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By Candido Bariáin

A new vapochromic material of formula [Au2Ag2(C6F5)4(bipy)2]n (bipy = 2,2´ bipyridine) has been developed and used for the detection of some volatile organic compounds as acetone either in vapour or in water solution. The material is presented in the form of powders which colour changes with acetone vapours turning from bright yellow in the absence of vapour to white in the presence of vapour. By using the sol-gel technique, the powder ? dispersed in tetraethyl orthosilicate- was easily deposited on optical fibres. In order to study experimentally the behaviour of this material for construction practical optical fibre sensors, a sol-gel material doped with the vapochromic material is deposited onto an extreme of a monomode fibre connected to a coupler. The behaviour of the material was studied for different wavelengths and concentrations of acetone vapours and acetone/water solutions. Changes up to 4dB in the reflected optical power were detected. Optical fibre sensors have many advantages over conventional ones, such as electromagnetic interference immunity, passivity behaviour, possibility of using multiplexation techniques, low weigh and little size, etc. Actually, there is an increasing interest in developing optical fibre sensor for vapour detection in the chemical industry and in fact many sensor had been developed [1]. Some are based on the deposition of a sol-gel-based material either over the core of an optical fibre [1] or onto the thinner zone of a biconically tapered optical fibre [2]. Others are based on Fabry-Perot interferometers [3]. Also there are sensors based on the reflection of the light on films, on the fluorescence of dye-doped polymer cladding in fibre, on colorimetric reagents in the core of a silica fibre or on surface plasmon [4]. The possible materials for the construction of such sensor should be colorimetric reagents able to change the colour or refractive index in the presence of same organic vapours. There are not many metallic complexes with these properties, although same interesting examples have been reported in the chemistry of palladium and platinum as [Pt(p-R-C6H4NC)4][Pd(CN)4] described by Nagel [5] and Mann [6], which reported the construction of some LEDs. We recently reported the preparation of a novel vapochromic material (Fig 1) [7] which can be used for the construction of optical fibre tapered environmental sensors [8,9] of vapour organic compounds (VOC´s). Also we reported other nickel and palladium derivatives which present this type of behaviour [10]

Oct 1, 2003

By K. E. Haque

"Radium is selectively leachable from uranium ores with various types of lixiviants. Among a number of lixiviants tried on Midwest Lake uranium ore, KCl provided the highest per cent of radium extraction (60%-65%). Leach results further confirmed that a certain portion of Ra is not amenable to KCl leaching. More than 99% of the dissolved radium could be removed by treating the KCl leach liquor with barite or with radium selective complex resin (XFS-43230 resin of Dow Chemical Inc.) or by precipitating as RaBaSO4. Uranium leachings from the Ra-preleached uranium ores indicate that radium leaching prior to uranium may be applied as an extension to the conventional or alternative (i.e. acid chloride) leaching process of uranium ores in order to yield environmentally acceptable tailings (in terms of radium in the solids).IntroductionAt present, radium is considered as an environmental issue, particularly for uranium ore mine mill operations, rather than a commercial commodity. Radium was once a highly priced commodity ($180/mg during the first great war) but now it hardly has any commercial value. Its principal applications were in the field of cancer treatment and in the manufacturing of lwninous dials for watches. Nowadays readily-available synthetic radioisotopes are finding applications in place of radium.Because of scarcity and high toxicity, further commercial applications have never been explored.Radium was first discovered and extracted from uranium ore by P. Curie, M. Curie and G. Bement in 1898. Radium is widely distributed in nature but in exceedingly minute quantities. It is one of the daughter products of uranium or thorium and its maximum concentration is 3.3 x 10-7 part/part of U(21). Because of its short half-life (approximately 1620 years) in a geological time scale, its occurrence in nature as a distinct mineral is most unlikely.The details of the original radium leaching process developed by the Curies and Bernont are in the literature. This process essentially involved the roasting of uranium ore with caustic. carbonate followed by sulphuric acid leaching. The precipitated RaSO4 and BaS04 were treated with boiling Na2CO3 to convert them into the corresponding carbonates which later were dissolved in HCI. RaCI2 and Ba02 were separated and concentrated from the chloride liquor by fractional crystallization. But, in the course of time several modifications were made or proposed to the original process. Regardless of the process employed 226Ra extraction from the uranium ore was seldom better than 90%, and further as much as 20% 2URa loss took place during the concentration and purification process."

