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By T. Shumba

The solvent extraction section of an old Uranium Plant in the Vaal River region produced a sub-stance called Crud (Chalk River Unidentified Deposit) that formed within the aqueous/organic interface of the settler of the solvent extraction circuit. The crud was deposited together with gold tailings to the tailings dam many years ago. Previous research done on the crud confirmed that ex-posed crud leaches Mn and Ni at concentrations that are well above their acceptable risk limits as well as Zn that leaches at concentrations that are slightly lower than its acceptable risk limit. Soil washing and bioremediation technologies were employed to treat the contaminated soil. Various laboratory test work and the pilot scale studies were conducted in parallel with each other and the results of the laboratory studies were used to determine critical parameters. Four lixiviants, i.e. sulphuric acid, acetic acid, oxalic acid and ethylene diamine acetic acid were tested at three concentration levels i.e. 0.001M, 0.0001M and 0.00001M, respectively. Column tests showed that the leaching of the heavy metals increases as the soil porosity increases. Silica sand was added to increase porosity of the contaminated soil. Highest Mn removal was achieved mainly by sulphuric and oxalic acid at 0.001M at all soil levels. EDTA was significantly efficient in the removal of Ni and Zn. The recovery of heavy metals, particularly Mn, decreased as the depth of sampling in-creased. Heterogeneous bacteria and filamentous organism plate counts were conducted to evaluate the growth of the bacteria and filamentous organisms in the soil. Results showed that more organism growth took place in the bioremediated soil with a fertilizer added to it. The leaching of metals from the soil that was bioremediated in the pilot study was generally higher than the extraction of the metals from the soil that was leached with no bioremediation carried out. The results from this study suggest that the leaching of heavy metals from the contaminated soil is to a large extent dependant on the pH of the leaching solution. By increasing the soil?s porosity and bioremediating the soil, higher extractions of metals were achieved.

Jan 1, 2014

By Azin Zangooi, Cesar Gomez, James Finch

Frother concentration is a variable which significantly affects the flotation performance by decreasing bubble size and helping froth stabilization. Variations in frother concentration, which mostly go unnoticed in industrial operations, may affect these functions. Some factors that can cause variations include the fact that frothers are normally dosed based on feed tonnage and not solution concentration, unstable frother delivery, incomplete dissolution for low solubility frothers, addition of frother-free wash water, remnant frother in recycle waters and frother partitioning to the froth. A colorimetric technique developed for determining frother concentration on site makes it possible to detect the occurrence of these problems and to establish their magnitude, allowing conditions to be adjusted to reduce frother concentration variations. By sampling and analysis, frother distribution throughout a circuit can be established, referred to as ‘frother distribution mapping’. Experiences at several concentrators processing sulphide ores are used to illustrate time restrictions for sample analysis, and to demonstrate temporal and spatial frother concentration changes as a consequence of variations in the grinding stage, recycled waters containing frother, and frother partitioning.

Jan 1, 2014

By W. Kobal

The extraction of nickel (Ni) and cobalt (Co) from the laterite deposit of Ramu nickel-cobalt Project in Papua New Guinea was performed in this study. Chemical analysis by Inductively Coupled Plasma (ICP-AES) atomic emission spectrometer, SPS-3000 (Seiko Instruments (Inc.), shows the ore contains 48% Fe, 1% Ni, 0.1% Co, 1.8% Al, 0.14% Mg, and 0.8% Mn. Characterization by X-ray diffraction (XRD) analysis of the laterite ore obtained from the mine site shows the ore contains 70 to 80% goethite (FeOOH), assuming Fe content of 48% is mainly from geothite. The main leaching parameters investigated include; slurry temperature, leaching time and sulphuric acid (H2SO4) concentration to evaluate nickel and cobalt extraction. For all experiments, 10g batch samples are put into 300 ml beaker containing 100 ml of sulphuric acid of varying concentrations (1M, 2M, 4M). During the leaching period, 5 ml slurry samples are withdrawn at different times and filtered to obtain filtrate for ICP analysis to monitor nickel and cobalt extraction. Solid samples at the end of all tests are also obtained by filtration and after drying, XRD and ICP tests are performed to monitor nickel and cobalt contents. According to the test results performed at normal atmospheric pressure, over 99% of nickel and over 50% cobalt were extracted into solution within 120 min at 95ºC in 2M H2SO4 solution. Similar results were obtained when only temperature was reduced to 90ºC, but cobalt extraction increased to over 70% when leaching time was increased to 240 min. Further reduction in temperature to 80 and 60ºC resulted in reduction of nickel and cobalt extraction. At the end of each leaching test, magnetite was seen to attach to magnetic stirrer. The study showed nickel can be completely leached into solution but cobalt only up to 70%. Keywords: atmospheric pressure, sulphuric acid leaching, nickel laterite

