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By I. J. Kotzé, R. T. Jones

Conventional PGM matte smelting requires the presence of a certain quantity of base metal sulphides in order to collect the platinum group metals in a molten sulphidic matte phase in the furnace. Furthermore, the quantity of chromium oxide in the feed materials is controlled in order to avoid the build-up of high-melting chromite spinels in the furnace. Mintek has developed a process for smelting difficult PGM-containing feed materials that contain low amounts of sulphur and/or high amounts of chromium oxide. A DC arc furnace is used to provide the appropriate conditions to generate an iron alloy that collects PGMs very effectively, leaving extremely low residual quantities of PGMs in the slag. Various feed materials have been treated successfully in furnace campaigns running at power levels up to 1.5 MW. The longest of these campaigns was run continuously for more than four months, treating more than two thousand tons of materials such as low-grade concentrates, revert tailings, and converter slag. The campaigns demonstrated the robustness and versatility of the process, and proved that it is possible to sustainably produce a PGM-containing alloy and discardable slags containing an average of less than 1.4 g/t of PGMs over the entire campaign. Keywords: DC arc, smelting, furnace, platinum, PGM, revert tailings, converter slag, ConRoast

Jan 1, 2004

By D. van der Westhuizen, H. Krieg, M. Kruger

In the field of Fischer-Tropsch synthesis catalysts, cobalt, platinum, and aluminium are the primary metal constituents of the conventionally used cobalt catalyst. While platinum recovery remains a focal point in this field, a recent endeavour by a South African company emerged, which aimed to recover cobalt and aluminium from spent Fischer-Tropsch synthesis catalysts for potential use in the agricultural sector. This study aimed to optimally separate cobalt and aluminium from spent Fischer-Tropsch synthesis catalyst for this purpose. It further leverages the OLI database to predict metal speciation during solvent extraction to aid with experimental planning. Shake-out tests were conducted to determine optimal separation. conditions, which were validated using three distinct methods: (i) evaluating the experimental error, (ii) comparing results with similar research, and (iii) validating results against the OLI database. The investigation revealed the pivotal role of the aqueous pH yielding effective separation at pH 3.13 ([H2SO4] = 2.5 × 10−4 M) when using 20 vol.% CYANEX 272 and 50 mol.% pre-neutralisation. Effective cobalt scrubbing was achieved with 50 g/L Al at pH 2.8, while successful stripping required 1 M H2SO4. Competitive interactions between complexing aluminium and cobalt species were observed when contacting with CYANEX 272 at a pH < 4. Equipment design analysis for a targeted separation efficiency of 87% dictated the necessity of two mixer stages and a settler measuring 1.5 m × 1.5 m × 6.0 m (height × width × length). This settler would ensure sufficient residence time for gravity separation at a flow rate of 10 m3/h.

May 27, 2025

By M. Bryson, G. Marap, M. Ntlhane, M. D. Hlahane

This study investigated flotation of phosphate from a low-medium grade 8-12% P2O5, 65-73% SiO2 sedimentary phosphate ore from Kropz Elandsfontein (herein referred to as Elandsfontein) in South Africa. Quantitative evaluation of minerals by scanning electron microscopy (QEMSCAN) was used to determine apatite grain size distribution, liberation and mineral association in the F2 horizon sample. The mineralogy indicated that apatite was liberated and for the Elandsfontein plant to operate at the design throughput, the flotation feed has to be milled to a coarse grind ranging between 300 μm and 425 μm. Reverse flotation process routes using varying reagent dosages, and flotation feed top sizes that could possibly yield a final product of 31% P2O5,10% SiO2 at a reasonable +70% P2O5 recovery were investigated. Based on the results, a split circuit of coarse (-300+212μm) flotation and fine (-212+20μm) flotation, was mostly preferred as compared to treating the whole ore. A final combined concentrate of 31% P2O5 and 10% SiO2 with P2O5 recovery of 84% could be produced from the reverse split circuit. The robustness of reverse flotation for both coarse and fine fractions was further investigated. Reverse flotation of the fines fraction was found to be robust and produced a final product of 31% P2O5. It was however more challenging to achieve the required product grade and recoveries on the coarser fraction (-425+212μm), suggesting that reverse circuit was not adequately robust at fractions coarser than 300μm. Keywords: Phosphate, sedimentary, reverse flotation, particle size

