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By A. T. Adema

The cohesive zone, where the ore fed into the blast furnace softens and melts, is critical to the blast furnace performance and stability due to its influence on the gas and solid flow. This paper de-scribes a project for the development of a process model to predict the cohesive zone properties and the results of its first step; the solid flow model. The process model is expected to describe a realistic solid burden flow and the formation of the cohesive zone, its shape, location, structure, permeability, and in particular the mineralogical changes within the cohesive zone. This will be achieved using various simulation and computing tools: a combination of the Discrete Element Method (DEM) and Computational Fluid Dynamics (CFD), the DEM?CFD hybrid approach, together with models for the thermodynamics and reaction kinetics. The key benefits of the hybrid approach lie in the coupling of the continuous phase and the discrete particles, and the possibility of introducing thermodynamics and reaction kinetics into the system in a more realistic manner. Two DEM simulations are presented for a small scale blast furnace to investigate the influence of non-spherical particles on the solid flow. This influence can be observed from a more even solid flow pattern and a reduced deadman size. The results indicate the requirement to include non- spherical particles in a blast furnace simulation to achieve a realistic solid flow.

Jan 1, 2014

By A. M. Raichur, S. P. Vijayalakshmi

Fine coal dewatering is a major problem in the coal industry because the fines hold significant amounts of water and account for two-thirds of the product surface moisture. Present methods include flocculation using polymeric flocculants followed by filtration. But the kinetics of filtration are not favorable with such flocculants. In this study, a novel method involving flocculation with microorganisms for improving the settling rates and dewatering kinetics has been investigated. Two Gram-positive microorganisms, Mycobacterium phlei and Bacillus subtilis were used as bioflocculants. The effect of time, pH and ionic strength of the electrolyte used on adhesion and flocculation were studied. Adhesion tests showed that maximum adsorption occurred in 20 minutes in the pH range of 2-7 and the total amount of bacteria adsorbed was almost the same with both the flocculants. Nearly 98% of the coal flocculated with both the microorganisms in about 5 minutes. The filtration rate of fine coal almost doubled with addition of bacteria and electrolyte and maximum filtration occurred near the point-of-zero-charge of the bacteria.

Jan 1, 2003

By H. G. Hedlund

Tailings in Mining Industry can be handled in different ways. Today tailings disposal is in focus by projecting new plants as well as treating and handling of old Tailings dams.The trend today is to process minerals, detoxify the Tailings and place them as dry surface Deposition or Underground Backfill. This paper will briefly present five different Mining plants in North and Central America, where Tailings have to be dewatered for dry depositing. The Metso-Sala VPA is a filter especially developed for dewatering and drying of Mineral Concentrate and Mineral Tailings. Keywords: tailings disposal, dewatering, drying, mineral tailings

Sep 1, 2012

By Lilong Huang, Xiang Zhao, Yuan Long, Li Shi, Guowang Zhang, Xiao Xiao

"Vertical stirred mill is expected to upgrade the iron concentrate by further size reduced efficiently. The tests for fine grinding of iron ores from Baiyun Boyu iron ore, Baogang Goup, iron contained tails of Cu-Pb-Zn ore in Wanguo ore, Xiaoshalong iron ore in Qinghai were conducted in this paper. The data of appropriate grinding fineness, optimum grinding conditions and energy consumptions obtained from the test were used to select appropriate scale of the vertical stirred mill, optimize the parameters of the grinding process and upgrade the iron concentrate of the iron ore dressing plant or design the new ore dressing plant. Based on the laboratory tests, industrial system of regrinding and magnetic separation with vertical stirred mill as the regrinding mill in micro-fine grained iron concentrate upgrading has worked out very well. The grade of Fe in iron concentrates has increased to about 65.0% (by 4.0~6.5 point percent) when the iron concentrates were reground to designed fineness and the specific energy is 5.0~7.1kWh/t. The system of regrinding and magnetic separation is proven to be eco-efficient in iron concentrate upgrading."

