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By J. Fournier

A novel sol ? gel (SG) synthesis procedure utilizing varying ratios of glycine and ethylene glycol to total metal cations has been developed to create high purity nanometer sized La0.65Sr3.5MnO3 powders. X-ray powder diffraction (XRD), transmission and scanning electron microscopy (TEM, SEM), and dynamic light scattering (DLS) have confirmed that the crystallite sizes of such powders are ~ 20 nm, and the aggregate particle sizes vary between 100 to 300 nm. Mixing varying weight percents of SG LSM powders with commercially available Praxair LSM in a composite LSM/YSZ functionally graded cathode has been shown, through the use of electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV), to exhibit enhanced oxygen reduction kinetics vs. at conventional cathode materials.

Jan 1, 2005

By J. Fournier

A novel sol ? gel (SG) synthesis procedure utilizing varying ratios of glycine and ethylene glycol to total metal cations has been developed to create high purity nanometer sized La0.65Sr3.5MnO3 powders. X-ray powder diffraction (XRD), transmission and scanning electron microscopy (TEM, SEM), and dynamic light scattering (DLS) have confirmed that the crystallite sizes of such powders are ~ 20 nm, and the aggregate particle sizes vary between 100 to 300 nm. Mixing varying weight percents of SG LSM powders with commercially available Praxair LSM in a composite LSM/YSZ functionally graded cathode has been shown, through the use of electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV), to exhibit enhanced oxygen reduction kinetics vs. at conventional cathode materials.

Jan 1, 2005

By Jean Robitaille

La découverte du gisement du puits Penna a nécessité une révision complète de tous les circuits du concentrateur Laronde pour permettre, premièrement, l?adaptation du procédé à la nouvelle minéralogie et deuxièmement, l'accroissement du tonnage de 1800* à 4500 t/j. Aux circuits existants de broyage, de flottation du cuivre, de cyanuration et du charbon en pulpe, les circuits suivants furent greffés : broyage semi-autogène, flottation du zinc, manutention des concentrés (épaississage, filtration, entreposage et chargement automatisé), décantation à contrecourant et précipitation au zinc, destruction des cyanures et remblai en pâte. Cet article se veut une revue des différentes étapes du projet d'agrandissement du concentrateur qui se sont effectuées par phases progressives de 1997 à 2000. De plus, une description des nouvelles technologies sélectionnées et implantées est présentée.

May 1, 2001

By L. Wolofsky

"The Candego property is in Boisbuisson and Christie Townships, Quebec, about 13 miles south of Marsoui, a village on the north coast of the Gaspe peninsula, 80 miles east of the railhead at Matane. It was the first producing mine in the peninsula. Production to October 1954, when operations were suspended, totalled 68,497 tons of ore, which yielded concentrates containing 8,706,535 lb. lead, 5,870,272 lb. zinc, 355,526 oz. silver, and about 1,000 oz. gold. The property was acquired by the present company in the summer of 1955.The mine has been developed by seven adits, driven into the west slope of the valley of the Marsoui River. The river here is at an elevation of about 1,600 feet, and is roughly 1,500 feet below the level of the adjacent upland. Adit elevations range from 1,760 to 2,330 feet. Five of them are in one vertical zone, on what was originally believed to be a single vein. Past production has come from Nos. l to 5; the chief present high-grade ore reserves are in No. 7.The author's observations were made in adits Nos. 3 to 6, in several of the old pits, in the surface trenches, and on drill core, at various times between December 1952 and September 1953. Much of the surrounding area has been mapped by Jones (I) and McGerrigle (2) for the Quebec Department of Mines. H. M. Kingsbury served as consulting geologist to the mining company for several years.General GeologyThe Candego veins occur in Lower ( ?) Ordovician sedimentary rocks which form a strip about 15 miles wide along the north coast of the Gaspé peninsula. The series includes limestones, shales, and sandstones, mildly metamorphosed in places. Three miles south of the mine is the north contact of the granitic intrusive, regarded as Lower or Middle Devonian, which underlies the Tabletop Mountains area. This batholith is about 10 miles long, in a north-south direction, and about 4 miles wide. At Mount Albert, about 5 miles west of the Tabletop intrusion, is a group of basic rocks, amphibolites and serpentinized peridotites, thought to have been intruded at the close of the Ordovician."

