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By Fred N. Kissell

Tracer gas decay curves were experimentally obtained in a full-scale model coal mine working face area. The concentration of tracer gas was found to decay in exponential fashion but with a change in slope. This change in slope is attributed to eddy zones in the face area. A simple theory was developed that allows one to calculate the approximate amount of gas in the eddy zones and thus estimate the size of the eddy zones.

Jan 1, 1974

By H. B. Carroll

The Bureau of Mines has designed and built a controlled-environment test chamber specifically for instrument evaluation in simulated work atmospheres. The atmosphere inside the 300-liter stainless steel chamber can be controlled at any selected temperature and relative humidity in the range of 2° to 93° C and 20 to 95 percent, respectively. Instruments placed inside the test chamber are subjected to an atmosphere at a preset temperature and humidity containing various concentrations of toxic gases such as CO, C02, NO, NO2, S02, and H2S. Toxic gas losses resulting from wall reactions, monitoring instruments, and instruments under evaluation are compensated by the use of a dynamic gas blending system.

Jan 1, 1973

By R. P. Vinson, D. P. Tuchman

The personal dust monitor (PDM) is a sampling device developed for measuring the personal exposure to coal mine dust of mine workers. The device is based on proprietary technology known as the tapered element oscillating microbalance (TEOM) originally developed as a fixed- site environmental particulate mass monitor by Rupprecht and Patashnick Co., Inc., Albany, NY. Currently, the monitoring of exposure to coal mine dust relies on periodic samples taken by traditional coal mine dust sampling units that use a cyclone, filter, pump, and laboratory measurement of the filter mass. Better measurement of mine dust levels has been the goal of industry and labor for nearly two decades. PDM technology offers accurate, end-of-shift and near real time assessment of worker dust exposure. Laboratory and underground tests compared measurements taken by a prototype PDM-2 (a two-piece TEOM) to the average of multiple personal dust samplers monitoring the same space. In the range of mass loadings P between 0.5 and 4.0 mg/m the PDM met a 25% accuracy criterion 95% of the time with 95% confidence. However, some questions still exist about potential bias between types of coal. The prototype two-piece device is in the process of being combined into a single unit that also contains the miners' cap lamp creating a more ergonomic dust sampling system.

By Charles Findlay, Stephen Krickovic

A methane emission rate study was conducted in 1969 on a longwall section of a Lower Kittanning coalbed mine in central Pennsylvania. The longwall face was mined with a drum shearer between developed headings on the head end and headings on the tail end that were driven with a ripper-type continuous miner as needed. The study was conducted over 22 consecutive shifts (7-1/3 days). The average methane emission rate from the Lower Kittanning coalbed during mining at the face and developing the headings at the tail end of the face was 34 cfm. Caving of the gassy overlying strata as the result of mining at the face increased the methane emission to rates ranging from 702 to 1,049 cfm.

Jan 1, 1971

By K. C. Dean

Horizontal and vertical air classification systems were tested individually and in simulated tandem use for the recovery of ferrous and nonferrous metals and of other noncombustible and combustible products from shredded urban refuse. The horizontal air system with a larger tonnage throughput was used to obtain preliminary separations, and a smaller capacity vertical system was used as a cleaning device. Air elutriation, magnetic separation, and screening of shredded minus 6-inch municipal refuse recovered 92 percent of the metal in a relatively clean iron product contaminated only by adhering coatings or entrapped materials, recovered 97 percent of the combustibles in a 97-percent combustible product, and rejected 88 percent of the nonmetal noncombustibles. Cleaning of the preliminary combustible fraction produced a 98-percent paper product while rejecting other combustibles (plastics, rubber, textiles, etc.) into a 94-percent combustible product. Retreatment of the preliminary noncombustible fraction produced a relatively clean glass product.