Jan 1, 1987

By C. Chongo, L. Little, Q. Mclennan

Since commissioning in 2005, First Quantum Minerals’ Kansanshi Mine in Zambia has produced over three million tons of copper and 1.8 million ounces of gold from a deposit with highly varied copper mineralization. The processing plant is complex with three independent flotation circuits, gold gravity concentration, atmospheric and high pressure leaching, solvent extraction, and electro-winning. For the first ten years of operating the plant, copper mineralogy was inferred from total copper and acid soluble copper assays, and various misconceptions developed about the mineralogy which impacted operational strategy and project decisions. In 2015, an on-site mineralogy section was set up with an Automated Scanning Electron Microscope, the Zeiss MinScan. This instrument has provided detailed mineralogical data that have debunked some of the mineralogy myths that had developed, highlighting the key underlying issues affecting processing performance. This has enabled the development of projects targeting losses of specific copper minerals in defined size classes, unlocking significant value. This paper describes some of the early misconceptions around mineralogy at Kansanshi processing plant, outlining projects that have benefitted from understanding copper mineral distribution. Learnings from Kansanshi are to be applied at other FQM sites, with a similar mineralogy program being set up at the Cobre Panama project. INTRODUCTION The deposit Kansanshi Mine is located in the North Western Province of Zambia, and it has been the largest copper producer in Africa for over a decade. The deposit occurs within a broad northwest trending antiform that can be traced for 12 km, hosted in a zone of complicated faulting, abundant vein injection, breccia development and down-dropped rock units that lies within Kansanshi’s mining license. The copper mineralization within the deposit is predominantly vein-hosted, although some is strata-bound, occurring in thin bands and veinlets parallel to foliation, and some is disseminated associated with albite-carbonate alteration (Gray, 2015). Supergene enrichment has led to significant variety in the copper mineral speciation. This alteration is complex, and has not followed the text-book principles with a neat layer of supergene mineralization overlying fresh hypogene ore. Rather, the occurrence and extent of oxidation and supergene enrichment is highly irregular throughout the deposit, sometimes occurring at significant depth in localized pockets and along fault lines. Gold mineralization tends to follow the copper within the deposit, but it is dominated by coarse-grained, free-milling native gold. The extent of copper oxidation – measured as the fraction of total copper that assays as acid soluble – is used to classify ore into three main ore types, named Sulphide, Mixed, and Oxide, which are then fed to three different primary crushers for processing in independent circuits.

Jan 1, 2019

By F. Weinberg

"The recent development of the continuous casting process for steel has required basic understanding in a number of areas in the metallurgcal sciences. In some areas, information is still lacking. The success of the application of basic knowledge and research to the process is evidenced by the fact that a large percentage of the steel now produced in the world is produced by continuous casting.A number of areas in which metallurgical science has contributed and is currently contributing to better design and control of the continuous casting process and leading to a better quality product will be considered. These include:(a) heat transfer studies of the entire casting process;(b) fluid flow in the tundish, strand and liquid metal stream;(c) solidification structure and segregation;(d) strength and ductility of steel at high temperatures related to bulging and cracking; and(e) problems related to horizontal casting developments.IntroductionThe continuous casting of steel is a relatively new technology in steelmaking. It is now used extensively throughout the industry. In Japan, for example, continuous casting accounts for approximately 40010 of steel production, and this value is expected to increase to over 50% in the near future . New steel plants are now designed to use continuous casting exclusively. This means the process must work well and be completely reliable, because all the steel produced must go through the caster.The development of the continuous casting process in a short period of time has required concerted research and development in many areas . I shall cite a number of examples of these developments and refer to work done in Canada when applicable. No attempt will be made to review all of the research in continuous casting, nor refer to all of the workers in the field.The developments in continuous casting are based in many cases on metallurgical science, as described below. The use of metallurgical science in these developments is qualitative, in that concepts and idea s are used, as opposed to quantitative values calculated from fundamental equations. In general, most metallurgical problems are too complicated to enable fundamental equations to be used without the introduction of uncertain approximations and boundary conditions in the calculations.Starting at the beginning of the steelmaking process, very extensive research and development has been carried out to produce liquid steel of the required composition and temperature. The replacement of open hearth furnaces with BOF furnaces reduced refining time from many hours to roughly 30 minutes for 250 tons of steel. Two BOF furnaces effectively enable a continuous flow of steel to be available in a plant, essential for the introduction of the continuous casting process. This area of research will not be considered here."

Jan 1, 1981

By Michael S. Moats, Addin Pranowo, Gerardo R. F. Alvear F., Nigel Aslin

The toxicity of arsenic is well known and documented. However, the presence of arsenic in copper electrorefining anodes and electrolyte is critically necessary to produce high quality cathode. Arsenic as well as antimony and bismuth concentrations vary depending on their relative concentration in the anode copper received from the smelter. This paper will discuss the behaviour and benefits of arsenic in copper electrorefining and the detrimental effects of antimony and bismuth on cathode quality and tankhouse performance. This will include the minimization and mitigation of problems associated with arsenic, antimony and bismuth including cathode contamination, floating slimes, scaling and anode passivation.