Jan 1, 2020

By M. D. Prendergast

Research into the ferrous metallurgy of Rhodesian Iron Age societies M. D. PRENDERGAST (Visitor) Iron-working was a widespread economic activity in Iron Age Rhodesia, and merits historical and metallurgical investigation. However, the research done so far has been incidental and poorly disseminated. This paper reviews the available evidence and the ways in which it can be interpreted by archaeologists and historical metallurgists. Particular attention is paid to smelting techniques and current metallurgical research, and brief suggestions are made for future research. v074n06p254.pdf

Jan 1, 1974

By C. K. Chabedi

"This paper discusses the difficulties associated with the potential exploitation of the deep multi-seam resources east of the Daarby fault in the Waterberg coalfield. The resources occur at a depth greater than 250 m and the thickness of the coal is roughly 110 m, but the top 50 m comprises coal intercalated with shale and the bottom 60 m contains five seams with sandstone and shale partings. Various factors affecting multiple seam mining at these great depths are discussed with reference to lessons learned from local and international experience on multi-seam mining. Field geological and geotechnical data was utilized to assess the stability of the roof of the seams. There is no specific rock mass rating for the Waterberg area, therefore approximate coal mine roof rating (CMRR) values were used to propose appropriate support strategies. Analysis of Multiple Seam Stability (AMSS) was used to analyse the strength of the parting or interburden between the various seams, the mining sequence, and the interaction between the various seams.The research indicated that it is possible to mine seams with a low CMRR at high mining rates using longwall mining, although support for gateroads is expected to be expensive, time-consuming and onerous to install, and will impact gateroad development rates. It will not be possible to simultaneously mine zones in close proximity and failure of the interburden is predicted, thus dangerous mining conditions are anticipated. However, it will be possible to mine just two of the eleven zones using longwall mining. IntroductionThis paper discusses the difficulties associated with the potential exploitation of the deep multi-seam resources east of the Daarby fault in the Waterberg coalfield using bord and pillar and longwall mining. Figure 1 illustrates the location of the Waterberg coalfield relative to other coalfields in South Africa, while Figure 2 shows the areas containing deep and shallow resources. The Waterberg resources are expected to contribute to South Africa’s future energy requirements, and are currently exploited at the Grootegeluk open pit mine. Grootegeluk produces coal mainly for a power station, with the higher quality product supplied as metallurgical coal. The deposit is technically unique and challenging, being a multi-seam coal deposit with a total of 12 seams over a thickness of 110 m as shown in Figure 3, including Zone 5. There is currently limited knowledge on the multi-seam mining of the deep Waterberg resources. Multi-seam mining utilizing the bord and pillar method has been practised in South Africa before, but at a depth of less than 100 m in the Witbank coalfields. Multi-seam mining in thin seams has also been performed in the Natal coalfields at a depth of less than 160 m, but mostly using bord and pillar mining and secondary mining (partial pillar extraction)."

Jan 1, 2016

Jigging is a process of particle stratification in which the particle rearrangement results from an alternate expansion and compaction of a bed of particles by a pulsating fluid flow. The rearrangement results in layers of particles that are arranged by increasing density from top to bottom of the bed. The particles, in addition to the vertically expanded and compacted bed motion, move continuously, horizontally across the supporting screen and helped and influenced by the feed material that is introduced at one end. Following the particle stratification, the particle bed is physically ?cut? at a desired horizontal particle density plane to separate the desired product from the less dense gangue material. The issue of correct pulse characteristics (shape, amplitude and frequency) for the optimal metallurgical stratification of air pulsating jigs has been the subject of much discussion over the years. The accuracy of the dissymmetric stratification depends on the control parameters and the mechanical condition of specific equipment used. This paper will touch on some of the control and mechanical parameters affecting the separation efficiency.

