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This report summarizes the work performed by the Bureau of Mines on the development of analytical procedures for determining metallic and interstitial impurities in high-purity tungsten. Fourteen published methods and seven unpublished methods are briefly described. Carbon, hydrogen, nitrogen, and oxygen, in microgram to higher quantity levels, can be determined by several methods. Trace levels of 29 metallic impurity elements can be determined by optical spectrography, X-ray spectrography, and other instrumental methods.

Jan 1, 1968

By Miklos D. G. Salamon, Jim M. Galvin, Bruce K. Hebblewhite

A series of mine design accidents in the late 1980s resulted in a major research program at the University of New South Wales, Australia, aimed at developing pillar and mine design guidelines. A database of both failed and unfailed Australian underground coal mine pillar case studies was compiled. A procedure was developed to enable the effective width of rectangular pillars to be taken into account. The database was analyzed statistically using the maximum likelihood method, both independently and as a combined data set with the more extensive South African database. Probabilities of failure were correlated to factors of safety. It was found that there was less than a 4% variance in pillar design extraction ratios resulting from each of these approaches. There is a remarkable consistency between the design formulas developed from back-analysis of the two separate national pillar databases containing many different coal seams and geological environments.

Jan 5, 1999

By Floyd G. Anderson

Owing to the rapid growth of the perlite industry in recent years, the Bureau of Mines has received numerous requests for information relative to the possible harmful effects of breathing dust resulting from the processing and use of perlite. As published information on the composition of perlite is rather meager, consisting chiefly of conventional chemical analyses, samples of crude and expanded perlite from 9 deposits in 6 Western States were studied. Crude perlite ores were examined petrographically and analyzed by chemical, spectrographic, and X-ray-diffraction methods. Sized crude and expanded perlites were analyzed chemically for total free and combined silica content.

Jan 1, 1956

To reduce operator exposure to drilling noise from roof bolting machines. Background Noise-induced hearing loss (NIHL) is a prevalent occupational illness in the United States. Studies indicate that 70%?90% of miners have NIHL significant enough to be classified as a hearing disability. Mine Safety and Health Administration studies indicated that roof bolting machine operators are among those overexposed to noise. Field studies support the premise that, on average, drilling is the loudest noise source to which a roof bolting machine operator is typically exposed and contributes greatly to the operator?s noise exposure. The National Institute for Occupational Safety and Health (NIOSH) has further determined that the drill steel and chuck radiate a significant amount of noise during drilling. To address this noise hazard, NIOSH developed a collapsible drill steel enclosure (CDSE) to encapsulate the drill steel during the drilling portion of the roof bolting machine duty cycle. In addition, NIOSH is collaborating with J. H. Fletcher & Co. in the continued development of a CDSE.

Sep 1, 2008

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

B 6 Listing The following is a listing of the Mine Evacuation Simulation Program

Jan 1, 1976

By Lloyd A. Morley, Robert Stefanko

A major difficulty encountered during the research was that nation¬al countries (almost world-wide) are in the process of revising their electrical hazard reduction standards. Their principal goal is to align their standards with the International Electrotechnical Commission (IEC) Recommendations Publication Series 79. (31-37) Additionally, CENELEC is requiring all Common Market countries to harmonize their standards. (85) However in the coal mining industry some hazard re¬duction techniques are not being accepted because some systems may not be applicable. Therefore, past literature might not directly relate a country's current feeling about explosion-proof standards. An authority in the United Kingdom (which has been a leader in hazard reduction mainly through work at the Safety in Mines Research Establishment) brought up an additional point. (15) He hopes that since revising British standards BS229 into BS4683, with the intention of corresponding with the IEC 79 series, the recent CENELEC harmoni¬zation process will also follow IEC. (8, 9, 10) The past trend in other major Common Market countries prior to CENELEC's requirement results in the authors' speculation that the standards will be pattern¬ed after the IEC Publications. (5,17,60,84,102) Several letters were sent to the East Block countries but, disa¬ppointingly, replies were dispatched only from the USSR and Poland. Recent Polish standards (1973) were received, and a very close match to the IEC Publications has been noted. (76,77) Because of their economic community, it is extremely logical to assume that the East Block stand¬ards are therefore in concurrence with the IEC. Japanese specifications also appear to be compatible with the IEC Recommendations. (42,43)