Jan 1, 2014

By H. R. Manouchehri

"In all electrical beneficiation methods, the difference in electro-physical properties of the contributed mineral particles, essentially frictional charge, electrical conductivity and dielectric constant properties are exploited to achieve separation. The composition of the raw material determines what kind of either corona charging, conductive induction, or triboelectric separation method should be employed. The process is versatile and is influenced by different parameters related to mineral characteristics, surrounding ambient conditions and electrical and mechanical attributions of the separating device. Electrical separation is surface based beneficiation method which is mainly affected by the surface and surface changes of the minerals. Therefore, it is essential to understand how the electrophysical properties of the minerals can be changed/modified. During electrical/electrostatic separation process, both charge magnitude and its polarity that developed on the particles and therefore, their electrical beneficiation potential is essentially defined by surface phenomena. Therefore, it is essential to understand how the main electro-physical parameters can be changed/modified with applied surface treatment/pretreatment methods to promote separation. Surface treatment of minerals is carried out by different means, including chemical conditioning, irradiation, thermal treatment, etc. This paper discusses and analyze the electrical separation process, electrophysical properties of the minerals with special focus on the effect of surface pretreatment/treatment methods to affect electrical beneficiation potential of the minerals. The surface treatment methods vary in a wide range from simple surface cleaning to more complicated chemical conditioning and doping. The knowledge of the solid-state physics and chemistry leads to improve the beneficiation potential of different mineral systems by choosing suitable treatment method(s). Despite the complexity and multiplicity of the charging mechanisms, difficulties in separating fines it seems to be beneficial make our attempts to further investigate and develop the process as dry, low cost beneficiation process, especially nowadays when environmental concerns, as well as energy and water consumptions are main concerns for mining industry."

Jan 1, 2018

By A. N. Zagorodnyaya

The results of research on recovery of ammonium perrhenate from by-products of lead production are presented in the article. For the first time in the world, rhenium marketable products were produced on lead plant of Kazakhstan. Distribution of rhenium in lead production has been studied. During oxidative agglomeration of lead charge, 67.43% rhenium is sublimated and at that, 67.27% rhenium is trapped by the dusts of a system of gas purification, out of them 6.21% is transferred into different solutions, 1.89% into slime and only 0.09% into exhaust. During agglomerate smelting, up to 72% of its rhenium is sublimated and condensed in the dusts also. At leaching stage of sulphate product under dusts processing by the method of sulphatization, 15% of its content in the dusts is transferred into solution. The sorption method on the ionite ?N-21 has been proposed for recovery of rhenium from the solutions of sulphatization. At the same time, rhenium recovery from the dusts into commodity was 13%. The method of direct hydrometallurgy - leaching the dusts by solutions of sulphuric acid under presence of manganous concentrates, has been proposed as alternative method of recovery. This method has allowed increasing recovery of rhenium and other metals from the dusts into solution up to 90%~95%. Rhenium solvent extraction by ??? has been proposed for recovery of rhenium from the leaching solutions. At that, extraction of rhenium into marketable product from the dusts is above 75%.

Jan 1, 2014

By Z. H. Liu

We experimented with slurry which from one of coal preparation plant in Guizhou province and made researches on double hump gradation, one of critical factor of gradation technology, which can influence pulping character in the process of making coal water mixture (CWM). The purpose for it is to find the best particle gradation which can meet the requirements in concentration, viscosity, and stability for CWM. The final result is that the concentration, viscosity, stability of CWM can meet the requirement for industrial use while the rate of fine particle in the slurry is 70%~75% and the maximum concentration of 62%.

