, and solve the problem of secondary pollution of fugitive odor and dust during the crushing process, a wet impacting crusher was adopted to achieve comminution liberation of PCB in water medium. 96.79% of the crushed yield was distributed in ?2mm, and metal took 97.18% in this grade of production. Size distribution of PCB particles was characterized double peaks at the sizes of ?1+0.5mm and ?0.074mm. A double Rosin-Rammler function, is called DRR function, is put forward to describe the size distribution of PCB particles. The DRR function of cumulative weight percentage oversize of PCB was non-liner fitted by self-defining DRR function of the Origin 7.0. The evaluation indexes of the fitting results are the correlation coefficients R2 of 0.9994 and residual E of 0.18671, those show that DRR function is perfectly accurate. Based on the research the mechanical separation and material properties of PCB, a wet process of reclaiming metals from PCB using a new style separator ? tapered diameter separation bed (TDSB) in water medium was designed, and the related separation mechanism was studied. The fluid field of the tapered diameter separation equipment was simulated by the Ansys Flotran software, the variation laws of the velocity in each position in the fluid field as well as the equation of axial distribution sectional max velocity were analysed according to the simulation result, the stress change and motion trajectory of the pellet in the certain fluid field were analysed. The results show that the expanding tubular structure of the varied diameter separation bed indicates gradually decreasing velocity of water flow along the axis, assuming a certain angle in the bed, as a result of the gravity?s influence, and there was corresponding change to the distribution of the flow velocity, thus the whole formed a special fluid field where velocity variations exist in different positions. When the material passed through the fluid field along with the water flow, as a result of the difference to the particle density, the granularity and the shape, there would appear the difference to the motion trajectory as well as the movement distance under the action of the fluid: The lower density materials discharge along with water flow, but the higher density materials would be kept in bottom of the bed and discharge through material mouth. Therefore, light and heavy products were separated effectively according to the density. Using tapered diameter separation bed to process the ?1mm size crushed material of waste printed circuit boards, with the discharge of water 5.5m3/h, feed-rate of the material 250g/min and with an obliquity 35°, product with 93.92% in integration efficiency and 93.73% in recovery ratio of the metal were obtained by the primary separation. Compared with other mechanical methods, the range of particle size was broaden using the TDSB to recovery metals from PCB, and lower limit size of separation almost approach to 0. An innovative process of ?wet impact crushing+ classifying+ tapered diameter separation? recycling metals from waste PCB was developed.

Jan 1, 2014

By Robert M. Becker

This report (part 3 of a five-part series) presents computer programs for evaluating moments and moment relationships of the generalized probability distributions extended or developed in parts I and 2. The principal program is for evaluating the first three moments and moment relationships of the compound-multinomial distribution for finite as well as for infinite populations. This is the generalized distribution for sampling to some amount of items per sample. Another program is for evaluating the first four moments, the moments of the mean, and the moment relationships of the multinomial and generalized hypergeometric distributions. This is a general moment program in sampling to some number of items per sample or for sampling to some number of samples. This program will accept either ungrouped data, frequency data, or probability data.

Jan 1, 1965

By Stacy Loizeaux

The Beirut Hilton Hotel, which was built in 1975, but never occupied, was imploded on Sunday, July 14, 2002 by Controlled Demolition, Inc. (CDI) of Phoenix, Maryland and their client, Optimal Engineering Consulting & Contracting, SARL, (OECC) of Antelias, Lebanon to make room for a new hotel. Twenty-seven years ago, just days before the grand opening, the Hilton Hotel became the site of fighting in Lebanon’s Civil War. Christian and Muslim militiamen fought room to room for control of the building and other nearby hotels. The Hilton, two other major hotels and other high-rise buildings were ravaged by the fighting. The building was one of the three major hotels badly damaged, but not rebuilt, in Lebanon. Located in the City Center, the Hilton stood out in a major redevelopment area which, in recent years, had erased the scars of the 15 year long Civil Wa r.

Jan 1, 2003

By D. C. Jackling

I BESPEAK your indulgence for a brief expression of the views of a patriarch in the field of mineral industry technology relative to young men's problems in that sphere of education and endeavor. Wherever hereafter I employ the terms "technical education," "engineer," "technologist," or similar expressions, these are intended to be understood as relating to the broad field of the sciences and arts applicable to the mineral industries. First, the usefulness of technical education to either the possessor of it or those to whom its services may be made available industrially depends primarily upon the quality of the education and the capabilities of the educated to put his talents to effective and constructive employment in his chosen field of applied science.

