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By G. W. Jones

[As a part of its investigations pertaining to the promotion of safety, the Bureau of Mines is investigating various means, useful for the elimination or mitigation of the explosion hazards of combustible gases encountered in mining and industry. Information has been obtained and a procedure developed whereby the explosibility of many complex, gaseous, combustible atmosphere may be calculated in a simple manner without the necessity of performing laborious laboratory experiment. In a previous publication4/ data were given and a method described whereby the limits of inflammability of gaseous mixtures, including methane, hydrogen, carbon monoxide, nitrogen, carbon dioxide, and oxygen, could be determined by calculation. The information published in that retort enables one to calculate the limits of inflammability of such gases are liberated by mine fires, gases from explosives, automobile exhaust gas, gases present after mine explosions, blast-furnace gas, and other gases containing part of or all of the above-listed constituents.]

Jan 1, 1938

By G. W. Jones

As a part of it investigations pertaining to the promotion of safety, the Bureau of Mines is investigating various means, useful for the elimination or mitigation of the explosion hazards of combustible gases encountered in mining and industry. Information has been obtained and a procedure developed whereby the explocibility of many complex, gaseous, combustible atmospheres may be calculated in a simple manner without the necessity of performing laborious laboratory experiments. In a previous publication4/ data were given and a method described whereby the limits of inflammability of gaseous mixtures, including methane, hydrogen, carbon monoxide, nitrogen, carbon dioxide, and oxygen, could be determined by calculation. The information published in that report enables one to calculate the limits of inflammability of such gases as are liberated by mine fires, gases from explosives, automobile exhaust ran, uses present after mine explosions, blast-furnace gas, and other gases containing part of or all of the above-listed constituents.

Jan 1, 1938

By John M. Devine

Hydrogen sulphide associated with natural gas was noted as early as at Point Albino, Canada. The presence of this impurity was recognized also in other of the earlier oil and gas fields, although the occurrence was by no means common. However, in recent years, with the development of the producing zones of test Texas and the Texas Panhandle, the Production of "sour" crude has increased greatly and hydrogen sulphide has proved a generally troublesome factor--frequently a major problem--in the drilling and operation of many wells in those areas. The problems arising from the drilling and producing of oil or gas wells in hydrogen-sulphide areas, fall under two general divisions: safety problems and corrosion problems. Mention is made of a third division which is closely related to the other two, that of treating--or the development of processes for the removal of hydrogen iron the standpoint of safety and health hazards, hydrogen sulphide in the petroleum industry has been discussed in a number of publications. Likewise, the problem of hydrogen-sulphide corrosion of production equipment has been given considerable attention in the literature.

Jan 1, 1931

By W. W. Adams, T. D. Lawrence

The National Safety Competition , a safety contest conducted annually by the Bureau of Mines , United States Department of the Interior , to promote safety at mines and quarries , has just resulted in the award of safety trophies , known as the " Sentinels of Safety" , for 1939. Awards were made to a bituminous- coal mine in Wyoming , an anthracite mine in Pennsylvania , a metal mine in Michigan , and a nonmetallic -mineral mine in Alabama ( all being underground mines ) and to anopen-cut mine in Minnesota and a stone quarry in Michigan. The awards signify that the recipients won first place in their respective groups in an accident-prevention contest by operating during 1939 with the smallest loss of time in proportion to the total number of man-hours worked at the mine or quarry . Each of the trophy-winning companies for 1939 operated his property without a disabling injury to an employee , except at the anthracite mine , whose record , while not free of accidents , was better than that of any other mine in the anthracite group . The " Sentinels of Safety" trophy is a bronze statue of a mother and infant welcoming the father safely home after his day's work in the mine . Six trophies were provided by THE EXPLOSIVES ENGINEER magazine to be awarded annually by the Bureau of Mines . These trophies remain in the custody of the mining companies for 1 year , after which the trophies are transferred to the winners of the succeeding year's contest . A replica of the trophy is provided for permanent retention by the company surrendering the bronze trophy . In addition to the award of the safety trophies for 1939 , each man employed at a winning mine or quarry receives from the Bureau of Mines a certificate of honor in recognition of his part in helping his company to win the trophy . Companies ranking second , third , fourth , or fifth in their respective groups , and all mines and quarries whose records were free of disabling ( losttime) injuries and showed at least 30,000 man-hours worked during the contest year were awarded certificates of honorable mention . Mines and quarries that won the " Sentinels of Safety" trophies for 1939 and those that were awarded certificates of honorable mention are indicated in the following paragraphs .

