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By K. A. Natarajan, J. M. Modak, B. Saha

Nonliving waste biomass consisting of Aspergillus niger attached to wheat bran was used as a biosorbent for the removal of copper and zinc from aqueous solutions. Copper and zinc uptake by the biomass obeyed Langmuir isotherms. The binding capacity of the biomass for copper was found to be higher than that for zinc. The metal uptake, expressed in milligrams per grain of biomass, was found to be a function of: •the initial metal concentration (with the uptake decreasing with increasing initial concentration), •the biomass loading (with the uptake decreasing with increasing biomass loading) and •pH (with the uptake increasing with increasing pH in the range of L5 and 6.0). The metal uptake was significantly affected in the presence of a co-ion. The uptake of copper by the biomass decreased in the presence of zinc and vice versa. The decrease in metal uptake was dependent on the concentrations of metals in the two-component aqueous solutions. The effect of copper on zinc uptake was more pronounced than the effect of zinc on copper uptake.

Jan 1, 1997

By Wei Victor Liu, Na Zhang, Chengkai Fan, Bei Jiang

This study used artificial neural networks (ANNs) coupled with Gaussian mixture modeling (GMM) to analyze truck haulage data from openpit mines. The proposed weighted ensemble models performed better than benchmark models in predicting truck productivity, providing a new means of solving complex data and improving mine planning and decision-making.

Jun 1, 2023

By Richard Dunmore

Most coal seams in the United Kingdom contain firedamp, some of which is released into the ventilating airways as the strata around a working relax. The close sequence of seams in carboniferous strata is usually such that seams in adjacent roof and floor strata are also disturbed and potentially large quantities of firedamp can enter the workings from these sources. Since emission depends on the disturbance rate of the seams, higher coal production rates associated with increased mechanisation in the colliery accentuate the problem. Firedamp concentrations in UK underground workings are subject to statutory regulations1. To enable production to continue uninterrupted and in safety the problem is tackled by ventilation engineers by the provision of adequate ventilation in the airway and by the technique of firedamp drainage. In the UK the latter usually takes the form of cross-measure boreholes in roof strata, and increasingly also in floor strata, drilled from the gateroads, especially from return airways. In this way firedamp emitted from disturbed seams in adjacent strata can be extracted directly to the surface or to some safe position outbye, and the airways of the working district are not contaminated. Despite the use of firedamp drainage, considerable quantities of firedamp enter the ventilation air- stream and the concentration levels may be seen to be related to the coal production activites in the district. Figure 1 shows a typical recording of methane concentration obtained by a BM1 methanometer at a position outbye in a return gate where firedamp drainage was operating. The general rise in level throughout the working week may be seen, together with peaks occurring during production shifts and the gradual decay of emission over the weekend. In view of the fact that ventilation and firedamp drainage contribute a considerable proportion to the operating costs of the colliery, it is essential that the ventilation and firedamp drainage requirements be calculated as accurately as possible at the planning stage of the working. In the past the ventilation engineer has had to rely heavily on experience in neighbouring workings but with the development of mines in previously unworked areas there is clearly a need for a methodical approach to meet the requirements of planning. The work described in this paper represents such an approach and it is hoped that successful development and application of the method of prediction will lead to the widespread adoption of a routine procedure. The current development of a method of prediction of firedamp emission into longwall workings is based on the theoretical treatment of gas emission from coal seams proposed by Airey2 in 1971, which was based on his study of gas emission from broken coal 3 which was published in 1968. In common with other experimental methods of prediction, the method enables a calculation to be made of the total make of gas emitted from all sources of gas in the strata per tonne of mined coal.

