Search Documents

By S. G. Ozkan

An investigation was carried out into the effect of physical parameters, such as particle size of the sample, residence time, solid/liquid ratio and impeller speed in the flotation cell, on the solubility in soft tap-water of colemanite (calcium-bearing borate) from Emet, in Turkey. Solubility increased steadily with residence time from 5 to 20 min but only minimally thereafter. There was a similar increase with impeller speed from 500 to 1 500 rev/min, beyond which a solubility of around 1.05 g/l was again established. There was a slight decline in solubility as the solid/liquid ratio was increased from 1 to 30%, with stable values around 1.05 g/l at a 20% ratio, while a sharp decrease was observed with decrease in size down to the -20 micrometre fraction. The effect of solubility should be taken into account if the application of a wet-processing method is being considered for the ore, while it can also result in losses of material during handling and storage

Jun 21, 1905

By L. G. Billington

"The Agnew nickel deposit occurs in a major linear greenstone belt in the Archaean Eastern Goldfields Province of Western Australia, and has been subjected to mid-amphibolite facies nietamorphism of dynamic style. The largest dunitic ultramafic body in the Perseverance Block is host to the bulk of the nickel mineralization. The Perseverance Ultramafic is mineralogically zoned and has an embayed western margin against a mixed metasedimentarv-metavolcanic wallrock sequence.Three categories of nickel sulphide mineralization are concentrated on this western margin at the thickest part of the ultramafic exposure. Massive sulphides characteristically occur as contact mineralization, internal mineralization and as remobilized concentrations in vein form structures. Disseminated ore constitutes the largest volume of mineralized materials in the deposit and occurs in three separate shoots in en-echelon relation. Weakly mineralized 'cloud sulphide' zones surround and envelop the shoots and persist much further along strike. In the upper mine levels the shoots are truncated by a shear or crush zone, which inhibits geological knowledge to the south but marks a major fundamental structural break.Most of the ore types have suffered supergene alteration and there is a complex variable distribution of the mineralogical facies. The ore types have been metamorphically retextured, but the oreshoots can be characterized by their Ni tenor and some chemical ratios. S/Se values, PGF. and precious metal values are distinctly different from those of other nickel sulphide ores extracted.Despite intense structural and metamorphic modification of the mineralizations, some features support an original magmatic derivation for the sulphides. These include the localization of massive sulphide ore types on one marginal contact within an emhayment structure, the general distribution of disseminated mineralizations located immediately above the massive sulphides and the Ni/Cu, Ni/Co, Fe/Ni ratios of the oreshoots being similar to those of deposits that typify the intrusive dunite- associated class of nickel sulphide deposit. Varying S/Ni ratios between different shoots suggest a revision of the single magmatic intrusion model in favour of a changing composition between successive magmatic episodes."

Jan 1, 1984

By A. Ludkin

The paper presents the history of the occurrence of spontaneous combustion in the north area, together with the associated problems. These are examined and a description is given of the methods used to combat the danger, including the use of modern scientific instrumentation. Detailed reference is made to the underground trials with pack injection and sealant coatings which were carried out at Seafield Colliery following the formation of a working group to assess the performance, in the same underground conditions, of (1) sandbagging, (2) pack injection, (3) surface coating. Based on these trials, an improved and more economical method of prevention has been established. There is, however, still scope for further improvement in techniques which would take into account the problems of gradient, transport, manpower and cost.