Jan 1, 2014

By Ron Bradburn, Derek Perkins

"The Brenda mine is located in south central British Columbia, 22 km north west of Peachland, in the heart of the Okanagan Valley. Situated at an elevation of 1500 metres, the mine area straddles the divide between the headwaters of Trepanier Creek and Peachland Creek. These flow into Okanagan Lake, the chief valley water resource located 1100 metres below. The creeks are of great significance to the water management of the area as they constitute the water supply for the Municipality of Peachland, a thriving retirement community with a population of 5000. A location map is shown in Figure 1.The history of the Brenda Mine operation has been well documented previously. After twenty years of operation, the open pit mine shut down in June 1990 due to the depletion of its ore reserves. During the course of its life, it produced 109 million tonnes of waste rock which is thought to contain approximately 0.10% copper as chalcopyrite and 0.015% molybdenum as molybdenite stored in four rock piles around the pit. Similarly, approximately 200 million tonnes of tailings were produced grading 0.015% copper and 0.005% molybdenum. During operation, tailings were hydrocycloned to produce a coarse sand for dam building with the fine slime stored behind the dam. It is estimated that 40% of the tailings were used for the dam construction. The layout of the mine site is shown in Figure 2.The mine was operated under a zero discharge permit. This was achieved by diverting practically all surface water flowing towards the mine area around the site. Water affected by mine operations, was discharged to the tailings impoundment, and recycled to the mill for reuse. The recycle rate was 90% and seepage from the tailings embankment and saddle dam was pumped back to the tailings pond. Because acid drainage was not a problem with the low grade Brenda rock, runoff from the rockpiles was initially released to the local environment. However, due to the alkaline nature of the waste rock, dissolution of low concentrations of molybdenum in the site runoff waters became evident by the late 1970's. The molybdenum content of Peachland Lake, the water reservoir for the municipality of Peachland, approached the Canadian Drinking Water Standard of 0.25 ppm. By 1979, a series of diversion and collection ditches was completed to direct all runoff water from the rockpiles to the tailings impoundment area. This had a significant detrimental effect on the site water balance causing it to go into a considerable surplus condition. During normal operation, this oversupply was contained by the rate of tailings dam building. An economic shutdown of the mine during 1984 forced a limited discharge from the site to protect the integrity of the tailings dam."

Jan 1, 1995

By Bruce K. McKnight

"The new H-W orebody was evaluated by considering its production at three technically feasible rates. Capital and operating costs were estimated f or each rate and production sequences were established using mining cutoff limits generated by an ore value algorithm. The viability of the project was then examined by conducting economic and financial analyses of each of the three production cases under various world economic scenarios. These analyses employing standard profitability measures demonstrated all three cases would be economically viable; the production case which maximized the Net Present Value of the project was the one selected for development and production.IntroductionWestmin Resources Limited and its predecessor company, Western Mines Ltd., has been continuously carrying out mining operations near Myra Falls in Central Vancouver Island since December 1966. The mining operation, whose current production rate is approximately 830 tonnes / day (t/d), based on ore derived from the Myra and Lynx Mines, produces copper, lead and zinc concentrates which contain significant quantities of gold and silver in addition to the base metals.In the late 1970s, with Lynx and Myra ore reserves slipping to unacceptably low levels, a major increase in mine-site exploration was initiated, with outside geological staff brought in to complement the efforts of the mine's geological staff. By the end of 1979, this program had resulted in the discovery of a significant new orebody on a deeper horizon some 300 metres below the one which hosts the Lynx and Myra deposits. Throughout the period 1980-1982, major drilling was carried out to evaluate the new H-W deposit and by the end of 1982, drill-indicated mineral inventory for the deposit compared with Myra, Lynx and Price ore reserves was as shown in Table I. During this same three-year period, a major development and evaluation program was underway comprising environmental monitoring and control programs, shaft sinking test mining, bulk sampling and mill testing, rock mechanics studies and preparation of the Stage I and II reports for the multidisciplinary Environmental Land Use Committee (ELUC).As a result of the preliminary engineering work and exploration drilling, it became rapidly apparent that the H-W deposit could support a considerably higher production rate than the current one. Accordingly, engineering studies including scheduling of development and production as well as capital and operating cost estimates, were focused on three possible production rates: 1350, 1800 and 2700 t/d. Our task was to select the optimum one of these three rates."