Jan 1, 1971

By John Nagy

Limited experiments in the laboratory with specimens of mine rock from a Virginia bituminous coal mine indicate that natural gas-air mixtures can be ignited by sparks generated by rubbing friction of sandstone against sand-stone, shale against sandstone, sandstone against (roof-bolt) steel, and shale against steel. Such sparks, generated during a roof fall, may have initiated a recent gas explosion in this Virginia mine, although this cannot be stated with certainty. No ignitions of gas were produced by sparks or heat generated by impact friction between mine rocks or steel, during tension breaks of roof bolts, or by pull tests of roof bolts through their washers and roof plate. However, this negative result of limited experiments does not preclude the possibility of gas being ignited by these conditions.

Jan 1, 1960

By James M. Spear

The U.S. Bureau of Mines and the U.S. Geological Survey conducted a mineral survey of the Black Butte RARE (I area during the summer of 1981. The study area encompasses 17,800 acres [27.8 sq mi (7,233 ha)] along the course of the Black Butte River, 13 mi (22 km) southeast of Covello, California. No mineral deposits were identified by the U.S. Bureau of Mines during this survey. Assay results of samples taken in this area indicate only trace amounts of manganese, chromium, and nickel. No radioactive or fluorescent minerals were detected. No oil and gas, coal, or geothermal leases have been recorded for the study area.

Jan 1, 1982

Objective As mines become safer and disasters fewer, a time may come when no employees in the mining industry have any practical experience in managing a mine emergency. To fill an emerging gap in mine emergency response training, a multidisciplinary team of researchers and computer programmers from the NIOSH Pittsburgh Research Laboratory has developed an intervention for mining personnel who would be in leadership positions in the command center during emergencies. It is called MERITS, a computer-based emergency simulation exercise. MERITS is short for "Mine Emergency Response Interactive Training Simulation." It provides trainees an opportunity to gain command center experience during a simulated underground coal mine emergency. MERITS allows trainees to practice information gathering, situation assessment, decision-making, and coordination skills without risk to personnel or property. Individuals representing mine emergency response personnel, various State safety officials, and private mine management from three States have participated in MERITS training. What Is MERITS? MERITS is an extension of previous work that compiled a knowledge base relevant to mine disaster management via interviews, analysis of literature, reviews of past events, and observations of mock mine disasters. Findings from prior research found a need for an alternative method of command center training. This new computer simulation is being used to train emergency command center personnel to effectively manage an underground mine fire. Modeled after training simulations developed for other industries (e.g., to address nuclear accidents, chemical spills, evacuations, etc.), MERITS simulates underground and surface events related to the disaster. It exposes the user to events that typically occur during a mine emergency, such as lack of information and miscommunication. It also presents trainees with issues that must be addressed, such as making provisions for briefing news media and victims' families, ordering needed supplies, interfacing with Government enforcement agencies, and housing mine rescue teams. The outcome of the scenario is determined by the users' decisions and their emergency response plans. Field Results Field testing of MERITS was conducted with eight full-day training sessions at four different locations in Colorado, Pennsylvania, and West Virginia. These field tests benefited from the knowledge and experience of State of Pennsylvania inspection officials, representatives of the United Mine Workers of America(UMWA), and private mine management who served as trainees for the MERITS training sessions. Trainees self-reported an average of20 years of work experience in the mining industry. All trainees had participated in Mine Emergency Response Development (MERD) training exercises, and many had been involved in real mine emergencies. Trainee evaluation of the MERITS program is summarized below: •Twenty-six of the 27 trainees believed that the MERITS simulation helped them know how to prepare for a real emergency. •Twenty-five of the 27 trainees believed that the storyline for the MERITS simulation was either "very realistic" or "realistic." •All 27 trainees believed that the MERITS simulation helped them learn how to better handle a real emergency. •None of the 27 trainees stated that they were bored during the simulation. After the initial field tests, MERITS was refined and retested during training sessions for individuals from State agencies, the UMWA, and private industry. Mining personnel from underground coal and underground stone mines participated and responded positively to the learning experience. Technology Transfer Industry introduction to the MERITS program will occur throughout 2002. MERITS presentations at the Joseph A. Holmes Safety Association National Meeting in Virginia Beach, VA, in June.