May 23, 1905

By B. M. England, L. C. Mackey

Magnesia minerals are included in most iron ore sinter mixes to provide the MgO requirements of blast furnace slag. The properties of these minerals have an influence on the eventual sintering properties of the mixes. A detailed study was undertaken of serpentine and dolomite and the use of limestone, olivine and magnesite was also investigated. A consideration of particle properties indicated that as these materials calcine a reduction in size can occur together with cracking and changes in surface properties. These changes could affect the permeability of the sintering bed and sintering performance. Studies of sintering reactions showed that magnesium and calcium, formed from the calcination of dolomite, are extremely mobile before the formation of melt. Evidence suggests that the movement of these oxides into surrounding areas is via a solid-state diffusion process. The diffusion of Ca into the surrounding hematite particles is faster than that of Mg, resulting in the formation of dicalcium ferrite and magnetite or magnesioferrite, the last two subsequently being converted to dicalcium ferrite in the presence of Ca with removal of Mg from the structure as ferroan periclase. Studies of pilot-plant sinters indicated that reaction mechanisms formulated from the bench-scale studies were occurring in actual sintering processes. The differences in sintering reactions between dolomite and serpentine were considered to be the major cause of differences in the availability of lime for bonding phase formation. Pilot-scale studies indicated that the sintering properties of a mix containing dolomite could be improved by increasing the basicity of the sinter mix while keeping the MgO level constant

Jun 18, 1905

By D. G. Skinner, J. H. Griffiths, F. T. Williams, A. G. Withers

"The absence of homogeneity, in dust-clouds underground indicates the use of a method in which the volume of air sampled is an appreciable proportion of the total volume under consideration. Of the available methods, only the impinger and gravimetric techniques seem to comply with this requirement. In practice, greater efficiency of collection of the smaller particles is possible by the use of a gravimetric filter than with the impinger. For this reason if, as seems desirable, a standard method of sampling be sought, the adoption of a gravimetric technique is to be recommended.Provided that the amount of dust collected is reasonably large, the paper filter would seem to be preferable to the solid crystal type of filter on account of its greater convenience in use.Alternative methods of sampling are desirable to cover the wide range of practical conditions."

Jan 1, 1947

By A. S. W. Kurny, M. Z. Huq

Bangladesh ilmenite is partially altered, containing pseudorutile, rutile and haematite as well as the predominant ilmenite phase. A typical analysis is 39.45% TiO2, 24.19% FeO and 33.0% Fe2O3. Reduction of the ilmenite by charcoal was found to involve two major reactions: conversion of pseudorutile into ilmenite and rutile, and change of ilmenite into metallic iron and rutile. The first, which was much the faster reaction, was responsible for an initial increase in ilmenite content with reduction time at lower temperatures. Apart from these two major reactions, rutile was reduced to lower oxides at 1 100 degrees C with a consequent decrease in its XRD peak height

Jun 19, 1905

By S. Al-Hassan

The deposit has been exploited for Mn oxide and carbonate since 1916. Known reserves of MnO, however, are almost depleted and the survival of the mine will depend on the exploitation of the carbonate. Kriging, inverse distance weighting (IDW) and cross-sectional methods have been applied to the evaluation of the carbonate resources and reconciliation of the estimates obtained shows that kriging and IDW give almost identical block values. A comparison using conditional probability indicates that there is virtually no difference between the global reserve estimates derived from the cross-sectional and kriging methods. The physical causes of these similarities are highlighted and the problems of dealing with multimodal distributions are discussed together with the difficulties of semi-variogram modelling

Jun 19, 1905

By I. L. Bell

The ironmasters of America had asked the Iron and Steel Institute to visit the USA. The Council decided it was not possible to accept, but Mr. Bell visited; this is an account of his trip. Topics covered include transport, charcoal, coal measures, coal, anthracite, bituminous coal, flux, magnetic iron ore, specular iron ore, limonite, red hematite, clay ironstone, black band ironstone, smelting works, blast furnaces of Pennsylvania, Lake Champlain furnaces, Lake Superior furnaces, Cleveland furnaces, Pittsburg furnaces, Missouri furnaces, and those of the southern states. He goes on to describe Catalan hearths, malleable iron works, Bessemer works, the Blair steel process, and labour.