Jan 1, 1949

By J. Koike

Mg alloys for structural application have attracted much attention. However, high process cost and poor mechanical reliability are major concerns upon expanding the application to a wider area. In order to break through these barriers, better ductility is desired at lower temperature. Plastic anisotropy and peculiar twin formation appear to play key roles in the deformation and fracture mechanisms of Mg alloys. In the paper, dislocation slip and twin formation are reviewed. The effects of crystallographic texture and grain size are discussed. The results suggest that a good control of microstructure and texture can improve ductility and mechanical reliability of Mg alloys.

Jan 1, 2006

By Sergio Fuentes

During the past fifteen years, mines utilizing the block caving method have improved performance and systematically reduced total mining costs. This paper describes improvements in mine design, mine planning and mine management, including methods enabling the Chilean and International mining industry to ensure cost savings and productivity growth while using the block caving method. These improvements have encouraged the re-evaluation of underground operations at operating and closed open pits, and challenge surface mining applications as the only low cost mining method. This paper describes a strategy to estimate the optimum open pit to underground transition time during the life of a mine.

May 1, 2003

"In the UK, Ireland, and Western Europe, the mineral resource and reserve reporting standard is the PERC Code, developed and maintained by the Pan-European Reserves and Resources Reporting Committee, which is a standing committee set up under the auspices of a number of professional organisations which include the Institute of Materials, Minerals and Mining (loM3), the Geological Society of London (GSL), the European Federation of Geologists (EFG) and the Institute of Geologists of Ireland (IGI) to develop a Pan-European reporting code. The PERC Code supercedes the old IMMM Reporting Code 2001 and is recognised by the UK securities regulators and stock exchanges.""FOREWORD1 The Pan European Reserves and Resources Reporting Committee (PERC) Code for Reporting of Exploration Results, Mineral Resources and Mineral Reserves (further referred to as 'the Code') sets out minimum standards, recommendations and guidelines for Public Reporting of Exploration Results, Mineral Resources and Mineral Reserves in the United Kingdom, Ireland and Europe. The history of development of this code is summarised in Appendix 4.This 2008 edition supersedes all previous editions of The Reporting Code and the IMM Reporting Code.INTRODUCTION2 In this edition of the PERC Code, important terms and their definitions are highlighted in bold text. The guidelines are placed after the respective Code clauses using indented italics. They are intended to provide assistance and guidance to users in interpreting the application of the clauses in the Code. The same indented italics typeface formatting has been applied to Table 1, and to Appendices 1 and 2 which form part of the Guidelines.3 The Code has been adopted by the Institute of Materials, Minerals and Mining (loM3), the Geological Society of London (GSL), the European Federation of Geologists (EFG) and the Institute of Geologists of Ireland (IGI), and is therefore binding on their individual members.Appendix 1 contains a table of generic terms and their equivalents, designed to avoid unnecessary duplication or ambiguity in the textAppendix 2 provides Rules of Conduct for Mineral Resource and Mineral Reserve estimators that should be considered in addition to the Codes of Ethics normally applying to members of professional institutions."

Jan 1, 2003

By Laxman (Lucky) Amaratunga, Hisham Madi

Final disposal of mine wastewater neutralization sludge continues to be one of more pressing problems in the mining industry. The disposal of mining and metallurgical waste products into underground reduces the environment impact and improves the safety of the mining operation and the economics of the enterprise. This current research focuses on an investigation of utilization of mine wastewater neutralization sludge obtained from Kidd Creek Mine site, as a supplementary material for their proposed deep mine pastefill system. Their proposed pastefill consist of combination of rock aggregate in a matrix of imported sand and tailings with binder (Portland cement + Slag cement). Pastefill mixes containing various percentages of the waste sludge 0 (control mix), 1, 2, 3, and 5% by weight as replacement to the fine sand were prepared and tested with different percentages of binder. Hypothesis behind this approach is to study the behavior of sludge as replacement of sand in matrix as well as its ability to act as a binder. Compressive strength, percentage of sludge, binder dosage, slump, water to cement ratio, percentage of solid, and curing time are being observed. The results indicated that sludge can be incorporated into the pastefill and enhance its strength without compromising the pastefill quality and integrity.