Jan 1, 2014

By S. Leroy

Grinding is the most energy consuming step in mineral processing, however, it is still poorly understood and its efficiency is difficult to monitor. Mill performances are traditionally measured at the mill discharge, on the basis of a mass percentage passing a certain sieve. This approach does not reflect what happens to the fines through milling. On another hand, if many macroscopic parameters, such as the percent solids of the pulp, its viscosity, or its mean residence time in the mill are known to be related to grinding efficiency, the link between these parameters and particle size distribution (PSD) is still unclear. Here, a methodology is established to understand the effect of ball mill operating conditions on particle size and shape distribution in the grinding process. The study focuses on the particular case of an Upper Group 2 (UG-2) platinum ore concentrator. Due to the very low grade of sulphide and PGM (Platinum group metals) in UG-2, grinding mechanisms are entirely control by gangue minerals. These two minerals have contrasted properties and PGM content and these properties immediately affect the entire recovery process. So, the grinding of both gangue minerals is studied on a size by size basis. At particle scale, three parameters are addressed: particle size, particle composition and particle shape. The specific behavior of chromite and silicate grains is demonstrated. As a conclusion, this study gives some clues to operate ball mills in a more efficient manner regarding chromite issue in the processing of UG-2. Keywords: ball milling control, UG-2, chromite, fine particle, particle shape, segregation

Sep 1, 2012

By Vinay Jain

Beneficiation of alumina rich iron ore slimes is a major challenge for the Indian iron ore industry. One of the methods by which this problem might be addressed is by design/screening of suitable reagents (flocculants/depressants/collectors) which act selectively towards either aluminum containing minerals (gibbsite and kaolinite) or iron bearing minerals (hematite and goethite) in order to separate them. Our earlier work indicates that separation of iron oxide minerals from gibbsite is relatively more difficult than from kaolinite. Accordingly, our research work has been focused on finding selective reagents for iron oxide ? gibbsite separation. We have performed density functional theory (DFT) computations to evaluate the interaction energies of seven different reagent groups - carboxylic acid, flotol, hydroxamic acid, phosphonic acid, iminobismethyl phosphoric acid, xanthate and starch with hematite and gibbsite surfaces. The objective was to identify if any of these groups show selective adsorption towards one of the mineral surfaces. Among all these reagents, starch exhibits the highest selectivity towards the hematite surface with a difference in interaction energy of ~63 kcal/mol between hematite and gibbsite surfaces. This is consistent with experimental findings at our laboratories on slime samples from Noamundi mines wherein it is being observed that usage of starch as a flocculant does lead to an improvement in the final grade of the ore with significant reduction in the Al-content. A binuclear complexation mechanism based on affinity between Fe and Ostarch atoms combined with a geometrical templating effect, arising out of a close correspondence between Fe-Fe distance on the hematite surface and O-O distance in starch, is proposed to explain the strong adsorption of starch on hematite surface. Keywords: slimes, iron ore, alumina, hematite, gibbsite, DFT, adsorption, flocculants

Sep 1, 2012

By C. Igathinathane

Coal is the most widely used fossil fuel in the world, providing more than 25% of world?s electrical power. Since, the behavior of coal particles in crushing and grinding circuits, concentration operations, and solid-liquid separations is strongly dependent on size, a reliable and accurate measurement of particle size and particle size distribution (PSD) is a vital aspect in coal cleaning. This paper presents a method for the characterization of ground coal particles using image analysis. We utilized a machine vision (MV) approach that used a document scanner as the imaging device and a user-coded ImageJ plug-in that processed the image and automated the PSD analysis and output results in textual and graphical forms. This approach used a sum of volumes (SVolume) as weighting factor for particle length as the primary dimension of analysis and was successfully applied to ground coal. The plug-in was further improved for computational performance in this study. Mechanical sieving (MS) was also used to compare the MV results. MV results showed that the PSD of ground coal followed a uni-modal normal distribution, and the log-normal plot against particle size exhibited a linear trend for most of the range. MS results, however, had three linear segments, when the width-based sieving results were transformed to lengths by applying the shape factor (width/length), but a definite deviation between the PSD plots was observed. This study demonstrates successful application of the MV SVolume approach for PSD analysis of ground coal, which can be extended to similar particulate minerals and products. Keywords: dimension, fiji, image j, image analysis, coal, particle size, plug-in

