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By D. H. Stonehouse

Of the f ive Canadian cement producing regions- Atlantic, Quebec, Ontario, Prairie and Pacific-Ontario has the greatest capacity and normally produces the most cement. However, during the last 5 years the greatest activity within the industry in Canada has been in the Prairie and Pacific regions where major capacity increases have taken place. Most Canadian cement companies produce normal Portland, high-earlystrength Portland and sulphate resisting Portland cements. Some companies also manufacture moderate Portland cement, and low-heat-of-hydration Portland cement. Escalating energy costs highlight the need for technology research into more energy-efficient equipment for the energy-intensive cement industry. The industry is well integrated and plants are well situated to support construction in Canada. Expansion into the United States has become common during the past decade.

Jan 1, 1984

By P. Hickey, G. Hubert, P. Healy

"J. S. Redpath Limited, an underground contractor with a worldwide presence, has implemented innovative techniques in various projects in Canada to shorten the development cycle. Conventional methods currently used for installing primary ground support are compared with the Australian technique of bolting and meshing with jumbos equipped with twin telescopic booms, in-cycle shotcreting, and the use of two jumbos and two scissor bolters set up side by side in wide headings. Recommendations and lessons learned are presented with the aim of providing realistic expectations with regard to development advance rates in a mining environment.RÉSUMÉ J. S. Redpath Limitée, un entrepreneur minier souterrain d’envergure mondiale, a complété plusieurs projets au Canada où des techniques novatrices ont été mises en oeuvre pour raccourcir le cycle de développement. Cet article présente une comparaison entre les méthodes conventionnelles fréquemment utilisées pour le support de terrain, la technique australienne de boulonnage et d’installation de grillage au moyen de jumbos équipés de flèches télescopiques doubles, du béton projeté appliqué durant le cycle de développement et de l’utilisation de deux jumbos et deux boulonneuses côtes-à-côtes dans des galeries de grandes dimensions. Les recommandations et les leçons apprises sont présentées dans le but de fournir au lecteur des attentes réalistes quant aux taux d’avancement du développement dans un environnement minier."

Jan 1, 2016

Infrared spectroscopic data collected using HyloggerTM technology is being used to assess the mineral composition of Archean iron ore bedrock and Cenozoic detrital units in Western Australia’s Pilbara region. Analysis of infrared spectra enables quantification of: (1) composite iron mineralogy, (2) composite clay mineralogy, (3) hydrous silicates and (4) carbonate mineral abundances. Stratigraphic and rock mass unit logging of core has identified several detrital and bedrock units recognisable across the Pilbara. However, due to alteration related to mineralisation, weathering and later stage precipitate overprinting, it can often be difficult to assess the detrital-bedrock boundary and the occurrences of specific geotechnical units in the detritals and bedrock, particularly when using non-core drilling techniques and traditional geochemical assays. Infrared spectroscopic data collected concurrently on core from several sites has shown distinct correlation against existing unit subdivisions and associated geochemical parameters. Where infrared spectroscopic data have also been collected on rock chips recovered from reverse circulation infill drilling, these correlations allow robust geological and geotechnical models to be developed based on the typical mineralogical-geochemical signatures. The geotechnical sub-units identified in core can be readily distinguished using the various iron and clay minerals captured by the HyloggerTM technology as opposed to total iron, potassium, and alumina captured by geochemical assays. Further, some of the minerals targeted by infrared spectroscopic analysis (eg gibbsite, white mica, vitreous goethite) and their ubiquitous presence as the products of weathering, assist in recognition of various ancient weathering surfaces and help to define the origin of the material, whether bedrock or detrital. Overall, HyLogging of core and chips allows important mineralogy focussed data to be captured at minimal additional financial outlay. Correlations against geochemical unit identifiers are robust both within deposits and between deposits. Significant improvements in the confidence of geological and geotechnical models are attained.

