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By B. Gazea, A. Kontopoulos, A. Kourtis, K. Adam

Static tests give a measure of the balance between acid-producing and acid-neutralising mineral components in a material, while kinetic tests determine acid generation and neutralisation over a long period. Drill-core samples from the amphibolite and gneiss host rocks of the Stratoni lead-zinc sulphide deposit in Greece and mine/mill waste samples from Stratoni and Olympias were examined by the standard acid base accounting, BCR and net acid production tests. Mineralogical data on the materials and resulting residues were used to illustrate the differences between the methods and establish their ranges of applicability. BCR seems to simulate most closely the conditions prevailing during generation of acid mine drainage but is time-consuming and requires elaborate equipment. Acid base accounting is suggested for standard screening; net acid production might be used in the field or for solids with less than 10% S

Jun 19, 1905

By M. Foguenne, A. van Lierde, P. Henry

Leaching experiments were carried out on a spent catalyst sample with a honeycomb structure, containing 47.5% Ti, 5.8% Mo, 2.7% Si, 2 035 ppm As, 52 ppm Pb and 8.8 ppm Hg. More than 93% of the Mo and As was removed by direct alkaline leaching after grinding to 80% -36 micrometres. The residue contained 0.3% Mo and 60 ppm As. To obtain a TiO2 matrix with 30 ppm As, acid leaching at controlled pH with 90 kg/t Al scrap was followed by oxidising alkaline leaching. Treatment of the direct alkaline leach solution or of the mixed solutions from the two-stage process involved two successive operations: purification by neutralisation with Al(OH)3 addition to raise the Al concentration to 4 g/l, and ion exchange on Amberlite IRA 94 S resin. Whatever the type of solution treated, elution with 200 g/l NH4OH solution gave an eluate of very high purity containing 164 g/l Mo, less than 70 mg/l V and less than 2 mg/l As

Jun 19, 1905

By T. C. Alex, S Srikanth, Premchand

It has been suggested that reduction of the iron and manganese phases as far as FeO and MnO is preferred for the complete liberation and selective reduction of the copper, nickel and cobalt oxides in manganese nodules. The oxygen partial pressure/temperature regime suitable for this purpose has been delineated. Free-energy minimisation and thermogravimetric results indicate that the requisite conditions can be achieved if more than 10% of neutral oil is used at temperatures greater than 923 degrees C. Neutral oil content, temperature and roasting time have been optimised to maximise leaching recoveries of Cu, Ni and Co: up to 96% of Cu and Ni and up to 85% of Co can be recovered if 15% of neutral oil is used as a reductant at 973 K for 90 min

Jun 21, 1905

By S. Babendererde

The twenty-ninth Sir Julius Wernher memorial lecture of the IMM, presented at Tunnelling '97, London, 2-4 September 1997. The tunnelling industry is well prepared to face the challenge from the population explosion in urban areas in the near future. Many well-established yet redundant concepts are still impeding progress, however, including the prediction of excessive surface ground settlements. The correct selection of TBM can minimise these, and ground deformations can be avoided completely if the appropriate techniques are applied. Advanced techniques have been used in the Tokyo Bay Crossing, where the tunnel lining was installed by robots. Other advanced techniques include the use of a sliding slip form to give temporary support to an extruded tunnel lining, the chemical processing of ground by polymers during earth-pressure balanced tunnelling and the use of electronic monitoring and steering devices in TBMs. There will be challenges to tunnelling in urban environments, as open cut techniques will no longer be tolerated. Two examples of mined stations are briefly discussed

Jun 19, 1905

By R Adamian, F. T. Da Silva, D. H. Gameiro

Schytill and Geldart diagrams were developed for the TiO2-C-Cl2 system at 1 073 and 1 273 K, so as to define the hypothetical relations between particle sizes and chlorine velocity for simultaneous fluidisation of mixtures of anatase concentrate and charcoal for carbochlorination. It was concluded that the operating limits on chlorine gas velocity will be controlled by the behaviour of the reducing agent, mainly because of its lower density. An increase in temperature from 1 073 to 1 273 K will have only a small influence on the fluid-dynamic behaviour of the mixture. For bubble fluidisation, the maximum sizes 0.413-0.478 mm for anatase and 0.529-0.611 mm for charcoal will be adequate. When the particle size distribution is large, fluidisation will be feasible only if conducted in two stages, otherwise the residence time of the small particles in the reactor will be very short. New diagrams will be needed for the gaseous chlorides in the second stage