Sep 1, 2012

By Ben Murphy, Alejandro Yanez, Tatu Miettinen

"Flotation using large volume cells has grown in importance during recent years, particularly given the increasing demand for minerals whilst ore grades are decreasing. Outotec introduced the TankCell® e300 in 2007 to enable concentrator plants to process these higher tonnages. From the beginning, TankCell® e300s with FloatForce® mixing mechanisms have demonstrated good metallurgical performance with decreased operating costs and high availability. This paper deals with specific engineering challenges that need to be considered when installing these units rather than giving examples of performance. Today there are over 100 TankCell® e300s operational worldwide. As more of these units are installed new technical challenges are encountered and solutions developed to maximize their productivity. Lessons have been learnt by operators, engineering companies and the cell manufacturers on how best to design and layout these cells in modern concentrators to ensure smooth transition from design to installation to operation. This paper presents information on important design considerations and learning that has been obtained through the design, installation and commissioning of the TankCell e300 around the world. Areas pertaining to cells layout such as feed and discharge arrangements along with items of metallurgical concern such as sampling, reagent addition and the potential benefits of installing a variable speed drive on the motor will be covered in depth."

Jan 1, 2014

By M. Taheri

Multiple Attribute Decision Making (MADM) method is applied to select tailings site of the Gol-e-Gohar Iron Ore Processing Plant in the Kerman province, south-eastern of Iran. To select tailings site, screening is applied on eight location proposed by Binnie and Granges. Consequently three sites identified for further studies. Evaluation factors include only the most important factors such as efficiency ratio, elevation and distance to processing facilities, occurrence of faults and fractures. Crisp values such as efficiency ratio, elevation and distance can be determined by measurements and calculations, but some factors such as occurrence of faults and fractures are presented as linguistic values that can be described with triangular fuzzy numbers. Based on evaluation values obtained an optimal tailings site can be selected using a modified Technique of ranking Preferences by Similarity to the Ideal Solution (TOPSIS) given crisp data and linguistic variables as the alternatives of attributes. Each attribute?s weight is assigned using the analytic hierarchy process. The final ranking order aids in the selection of tailings site. Finally, the stages of modified TOPSIS method were applied and site No.2 situated in 5400m to the mill was selected as the best alternative.