Jan 1, 2004

During industrial copper electrowinning, a fraction of the electrolyte becomes entrained with the oxygen gas bubbles that are evolved at the anodes. The fraction of entrained bubbles increases from the bottom of the anode to the top, resulting in a bubble distribution that appears as an inverted wedge between the cathode and anode. Since the bubbles act as insulating spheres, electrolyte resistance increases from the bottom of the electrodes to the top resulting in correspondingly higher local current densities and uneven copper growth along the cathode. To counter-act the inherent tendency toward excessive copper growth near the bottom of the cathodes, the use of tapered anodes was examined. The potential improvement in cathode current distribution was evaluated by comparing the primary current distributions for 2-D computer models of a copper electrowinning cell with plate shaped anodes against one with tapered anodes.

Jan 1, 2007

By O. Moselhi

This paper describes a method for selection of most suitable project delivery systems for capital projects. It expands upon the method advanced by the Construction Industry Institute (CII) in 2003, and incorporates additional decision criteria and project delivery systems in a multi-tier decision computational platform. The paper integrates the analytical hierarchy process to alleviate the inherent subjectivity associated with the assignments of relative weights to selection criteria used in the CII method. It also expands the range of project delivery options to include Public Private Partnership (PPP) and Integrated Project Delivery (IDP). The range of selection criteria was expanded by 60, beyond the 20 criteria of the CII method. Relative effectiveness values are proposed for the added project delivery systems making use of recent project cases in Canada and the USA. The method was implemented in a spreadsheet application. Multiple scenarios were considered for one of the cases presented in the CII study and a sensitivity analysis performed based on the developments made in this paper. The differences in outputs between the CII method and the proposed method are discussed. This is the first decision framework that incorporates both the presently used PPP and the recently introduced IDP, along with the widely used project delivery systems. The developed method allows users to filter out the factors and alternatives that do not apply to the case at hand, based on key inputs at the upper tier. The method is flexible and can easily be expanded upon and customized by the user.

Aug 1, 2013

By Edward R. T. Tiekink

Metal complexes continue to find therapeutic applications for the treatment of a wide variety of human ailments. Amongst these, gold(I) thiolates are used to treat rheutmatoid arthritis but, usually in combination with other treatment or as a last resort. New therapeutic uses of gold, both as gold(I) and gold(III), are being sought, including against cancer, the focus of the present contribution. It will be demonstrated that certain gold(I) complexes show exciting cytotoxicity profiles, rivalling those of cisplatin and standard chemotherapeutic agents. More importantly, anti-tumour activity is demonstrated in vivo, albeit in a mouse model. The presentation will give a brief overview of ?metals in medicine? with a focus on gold and will summarise some recent advances in the development of goldbased anti-tumour agents.

Oct 1, 2003

THIS article describes the origin and details of a hydraulically operated switch to control the operation of an automatic underground pumping system. This system was installed in December, 1939, on the 2,350-foot level at No. 5 shaft of the Buffalo Ankerite mine. The pumping unit consists of an 8-stage centrifugal pump direct-connected to a 150 h .p., 2,200 volt motor. Pumping capacity is 200 gallons per minute under a 1,315-foot head and with a flooded suction. The control consists of a 200 amp., 2,200 volt oil-immersed starter with thermal overload protection, thermal protection on the pump, and a flow switch that is bypassed for 30 seconds after the pump starts. The 30-second time lag is operated by a relay mounted on the panel. There is a swing check valve in the discharge line of the pump which originally operated the flow switch by means of a connected outside lever which closed the switch as the check valve opened.

Jan 1, 1945

By David F. Machuca-Mory

Modelling the geometry of a vein is a crucial step in resources estimation. The resulting models are used as mineralization domain boundaries and have a direct impact on the tonnage of estimated resources. Deterministic models are often built using time consuming wireframing techniques usually based on hand interpretation of the drillhole intercepts. Another approach consists in coding the drillhole samples by a function of their distance to the veins contacts. The coding is subsequently used for modelling the vein contacts away from drillholes. This is a more efficient approach and is able to provide a measure of tonnage uncertainty. The use of location-dependent variograms improves the modelling by incorporating local changes in the anisotropy of the vein structure. This combined approach results in more realistic vein models, particularly when the geometry of the vein has been are altered by folding, shearing and other structural processes. The approach is illustrated on a realistic case study.

Oct 1, 2009

By C. Andrews

Fuel cell testing requires fully automated operation, on-site configuration of tests, and real-time monitoring for performance and failures. Balancing the flexibility and programmability of a test station with reliability, cost, and user interface can be a daunting challenge to the test equipment engineer. Endurance testing of fuel cells requires the highest level of reliability for test stand hardware and software without compromising automation capabilities or users interface. Techniques for implementing an ultra-reliable test platform addressing hardware limitations, sophisticated watchdog monitoring to prevent inadvertent shutdowns, and software limitations (e.g., balancing a highly-functional graphical users interface with reliability) are presented.