Jan 1, 2015

By R. Flood

"Oil has been discovered off Newfoundland in a number of locations on the Grand Banks, the most notable and exciting being in 1979 when Hibernia was discovered. This discovery has brought new challenges to the province as well as to all of Canada. During the seven years"" since its discovery, both industry and governments have attempted to define its parameters and to find the most efficient and economical way to develop the field.A number of studies have been completed during the interval and in 1985, Mobil Canada Ltd. and partners stated that they would prefer to develop the field by using a concrete Gravity-Based Structure (GBS). IntroductionHibernia is located in an environmental climate much more severe than that of any previously developed oil field. The wind and wave conditions are similar to those of the North Sea, but unlike the North Sea, any structure on the Grand Banks would have to contend with ice floes and icebergs. Decisions had to be made on whether fixed structures could be put in place that would withstand the pressures of the ice and the impact of an iceberg, or whether structures that could be removed when such impacts were imminent would be used.Early studies in 1981, determined that it was possible to build a concrete Gravity-Based Structure which could withstand the impact of the largest icebergs that are anticipated to float in that area of the banks.Additional studies increased the knowledge of icebergs: their patterns and size, and verified the original conclusions that Concrete Gravity-Based platforms would provide a practical solution."

Jan 1, 1988

By Wayne F. Luinstra, Frédérique Vincent, André R. Laplante

"A test to determine the amount of gravity recoverable gold (GRG) in an ore is described. Typical GRG results are given; possible uses are discussed. A case study of how the technology was used at Hemlo Gold Mines is presented.IntroductionUsing gravity to supplement either flotation or cyanidation is a well established practice in the gold industry. It differs from most recovery circuits in that most of the gold recovered by gravity would be recovered in any case by the circuit downstream, be it flotation or cyanidation. The economic justification of gravity is therefore based on small margins (for example. a net smelter return of gravity gold of 99%, as opposed to 94% by flotation). It was easily demonstrated when either flotation or cyanidation were relatively inefficient processes, and labour costs low (as gravity can be labour intensive). Over the past thirty years, the advent of better flotation machines (flash, column, high capacity), more effective collectors, and better control systems has increased flotation's metallurgical performance, thereby decreasing the incentive for gravity recovery. Cyanidation technology has undergone similar changes, with the advent of activated carbon, oxygen and lead nitrate addition, and improved impeller design.Today, gravity could remain an attractive option only inasmuch as it can be implemented with very low capital and operating costs. This has resulted in a relative shift away from gold gravity recovery (except for alluvial deposits), in the seventies and eighties. For example, as of the early nineties, gold gravity recovery has disappeared from the typical South African flow sheet. The advent of the Knelson Concentrator, at the beginning of the eighties, foreshadowed a resurgence of gravity recovery, as gold's grinding and classification behaviour (Banisi, Laplante and Marois, 1991) makes it possible to achieve adequate gold recoveries with very simple, Knelson based, gravity circuits (Laplante et al., 1994).Consider for example the Hemlo recovery circuit, made of a single 61 cm x 122 cm (2' x 4') screen, an automated 76 cm (30"") Knelson feeding a Gemeni table, to produce a 70-80% Au concentrate which accounts for approximately one fourth of the gold production (about 3 million grams per year). The low capital and operating costs make it possible to justify the gravity circuit on the basis of savings in other operating costs (e.g. fewer carbon stripping and reactivation cycles). Any improvements in recovery, which would at Hemlo be difficult to measure, would be additional benefits. Such a circuit is rapidly becoming a standard in Canadian and Australian operations.The justification for installing a gravity circuit must be first based on an estimate of how much gold it will recover (irrespective of what the potential benefits are). This is a function of the nature of the gravity circuit to be installed; however, Knelson circuits, by their very simplicity and efficiency, limit the options. This leaves the amenability of the ore to gravity recovery as the single most important parameter. Various approaches can be used to characterize this response (Woodcock, 1993). The present work sought a route which would fulfil the following criteria:"

Jan 1, 1996

By V. Shumila, T. Butler

Microseismic monitoring systems listen to a rockmass and record ground vibrations associated with brittle rock fracture. Modern systems record continuously and can identify as many as one thousand small and possibly larger magnitude events occurring each day from induced stress change and redistribution. This paper presents examples of the real time use of microseismic information in mining applications. It shows how alerts can quickly identify large magnitude events or unexpected clusters of seismicity and how seismic re-entry protocol can help to improve safety decisions. Additionally, newly developed advanced analysis techniques applied to mine seismic data sets are shown including the use of clustering methods to see into a cloud of seismic data to identify significant activity and quantify possible planar features. The use of source parameter trend analysis is shown to be a beneficial method for interpreting changes in relative stress levels. Seismic moment magnitude distributions are analyzed using the TGR (Truncated Gutenberg Richter) and TMD (Tapered Moment Distribution) methods to estimate bvalue and expected maximum magnitude. Seismic hazard analysis is shown as a useful way to simplify a dataset and highlight seismic hot spots. The rockmass response to excavation is a complicated spatial and temporal process and microseismic monitoring is a method that can be used to help understand the location and mechanics of failure occurring in the rock ultimately helping to improve safety and productivity at a mine site.