Jan 1, 1987

By M. R. Henzinger, G. Lenz, A. Gaich, Pötsch, W. Schubert, P. Wagner

"The better the information on the rock mass and its fracture system, the better is the basis for any rock mechanical decision that is required during the excavation process. While in conventional tunnelling free view to the tunnel face is available, possibilities are limited for mechanised tunnelling using a tunnel boring machine (TBM). An approach, already formulated in 2005, is used that produces digital photographs through openings in the cutting wheel of a TBM and merges them into a circular three-dimensional image. The 3D image is then used for geometric rock mass characterisation purposes including geological mapping, for example to measure spatial orientations or determine joint spacing. In the paper the basic concept is described together with first results from a pilot test.INTRODUCTIONA three-dimensional image unites digital photographs with spatial information on the objects/surfaces it shows. Since they combine geometric and visual information they are a straightforward source for geometric rock mass analysis and geological mapping. Their obvious benefits among others are: (i) they allow spatial measurements even in inaccessible regions, (ii) they provide objective and reproducible records of the rock mass conditions, and (iii) they increase working safety (Gaich et al. 2004).Pre-requisite for the generation of 3D images is the acquisition of at least two photographs from the region of interest. From the photographs the imaged object surfaces are reconstructed by means of image analysis using methods from photogrammetry (Slama, 1980) and computer vision (Hartley & Zisserman, 2001). See also Figure 1."

Jan 1, 2015

By O. Guyot, A. Broussaud, M. Revalor, G. Legrand, D. Kok, E. Roux

"The paper describes the advanced grinding control system implemented at Newmont Ahafo gold mine, Ghana in 2009 and 2010. It shows how the different components of the Advanced Process Control (APC) system cooperate for increasing plant performance.The SABC circuit processes hard rock from different pits mixed with a variable proportion of oxides. The control strategy is designed to address specific disturbances, including start/stops of pebble crushers, unavailability of oxides, changes in rock size distribution resulting from segregation in the stockpile, and changes in ore type and hardness.The system consists of an expert system per se with extensive use of fuzzy logic, supplemented by an online dynamic model of the process used as a soft sensor, a VisioRock™ rock size measurement system over SAG mill feed before addition of recycled pebbles, and an AudioMill™ system to analyze the SAG mill sound and detect impacts on liners. All these components are embedded in the same OCS© software platform, which, among other benefits, makes it easy to support the entire system remotely. The paper details the physical constraints and the variables that are manipulated. It describes the control strategy and the contribution of each component of the system. It also describes the project implementation and the performance of the system. In addition to a strong involvement and support of management, the very good acceptance of the operators has been facilitated by the remote access system that made it possible to immediately modify the system each time it was needed during the baby sitting phase.The system made it possible to increase gold production significantly through increases in tonnage and recovery thanks to a better control of the grind size through a stabilization of the secondary ball milling circuit and an improvement of the operating conditions of the classifying cyclones."

Jan 1, 2012

By É. Poulin, J. Bouchard, E. M. Pérez-García

Process control and optimization have always been crucial aspects in the mineral processing industry, and expectations constantly increase to cope with more stringent security, quality, efficiency, and environmental performances. The main challenges to reduce variability of key process variables, and steer profits to higher values while maintaining sustainability indexes within acceptable ranges come from nonlinear responses and circulating loads. The most commonly implemented control strategies rely on simple PID controllers for practical implementation and maintenance considerations. If arguably good performances are accomplished when these are adequately set up, there is also room for further gains by using more advanced methods such as model-based techniques. There is thus a need for more realistic process and equipment models. Based on advances of the past few decades, this paper introduces an autogenous/semi-autogenous mill (AG/SAG) model to be included in a modular comminution circuit simulation toolbox comprising ball/rod mills, material handling, and classification devices. The proposed mill model incorporates a modified version of the classic comminution equation that makes grinding rates proportional to the energy input. It requires the determination of a selection function (fragmentation rates) and a breaking function (fragments distribution). The former is modelled with an S-shaped curve characteristic of AG/SAG processes and the latter is a size-relative distribution of the produced fragments. The power draw is predicted employing the empirical equation of Austin. The paper also develops a case study to illustrate how the proposed simulation framework can capture the behaviour of an actual plant. Model calibration consists in an optimization problem that search the global minimum of the difference between predicted and measured/estimated size distributions, power draw, solid fractions, etc. Results demonstrate that the mill simulator can mimic an actual process in its operation conditions. INTRODUCTION Comminution is a key stage in the mineral processing industry, obviously because the phases of interest must be liberated to be able to recover them. In general terms, the global performance of a plant depends largely on the efficiency of the grinding circuit and on the material properties such as its grindability, density, and mineral grades. The subject has vastly been studied since as early as the 19th century, when Rittinger (1867) and Kick (1883) developed some of the first empirical models to relate grinding and energy input. The great interest in the subject comes from the fact that this operation is costly and, probably most concerning, highly inefficient. Buckingham et al. (2011) estimated that ore comminution can represent up to 60% of the overall plant power draw. Moreover, only a modest fraction of the power draw effectively translates into rock fragmentation. For grinding, estimates range between 1% and 25%, depending on the reference used, while the rest is mainly lost as heath (Fuerstenau & Abouzeid, 2002; Tromans & Meech, 2002; Bouchard et al., 2017).