Jan 1, 2010

Actual observations of rockburst damage, together with some theoretical considerations, strongly suggest that conventional approaches to the design of tunnel support are inappropriate where there is a significant seismic risk. The present widely used support systems, which are based on stiff, fully grouted re-bars, are inadequate where rock displacement velocities exceed 1 m/s. It is shown by means of a simple conceptual model that yielding of the support elements is essential to ensure their survival when they are subject to the high strain rates typical of severe rockbursts. The model proposes that the total load in the element is an impulsive tensile force imposed and sustained by a single &apos;tributary&apos; block ejected from the tunnel wall. The stability of the system is determined from a comparison of the kinetic energy developed by the block with the energy of deformation absorbed by a grouted steel tendon. A novel test procedure was developed for the validation of this approach, and for an examination of the energy-absorbing capacity of stiff and yielding tendons. The results of an initial series of tests showed that the recently developed cone-bolt is an effective yielding device. It absorbs twenty times more impulsive-load energy than is consumed by the complete fracture of grouted re-bar of equivalent strength, and it remains totally unscathed. Importantly, the results demonstrate that the ejection model is not merely an explanatory concept, but can be used as a representative and valid design method.

Jan 1, 1994

By J. Arzuúa, U. Castro-Filgueira, L. R. Alejano, F. Malan

"Pillar design for underground mining is typically done using empirical formulae or numerical modelling. Practical experience and recent literature, nevertheless, illustrate the shortcomings of these design approaches. Ongoing monitoring of pillars is therefore recommended to minimize the risk associated with these designs.In a mine where a large number of pillars are cut, different pillar strengths can be expected owing to variations in rock mass strength from area to area. This problem is compounded by the fact that in mining environments the pillars are not always cut according to the prescribed dimensions. Although the original design using either empirical methods or modelling may predict stable pillars, unstable pillars will be encountered in reality. Very conservative designs with large factors of safety may circumvent this problem, but this approach is uneconomical.A possible solution to localized stability problems may be to enhance the strength of a few unstable pillars. It may even be hypothesized that reinforcing a few critical pillars may prevent ‘pillar runs’ on a much larger scale. Rockbolting, strapping of pillars, and pillar shotcreting have occasionally been used in the past as possible solutions. It appears that these have not been successful in all cases and large collapses have occurred in spite of the pillar remedial work.The authors investigated the strapping of pillars by conducting laboratory tests on cabled rock specimens. The results were qualitatively compared to actual attempts of pillar reinforcement available in the literature, as well as additional observations in an old haematite roomand- pillar mine in Spain. Based on these results, the value of steel cabling and mesh wrapped around pillars to improve stability is demonstrated. Some cases where this approach will not be successful are also discussed."

Jan 1, 2017

By E Matinde, M. Mnisi, I. C. Thobadi, W. Clark, J. D. Steenkamp

Pyrometallurgical smelters utilise tap-holes, through which liquid metal, matte and/or slag are tapped at regular intervals. However, tap-hole failures can have a devastating impact on smelters, which includes loss of equipment, human life and business interruptions. Contributing factors to tap-hole failures include poor and/or incorrect refractory material selection, including tap-hole clays. The functions of tap-hole clays in smelters include their ability to be extruded and drilled with ease at the end and beginning of a tap, and their ability to resist chemical wear due to molten metal and slag during tapping. Mintek is currently developing methods of evaluating properties of tap-hole clays with a specific focus on workability, and wear mechanisms of clays due to ferrochrome alloy and slag. Of particular interest to this study was the characterisation of various tap-hole clays. This paper evaluates the chemical and phase chemical properties of three different tap-hole clays. The bulk chemical composition of the tap-hole clays was determined by inductively coupled plasma optical emission spectroscopy, proximate analyses and combustion methods. The bulk phase compositions and specific phase chemical compositions were studied using quantitative X-ray diffraction, scanning electron microscope and electron probe microanalyses techniques. Keywords: Tap-hole clay, chemical analyses, phase chemical analyses, ferrochrome

Jan 1, 2020

By A. Koursaris, Y. N. Turan

This paper reports the results of a literature review carried out on nitrogen-alloyed austenitic stainless steels and their properties. It was found that a large volume of work has been carried out on the subject, particularly with regard to the more common stainless steels such as types 304 and 316. No work appears to have been conducted on the highly alloyed steels such as type 310S. Nitrogen has been found to increase the stability of the austenite in stainless steels and to impart significant improvements in the mechanical and corrosion properties of these alloys. Importantly, nitrogen appears to increase both the ductility and the strength of austenitic stainless steels over a wide range of temperatures.