Jan 1, 1980

By James A. Jones

The Doe Run Co. emerged from the depressed lead market of the mid-1980s as North America's leading lead producer. Doe Run was lean and mean but quickly recognized that technology had advanced while the company was held to the belt tightening slump. With the 1990s approaching, Doe Run moved quickly to update its technology and control equipment to ensure its position as an industry leader. Doe Run was formed in 1986 when Fluor Corp. and Homestake Mining Co. combined their lead-zinc-copper assets in Missouri to form a joint venture. Doe Run is now owned by Fluor Corp. A rich history of mining, milling and smelting started in Missouri in 1862 when the St. Joseph Lead Co. was founded. Subsequent acquisitions led to the formation of St. Joe Minerals, which was later purchased by Fluor Corp. Six mines, four concentrators and two smelters are presently being operated, and a secondary lead smelter was recently commissioned. The Viburnum, Buick and Fletcher operations are lead, zinc and copper flotation concentrators, while the Brushy Creek plant is set up to process high copper-low lead ores. This article looks primarily at the process control installation at the Fletcher concentrator.

Jan 1, 1991

By Thomas A. Gwynn

"A beautiful America will require the effort of government at every level, of business, and of private groups. Above all it will require the concern and action of individual citizens, alert to danger, determined to improve the quality of their surroundings, resisting blight, demanding and building beauty for themselves and their children." "Improvement of our environment" has become a cause much like "motherhood". The increased awareness of the public concerning this subject makes it most unpopular for anyone to be involved in anything that seemingly is detrimental to our environment. And this awarement goes far beyond our biggest pollution problem in America - the distribution of paper, abandoned automobiles, beer cans and other garbage by our enlightened society along every city, highway, trout stream, river and mountain in America. In fact, the greatest awarement comes because of the "sensational" reporting and writing in our various national communication media, wherein the same voting citizens who so generously distribute their refuse about the countryside are emotionally aroused and duped into transferring what is truly a national problem onto the shoulders of a few industries - notably and particularly the mineral extraction industry. Certainly mankind is more and more stumbling over his own garbage daily, a fact that is easier to sell a citizen of one of our large cities than a resident of the wide open spaces of the west. Yet even in the Rocky Mountain states, the "Land of Sky Blue Waters", the "Big Sky Country", and particularly in Salt Lake valley smog is not unknown. Pollution and littering have become problems that need to be faced squarely. In North Dakota alone it has been estimated that one section of farm land each year flows down the mighty Missouri and the greatest producer of sediment is now reported to be the highway department.

Jan 1, 1969

By George H. K. Schenck

The North American-based mining engineer needs to understand the differences that exist between mechanical mining or boring machines built on this continent and those built in Europe. The differences Ere most clearly seen when machines for large-sized openings--about 15 feet high-are considered. This report will focus on the innovations of European origin. The rock-breaking tool, drag bit, or roller cone that is efficient for a particular project is related directly to the strength of the rock involved. This strength is generally stated in reference to the rock's unconfined compressivee strength in pounds per square inch (psi) although it is well recognized that a rock's shear strength is also important. Compressive strength has been adopted because it is simple to test for and provides a convenient comparison. Table 1 relates cutter type to compressive strength and indicates the general nature of the machine innovation devel¬oped in Europe.

Jan 1, 1970

By E. D. Attanasi

Exploration for non-fuel minerals has declined since 1988 as recessionary pressures have slowed growth in the industrialized economies. By most accounts, however, 1990 expenditures were still significantly greater than the low levels experienced in the mid-1980s. The Persian Gulf crisis introduced instability in energy prices and greater uncertainty into an already cloudy economic picture. As 1990 unfolded, the US savings and loan problems spread to the commercial banking system, leading to the failure of several major US commercial banks. The Japanese stock market also suffered significant losses as Japan's Central Bank raised interest rates. The Soviet Union experienced shortages of food and other basic items. Its government faces resistance to changes leading to a market economy. Individual Soviet republics also are seeking more control of their own destiny. The cost of German reunification, in terms of the capital required to bring the east's infrastructure and industrial base to western standards, also appears to have been underestimated.