Jan 1, 1974

By Edward Thimons, William A. Hertbrink

The effect of wind speed upon aerosol penetration into an idealized enclosure was studied The idealized enclosure was a painted plywood box that was 1 2X1 2 XI meters in volume Two fans supplied 1 7 m3 /min of filtered air to this enclosure at a static pressure of 2 8 mm of water The enclosure had a 7 5 cm diameter vent port which was isolated from the air flow around the enclosure To simulate holes in real enclosures, three 16-cm diameter holes were drilled on the front and back sides of the enclosure This simulated enclosure was placed in a tunnel-like structure The air flow from an ultra-light air craft was directed at the front of the enclosure The air speeds were varied between 14 and 36 km/hr as measured by rotating vane anemometer Static pressure in the enclosure was measured with an electronic manometer Two optical particle counters measured the particle number concentration of particles between the 0 35 to 0 5 µm inside and outside of the enclosure Aerosol penetration into the enclosure was computed as the ratio of the aerosol concentration inside the enclosure to the concentration outside of the enclosure The enclosure static pressures measured increase from 2 8 to 3 4 mm of water (P=00001) Aerosol penetration into the enclosure increased linearly with air velocity above 20 km/hr Theoretically estimated penetrations were correlated with observed penetration into the simulated enclosure When simple linear regression was used to model the observed penetration as a function of the estimated penetration, the value of the slope was 0 69±0 12 and the P value for the regression model was less than 0 0001 These results indicate that enclosure static pressure needs to be higher than the wind's velocity pressure in order to minimize aerosol penetration into these enclosures

Jan 1, 1999

By M. D. Schlesinger

Experimental data for coal hydrogenation are presented to show that when a vehicle oil produced from coal is present, coal is hydrogenated to the same high conversion whether molybdenum catalyst is impregnated on the coal or intimately mixed with the slurry. Differences in product distribution could be related to the severity of operating conditions. No minimum mixing time was established, but 2 hours was sufficient. Longer periods of mixing, to 14.75 hours, had no effect on the results. The hydrogenation conditions were in the pressure range of 8,500 to 10,000 p,s,i. at 400° to 500° C. Most of the experiments were made in duplicate. The results were obtained with molybdenum concentrations of 0.01, 0.1, and 1 percent. Al the mentioned pressure range and a time at temperature of 15 to 60 minutes, coal conversions higher than 98 percent were obtained.

Jan 1, 1962

"A coordinated, integrated research effort aimed at studying the scientific, engineering and medical aspects of the respirable dust problem is underway in the areas of dust generation, dust dispersion and dilution, dust characterization, interaction of dust and lungs, and relationship of seam characteristics to dust generation and mobility. (FIGURE 24) The Center's research program explores these concerns with the objective of refining existing strategies and developing new respirable dust control techniques that are consistent with the dust-lung interaction processes that lead to mine worker disability. The fundamental aspects of this work are applicable to the control of respirable dust problems in both hard rock mines and coal mines and to other dusts such as diesel-generated.Research projects in the Generic Mineral Technology Center for Respirable Dust have effected several improved methods for the preparation and characterization of the dusts needed by these projects. Superior procedures for generating ""standard"" dust samples have been developed and are in regular use in the laboratory. Questions raised during the course of some projects regarding ""stale"" versus ""fresh"" dust have led to the development of sampling techniques where the dust is directly collected in a surfactant. MSHA and CANMET have requested and received information on Center generated software. An equipment manufacturer, TSI, Inc., requesting input on modifying the inlet of an aerosol sampler has been assisted as a result of research that was conducted at the University of Minnesota.The objectives, scope and progress of all the research projects in the Center, in the form of abstracts and reports, have been detailed in Volume 1 of this series. Research papers written by the principle investigators and resulting from the findings of projects (FIGURE 25) and which are funded by U.S. Bureau of Mines grant number G1135142 have been published in Volumes 3 through 6 and Volume 8 of this series. Volume 2 relates the cooperation and interaction of the U.S. Bureau of Mines and the Generic Mineral Technology Center for Respirable Dust in research on the problem of respirable dust in the mineral industries."

