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The Boleo project is located in Mexico close to the town of Santa Rosalia on the Baja Peninsula. The Boleo deposit contains copper, cobalt, zinc and manganese values as oxides with minor sulfides. The Boleo deposit is metallurgically challenging due to: 1) the requirement to recover four separate metals; 2) the presence of high levels of clay in the deposit resulting in difficult solid-liquid separations, and; 3) the need to use seawater for the bulk of the processing. Baja Mining, Bateman Engineering and SGS Lakefield Research have collaborated to develop and test a process flowsheet to recover copper, cobalt, zinc and manganese products at Boleo. The key steps in the flowsheet are: ? Feed preparation (scrubbing and ball milling of oversize) in copper raffinate ? Ore leaching using oxidative and reductive leaching ? CCD washing using high rate thickening technology ? Copper SXlEW ? Treatment of a bleed solution for cobalt, zinc and manganese recovery The process for cobalt, zinc and manganese recovery involves iron and aluminum removal followed by cobalt/zinc bulk extraction using CSIRO's DSX solvent extraction system and selective zinc and cobalt stripping. The zinc strip solution is evaporated to produce zinc sulfate monohydrate crystals to market and cobalt is recovered via a further SXlEW process as high purity metal. Manganese is precipitated as manganese carbonate from the DSX raffinate solution. This paper will review the Boleo process flowsheet and provide detailed results from the 2006 pilot plant operation conducted at SGS Lakefield in Canada.

Jan 1, 2007

By M. Kalin

Tailings deposits are frequently the source of ground water contamination due to the transport of contaminated tailings pore-water. If amendments to tailings covers could be made to facilitate a precipitation reaction and halt or reduce the generation of acid in pyritic tailings, the quality of pore-water quality would be improved which would in turn reduce the production of contaminants. The effects of phosphate wastes, added to base-metal mine tailings in Newfoundland, Canada, were tested. Laboratory and field experiments determined the effects of different mixing ratios of phosphate wastes to tailings volume (1:4, 1:8, 1:12 and 1:20, dry weight) for a total period of 3.2 years. The addition of phosphate at ratios of 1:4 to 1:12 substantially increased the pore water pH, and reduced both acidity and Zn concentrations. These results suggest that addition of phosphate wastes to tailings covers can reduce acidity generation and improve tailings pore-water quality.

Jan 1, 2004

By M. Eikerling

The full competition between mass transport and reaction in PEMFC unfolds in cathode catalyst layers (CCLs). Recently developed models provide vital insights into effects of thickness and composition on effectiveness of catalyst utilization and performance. However, the CCL's key function in liquid water removal is rather unexplored. Studies of water balance in PEMFCs focus mostly on other cell components. Notwithstanding this prioritization, a simple calculation shows that the CCL is the PEMFC's favourite medium for conversion of liquid water into vapor. Porous structure and wetting properties steer the interplay of evaporation, transport and reaction. A model will be presented, that links pore space morphology, composition, distributed properties (concentrations, pressures, reaction rates, potential) with global performance (critical phenomena). It reveals how problems of flooding in the fuel cell could be mitigated by properly adjusting catalyst layer structure and operation conditions and under which conditions all liquid water arriving in the CCL would leave it as water vapour through the CCL/GDL interface. Results for a simple variant of the model emphasize the role of the CCL as a watershed for the whole cell.

Jan 1, 2005

By R. M. Kalanchey

The application of pressure oxidation processes to copper feed materials has gained increased exposure in recent years and some of these processes have made commercial inroads, although rather limited to date. Among the hydrometallurgical processes with significant commercial potential, Dynatec's copper pressure leaching process has been applied to arsenic-bearing copper materials and has shown, through a number of batch and continuous test programs, that pressure oxidation is a technically feasible option for the recovery of copper with coincident sequestration of arsenic in an environmentally benign residue.

Jan 1, 2007

The uranium ore processed by the McClean Lake Operation is co-mineralized with niccolite, rammelsbergite and gersdorffite (nickel arsenides). During the strong acid leach process, the majority of the reduced arsenic is oxidized and liberated into the lixiviant solution as As+5. Following uranium extraction, the residual raffinate solution, enriched in As+5, reports to the tailings preparation process. In this process, Fe+3 is first added and mixed with raffinate (pH~1) to achieve a Fe+3/Astotal molar ratio of at least 3. This is followed by two stages of neutralization, using slaked lime to achieve a solution pH of 4, and approximately 7.5, respectively. Synchrotron based x-ray absorption techniques (XANES, EXAFS) applied to neutralized raffinate solids and tailings samples collected from the tailings management facility provide evidence that arsenic has been precipitated as a poorly crystalline form of the mineral scorodite (FeAsO4?2H2O).