Jan 1, 1940

By M. K. G. Vermaak

Spiral concentration forms a crucial part of gravity separation circuits. The application of process models in the operation of gravity separation circuits offers significant benefits in recoveries and grade control. Significant strides in the modelling of spiral concentrators have been made during the last couple of decades. Despite these advances in modelling techniques and models, application in industrial processes is not fully optimized. The adjustment of splitter positions to accommodate changes in the feed parameters is impractical and difficult, resulting in losses. In this work an optical method is employed to detect the concentrate band position as a function of operating variables. As expected, the results indicate a strong influence of the solids content and total heavy mineral (THM) feed grade on the predicted gangue-mineral interface. Viscosity modifiers indicated the band position to be sensitive to viscosity and therefore the slimes content. Validation on an industrial sample indicated the possibility of using this model in feed-forward control application.

Jan 1, 2008

By D. Bienstock

To develop a rugged catalyst capable of withstanding hydraulic attrition resulting from the oil-circulation process for synthesizing liquid fuels, use of an iron catalyst containing an active coating surrounding an inert solid core of metal was investigated. This massive-iron catalyst in the form of steel shot and lathe turnings was activated by partial oxidation with steam at 600° C, impregnated with alkali, and reduced with hydrogen at 450° 6. The massive-iron catalysts were resistant to oxidation and spalling, and a 6-month catalyst life was attained. Higher operating temperatures could be employed than with fused iron oxide catalysts, resulting in greater gasoline yields. Because the lathe turnings pack with void volumes of 70 to 90 percent, it has become possible to employ a fixed bed without the danger of cementation that occurs with fused iron oxides.

Jan 1, 1963

By Leping Liu, Li‑Ting Chen, Sachin Urade, Pengbo Chu

Mining industry requires constant adaptation to its practices in response to the dynamic change of the societal demand. Little information exists regarding how the US metal mining engineering education is prepared to meet with its industry needs due to the increase in critical minerals driven by the green energy transitions. This study aims to provide industrial perspectives on the current US metal mining engineering education and areas for improvement. An online survey with both closed- and open-ended questions were designed to seek opinions from the US mining industry. Findings indicated a shortage of qualified graduates from the current US metal mining engineering education system. The qualifications need to be improved include engineering sciences underlying mining methods, mining design experience, mining feasibility study, the connection between theory and practice, and understanding of the overall mining operation. The survey also identified future desired qualifications. The most desired ones in the next 5 years include an ability to acquire and apply new knowledge as needed and sufficient experience in the field. Respondents, regardless of the nature of their affiliated mining companies, unanimously recommended that collaborations between the industry and academia should be enhanced. The analysis of the results concluded four recommendations: (1) involve more multiple stakeholders in reforming mining education programs, (2) reinforce field experiences as a key part of mining engineering education programs, (3) enhance a closer collaboration between academia and industry, and (4) integrate emerging technologies (e.g., artificial intelligence/virtual reality) guided by pedagogical theories into new mining engineering curriculums.

Jun 26, 2023

By G. W. Elger

The Bureau of Mines investigated the conversion, at both laboratory and pilot plant scale, of a low-grade ilmenite to chlorination-grade feedstock that could substitute for imported rutile used to produce titanium tetrachloride. The concentrate was derived from the Tahawus, NY, lode deposit of ilmenite-magnetite in rock that contains anorthosite and gabbro. Charges of the ilmenite concentrate, containing 46.6 wt pct Ti02 blended with soda ash, were carbothermically reduced in an electric arc furnace, which separated most of the iron and left a high-titanium slag. However, the slag contained Ca, Mg, and Mn constituents that rendered the material unsuitable for continuous chlorination by causing plugging problems. After being ground and pelletized, the slag was reacted with S02 and air at 7000 to 9000 C, which selectively converted the harmful impurities to soluble compounds that were removed in a subsequent water or dilute HCI leach. In laboratory tests, the combined levels of harmful impurities were decreased from 5 to as low as 0.5 wt pct in leached slags. In pilot plant tests, leached slags sulfated at a rate of 10 lb/h averaged 85.5 wt pct Ti02 with pertinent impurity levels averaging 1.86 wt pct. The leached slag was successfully chlorinated in a laboratory fluidized-bed reactor at 9500 C to extract titanium as TiCI4.

Jan 1, 1986