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By R. Pérez, James A. Finch, F. Tavera, Cesar O. Gomez

"Gas holdup is a variable which affects the operation of flotation columns. On one hand, gas holdup is a function of bubble size (a function of sparger type, frother characteristics and concentration, and air flowrate), tailings flowrate, solids content, and mixing patterns in the collection zone. On the other, gas holdup defines flotation kinetics and carrying capacity. Therefore, gas holdup is a useful variable to control and diagnose the operation of a flotation column, but the lack of a reliable sensor for on-line gas holdup monitoring has prevented its use in industry.This work describes the principle and the practical difficulties associated with the development of a gas holdup sensor based on the measurement of the electrical conductivity of dispersions. Two different approaches have been devised. These approaches will be described and test results presented of prototypes in laboratory and industrial columns.Background.Several years ago, a research program was initiated at McGill to use electrical conductivity as the basis for developing sensors for process measurements in mineral processing. Electrical conductivity is an intensive property which is a function of the concentration of the different phases present in a dispersion. The initial focus was on the detection of the interface between two dispersions with different characteristics (i.e., that between the collection and froth zones in flotation columns or that between clear water and sedimented solids in thickeners). The technique works in this case by searching for the location at which a sudden change in specific conductivity occurs, as a consequence of different gas holdup or solids content, and absolute values of the specific conductivity of the dispersions involved are not necessary1,2."

Jan 1, 1995

By M. L. Jeremic

"Hydraulic mining consists of coal erosion by powerful jet s of water from hydraulic monitors operated by remote control. The broken coal is crushed and mixed with water and then transported from the face to the surface using gravity whenever possible. This is a simple, safe and productive method. It will easily satisfy North American productivity standards if the structural features and coal properties are favourable for water jet cutting technology (Kaiser Resources Ltd. , hydraulic mine). General ConsiderationIn open-pit mines, placer mining (Fig. I) and hydroelectric construction projects, hydraulic earth moving techniques have been successfully applied. The stripping and transporting of the overburden has been accomplished by means of large monitor jets augmented by slurry pumps and pipes. An extension of this technique has led to the underground extraction of coal and ores. To date, the method has been most successfully used in undergrond coal mining, because the coal can be easily cut and flushed away by water jets, and the rocks of the roof strata can be left behind. Due to this favourable situation, the hydraulic mining definition only relates to the underground coal mines.At present, there are four basic types of hydraulic mining, which can be defined according to the coal breaking technique used in each case. The methods are briefly discussed below:(1) Coal excavation may be carried out by conventional techniques, but the mine is designed and equipped for the hydraulic transport of the mineral from the working place to surface. Under these circumstances, the coal breaking may not be influenced by the water jet, however it may be indirectly involved. For example, pre-loosening of the coal may be done by water infusion-hydraulic fracturing. Water may also be used to flush the broken coal, which has been excavated either by drilling and blasting or by mechanical cutting, into the transport flumes. In other cases, a mechanical loader may load the coal directly into the hydraulic transport system, without using any water for the extraction process. This hydraulic mining concept is primarily used for hard and impermeable coal, such as anthracite."

Jan 1, 1980

By K. Reinharter, J. Schmidl, D. Gregurek, A. Spanring

Copper smelting furnaces are typically lined with magnesia-chromite refractories, which are exposed to multiple and complex stresses. The selection of the processing route, furnace type and slag system will be dictated by the specific ore type available, this will determine the individual refractory wear. This paper evaluates the common refractory wear mechanisms as observed in the copper Peirce-Smith converter and in the copper anode furnace. The chemical factors include corrosion caused by fayalite type slag and sulfur supply, as well as, by Cu-oxide attack. Changes in the temperature during the furnace operation (thermal-shock) create stresses in the brick lining which can only be absorbed in limited extent. Mechanical factors include erosion, caused primarily by the movement of the metal bath, slag and charging material, as well as, stresses in the brickwork due to punching. Finally improper lining procedures can also effect the service life. All these wear parameters lead to severe degeneration of the brick microstructure and a decreased lining life. Therefore, a detailed investigation and understanding of the wear mechanisms through “post mortem studies” together with thermochemical calculations by FactSageTM software is an important prerequisite for the refractory producer. Based on these research results, combined with specific process knowledge, appropriate brick lining solutions for copper processing furnaces can be recommended. INTRODUCTION The refining of copper includes converting of matte or black copper into blister copper for final fire refining process in the anode section. Typically Peirce-Smith (PS) converters are in use. Other technologies include Hoboken Converter, TBRC but also Flash Converting Furnace and bath smelting furnaces (ISA, Ausmelt) (Davenport et al., 2002). For fire refining two types of furnaces are used – the rotary furnace type is dominantly used in the primary production route while secondary smelters tend to use hearth refining furnaces which are more suitable for scrap melting. Installed working linings are based on magnesia-chromite bricks but especially in the anode refining section the application of alumina-chromia bricks have become more popular in the recent years. It comes without saying that, to some extent, large variations in the slag composition can be observed from the data provided to RHI Magnesita during post-mortem studies of used refractory samples and this needs to be addressed properly during the selection process of refractory linings.77