Aug 1, 2010

By O. Moselhi

The purpose of this research is to evaluate the impact of Building Information Modeling (BIM) on Just-In-Time (JIT) material delivery, with a focus on how the use of BIM can help improve efficient implementation of JIT and reduce the cost of material management. Previous research and a number of case studies have addressed the positive impact of BIM on construction at large but none focused on JIT in construction. This paper presents a methodology for selecting reliable material vendors. It also utilises the integration of BIM and scheduling software to generate quantities of material and its required delivery time to improve the flow process and improve its reliability to minimise related delays and productivity losses arising from idle and non-productive time of equipment and labour on jobsites. 4D visualization is utilized to support coordination and timing of JIT material deliveries in an effort to minimize congestion on job sites. Case studies on JIT material deliveries are presented and the impact of BIM implementation on reducing the cost of material management is evaluated. The joint effect of BIM and JIT on quality control, elimination of waste, reduction of inventory buffers, and on relationships with material vendors are evaluated by analysing and comparing data from case studies. The paper also presents a methodology based on multi-attribute decision criteria for modelling the selection criteria for material vendors. The model can assist in ranking vendors not only based on cost and quality but also on their reliability in delivering material on time.

Aug 1, 2013

By Leibniz University, D. Zapf

"The demand for gas storage operations with high withdrawal rates and operation modes different to a seasonal storage regime requires a more detailed rock mechanical consideration of thermal induced stresses in the vicinity of the caverns. This means that the change of gas temperatures during operation and the consequences of these temperature changes on the stressing of the salt rock mass must be taken into account in the rock mechanical dimensioning. Within the rock mechanical calculations a loading history, i.e. a pressure versus time dependency, has to be defined. As rock salt has a time dependent material behavior stress redistributions in the rock salt mass take place even under constant internal pressure conditions. Therefore not only withdrawal and filling periods but also the duration of phases with nearly constant internal pressure is significant for the resulting state variables. Within the paper the differences and consequences for the rock mechanical recommendations are discussed. As a result it can be concluded that recommendations with respect to minimum operation pressure as well as for maximum withdrawal rates can be answered only in connection with the respective time intervals."

Jan 1, 2015

By Lyall J. Lichty

THE property of New Calumet Mines, Limited, is on Calumet island, in the Ottawa river, about sixty-six miles northwest of Ottawa. Lead and zinc orebodies were discovered here in 1893. A gravity concentration plant was built in 1912 but was not a success metallurgically, and the plant was later destroyed by fire. A programme of diamond drilling on the property, started in 1937 and continuing to 1942, indicated ore reserves amounting to 1,300,000 tons averaging 2.75 per cent lead, 8.82 per cent zinc, and 0.041 oz. gold and 6.24 oz. silver per ton( l ). These orebodies have been developed underground by cross-cutting and drifting from a three-compartment vertical shaft, sunk to a depth of 745 feet. 'The ore is a contact metamorphic deposit occurring in rocks of the Grenville series, on or near the contact between biotite gneiss and an overlying calcareous amphibolite(2,3). It consists chiefly of iron-bearing sphalerite, galena, pyrrhotite, pyrite, and minor amounts of chalcopyriteand argentite. The gangue minerals closely associated with the ore are calcite, quartz, and various lime-silicate minerals.

Jan 1, 1945

By Z. -E. Nakagawa, O. Yamamoto

After the formation of a concentration gradient of SiC within C-C composite, either zircon or mullite thin films were coated on the surface by sol-gel process. Oxidation resistance tests of as-prepared composites with a couple consisting of a ceramic thin film and a SiC-gradient were then carried out in air at the temperature range from 600 to 1600°C. By the coating of zircon with a thickness of 1.5 µm, a pronounced oxidation resistance was observed; the mass loss by oxidation was almost negligible at 1000°C and one hundredth of original composite at 1400°C. In the case of the coating of mullite with a thickness of 1.0 pm, the marked improvement in oxidation resistance over the whole temperature range examined, from 600 to 1600°C, was found with the combination of a SiC-gradient and a mullite thin film