Jan 1, 1993

By P. C. Pistorius, D. Kruger, Y. Kacar

Because of its superior properties, stainless steel has been widely used for many applications. Nonmetallic inclusions can influence the quality of stainless steel products. A set of samples was used to track the response of inclusion composition during processing of a heat of titanium-bearing 18% chromium steel, from deoxidation after decarburization, to the solidified slab. The oxide inclusions responded as expected to additions of deoxidizers and calcium treatment, changing from silica to alumina and spinels, and then to calcium aluminates. The samples confirmed that titanium nitride can nucleate on liquid calcium aluminate during steel solidification.

Aug 1, 2021

By A. Koursaris, Y. N. Turan

A series of experiments was caried out in a vacuum-induction furnace to investigate the solubility of nitrogen in stainless steel type 3100S. Melts were made under constant and variable partial pressures of nitrogen so that the absorption of nitrogen from the atmosphere could be examined. Additions of nitrogenized ferochromium were made to give high nitrogen contents in the steel. Nitrogen contents of up to 0,16 wt per cent were obtained under gaseous atmospheres. With additions of nitrogenized ferochromium, nitrogen contents of up to 0,525 wt per cent were obtained. Comparisons of the later value with existing data indicate that the equilibrium concentration of nitrogen was reached for the experimental conditions used.

Jan 1, 1992

By T. Uysal

Various morphological parameters that affect the flotation recovery of sphalerite were modelled and optimized using the response surface method (RSM). The effects of roughness value, shape factor, and collector concentration were investigated using the central composite full design method. The results were evaluated by analysis of variance. The optimum roughening time was found to be 25minutes, the optimum roughness value was 2.9071 μm, and the optimum collector concentrationwas 0.001 M. Using these values, a flotation recovery of 98.01% was obtained. Similarly, in shapefactor studies, the optimum grinding time was 15 seconds, the optimum roundness value 0.7421, and the optimum collector concentration 0.0009 M, which resulted in a flotation recovery of 94.30%. The average error between the optimization results and the experimental results was estimated to be less than 6%, and the R2 values were greater than 90%. The study shows that RSM can be effectively applied in finding the economic optimum condition for obtaining maximum flotation recovery with minimum reagent consumption.

Sep 6, 2023

By R. Kuyvenhoven, A. Parbhakar-Fox, X. Prieto, J. Quevedo, L. V. Danyushevsky

This paper presents the results of a study focussed on determining the distribution of cobalt in different types of pyrite of the La Estrella IOCG deposit in Chile. In the IOCG mineral deposits, where copper is the main product, the quantification and distribution of cobalt is required to correctly define the technical and economic viability of recovering cobalt as a by-product. In the La Estrella mineral deposit, seven alteration and mineralisation events were recognised through both optical and automated electronic mineralogical analysis. Of these seven events, five different types of pyrites were identified, each with unique characteristics of the pyrite crystals. Through advanced elemental analysis of these five types of pyrites, it was determined that the concentration and distribution of cobalt within the pyrite crystal is dependent on the mineralisation event. The results indicate high cobalt concentrations in the early pyrite mineralisation events, associated with relatively fine pyrite grains, and cobalt generally occurring in a solid form in the pyrite core. The late pyrite mineralisation event exhibits the lowest concentrations of cobalt, with cobalt predominantly present along the outer periphery of the pyrite. These results are relevant from a metallurgical point of view because the preferential location of cobalt within the pyrite crystal will influence the maximum metallurgical recovery of cobalt. For this, a cobaltiferous pyrite concentrate must be formed which, according to the characteristics of pyrite, must be processed with the optimal solubilisation method. The overall objective is to ensure both good cobalt recovery and a high concentration of cobalt in the leach solution resulting from pyrite leaching. Keywords: Cobalt, pyrite, IOCG, copper, metallurgical recovery, solubilisation, Chile

