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By E. F. Ferrell

The Bureau of Mines, U.S. Department of the Interior, studied the use of manganese sea nodules for catalytic oxidation in air of 1 pct carbon monoxide, 1 pct propane, and 1 pct methane. Catalysts were prepared from both Pacific Ocean and Atlantic Ocean nodules and compared with a platinum catalyst using a fixed-bed, steady-state microreactor with gas chromatographic analysis. Combustion temperatures with manganese nodules were 50° to 100° C lower than those with the platinum catalyst. Ion-exchange addition of rare-earth promotors to the nodule catalyst decreased combustion temperatures an additional 5° to 45° C.

Jan 1, 1978

By Merle Randall

Application of a new chemical spray in a mercury mine in which ore rich in native metal was causing salivation among the miners has given such favorable results that it is believed the process will be useful in other mines and perhaps in some plants where similar conditions exist. The process was originated by Merle Randall, professor of chemistry at the University of California. GENERAL PROBLEM The presence of native quicksilver in mines from which the metal is produced has long been a source of trouble and danger to the workers. Men have been sickened and some of them have been disabled by exposure to the vapors present (even in workings that were well-ventilated by ordinary standards) and to contact with dust, dirt, and moisture with which the finely divided quicksilver was mixed. Where the ore was rich and this exposure was considerable men were able to work only a few days or weeks; where the exposure was less they were weakened and subject to ailments often attributed to other causes.

Jan 1, 1942

By Harry W. Campbell

A mineral survey by Bureau of Mines personnel identified no mineral resources or mineral occurrences with development potential at prospects in the Mecca Hills Wilderness Study Area (WSA). Bentonite occurrences are in Skeleton Canyon and Surprise Canyon. Sand and gravel occurrences are numerous in and near the WSA. Much of the Mecca Hills WSA was leased for oil and gas exploration in 1983. No current mining claims or other leases were found in the study area. The Skeleton Canyon Clay Mine yielded clay to seal irrigation canals, Clay to seal ponds was also mined from the Red Top Clay Mine west of the USA. A sand and gravel pit south of the study area (near Box Canyon Wash) supplied material for local construction projects. A commercial sand and gravel pit was operating in 1983 near the mouth of Thermal Canyon 4 miles west of the WSA.

Jan 1, 1984

By Harry E. Tuff

"This paper is based data obtained by the Bureau of Mines from some of the principal mine operators in Pennsylvania, in the course of a study conducted in cooperation with the U. S. Forest Service, with regard to economies that might be effected in the selection storage, and preparations of timber particularly treatment with preservative to prolong its life.The Pennsylvania anthracite region, considered as a single mining district is by far the largest user of mine timber of any mining district, either coal or metal, in the United States, and the bituminous districts of Pennsylvania rank second. The present annual consumption of mine timber by the coal-mining industry of Pennsylvania probably exceeds 100,000,000 cubic feet annually.In 1919, Pennsylvania produced, in round figures, 145,300,000 tons of bituminous coal, 86,200,000 tons of anthracite, and 5,400,000 tons of iron ores. If it be assumed that the bituminous coal mines required 0.33 cubic feet, anthracite mines 0.7, and iron mines 0.9 cubic feet per ton mined the timber requirements were bituminous. 47,950,000; anthracite, 60,340,000; iron mines, 4,860,000 or a total of over 113,000,000 cubic feet.The average cost of round mine timber in the anthracite region in 1905, was, according to the U. S. Forest Service, 6.6 cents per cubic foot, and $15.00 per 1000 board feet for sawed timber. The present cost Las advanced to 27.5 cents per cubic foot for round timber, delivered to the mine, of which cost 57.4, represents freight charges."