Jan 1, 1991

By J. R. Johanson

Many solids processes that look feasible on paper or even in pilot studies become disasters in full scale. Changes in solids flow characteristics from pilot scale to full scale because of larger so lids contact pressures, thermal shocks or unforeseen temperature excursions often cause full scale solids flow problems not encountered in the laboratory or pilot studies. Fortunately, proper applications of solids flow principals and solids flow property measurement at full scale conditions can anticipate the problems and thus provide an accurate basis for full scale design or existing plant modifications.

Jan 1, 1988

By Joseph T. Matoney, Okley B. Bucklen, Claude A. Goode, Philip G. Meikle

INRTODUCTION Annual coal production rose to over 1.03 billion st (931 Mt) in 1990. At the same time the number of mines producing this increased tonnage has decreased over 60% in a 30-year period, from 9230 mines in 1960.1 The great increase in production made possible through continued mechanization requires greatly improved loading facilities just to get coal away from the mine. Also the trend to combine production from more than one mine and cleaning it in a single preparation plant continues. A recent census of US coal preparation plants indicated that 310 plants were in operation.2 In addition to increased loading capacity, storage and blending facilities are more necessary both at the producer and user end. In this climate of rapidly changing technology, any written account is faced with the possibility of obsolescence before its appearance. Thus, this chapter seeks to define the common and current practice in coal loading and storage facilities with the full knowledge that this practice is an ever-moving target. FUNDAMENTALS OF COAL STORAGE Storage of coal is becoming an increasingly important part of coal handling systems at mines, particularly since the advent of the unit-train concept in transportation. In order to take advantage of reduced transportation rates on trainload shipments of coal offered by unit-train movement, operators have found that storage is an economic necessity. In unit-train practice, large predetermined quantities must be loaded in relatively short periods of time, as opposed to conventional practice where coal is loaded at a speed dependent on the production capacity of the mine and/or the cleaning capacity of the preparation plant. Clean coal storage is generally practiced in order to accomplish one, or a combination, of the following objectives: 1. To load out promptly and economically. 2. To facilitate blending in order to even out chemical and physical inconsistencies and to prepare desired products or to attain maximum product uniformity. 3. To store certain sizes whose prices and market demand fluctuate with seasons and to permit shipping in good weather. Coal storage, then, is necessary and desirable, both from production and utilization standpoints. There are, however, several undesirable aspects attendant to the storage of coal, the most important of which are oxidation and spontaneous combustion, changes in properties which may affect utilization of the coal, degradation of coal due to rehandling, and the added cost of handling and storage facilities.

Jan 1, 1991

By Alden B. Carpenter

Brines (a solution containing more than 100,000 mg/l dissolved solids) in sedimentary basins are genetically related to evaporites in one of three ways: (1) dissolution of evaporite minerals, generally halite; (2) interstitial fluids in evaporites which are expelled from their source rock during compaction; (3) incongruent alteration of hydrous evaporite minerals (carnallite). Most brines of commercial interest originate as interstitial fluids in halite-rich rocks. These fluids are initially rich in magnesium, sulfate, and potassium but evolve in composition to an Na-Ca-Cl brine during their migration to their present host rock. A particularly important reaction in this process is: 2CaCO3 + Mgt+ = CaMg(CO3)2 + Cat (1a) This reaction reduces the magnesium content of the brine and ultimately converts it to a calcium-rich brine. The loss of sulfate occurs by two mechanisms. One of these is by direct precipitation as calcium sulfate (either as gypsum or anhydrite): Ca 2+ + SO4 2- = CaSO4 (2a) Additional sulfate may be lost from the brine by sulfate reduction: S042 + 1.33CH2 + 214- = H2S + 1.33CO2 + 1.33H20 (3a) The loss of carbonate species occurs by precipitation as carbonates: H2O + C02 + Cat = CaCO3 + 2H+ (4a) The net result of reactions 3 and 4 is: Ca 2+ + SO4 2- + 1.33CH2 = H2S + CaCO3 + 0.33H2O + 0.33CO2 (5a) The loss of potassium from brines is caused by the formation of potassium aluminosilicates: 2K+ + Al2Si2O5 (OH)4 + 4SiO2 = 2H + 2KAlSi2O8 + H2O (6a) The hydrogen ions produced by this reaction dissolve carbonates: 2H+ + CaCO3 = Ca 2+ + CO2 + H2O (7a) The net result of reactions 6 and 7 is: 2K+ + CaCO3 + Al2Si205 OH)4 + 4SiO2 = Ca2 + 2KA1Si3O8 + H2O + C02 (8a) A study of brines from central Mississippi has shown that the composition of these brines is related to the interaction of pore fluids from evaporites with minerals in the enclosing sedimentary rocks.