Jan 1, 2019

By Avi Nanda, Robert Brandt, Alex Piatkiewicz, David M. Jones

In 2010 the United States Environmental Protection Agency (UESPA) revised the National Ambient Air Quality Standards (NAAQS) by lowering the permissible value to a 1-hour average SO2 concentration of 75 ppb. In 2012, the USEPA designated the Miami area as non-attaining for the new SO2 NAAQS. A number of options were studied to assist in bringing the Miami smelter into attainment with the new standard. The chosen solution included: Installation of a large tertiary hooding system over the converter aisle; Hooding of the anode vessels and treatment of the anode gas in a baghouse; Installation of a large 2,325,212 Nm3/hr caustic scrubber to treat the captured converter fugitives and anode off-gases; Installation of a secondary ESP for the tapping fugitive off-gas treatment system; and the continuous scrubbing of all acid plant tail stack gases. The modifications have reduced smelter SO2 emissions by 85%, achieving a world class SO2 stack emissions rate of 0.45 kg of SO2/tonne Cu. INTRODUCTION The Freeport McMoRan Miami smelter has been previously described in literature (Steinborn, Pasca, Sallee, Binegar, Bhappu). For the sake of brevity a brief description is given here. The Miami smelter is located 129 km east of Phoenix, Arizona near the town of Miami, Arizona. The smelter was established in 1915 and has undergone a number of process upgrades and modernizations over the years. The present smelter consists of an Isasmelt furnace, an electric settling furnace, four Hoboken converters, two anode refining vessels & one casting wheel; and one double contact sulfuric acid plant. Concentrates are railed & trucked to Miami from four Freeport McMoRan mines located in Arizona & New Mexico. The wet concentrates, typically containing 10% H2O with a Cu/S ratio of 0.85, are smelted in an Isasmelt furnace to a matte grade of 58%. The entire output from the Isasmelt is laundered into an Elkem electric furnace (originally installed in 1972 as the primary smelting furnace) for separation into matte and slag. Slag containing 0.85% Cu is skimmed from the electric furnace and discarded. Molten matte, containing 60% Cu, is tapped from the electric furnace and processed in one of four Hoboken converters to produce blister copper. Two anode refining vessels further refine the blister copper before the final product is cast on a single, 30 mold, casting wheel. All of the anodes produced at Miami are shipped to the Freeport McMoRan electrolytic refinery in El Paso Texas for refining into cathode copper. Smelter off-gases from the Isasmelt, electric furnace and Hoboken converters are combined and treated in a double contact acid plant to produce sulfuric acid. Acid produced at Miami is internally consumed at Freeport McMoRan mines in the region.

Jan 1, 2019

By Peter J. Barnard

Mitochondria play a key role in the regulation of apoptosis (cell death) and in diseases characterised by abnormal apoptotic responses such as cancer. Mitochondrial membrane permeabilisation (MMP), regulated by the mitochondrial permeability transition pore complex, is widely accepted as being central to the process of cell death. As a result there has been considerable recent interest in targeting mitochondrial cell death pathways in the development of new chemotherapeutic agents.(1) There is potential to overcome the two overriding problems in cancer chemotherapy?the common occurrence of drug-resistant tumour cells and the lack of selectivity of cancer drugs in differentiating between tumour cells and normal tissues. Significantly, carcinoma cells have an elevated mitochondrial membrane potential relative to normal cells and lipophilic cations are concentrated within mitochondria in response to mitochondrial membrane potentials. There is potential for the selective targeting to tumour cells with compounds having optimal lipophilic-hydrophilic character. Research stemming from the early 1980?s points to two distinct classes of Au(I) phosphine antitumour agents where an antimitochondrial mode of action has been implicated: (i) neutral linear two-coordinate Au(I) complexes such as triethylphosphinegold(I) chloride and the tetraacetylthioglucose gold(I) phosphine complex, Auranofin; (ii) cationic tetrahedral bis-chelated Au(I) phosphine complexes related to [Au(dppe)2]+.(2) Recently it has been reported that Auranofin, at submicromolar concentrations, induces MMP observed as mitochondrial swelling and dissipation of membrane potential.(3, 4) Both events are completely inhibited by cyclosporin-A, the specific inhibitor of MMP. The permeability changes were shown to occur at concentrations associated with the selective inhibition of mitochondrial thioredoxin reductase.(3) Auranofin is a potent and specific inhibitor of this enzyme due to Au(I) binding to the active-site selenol group.(5) The redox state of mitochondrial thiols may be critical in the control of MMP.(3) In general, swelling is stimulated by thiol blocking or oxidising agents and is prevented by thiol reducing agents.(1) Mitochondrial thioredoxin reductase may play an import role in the redox control of the permeability of mitochondrial membranes.(3) Our interest is in investigating the antitumour potential of Au(I) phosphine compounds using a number of different approaches. In recent work we have evaluated a series of hydrophilic analogs of [Au(dppe)2]+ containing pyridylphosphine ligands which have demonstrated greater tumour selectivity than the parent compound. To investigate the possible antimitochondrial mode of action we are studying the effect of [Au(dppe)2]+ and related compounds on isolated rat liver mitochondria. To assess whether the lipophiliccationic nature of the compounds determines the antitumour activity, we have synthesized a series of novel Au(I) complexes based on heterocyclic carbene rather than phosphine ligands. The similar chemistry and structural features of the two classes of complexes allow us to assess whether the phosphine ligands are essential for the antitumour properties.