Jan 1, 2019

By I. Stefanou, J. Sulem

"In the last thirty years, the study of earthquake mechanisms has emphasized the major role of rock friction. Earthquakes appear to be the result of a frictional instability and occur by sudden slippage along a pre-existing fault or a plate interface. Multiphysics couplings play a major role in earthquake nucleation and seismic slip. The effect of shear heating and thermal pressurization may be of prime importance in the control of the stability of shear deformation inside the slipping zone. Other mechanisms in relation with thermal decomposition of minerals affect the pore pressure and the temperature evolution of the system, and can play a significant role in the extreme strain localization observed in field. The actual width of the localized zone is a key parameter for understanding fault weakening mechanisms. On the basis of field observations, laboratory experiments and recent advanced modeling, these phenomena are analyzed and discussed in order to bring some new insights in the understanding of earthquakes nucleation.INTRODUCTIONIn the last thirty years, the study of earthquake mechanisms has emphasized the major role of rock friction. Earthquakes appear to be the result of a frictional instability and occur by sudden slippage along a pre-existing fault or a plate interface (Scholz, 1998; Sykes, 1978). The conceptual model of spring slider system is commonly used to represent the interaction between an elastic crustal block and a fault zone. Stick-slip instability is possible if the softening rate of the shear resistance of the fault zone is high enough as compared to the stiffness of the crustal block. Therefore, weakening mechanisms that can explain how the frictional resistance of a fault decreases with slip and/or slip rate is of prime importance to understand how an earthquake nucleates. In recent years, several drilling programs in active faults (e.g. the Nojima fault in Japan, Boullier, 2011; the Aigion Fault in Greece, Cornet et al. 2004, the Chelungpu fault in Taiwan, Ma et al. 2006, and the San Andreas fault in the U.S.A. Ellsworth et al. 2000) as well as high velocity friction experiments (e.g. Tanikawa et al 2012a; Tanikawa et al. 2012b) have highlighted the physico-chemical processes involved in the nucleation of seismic slip (see for the example the review paper of Niemeijer et al. 2012)."

Jan 1, 2015

By L. Beiza, L. Velásquez-Yévenes

Chalcopyrite is by far the most abundant copper sulphide on Earth, but it has proved to be problematic in its processing by leaching, mainly related to its refractory nature, slow kinetic rates of dissolution and the formation of an inhibiting product layer on its surface during leaching. This study is focussed on the electrochemistry of chalcopyrite dissolution in acidic chloride system, which has recently gained attention as a feasible alternative to conventional sulphate media for chalcopyrite leaching. It is well understood that chalcopyrite dissolution from mineral grains depends strongly on the solution redox potential at the mineral surface as well as the composition of the product layer that may form on its surface. The chloride ions in solution support the Cu(II)/Cu(I) couple as the primary oxidant, as they can form complexes with the cuprous ions formed, increasing the dissolution rate. Additionally, these ions increase the potential range where chalcopyrite can be oxidized. The chemical reaction that occurs on the surface of chalcopyrite in chloride solutions in the presence of cupric ions will be characterized and the coulometry of the reaction will be reported to understand what is happening on the surface of chalcopyrite. Electrochemical experiments have been carried out to investigate the behaviour of mixed potential by open circuit potential (OCP) measurement for 30 minutes using sulphuric acid at pH 1 under nitrogen at 25⁰ C. The effect of chloride was analysed at 0, 20, 50 and 100 g/L and cupric ions from 0 to 50 g/L. The potentials obtained were then used to carry out chronoamperometry tests for a period of 30 minutes in absence of cupric ions. The mixed potential did not show a significant difference with an increase in cupric concentrations in the absence of chloride. Increased mixed potentials and current densities were observed at higher chloride and cupric concentrations. Chronoamperometry tests at those potentials were used to construct a voltammogram trace which has the same trend as a normal cyclic voltammogram but with much lower current densities. INTRODUCTION As a result of the depletion of copper oxides, the leaching of copper sulphide minerals has become the focus of many studies. Chalcopyrite, (CuFeS2) which is the most abundant of copper minerals, has proved to be challenging to process via hydrometallurgy, mainly related to its refractory nature, slow kinetic rates of dissolution and the formation of an inhibiting product layer on its surface, during leaching.

