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By H. N. Dunning

A comprehensive production research program, now in progress at the Petroleum Experiment Station of the Bureau of Mines at Bartlesville, Okla., includes studies of the displacement of petroleum from sand by detergent solutions. An earlier report (12)2/ presented the results of an extensive research program to determine the value of detergents as floodwater additives. This report presents later results of the detergent-testing program (13, 17). Although water-flooding methods and controls are constantly being improved to increase the production of oil from secondary-recovery operations, considerable crude oil commonly remains.in place after a water flood has been terminated. Therefore, the possibility of improving the efficiency of a waterflood by the use of detergents is of increasing interest. The effects of many substances on the efficiency of water flooding have been investigated in laboratory studies (5, 11, 13, 17, 19, 24). Of the various sub-stances tested, only surface-active agents were consistently effective in removing oil from sand. Results of laboratory studies presented in earlier reports (9, 11, 12, 13) show that many detergent solutions effectively displace petroleum from sand surfaces under varying conditions encountered in centrifuging, manual and mechanical agitation, ultrasonic vibration, and imbibition.

Jan 1, 1957

The coal-bearing areas of Kansas cover approximately 18,800 square miles (23 percent of the state's total area). Coal in Kansas ranges from lignite to high volatile bituminous, located principally in the south-eastern part of the state. Kansas reserves are estimated to be 987,500,000 tons, approximately 0.2 percent of U.S. reserves. Coal beds generally occur in thin seams up to five feet thick. The overburden-to-coal stripping ratios in Kansas are among the highest in the nation, typically 20 to 1, with some ratios up to 35 to 1. The first commercial coal mining operation in Kansas opened in 1865 at Fort Scott in Bourbon County. As in other states, coal production in Kansas increased during the industrial revolution, and then fell as industry converted to alternative fuels. Production peaked in 1916 and 1917, with annual production of 7,250,000 tons. Coal production today is by surface mining methods. The Kansas regulatory program was approved April 14, 1982; the Abandoned Mine Land Program was approved February 1, 1982; and the emergency program authority was approved January 10,1989.

Jan 1, 1992

By John W. Moore

The discovery of porphyries in petroleum by Treibs (17-19) is one of the most significant achievements relating to the origin of petroleum. The presence of these remnants of chlorophyll and hematin in petroleum has immediate practical interest in several aspects of the petroleum industry. Because of their interfacial activities and film-forming tendencies, the metal-porphyrin complexes may be expected to affect the wettability of petroleum-reservoir rock surfaces and influence the flow of fluids in these reservoirs. Also, studies of the relationship of trace elements and porphyrins in petroleum may be expected to yield valuable information on source beds and petroleum migration. Finally, the extreme stability of several metal-porphyrin complexes complicates removal of these metals from some petroleum stocks where they exert deleterious effects on processing and utilization. Metal-porphyrin complexes are commonly associated with the asphaltic residues of crude oils in which they occur (8, 9, 15). However, investigations in this and another laboratory (15) show that small amounts of these complexes often remain in partly refined petroleum products, such as thermally cracked distillates and deasphalted stocks.

Jan 1, 1957

By B. J. Moore

This Bureau of Mines publication reviews U.S. helium resources as of January 1, 1973. These resources, estimated to be 693.7 billion cubic feet, are broken down into four classifications, as follows: helium in storage, 34.9 billion cubic feet; helium in measured helium-rich natural gas reserves, 119.5 billion cubic feet; helium in measured helium-lean natural gas reserves, 62.8 billion cubic feet; and helium in indicated or undiscovered natural gas resources, 476.5 billion cubic feet. The helium in undiscovered natural gas is considered a national resource; however, this gas may not be discovered depending on many factors beyond the scope of this paper, and most of the helium in natural gas will be dissipated as the gas is consumed for fuel and other purposes.

Jan 1, 1976

By A. J. Kraemer

For a number of years the Bureau of Mines has conducted semi-annual survey to determine the changes in the characteristics of the rotor gasoline being sold in the United States. Certain cities have been decided upon as points of origin of samples. Tare choice of these cities has been governed by their situation as the representative of a more or less definitely bounded marketing territory. Samples have been taken on or about the fifteenth day of January and July of each year. In the collection of the samples an attempt has been made to get a representation of the important types of motor fuel being sold, and also to tame into consideration the proportion of tie total consumption that is supplied by the different marketers. It is therefore felt that the survey affords a reliable indication of the quality of the gasoline being sold throughout the United States at the time of sampling. The figures in Table I, below, were obtained by averaging the end points of the least volatile and most volatile samples of gasoline. For example, of 850 samples analyzed in 1919, the 10 per cent (85 samples) having the highest end points, and the 1C per cent having the lowest end points were averaged. These averages are represented in the table as the "Maximum 10 per cent" and the "Minimum 10 per cent", respectively. The same scheme was used in the succeeding surveys.