Jun 1, 1940

By M. M. Tilman

As part of ongoing research to improve mine safety, the Bureau of Mines conducted research on the corrosion of friction rock stabilizer steels in five Missouri lead and iron mine waters. Electrochemical corrosion tests, including evaluation of pitting tendency, were performed on two types of high-strength, low-alloy (HSLA) steels and galvanized steel in four Missouri lead mine waters and one Missouri iron mine water. The tests were conducted at in-mine water temperatures in both air-saturated and deaerated waters. Static, weight-loss corrosion tests were also conducted on HSLA steel specimens in the five Missouri mine waters for 2,900-h duration at average in-mine water temperatures and air-dissolved oxygen contents of 6 to 7 ppm. Corrosion rates determined by the weight-loss tests were roughly comparable with rates determined electrochemically in deaerated waters containing 0.3 to 0.5 ppm dissolved oxygen content. Passivation of specimen (nongalvanized) surfaces in air-saturated waters resulted in very low electrochemically deter- mined corrosion rates. Pitting-tendency was generally higher for both HSLA steels in air-saturated waters than in deaerated waters. Galvanized steel generally exhibited higher tendency to pitting in the deaerated waters than in the aerated mine waters.

Jan 1, 1985

By Robert W. Geehan

"INTRODUCTION The Bureau of Mines has been investigating deposits of critical and essential minerals in the United States since 1939. Many of the mines were developed.A preliminary examination of the Sultan mine was made in January 1945 by the author, who recommended investigation by drifting and crosscutting. The Bureau conducted a project at the mine from April to June 1946. Claims investigated are in sec. 20, T. 25 S., R. 58E., Mount Diablo base and meridian, in southern Clark County, Nev., about 7 miles southwest of Good-springs.The Sultan mine has been an intermittent producer of zinc-lead-silver ore since 1910. During World War II, ore was shipped to the Government stock pile at Jean, Nev., and to the International Smelting& Refining Co.'s smelter near Salt Lake City, Utah. Throughout the past year, ore has been milled and the concentrates have been shipped to the smelter."

Sep 1, 1947

By D. A. Reynolds, L. P. Rockenbach

"The method of analyzing light oil for benzene is fully described by Fieldner and others 4/ and Kester and Kolmes 5/. In this procedure, benzene is determined by shaking 20 cc. of the 79º to 81º C. boiling point cut from the fractionation of the refined light oil with 3 volumes of 98—percent sulfuric acid in an A. S. T. M. separator funnel of the type used for determining water in bitumi¬nous materials. After the mixture has been shaken 5 minutes it is allowed to settle at least half an hour and the acid is drawn off; the residual oil is reported as paraffins and the decrease in volume as benzene. The method has been found satisfactory for light oils from coals carbonized at 5000, 600°, and 7000 C. but does not give accurate, reproducible results for oils from the 800° C. tests.The content of benzene of the 790 to 81° C. cut is high, 90 to 95 percent, for 800° C. light oils, whereas for lower—temperature light oils it is considerably less. Benzene is the most difficult of the aromatics to sulfonate, hence the acid concentration must be maintained above 95 percent to insure complete sulfonation. Sulfuric acid (98 percent) reacts with benzene, but its reaction with paraffins at ordinary temperatures is negligible; however, more concentrated acid will attack paraffins and give erroneous yields of benzene. The reaction between benzene and sulfuric acid forms water that will dilute the acid. The effect of this dilution may be overcome by increasing the acid-to-oil ratio or increasing the strength of the acid. The latter, however, must not be used, because the stronger acid reacts with paraffins."