Jun 1, 2002

By William E. Wallace, S. J. Page, B. L. Razzaboni, C. A. Hill, Pamela Mike, P. Bolsaitis, M. J. Keane, Val Vallyathan

"Respirable quartz cytotoxicity, as measured by erythrocyte hemolysis and pulmonary macrophage release of lactate dehydrogenase in vitro, is neutralized by boiling in water in glass test tubes for 10 to 40 minutes. The cytotoxicity is reduced to near zero by boiling l to IO mg quartz per milliliter water. For greater concentrations of quartz in water the hemolytic potential after 40 minutes of boiling approaches that of native quartz. Replacing the medium with fresh water midway through boiling results in full detoxification through 20 mg quartz per milliliter water. Pre-boiling the medium with silica reduces the detoxification effect. Detoxification persists after mild drying at l 10°C for 8 hours, and persists after three days of resuspension in water at room temperature.INTRODCJCTIONResearch underway to determine interactions of quartz and other mineral dust surfaces with pulmonary fluids and alveolar macrophages in culture led to the observation that when dusts were autoclaved in aqueous suspension, their cytotoxic effects on macrophages were suppressed, in some cases fully and even after several days incubation with the cells. This finding was in direct contradiction to earlier results from both short term macrophage lysosmal enzyme release assays, as well as longer term cytotoxicity assays from macrophages in culture; in those studies, dusts were steam autoclaved at 121°C with no liquid water but with steam present. 1.2 However detoxification under boiling conditions has been reported in other research. 3 It was decided to use the hemolysis assay to further investigate these findings, because of its sensitivity simplicity and cost.RESCULTS AND DISCCISSIONRespirable quartz dust used in this study was taken from a stock of crystalline silica, Min-U-Sil; obtained from Pennsylvania Sand Glass Corporation, fractionated in air with a particle classifier. The small size fraction retained for use was 80% less than S micrometer particle diameter, with an area equivalent median diameter of 1.24 micrometers as estimated by automated image analysis. The silica was at least 98.S mass percent silica as determined by X-ray energy spectrometric analysis; and the crystalline form was alpha-quartz as determined by X-ray diffraction. It's specific surface area was 3.97 square meters per gram as determined by nitrogen adsorption isotherm methods. I"

Jan 1, 1990

By C. A. Herbert

"The Bureau of Mines for a number of years has conducted experiments at its experimental mine near Bruceton, Pennsylvania, on the explosibility of coal dust, with particular reference to dust explosions in coal mines, and the knowledge so rained may well be applied to the handling of coal dust at industrial plants and elsewhere.Powdered coal is coming into use more and more as a fuel, and the dangers incident to its use should be recognized and guarded against, as a number of accidents have occurred in recent years due to ignorance of this danger or to carelessness.Within the past three years two very serious accidents, under almost identical circumstances, have occurred on the surface at two different coal mines in Southeastern Iowa, due in each case to the sudden ignition of a cloud of fine coal dust.The first accident resulted in the burning of six men, three of them fatally; the second burned eleven; three men died as a result of their burns.The mines in the Southeastern part of Iowa, where these two disasters occurred, are operating in a thin coal bed averaging about three feet in thickness, and are worked on the long-wall advancing system similar to that of Northern Illinois.The miners in this section are paid on a screened coal basis; in other words, receive no pay for the fine coal. As a result they use forks in loading the coal into the mine cars, and naturally a considerable quantity of coal is left along the roadways. Subsequently this fine coal, together with the roof rock that is taken down to give sufficient height on the roadways, is loaded into cars and dumped in piles on the surface. This roof rock is a block, oily shale and the contribution of fine coal and oil shale gives ample combustible material to thoroughly burn the rock as it is dumped."

Jul 1, 1923

By D. Z. Hobbs

Because an economic method for preparing pure boron has not been developed, a program was started by the Bureau of Mines to evaluate existing techniques or to develop new methods for preparing the pure element. This report describes investigations directed toward the development of techniques for the preparation of pure boron by fused-salt electrolysis. Only two of the several fused-salt baths tested were satisfactory for the preparation of boron. These baths contained (1) potassium fluoride, lithium fluoride, potassium fluoborate and boron trioxide; and (2) potassium fluoride, potassium chloride, and boron trioxide. Of these two mixtures, the latter was more satisfactory. Elemental boron of from 90- to 95-percent purity and, in isolated cases, as high as 98-percent purity, was prepared from these two types of fused-salt baths. There appeared to be no distinct differences either in the yields or the purity of boron prepared at current densities ranging from 795 to 1,000 amperes per square foot. Current efficiencies were as high as 85 percent.