Jan 1, 1925

By J. R. Thoenen

This circular is part 3 of the third paper (entitled "Excavation") of a series summarizing the technical problem; involved in the production and preparation of sand and gravel. Part 1 discussed the use of power shovels, draglines, and excavator cranes. Fart 2 discussed the use of power scrapers, slackline cableway excavators, and hydraulic monitors. This circular discusses the use of the hydraulic, clamshell, ladder, and dipper dredge. Part 4 to follow will discus the use of haulage equipment, and subsequent parts will discuss the application of both excavating and haulage equipment to various types of deposits. HYDRAULIC DREDGE Judged by the number of installations and the tonnage produced, as recorded in part 1 of this circular, the hydraulic or pump dredge is the most popular type of underwater sand and gravel excavator.

Jan 1, 1935

By Albert W. Deurbrouck

This report describes the preparation characteristics of the significant coalbeds in Russell County , Va . Almost 2 million tons of coal was mined in 1961 ; 75 percent of the coal was cleaned mechanically in preparation plants in the county . The coal of Russell County is ranked as medium- to high- volatile bituminous , contains small amounts of sulfur , and generally requires some cleaning to reduce the ash content to limits acceptable for metallurgical purposes .

Jan 1, 1963

By PAUL L. FISHER

This bibliography has been compiled by the Bureau in answer to many requests now being received for information on the briquetting coal and other carbons . In addition to publications issued by the Government in printed or mimeographed form, references are included to articles appearing in the technical press and in cooperative reports of work done jointly with states , colleges , and industries . References and patents are arranged in chronological order . Bureau of Mines bulletins , technical papers and Minerals Yearbooks are printed , and are obtainable from the Superintendent of Documents ,. Government Printing Office , Washington 25 , D. C. Reports of investigations , information circulars , and the directories and reports of the mineral industry surveys are published in mimeographed form and may be obtained without charge from the Publications Distribution Section , Bureau of Mines , 4800 Forbes Street , Pittsburgh 13 , Pa . Many Bureau of Mines publications , as well as bound copies of the foreign and American scientific and trade periodicals , may be consulted in technical , college , and large public libraries throughout the country. Dealers in new and second-hand books sometimes have copies of these reports for sale .

Jul 1, 1948

By Peter Grandone

Bureau of Mines engineers engaged in studying stimulative methods of recovering oil have been making a series of tests on the effectiveness' of methods that may be applied in water flooding oil-bearing sandstones. The report gives the test procedures and results of a study of the rates and pressures used for injecting water into several sandstone formations in the Mid-Continent fields for the purpose of learning more about the mechanics and efficiency of the flooding process and to provide useful information for operators of water floods in this area.

Jan 1, 1949

By Joe Maher

Adequate mine roof support to insure the safety of men and equipment is essential to successful mining. It is also expensive, amounting to more than one-fifth of the total mining cost at the White Pine mine. Cost effectiveness is therefore a prime consideration in developing optimum roof support. Roof bolt length is an important cost factor. This Phase II work compared uniform four-foot length Resin Bolts with the hitherto standard alternating four-foot and six-foot Resin Bolts, aiming at more cost-effective roof bolting. The data generated under this Phase II show that there is no discernible difference in the roof support given by uniform four-foot, and by alternating four- and six-foot, Resin Bolts in the relatively difficult ground selected for a severe initial test comparison; subsequent data from less difficult ground led to the same conclusion, namely no discernible difference between four-foot and four-six foot bolting.

Jan 1, 1975

This article updates the status of fatalities occurring in both coal and metal/nonmetal mines from January through December of 2001. Based on preliminary accident reports, as of December 31, 2001, seventy-two fatalities have occurred at coal and metal/ nonmetal mining operations. During this period, forty-two fatalities occurred at coal operations and thirty fatalities occurred at metal/nonmetal operations. Ignition or explosion of gas or dust and fall of roof were the most frequent accident classifications in coal and powered haulage fatalities were the most frequent accident classification in metal/nonmetal.