Sep 1, 2012

By G. J. Feng

Based on detailed theoretical analysis of coarse floatation and three-phase froth, a laboratory system which contains a new type of froth floatation equipment is established. Through water experiment, the relationship among floatation dynamics parameters of the equipment is studied and the best work parameters are educed too. Based on all of above, Slurry test is carried out in a copper concentration plant. Granule between 0.28~0.45mm can be reclaimed successfully. The slurry test proves that to separate coarse minerals in froth floatation equipment is a kind of effective method, it is well worth to make a further study.

Jan 1, 2014

By Kozlov Andrey, Matveeva Tamara

"The results of mineralogical and technological studies of platiniferous dunites from Svetloborsky zonal massif (Urals platinum belt) are presented and the basic typomorphic signs of productive mineral assemblages are substantiated. The characteristic features of platinum ore mineralization are revealed: a wide range of iron-platinum alloys, enrichment of ore-formed system by the elements Os, Ir, Rh and activity of the S and As in it, intrusion of Fe-Ni sulfides in platinum and its fusion with magnetite. More than 80% of PGM mineral grains has size less than 100 microns, that determines the possibility of significant losses of platinum in the process of gravity separation and the need for additional recovery processes for small and fine fractions of platinum tailings and sludge products. Summarized results of laboratory tests of small-volume sample processing of platiniferous dunites are presented and the processing flow sheet is developed and tested. The flow sheet incorporates several stages, including stage-wise grinding and gravity separation of ore using the centrifugal concentrator Knelson KS-MD for differently sized material and flotation treatment of tailing products using new classes of reagents for additional recovery of PGM fines."

Jan 1, 2014

By B. McFadzean, S. Geldenhuys

"Dynamic froth stability tests have found widespread application to quantify froth performance. However, little to no attention has been given to scale parameters in the performance of these measurements. One of the most frequently changing scale parameters in the laboratory scale is the column diameter as this directly influences the amount of material needed for testing. Four different column diameters (50, 100, 200 and 300 mm) were used for this study. Column diameter experiments were done on an industrial scale by means of manual tracking of froth growth versus time. An increase in measured dynamic stability was seen with increasing froth column diameter, which reached a limiting value at large column sizes. It is thought that this behaviour is controlled by the differences in drainage rates of the bulk froth compared to froth in contact with the wall. The column diameter required to represent full-scale froth stability is proposed. A ratio of column surface area to total bubble surface area was used to correct for different column diameters.INTRODUCTIONThe froth phase in flotation contributes significantly to the overall performance of the process (Zanin, et al., 2009). Numerous parameters have been investigated to quantify froth performance, most notably froth recovery (Feteris, et al., 1987; Seaman, et al., 2004; Vera, et al., 1999). Experimentally gathering data to determine froth recovery is challenging and for this reason froth stability has been highlighted as a possible alternative.Froth/foam stability is defined as the time of persistence of the froth/foam and is affected by numerous factors, such as: drainage of the liquid in the lamellae (gravitational and capillary), viscosity at the bubble surface, thickness of the electrical double layer and gas diffusion through liquid films caused by pressure differences between bubbles (Aktas, et al., 2008; Beneventi, et al., 2001). It is well documented in both froth and foam literature that froth/foam stability will heavily influence the performance and appearance of the froth/foam phase (Ata, 2012; Farrokhpay, 2011; Weaire, et al., 2005). Experimentally this has been explicitly proven as an increase in froth stability, characterised by water recovery, usually results in an increase in both valuable mineral and solids recovery (Wiese, et al., 2011; Banford, et al., 1998)."