Nov 1, 1923

By Lars Osen

This investigation was undertaken to contribute to the understanding of underground pull tests by conducting laboratory tests under closely controlled conditions. Steel bolts, instrumented with electrical resistance strain gages, were anchored in an aluminum block, a granite block, and a steel sleeve, and were subjected to pull tests. The bearing plates used were either flat7 dished, or embossed. In pull testing a bolt that is prestressed, there is a range of loading during which bolt load is greater than the jack-applied load, This study showed that preload, the size, shape, and type of bearing plate; and the geometry of the system determine the point at which bolt load and applied load become equal. The effects on bolt load of both a theoretical solution and actual pull tests were analogous and led to similar results.

Jan 1, 1965

By S. H. Katz, J. J. Bloomfield

In studies of mine and tunnel ventilation conducted by engineers of the Bureau of Mines , various smokes are used to determine flow of air , direction of the currents , and the rate of mixing . The instrument for generating streams of sulphur trioxide (SO ) smoke , shown in the drawing herewith, has been found helpful , convenient and practicable for such purposes ; it is also especially useful in some places where fire for generating smokes is not permissible . The apparatus consists simply of a glass tube containing fuming sulphuric acid on granular pumice stone , attached to a rubber syringe bulb . When a squeeze of the bulb blows air through the tube , a stream of dense white smoke evolves, which follows and makes visible the air currents . The tubes after preparation are hermetically sealed to prevent deterioration . When ready for use , they are easily broken open at a file scratch for the purpose on both tips , and inserted into a rubber nipple at the bulb . Sometimes it is of advantage to attach them to a longer rubber tube leading to the bulb . Tubes of the size shown (about 1/2 inch outside diameter by 5 inches long) are usually sufficient for the needs of a day . Thereafter they cease to fume because the acid absorbs moisture from the air and looses its effectiveness . Smaller sizes of tubes and larger have been made , but the size shown has proved most practicable . Immediately after a person has finished using a tube it should be buried or disposed of in a place where it will not be touched by shoes or clothing, or come in contact with wooden floors , furniture , or metals , because the acid , which will eventually leak from the tubes , is highly corrosive . -- Reports of Investigations , Department of the Interior , Bureau of Mines .

Jul 1, 1923

By E. W. Pehrson

In making any canvass of secondary metals great care must be exercised to avoid duplication or exaggeration of net consumption. One of the major difficulties is to trace the metal accurately as it passes through the many cycles of manufacture. Greater or less duplication probably occurs in any canvass. The manufacturer of tin plate, for instance, purchases primary pig tin exclusively as a raw material. Most of it goes into the coating on the steel sheet, but a substantial part emerges in the form of byproducts such as scruffs and drosses. These are sold to other plants, where they are used in the manufacture of alloys and chemicals. Alloys and chemicals, however, are not necessarily articles for final consumption. The alloy may be sold in ingot form to a bearing manufacturer, who, in turn may produce some scrap, which he may sell to still' another plant that may make still other products. There is a considerable return of tin in the form of waste products from chemicals sold to the silk industry. Even tin plate does not represent an ultimate use of tin because the tin-can maker produces large amounts of clippings, which are sold to detinning plants, where the tin is recovered and used again for some other purpose. Thus the degree of duplication in consumption statistics depends on the point in the industrial cycle where consumption is measured.

Jan 1, 1936

Publicize the valuable information resources covering research conducted by the U.S. Bureau of Mines (USBM) and other federal laboratories that may be of interest to USBM customers. Access to this information is important for promoting further research and in transferring the technology to the end user. USBM Information Resources The USBM serves as the Nation's premier agency for mining- and minerals-related research. In sharing the benefits of this research with American industry and the American people, the USBM supports information systems outlining this vast array of technical knowledge. The USBM is dedicated to making its technology readily available and will continue to expand its electronic communications capabilities. The following resources provide instant access to USBM information. U.S. Bureau of Mines Bulletin Board. The Bulletin Board is a free service accessed by computer modem. All that you need are a computer, a modem, and communications software. The telephone number for the Bulletin Board is 202-501-0373; for information on using the system call 202-501-0406. Use X-modem protocol set to 1200, 2400, or 9600 baud, 8 data bits, and 1 stop bit (8,N,1). The information on the system can be viewed or downloaded. This service includes the following: announcements on Bulletin Board and other USBM activities; mineral news, features, and press releases from the Bureau's Office of Public Information; a list of recent publications and articles by USBM authors; mineral commodity data and Mineral Industry Survey reports; USBM Technology News, concise factsheets announcing milestones in USBM research and technology; a current list of computer products available from the USBM and the National Technical Information Service (NTIS); and a listing of cooperative research opportunities with the USBM.