Mar 1, 1942

By A. E. Harak

To determine the retorting characteristics of a column of mine-run, ungraded oil shale ranging in size from fines to pieces weighing as much as 5 tons, a 150-ton batch retort was designed and constructed at the Laramie Energy Research Center, Laramie, Wyo. The retort vessel is 45 feet high by 11-1/2 feel in inside diameter and is supported in a 92-Foot-high steel superstructure. Mine-run shale from the Bureau of Mines facility near Rifle, Colo., assaying about 25 gallons of oil per ton, is currently being used as the test shale. To date, three runs have been completed. Results of the second and third runs are reported in this paper. The two runs considered in this report are the first of a series of nine to determine operating conditions that will yield maximum oil recovery from a column of mine-run shale. Variables studied :ire the oxygen content of the retorting gas and the space velocity of the retorting gas expressed as ft3 gas/ft3 bed/min. Oil recoveries for the two runs reported are 62.2 volume percent of Fischer assay for the run using higher oxygen and space velocity, compared with 39.3 volume-percent when less oxygen and a Lower space velocity were used.

Jan 1, 1971

By Charles Findlay, Stephen Krickovic, J. E. Carpetta

As one of its projects for degasification of major panels of coal prior to mining within them, the Bureau of Mines conducted methane emission studies during development of a set of three headings 1,800 feet in a major coal panel (2,700 by 3,500 feet) which had been completely isolated by sets of main headings for 12 months in the Federal No. 2 mine (Pittsburgh coalbed) in northern West Virginia. Similar emission studies were conducted in the development of two sets of main headings in virgin coal areas nearby. Comparing the two sets of data indicated that the isolated coal panel had been degasified by approximately 70 percent.

Jan 1, 1973

By Laurance L. Oden

Titanium-enriched smelter slag produced commercially by Quebec Iron and Titanium Corp., Sorel, Quebec, was evaluated as feed material for a process developed by the Bureau of Mines to prepare rutile. Glass-forming agents including P205, B203, and two binary mixtures were added individually to the as-received and preoxidized smelter slag, and the nonferrous tramp oxides were effectively partitioned into the resulting noncrystalline phase. Iron in the ferrous oxidation state was moderately soluble in the glass of reduced specimens but less soluble under oxidizing conditions. The solubility of iron oxide in phosphate glass exceeded the solubility of iron oxide in borate glass. Effective conversion of titanium oxide to rutile was not achieved in the high-iron commercial smelter slag, and 20 to 30 pct of the titanium remained as pseudobrookite, a mixed iron-titanium oxide.

Jan 1, 1973

By Tilman M. M.

The effects of substituting cobalt for nickel on the acid corrosion resistance of two types of austenitic stainless steel were determined. Cobalt substitutions to a maximum 2.2 weight-percent were made in types 302 and 309 stainless steels. Total immersion corrosion tests were made in 10 volume-percent hydrochloric acid, and boiling-acid tests were conducted in 65 weight-percent nitric acid and in undiluted glacial acetic acid. For modified type 309 in acetic acid, corrosion rates decreased for additions greater than 0.57 weight-percent cobalt. Corrosion rates increased as cobalt was increased up to about 1 weight percent for modified type 302 in nitric and hydrochloric acids and for modified type 309 in nitric acid, but these rates decreased with a further increase in cobalt content. A gradual increase in corrosion rates with increasing cobalt content was shown for type 302 in acetic acid and for type 309 in hydrochloric acid. Cobalt substitutions in larger amounts (above a ratio of 8 Ni to 1 Co) may increase the corrosion resistance of the austenitic stainless steels.