Jun 21, 1905

By A. Z. Lang, D. A. Hall

After a brief description of the causes of spontaneous heating and of general preventative methods, a detailed account is given of occurrences of spontaneous heating in the Main Seam (locally known as the 5/4 Seam) at Westoe Colliery. This seam is about 12 feet thick consisting of hands of coal and shale, but only 4 feet 6 inches is worked because of the thickness os strata in water-bearing rocks and the worked section is selected on quality considerations. An advancing longwall face in this seam (2nd South) began to heat after working for six months and ultimately had to be abandoned. By adopting retreating methods and mining narrow panels it has been possible to extract this coal at an excellent rate of productivity. The system of goaf ventilation is important, because the use of a bleed road would have given rise to dangerous conditions in a goaf which of necessity would have contained fallen coal. Preparatory seals were prepared at selected sites so that, if necessary, a panel could be sealed off quickly; these seals are completed as soon as possible (within three weeks) of finishing a panel. A gas sampling system has been instituted which includes daily sampling on the face and in the goaf, and weekly sampling at the stoppings of all completed panels. The coal has now been extracted from this seam for three years without any further difficulties from spontaneous heating.

May 23, 1905

By Jinsheng Chen, S. S. Peng

The relationship between support performance parameters and parameters representative of mining and roof conditions is characterised by uncertainty, non-linearity and dependence, so the theory of artificial neural networks was selected as a basis for shield design. A computer program based on a back-propagation training algorithm was written to derive the weighting factors between inputs and outputs from field data; once these had been established two mathematical models were developed to describe the relationship. Back-calculation of field data indicates that the results generated from the neural network models are much more accurate than those derived by traditional methods and can be used with a higher level of confidence. The support density, possible yield frequency of face supports and interval of periodic roof weighting under specific mining and roof conditions can be determined by application of the models

Jun 21, 1905

By A. T. Iannacchione

Underground mining of stone in the US is increasing, as is the depth of overburden above the mines. Data gathered from mine visits, maps, discussion with operators and numerical simulation have been used to investigate pillar design and recommend safe practice. Many pillars have slender shapes with relatively large adjacent mine openings: width-to-height ratios range from 0.54 to 3.13 and extraction ratios from 0.56 to 0.91. The pillar material is often very strong and average overburden only 80 m, but occasional failure due to excessive local stress has occurred where pillar size had been unintentionally reduced, overburdens were greater than 200 m, width-to-height ratios were less than 1.25 or extraction ratios were greater than 0.83. Pillars with width-to-height ratios of less than 1.5 appear more likely to fail under excessive stress. When width-to-height ratios fall below 1.0, defects such as through-running discontinuities can have a significant influence on stability. Dip, orientation and material properties are also important

Jun 21, 1905

By C. S. Spirakis, A. V. Heyl

Paper presented at the conference Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. The modified basinal brines, containing partly oxidised sulphur species, scavenged metals from basement rocks and sediments and transported them through the host rock, which contained local concentrations of organic matter. Reacting in various ways with the mineralising solution as temperatures at the sites of mineralisation changed, organic matter caused the precipitation and dissolution of a variety of minerals in the ore zones; it was organic matter that caused all of these reactions to occur at the same sites. Thus all components of the mineralising fluid - salt, water, heat, sulphur and metals - were obtained within the ore district. The siting of the mineral districts was related to the locations of faults through U- and Th-enriched granites beneath sediments containing basinal brines, and the locations of ore deposits within the districts were controlled by local concentrations of organic matter

Apr 1, 1995

By J. S. WARWICK, E. J. Browning

Ignitions continue to occur underground, sometimes leading to major explosions. There has been considerable effort in the UK, and more widely in the European Community, to formulate the best ventilation practices and other means of minimising these incidents. Practices and procedures to prevent ignitions are discussed in the light of the risks from current mining methods.