Jan 1, 2019

By Behzad Vaziri Hassas, Firat Karakas, Esra Tanisali, Mehmet S. Çelik, Ahmad Hassanzadeh

Coagulation is basically an aggregation process where particles settle under the influence of interfacial forces with electrostatic forces playing a governing role. Although particle morphology consisting of shape and roughness dictates the physical encounter of two particles, their eventual coagulation is not only influenced by columbic forces but also other interfacial forces such as hydrophobic interaction, which affects the extent of aggregation of particles through increasing the distance of interaction. Roughness is well known to increase the effective contact angle on hydrophobic surfaces and also enhance interfacial forces. In this study, the effect of morphology of particles and particularly roughness on the settling velocity and in turn coagulation tendency was investigated. Batch settling tests (BSTs) of different particle morphologies were investigated as a function of pH. Two different morphologies of silica particles were utilized with the same particle size distribution (PSD) including smooth-spherical and rough-spherical (Etched). Rough particles were prepared by acid etching technique using hydrofluoric (HF) at different time intervals (15-300 sec). Etched samples were identified and quantified by optic profilometry. Settling test results showed that the settling velocity of particles in a suspension of 2% solids in the massive settling region is significantly affected by particle morphology of the suspension. Coagulation results further revealed that aggregation of rough particles is faster than smooth-spherical particles. Coagulation results are elucidated on the basis of particle morphology and its effect on distance of separation through hydrophobic forces.

Jan 1, 2016

By F. Urekar, R. B. Pankhurst

"Air spaces and air gaps in an explosives column are known to allow greater distribution and cushioning of explosive energy from the rock mass. This energy distribution is enhanced if the explosives ' gases can be confined in the borehole for as long as possible by plugging and stemming above the air space.Power Plug is an inflatable plug which can seal a borehole at any point to separate the stemming from an air gap and explosive toe load.IntroductionThis paper will discussion-going work by C-I -L Inc. and operators of two open pit mines to study the results of using Power Plugs:I. Pit wall stability - the authors have found the Power Plug effective for wall control blasting in open pit mines.2. Selective mining of coal seams - the authors work shows the Power Plug allows mining selective coal seams by predrilling underseam waste wedges.Pit Wall StabilityWall stability in an open pit mine is essential for safety. Good wall stability can be achieved with wall control blasting techniques which cushion the effect s of the explosives charge by decoupling the charges from the borehole wall. The usual method of decoupling a charge in a large-diameter rotary borehole is to load the explosives in tubes (Fig .I) . We now believe the air deck system is effective in sea ling a borehole above the explosive charge to create an air deck within the borehole which will cushion the blast.In a linear decoupled charge, an air annulus surrounds the explosives charge and cushions the effects of detonation genera ted gases on the pit wall. In an air deck, i.e. with the hole plugged at the collar, the gases genera ted by an explosive toe load are sealed in the empty borehole column. After a period of time, these trapped gases produce radial cracking between holes along the entire length of the borehole.It is common practice to employ de coupled explosive charge columns in the borehole to limit blast damage to surrounding rock. The exact mechanism of energy transfer in such blasts, however, is not well understood. Interruption of the continuous explosive column in a borehole by means of stemming, or air decks, may also be viewed as another form of decoupled blast. Decoupling of the explosive charge from the borehole wall affects both explosive energy release and explosion pressure developed in the borehole."

Jan 1, 1988

By Roger St. C. Smart, Paul Weber, Joan E. Thomas, William M. Skinner, Warwick Stewart, Stuart Miller