Jan 1, 2014

By P. Altinkaya, O. Celep, H. Deveci, E. Y. Yazici

"Copper-bearing gold ores have proved difficult to treat in conventional cyanide leaching process owing to prohibitively high consumption of cyanide by readily soluble copper minerals interfering with gold extraction. Cyanide leaching of gold from copper-rich ores can be improved by intensive cyanidation or application of physical and chemical pre-treatment methods (e.g., ultra-fine grinding, roasting and leaching). In this study, nitric acid leaching of a copper-bearing pyritic concentrate (0.3% Cu, 62 g/t Au and 110 g/t Ag) as pre-treatment prior to cyanidation was investigated. The mineralogical analysis of the concentrate has revealed that it is composed of mainly quartz (25%), pyrite (32.7%), sphalerite (5.37 %), galena (2.12 wt %) and anglesite (1.13 %). Arsenopyrite, chalcopyrite, covellite and bournonite were also detected as minor phases present. Previous studies carried out by the authors showed that direct cyanidation (1.5 g/L NaCN) of the as-received concentrate (d80: 80 µm) produced low gold (45% Au) and silver (46% Ag) extractions. Nitric acid pretreatment of the as-received concentrate was performed for 5 hours at 1-5 M HNO3 and 80oC. In these tests, 65% Cu/Pb and 94% Zn were leached. The nitric acid pre-treatment improved the extraction of gold and silver in subsequent cyanide leaching (1.5 g/L NaCN) to 82% Au and 87.5% Ag with a concomitant decrease (up to 54%) in cyanide consumption. It can be inferred from these findings that the removal of copper from the concentrate and the liberation of the occluded gold by nitric acid leaching as pretreatments can be appropriately employed for the treatment of the copper-bearing pyritic concentrate with high gold/silver content. INTRODUCTION Refractory ores are often characterized by their low amenability to cyanide leaching resulting low (often <80%) Au/Ag extractions (Bhappu, 1990; Celep et al., 2009; Marsden and House, 2006). One of the most common causes of refractoriness is the physical or chemical encapsulation of submicroscopic or fine-grained gold in sulphide minerals such as arsenopyrite and pyrite (La Brooy et al., 1994; Vaughan, 2004). To render refractory gold ores/concentrates amenable to cyanide leaching, the decomposition of sulphide minerals within a pre-treatment process to expose the encapsulated gold grains to the action of cyanide is required. In this regard, roasting, pressure oxidation and biooxidation are commercially used processes for pretreatment of arsenopyrite/pyrite gold ores/concentrates ahead of cyanide leaching (La Brooy et al., 1994). Presence of cyanide-soluble copper minerals in the ore leads to low gold recoveries and high cyanide consumptions under conventional cyanide leaching conditions. High cyanide concentrations (CN:Cu>4) should be employed to achieve high gold recoveries from copper-rich gold ores/concentrates. This may require recovery of cyanide from effluents. In this regard, SART Process (sulphidisation-acidification-recycling-thickening) employed industrially for recovery of cyanide and copper as a by-product. This process simply relies on the addition of sulphide (as Na2S, NaSH or H2S) to the leach solution prior to the acidification to pH 4-5. This results in the precipitation of copper as Cu2S and occurrence of free cyanide which is recycled to the leaching circuit after S/L separation (Dai et al., 2012)."

Jan 1, 2018

By M. D. Kaizer

PETROBRAS started its Oil Shale process development in 1953, the PETROSIX process which was developed and tailored to Irati Oil Shale formation. Since 1991, the industrial plant called MI (Industrial Module) has been operating, producing more than 20 million barrels of oil. In order to continue the oil shale exploration, a new shale mine is been opening. This article reports the planed measures taking in order to limit the environmental impacts and to return the land as close as possible to the original condition, as well as with the disposition of the process waste and the city garbage. It shows that the remediation process starts during the mining activities and continues after the mine exploration. Another characteristic of the Petrosix process, the pyrolysis of tires will be focused.

Jan 1, 2014

By D. Chen

The experiment adopted magnetic separation-priority flotation (first to float copper,then float lead) combined technology to deal with a complex Cu,Pb ,Zn multi-metals ore which has high sulphur content, difficult to separate Cu, Pb ,Zn minerals from sulphur and separate Cu from Pb. Floatable pyrrhotite was separated through magnetic separation which could eliminate the adverse effect on the flotation followed up. And then adopting the priority flotation process to recover the Cu, Pb ,Zn from the magnetic tailings. In priority, flotation Cu, BP(a kind of ethionine ester collector ) and ethyl xanthogenate were used as the collector, LD-1 and sodium sulphite were used as the depressant.The depressants combined with humic acid sodium and lime were used for chalcopyrite ? pyrite separation to further improve the copper concentrate grade. Considering the raw ore that contain 0.32% copper, 0.54% lead and 25.54% sulfur. The copper concentrate grade is 23.61%. The lead content of copper concentrate is only 0.85% . The recovery of copper is 75.03%,and the lead concentrate grade is 54.58%, the copper content of lead concentrate is only 0.81% and the recovery of lead concentrate is 62.24%. The mineral processing indexes were excellent, finally realizing the high effective separation of Cu, Pb , Zn and pyrite. This technique provides a new approach to highly utilize complex copper-lead-zinc ore.