Jan 1, 1978

By Daniel Tempelis, Tom Freeman, Eric Fordham, John Shamma, Steven Duke

The Arrowhead Tunnels in southern California are being completed by MWD under stringent groundwater in?ow limits established by the U.S. Forest Service. Pre-excavation grouting, new TBMs and a bolted, gasketed, pre-cast concrete segment initial lining are employed to control water in?ows. The effectiveness of prescribed water control measures was analyzed using conservative assumptions with the analytical techniques described by Goodman (1964), Heuer (1995), and numerical modeling. Analyses results suggest groundwater in?ows to the tunnels can be maintained well below the limits with aggressive pre-excavation grouting balanced against a reasonable rate of advance and quality erection of the initial lining system.

Jan 1, 2003

By George P. Demopoulos, Vladimiros G. Papangelakis, Dimitrios Filippou, A. J. Monhemius, G. W. Warren, E. Peters

A new method developed for the estimation of the activity of Ht in mixed sulfate solutions is described and examples of application of this method to the system H2SO4-ZnSO4-FeSO4-Fe2(SO4)3 from 298 to 473 K are offered. The method makes use of an "extended Debye-Hiickel" type of equation that was originally put forth by Das for pure H2SO4 solutions at ambient temperature. The treatment of mixed sulfate solutions was made possible by combining that equation of Das with a speciation algorithm which calculates the abundance of all species formed. The developed method, which also takes into account ionic strength and temperature effects, was used to generate hydrogen ion activity and speciation data for all possible acid/metal sulfate pairs of the system H2SO4-ZnSO4-FeSO4-Fe2(SO4)3. Finally, under the light of the reported data, specific examples of hydrometallurgical reaction systems are analyzed in terms of thermodynamics or kinetics. In particular, the systems discussed are: hydrometallurgical precipitation of hematite, solvent extraction of Fe(III), acid leaching of zinc ferrite, and oxidation of Fe(II) to Fe(III) by O2(aq).

Jan 1, 1993

It is widely accepted that particles stabilize flotation froths and that stable froths result in improved flotation performance. Predicting the effect of particle addition on froth stability is, however, challenging. Furthermore, there is currently no technique that allows the prediction of the effect of different flotation reagents on froth stability, without carrying out froth stability experiments.

By E. Ilgar

Biodegradation of spodumene by Asnergillus niger has been investigated. This organism oxidizes sucrose to citric and oxalic acids (in approximately 50-sot proportions) which degrade the spodumene mineral. The kinetic effects of leach variables on the dissolution of lithium were determined. The maximum theoretically attainable rate of lithium extraction was calculated for the effect of pulp density, to be V : 3.01 x 10 kg m sand the corresponding constant value, K = 12.47% pulp density. The apparent activation energy of lithium extraction vas found to be ^E = 20.3 kJ and frequency factor A = 5.66 x 10 s for S-spodumene leaching by synthetic -3 citric and oxalic acids (each in 0.05 kmol m-3 concentrations).