Jan 1, 1995

By Albert E. Long

This paper presents a description of the operational mechanics involved in block-caving a granodiorite-capped, limestone deposit. This method was used for 24 years at the Crestmore mine, near Riverside, Calif., which was operated by the Riverside Cement Co. as a source of raw material used to manufacture a portland cement. The Crestmore mine is the only place where a block-cave method has been used to mine a limestone deposit. Structurally, limestone is relatively strong, and it is not usually considered to be a substance amenable to mining by block caving. It is therefore a credit to the engineering department of the Crestmore mine that it developed a satisfactory, relatively efficient method of block-caving a structurally stable rock. In the discussion, covering the methods applied to produce about 7.9 million tons of limestone and granitic rock materials by block caving, particular emphasis has been placed on an assessment of (1) physical properties of the deposit, (2) ground pressure and support, (3) methods used to induce fragmentation and maintain cave action, (4) surface and subsurface subsidence, (5) secondary blasting of oversize, (6) production rate, (7) safety, and (8) the advantages and disadvantages of the cave method as applied to this specific limestone deposit.

Jan 1, 1958

Research workers from the Bureau of Mines and industry met with other government and industry representatives at the Mont Chateau Lodge, Morgantown, W. Va., on May 30-31, 1973, to discuss the current status of methane control in eastern U.S. coal mines. The opening remarks, the eight technical presentations, and the discussions of the members of a government-industry panel are published here for the benefit of those concerned with the control of methane in coal mines. In addition, an introduction has been added to present the background of work in this field.

Jan 1, 1973

By Oliver Bowles

"On January 15, 1920, a man was killed by falling rock in a limestone quarry in Utah. The quarry was visited by a representative of the Industrial Commission of Utah, and the cause of the accident was carefully determined. The facts concerning this accident, and the Bureau's recommendations are given in some detail in the hope that quarrymen may take steps to avoid dangerous conditions, and thus reduce the liability to accident.The quarry rock face is about 180 feet high, and the ledge is covered with an overburden of 10 to 20 feet of a mixture of soil and boulder. The rock face is not vertical, but slants at an angle of about 45° to 50°, while the stripping face stands at an angle of 70° to 80°, and is flush with the rock face. The conditions are shown in the accompanying figure.The man who was killed was employed in breaking rock at the foot of the quarry wall. The sun had been shining on the stripping face, and probably thawed the ground, thus permitting a boulder weighing about 20 pounds to roll down the slanting face, striking, and almost instantly killing the workman who was working with his back toward the quarry wall."

Feb 1, 1920

By David E. Emerson

An improved method and apparatus for determining the impurities in helium by preconcentration and subsequent analysis by mass spectrometry are described. Preconcentration of the impurities is accomplished by passing a known volume of helium, at slightly above atmospheric pressure, through a metal coil and trap assembly immersed in liquid helium. The concentrated impurities are then analyzed by mass spectrometry. This method can detect impurities in the range of 0.01 to 600 ppm with an accuracy of better than ±0.05 ppm at the 1-ppm level. One operator can analyze 15 samples in an 8-hour day.