Jan 1, 1961

By J. R. Allsup

In cooperation with the Division of Advanced Automotive Power Systems Development, Environmental Protection Agency, the Bureau of Mines studied a conventional spark-ignition engine as a prime mover for use in a hybrid system. The study involved both steady-state and transient engine operation with ignition timing, air-fuel ratio, exhaust gas recirculation, oxidizing type catalytic converters, engine speed, and power output as variables. Data were obtained from two 1971 model 350-cubic-inch-displacement engines mounted on engine dynamometer stands. When the hybrid engine was operated with an oxidizing catalyst at power output levels required for a 4,000-lb curb weight hybrid vehicle, carbon monoxide and hydrocarbon emissions could be reduced to approximately 2.0 grams and 0.3 gram per brake horsepower-hour, respectively. With exhaust gas recirculation, oxides of nitrogen emission levels could be reduced to approximately 1.2 grams per brake horsepower-hour.

Jan 1, 1974

The twelve latexes listed in Table XI penetrated A horizon soil as shown by elution through a laboratory soil column and gave good sealing efficiency. See details in Table XII. High elution through laboratory soil columns of 4 to 6 inches depth is desirable because it predicts penetration of latex to a greater depth in the field. No definite correlation was evident between penetrating ability and particle size, surface tension, or pH. Most of the materials, however, were characterized by low surface tensions in the 36 to 53 dynes/cm range while particle sizes were usually in the intermediate range of about 1500 to 2500 Å. Naugatex J-3471 (a highly crosslinked styrene-butadiene copolymer) was the most promising of this group for stability, penetrating ability; and sealant efficiency. It also showed utility with [B] profile soil. Many of the other latexes tested in this investigation showed good sealing efficiency but were judged unsatisfactory because they gave low penetration or formed surface films with & horizon top soil. In general, latexes containing cationic surfactants were not satisfactory because they formed a heavy surface film. This is due to neutralization of the positive latex charge by the negatively charged soil particles.

Jan 1, 1972

By Charles P. Lazzara

Concentration profiles of low-pressure, slightly lean CH4-02-Ar flames have been measured in situ for the following unstable species: oxygen atom, hydrogen atom, hydroxyl radical, methyl radical, and formyl radical. The observed maximum mole fractions were 2.0X10-2 for H, 1.1X10-2 for OH, and 0.8X10-2 for 0; the maxima occurred in the recombination zone. Methyl and formyl radicals have maximum mole fractions in the reaction zone of 2.2x10-3 and 6x10-5, respectively.

Jan 1, 1973

By J. Bender

The objective of this research was to (1) Further develop cyanobacteria mats' for metal-tolerance and cold-tolerance, (2) test them for durability in the field environment and (3) assess them for metal sequestering potential with actual and simulated field samples. Results show that mats performed well In the field and effectively sequestered metals from actual and simulated field samples. Metal uptake from Iron Mountain Hine samples was for Ins 87%, Cu and Cd 99%, Initial concentrations (mg/L) were Zn = 3,250, Cu , 279, Cd = 28. In solutions simulating the Gulf Tunnel drainage, Zn and Mn were effectively removed by mats immobilized on glass wool. Effluent water, after treatment, generally had a Ph of 7 .5-8.5. Al though the final metal concentrations in the mats 'harvested from the decontaminated water were only 1% or less, the actual mechanism of metal deposit was probably a mat-mediated alteration of the environmental conditions causing the metals to deposit outside the mat as oxides or carbonates. Bioflocculents, released by the mats, were likely involved in the metal-removal process.