Jan 1, 1993

By J. H. Morris, G. M. Steed

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Oxygen isotope analysis indicates that quartz, carbonates and muscovite could all have formed in near-isotopic equilibrium with the mildly saline H2O-CO2 ore fluid at 330 degrees C. Calculated values for O, C and S in the ore fluids imply derivation from a deep, homogeneous source region and are consistent with formation either as a direct or an indirect result of igneous processes. Values for delta-O18 plot a little outside the accepted magmatic range, but have almost certainly been modified by exchange reactions with wall rocks. These reactions were also the most likely cause of deposition of the ore constituents. The chemical and isotopic character of the fluid was similar to that in many Archaean and later mesothermal auriferous vein systems, especially the Mother Lode region of California. If the Southern Uplands-Longford Down accretionary complex conceals an Ordovician arc, the tectonic setting was also broadly comparable

Jun 19, 1905

By Hardwick F. W., O'Shea L. T.

The survey covers: coal-mine lighting prior to the invention of the safety-lamp, including candles, the flint-and-steel Spedding mill, and mirrors; the growth in knowledge of firedamp; the Society in Sunderland for Preventing Accidents in Coal Mines; Dr. Clanny's blast lamps and steam lamps; George Stephenson's tube-and-slider lamp, triple-tube lamp, punched-plate lamp and gauze Stephenson lamp; Sir Humphrey Davy's lamps; the controversy over invention priority, and other early forms of safety-lamp; 1816-1835 developments including the lamps of Upton and Roberts, M.Mueseler, John Martin, Dr. Clanny (new 4th lamp), M. Agre, John Newman, Gossart and Roberts, Francis Ellis, John Dillon and Mr. Wood (refrigerating lamp); 1836-1843 developments, notably of Mueseler lamps; 1844-1866, including lamps of the Davy, Clanny, Boty, Eloin and other types; 1867-1879, including the Gray lamp; 1880-1887, including the Marsaut lamp; and 1888-1913. Detailed reference is made to the findings of various relevant Royal Commissions and appendices include a list of the safety-lamps described in an appendix to the 1886 report and a publications list. The paper was prepared for the International congress of mining, metallurgy, applied mechanics and economic geology to have been held in London in July 1915. Discussion (p.718-724) includes a brief comment by Blackett W.C. and a longer contribution by Ashworth J., with the authors' response

Dec 1, 1916

By R. A. D. Pattrick, R. A. F. Ixer

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. At Calliachar Burn, 14 steeply dipping quartz-sulphide veins, with and without gold, infill master joints that crosscut gently dipping metasediments and metabasics of the Pitlochry Schist Formation. The wallrock is extremely bleached and enriched in sericite, chlorite and carbonate. Gold grades vary from high with quartz-galena-pyrite to low with galena-chalcopyrite; the gold forms electrum inclusions smaller than 20 micrometres in pyrite or, rarely, arsenopyrite. At Urlar Burn, gold is present in small amounts in 4 quartz-galena-chalcopyrite veins. Although much of the mineralogy is similar to that at Calliachar, there are significant differences in Sb-, Te-, Bi- and Hg-bearing phases. Fluid inclusion data suggest mineralisation occurred over the range 320-140 degrees C, from fluids with significant CO2 and 2-13 wt% equiv. NaCl. Mantle-derived fluids appear to have been generated during the late Caledonian and focused by the Urlar Burn fault

Jun 19, 1905

By R. A. Ixer, R. A. Lord, H. M. Prichard, A. J. Boyce, P. McConville, C. T. Pillinger, I. P. Wright, J. Maynard

Analysis of 62 samples show that the sulphides throughout the igneous stratigraphy have a magmatic signature, with the exception of the uppermost gabbros and the lowermost basal thrust talc-carbonate lithologies. Mean delta-34S values for whole-rock samples from harzburgites, dunite pods in harzburgite, crustal dunites and wehrlites, the main and high-level pyroxenites and gabbros suggest that the primary sulphides derived their sulphur from a magmatic source enriched in 34S. This finding is compatible with the proposed origin of the ophiolite above a subduction zone. Values for pyrite mineralisation in the uppermost part of the gabbros are thought to result from precipitation from a seawater-derived fluid, while isotopically light sulphur in the basal thrust could have been introduced from underlying metasediments. The replacement of pentlandite by heazlewoodite has not led to sulphur fractionation