Jan 1, 1970

By D. J. Stoops

The object of the research described in this paper was to investigate the effect of metallurgical and surface treatments on the corrosion behavior of arc-melted reactor-grade zirconium in cupric or ferric chloride solutions. An apparatus was constructed and specimens of various metallurgical conditions and surface treatments were tested for 6 days at 35° C., with aeration. Some correlations were observed between corrosion rate and the metal's condition and treatment, Specifically, the unattacked or least attacked specimens were those that had been etched as a final treatment before testing. The most severely attacked specimens were those that had been vacuum-annealed as a final treatment before testing. The moderately attacked specimens were those neither vacuum-annealed nor etched, but having a final surface treatment which left a cold-worked surface. Attack by cupric and ferric chloride was by pit- ting with no preference for grain boundaries, The corrosion scale was cow posed predominately of very fine zirconim particles, Particles from the FeC1,-corroded specimens were more pyrophoric than those from CuCl2-corroded specimens, and appeared to have a higher surface area to volume ratio. Comparison of results to those of previous investigators showed that at certain salt concentrations the more pure, reactor-grade zirconium was quite resistant to attack while the less pure, graphite-melted zirconium was severely attacked.

Jan 1, 1962

By Michael J. Sapko, Samuel P. Harteis, Eric S. Weiss

The Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) recently conducted full-scale explosion experiments; these experiments evaluated the strength characteristics of various seal designs used for safely isolating worked-out areas in underground coal mines. Large-scale explosion tests were conducted within the multiple entry section of PRL’s Lake Lynn Experimental Mine (LLEM) employing the only currently accepted test method endorsed by the Mine Safety and Health Administration (MSHA) for seal design in American mines. These explosion tests are labor-intensive, expensive to conduct, and can interfere with other critical underground safety and health research programs conducted by NIOSH. Therefore, the PRL has developed an alternative seal evaluation method, based on a hydrostatic pressure loading concept, that can facilitate the in-situ testing of seals in an operating mine. Two chambers within LLEM and one within the Safety Research Coal Mine (SRCM) were used for hydrostatic pressure loading various seal designs. The results from tests in these chambers compare favorably with those from the large-scale explosion tests in the multiple entries. Preliminary size-scaling relationships for predicting the strength of standard seal designs as a function of entry size is also presented. In addition to testing seal designs at the required 20 psi static pressure level, the new facilities also allow for the determination of the seal’s ultimate failure pressure. This new approach shows promise as an alternative evaluation method for improving mine sealing technologies which, in turn, will enhance the safety of the underground personnel.

By R. P. Vinson

The Bureau of Mines evaluated two real-time light-scattering dust monitors by measuring their response to Pittsburgh Seam coal dust and Arizona road dust (ARD). Both monitors, the model PDS-l, a personal dust sensor, and the model PCD-l, a digital dust indicator, are made in Japan by Sibata Scientific Ltd. Tests were conducted inside a laboratory aerosol chamber designed to maintain a uniform spatial distribution of the test dust. PDS-l and PCD-l measurements of concentrations for each test dust were averaged over 4-h test periods and compared with simultaneous gravimetric measurements. Both dust monitors responded linearly with mass concentration with both coal dust and ARD. However, the linear response of the PDS-l differed from that of the PCD-l for both dusts.

Jan 1, 1987

By G. W. Jones

[A survey of the literature relating to ignition temperatures of acetylene-air and acetylene-oxygen mixtures reveals rather wide disagreement in the reported results. In some instances the ignition temperatures of acetylene-air mixtures were reported to be lower then those of acetylene-oxygen mixtures, which is contrary to experience with other combustibles. To clear up some of the reported discrepancies, the authors have investigated the ignition temperatures of acetylene both in air and oxygen, and their results are presented in this report.]