Aug 31, 1989

By D. S. Colby, E. M. SEELEY

The total production capacity of the natural-gasoline industry increased to 27,212,000 gallons (647,905 barrels) daily on January 1, 1950, from 21,322,000 gallons (507,670 barrels) daily on January 1, 1948. The rate of growth during these 2 years averaged 13 percent per year, compared with 9 percent per year from 1946 to 1948 and 6 percent from 1944 to 1946. The total number of operable plants on January 1, 1950, was 554, 5 more than at the beginning of 1948. The number of absorption plants increased by 12, the number of cycling plants by 7, and the number of combination plants by 4. The number of compression plants and charcoal plants continued to decrease. Absorption plants accounted for 67 percent of the total capacity on January 1, 1950, compared with 62 percent 2 years previous. Eighty-two per- cent of the expansion in these 2 years was in absorption-plant capacity. Cycle plants accounted for 24 percent of the total industry capacity at the beginning of 1950, compared with 27 percent on January 1, 1948. The average daily capacity of absorption plants increased from 38,400 gallons at the beginning of 1948 to 50,600 gallons at the beginning of 1950. During the same period, the average daily capacity of cycle plants decreased from 150,200 gallons to 144,100 gallons. Texas showed the largest gain in number of plants 13 absorption, 4 compression, and 4 cycling plants. The State accounted for 67 percent of the gain in capacity and on January 1, 1950 had 50 percent total national capacity. Louisiana followed with 7 additional plants. Pennsylvania reported 14 and West Virginia reported 13 fewer plants than in 1948. Most of these reductions were in the number of compression plants.

Jul 1, 1950

By G. B. Atkinson

Properties of catalysts prepared from intermetallic compound precursors were investigated by the Bureau of Mines as part of its mission to decrease U.S. dependence on foreign sources for scarce catalytic materials, such as nickel, cobalt, and chromium. Methods were developed whereby catalysts with surface areas of 30 to 40 m2/g were prepared from intermetallic compounds. Activity of these catalysts for the methanation reaction and methanol synthesis was deter-mined using a fixed-bed, single-pass, flow-through reactor. Catalysts prepared from rare-earth-nickel intermetallics had specific activity for methanation that was five times greater than that of commercial catalysts and were equal to or better than commercial catalysts with regard to sulfur tolerance. Under identical reaction conditions, catalysts prepared from thorium-copper intermetallics produced more than 10 times as much methanol as a commercial low-pressure catalyst and exhibited a high degree of catalytic stability.

Jan 1, 1982

By Lloyd A. Morley, Robert Stefanko

In addition to explosion-proof enclosures, the IEC has published recommendations: 1. 79-2 Pressurized Enclosures, 2. 79-3 Intrinsic Safety, 3. 79-5 Sand-Filled Apparatus, 4. 79-6 Oil-Immersed Apparatus, and 5. 79-7 Increased Safety. All these are valid methods of electrical hazard reduction and find wide use in industries other than mining. Magison (52) discusses in detail each technique and, therefore, such an examination will not be repeated. Two other systems, lamina and labyrinth, are but variations of common explosion-proof enclosures and, therefore, will not be cov¬ered. (34,35,46,53,54,61) By examining other national authorities' opinion, the following will investigate each system's applicability to coal mining. Intrinsic safety applies to any system which is incapable of re¬leasing sufficient energy to be an electrical hazard. (49) Not one foreign country contacted disagreed with the concept, and they find these systems totally acceptable. Only South Africa does not accept oil-immersed apparatus, but no reasons were given. (62) Healy (27) stated that Queenlands, Austrailia would accept all techniques, yet some were still to be employed. Japan specifications allow for all but sand filled. (42,43) Increased safety or Protection Type "e" is an approach in hazard reduction in which special design considerations are applied to ensure an extremely low probability of electrical or mechanical breakdown

