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By M. A. Golozar

Partially stabilized zirconia (PSZ) has been proven to be an excellent candidate as a thermal barrier coating (TBC) for hot sections in, for instance, heat or internal engines and gas turbine parts. The main functions of these coatings are reduction of heat losses, reduction of fuel consumption, increasing efficiency, and extending durability and life. One of the main problems involved is wear behavior in the development of such coatings for these applications. Using air plasma spraying (APS) technique, conventional and nanostructured 8 wt % yttria partially stabilized zirconia (Y-PSZ) coatings were deposited on austenitic stainless steel (AISI 304) disc-shaped substrates. The coated substrates were subjected to pin-on-disc wear tests, using 10 mm silicon nitride and zirconia balls as the pin. The coefficient of friction was recorded in real time. The weight loss of coated substrates was measured. Coatings were characterized before and after being subjected to wear testing by various techniques including optical microscopy, scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDX) and X-ray diffraction (XRD). Effects of various experimental parameters such as wear distance, test temperature, and counterface material were also investigated. Results obtained revealed that, regardless of experimental conditions applied, the nanostructured zirconia coating shows better wear and tribological properties than those of the conventional one.

Jan 1, 2005

By J. Brent Hiskey

At present, approximately 80 % of the worlds mine production of copper is achieved by smelting and electrorefining. The principle aim of copper electrorefining is to satisfy the large demand for extremely pure copper. It is remarkable that high quality copper cathodes with the required purity (99.99+% Cu, ASTM B115-10) and structural characteristics (i.e. deposit density and morphological texture) are produced from impure copper anodes dissolved in electrolytes containing a variety of impurities. This is accomplished with the proper control of operating parameters such as: current density; temperature; copper and sulfuric acid concentration; agitation; substrate preparation; and the application of electrolyte additives. The basic elements of the electrolysis of copper have not changed significantly over the past 150 years since the early developments of James Elkington. Importantly, our fundamental understanding of the underlying electrochemistry has advanced considerably. This is especially true regarding our knowledge of the mechanistic role of additives during the electrocrystallization of copper. This is a very complex subject and modern electrochemical techniques and the development of surface characterization and imaging instruments has helped immensely in our ultimate understanding of how additives control the deposit structure and morphology. The purpose of this paper is to review the historical development and application of electrolyte additives in copper electrorefining and to examine our current knowledge regarding their use. INTRODUCTION The first transatlantic telegraph cable was completed in August 1858. Regrettably, this cable failed shortly after the initial connections. After several more failed attempts, improvements in materials and copper quality resulted in successful communication between Europe and America on July 28, 1866. In many ways this hallmark event demonstrated the need for high purity copper. The first copper refinery in the world was commissioned in May 1869 in Pembrey, South Wales by partners Josiah Mason and James Balleney Elkington. (Historical Note). The 1865 and 1868 British patents issued to James Balleney Elkington were the foundation for the first commercial production of high purity electrolytic copper (Elkington, 1865, 1869, 1870). This important achievement was made possible primarily by the invention of the dynamo which was based on the fundamental operating principles advanced by Michael Faraday. A symbiotic relationship between copper refining and the dynamo was henceforth established. The dynamo provided electric current for electrolytic refining of copper and the electrorefining tankhouse provided pure copper which was required for the generation and transmission of electricity.

Jan 1, 2019

By A. Valenzuel

Arsenic is a common impurity in copper sulfide concentrates treated pyrometallurgically, which inevitably during the smelting-converting process reports in the final copper product affecting its properties, but also it is a very toxic occupational hazard. Arsenic recovery or disposal from concentrates or arsenic-containing copper smelter dusts have been practiced in the metallurgical industry for many years. It has been recovered principally as arsenic trioxide by roasting or leaching then precipitated. On the other hand, several hydrometallurgical processes have been developed and implemented in smelters to remove it from arsenicbearing dusts and stabilize it prior to disposal in the form of a solid compound, either as calcium arsenate, arsenic sulfide or ferric arsenate. This paper reviews the methods implemented for arsenic recovery worldwide and arsenic disposal in the metallurgical industry.