Jan 1, 2002

By Harry R. Nicholls

Six different chemical explosives were detonated in a test series to com-pare their relative performance in granite. From 5 to 255 feet from the detonation point, strain, acceleration, and particle velocity were recorded and analyzed for amplitude and pulse shape. Strain energy was calculated from strain data, and displacement data were obtained from particle velocity data by integration. The results show that explosives which have a characteristic impedance more closely matching that of the rock generate larger peak amplitudes than explosives with a lower characteristic impedance. The results also show that as the ratio of characteristic impedance of exp1osive-to-rock approaches unity, more rock is crushed and a larger percentage of the avail-able explosive energy is transferred to the rock as seismic energy. The effect of characteristic impedance is shown to be greater than the effect predicted from acoustic theory and is believed to be indicative of shock wave effects at the explosive-rock boundary.

Jan 1, 1965

By E. D. Gardner

"Introduction Ore from stopes in metal mines is generally dumped or drawn into chutes or raises through which it passes by gravity to the haulage levels. Occasionally, and under some conditions quite frequently, the ore in a chute will wedge or hang and refuse to run. This hanging of the ore may be due to the packing of damp or clayey material, to boulders forming an arch, or to loose lagging or other timber becoming lodged in the chute.In drawing material from a loading chute it is drawn out a car at a time, and the intermittent flow of the material .increases its tendency to hang. When the obstruction in the chute is near or at the loading gate, the chute pullers start the ore by punching it with iron bars inserted through openings in the chute gate. When the obstruction is beyond reach of the bars, other means of starting the ore must be used.In some systems of mining, chutes or ore raises are built with timber as the stope extends upward. Generally, a manway is left alongside of the chutes, and when the ore hangs in a chute usually it can be started by a miner from the manway ladder by pounding on the timbers of the chute or by punching the ore with a bar inserted through small holes in the chute lining. Special methods of starting clogged ore, such as shaking a chain left hanging in the chute, are used at some places.In other systems of mining, ore passes or chutes are run through solid rock and when the ore hangs in one of these passes, either it must be blasted or else started from the top. Sometimes the ore can be started by running water into the top of the chute, but if the water does not start the ore moving, it must be blasted from underneath. This is done by detonating a bundle of cartridges under the obstruction in the chute or raise."

Jan 1, 1927

By Charles L. Kimbell

On the basis of world production data alone, 1985 appears to have been a year in which the world's mineral industry took another step upward in its recovery from the very poor years of 1981, 1982, and early 1983. Despite a drop in the output of crude oil, which was the single most significant crude mineral product from the viewpoint of value, the estimated value of world crude mineral production advanced by 3.4% to about $1,054 billion constant 1983 dollars, with output increases logged for nearly two-thirds of the commodities and forms of commodities for which the U.S. Bureau of Mines calculates a total world output. However, the economic well-being of any industry or group of industries cannot be measured solely in terms of the volume and/or value of its production, and examination of statistics reflecting other aspects of mineral industry performance shows that 1985 was a less than ideal year in many respects. In the case of consumption of mineral commodities, although there were gains registered in diverse sectors such as iron and steel, aluminum, fertilizer materials, solid fuels, and gaseous fuels, there were also proportionally small but notable declines in use among the older major nonferrous metals (copper, lead, tin, and zinc) and in the all-important liquid fuels. In the case of international trade in mineral commodities, although comprehensive data for 1985 were not yet available, there were indications that the value may well have fallen below the estimated 1984 level of $632 billion, although the volume may have increased slightly. This, if true, would be chiefly the result of declining prices of mineral commodities, and indeed, price declines were noted for a number of significant materials in terms of current dollars, and even more would register declines if calculated on the basis of constant dollars, adjusting for inflation.

Jan 1, 1987

By R. D. Wilson

Ten to twelve million tons of dust is produced by cement kilns annu-ally in the United States, resulting in a serious waste disposal problem. The Bureau of Mines investigated two alkali volatilization methods for converting this dust into materials for making portland cement and a useful potassium product. Portland cement kiln dust was found to be composed of finely ground cement raw materials (CaC03 and 8i02) having a layer of alkali sulfate (K2S04 and Na2S04). In this form, it cannot be directly recycled to cement kilns because concrete is weakened by a reaction between the alkali and the aggregate. Portland cements with 28-day strengths above 5,000 psi were produced from low-alkali residues using sintering and melting methods. For nearly complete removal of alkalies, primarily potassium sulfate, from cement kiln dust, a temperature above 1,300° C and a reducing atmosphere were required.