Jan 1, 1974

By BUREAU OF MINES

The approval of the U. S. Bureau of Mines when granted to a manufacturer for a gas mask is a certification that the particular device has been submitted to the Bureau of Mines for inspection and test and has been found to meet that bureau's published minimum requirements for safety , durability , and satisfactory performance . Any de- Gas masks are approved by the Bureau of Mines only as a complete unit or assembly of parts , as canister , facepiece and harness . This is in order that responsibility for rigid adherence to the bureau's requirements may be definitely located and not divided . vice marketed under this approval must be a unit composed of parts identical in detail of design , assembly , workmanship , and quality , and produced under the same control and inspection as the original device to which approval has been granted . The particular parts which comprise the approved assembly are designated in a letter to the manufacturer at the time the approval is granted . In recent years they are also specified in the approval plate authorized for use in connection with the sale of the device . Each part permitted in the assembly is legibly marked by name or number for the guidance of users of masks in ordering and identifying approved parts when making repairs , and thereby maintaining their equipment as an approved device . In view of the foregoing , any change in the design of parts or deviation from the permitted assembly of parts would violate the conditions under which approval was granted and the device would not be considered as meeting the approval requirements of the Bureau of Mines . The U. S. Bureau of Mines has been frequently requested to interpret the approval status of a gas mask assembled from parts which have separately met its requirements as components of two or more approved devices but which in the form of a complete unit has not been submitted for tests or been granted approval . Responsibility for the elements and for their proper assembly is in such case divided . Such assembled units have no status as permissible equipment under the Bureau of Mines system of schedules . The reasons underlying this policy are that the approval is granted only to some one who assumes responsibility for the whole and that the details of assembly and coordination of parts are considered to be important to the satisfactory performance and safety of the device .

Sep 1, 1932

By J. H. Perry

The Bureau of Mines is conducting research to determine the effectiveness of long holes in degasifying an area of the Upper Split of the Lower Sunnyside coalbed at Kaiser Steel Co.'s Sunnyside No.1 mine. These holes were drilled from the two outside entries of a section that was closed to mining because of excessive methane emissions. Two holes drilled to 430 and 450 feet produced initial gas flows of 160,000 and 127,000 cfd, respectively. Sixteen days after the completion of the second hole, the total gas production declined to just over 144,000 cfd. In 9 months of degasification, over 35 MMcf of commercial-quality gas has been removed from the coalbed. The combined gas flows declined to 106,000 cfd in the 9-month period. The two holes have reduced face emissions by about 40 pet.

Jan 1, 1978

By J. H. Perry, Joseph Cervik, G. N. Aul

The Bureau of Mines is conducting research to determine the effectiveness of long holes in degasifying an area of the Upper Split of the Lower Sunnyside coalbed at Kaiser Steel CO.'s Sunnyside No. 1 mine. These holes were drilled from the two outside entries of a section that was closed to mining because of excessive methane emissions. Two holes drilled to 430 and 450 feet produced initial gas flows of 160,000 and 127,000 cfd, respectively. Sixteen days after the completion of the second hole, the total gas production declined to just over 144,000 cfd. In 9 months of degasification, over 35 MMcf of commercial-quality gas has been removed from the coalbed. The combined gas flows declined to 106,000 cfd in the 9-month period. The two holes have reduced face emissions by about 40 pct.