Jan 1, 2018

By M. Saghaeian, R. Hejazi, H. Abedini, M. Zare

Water recovery in mineral processing plants is one of the most important subjects because water supply is a critical matter economically and environmentally, especially in desert areas. In this paper, the filtration behaviour of two iron ore tailing sample has been investigated using laboratory scale vacuum and pressure filtration units. These samples including tailing from Sirjan and Zarand concentrate production plants with the d80 of 94 and 41 micron, respectively. The results show that by using vacuum filtration the cake moisture content of Sirjan sample would be about 24%. But the filtration time is too long and vacuum belt filter cannot be used in industrial scale. Adding about 40 g/ton of flocculant would decrease the filtration time by about 30% and make the vacuum belt filter appropriate for dewatering of this sample. For Zarand tailing sample, the vacuum filtration would produce a wet cake by about 31% moisture content. Filtration time is too long and adding flocculant would not improve the results very much. So pressure filtration must be used for dewatering of this sample. The results of laboratory tests show that using pressure filter would reduce the cake moisture content to 21%. The filtration time is logical, so this process can be used for Zarand tailing dewatering.

Jan 1, 2014

By Q. Shi

An investigation into the hydrophobic aggregation of ultrafine smithsonite in surfactant solution has been undertaken through a combination of hydrophobic flocculation experiments, zeta potential measurements, surface tension measurements, and contact angle measurements. The experimental results have revealed that the behaviors of hydrophobic aggregation were closely correlated with the particle hydrophobicity, but they were not lowered byte change of the particle surface charges due to surfactants adsorption. On the other hand, the liquid (solution) surface tension (?LV) plays an important role in hydrophobic aggregation, and the hydrophobic aggregation could not occur below the critical liquid (solution) surface tension (?c). Meanwhile, this flocculation has been observed to require sufficient stirring strength and magnitudes of kinetic energy input to achieve the maximum aggregation degree. From the microflotation results, it has been found that the flotation kinetics response of smithsonite fines is markedly improved due to sufficient stirring strength, and the stirring strength influenced the floc flotation in a manner quite similar to their influence on the hydrophobic aggregation, suggesting that the formation of hydrophobic flocs is a promising means to recover smithsonite in the fine size range.

Sep 1, 2012

By Matthew Thurley

Optimisation and control of comminution, pelletization, and agglomeration processes is a complex task with large potential for gains in productivity, energy efficiency, and particle size distribution quality. One factor in realising these gains is the requirement for fully-automated online particle size distribution measurement. Moreover, online particle size distribution measurement that is based on the particles on the visible surface and can avoid or mitigate substantial errors that result from under-sizing overlapped particles and over-sizing areas of fines particles. Literature review indicates a body of substantially 2D photographic based particle size measurement systems that suffer from a large number of significant errors except in the simplest case of a monolayer of particles under good illumination with limited color variation in the material. In order to measure the visible particles on a pile there are a number of requirements including; avoiding particle delineation errors due to variation in material color and shadows, detect overlapping versus non-overlapping particles, and identify areas of fine particles as fines and not large rocks. Results are presented using a fully-automated online measurement system of crushed rock on conveyor belt using a 3D surface laser profile. The system provides continuous online measurement and results are shown on over four hours of production after the primary crusher. Size distribution results are calculated using volumetric estimation of the particles on the surface of the pile. The results show a strong capability to discriminate size variation especially in the 10% and 20% passing values. Furthermore results show that if areas of fines are misclassified as large rocks, and overlapped particles misclassified as small rocks, then a near complete loss of discrimination occurs for the P10 and P20 values which become largely constant values.