May 1, 2001

By G. C. Bateman

THE cause of silicosis and its prevention have held the attention of medical men and mine operators for many years and at the present rime the study of this disease is more than ever to the fore, even though a considerable abatement in the incidence of silicosis has been noted of late. This abatement is due to individual and collective efforts. The Industry is keenly alive to the situation and much research is being carried on. Silica dust is assumed to be a contributing factor in the cause of silicosis. How it acts progressively in the early silicoric is nor fully understood. As the study advances, more effective measures of control may be evolved. At present the Industry has three known methods of reducing the incidence: 1. By thorough X-ray examination of all applicants, with special reference to chest conditions. Those who are considered to be susceptible to the disease are prevented from entering the industry. 2. Thorough ventilation of the mine. 3. Control of tuberculosis in mining centres and removal of miners when first symptoms of tuberculosis become apparent. In 1934, the Ontario Mining Association formed a Committee, known as the Technical Silicosis Research Committee, to study and supervise work on problems related to silicosis. This Committee obtained the full-rime services of a mining engineer to carry our research work at the mines in the Province of Ontario. The Ontario Mining Association has also provided funds for the purpose of carrying on research work along pathological and biological lines. This work is being done in the Department of Medical Research of the University of Toronto, in the Banting Institute, under the supervision of Sir Frederick Banting. The Silicosis Committee work in full cooperation with the doctors in the Banting Institute and provide material from the mines for the it use.

Jan 1, 1936

By Thomas H. Heine

"The Rabbit Lake uranium deposit is located at 58° 11’00”N.. 103°42'36""W., close to the west side of Wollaston Lake, and approximately 800 km north of Saskatoon. The orebody is hosted by Aphebian Wollaston Group rocks, initially deposited as a series of shallow-water marine sediments consisting, in part, of carbonates and possible saliferous petites. Metamorphism during the Hudsonian Orogeny, peaking at about 1850 Ma, recrystallized the sediments to upper amphibolite grade paragneisses. This was accompanied by partial anatexis. The waning stages of Hudsonian orogenesis appear to be marked by minor granitic intrusive activity.The post-Hudsonian period was marked by a long interval of physical and chemical erosion, resulting in the unroofing of the Wollaston metamorphic complex. The entire region underwent extensive lateritic weathering under tropical to subtropical conditions. Carbonates were especially vulnerable and, in the Rabbit Lake area, suffered extensive solutioning with accompanying formation of collapse breccias. Old zones of weakness also underwent periodic reactivation.It was during this period that uranium was leached from the surrounding meta-sediments by oxidizing meteoric waters, and transported into the karsted and fractured rocks of the Rabbit Lake doline.Athabasca Group sediments eventually covered the deposit, their diagenesis taking place at about 200 °C and 900 bars. This allowed the partial to complete recrystallization of the initial mineralization, resulting in a minimum age of 1281 ± 11 Major ""first""-generation pitchblende. Periodic fault/fracture reactivation modified the hydrologic regime within the deposit, resulting in episodic mobilization and recrystallization of pitchblende and other uraniferous species. This is clearly shown in the open pit at the present time: uranium is being mobilized and recrystallized on damp pit walls as bayleyite and liebigite due to the modification of the hydrologic system by mining activities.The uranium mineralization occurs mainly as fracture fillings, coatings, and impregnations within breccia zones and intensely altered metasediments. Lesser mineralization is intimately associated with phyllosilicates which form the matrix of a carbonate-col/apse mega-breccia. The primary ore mineral is pitchblende, consisting of five generations, and from which a large suite of secondary uraniferous minerals have formed. On a gross scale the metal content of this deposit appears to be simple, consisting almost exclusively of U, but minor Ni, As, Cu, Se, Fe and Co are also present. The eastern limit of the mineralization is defined by a vertically-dipping microgranite dyke - breccia complex, containing high-grade uranium values. The orebody is truncated to the west and at depth by the Rabbit Lake reverse fault. Minor mineralization occurs as fracture fillings in unaltered plagioclasite in the footwall of the ore body. Precipitation of uranium from solution could have taken place by a number of processes. A mobile reductant (methane, carbon dioxide, etc.) may have been generated from graphite present in some of the host rocks of the orebody. Sulphides are also a common accessory and may have aided in the formation of a reducing environment. Phyllosilicates may have acted as adsorbants for uranium, allowing for its fixation. This metal has also been incorporated into the phyllosilicates themselves."