Jan 12, 1875

By A. Dean, J. Roberts, I. Stone, J. R. Merefield

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 10pp., 11 refs. No completely reliable method for characterising and quantifying airborne dust risk exists. A new monitoring technology has been developed whereby dust collected from four-way directional and high volume samplers is analysed for mineral content and particle size for integrated dust mapping. A dust database was set up for the area surrounding the Ffos Las open cast coal site in South Wales. It included XRD directional traces from 17 gauges over 20 months, XRD traces from window ledges in the nearby communities, the major soil types in the area, dust data from haulage roads and public roads and reference-type mineral samples. The database can be accessed relationally to compare and analyse the data using mineral, direction, time, weather and geographical relationships. The data has been used to assess areas of low, intermediate and high levels of risk from dust fall-out

Apr 1, 1995

By B. M. England, C. Y. Yang, L. T. Matthews, J. Y. Yin

The domestic concentrate used by the Shanghai Meishan Metallurgical Corporation in Nanjing contains significant siderite, magnetite and haematite, the siderite having a substantial influence on its sintering behaviour. On the basis of experimental findings and published information it is proposed that siderite decomposition starts at c.400 degrees C and results in the formation of CO and/or H2, which then reduces the haematite to magnetite prior to the initiation of high-temperature sintering; inter-mixed particles of Australian haematite and pisolite ores also undergo significant reduction. As the gaseous reduction process is so effective, low-temperature forms of silico-ferrite of Ca and Al (SFCA) cannot form even at high sinter basicity. The bench-scale results were confirmed in a pilot-scale facility whose sinters consisted mainly of magnetite, high-temperature SFCA and glass, which is typical of sinters formed from mixes with high magnetite levels

Aug 1, 1995

By A. P. Gize, J. F. W. Bowles, D. J. Vaughan, S. J. Norris

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. Geological evidence from tropical laterites indicates clearly that platinum group metals are taken into solution and precipitated to form grains larger than those in the source rocks. Platinum and palladium move differentially in the surface environment, with Pt partitioning into soils and eluvial or alluvial deposits while Pd remains more mobile in natural waters. Natural organic acids, particularly humic acid, can interact with platinum-group elements and concentrate them even in areas where their content in rocks is very low. Experimental work has confirmed that Pt and Pd can be taken into solution by humic acid at room temperature and in geologically short time-spans. Solubility and deposition may be controlled by physicochemical conditions, reaction kinetics or an adsorption effect, or there may be two competing reactions, solubilisation assisted by organic matter and a kinetically slower metal precipitation

Apr 1, 1994

By R. G. Kidel, S. C. Doming

The project has shown that it is feasible for a junior company to reopen a narrow vein-style gold mine and successfully take it into production. An intimate understanding of the mineralisation and a flexible approach to mining are crucial, as are stringent cost control and efforts to keep overheads low. The project has confirmed the geological complexity of the Main Lodes, which consist of highly sheared quartz-sulphide infill in strongly sericitised granodiorite. The existence of discrete high-grade zones within the Hangingwall Lodes has also been confirmed. Broad low-grade zones continue to be recognised and require the local application of bulk longhole mining methods. The initial mine plan called for predominantly longhole stoping, but adverse ground conditions have meant that a switch to air-leg mining has produced higher run-of-mine grades. The excess capacity at the processing plant can best be used by batch processing, with its reduced maintenance requirements

Jun 21, 1905

By J. K. Brimacombe, F. D. Richardson

Studies have been made of interfacial turbulence occurring in reactions in which indium, zinc and cadmium, dissolved in amalgams, are oxidised into aqueous phases by ferric or mercurous ions. It has been found that this turbulence occurs when the concentrations of oxidising ions in the aqueous phase become sufficiently great. These concentrations are the same as those at which the mass-transfer coefficients in the aqueous phase increase sharply when both phases are stirred by gas bubbles rising through them. The effects of gas flow rate on the mass-transfer coefficients for zinc in mercury have been established, and the oxidation of pure mercury has been investigated. The relevance of the work to processes involving liquid metals is discussed