Jan 1, 1965

By Thomas J. Peters

The Danskin/South Fork Boise River study area is 40 air km southeast of Boise, Idaho. The 16,000-hectare, two-segment area is mainly underlain by Cretaceous-age granodiorite and an aplitic and pegmatitic complex of the Idaho batholith, Miocene-age rhyolitic tuffs and lavas, and late Tertiary-age basalt flows. No mineral resources were identified in the study area. One mine, The Flat Creek mine, which produced several ounces of gold and silver, was found in the study area. It is geologically similar to deposits in the Neal mining district, adjacent to the northwest corner of the area; gold mineralization occurs along east-northeast-trending faults and associated quartz veins, which dip moderately to steeply southeast, and within adjacent Cretaceous granitic rock. Samples indicate the Flat Creek deposit is not rich enough to mine underground, and near surface, open-pit-mineable deposit areas could not be identified. However, exploration is warranted there and also in the 7-km interval to mines in the Neal district, and for extensions of those mines. No evidence of geothermal activity was observed, although there are hot springs in the vicinity. Some alluvial (placer) samples from the interior of the study area contained free gold, but no substantial gravel deposits were seen.

Jan 1, 1993

By R. J. Leary

Oxidation testing of copper-clad steel strip was performed in a muffle furnace to determine whether copper in contact with steel scrap could be removed by oxidation in an airstream at high temperatures. Substantially all of the copper was oxidized before any significant iron oxidation occurred. The rate of copper oxidation was not affected by contact with iron. Copper oxide scale separated spontaneously from the underlying metal during cooling. Results indicate the possibility of removing light-gage copper coatings and components from ferrous scrap by oxidation in an incineration process.

Jan 1, 1965

By W. J. McConnell, C. P. Yaglaglou

"IntroductionThis paper on the kata thermometer is issued by the Bureau of Mines on account of the general interest in this instrument and the fact that it is frequently used in studies of mine ventilation conditions with regard to comfort and health of miners. It has been used in the studies being conducted along this line by the Bureau of Mines on the effects of high temperatures and humidities of air in mine working on the comfort conditions, as well as in studies of atmospheric conditions in mine, railway and vehicular tunnels.The study of the various physiological responses of the human body to different degrees of temperature combined with different percentages of relative humility in still and in moving air, now being conducted at the Pittsburgh experiment station of the bureau in the research laboratory of the American Society of Heating and Ventilating Engineers, cooperating with the Bureau of and the U. S. Public Health Service, presents an added opportunity of investigating the instruments that have been devised to measure atmospheric conditions as they affect the comfort and health of human beings.The ordinary mercury thermometer, as pointed out by Heberden3 almost hundred years ago is a very inadequate instrument for measuring the physiological effects of atmospheric conditions. It merely accounts for that part of the body heat lost by raliation and convection, while as a matter of fact greater part of the body heat resulting from the metabolic process within the body is eliminated by means of evaporation from the surface of the body."

Jan 1, 1924

By A. J. Barry

An apparatus and procedure have been developed for testing the anchorage effectiveness of slotted-type bolts. The apparatus consists of: (1) A hydrualic Jack assembly for loading the bolt and (2) a device (extensometer or cathetometer) for measuring displacement of the bolt as it is loaded. This apparatus and procedure permit measurment of anchor slip for loads up to the yield load of the bolt. Two representative makes of slotted-type bolts (a total of 94 bolts) were tested in typical sandstone and shale mine roof. Analysis of the test results showed that (1) anchorage capacities up to the yield load of the bolts can be developed in either rock type; (2) the shape of the slotted end of the bolt affects the ease with which the bolt can be driven; (3) all bolts for which the driving distance was more than 1.25 inches produced satisfactory anchorage in both rock types (thus, driving distance can be used as a criterion for satisfactory anchorage); (4) for the group of bolts that was satisfactorily anchored the anchor slip was unaffected by the type of bolt but was considerably larger in shale than in sandstone; and (5) the bolt expansion, that is, the amount the wedge expands the prongs in excess of the diameter of the hole, can also be employed as a criterion for satisfactory anchorage. Although the bolt-expansion and driving-distance results do not differ appreciably, the latter is recommended because it is easier to determine.