Jan 1, 1986

By M. T. Ho, D. E. Wiley

The iron and steel industry accounts for almost 5 % of the total world CO2 emissions. Optimisation of the steelmaking process has led to significant reductions in the energy intensity to the point where it is now close to the thermodynamic limit. Further reductions are not likely to be achieved with efficiency improvement alone and will require the development of novel or breakthrough technologies. This paper will show the costs of implementing CO2 capture at direct atmospheric emission points for a number of iron and steel production processes. These include a conventional process, top gas recycling processes, the Corex and Hismelt smelt reduction processes and the Midrex direct reduction process. Depending on the point source emission, costs of capture with existing chemical absorption technology at iron and steel plants can be similar to capturing CO2 at pulverised coal fired power plants.

Jan 1, 2015

By R. Llewellyn

"Wear damage is responsible for very high maintenance costs and significant production losses in the oil sands industry of northern Alberta.It affects all areas of operations and involves a panoply of wear mechanisms from low stress sliding abrasion at extremely frigid temperatures during winter mining, to elevated temperature erosion/corrosion in processes where bitumen is converted to lighter hydrocarbon products.There is no universal panacea to defend against such diverse attack and a wide selection of resistant materials and systems is employed. These range from relatively soft rubbers which rely on their elastic properties for their protective capability, to some of the hardest ceramics and cermets which are currently available commercially.Details are presented of the characteristics and forms of the variety of wear materials being used and how they relate to the requirements of their areas of application. The review focuses on the practices followed at Syncrude Canada Ltd., which is the larger of the two commercial oil sands plants."

Jan 1, 1997

By R. H. Waddington

Historical The limitations of reverberatory furnace operation have prompted many investigators to consider electric furnaces for melting electrolytically refined cathode copper. In the majority of cases where experimental work was performed, the furnace used was of the granular resistor, induction, or indirect-arc rocking type, and attempts to adapt the three-phase direct-arc furnace to copper melting appear to have been relatively few. In 1935, the International Nickel Company of Canada, Limited, carried to an advanced stage its experimental investigation of continuous melting of copper in the three-phase direct-arc furnace, and demonstrated that this process was technologically and economically practicable. Trial operations were conducted at the Huntington, W.Va. works of the Company, and were followed by the installation at Copper Cliff, Ontario, in 1936, of a full-scale unit for commercial operation. Two years later, a second unit was installed -which raised the electric melting capacity to a point permitting complete replacement of the coal-fired reverberatory furnace operation in the production of refined copper castings.

Jan 1, 1946

By W. A. Bell

The Carboniferous system of rocks in the Maritime Provinces include as workable mineral and organic substances, gypsum, anhydrite, salt, coal, building stones, grindstones, limestones, brick-clay shales, fire-clay shales, oil shales, etc. The system is, therefore, pre-eminently of economic value to the provinces in which it occurs, and the more knowledge we may gain concerning it, the more we may be prepared to aid in the development of these useful substances. For this purpose it is not sufficient to state that the ground upon which we stand is underlain by Carboniferous rocks. In-discriminate digging or drilling will not open many new mines of wealth, however difficult it may be to dampen the optimism of gamblers. For mineral wealth has not been scattered in the rocks haphazard, now here, now there, but its distribution has been the result of natural earth forces acting at intervals throughout the countless millions of years that have elapsed since our planet was born. As regards the majority of metalliferous deposits, the earth forces involved have resulted in the penetration of surface or sub-surface rocks by molten rock-matter and associated mineral solutions from deep-seated sources. But the economic Carboniferous deposits that have been mentioned are themselves types of bedded surface rocks rather than immigrant deposits, and their formation and geological history is closely related to that of the rocks with which they are interbedded.

Jan 1, 1924

By M. L. Connolly

Zinc production by Cominco Ltd. began in Trail in 1916 at a rate of 55 metric tonnes per day (t/d) and was increased ,in several increments until now electrowinning capacity approaches 750 t/d. The last increment, 40-t/d high-productivity electrowinning plant, was commissioned in 1974. In this paper, the design and operating experience with both the existing electrowinning plant and the new high-productivity plant are described.