Sep 1, 2012

By C. Carrasco

"Over the last 30 years the average grade of mined ore bodies has significantly decreased while the proportion of waste removal has in many cases more than doubled. This has been identified as prime reason of a major increase in energy consumption and decrease in productivity across mining operation. Metal coarse preconcentration of ROM feed grades by size rejects low grade gangue/waste material in the size range of 10-100 mm prior to grinding, typically before primary crushing. This relies on propensity of metal to preferentially deport in the fine size fractions after breakage. Metal preconcentration by size has the potential to increase energy efficiency and therefore improve mining productivity on unit of metal basis. Results of an extensive belt cut sampling campaign conducted at a major Australian Au-Cu mine operation show that for some samples between 90% of Au and 80% of Cu is in 40% of the mass at -50 mm fraction. This indicates that low grade coarse material can be removed from the circuit, doubling feed grade at half of the tonnage and therefore improve energy efficiency per unit metal produced. This response, however presents significant variability in the same order as other processing attributes such as impact hardness and flotation recovery. This has led to development of geometallurgical laboratory tests using blast hole chips and drill core facilitating mapping and population of coarse metal preconcentration signatures in long term resources and short term production models. Preferential Cu deportment by size at drilling scale can be recognised, however scales up factors are required to transform laboratory results to production responses. At 50 % of mass the drilling products underestimate the belt cut responses by 20-30 %. Bulk sampling campaign with blast hole and drill core samples spatially related was also conducted to investigate in more detail the difference between production scale and drilling scale preconcentration responses."

Jan 1, 2014

By E. Isokangas

The production of minerals for economic use is a two-stage process, involving mining to extract the mineral from the ground, and processing to convert the mineral into a marketable product. Generally, mining and processing have been viewed as self-contained entities. Both have separate objectives, separate cost centres and key performance indicators (KPIs) that do not reflect the customer/supplier relationships that inherently exist. However, mining and processing operations are inter-connected and therefore intimately inter-related with the performance of one operation affecting the performance of another. Optimizing each stage separately without considering the whole system often misses potential economic benefits and energy savings. During the past fifteen years, the authors have been involved in implementing a holistic methodology ?Mine to Mill Process Integration and Optimisation (Mine to Mill PIO)? to maximize the overall profitability of the operation rather than just optimizing any individual process in a mining operation. Metso Process Technology and Innovation (PTI), along with their project partners, have conducted several projects to significantly increase their production- generating typically 5% to 20% higher throughput and improve the overall mine and concentrator performance through PIO methodology. This proven methodology has applications ranging from greenfield projects to long-standing operations with AG/SAG, HPGR or conventional grinding circuits. This paper explains the Mine to Mill PIO methodology and discusses the benefits of such an approach on the energy consumption, the overall costs and benefits of mining operations. The paper also summarizes several case studies illustrating the use of PTI methodology in a variety of applications. Keywords: integration, optimization, simulation, modeling, mine-to-mill, comminution, blast, drill, crushing, grinding

Sep 1, 2012

By X. P. Guo

In this paper the test results of flotation of the kyanite ore from a Chinese mine are described. The objective of this work is to determine effective recovery process to obtain kyanite concentrate with high quality and high recovery for a new concentrator design. The valuable minerals of the ore are kyanite, garnet and magnetite, contents of them are 14.0%, 5.9% and 1.2%, respectively. The gangue minerals are mainly biotite, feldspar and quartz, contents of them are 33.8%, 17.8% and 25.6%, respectively. The kyanite in the ore contains a little iron. In laboratory flotation tests the factors affecting the flotation such as slime, alkalinity of pulp, and flowsheet configuration are studied. The interference of biotite on kyanite flotation as well as selective flotation of garnet is examined. On the basis of above-mentioned results the flowsheet of ore treatment comprising de-sliming, mica flotation, low intensity magnetic separation of magnetite, high intensity magnetic separation of garnet and coarse biotite as well as flotation of kyanite is pre-sented for comprehensive recovery of kyanite, garnet and magnetite. The kyanite concentrate con-taining more than 59% Al2O3 is obtained with a kyanite recovery of 70.0%. The contents of Fe2O3and biotite in kyanite concentrate decreased from 2.02% and 5% to 1.30% and 1%, respectively. The disadvantage of low kyanite grade in raw ore is compensated by accessory recovery of garnet and magnetite in the ore.