Jan 1, 1954

By Wilder D. Foster

In the method used in the Health Branch of the Bureau of Mines for petro-graphic identification of the minerals in a rock, the sample is crushed, ground to a fine powder in a mortar, the powder is put on a slide, a drop of index oil and a cover slip are added, and the slide is ready for examination. The rock should be ground fine enough so that most of the particles consist of only one mineral, otherwise identification is difficult. Finally, the amounts of the minerals present in the sample are estimated to the nearest 5 or 10 percent. When quartz grains are mixed with some claylike minerals) of which by far the most common example is quartz and kaolinite in a shale, grinding in a mortar does not always separate the quartz from the kaolinite; instead, the quartz grains become coated with the kaolinite and are not visible, even after careful search. Talc acts Similarly, but muscovite and pyrophyllite do not. In evaluating the possible silicosis hazard of breathing dust from a shale, it is essential to be able to see and identify all of the quartz grains, as the other minerals present are relatively innocuous.

Jan 1, 1949

By Jr. Karr

The Bureau of Mines studied the influence of carbonization method, temperature, and carrier gas on the composition of eight different low-temperature tars produced from a Colorado subbituminous coal. A fluidized bed was compared with an entrained bed, temperature was varied from 500° C to 650° C, and external heating using recycle gas as the carrier gas was compared with internal heating using oxygen-containing gas. The entrained bed yielded significantly more m-cresol and m-ethylphenol, indicating that thermodynamic equilibrium was more nearly approached in the system. Increasing the temperature greatly increased the yield of benzenes and naphthalenes, while paraffins, olefins, and total tar acids were reduced. Using oxygen in the carrier gas decreased the yield of low-boiling phenols and increased that of paraffins and olefins at 650° C.

Jan 1, 1966

By L. C. IlsLey

A list of permissible mine equipment, tested and approved p or to July 1, 1934, was published in Bureau of Mines Information Circular 6813/. The present list4/ includes virtually all the electric air compressors, coal drills, mining machines, loading machines, conveyors, mine pumps, room hoists, mine telephones, rock-dusting machines, switches, electric cap lamps, flame safety lanes, electric hand and trip lamps, electric flood lamps, methane detectors, blasting units, storage-battery locomotives, tandem locomotives, mower trucks, and concrete mixers tested and approved by the Bureau to January 1, 1937. The system under which these devices were tested permits the manufacturer, after his equipment has passed certain tests prescribed by the United States Bureau of Mines, to mark his equipment with a seal showing that it has been approved by the Bureau. These tests are designed to insure that equipments have the minimum requirements for safety in use. The only object of the bureau in making such tests and publishing lists of permissible equipment is to help decrease the hazards of mining.

Jan 1, 1937

By R. T. Johansen

The adverse effects on waterflooding and well-completion methods of clay minerals indigenous to petroleum-production formations recently have received considerable attention. Knowledge of the types and amounts of clay minerals present would allow estimates of the response of such formations to injected or infiltrated water; however, the random distribution of clays in sedimentary formations makes direct evaluation of ?water sensitivity? desirable. A method for the direct evaluation of water sensitivity has been developed, based on measurement of water-vapor adsorption. Correlation of such data with the results of nitrogen-adsorption measurements provides valuable information on the content and properties of clay minerals in sedimentary rocks. The method is relatively simple and has the advantage that it may be used with small, irregularly shaped chips or shale-streaked samples, as well as with typical core samples. Methods previously employed required separating the clay from the rest of the reservoir-sample material and then performing a clay analysis either by X-ray diffraction, differential thermal analysis, liquid permeability, or a combination of these methods (2,3) .3/ This water-vapor-adsorption method requires measuring only a few points on the isotherm to tell whether or not the sample is water sensitive. The goal of these measurements is not to determine the type or amount of clay present, but what will be its sensitivity to flood water. This method gives a direct means of solving this problem.

Jan 1, 1958

By Richard F. Hewlett

Numerous populations of assays have been simulated for a range of assay values representative of low-grade mineral deposits to facilitate the study of problems encountered in evaluating these deposits. Analysis of these simulated populations of assays (obtained by using statistical probability models for the simulation) makes possible the quantification of the effects of (1) various composite assay intervals, (2) ore reserve computational methods, (3) uneven assay intervals, and (4) various cutoff grades on both the precision and the accuracy of the estimated average grade and tonnage of ore.

Jan 1, 1964