Jan 1, 1977

By Dallas W. Davis

"Since May 1980, New Brunswick has called separate tenders for the right to explore and develop several potash prospects, as well as areas underlain by Alberta oil shale. These tender calls had in common the provision for a basic ad-valorem royalty, combined with sharing of cash flow after exceeding a 15-20% discontinued cash flow rate-of-return threshold. In the case of potash, the bidding variable was a share of cash flow, but for oil shale it was exploration expenditures committed, with the cash flow sharing to be negotiated at the time of application for a production lease. The Millstream potash occurrence, previously discovered by government drilling, received five bids (21.1% highest), the Dorchester ""grassroots area"" with four surmised drill targets apparently received no bids, and in the case of oil shale there were only two bids on the one block previously subjected to the most exploration.It is concluded that New Brunswick will not be successful in awarding the potash or oil shale rights in return for a comparable level of basic royalty and cash flow share as in the case of Millstream, unless it spends money in discovering prospects or sharing the exploration risk with companies. The approach is likely to work for oil shales only if current exploration proves the existence of much high-quality material or a definite trend of real increases in the price of oil is again established. Undoubtedly, it continues to be desirable to assure an on-going stable investment climate through award of potash and oil shale rights under terms which provide for a return that the public and future governments will consider fair. This could mean that some form or risk sharing with companies would be advisable."

Jan 1, 1983

By S. Bantubani, I. Mc Dougall, S. Arjun, H. Joubert, R. Hansraj

The requirements determining the design of the Söderberg electrode columns used in base metal applications are different to those of other industries. There is a strong trend to position the contact shoes above the furnace roof in order to reduce the risk of water leakages directly onto the furnace bath. Tenova Pyromet has adapted its proven electrode column design for application on base metal electric furnaces based on these requirements. The design modifications implemented as well as considerations regarding the overall electrode-roof-furnace arrangement are discussed. Equally important is the management of the Söderberg electrodes to prevent over or under baking. Tenova Pyromet has developed the AutoFurn™ furnace controller to not only optimise furnace operations, but to improve electrode management. An overview of the electrode management control philosophy implemented by AutoFurn™ is provided, focusing on intelligent electrode regulation, slipping and baking. INTRODUCTION Tenova Pyromet has developed an electrode system for use in base metal furnaces, which builds on the experience that Tenova has gained during the past 30 years with electrodes in the ferroalloy and base metals industries. In base metals applications, an important safety consideration is the minimization of water within the furnace and on the furnace roof. In addition, direct contact between copper equipment such as contact shoes and pressure rings and the contents of the furnace is discouraged. In a 3 phase AC furnace, three electrode columns transfer the electrical energy to the furnace bath. Both Söderberg and prebaked carbon or UHP graphite electrodes are in use in base metal furnaces. In each column, the electrode is held in position by a hydraulic slipping and regulating device, a pressure ring and contact shoes. The electrodes can operate in a submerged-arc or brush-arc configuration, where the electrode is immersed in the slag or a short distance above the slag (Mc Dougall 2013). The electrode equipment is divided into an upper and a lower electrode assembly. The self-baking Söderberg electrode is made from lengths of steel casings that are added to the top of the electrode column and welded into place. Carbon electrode paste is added to the inside of these casings and is baked to form a solid tip in the region of the contact shoes. The working platform that surrounds the area where new electrode casings are added, is electrically isolated from the building and each electrode is isolated from the others to ensure the safety of the personnel who perform the electrode casing additions.

Jan 1, 2019

By A Frostick

Ranger uranium mine is surrounded by the World Heritage listed Kakadu National Park and offsite impacts resulting from mining at Ranger would affect the Magela Creek catchment first. Radionuclides, lead isotope ratios and metal concentrations were measured in sediment cores from the Magela Creek catchment around Ranger to investigate the dispersion of mine-derived particulates. The study found a localised area within the Ranger mineral lease, where upper sediments had elevated levels of radionuclides and trace metals and radiogenic Pb isotope ratios. There is no current evidence of sediment dispersion from Ranger further downstream within the Magela Creek catchment.