Jan 1, 2014

By Rhulani F. Maluleke, Francis W. Petersen, John H. Marsh, Johann de T. Steyl, Allan Nesbitt

"Pressure leaching of chalcopyrite and nickeliferrous pyrrotite at temperatures between 105 and 200 ºC has been proposed as a potentially viable route for the extraction of mineral elements from sulphide concentrates. In general, these concentrates contain iron, and the economic success of the processes is partially dependent on the choice of the environmentally acceptable iron-removal technique. One of the most widely used methods for the removal of iron from sulphate liquors is precipitation as hematite, goethite, or jarosite. The nature of the iron precipitate formed dictates downstream dewatering and residue treatment and disposal options. However, a better understanding of iron precipitation under the defined process conditions would consequently be of benefit in process design and optimisation.This study investigated the precipitation of iron in the autoclave at temperatures between 105 and 200 ºC. The effects of temperature, acid concentration, iron concentration, and the presence of other metal cations on the nature and composition of the precipitates were determined."

Jan 1, 2003

By Takashi Furuyama, Sukeyuki Mori, Tetsuo Ikejiri, Abel Bissombolo, Yoshitsugu Koga, Masamichi Hata

In Japan, the increasing number of automobiles newly put into circulation is followed by a larger amount of end-of-life vehicles from which valuable metals are being recovered in shredder and related plants. Nevertheless, the processing of these scrapped automobiles which has reach a recycling rate of about 75%, generates a huge volume of waste, locally known as .shredder dust., which is commonly dumped on landfills. The saturation and depletion of valuable disposal sites in the near future, as well as the social and environmental problems related to the accumulation of these residues disposals are a major challenge for the automobile shredding industry. To promote an alternative way for the management of these disposals, the authors have initiated and developed a system for their processing, on the basis that more than 90% of these residues are combustible materials that could be used as refuses derived fuel. The developed processing system points out the mechanical/physical separation of shredded automobiles residues into two streams by means of an ascending airflow passing through a vertical zigzag separator and, the compaction of the light-density fraction of materials (that is about 60% of auto shredder residue recovered as float products and mainly composed of cotton, sponges and light plastics) to form a refuse derived fuel (RDF), the density, calorific value and ignition loss of which are 1.19 g/cm3, 4470 kcal/kg and 60.7%, respectively.

Jan 1, 2003

By Arman Ehsani, Ersin Yazici, Haci Deveci

The downstream treatment of chloride leach solutions of WPCB for recovery of base and precious metals by a combination of adsorption and precipitation processes were carried out. A synthetic leach solution (1 M HCl, 116.5 g/L Cl-, 30 g/L Cu2+, 2.5 g/L Fe3+, 5 mg/L Au3+, 10 mg/L Ag+ and 20 mg/L Pd2+), which was prepared based on the composition of the pregnant leach solution obtained in the previous study was used in the tests. The leach solution was initially subjected to activated carbon (AC) adsorption (20 g/L AC, 80°C) in which gold was selectively recovered over silver and palladium i.e., 88% Au recovery at 0.5 h (92% at 3.5 h) compared with only 3-6% for Ag/Pd. Copper and iron were also observed to adsorb on AC as indicated by 1.4% and 17% decline, in their respective concentrations. Following the adsorption and filtration stage, metallic copper was added into the gold-barren solution to allow reduction of Cu2+ to Cu+, and to cement Pd on metallic copper. Over the mixing period (1 h), 93% of the Pd was recovered while only 1.4% of silver was cemented onto metallic copper. Subsequently, the leach solution was gradually neutralised by NaOH to pH 4, 7.5 and 9.5 for the precipitation of copper as cuprite (Cu2O). It was found that 41% and 46% of Cu and Ag, respectively, were precipitated at pH 4 at which iron was almost totally (99.8%) removed from solution. Precipitation of copper and silver was increased further at high pHs. At pH 9.5, cumulative recoveries for copper and silver were 91% and 85%, respectively. XRD analysis of the precipitates confirmed the presence of cupric copper oxides/hydroxides and revealed that copper losses occurred at pH 4 was due to the undesired presence of cupric copper in the solution.

Jan 1, 2014

By X. Y. Zeng

Most Chinese titanium bearing minerals are the composition of magnetite vanadium and ilmenite. All of such mineral processing plants use low intensity magnetic separators to recover magnetite and vanadium goes with magnetite. In the past years most of the plant tails containing about 10% TiO2 were abandoned. Now many of these plants use SLon magnetic separators to recover ilmenite in the roughing stage, which can throw away most of the gangs and slimes with very low cost. The new development of applications of SLon magnetic separators in Chinese ilmenite processing industry is introduced in the paper.