Jan 1, 2005

By I. H. Redeker

North Carolina is the leading state in the USA in feldspar, mica, and spodumene production. Mixed feldspar, spodumene, mica and quartz are mined from hard rock, open pit deposits and recovered by flotation from the fresh pegmatite type ores. Potash feldspar, mica, clay and quartz are recovered from weathered decomposed pegmatites. The North Carolina State University has a Minerals Research Laboratory in Asheville with trained personnel and flexible pilot plant equipment. The flowsheets for the feldspar, spodumene and mica producing companies and for large phosphate and glass sand flotation plants were developed and tested in Asheville. Examples and problems of pegmatite flotation are demonstrated with flowsheets and slides.

Jan 1, 1981

By Y. C. Kim

This paper discusses Air Liquide's patented SPALTM (Surface Protection Air Liquide) technology and process for the inerting of coreless induction furnaces using cryogenic liquid gas. Air Liquide Canada Inc., in collaboration with Riverside Brass and Aluminum Foundry Limited (Riverside Brass), conducted plant trials to demonstrate the applicability of the SPALTM technology for copper-based alloys. Results showed that with SPALTM, Riverside Brass benefited from a significant increase in metal yield as the level of dross formation was drastically reduced. Together with the many other benefits of this technology, SPALTM demonstrated to be a non-negligible cost-effective solution to reduce metal production costs. In an effort to optimize the argon flow, different flow rates were used and the oxygen level above the metal bath was measured to pinpoint optimal flow. The results of metal yield, charge mix, dross formation, and melt temperature are compared with and without argon. The metal yield improvements are dramatic and calculated net savings are presented hereunder.

Jan 1, 2007

By Lisa J. Renaud

For generations, the mining industry has been committed to work toward developing new technology that can improve safety and increase production. Now with a more environmentally conscious society and tighter environmental regulations, a natural progression for the industry is to develop and take-on ?green? or environmentally friendly technologies. Not only could this improve the sustainability of operations, but could also reduce the long-term environmental impact footprint that is left behind. Algae represent a new frontier in research and development. As discussed specifically in this paper, algae, specifically microalgae, can be used for the production of biodiesel and other green chemicals by exploiting carbon dioxide and waste heat contained within process off-gasses. The potential positive benefits of this approach in terms of contribution to community and the environment are significant, and the focus of our research and development on microalgae production technology.

Oct 1, 2010

By K Byrne, W. Hawker

The average grade of copper concentrate is steadily declining, forcing the industry to turn to lower grade and metallurgically challenging orebodies. When faced with a low grade, challenging ore, mining companies are often forced to choose between high recovery at low grade or low recovery at high grade. Hydrometallurgical processing of copper concentrates using metathesis reactions, which replace iron with copper in copper-iron sulphide minerals and increase the copper to sulphur ratio in copper sulphide minerals, provide an opportunity to upgrade copper concentrates and potentially allow high copper recovery for a high grade concentrate. Factors such as concentrate mineralogy, reaction time and temperature, and the concentrations of copper, chloride and acid in solution are reported to affect the reaction extent and mineral phases formed by metathesis. In this paper, a copper concentrate has been studied over a wide range of conditions to investigate the influence of these key parameters on the extent of copper metathesis reactions and product phases formed. Solution and solid phases are assayed with the main mineral phases identified by Quantitative X-Ray Diffraction. INTRODUCTION The minerals present in copper deposits determine the prospective processing options either: pyrometallurgical or hydrometallurgical. For copper oxide ores, copper is typically present as oxides, carbonate, chlorides, silicates and sulphates. These minerals are readily solubilised in acid and are usually treated through hydrometallurgical processes. The typical process route for copper oxides is to leach copper into aqueous solution, purify and upgrade the solution phase through solvent extraction and then recover copper as metal by electrowinning (Davenport, King, Schlesinger, & Biswas, 2002). Copper sulphide deposits may contain a multitude of copper bearing minerals, including chalcopyrite, bornite, enargite, covellite, digenite and chalcocite. The copper ore grade and treatment options are affected by the mineral type and distribution. Sulphide ores are typically treated through comminution and mineral flotation to form concentrates, followed by pyrometallurgical smelting. Hydrometallurgy can also be used to process sulphides depending on the mineralogy and impurity levels (Davenport et al., 2002). The trend of decreasing copper grade with increasing impurity levels are common across the mining industry and pose future challenges to copper processing. This trend has prompted research into hydrometallurgical options for upgrading copper concentrates. One promising hydrometallurgical option is using metathesis reactions. Metathesis reactions, sometimes also called double replacement or displacement reactions, are chemical processes involving the exchange of bonds between two chemical compounds or species. In this case, the metathesis reactions involve copper in solution exchanging with cations in the solid sulphide concentrate. The driving force for copper sulphide metathesis is the relative affinity of the exchanging cation elements for sulphide. Based on sulphide precipitation diagrams, the expected order of affinity for sulphide should be Hg2+ > Ag+ > Cu+ > Cu2+ > Bi3+ > Cd2+ > Pb2+ > Sn2+ > Zn2+ > Co2+ > Ni2+ > Fe2+ > Mn2+ (Monhemius, 1977). Hence, copper metathesis reactions are capable of increasing copper content and removing impurities such as iron, nickel, zinc and lead from copper concentrates.