For mine sites affected by acid rock drainage (ARD) or with a potential future ARD issue, the prime consideration is not only the classification of different waste rock as potentially acid forming or non acid forming but also the peak acid (and metal) release rates and expected ARD duration during which effective ARD management and acid neutralisation capacity (ANC) are required. Methods for assessment of this ANC (e.g., Sobek tests) are already available but can be unreliable in ARD containing significant proportions of framboidal pyrite or iron carbonates. The measurement of negative ANC values and the release of S to solution showed that significant sulfide oxidation may occur prior to and during testing in samples containing reactive (particularly framboidal) pyrite resulting in serious underestimation of the original ANC. A simple methodology with dissolution in Ar-purged water before ANC testing, removing ferrous salts, and sulfate assay after ANC testing corrects these effects. Results also showed that a significant lag period (up to 432 h) may be needed for complete hydrolysis of Fe associated with the standard Sobek ANC testing of, for instance, siderite. Hence, the ANC of iron carbonates is usually significantly overestimated. By filtering and the addition of H202 until there was no subsequent pH drop (due to Fe hydrolysis reactions), followed by back titration to pH 7.0, the ANC for siderite was similar to the ANC determined after 432 h lag by the Modified Sobek ANC test and to the mineralogical carbonate ANCcarb determined by calculation based on electron probe micro-analysis. A chemical ANC calculation, based on neutralising cations released to solution, has provided a method to quantify the short-term ANC of carbonates and silicates in simple mixed mineral assemblages and waste rock samples. Results showed that silicate ANC can be more important in short-term neutralisation than carbonate ANC in low carbonate samples. In the longer-term, decreasing sulfate and metal loads with increasing pH values suggests that eventually sulfide acidity generation rates will match the longer-term inherent acid neutralisation rates of the sample derived from silicates. A kinetic ANC measurement for silicates, after steady state dissolution is reached, that indicates the number of hydrogen ions neutralised/m2/yr has been developed. These values can be used in estimates of the net acid production profile from wastes with low (and decreasing) pyrite content after the short-term ANC is exhausted.

Jan 1, 2004

By H. C. L. Reemeyer

One of the fundamental trade-offs for copper concentrators is between grinding circuit product size and copper recovery. The capital and operating cost savings and throughput increases for a coarser grind should be evaluated against potential recovery reductions. Other benefits of coarser grinds, such as GHG emissions reductions and favourable effects on tailings and water management should also be considered. This paper assesses the formation of laboratory and pilot test programs, design of process flowsheets, equipment selection, and evaluation methods to determine the most appropriate and economical grind size for a given deposit. The paper will include an evaluation of case studies. INTRODUCTION The majority of the world’s mined copper comes from sulphide deposits, which are mostly processed using crushing, grinding, flotation and dewatering flowsheets to produce copper-bearing concentrates for smelting. Ores must be ground to a sufficiently fine size to achieve an acceptable level of liberation to allow both high recovery of copper and valuable by-product minerals while efficiently rejecting gangue to tailings. Therefore, a key design parameter in process plant design is the grind size of the flotation feed. Copper concentrators use a variety of grind size targets that depend on various factors, including ore mineralogy and the grain sizes of valuable and gangue minerals; the sensitivity of valuable mineral recoveries in the rougher flotation stages to grind size, ore hardness; electricity costs; and mining vs. processing throughput constraints. Typically, copper and by-product recovery increase as grind size is reduced, which can improve revenue, but finer grinds increase power and grinding media operating costs and may have implications for tailings management. This paper explores the trade-offs that should be assessed in determining the optimum grind size, and to answer the question if coarser grinds are worthwhile. METALLURGICAL AND FLOWSHEET FACTORS Recovery-by-size behaviour of sulphide-bearing particles In base metals sulphide flotation, it is typical that flotation recoveries vary by particle size. Metal sulphide particles rendered hydrophobic by collector in intermediate size ranges (e.g. 10 to 100 um) usually show very high recoveries, often approaching 100%. Recovery usually falls away in finer size fractions (<10 um) as fine particles have little inertia and can move around bubbles without colliding and attaching to them. Coarser particles (>100 um) are susceptible to particle-bubble detachment and dropback (Jameson, 2019).