Jan 1, 2020

By M. E. C. Snyman, N. Naudé

"Coal fines produced during processing are difficult to dewater and result in a lower quality product and consequent lower value. A South African coal mine experiences severe difficulties with belt filter dewatering operations due to the presence of fines reporting from the thickener underflows. Plant 2 currently handles super-fine particles of size -34 µm and has low belt filter efficiency: excessive moisture retention lowers the product quality and strains downstream processing. It was necessary to determine an alternative method for dewatering these fines. Blending of fine material with coarser material was proposed as a solution. The effect of coal particle size and layering during ultrafines belt filter dewatering was evaluated using various blends of the fine Plant 2 material with coarser Plant 1 material. The best layering arrangement of the two materials and its optimum blend required to achieve reduced filter cake moisture content was determined in practise using a vacuum filter to simulate belt filtration. A blend of the two materials gave improved dewatering efficiency for the belt filters compared with that of the Plant 2 material alone. The best layering configuration was with Plant 2 material at the bottom and Plant 1 material on top. The optimum blend for industrial applications comprised 48% fines from Plant 2. IntroductionFines are produced during the processing of coal. It is estimated that 2 to 3% of run-ofmine coal reports to the ultrafine portion (-100 µm) (le Roux, 2005). The particle size of coal is inversely proportional to the amount of water adsorption, so smaller particles adsorb more moisture. Moisture removal requires either mechanical processes or thermal drying: mechanical processes are less expensive, but the fines still have high moisture retention. Discarding of fines leads to economic losses, so it is essential that they be dewatered so that they can then be sold as a product: fines need to be treated for both resource management and conservation reasons (Kenney, 1994). Removal of free surface moisture from ultrafine coal particles using a belt filter therefore remains a process that needs to be continuously improved. Ultrafine coal originating from a thickener underflow is known to be difficult to dewater owing to factors such as filter cloth blockage and moisture retention due to clogging. Mixing of finer and coarser materials has been proposed to deliver better dewatering efficiency and improved the quality of the recycled water (Kenney, 1994)."

Mar 1, 2019

By J. N. Van der Merwe

Following the Coalbrook disaster in 1960, research into coal pillar strength resulted in the adoption of the concept of a safety factor for the design of stable pillars in South African coal mining. At the time when the original statistical analysis was performed by Salamon and Munro in the early 1960s, 27 cases of failed pillar workings were considered suitable for inclusion in the database of failed pillars. Pillar failure did not stop after the introduction of the safety factor formula by Salamon and Munro (1967). In the ensuing years, pillars that were created before the application of the formula deteriorated and later failed, as did ones that were created after the introduction of the formula. This means that over time, the database of failed pillar cases increased in size, allowing ever more reliable analyses to be performed. The number of failed cases in the database had grown from the original 27 in the 1960s to 86 by 2011. All the failed cases are contained in the updated database. The database of stable pillars, which is also used in the derivation of strength formulae, has now been extended from 125 to 337 cases. The new database of intact pillar cases is more complete as it bridges the time gap between the Salamon and Munro (1967) and the Van der Merwe (2006) databases. The original requirements for inclusion into the database were satisfied in the compilation of this latest collection. The characteristics of the original database of intact pillars did not change in a meaningful way. The mining depth and pillar dimensions of the new database are largely as they were in the original database. Time-related trends with regard to pillar dimensions and depth of mining could not be found, indicating that the geometrical parameters of coal mining in South Africa have not changed meaningfully in approximately a century of mining. The characteristics of cases in the updated database of failed pillars does not differ substantially from the one published by Van der Merwe (2006). The same difference between that database and the original Salamon and Munro database, namely that the average safety factor of the failed cases had increased dramatically, from 1.0 to 1.5, is still apparent. This may be due to the inclusion of more failures from specific areas that exhibit a disproportionate number of failures at higher safety factors. These areas are the Vaal Basin, Klip River, and Free State coalfields. The new database confirms yet again that there is no correlation between the safety factors of failed pillars and their time of failure. The safety factor on its own is thus not a reliable predictor of longterm stability of pillars. Keywords coal pillar, stable pillar cases, pillar collapse, pillar data base.