Jan 1, 1978

By William C. McBee

Prompted by forecasts of a sulfur oversupply, the Bureau of Mines, U.S. Department of the Interior, is conducting research on potentially large-scale uses of this commodity to extend or replace such construction materials as asphalt, cement, and mineral aggregates. Through these efforts, paving materials have been developed in which sulfur replaces up to 50 pct of the asphalt normally present and which can be prepared and placed with existing mixing and paving equipment. Laboratory properties and design methods for this direct mixing process are described along with properties obtained on small-and large-scale field demonstration projects. These properties are compared with those obtained from control materials prepared without sulfur additions. Monitoring for toxic gases during laboratory and commercial mixing and paving operations is discussed also.

Jan 1, 1978

By Joseph Cervik, Gerald L. Finfinger

The Bureau of Mines conducted an experimental degasification project in Island Creek Coal Co.'s Virginia Pocahontas No. 5 mine. Methane from the over- lying Pocahontas No. 4 coalbed was entering mine workings in the Pocahontas No. 3 coalbed through fractures in the roof rock. Small-diameter (1-5/8-inch) holes were drilled into the overlying coalbed to reduce the gas pressure and intercept methane flows, which were piped to the surface through an under- ground 6-inch-diam steel pipeline. The total methane flow rate from the vertical holes averaged 150,000 ft3/day for the first month. Methane flows into the mine were reduced by 47 pct, thereby demonstrating the effectiveness of this form of degasification in reducing ventilation requirements and providing a safer working environment.

Jan 1, 1979

By L. H. Johnson

"INTRODUCTION The Pennsylvania anthracite industry produced 53 million net tons of anthracite during 1945. Fifty-one million tons was prepared for the commercial market (3), 3/ and 2 million tons (consisting of fine sizes) was used for colliery power consumption. Of the number of tons prepared for market, 17 million tons (33 1/3 percent) was prepared by the use of acid mine water treated with lime.Mine water from underground workings is pumped, drained, and stored in huge quantities. The mine-drainage systems in the anthracite region handle over 200 billion gallons of water annually, of which 150 billion gallons is pumped to the surface. More than 69 billion gallons of water is impounded in underground pools (1). Much of this water is employed for breaker use, dust-control installations; hydraulic backfilling, combatting mine fires; and aiding in the transportation of anthracite in gently dipping places where sheet iron is used Roos(4) estimates that 1,100 gallons of mine water is utilized in the preparation of anthracite mined."

Nov 1, 1946

By Thomas E. Marshall, Roy H. Grau

The U.S. Bureau of Mines has developed an acoustic test for determining if a rock salt sample is from a "normal" nongassy salt face or from a gassy face where an outburst has the potential to occur. The test is based on the observation that a salt sample taken near an outburst-prone zone produces an audible popping sound when it is dissolved in water. The sound is produced when pressurized gas that is trapped in salt samples is released. In the acoustic test, the sound is electronically measured, digitized, and transmitted to a microcomputer; the output is an average decibel value that classifies the sample as "normal" or "outburst." The acoustic test procedure and equipment are described, and raw test results and data analysis are shown. Results are also shown for several salt samples that were analyzed using a laser Raman microprobe.

Jan 1, 1990

By J. H. Russell

A mathematical modeling method was developed by the U.S. Bureau of Mines for the prediction of the principal equilibrium species in the solvent extraction of nickel. Models were developed for the extraction of nickel from ammoniacal sulfate and carbonate solutions with commercial oxime extractants. Independent variables in the research were nickel concentration, ionic strength, pH of the initial aqueous phase, and extract ants and their concentrations in the organic phase. Results from laboratory shakeout tests compared fairly well with predictions of the equilibrium concentrations of nickel and pH values. For example, the loading of nickel onto the extractant was predicted on average within ±27 pct of the measured values, and the pH to within ± 0.17 pH unit.

Jan 1, 1991