Jan 1, 1989

By N. I. Fedunets

The development of variousworks on automatising of operational processes at coal¬extractive and coal-mining enterprises introduces an ever growing necessity to carry out investigations in the wide range of problems concerning the possibitity of joint functioning of different levels, which seems impossible without the use of integrated systems of passing on and prossessing the information on the basis of modern calculating machines and other means of automation. This view on the problem of automation of the enterprise operation presupposes that the structure of automated operational dispatcher control (AODC) should be very closely connected with that of integrated data processing system! In this case the AODC structure from the point of view of automation of its functions (or operations), i.e. from the point of view of informational techniques coinsides in general with the structure of dispersed information and calculating network (ICN), realizing the passing on and processing of the information as well as solving the functional tasks on the basis of local calculating networks of electrical calculating machines with correspond to different levels of AODC and located with regard to productional hierarchy of operational dispatcher control (ODC). In this approach however the use of dispersed, ICN gives opportunity to. realize the possibility of action only with realisation on the CM of algorithmic' task of ODC, when a dispatcher 'is the lastto make a final decision.. At the mining enterprises it's rather difficult for a dispatcher to make a final decision because of the great variaty of productional situations, the presence of contradictions and a number of other subjective factors which often lead to the dispatcher's mistaks causing great material losses of the enterprise. Hence the necessity arises to automize and formalize making a decision and including the expert systems (ES) into the ontour of AODC, which enables the dispatcher 2to get a neeessary advice in different situations, especially in case ofemergency on the basis of establishing the mechanism of logical layout of non-formalized data base (DB) procedures relying upon the background knowledge and experience of experts. The presently presented in this paper theory of establishing the. ISAODC on the basis of dispersed ICN and expert systems is aimed at trasformation ofoperational' tasks of the higher level into the technological ones, at solving the tasks of diagnostics and forseeing of the process of production, with a dispatcher getting an opportunity of making qualitative and effective decision concerrning the choice of operational impacts in actual time on the basis of generalization the realisation of presented conception must, as has been already mentioned, be accomplished only on the basis of the foundatoin of the united dispersed informational - calculating network of electrical calculating machines.. This includes ICN which would be operating in . different operational contours. . From what has just been said it followsthat the ISAODC Structure will conside with that of DICN (in our case) and hence all the problems of ISAODC structure would be regarded as the questions of DICN.

Jan 1, 1992

"In this review, the sintering process is first described and analyzed to identify the key factors affecting the structure and quality of iron ore sinter. Under fixed sintering conditions, the granulation efficiency, nucleus stability and primary sinter melt volume and properties of the iron ore are considered to have significant influence on the sinter structure and quality. Discussion is then focused on the effects of the chemical, physical and mineralogical characteristics of the iron ore on these key factors, and the consequences for sinter quality.IntroductionSintering is the most economic and widely used agglomeration process to prepare iron ore fines for blastfurnace use. In modern blast furnaces, particularly in East Asia, iron ore sinter typically constitutes more than 70% of blast-furnace ferrous feed. High sinter quality and efficient sinter production are thus required both to withstand extreme operating conditions and maintain the productivity of modern blast furnaces. At the same time, due to the increasing depletion of high-grade iron ore resources from large deposits, iron ore producers are moving toward developing an increasing number of deposits of much smaller sizes to maintain current production levels. It is therefore imperative for iron ore producers to develop long-term strategies to maintain the quality and consistency of the iron ore fines they are producing while exploiting these smaller, complex deposits. The iron grade, gangue minerals present, overall mineralogy as well as physical characteristics of iron ore fines being mined from these different deposits vary considerably. Overall, ores now have highly complex mineralogy, are becoming more porous and friable, and contain increasing amounts of gangue minerals, which will have important implications for the sintering process and sinter quality.Blending is one of the most effective options being explored by iron ore producers to deal with multiple small complex deposits. This allows the iron ore producers to reduce the number of products and take full advantage of the unique characteristics of each individual deposit to achieve long-term product consistency while increasing production. Blending is also a common practice in sinter plants as it is almost impossible to produce from one single ore a high-performance sinter mixture with the required processing characteristics. A typical sinter mixture used in Japanese steel mills (Nakano and Okazaki, 2007; Matsumura et al., 2013) often contains five or more ores to achieve balanced sinter quality and productivity with relatively low cost of raw materials."