Jan 1, 2004

By Lou Covello

Bow Valley Industries Limited i conducting an on-going exploration program for gold in Archean, turbidite-hosted iron formations near the Lupin mine on Contwoyto Lake, orthwe t Territorie . Exploration philosophy and practice are modelled on the Lupin deposit where 70% of the gold occurs within laminated pyrrhotitechert. sulphide facie iron formation. Thi i intimately associated with barren to low-grade silicate facie iron formation which i enclosed by predominantly argillaceou meta ediment . This type of mineralization i amenable to exploration through an integrated program of geological and geophy ical surveying, consisting of the following: i) Geological urvey both regional and local to outline area of turbidites and a ociated iron formation. Structural and tratigraphic trends documented during this phase are useful in determining eventual grid configurations. Grids are then mapped and ampled at 1:2000 cale. ii) Magnetometer and gradiometer urvey at the ame scale define strongly magnetic diabase dyke and erratically magnetic portions of iron formation. iii) VLF-EM survey are u eful in outlining conductive trend invariably as ociated with sulphidic or graphitic phase of iron formation. iv) Geological updating and ampling of iron fom1ation based on the geophysical su rveys. This is necessary for the production of a final geologic map and a an adjunct to drill target election. In problematic instances self-potential urveys have documented the pre ence of non-conductive sulphide accumulations, and horizontal loop EM surveys have been used to determine conductor geometry and quality. Target selection is based on a synthesis of the information from all of the above surveys with the results of no single survey being critical to drill decisions. The program is designed to provide first-pass, detailed , cost-effective ground coverage of large areas of highly prospective geology.

Jan 1, 1986

By Steve Simard

Suite aux excellents résultats, obtenus avec la technologie des détonateurs électroniques dans des chantiers longs trous de grandes dimensions, nous avons décidé d?étendre cette technologie dans les ouvertures, dans le dynamitage de piliers et dans différents chantiers complexes. Cette technologie nous a permis d?effectuer l?abatage de chantiers avec un très grand nombre de trous sans détériorer le terrain. L?équation est bien simple avec les détonateurs électroniques, plus gros sont les dynamitages moins de fois les épontes se font ébranler, moins de blocs d?effondrement se retrouvent dans les points de soutirages entre les dynamitages et plus la fragmentation est meilleure. La flexibilité d?opération que nous avons obtenu avec les détonateurs électroniques est difficilement quantifiable, mais elle nous a permis de maintenir notre rythme de production mensuelle même avec certains chantiers complexes. Il est bien certain que l?utilisation des détonateurs conventionnels a encore sa place dans une mine conventionnelle comme Beaufor, mais l?utilisation des détonateurs électroniques a aussi sa place dans certaines situations spéciales. Pour terminer, bien que la technologie des détonateurs électroniques soit encore dispendieuse, nous pensons encore l?utiliser pour optimiser certains dynamitages et ainsi maintenir notre flexibilité d?opération.

Oct 1, 2004

By J. Standen T.

The main purpose of this publication is to present relevant advances in processes and technologies of importance for consideration in the design of new refineries and the modernization of existing refinery facilities. Operation at current densities of between 300 A/m2 and 350 A/m2 is already part of the criteria customarily implemented on recent projects. This is due in part to the development of permanent cathode technology. In recent years, this technology has also been integrated with process control and automatic electrode handling and preparation machines. The combined implementation of these technologies has the advantage of enabling the process to be monitored, thus assuring traceability and allowing greater knowledge of the process to accrue.

Jan 1, 2007

By H. Saari, D. Y. Seo, J. Beddoes, T. R. Bieler

Prior work on effects of lamellar orientation on creep rates and other mechanical properties have shown that having lamellae parallel to the tensile axis provides optimal creep resistance and good strength. Consequently, a directional solidification system was used to examine the effect of solidification rate on the development of crystals with lamellae parallel to the growth direction. The nominal chemical composition of TiAl ingots was Ti-46A1-2Mo-2Nb (at%) and the ingots were 20 mm in diameter and 180 mm long. The master alloy bars were placed in a high purity yttria mold on a copper chill plate and raised into the hot zone of a Bridgman furnace. The alloys were melted and then directionally solidified at withdrawal rates of 4, 8, and 12 mm/min. As-cast specimens were sectioned at positions of 4, 22, 66, 111, and 155 mm from the bottom of the ingot to evaluate microstructure and crystallographic texture as a function of distance from the bottom of the ingot. The directionally solidified microstructure consists of continuous columnar grains with fully lamellar structure, a network morphology of primary 13, yttria particles, and interlocked columnar boundaries. For all three ingots, the texture at 4 mm shows many peaks, with isolated strong peaks, and a slight tendency toward <111> plane normals within about 20° of the cylindrical axis. At 155 mm, all specimens showed substantially stronger clustering of <111> orientations near the cylinder axis, with the strongest clustering of poles occurring for the 8 and 12 mm/min specimens. Analysis of diffraction peaks indicates that strongly compressive residual stresses in the radial direction are present in the casting. The combined microscopy and texture analysis provides more complete understanding of the processes of directional solidification of TiAl alloys.

Jan 1, 2004

By L. Sun

Recently, micro-tubular solid oxide fuel cells (SOFCs) have attracted the attention of many researchers because of their numerous advantages over larger tubular and planar SOFCs. These include excellent thermal shock properties giving rapid startup/shutdown capability, a high volumetric power density compared to larger tubular SOFCs, and reduced sealing problem compared to planar SOFCs. In order to screen cathode materials for micro-tubular SOFCs, the perovskite cathodes were deposited, using a variety of methods, on 10.5 mol % yttria-stabilized zirconia (YSZ) tubes. Their electrochemical properties were then evaluated by using electrochemical impedance spectroscopy and steady-state polarization methods, based on a three electrode configuration, and with the reference electrode position carefully optimized. The oxygen reduction reaction kinetics at the cathode/electrolyte half cell were then investigated in detail.