Jan 1, 1941

By Joan C. Biordi

[Composition profiles for atomic, radical, and stable species, as well as temperature and area expansion ratio profiles, have been determined for a nearly stoichiometric CH4-02-Ar flame and one to which 0.3 percent CF5Br inhibitor had been added. Net reaction rate profiles were calculated for all the observed species. For the normal flame, these and the mole fraction profiles gave rate coefficient information about the elementary reactions in the methane flame, for example, CH. + 0 4- H2CO 0 H, k4 = 1.05 X 1014CM3 mole-1sec-1 for 1,550§T 0,725' K; CO + OH 4 C02 + H, k6= 4.7 X 1011 for 1,350{T X1,750° K. Comparison between the inhibited and normal flame showed that A] and [CH3] were significantly reduced at the lower temperatures in the inhibited flame even though in the hot gas region the [E] [OH!, and [0] were essentially the same in both flames. The CF3Br disappears very early in the flame, relative to the fuel, and the reaction primarily responsible for its disappearance is H v CF3Br 4 HBr + CF3, where k7 is found to be 2.2 X 1014 exp(-9460/RT) for 700-1,550° K. Reaction of the inhibitor with methyl radicals provides for the relatively small amounts of CH3Br observed, but CH3 + Br2 - CHs Br + Br must also occur. The HBr formed reacts rapidly with H atoms to form H2 and Br, but the reaction is soon "balanced" in the flame as may be demonstrated by calculation of the equilibrium constant at various temperatures. The fluoro-carbon fragment produced in reaction (7) also reacts rapidly, in part with methyl radicals to give the observed elimination product CH2CF2 Later in the flame, above -1,400' K, F2CO is formed from the reaction CH2CF2 + 0 P F2CO + CH2 and k., -1.5 X 1013 at 1,600° K. The rather slow decay of carbonyl fluoride is attributed to reaction with H atoms according to the sequence F2CO I H - HF + FCO and FCO + H HF + CO.]

Jan 1, 1975

By John C. Edwards, Gerald S. Morrow

The U.S. Bureau of Mines has constructed a smoke chamber and developed sensitivity tests for smoke detectors. Response of ionization- and optical-type commercially available smoke detectors have been investigated. Six smoke detectors were measured with respect to visually obscuring smoke characterized by a corresponding optical density for smoldering and flaming coal combustion in the smoke chamber. It was determined that for one type of ionization smoke detector the alarm time was nearly equivalent to that of an odor monitor's alarm for smoldering coal combustion experiments and earlier for flaming coal combustion experiments. The experiments showed that an average CO concentration of 5 ppm corresponded to an optical density of 0.022 m for smoldering and flaming-1coal combustion. Two of the commercially available ionization-type smoke detectors were more responsive to flaming than smoldering coal combustion at an optical density of 0.022 m, whereas the optical smoke detectors-1showed the opposite trend. The responsive characteristics of the detectors evaluated with respect to known smoke conditions in the smoke chamber shows their potential for use as mine fire sensors or part of a mine atmospheric monitoring system to improve mine safety.

Jan 1, 1995

By John D. Sullivan

The present article is one of a series which is being prepared by the Southwest Experiment Station of the United States Bureau of Mines in cooperation with the Department of Mining and Metallurgy, University of Arizona, Tucson, Ariz., of papers dealing with factors involved in the leaching of copper ores. A knowledge of the time required to dissolve the various copper minerals present in ores, as well as of the consumption of leaching reagents is very desirable, because with the decrease of the Nation's total tonnage of sulphide ores increasing attention is being given to the recovery of copper by leaching methods from low-grade disseminated ore containing both oxidized and sulphide minerals. As leaching has already been applied with success and profit, this study was undertaken to determine certain fundamental characteristics that are applicable to all ores suitable for leaching.

Jan 1, 1929

By T. D. Ralston

This Bureau of Mines report presents a mathematical model for heterogeneously catalyzed chemical reactors operating under turbulent conditions. The model includes reaction kinetics on the catalyst surface as well as diffusion of the reacting components within the reactor. Three applications of the model to tube-wall methanation reactors are discussed. The first application is a computation of catalyst activity from measured reactor data. This result is then used in a reactor sizing problem and a problem of reactor simulation with recycle. In addition to the reactor model, a novel approach to solving the recycled reactor problem is given.

Jan 1, 1974