Jun 19, 1905

By S Durucan, A Korre

The application of simple methods of statistical analysis, coupled with geostatistical analysis and geographic information systems, can only summarise and give an outline of the spatial distribution of the parameters measured. Spatial analysis of the components or factors calculated, through principal component analysis or factor analysis, allows assessment of the geographical distribution of the dominant processes contributing to soil composition and/or contamination. Neither of these tools, however, distinguishes between the different sources of pollution. The application of canonical correlation to the data, driven by expert appraisal of the potential pollution sources, allows their quantitative and spatial assessment while GIS provides the environment in which to organise and present the results. The methodology is illustrated by its application to soil-contamination data from the Lavrio area in Greece, where silver-bearing orebodies have been mined for more than 25 centuries

Jun 21, 1905

By R. A. Halatchev

A risk model for assessment of the uncertainty in the forecasts of the planned profit is developed. It is based on the selling price of the metal recovered from the ore and the production per shift of the excavators. These two critical variables characterise the economic and technical aspects of the mining venture. Time-series methodology is used to describe the behaviour of the economic variable, which improves the adequacy of the modelling. A hypothetical open-pit gold mine is used to illustrate the application of the model. Results obtained show that the model is a good alternative to sensitivity analysis in taking account of the stochastic character of the price of the metal recovered from the excavated ore and the production per shift of the excavators used. The model can be extended by the inclusion of new variables that have a probabilistic nature

Dec 1, 1996

By A. R. Naderian

Laboratory strength and deformation testing of freshly blasted sandstone and claystone overburden from Jeebropilly colliery in Queensland and in-situ plate-bearing tests on four backfills of different ages showed that the bearing capacity of backfill is a function mainly of compaction, not of age. The modulus or stiffness of the backfill is significantly increased by previous loading, in some cases up to threefold. Backfill material experiences some compaction through the passage of mining vehicles, likely to provide a bearing capacity that will support normal construction activities; the limited testing performed suggested that completed backfills are capable of supporting loads of up to 200 kN/m2 while sustaining displacements acceptable for a wide range of residential and industrial uses, but may be susceptible to collapse settlements due to saturation in the long term

Jun 19, 1905

By K. C. Garner

The visit reported was made with support from the 1997 J.C. Boyle travelling scholarship. The management and control of hazardous gases released into the underground environment are an integral part of coal mining. The power-generations stations at Appin and Tower collieries, with a combined electrical output of 94 MW, have been operating for some time and have demonstrated a technology that is able to exploit the available gas fully. Contributory factors have been the development and introduction of directional drilling techniques, pre- and post-drainage of coal, relatively high seam permeability, a high gas content of the worked seam, high production rates and a willingness to embrace new ideas and technology

Jun 21, 1905

By P. Golledge, A. D. S. Gillies

An investigation has been carried on samples of three Queensland coal dusts to determine the potential explosibility of dust-gas mixtures. The explosion potential of the samples was classified by the lean and rich limits of explosibility and the limiting oxygen concentrations for each sample. Plotting of these points showed 2-dimensional flammability limit surfaces for coal dust/oxygen, methane/oxygen and coal dust/methane mixtures. From these plots the 3-dimensional flammability envelopes defining the explosibility of the mixtures were defined. The explosion limits of the coal dust/methane/oxygen system were seen to be influenced most by the explosibility characteristics of coal dust. Methane exerted a stronger influence over the explosion limits when the coal had a low volatile content

Jun 19, 1905

By R. R. Hart, R. A. Evans

This paper outlines the the methods currently being used in the West Wales Area for preventing the occurrence of any outbreak of spontaneous combustion. Stress is placed on the importance of correlating the position of a Rider Seam which is prone to spontaneous combustion. The recent introduction of the UNOR Recorder has contributed to the ability to monitor the CO content of the general body of the air during any incident. The use of modern sealants and improved methods of applying them have enabled the few instances of spontaneous combustion in South Wales to be treated promptly and efficiently. The authors describe the current spontaneous combustion problems at two collieries.

May 23, 1905