Oct 1, 2003

By Chun-Sheng Liao, Chun-Hua Yan, Sheng Wu, Fu-Xiang Cheng

"INTRODUCTIONChina is providing more than 90% of the rare earth products consumed in the whole world. Acidic extractants are commonly used in the extraction separation of rare earths. Saponification of the acidic extractants by basic substances is usually necessary for the purpose of increasing and stabilizing their extraction capacity, and meanwhile inorganic acids are required for both scrubbing and stripping. Thus acids and bases are the main consumed chemicals, and the resulting salts are the main pollutants generated by rare earth separation processes. Currently, due to increasing environmental concerns in China, rare earth solvent extraction separation techniques are being developed to reduce both consumption and emission of chemicals, which is driving the developments on both theories and processes for solvent extraction separations.In the 1970s Prof. Xu et al. developed the Theory of Countercurrent Extraction (Xu, Li, & Yian, 1985). In recent years, the development of novel processes for rare earth separation has moved beyond the earlier theory. One rare earth separation process, the so-called hyperlink process, has been developed in the past decade and proven in industrial practice to dramatically reduce both the consumption and emission of chemicals during multi-component solvent extraction separations, and therefore is now widely used in the Chinese rare earth separation industry (Liao, Wu, Cheng, Wang, Liu, Zhang, & Yan, 2013). The present article will give a brief review of the development of the theory of the hyperlink processes, and the hyperlink separation flowsheets for typical rare earth mines in China designed using the theory.HYPERLINK PROCESSES (LIAO et al., 2013)A flowsheet of multiple-component separation consists of a couple of separation units. The units of a conventional flowsheet separately consume chemicals for saponification and scrubbing and discharge wastewater with resulting salts. In contrast, the separation units in a hyperlink process are hyperlinked and thereby the chemical demands of the whole flowsheet are decreased. For a feed containing t components of A1, A2, …, and At, it has been proved in theory that the separation mode of (AtAt-1…A2)/(At-1At-2…A1) is preferred in a single separation unit. The hyperlinking between separation units can have two forms. The link between two units locating at a same separation level, such as between (A4A3)/(A3A2) and (A3A2)/(A2A1), is known as horizontal hyperlinking. The link between two units located on different levels, such as between (A4A3A2)/(A3A2A1) and (A3A2)/(A2A1), is known as vertical hyperlinking. Both the hyperlinking forms have been proven to save chemical usage and consequently to lower the pollution emissions in industrial practices as well as in theory."

Jan 1, 2016

By F. W. Wellmer

"This paper discusses the changing nature of reserve/consumption ratios, using data from Canadian operations and focussing particularly on copper.IntroductionStudies in world metal consumption and world metal reserves are done regularly by the U.S. Bureau of Mines, the German Federal Institute of Geosciences and Raw Materials, and other institutions. Formerly, on the basis of these data, the following figures were calculated:• a static lifetime of reserves-reserves at year end divided by the consumption of the previous year;• a semidynamic lifetime of reserves-reserves at year assumed constant growth rate.These figures were severely criticized because they were purely theoretical and did not consider the availability of the raw materials.Recent practice is to calculate reserve/consumption ratios (R/C ratios) for periods(1) or for different years(2,3) and to interpret the trend. For base metals, these R/C ratios are increasing (Table 1). This had led to the conclusion that today the relative availability of base metal reserves has increased as compared to 10 or 15 years ago(4,5) As there are normally numerous deposits for each commodity, the anticipated production rates of deposits are irrelevant to this conclusion as long as the statistical distribution of possible production rates does not change significantly.The above conclusion is only justified if the quality and the nature of the data base remain the same. This is certainly the case for the consumption data. It is also assumed for the quality of the reserve figures, which usually take into account only proven and probable reserves. For the nature of the reserve figures, however, this does not seem to be true.Undoubtedly, the reserves increased in absolute terms between 1966 and 1978. To put the absolute reserve figures into perspective, it is common, as said above, to compare them with the mine production, which increased in the free world between 1966 and 1978; e.g. for copper by 40%, for Pb by 17% and for zinc by 36%. However, the reserves are also influenced by other factors, such as average size of the mines, changes in the grade of the mined ore, price-to-cost relationships and the like.The purpose of this paper is to examine the nature of the reserve figures in more detail. Because the completeness of mining data published in Canada is rather exceptional, Canadian .data serve as an example and it is assumed that the conclusions can be extrapolated to other mining countries or at least to those with free market systems."