Aug 1, 2010

By M. Venkatraman

The limit of Hall - Petch relationship in ultra fine grained steels has been examined based on dislocation pile-up mechanism. When the grain size becomes small the dislocation multiplicity ceases resulting in very low work hardening rate in these materials. An approximate analysis of the theories of hardening indicates that H-P relation is obeyed up to 100nm. It appears that grain refinement is not the suggested approach to improve toughness as well as strength below a critical size.

Jan 1, 2004

By J. R. Giegerich

THE problem of dust control in metal mines has, of late years, received considerable attention. In 1932, a detailed study of dust conditions at the Sullivan mine was undertaken and, while there are no actual data available regarding conditions prior to that date, there has unquestionably been a great improvement as a result of the investigation and of the preventive methods adopted. In attacking the problem, three main factors were considered: first, and most important, how to prevent dust from being formed; second, how to depress or collect it if formed; and third-if unable to accomplish these-what precautionary measures must be adopted to prevent inhalation of this dust. Seven distinct methods of dust control are now practised at the Sullivan. Six of these are employed underground; they are tabulated below in the order of their relative importance. The seventh method is used in the crushing plants on the surface. (1) Improved ventilation (2) General use of water sprays and atomizers (3) Curtailment of secondary blasting during shift hours ( 4) 100 percent wet drilling-primary and secondary (5) Wearing of protective equipment (6) Change from carbide to electric lamps (7) Installation of dust collectors

Jan 1, 1936

By M. Mahdi Aboutalebi, Roderick I. L. Guthrie, Mihaiela Isac

"A preliminary computational fluid flow model has been developed to simulate the flow field of liquid steel in the mold region of billet mold casting. This study reports the effect of different Submerged Entry Nozzles (SEN) on the fluid flow in round and square billet, curved mold, casters. In this study, ANSYS Fluent 14.5 software was used to model the 3-D turbulent flow of liquid steel. The standard k-0 model was used to simulate turbulence in the mold region. Similarly, the species transport equations were discretized to simulate the dye injection test into the mold cavity. The behavior of flow in the mold region was validated against previous experimental work. Predicted results showed that different nozzle types plus the slight curvatures in the molds can significantly influence the flow patterns generated within the mold region, and thereby affect the finished quality of the billet products.INTRODUCTIONConventional Continuous Casting (C.C) processes are presently used to solidify more than 95% of the 1.5 billion tons of steel now produced in the world annually (World Steel in Figure, 2014). This overwhelming contribution of C.C processes for steel production is the prime motivation for this study, in order to understand and optimize the casting processes and thereby reduce internal defects and minimize energy consumption. The primary objective of all C.C processes is to maintain liquid metal purity during the casting process and to create a uniform flow within the caster so as to avoid internal and external defects. In this regard, studying fluid flows in the mold region of continuous caster has attracted many research groups, in both academia and industry, in recent years. The mold region is one of the most critical parts of the C.C. process, in which the transport phenomena associated with this region can significantly affect the quality of the final products. Thus, proper control of fluid flows within this region can be expected to greatly decrease both internal and surface defects such as Oscillation Marks (OM), inclusion entrapment, and Mold Powder Entrapment (MPE). In the casting process, the fluid flow in the mold region can be affected by a number of variables, such as; the flow control system (stopper rod or slide gate), nozzle geometry, SEN (Submerged Entry Nozzle) depth, casting speed, mold dimensions, gas injection, and the application of electromagnetic fields. One of the most influential and easily-changed fluid flows are the jets of steel issuing from the SEN. Nozzle geometries are variable, consisting of a number of exit ports, different port angles, and/or port sizes, the bottom shape of the nozzle, and the SEN immersion depth (Thomas, 2001). The SEN characteristics can markedly affect meniscus surface velocities, surface level profiles, and turbulence levels that can vary in terms of the frequency and the magnitude of their fluctuations."