Jan 1, 2019

By Claude Gosselin

En 1995, la Compagnie minière Québec Cartier a mis de l&apos;avant un projet de recherche sur la modélisation de l&apos;écoulement des gaz pour ses fours de frittage à l&apos;usine de bouletage de Port-Cartier. Cette démarche s&apos;inscrivait dans un large processus de collaboration avec l&apos;Université Laval et le Consortium de Recherche Minérale (COREM). L&apos;usine de bouletage possède deux fours de frittage d&apos;une capacité moyenne de 600 tonnes/heure pour chacun des fours. Les fours de frittage sont des systèmes complexes d&apos;échange de chaleur qui fonctionnent à contre-courant (le débit de boulettes versus les débits de gaz). Pour rencontrer les spécifications reliées aux propriétés mécaniques des boulettes, le processus de fabrication requiert des mesures et un contrôle des systèmes très précis. L&apos;information fournie par plus de 70 capteurs (pression, température, puissance, vitesse, hauteur de lit, position de volet....) est utilisée pour manipuler une vitesse de grille, cinq ventilateurs et neuf zones de brûleurs. Malheureusement, les variables qui influencent fortement les mécanismes de frittage, c&apos;est-à-dire les débits de gaz dans les différentes zones du four ainsi que la masse de boulettes qui circulent ne sont pas mesurées. Une méthode est donc proposée pour une estimation en ligne de ces variables. La méthode est basée sur un arrangement de 65 équations reliant pressions, températures et débits de gaz dans les conduites, les ventilateurs, les sections du lit et les fuites (Gosselin, 1998). Pour des raisons de simplification de cet article, seul un sous-système du four sera présenté. Les techniques de réconciliation des données reliées à la conservation de la matière et de l&apos;énergie montrent que la mesure en ligne du débit de boulettes mène à l&apos;estimation des débits de gaz et apporte des avantages intéressants pour le contrôle des variables stratégiques des fours.

May 1, 2001

By M. P. Du Plessis

"The paper discusses coal research in relation to the special needs of Western Canada, with its large resources of lignite and subbituminous coals. Research programs are presented under the following headings: Coal Liquefaction, Pyrolysis, Fluidized-Bed Technology, Underground Coal Gasification and Supporting Investigations. Typical processes are presented and their relevance to Canadian coals is described. The longterm plan of the Alberta Research Council for coal research and the steps taken for its implementation are discussed. Finally, some innovative concepts arising from basic research in coal chemistry are discussed.Canada&apos;s Coal ResourcesCanada is richly endowed with coal reserves. With estimated ultimate reserves of 600 billion tons in O.76-m (2.5-ft) thick seams under less than 762 m (2500 ft) of overburden, Canada rank s fourth after the USSR, the USA and Chinatu (see Table I) . Canada&apos;s reserves are incompletely explored and estimates are constantly being upgraded. Preliminary information from deeper test-hole logs suggest that similar , if not larger, tonnages occur at depths greater than 762 m (2500 ft).The types of Canadian coals and their regional Distribution(2) is shown in Figure 2. Alberta&apos;s subbituminous Plains coal represents about 70% of estimated national reserves. A large portion of the coal can be mined at relatively low cost by surface mining techniques, and it is currently being used exclusively for power generation in conventional thermal plants. This coal, however , also represents a large potential .source of liquid fuels which could equal or exceed that of oilsands and heavy oil. Table 3 compares Federal Government estimates for resources and reserves of fossil fuels in Canada and their recoverable oil content or equivalent.A conservation estimate of only the reserves of thermal coal represents an oil equivalent of 27.6 billion barrels , which equals the recoverable reserves of oil-sand bitumen and heavy oil. A more realistic estimate is probably several times this amount. Although coal can be converted to many other end products, such as fuel gas and synthesis gas for hydrogen and ammonia production, liquid fuels remain the most desirable product mainly because they can be transported more cheaply over long distances and their high energy density makes them uniquely suitable as fuels for transport and agriculture."

Jan 1, 1981

By R. E. Whitehead

"Abstract - Biotite from aplite that appears to have crystallized simultaneously with disseminated Cu-Mo mineralization at MacLeod Lake in northern Quebec yields K-Ar dates in the range 2032 ± 44 Ma to 2097 ± 47 Ma. The mean value, 2065 Ma, is some 400 Ma younger than the 2485 ± 64 Ma date obtained from a hornblende concentrate separated from a granodiorite sill that is spatially, but apparently not genetically, associated with the disseminated Cu-Mo deposit. The mean biotite date of 2065 Ma at MacLeod Lake, a K-Ar date of 2055 Ma reported from an area 50 km east of MacLeod Lake and published dates of about 2000 Ma for galenas from the Chibougamau Cu-Au ores, suggest a widespread thermal and mineralization event, in that part of the Superior Province east of James Bay, that differs from the common late Archean mineralization that is related to volcanism and metamorphic-intrusive activity.Sommaire - Les datations au K-Ar sur des biotites qui auraient cristallise en même temps que la minéralisation disséminée en Cu et Mo dans une aplite mise en place au Lac MacLeod, au nord du Québec, s&apos;échelonnent entre 2032 ± 44 Ma et 2097 ± 47 Ma. La datation moyenne, soit 2065 Ma, est d&apos;environ 400 Ma plus récente que la datation obtenue pour un concentre de hornblende extrait d&apos;un filon-couche de granodiorite qui est spatialement mais ne serait pas génétiquement associée à la minéralisation disséminée en Cu et Mo. La datation moyenne de la minéralisation au Lac MacLeod, soit 2065 Ma, la dataion au K-Ar à 2055 Ma citée pour une région à 50 km à l&apos;est du Lac MacLeod, de même que les datations d&apos;environ 2000 Ma établies pour des galènes qui se trouvent dans le minerai aurifère et cuprifère à Chibougamau, suggèrent un phénomène thermique répandu qui aurait produit la minéralisation dans cette région à l&apos;est de la Baie James, dans la province du lac Supérieur. Ce phénomène serait diffèrent de celui qui aurait produit la minéralisation répandue d’âge archéen tardif qui elle serait associée à l’activité volcanique et à l‘activité intrusive accompagnée de métamorphisme."