Jan 1, 2014

By C. L. Tang

Parts of the wastewater are reused directly and the rest moderately purified and reused, so the utilization rate of wastewater of the whole processing plant reaches 100 percent. At the same time, beneficiation indicators have been improved stably, and great economic and social benefits have been achieved.

Jan 1, 2014

By C. Martinez, S. Helle, M. Pincheira

We studied the feasibility of automated mineralogy to discriminate between tennantite and enargite, the main sulfosalts found in the Rio Blanco deposit, Codelco-Chile, in order to predict the content of minor elements (As, Sb, Ag, Pb, Zn) that impact on the process and concentrate prices. The identification of these minerals is feasible using traditional microscopy, however not possible by automated mineralogy. This drawback prevents comparing the databases generated in the past by means of conventional microscopy with the information obtained at present by QEMSCAN. To differentiate enargite from tennantite the mineral composition of both sulfosalts was studied by electron microprobe. The presence of associated minor element contents of about 8% zinc in tennantites and not exceeding 0.07% in enargites were used to modify the SIP database of QEMSCAN to enable the quantification of these phases in samples of head, residue and concentrate coming from As-bearing domains of the deposits. Detection limits allowed to determine the mineral species in the head, concentrate and residues. The integration of methodologies such as automated mineralogy and microprobe can be used successfully to quantify the presence of some ore forming solid solution.

Jan 1, 2014

By Marko Hilden

"A stochastic model of mineral texture is discussed and used to demonstrate that grain association within the intact texture has a significant effect on the liberation characteristics of breakage products. The majority of previous models have simulated texture and liberation of binary systems. This new model is able to simulate complex multi-component (multi-mineral) aggregate textures and their breakage products. Grain size distributions can be defined for each of several minerals. Mineral-mineral associations can be controlled by inserting mineral grains within grains of another mineral. Repeated Monte Carlo sampling of the aggregate is used and the liberation properties of the fragments are calculated. These are analysed to generate data in a similar form as reported by mineral liberation analysis systems, including density distributions, liberation distributions, and particle class distributions. Simulations results are presented where the model has been fitted to complex sulphide ores with four minerals. Comparison of the simulated particles and experimental data show that the model is able to reproduce similar particle class distributions as measured by QEMSCAN. The texture of real complex ores can be simulated and fitted to conventional mineral liberation analysis data. The model should provide a useful and practical means of modelling the effects of mineral texture on separation processes and in geometallurgical models."

Jan 1, 2014

By Kauko T. Ingerttilä, Jouko O. Kallioinen, Jaakko O. Leppinen, Alexander V. Lashkul, Vladimir E. Nenno

The Separation in Froth (SIF) technique is based on the idea that the pulp is fed directly onto the froth layer prepared on the surface of liquid medium providing an effective method for separation of coarse particles up to a few millimeters size. Thus the SIF process can result in substantial savings in grinding energy and flotation chemicals. In this work flotation of apatite, calcite and silicate minerals from various industrial sources was investigated using laboratory and pilot plant-scale SIF machines. Flotation of diamonds was also investigated on laboratory scale. It was observed that all the minerals mentioned above can be successfully floated up to about 3 mm particle size. Beneficiation tests with the coarse fractions of classification circuits indicated that final grade calcite concentrate can be obtained with over 90% recovery in one SIF step in this grain size (typically 0,1 to 1,5 mm). Similarly, substantial upgrading of coarse apatite was achieved without grinding it to the fineness required by conventional flotation. SIF could also be applied to the recovery of coarse apatite from the tailings of a conventional flotation process. The capacity measured in the pilot plant test runs for a 1 m2 cell was typically 30 t/m2h. Presently, a full-scale process using the SIF technology is being installed for coarse apatite recovery.