Jan 1, 2005

By M. L. Free

Laboratory scale extraction of metals from heterogeneous materials such as copper ores is often performed using fine material to increase kinetics and reduce sample size requirements and costs. In contrast, commercial extraction is usually accomplished using much larger material sizes than are used in laboratory settings. The large size difference between laboratory testing and commercial application materials makes it difficult to use laboratory test data to accurately predict performance for commercial material. One solution adopted widely in industry is the use of large test columns. Large test columns cost considerably more to set up and run and take much longer periods of time to evaluate than laboratory scale tests with small particles. Consequently, from a cost and data collection efficiency perspective, the development of accurate scale up methods offers significant potential for saving both time and money. This paper provides details for a new approach to correct for scale-up phenomena in heterogeneous material processing.

Jan 1, 2007

By Kousuke Takahata, Hirofumi Yoshimura, Jun Nakahigashi

Studies of a protium treatment for grain refinement of a + ß type titanium alloy are reviewed and recent experimental results are introduced. Protium treatment consists of the following three processes: (1) protium absorption, (2) martensitic transformation and hot working, and (3) final treatment for protium desorption and recrystallization. A combination of these processes results in the ultra-fine grains of 0.3 to 0.5 µm in diameter with high angle boundaries. The ultra-fine-grained material exhibits superplastic elongation of over 9000%. Superplastic forming was successfully used to fabricate a denture base. These materials may be widely applicable as biomaterials in various medical industries.

Jan 1, 2004

What Discounted Cash Flow Analysis can do for you: ?Provide an accurate financial analysis of a project for the first 25 to 30 years of operations ?Identify cash flow requirements ?Identify relative sensitivity of the project to the various input parameters ?Place a value on the resource in place after 30 years of operations ?Correct for errors in input parameters

May 1, 2010

By Y. -B. Kang

New databases are being developed to provide the capability to evaluate the suitability of present and potential new Mg alloys for automotive applications through cost-effective calculations. An extensive and complete thermodynamic database is being prepared for Mg alloys formed from among 25 present and potential alloying elements. The database is being developed by critical evaluation, modeling and optimization of available phase equilibrium and thermodynamic data. It contains model parameters giving the thermodynamic properties as functions of temperature and composition. Using the FactSage thermodynamic software, users can access the database to calculate the amounts and compositions of all phases at equilibrium at any temperature and composition or to calculate any phase diagram section in multicomponent alloys, to follow the course of equilibrium or non-equilibrium cooling, to calculate corresponding heat effects, etc. A database of densities and lattice parameters of Mg alloys and intermetallics (as functions of temperature and composition) is also being developed in order to permit the calculation of volume changes during cooling and phase transformations, c/a ratios of the hcp phase, etc.

Jan 1, 2006

The successful application of color sorting machines has established sensor-based sorting in the mineral industry in recent years and is considered today as a significant innovation in processing technology. However, we are only at the beginning of (market) introduction. New sensor systems have been developed, which exploit material properties such as electrical conductivity, magnetization, molecular structure, thermal conductivity etc. This opens up new exciting pre-concentration and upgrading possibilities for many applications such as nickel, gold, copper and other ores as well as for industrial minerals, diamonds and other gem stones.

Oct 1, 2009

By Jeffrey D. Smith, William G. Fahrenholtz, Jose M. Soto

Interactions between A356 aluminum (Al-Si alloy) and dense fused silica (FS) riser tubes used for low-pressure casting of aluminum alloys were evaluated using a sessile drop approach. The tubes have a short service life, but cost and thermal shock resistance make them an effective solution. The main problem encountered during use is the reaction of aluminum with silica to form alumina and silicon, which causes failure. Tests have been conducted on as-fired (uncoated) and modified (coated) tubes. Experiments were carried out in a horizontal furnace at 1225°C under argon to minimize the effect of the aluminum oxide on the interactions at the alloy-silica interface. Images of the drop were acquired and contact angle values were estimated for uncoated and coated samples, but no significant differences in the contact angles were observed. Scanning electron microscopy revealed the presence of cracks at the interface between the reaction zone and the unreacted silica. The presence of reaction products (silicon in the reacting alloy and aluminum in a reaction zone between the alloy and the unaffected silica) has been confirmed using energy dispersive spectroscopy. A two layer coating system was found to be effective in reducing penetration of the aluminum alloy.

Jan 1, 2004