Jan 1, 2014

By Ajay K. Jha1

Drilling and Blasting are two important unit operations in the production cycle of a mine and a strong link exists between these two and other unit operations/subsystems like loading, transportation, and crushing. Under the present concept of ? Mine to Mill?, it is important to optimize the drilling and blasting operations by applying scientific approach to drilling and blasting using sophisticated instruments and new technologies, which depends heavily on Information technology (IT) to meet this imperative. Development of innovative models and software has lead to blast optimization process. Till date, the blast results are evaluated in terms of available empirical approaches like powder factor, which are too simple to exclude some key parameters or lack in providing reliability because of non-availability of user friendly IT enabled techniques. Although with the help of developed approaches, formulation of user-friendly software to assist the site engineers in effective post blast assessment has started but there is a dearth of holistic approach to design an optimum blast considering the techno-economic feasibility of the subsystems and the geo-mining conditions to achieve blast optimization. The science of IT enablement in drilling and blasting is capable to build innovative models for achieving blast performances which will be doped with productivity, economy and safety with due regard to environment. The present paper discusses the use of existing IT enablement in various mines of India citing the Indian scenario and the future requirements for achieving the techno-economics in overall mining operations.

Sep 1, 2012

By S. F. Ye, L. Xiao, Y. L. Wang, P. W. Han

"Copper anode slime is a precious secondary source for the recovery of silver. However, current recovery process are constrained by either sever pollution or high cost. To cover the drawbacks of current process, this research employed a novel strategy by using the manganese dioxide as the oxidant in acid solution, which avoided the generation of sulfur dioxide while high silver extraction rate was achieved. The effects of manganese dioxide, sulfur acid concentration, stirring speed, temperature and leaching time on silver extraction rate were investigated. The silver recovery reached to 91.68% under the conditions of 1.2 g manganese, 2.0 mol/L H2SO4, 300 rpm, 80 °C and 6 h. INTRODUCTION Copper anode slime is generated from the electrolysis refining of copper and is extremely precious for its containing noble metal such as silver (Chatterjee, 1996; Amer, 2003; Yldrm et al., 2014; Syed, 2016; Wang et al., 2017). Therefore it is of great significance to extract silver from anode slime for the full utilization of resource. Pyrometallurgy is the most mature process for the extraction of silver because of its stability and adaptability (Hait et al., 2009; Zhao et al., 2010; Gao et al., 2017). However, it also suffers the drawbacks of high operating cost, low extraction rate of silver and severe pollution of smoke dust (usually containing lead and arsenic) (Ludvigsson and Larsson, 2003). To cover the drawbacks of pyrometallurgy process, more and more attentions are giving to the semi-hydrometallurgy process which usually includes a pretreatment process of sulphatising roast or low temperature oxidizing roasting (Tishchenko, 1964). After pretreatment, the refractory silver bearing phases (silver selenide, silver sulfide and silver) are converted into readily leached forms which are often extracted by ammonia, sodium sulfite in alkaline solution (Valiuniene et al., 2010; Wojciech, and Kitka, 2017). Despite its relatively high extraction rate and low investment, it still has the disadvantages of releasing harmful gases since the sulfur dioxide are generally generated in the pretreatment process. In addition, the use of ammonia can easily lead to a leaking into the atmosphere once not carefully dealt with (Aylmore and Muir, 2001). As for silver recovery by sulfite leaching, the consumption of sodium sulfite is rather high which often results in a pipe blocked (Yang et al., 2006)."

Jan 1, 2018