Jan 1, 1992

By T. Yameogo

Many ideas, tools, technologies, and methodologies are believed to have staked their claims on the future of mining. For example, automation is strongly positioned as the platform within which mining will be practiced. A subset of automation ? intelligent mining ? will add some smart interactions between machines, technologies, the rock, and the environment. The future also calls for an improved approach to sustainability and corporate social responsibility. Mines of the future are dreamed of to be more ethical and more balanced. They will boast optimized designs, integrated value and supply chains, produce less waste, recycle and reuse, and will require less energy to operate. Then, what about the people that will operate this optimized ecosystem? How is the education system teaching the operators of the mines of the future? What kind of a future should mining education foresee to prepare the workers appropriately? In recent years, the shortage of skilled labor for mines around the world has created a tough competition to attract, retain, and train the very people without whom mining will cease to exist. In Australia, Canada, and the United States in particular, the war for talent has resulted in higher-than-usual labour costs. Such costs have dented the unit costs of many mining businesses. Concomitantly, mining contractors? and consultants? prices have increased to reflect the escalation of labour costs across the value chain. From labourers to engineers, from juniors to seasoned professionals, the increase in compensation is unprecedented. Yet, the shortage is still hurting the industry, and the high calibre candidates continue to be rare gems. The industry has been implementing aggressive solutions that include the increased hiring of skilled immigrants, the training and recruitment of minorities, and the retaining of near-retirement experienced employees. Public relation campaigns about the benefits of embracing careers in mining are also common. The CIM has also devoted a ?M4S? section to its pan-Canada meetings to educate the public, especially the youth, about the importance of the mining industry for Canada. Moreover, mining associations and universities are enticing students? enrolment through scholarships and financial support. Still, the balance between quantity and quality of workers can be discussed. This paper intends to discuss the present state of mining education as an essential part of the future of mining. The authors brush the picture of the education of miners, technicians, and engineers, against the backdrop of the technology-advanced mines of the future.

Aug 1, 2013

By R. Alarcón Sch., R. Abel F.

For many years, copper cathode quality has been a priority for end consumers, since it affects the variety of products that can be obtained from them. From the beginning, physical and chemical quality of the wire bars was controlled, as this product was used to obtain wire rod and other forms of copper by wire drawing. At that time, all the electro refined cathodes were melted and casted as wire bars. Subsequently, in the 80’s, with the introduction of continuous casting furnaces, it was possible to directly produce wire rod from cathodes. From then on, cathodes quality standards were consistently increased, by the introduction of uniform criteria, among which we can identify ASTM and British Standards as well. Also, producers began to use more demanding internal standards than the existing specifications, in order to differentiate their cathodes as high quality products among customers. Today the physical aspect of cathodes, including nodules, cracks, sulfates, or others, is the first element used by end customers to assess their quality. This paper aims to show a brief vision of the evolution of quality specifications for products used to manufacture copper wire. INTRODUCTION From the beginning of refined copper production for industrial purposes, mandatory minimum quality conditions were established. These quality conditions were used as the main element to determine prices and discounts of the respective sales contracts. Reviewing the copper development history, we can appreciate that its quality requirements had been constantly evolved, so that currently refined copper has an extremely high quality standard, that allows its direct use in the production of ultra-thin cables and other products applied in the industry. In each stage, refined copper production has fostered the development of technology used in their treatment. Similarly, cathode processing technology has been evolving to minimize treatment costs in order to generate a wire rod for several uses, ranging from power cables to super conductors. In this sense, to the already known type of fusion processes of the Southwire or Asarco type (capacities over 80 kt / year), wire rod production processes of the Upcast or Rautomead type (capacities between 20-50k t / year) have been added. They immediately deliver oxygen-free wire rods. In both cases, we can conclude that the clients' requirement had evolved from a chemical criteria focus, to considering more subjective aspects, such as visual control as the first stage of inspection.