Dec 1, 1971

By S Colak, M Tunc, C Celik, M. M. Kocakerim

The most important parameters affecting the solubility of ulexite (sodium calcium borate) in H2SO4 were found to be reaction temperature and solid:liquid ratio, in that order. Dissolution increased with increase in temperature and stirring speed and with decrease in solid:liquid ratio, particle size and acid concentration, the last effect as a result of decreased precipitation of CaSO4 on unreacted particles. Optimum conditions, in which around 99.5% of the ulexite could be dissolved, were a reaction temperature of 60 degrees C, a solid:liquid ratio of 1:8 g/ml, an acid concentration of 8 mol/l, particle size smaller than 425 micrometres, a stirring speed of 52.33/s, a reaction time of 1 800 s, a calcining time of 3 600 s and a calcining temperature of 170 degrees C. These conditions, determined by the Taguchi method, are reproducible in a commercial production environment

Jun 21, 1905

By B. R. Reddy, Y. V. Swamy, B. V. R. Murthy, H. S. Ray

The Ni oxide was reduced with a CO-CO2-N2 gas mixture and the effects were observed of process variables such as roasting temperature, time and CO partial pressure. Extraction of over 90% of Ni was achieved by ammoniacal leaching of ore that had been reduced for 1 h at 760 degrees C under a gas mixture with a volumetric CO/(CO+CO2) ratio of 0.57. The kinetic data were found to conform to the Ginstling-Brounstein equation. The applicability of this model was confirmed by evaluating the apparent activation energy with the use of independently constructed differential and integral plots, which showed an excellent match

Dec 1, 1995

By S. C. Tennant, G. M. Steed

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Immobile-element lithogeochemistry is providing a detailed chemostratigraphy of the submarine Ordo-Silurian volcano-sedimentary sequence. Primary lithologies and magmatic affinities of the sericitised and silicified volcanics are determined from binary plots of Nb, Zr, Y, TiO2 and Al2O3, while mass-change calculations using immobile-element anchors can identify and quantify zones of significant hydrothermal alteration. Stratiform polymetallic mineralisation at the western margin of Parys Mountain, around the Penymynydd fault zone, has been shown to have a distinct hanging-wall and footwall stratigraphy. These ore zones are probably part of a homoclinal, north-younging volcano-sedimentary sequence. The apparent stratigraphic complexity results from primary lithofacies variations and pervasive alteration, with the modifying role of the Caledonian orogeny much less than previously suggested

Jun 19, 1905

By Stainier X.

The connexion between the Kent and the Continental coalfields on the one hand and the western British coalfields on the other has been for many years a controversial subject between geologists. These coalfields were once considered as detached portions of a former extensive sheet of Carboniferous deposits, but some geologists seem now to incline to the view that they were never connected. The writer hopes to show that the problem is one of the most difficult of geological investigations; that we are still far from a perfect solution; and that both of the extreme theories must be set aside. The physiography of NW Europe during the Carboniferous, with its various generations of earlier folds, is outlined and the features of the Lower and Upper Carboniferous anticlines and synclines discussed, followed by consideration of the denudation of the coalfields and local descriptions of the Malvernian range and Usk anticline, the Pennine chain, the Shropshire coalfield and the Kent coalfield. An attempt is made to trace the transverse Midland anticlines southwards and to deal with the intervening syncline: for example, if the dissymmetrical profile of the Pennine Chain holds good at its southern end then the syncline west of the chain must be deeper than the syncline east of it (the Kent syncline), and in this syncline the deepest part must be at its south-eastern corner, and therefore south of the diagonal ridge. T here is some actual evidence of the existence of Coal-Measures in this syncline, as the results of the Batsford and Burford borings prove. The hypothetical character of most of the conclusions will prove, beyond any doubt, how fa r geologists still are from a perfect settlement of this problem, and how much this settlement is dependent on the more or less advanced state of knowledge regarding all the geological features of these coalfields and of the surrounding country