Jan 1, 2019

By T. T. Chen, J. E. Dutrizac, G. Poirier

In the Waelz kiln process, EAF dust is converted to an Fe-rich slag, a (Zn, Fe)-rich dust that is recycled to the kiln and the Zn-rich Waelz oxide which is subsequently up-graded for the recovery of zinc. To clarify the reactions occurring, the Waelz kiln products from a European Waelz plant were characterized mineralogically to determine the mineral species present, their micro-textures and the metal carriers. The EAF dust contains 27 % Zn, and consists mainly of ZnFe2O4 and ZnO, together with minor to trace amounts of NaCl, PbCl2, KCl, CaO, Ca2Fe2O5, Fe203, FRO, Pb oxide and various Ca-Fe-Al-Mn silicates. The KCI and NaCI sometimes agglomerate the other particles. The slag consists of nodules which often exhibit colloform structures. The slag contains of variable amounts of Fe, FeO(OH), FeO, gypsum, Ca(OH)2, Ca2SiO4 and various Ca-Fe¬Al-Mg-Mn silicates as well as minor to trace amounts of ZnFe2O4, Cr-Fe oxide, Mn-Fe oxide and other species. The Waelz oxide contains 57-61 % Zn, and consists predominantly of ZnO, with minor to trace amounts of KCI NaCl, Pb(OH)Cl, Pb20(SO4), Pb chloride, ZnSO4, ZnFe2O4, Ca2SiO4, Ca2Fe2O5, Ca-Fe silicate and NaZn4(SO4)(OH)6Cl.6H2O. The KCI agglomerates the other particles in the Waelz oxide. The recycled dust appears to be a mixture of EAF dust and Waelz oxide, but it contains relatively more coarser-grained metallic Pb and Pb oxide particles.

Jan 1, 2004

By Marcel Vallée

"Abstract-In recent years, several unsavory events in international mineral exploration, as well as several widely publicized project difficulties and failures have occurred. The report Setting New Standards has "raised the bar" and proclaimed a "commitment to continuous improvement... and change." We need to evolve from our "generally accepted" practices to more effective quality assurance policies, guidelines and standards. Several steps will be required to support the work of the "qualified persons" now wholly entrusted with technical and professional matters:• adopt a mineral development model and objectives appropriate to orient the selection of workmethods and verification procedures suitable to increase the profitability of these activities;• review the definitions and implications of the terms practice, guideline and standard;• review three quality assurance systems with emphasis on commitment of company management and complementary emphasis on systematic quality policies, plans and manuals (ISO 9000), continuous improvement through "profound knowledge" (Deming, 1986), and self-appraisal of continuous improvement and client satisfaction using the Qualimeter Guide (Québec Society for Quality);• determine, from the objectives of the mineral development model proposed and the problems often encountered, the requirements of resource/reserve estimation and the production feasibility study. To regain investors’ confidence and improve the returns from mineral development activities, an explicit commitment to quality by the board of directors and the management of every company is required.A number of mining companies have gained ISO 9002 certification for their operations but exploration companies should start by developing and implementing quality assurance guidelines and standards based on the ISO 9001 pattern, without achieving actual ISO certification in the short term. Both professional associations and industry organizations must be involved in the process of developing the required quality and continuous improvement guidelines and standards."

Jan 1, 1998