Jan 1, 2019

By A. Mykytiuk, I. E. Puddington, W. D. Macleod, F. W. Meadus

"A laboratory-scale continuous procedure for the up-grading of naturally occurring tin ores, based on the principle of spherical agglomeration, is described. High recoveries are indicated. A proposed second stage suggests useful fractionation steps.IntroductionA LABORATORY-SCALE batch process for the upgrading of a tin ore using the principles of spherical agglomeration has already been described (1). This procedure consisted of milling, for about an hour, a precrushed ore with at least 200 per cent water, 0.2 per cent of a reagent such as tall oil (to render the de-sired ore particles hydrophobic) and about 3 per cent of a viscous petroleum oil. The feed material passed an 8-mesh Tyler sieve, and the percentages of re-agents are based on the dry weight of the feed. Du-ring the grinding, the hydrophobic particles transfer into the oil phase to produce coherent semi-solid bodies while the gangue stays preferentially in the aqueous phase. The concentrate can be separated from the gangue easily by a mechanical operation. Using an ore containing about 0.3 -0.5 per cent tin, grades of from 1.5 to 7.0 per cent were obtained by varying the pH of the system. Recoveries fell from about 80 per cent to as low as 50 per cent as the grade in-creased."

Jan 1, 1966

By N. Morrison, E. J. Rogans, A. J. Macintosh, N. Schoeman

"The design of carbon-in-pulp (CIP), and carbon-in-leach (CIL) adsorption circuits has essentially remained unchanged since the early days of the carbon process for gold recovery. For CIP circuit the pulp residence time is traditionally fixed at one hour per contactor with a carbon concentration of between 15 and 20 grams per litre, and the counter current carbon transfer rates are in the region of 15% pulp recycle. For CIL, the pulp residence time is usually three hours per contact or, with lower carbon concentrations ( 5 to 10 grams per litre).The drawbacks of using the counter current CIP/CIL adsorption circuits are discussed using modeling developed for CIP/CIL plant design. Counter current CIP/CIL, circuits are then compared with the carousel method of adsorption circuit design.The use of equipment suitable for the carousel approach is discussed which is, the AAC cylindrical and pumping (MPS) screens, the AAC pump-cell plant and launder designs.Finally, two plants at the Vaal Reefs Gold Mining and Exploration Company that use carousel adsorption circuits, namely the Vaal Reefs No. 1 Gold Plant, a CIL plant with stepped contactors, and the Vaal Reefs No. 2 Gold Plant, a CIP using a very short residence time (AAC pump-cell) are discussed."

Jan 1, 1998

By M. Carvalho

The primary motivation underlying the proposal of polygeneration systems for mine sites is to increase the efficient use of natural resources by combining different technologies and energy resources while satisfying energy service demands. For many mineral producers, particularly in Canada?s mining extremes of climate and depth, energy in support of mineral production can be the second largest cost centre after labour. A generic methodology is proposed for the design of energy supply systems in mine sites, based on a search for the minimum discounted cost of energy supplied for all feasible different plant configurations. These configurations can be represented within a connectivity matrix which corresponds to a network representation. A Mixed Integer Programming formulation is set out for the multiperiod synthesis and operational planning problem. This is characterized by i) binary variables for the selection of technologies, ii) integer variables for the determination of the number of units installed, and iii) by continuous variables for the representation of energy and economic flows. Through the integration of particular energy supply strategies matching specific mine circumstances (on-grid, remote, degree days, etc) and consideration of technologies that improve energy efficiency, hitherto not considered new technologies and demand management systems or new perspectives on optimal mine site energy supply can be investigated. Some of these investigations identify the economic conditions through which biomass energy feedstocks should be used, for direct heat production, for gasification and providing for Fischer-Tropsch syndiesel manufacture. As well as integrating demand from mobile diesel-fuelled plant into an optimization procedure that hitherto has only been considered for static energy production and consumption plant, this analysis shows how the techniques can be used to explore economic conditions of threshold prices for biomass (purpose-grown biomass and peat are considered herein) and trucked-in diesel. The methodology also allows for electricity and syngas storage and diesel and biomass bunkering. Within the paper the energy demands for a remote, open pit mining operation located in Northern Ontario are considered as a case study to illustrate the technique and investigations. As expected, for mines close to electricity, natural gas, and diesel distribution infrastructures, the optimal choice is to connect. When a constraint is applied specifying that connection is not possible, as would be for the case exemplified, the optimal choice includes some of the more exotic options for mine site energy supply.