Jan 1, 2003

By Mahdi Shevrini, Hamed Haghi

"In this research, the operation of screen classifying in silica processing circuits was investigated and modified by replacement of available trommel screens with teetered bed separator (TBS). In addition the effect of the mentioned replacement and addition of attrition scrubber on quality of final product, impurities removal, recovery and production rate were inspected. Considering screen efficiency problems to achieve certain particle size distribution, hydraulic classifying system was selected instead of trommel screens. Application of suggested plan improved quality and particle size distribution of produced silica significantly. Optimization of size classification in process circuit resulted in increase in production rate up to 21% (from 67% to 81%), silica recovery (from 68.35% up to 83.11%) and relative enhancement in removal of impurities such as Fe2O3 and TiO2. After optimization and stabilization of grinding and size classification section, industrial attrition scrubbing tests were carried out and the best solid percent and retention time were determined i.e. 70% and 6 minutes, respectively. Using sodium carbonate during attrition scrubbing, has major effect on removal of surface coating and staining especially sharp increase in clay removal; therefore 2 kg/t of sodium carbonate can be optimistic point of industrial procedure for this silica processing plant. It should be mentioned that application of attrition scrubbing which is followed by screw classifier for de-sliming were useful for better cumulating of particles in the range of appropriate liberation degree (+106-300µm) and efficient removal of metallic (iron and titanium oxides) and non-metallic (clays and feldspars) impurities."

Jan 1, 2014

By O. Martinsson

The Kiruna area is an important mining province in northern Sweden, which is dominated by Fe- and Cu-Au deposits. Economically most important for the region, are the apatite iron ores with an annual production of c. 43 M ton of crude Fe-ore and a total production of more than 2000 M ton of ore the last 100 years. The apatite iron ores in the Kiruna area are dominated by either Magnetite or Haematite and contain varying amounts of apatite giving them a content of Fe and P, which varies between 30-70 % and 0.05-5 %, respectively. A typical geochemical feature of the ores is the strong enrichment of REE that is caused by a high content of REE in apatite and the occurrence of Allanite and Monazite containing 22.4 and 69.8 wt% REO, respectively. At Kiirunavaara, the content of REE in apatite varies between 0.07 to 1.57 wt% REO with a dominance for the light rare earths. The variation in REE-content of apatite depending on textural and paragenetic aspects is not known but apatite grains may display a strong LREE-depletion due to hydrothermal alteration. Monazite occurs as rod-shaped or tabular inclusions in apatite and is suggested, to have formed in response to hydrothermal alteration of apatite after the emplacement of the ore. Inclusions are mainly found in the central part of apatite grains occurring in veins and schliren, while they are rare in apatite occurring disseminated in the ore. Monazite also occurs as larger grains outside apatite and together with Allanite is found in texturally and paragenetically different settings within the ore. These occurrences of REE-minerals may largely be a product of LREE mobilized by alteration of apatite after the emplacement of the ore. However, REE-minerals including Allanite and Monazite might also have formed directly from late magmatic fluids. Keywords: apatite, monazite, allanite, ree, kiirunavaara, iron ore of kiruna type, mineral chemistry

Sep 1, 2012

By Kilian Neubert, Hermann Wotruba, Henning Knapp

Sensor-based sorting has been integrated into more and more applications in mineral processing over the past decades. Various sensor types, such as line scan cameras, near infrared sensors and X-ray transmission sensors, allow the separation of a vast variety of raw materials. Sensor-based sorting has several economic benefits which can make the difference between an uneconomic operation and a profitable mine. Sensor-based sorters can be applied to fulfill various sorting tasks, such as waste rejection, product quality improvement and ore type diversion, and have a significant impact on the layout of the processing plant. Therefore, it is important to include sensor-based sorting into the planning of a processing plant at an early stage. To evaluate the applicability of sensor-based sorting for any specific ore type, it is currently necessary to provide several hundred kilograms of material for subsequent bulk tests. In exploration, ore samples are usually rare and only available in form of drill cores. The acquisition of drill cores is time-consuming and expensive especially for deposits in great depth. Hence, it is unfavorable to spoil valuable drill cores for bulk tests. This paper describes a methodology to evaluate the applicability of sensor-based sorting based on drill core analysis. That methodology offers the possibility to calculate the achievable performances of different sensor types for various grain sizes without comminution of drill cores. The general methodology is shown on basis of an exemplary test work on drill cores from a currently conducted exploration.

Jan 1, 2014