Jan 1, 1986

By Jos. R. Guiteras

This paper describes the operations of the St. Joe Mining & Milling Co. in Boulder County, Colo., as of June 1936. Later a brief visit was made to the mine in September 1936; information obtained at that time has also been recorded. The company operates a gold mine, the Grand Republic, in the Sugar Loaf mining district; a 100-ton flotation mill in Lefthand Canyon near Gold Hill; and a custom sampling punt, the Boulder Ore Sampling Works, at Boulder, Colo.

Jan 1, 1937

By R. J. Leary

The Bureau of Mines experimental blast furnace was blown with oxygen-enriched blast in combination with natural gas injected at the tuyeres. The air blast was augmented with oxygen to form an enriched blast containing 24,8 pct oxygen, and tests were run at natural gas injection rates of 4.5, 6.0, and 8.3 pct of the air blast. Similar enrichment to 26.8 pct oxygen was tested at natural gas rates of 7.2, 9.1, and 11,0 pct of the air blast. At intermediate proportions of natural gas to oxygen, (1) the fuel rate and the replacement ratio of coke by natural gas were unaffected by oxygen injections and (2) the productivity increased about 4 pct for each I pct oxygen added to the blast. The higher proportions of natural gas to oxygen were less efficient; in return for a lower coke rate, the fuel rate increased and productivity declined. A deficiency in reducing gas imposed a limit upon lower than normal proportions of natural gas to oxygen. Beyond this limit the formation of reducing gas was insufficient to support the rate of metal production. When this condition was encountered, the coke rate requirement for specification iron was abnormally high and production fell off badly. Adiabatic flame temperature is discussed as a means for proportioning oxygen and natural gas additions.

Jan 1, 1967

By W. B. Tarpley

This program was conducted to demonstrate the unique advantages of suppressing methane ignition in underground mines by use of Energy & Minerals Research Company's thixogel fire extinguishing system, which stably suspends dry powder extinguishing agent in thixotropically gelled liquefied gas extinguishant. As anticipated, the project demonstrated thixogel system advantages of: 1) capability to disperse state-of-the-art powders in thixogelled Halons; 2) non-agglomerating stability for dependable expulsion; 3) stability in storage for long shelf life; 4) virtually in¬stantaneous dispersion; 5) expansive cloud formation; 6) reach and re-forming around obstacles; 7) at least twice the extinguishant effectiveness; and 8) compatibility of use with Fenwal bottles and MSHA canisters. Thus, it should prove a superior explosion/fire suppressant for coal face cutters and triggered barriers, as well as for motorized equipment, electrical equipment and the like.

Jan 1, 1981

By Arthur Crowfoot

This paper describing t o concentrating practice of the Phelps Dodge Corporation, Morenci Branch, at Morenci, Ariz., is one of a series of articles on concentrating methods and posts being prepared by the Bureau of Mines. The Morenci concentrator, locally known as No. 6 concentrator, treats 5,000 dry tons of ore per 24-hour day by primary tabling followed by two stages of flotation treatment, at 48-mesh size and 65-mush size respectively.

Jan 1, 1931

By A. Visnapuu

The U.S. Bureau of Mines investigated the oxidation of American Iron and Steel Institute (AISI) Type 304 stainless steel (SS) during annealing in simulated combustion products from several air-CH4 fuel ratios. Atmospheres representing air-CH4 ratios of 14:1 and 18:1 contained free 02, while atmospheres representing 10:1 air-CH, ratio did not. A Cr203 layer formed on SS samples annealed in atmospheres containing free 0, while a Cr-Fe spinel layer formed in atmospheres with no free 02. The Cr203 layer was adherent and presented a protective barrier to metal diffusion, effectively limiting oxidation of the metal substrate. The Cr-Fe spinel was not protective and allowed the diffusion of Fe through the spinel to the gas-oxide interface where it was oxidized to magnetite, which spalled from the surface. This resulted in thick scale layers on samples annealed in atmospheres containing no free 02, as compared to layers formed on samples annealed in atmospheres containing free 02. These results confirmed and explained industrial operators' observations that thick, smoky (fine spalled magnetite) scales form on SS annealed in low free-02 atmospheres, while thin protective oxide layers form on sheets in atmospheres containing free 02.

Jan 1, 2010