Aug 1, 2013

By M. R. P. Snow

"This paper outlines geotechnical conditions that commonly exist in underground, hardrock mines and the challenges posed for ground-support steel, specifically rockbolts, used in these environments. A model is proposed whereby the in-situ stress and rock-mass classifications (based on Bieniawski’s rock mass rating) form the basis of determining the desired steel properties of the rockbolts used. Based on the ASTM F432 bolting specification, recommended minimum steel properties are defined for three ranges of in-situ stress levels, each with their own six ranges of RMR values. Heat treatment for the steel can be specified once these minimum steel properties are known.RÉSUMÉ Le présent article décrit les conditions géotechniques qui existent fréquemment dans les mines souterraines de roches dures et les défis que cela pose pour le soutien de terrain en acier, plus spécifiquement les boulons d’ancrage utilisés dans ces environnements. Un modèle est proposé dans lequel les contraintes in situ et les classifications de la masse rocheuse (selon la classification de la masse rocheuse de Bieniawski) servent de base pour la détermination des propriétés désirées pour l’acier des boulons d’ancrage utilisés. En se basant sur les spécifications de boulonnage de l’ASTM F432, les propriétés minimales recommandées pour l’acier sont définies pour trois plages de niveaux de contraintes in situ, chacune avec sa propre plage de six valeurs de classification de la masse rocheuse (RMR). Un traitement thermique pour l’acier peut être spécifié une fois que ces propriétés minimales pour l’acier sont connues."

Jan 1, 2016

By P. J. Oakley, W. M. Thomas, S. W. Kallee, D. G. Staines

A Friction stir welding (FSW) is now extensively used in aluminium industries for joining and material processing applications. The (FSW) technology has gained increasing interest and importance since its invention at TWI almost 15 years ago. The basic principle, recent applications and the continuing development of the FSW technology are described. The paper will introduce some of the variants of FSW, such as Dual-rotation, Twin-stir(TM), and the Stir-lock(TM) technique.

Jan 1, 2006

By Lin Li, Ahmad Ghahremaninezhad

"In this paper, the electrochemical behavior of ferric and ferrous couple on the pyrite surface was studied by application of the chronoamperometry technique in an acidic solution at room temperatures and atmospheric pressure. The effects of the pyrite origin, ferric and ferrous ions concentration on the electron transfer kinetics of Fe3+/Fe2+ reaction were probed. Tafel behavior of all the test conditions were developed. The results showed that the ferric-ferrous reaction on pyrite electrodes with different origins have a common mechanism, despite different reaction kinetics. The exchange current densities of the redox reaction have the same magnitude of about 10-5 A·cm-2, which is far lower than the value reported for the gold and platinum electrodes, but larger than that of the chalcopyrite electrode. The cathodic transfer coefficients are between 0.4 and 0.5, while the anodic transfer coefficients appear unusual with the lowest value being 0.23. It was also demonstrated that an increase of one order of magnitude of iron concentration has no clear effect on the exchange current density and cathodic transfer coefficients of Fe3+/Fe2+ redox reaction.INTRODUCTIONPyrite, FeS2, is mostly considered as a gangue mineral which frequently coexists with valuable minerals and metals, such as gold, copper and nickel. Its separation from valuable minerals can be a costly process (Chandra & Gerson, 2010). In refractory gold ores, the fine gold particles are locked inside the pyrite structure. Oxidative leaching of pyrite is a hydrometallurgical method to destroy the structure of pyrite and expose the fine gold particles to the cyanide solution in the downstream cyanidation circuit. Pyrite oxidative leaching can be achieved by oxidation of pyrite via oxygen and ferric ion(McKibben & Barnes, 1986). In fact, pyrite oxidation by oxygen and ferric is a significant source of acid mine drainage(AMD), which adversely causes serious environmental problems(V. P. Evangelou, 1995).The pyrite oxidation mechanism is accomplished in three consecutive steps: (i) pyrite is oxidized by oxygen and ferrous ion formation (Eq. 1); (ii) ferrous oxidation by oxygen and ferric ion formation (Eq. 2); (iii) pyrite oxidation by means of ferric ions (Eq. 3). Hence, both oxygen and ferric participate in the pyrite oxidation process (Moses & Herman, 1991):"

Jan 1, 2016