Nov 1, 2013

The case for national research in mineral processing PRESIDENTIAL ADDRESS given by R. E. Robinson*, Ph.D., B.Sc. (Eng.) (Wits.) Some of you have only raised your eyebrows, some have made tactful comments, and a few of you have been fairly outspoken, but all of you in industry are concerned at the high level of State expenditure by bodies such as the National Institute for Metallurgy. The case for a national research organization in mineral processing is not clear-cut and in fairness I must present both cases - for and against. Competition for student members Each year the South African Institute of Mining and Metallurgy offers a prize (or prizes should the entries warrant it) of up to Rl00 for the best paper or dissertation on a topic appropriate to the interests of the Institute.

Jan 10, 1975

By H. Jiang, W. Wang, Y. Zhao, J. Qiao, C. Duan

DEM simulations were used in this research to study the screening process of a novel variable amplitude equal thickness vibration screen (VAETVS). The response regularity of mass distribution and granular moving velocity at the different screen panels to feed rate was investigated and the predictive model for the unit area processing load was proposed. The influence of aperture size, the size variance, and the opening ratio on the mass passing-distribution and overall screening performance, respectively, were revealed. The results showed that the response model of the unit area load Ф to the feed rate Q can be concluded as Ф∝0.324×Q. The moving velocity of particles also showed a positive relevance to the feed rate, besides which the passing rate of fine-grained material at the feed end was negatively related to the aperture size, while the case was reversed in the feed end. The increase of aperture variance AV enhanced the passing ability of small particles at the feed end,and reduced the misplaced ratio of the large particles at the discharge end. A better screening efficiency can be obtained when the average aperture size of the entire sieve is 7.5 mm, with the aperture variance of 1 mm between the adjacent panels. When the combination of the opening ratio is 35-35-40, a better screening effect can be achieved. Keywords: Equal thickness screening, DEM, particulate velocity, mass distribution regulation

Jan 1, 2020

By C. van Loggerenbergt, P. E. Ventert

A strong incentive exists for the coal-preparation engineer to improve plant efficiency by modifying circuits and upgrading process equipment, since these result in lower production costs and more valuable plant products. At the Grootegeluk Coal Mine, it was found that the overall plant efficiency could be improved by modifications to the dense-medium circuits, the installation of additional process equipment for the recovery of fine coal, and improvement of the fine-material processing circuit. Apart from these modifications, there is still potential to increase the plant efficiency, particularly in the utilization of plant waste, the recovery of slimes, and even the improvement of cycloning performance as a result of new cyclone design. This paper points to the potential wealth locked up in existing coal-preparation plants, and shows how the coal-preparation engineer, with new technology at his disposal, can unlock this wealth.

Jan 1, 1992

By G. A. Bezuidenhout, J. P. T. Kapusta, D. K. Chibwe

"Peirce-Smith converters (PSCs) are extensively used in the copper, nickel, and platinum group metals industries to remove iron and sulphur from the molten matte phase. This technology has not changed significantly since its inception in the early 20th century. The typical converting operation involves lateral purging of air/oxygen-enriched air into molten matte through a bank of tuyeres. This blowing operation occurs at low air pressure from the blowers, and the induced bubbling regime is considered inefficient from both a process and an energy utilization perspective. Inherent drawbacks include recurrent tuyere blockage, inevitable tuyere punching operation to clear airways, and low oxygen efficiency as a result of substantial air losses due to leakages.Investigations in the 1980s demonstrated1 that jetting into Cu and Ni converters could reduce or eliminate some of the process difficulties. In spite of these findings, very little progress has been made in the application of these concepts for converting of non-ferrous melts on a commercial scale.As part of its operational improvement and energy reduction initiative, Western Platinum embarked on a full-scale industrial evaluation of generating a jetting regime by using sonic injection. Prior to full-scale industrial evaluation, a numerical assessment was conducted to ascertain the feasibility of implementing sonic injection on Lonmin converters. The work included flow characterization at high injection pressures achieving sonic velocity at the tuyere exit. The 2D and 3D simulations of the three-phase system were carried out using the volume of fluid (VOF) and realizable k- e turbulence models to account for the multiphase and turbulence nature of the flow, respectively. These models were applied using the commercial CFD numerical code FLUENT.This paper discusses the key findings regard ing understanding of gas plume extension, velocity distribution, shear wall stress analysis, and phase distribution characteristics in the system. Plant trials are also discussed with reference to the commercial aspects of a fullscale implementation of sonic injection in the smelter."

Jan 1, 2014