Jan 1, 1981

By F. Pinto, C. A. Prato, R. J. Rocca, P. F. J. Huerta Soaje

"The seismic hazard for civil engineering structures is generally defined in terms of deterministic or probabilistic acceleration response spectra at an equivalent rock outcropping. The design of tunnels, however, requires the definition of demands in terms of accelerations at ground surface (near the portals) and in terms of both accelerations and velocities at different depths within the alignment. The design near the portals is controlled by inertial effects and is often times impacted by the possibility of slope instability and rockfall, whereas the design at deep sections is controlled by kinematic effects. These effects are accounted for in practice by introducing deformation patterns in the structure that are related to an assumed wavefield, often times ignoring the effect of the structural stiffness in the response. This paper presents a study regarding the definition of seismic demands for different sections of 14-km long tunnel in the Andes (Argentina-Chile), with a maximum overburden of 1750 m in a seismically active region. The tunnel will pass through volcanic massifs mainly composed by andesites and rhyolites.The study includes the definition of spectrum-compatible seismograms, deconvolution, and definition of accelerations and peak particle velocities for different overburden conditions. A kinematic interaction study for a 500-m tall ventilation chimney shaft is also described, where a simple formulation for the interaction analysis is considered in order to more accurately evaluate shear and bending demands. INTRODUCTIONThe seismic design of linear underground structures, such as shafts and tunnels, generally considers the inertial forces near the shallow sectors (e.g., portals) and the kinematically imposed deformations for the deep sections (e.g., Hashash et al. 2001). The inertial forces are often times evaluated on the basis of design spectra recommended by seismic hazard studies. The kinematic demands for the deeper sections, however, needs to be defined in terms of additional information which is not always indicated by the seismic hazard studies, e.g.; peak particle velocities and accelerations, and their variation with depth. These parameters can be determined by means of a site response analysis, whereby outcrop motions can be deconvoluted in order to evaluate motions inside the ground mass (e.g., Schnabel et al., 1972). Hashash et al. (2001) defines factors that may be used in order to account for attenuation of motions inside the ground mass. However, these factors are provided for depths up to 30 m only, whereas depths of tunnels structures can range up to thousands of meters."

Jan 1, 2015

By Avinash Kandalam, Markus Reuter, Jörg Kleeberg, Michael Stelter

The Top Submerged Lance (TSL) technology has obtained significant importance in the pyrometallurgy industry for nearly four decades. One of the advantages of TSL furnace is its high reaction rate, which is caused by splashing and turbulence of the melt. In contradiction, this phenomenon stands as a barrier for conducting experimental investigations to validate the simulation models. The highly turbulent and splashing environment in the TSL furnace is caused due to the immersion of the lance into the slag layer and thus the effect of the flame structure is directly related to the splashing, turbulence, reaction kinetics and life-span of the lance. Moreover, the material properties such as viscosity, density and the surface tension will also influence the flame structure. As a first step to understand the flame structure, attempts are made to generate a stable flame of the lance in an open environment. INTRODUCTION Top Submerged Lance (TSL) technology was invented during the 1970s at Commonwealth Scientific and Industrial Research Organisation (CSIRO), Australia by Floyd and Denholm. This technology was later commercialised and currently, there are about 100 TSL plants around the world commissioned by various licence holders such as AUSMELT (Outotec) and ISASMELT (Xstrata- Glencore Technology). Copper is the most produced non-ferrous metal followed by lead and zinc, see Hunt (2005). Today, a wide range of primary, secondary, and complex recycling materials are used as a feed material in the TSL, Alvear et al. (2010), Kaye et al. (2008). The working principle of TSL technology lies on inserting and submerging a lance from the top of a vertical cylindrical chamber into the slag layer. The lance is considered as the heart of the furnace, where the air and fuel are transported through two concentric tubes and are mixed in a combustion chamber, which is approximately 7 cm from the tip of the lance (considering the pilot-scale TSL furnace at the Institute for Nonferrous Metallurgy and Purest Materials - INEMET). The TSL furnace is very flexible with the type of fuel, feed material and the air input. The fuel can be natural gas/heating oil/fine coal particles and the air could be enriched with oxygen (Figure 1). The general mechanism of the TSL furnace lies on feeding the material from the top of the furnace and the material is pulled into the molten bath due to the high turbulent atmosphere, which results in high reaction rates. The thermocouples installed in the furnace (i.e. in the ceramic linings) allow the operator to know the temperature of the melt. For example, in the case of copper production the tapped material (i.e. matte/metal) can be transported to a settler for further processing or directly used.