Dec 1, 1916

"The Archaean komatiite-associated nickel sulphide deposits at Kambalda, Western Australia, exhibit a number of stratigraphic features that are indicative of a strong volcanic control on ore localization, including (1) a restriction to specific basal cumulate metakomatiite host units, (2) confinement within distinctive synvolcanic embayments in the footwall and (3) variations in the internal structure and composition of overlying and adjacent barren metakomatiite flow's and the distribution of interflow metasediments with proximity to the ore zones.The high magnesium content of the host units (up to 45% MgO volatile-free) in comparison with that of aphyric or spinifex- textured lavas (16-32% MgO) has been considered previously to indicate either magmas/lavas rich in intratelluric olivine or selective accumulation of olivine phenocrysts. The marked linear trend of the oreshoots, basal host units, footwall embayments and the volcanic stratigraphic relationships have been used as evidence for local linear feeding fissures. Rare relict igneous olivine in some host units is, however, demonstrably not intratelluric, and there is no direct or indirect evidence of a proximal eruptive site (e.g. footwall feeders, pyroclastic breccias, ultramafic intrusives) at Kambalda such as at some other deposits of this type. Kambalda is interpreted as a distal rather than proximal volcanic environment.Emplacement of the komatiite sequence at Kambalda was probably controlled by the locations of a few specific eruptive sites relative to regional topographic gradients and influenced by the topography of the pre-existing volcanic surface. Olivine enrichment in the basal host units occurred by in-situ fractionation and cumulus crystallization of olivine during longitudinal lava flow within linear lava conduits, possibly centralized on depressions between non-overlapping footwall basalt flows. The distinctive stratigraphic relationships are attributed to localization of lava conduits along the volcanic pitchline, flanked by more slowly moving parts of the flows. There are analogies with the physical volcanology of Modern basaltic and Proterozoic komatiitic lava flows.A corollary of this model is that the lava conduits thermally eroded and assimilated sulphidic sediments, contributing additional sulphur to sulphur-saturated komatiites or possibly inducing sulphide separation in originally sulphur-undersaturated komatiites. The latter would account for the restriction of ores to linear cumulate komatiite host units (thermally active lava conduits) and the locally mutually exclusive, but stratigraphically equivalent, relationship between the ores and sulphidic metasediments at Kambalda."

Jan 1, 1984

By G. B. Harris, A. R. Laplante

Fine tungsten was used to mimic gold and fine and coarse silica and magnetite to mimic gangue. The optimum flow rate of fluidisation water varied from 1.7 l/min for fine silica to 5.6 l/min for coarse magnetite. Overloading at optimum flow rate was then investigated. With fine silica gangue no overload occurred under any of the conditions studied, and there was very little overload with fine magnetite. Coarse silica caused appreciable overload, but only after a significant bed of tungsten had been formed; with fine magnetite gangue the onset of overloading occurred earlier. Finally, with coarse magnetite severe overloading occurred almost immediately. Overloading was modelled using a first-order kinetic rate constant for erosion of the concentrate bed and a critical mass of constant above which it takes place. The results clearly demonstrate the importance of removing oversize to maximise recovery, particularly with a high-density gangue

Jun 18, 1905

By R. J. Pine, J. S. Coggan

Distinct-element modelling has been used to study the mechanisms associated with observed deformation of the western face of the quarry. A complex failure mechanism involving distinct planar surfaces that was proposed for a slope failure in 1967 has been modelled and shown to be plausible. In addition, deep-seated flexural toppling may contribute to the slope instability. Modelling has confirmed the detrimental influence of a raised water-table on the stability of the slope and also indicates that the observed cyclic opening and closing of tension cracks may be attributed to seasonal rise and fall of the groundwater level

Apr 1, 1996