Jan 1, 1996

By J. E. Zeilinger

This Bureau of Mines study was conducted to determine the sulfur reduction potential attainable when washing fine-size coal on a spiral concentrator. Crushed samples of Middle Kittanning and Bakerstown bed coals washed on the spiral provided pyritic sulfur reductions of up to 90 percent for the plus 200-mesh material. Pyritic sulfur reductions on the minus 200-mesh material seldom exceeded 30 percent; consequently, this material would require further treatment. The capacity of the spiral was 2 tph per unit when washing l4-mesh by 0 coal. The ability to remove pyrite combined with the higher-than-expected capacity makes the spiral worthy of consideration as a rougher-cleaner in new fine-coal desulfurization circuits.

Jan 1, 1976

Lower noise exposure levels for operators and cleanup personnel working in portable nonmetallic mineral crushing and screening plants.

Jan 1, 1983

By D. B. Dow

In collecting and dissctinating inforr:.at'ion on ir.:,provec.. practices us0i in the pr eduction cf petroleur:1 and in the r;:;.:.1.nuf __ cture of gasoline, the Bureau of Mines ha.s aidei in creatin5 an interest i-n efficient 11:ethods in all phasas of tr.e oil ani gi:i.s iniustry. In the refinin£ ir...mstry ther.:: is a growing tend.ency for incre.:l.sea. effi. ,:;iency, ana inforr;.Eition rela:tin!s to ic:;p·roved practices should be of value not only to the larger and. core efficient plants, but particularly to srr.a.11 refineries unable to carry out a lar6e experLnental pro!§.rarn. The refi?eries of the United States required 4.3,915,029 barrels cf crude oil J.uring the year 1920*, inclu.::.in1:, 611136,210 barrels of Mexican cru::...e. This yielded. 4,8821546,599 gallons of E>asoline, a.n avara.t;,e ciaily pro;.iuct1on of 13,340,291 e,allons·, Besides the easoline obtainel fro;., cruie· oil by-fr:;.cticna.1 distillation and. from heavy oils by crackini:,, this a,-r;ount incluC1.es 3,152,924 bar­rels of natural-ga.$· gasoline blended. With asoline fro,., th otha two sourcs.

Apr 1, 1922

By H. E. Powell

The mineral dressing research here reported is part of a continuing program by the Bureau of Mines to develop new or improved concentration processes for oxidized or partly oxidized lead and zinc ores. A sample of low-grade sulfide-oxide, lead-zinc ore from Jasper County, Mo., containing galena, cerussite, pyromorphite, hemimorphite, smithsonite, and sphalerite was concentrated by froth flotation and tabling to a grade of 66 percent lead. Because of the presence of a high content of slime-size values, the overall recovery of lead was limited to 64 percent at this grade. Tests to recover the zinc by froth flotation and by gravity concentration did not give satisfactory results. INTRODUCTION Since its establishment, the Rolla Metallurgy Research Center has con-ducted studies of base metals as a part of its overall program (1, 2, 3, 4, 5,6,7).3/ This research has been, and is, directed to beneficiating complex and submarginal ores, to retreating rejects from commercial installations, and to developing fundamental data.

Jan 1, 1960

By R. F. Abernethy

A chemical method of determining microgram quantities of arsenic in coal was investigated by the Bureau of Mines to supplement a semiquantitative spectrographic method of determining arsenic in coal ash. In accordance with a method recommended by the International Organization for Standardization, 1-gram samples of coal are decomposed by wet oxidation with boiling sulfuric acid (H2S04) and nitric acid (HN03) to remove the organic matter. After heating to fumes of SO3 to remove HN03, the arsenic is separated as arsine by the action of zinc in H2S04 solution. The arsine is absorbed in dilute iodine solution in which the arsenic is determined colorimetrically by the molybdenum-blue reaction. Two modifications of the method for obtaining the arsenic in solution, in addition to the wet oxidation method, give satisfactory results. The modifications are (1) furnace ashing with MgO added to the coal, followed by treatment with H2S04, and (2) extraction of arsenic from the coal by dilute HNO3 without ashing. Float-and sink-tests show that arsenic is associated mainly with mineral matter in the three coals examined. High-temperature ashing tests show that very little arsenic is volatilized from coal ash below 1,000° C, but it is virtually all removed from the ash at 1,300° C.

Jan 1, 1968