Jan 1, 2016

By Darryel Boucher, Thomas W. Leadbeater, Raymond Langlois, Joshua Sovechles, McGill University, Zhoutong Deng

"Spiral concentrators are used to upgrade ore based on the density difference between their component minerals. This simple flowing film gravity separator is of interest for the processing of large amounts of material, as found in the iron ore industry. Addition of wash water at different points on the trough of the spiral affects the grade and recovery of the valuable concentrate by affecting the flow of particles within the thin slurry film. This paper shows how radiolabelled hematite (-355+300 µm) and quartz (–1,180+1,000 µm) tracers were used to determine the particles’ behaviour within the slurry film with and without the addition of wash water. The results presented provide a detailed particle flow pattern around a wash water addition point and its effect on the trajectory and velocity of the particles. This information is of interest in building knowledge about spiral wash water injection parameters such as injection location, direction, flow rate and nozzle orifice type (affecting jet shape and velocity).INTRODUCTIONSpiral concentrators are density based separation devices. They are extensively used in the upgrading of iron ore, fine coal and minerals sands (sources of ilmenite, rutile, zircon and monazite) (Wills & Finch, 2016). A spiral unit is composed of a channel of specific profile formed as a helix of 3 to 7 turns around a central structural post. The feed pulp is composed of 15 to 45% solids with particle size from 75 µm to 3000 µm (Wills & Finch, 2016). Throughput of a single spiraling trough can be up to 8 ton per hour and multiple trough unit (up to four trough) can process up to 30 ton per hour for a footprint of around 0.7 m2 (Palmers & Vadeikis, 2010). They are low cost concentrators considering manufacturing of their trough via polymer reverse molding. The energy intensity of a spiral plan is notably small considering the throughput and is mostly related to pulp pumping and final concentrate dewatering."

Jan 1, 2016

By LeRoy A. Thorssen

The use of lightweight aggregate as a constituent of concrete is not a recent development. Pumice was used by the early Romans, in pozzolana cement concretes, in the construction of many of their works. However, the recent development of manufactured lightweight aggregates, such as the expanded shales, vermiculite and perlite, has created a possible use for a whole new group of Portland cement concretes. Concrete can now be produced with unit weights ranging from 30 to 150 pounds per cubic foot and with various insulating, fireproofing, acoustical and structural properties. The tonnage of such materials being used has increased considerably in each of the past ten years, and can be expected to increase for the next several years as availability of the aggregates becomes more widespread and the properties of such concretes become more thoroughly investigated and more generally known. LIGHTWEIGHT aggregates of many types have become avail-able to the construction industry in most localities on this continent

Jan 1, 1963

Post--Crunch Financial Management -An Overview A. The Industry and the Capital Markets B. .The SME -De-risking the Current and New Assets Followed by: C. The Lender?s Perspective on Re-financing?Jeff Stufsky, BNPParibas, NYCD D. .The Agency/Export Credit Lender Perspective?Doug Macaulay, EDC, Ottawa E. The Foreign Political Insurance Perspective?Pierre Vieillescazes, Carrick-Bend, Washington, DC ?Four Fundamental Metal Models No Longer Prevail. ?Mining is in new ?waters?: so be prepared (next page). ?Capital markets are uncertain-so be your own financier first ?If tight capital may remain, prepare to triage based on cash-flow production (not oz, lbs, tonnes, etc) ?Know your banker/financier(and it should know mining) ?In the past, it was ?know your borrower? ?The climbing team can fall if one climber carries too much ?Constantly re-assess the risk matrix (and j/v?s), and ?De-risk/diversify both the asset and the capital base

May 1, 2010

By Jose A. Caceres

Mine planning and mineral processing optimization are usually treated as two unconnected problems, especially at open pit and panel caving mines where the cut-off grade is practically the only variable optimized and analyzed for in the planning proposes. Using existing planning tool, the output is a reserve consumption strategy privileging higher grades. With the earlier consumption of the highest grades, every year produces revenues which are closer to the cost and potentially even below cost. However, there are other ore characteristics that can also affect the profitability of the operation. A new methodology has been developed, incorporating the grinding and flotation relationship into the mining economic models for the simultaneous analysis and optimization of the throughput-work index-recovery relationship through changes in the mining limits, sequence and redefinition of the reserve consumption strategy. A mine-site that implements this new planning strategy, can expect to increase the NPV from 5 to 15% depending on the actual operational settings. Two case studies have been developed, showing how the inclusion of the work index in the economic model changes the phase and mining sequence in an open pit mine and the caving sequence and the optimum column height in a panel caving mine.

May 1, 2004