Jan 1, 2019

By F. H. Samuel, J. E. Gruzleski, S. Valtierra, H. W. Doty, N. Andrade

In this work, the age-hardening behavior of cast Al-Si base alloys was investigated. It was found that multiple aging peaks are present in the age-hardening curves of Al-Si-Cu-Mg alloys. TEM observations reveal that the age-hardening behavior is related to the precipitation sequence of the alloy. For the Al-Si-Cu-Mg alloy, the first aging peak is the result from the high-density GP zones, while the subsequent are from metastable phases. The transition from GP zones to metastable phases may be the main reason of the formation of multiple aging peaks.

Jan 1, 2006

By A. Scheltema Beduin, M. Kalisch, E. Floch, R. J. Dijkhuis, H. J. Oterdoom

In metallurgical copper production, the traditional aim is to increase recovery of copper to the maximum. SMS Siemag (SMS) has supplied numerous furnaces for this application. New targets are to make sure end of line products are as safe as possible with respect to health and environment, and to maximize raw material utilization. This means a for example a minimization of leachable metals in slag, so it can be safely used as a construction material, and either a targeted concentration or fixation of volatile compounds, such as arsenic. Currently, 2 process routes are generally applied for slag cleaning. The first is grinding followed by flotation, and the second is slag cleaning in an (electrical) furnace. Popularity of both options has fluctuated over the years, and currently the milling-flotation seems to be the more popular option. In this article some of the advantages and disadvantages of both methods are described, and especially how long term environmental policies could have an impact on the decision which process route to choose. Finally, this article will describe some of the developments SMS is working on in pyrometallurgical slag cleaning that could influence the direction for the design of the copper plant of the future.

Jan 1, 2014

By W. Yang, R. Rajasingam, K. Mohanarangam

"Copper Electrowinning (EW) is a complex electrochemical process that involves the production of LME grade copper from copper rich electrolyte. The process involves the deposition of the copper ions onto the cathode from copper rich electrolyte with the production of oxygen bubbles at the anode. The process setups up a complex flow pattern within the cell as it is subjected to varying density gradients due to the deposition process along with oxygen bubble driven flow. It is a necessity to understand and quantify the flow behaviour within these cells in order to maintain the production of highest grade copper. In fact, the oxygen bubbles originating from the process is responsible for the generation of acid mist which is a designated as a carcinogen a major health hazard around EW tank houses. Hydrodynamic assessment of the process has so far been restricted to simple mass balances and some limited numerical modelling. All the models are based on assumed boundary conditions which has not so far been verified by any real-time physical measurement. This apparent gap has led to models which could not be directly used to track process changes or troubleshoot problems in EW tank houses. In order to address this gap, CSIRO has established a full size (width and height) transparent cell capable of simulating plant operating conditions (across the range currently used). With the use of sophisticated diagnostic analytical tools and measurement techniques it was possible to study all the operating variables (current density, flow rate, temperature, etc.) independently and their effect of bubble size, bubble velocity, gas hold-up as well as acid mist generation and its size. In order to address safety concerns in tank houses around acid mist early results outlining the factors contributing to its generation as well as the effect of various barriers to mitigate acid mist is outlined below.INTRODUCTIONA significant part of today’s copper production is through hydrometallurgical route which predominantly involves leaching, Solvent eXtraction (SX) followed by ElectroWinning (EW). Producing copper using this approach have shown to be environmentally friendly (Dresher, 2001) compared to the traditional smelting process. EW is the final step in the production of LME grade copper using the hydrometallurgy route. The electro-chemical process involves the use of a lead anode (Pb-Sn-Ca) and a stainless steel cathode to produce copper sheets using the copper rich electrolyte from the SX process and with the applications of direct current to the electrodes. This electro-chemical reaction results in the deposition of copper ions on the cathode with oxygen released from the anode as a by-product. Hydrodynamically, the oxygen bubbles create a bubble driven flow within the EW tanks with the surrounding electrolyte. A direct result of this could be seen from the quality of the copper deposited on the cathode. Most of the copper plates produced from the traditional tank houses have a rough texture at its bottom one-third while the top two-thirds have a smooth finish with a finer grain structure."

Jan 1, 2016

By P. Lauzon, C. Oprea, S. Zhou, G. Oprea, J. Rigby, T. Troczynski

Hydration of basic refractories could occur during storage, drying after installation or in use. In order to assess the hydration resistance of various commercially available magnesia-chrome bricks, hydration tests were performed in steam at 110, 120, 130 and 150°C. The changes of the modulus of elasticity by the impulse excitation method, apparent porosity, air permeability, average pore size and pore size distribution were correlated with the hydration data. Mineralogical and microstructural changes were also studied on selected specimens by XRD and SEM/EDS. The hydration mechanisms were discussed in correlation with the chemical and mineralogical compositions of the experimental bricks, in particular with the nature of the mineralogical phases at the grain boundaries.

Jan 1, 2004