Jan 1, 2015

By R. S. Sheeta, C. J. Bise

The search for a more effective means of coping with methane liberation has resulted in the expanded use of seam degasification. Its advantages are measured not only in reducing the hazards due to methane, but also in producing a marketable commodity, the gas itself. However, the success of a methane drainage system is the culmination of many complex factors, the most important being the coal seam permeability. The two most popular drainage techniques used in mining today are the vertically stimulated borehole method and the in-seam horizontal borehole method. The objective of this paper is to determine the permeability range in which the selection of the degasification technique is based primarily on equipment and economic analysis. A discussion of the equipment involved will be incorporated into examples evaluated by the Pennsylvania State University coal methane simulation model.

Jan 1, 1990

By J. S. Whatley

The properties, origin and industrial uses of kaolin clay are briefly reviewed. The general waterwashed beneficiation process is described. Yost aspects of filtration and solids-liquid separation as practiced in the kaolin industry are mentioned along with devices that are currently in the developmental stage. The paper focuses heavily on the well known art of rotary vacuum filtration, including general construction and operating details. Devices under investigation that might be used to mechanically or electrically dewater clay slurries to higher cake solids levels than can be achieved with rotary vacuum filters are described briefly.

Jan 1, 1986

By A. J. Hendron, L. L. Oriard

INTRODUCTION Controlled blasting is used at some time during most civil engineering projects where there is rock excavation. Controlled blasting is often necessary because the blasting must take place in the near proximity of adjacent structures. In other instances, the blasting is controlled because a smooth perimeter is desired to minimize rock support and overbreak. The construction of tunnels and shafts for subways, rock excavations for foundations and the excavation of road cuts for interstate highways, sometimes require blasting operations which must be conducted in an urban environment. Unfortunately, blasting operations produce unwanted sounds and vibration along with their beneficial effects. Thus, in the writing of specifications for blasting in an urban environment, potential damage to adjacent structures by ground vibrations must be considered, possible damage to windows from airblasts must be considered, potential damage from fly rock must be considered, and the discomfort to people from ground vibrations, airblast, and noise must be taken into account. The contractor or the owner's engineer is faced with determining the maximum weight of explosives which may be detonated without damage to structures on adjacent property. If the weight of explosive is overestimated, the resulting damage to adjacent structures may result in costly losses. But, if the engineer or contractor is too conservative, and the weight of explosive becomes too restrictive, progress of the project may be curtailed and the cost of excavation will increase accordingly. The potential for damaging adjacent property is becoming more important in construction operations today. In the past, the plaintiff had to prove negligence in some states in order

Jan 1, 1997

By E. R. DeMen

In late 1965 General Mills announced the availability of a new liquid ion exchange reagent, LIX®-64, for the recovery of copper from various solutions, such as dump leach liquors. Acceptance of this material by the copper industry has been gratifying. A number of pilot plants have been operated, and at this writing there are four commercial plants either in operation or under construction. The properties and operating characteristics of this reagent have been described in previous papers.1,2 LIX-64 is quite effective and selective for copper extractions although partially limited in pH ranges, losing extraction efficiency as the acidity of the feed solution increases to below pH 1.0. Also, the LIX-64 content in the kerosine carrier was limited to about 10 volume percent (except for special cases) because of rapidly decreasing phase disengagement rates above this content. This in turn led to large plant capital costs, as the organic flow rates had to be in- creased (rather than LIX-64 content) to extract the copper from high content liquors. This was true in all circuits where the feed copper content ran above 2.0 g/l copper. A reagent was needed which would extract copper from more acidic liquors (or higher copper content liquors) and which exhibited improved phase disengagement characteristics with reagent contents up to 30 volume percent. General Mills is pleased to announce the availability in commercial quantities of a new and improved reagent, L+-64~. This reagent broadens the pH range in which copper can be extracted, and exhibits superior phase disengagement characteristics. The improvement in the reagent has been noted in laboratory circuits, as well as pilot plant runs and commercial operations.

Jan 1, 1970