Jan 1, 2015

By P. Ramirez

"To achieve an optimal metallurgical performance in the flotation process the bubble diameter should be between 0.5 and 2.5 mm. To control bubble size, frothers are added, reducing bubble size and conferring bubble stability against coalescence. However, the bubble generation mechanism determines predominantly the bubble size distribution produced. In mechanical flotation cells, bubbles are produced by the shear stress generated by a rotating blade on a gas stream. This mechanism produces a log normal bubble size distribution. In contrast, in column flotation, jetting gas injectors are commonly used in Chile and the bubble size distribution is bimodal with small and large bubbles. Bubbles larger than 2.5 mm mean a loss in surface area, while bubbles smaller than 0.5 mm move with the pulp stream and therefore collide less frequently with particles. In this paper, a new device based on a jetting sparger and a deflector disc (impinging jetting) is evaluated as an alternative sparger for column flotation.The new device was tested in a rectangular acrylic cell 1 m × 0.5 m × 3 m. High-speed cinematography was used to compare bubble generation with jetting and impinging jetting at different gas velocity in the nozzle (5–50 m/s). From the image analysis, it was observed that the deflector induces a shear stress, in analogy to a rotating blade but in this case the shear results from a high velocity gas hitting a static surface. The device was evaluated in a 0.5 m diameter 3 m high column. The McGill bubble viewer technique was used to compare the bubble size generated by jetting and impinging jetting. It was found that the Sauter mean bubble diameter reduced from 7.4 mm to 2.8 mm, when the jetting sparger was modified with the deflector. In the case of the impinging jetting sparger, 70% of the bubbles were in the effective range for flotation, while for the jetting sparger, only 10% were in the effective range."

Jan 1, 2016

By D. G. Brophey, J. A. O’Neill

"High costs, both in terms of human resources and financial costs, have long been the end result of accidents involving vehicles which continue to occur too often throughout our industry.For example, radio remote control LHDs too often seriously injure their operators in underground operations. Costly efforts are required by mine owners to provide safety bays and platforms from which their operators can work safely. In open pit operations, large heavy haulers have too frequently backed over vehicles or turned into vehicles unfortunate enough to be situated in their large blind spots. These are just two examples of situations that have occurred again and again under similar circumstances.Meanwhile, electronic methods of detecting proximity to vehicles have continued to develop. The time has come for the industry to think “outside the box” to evaluate whether many of these new methods can solve these recurring problems.This note takes a look at various types of proximity detection technologies that are in use today in other industries, and discusses the various potential applications within our industry."

Jan 1, 1998

By K. Adham

Both the dry and the wet fluorination systems require hydrogen fluoride (HF) for the process of uranium conversion to uranium hexafluoride (UF6). The dry methods depend on the electrolysis of HF to generate the fluorine (F2) required for the high temperature pyro-fluorination. The wet methods require aqueous HF in water solutions for the low temperature hydro-fluorination (Argonne, 2019). This paper uses the available HF safety guidelines and industry information to discuss the issues of transportation, storage and utilization. Health effects and environmental considerations are reviewed. Safe practices for handling the HF (both as anhydrous and as aqueous) are considered. Proper selection of different materials of construction are discussed, for both the anhydrous and the aqueous HF.

Jan 1, 2020

By Kyeong Woo Chung, Ho-Sung Yoon, Jyothi Rajesh Kumar, Chul-Joo Kim, Sung-Don Kim

The aim of the present study is to investigate the extraction, separation and recovery of the indivisible metals of dysprosium and neodymium from permanent magnets scrap leach liquor solutions with meaningful recovery. The present experimental development focused on dysprosium separation from neodymium and recovery by suitable mineral acids. Fundamental studies of the effect of time, pH and extractant concentration on the metal separation were conducted followed by proposal of a mechanism for extraction. Process development included generation of McCabe-Thiele diagrams and counter current extraction (CCE) studies. After loaded organic generation from the CCE process, this was followed by scrubbing studies as well final recovery of dysprosium.

Jan 1, 2014

By D. Want

In titanium-lined autoclave design the most critical point of its mechanical reliability is its titanium batten strips present at the circumferential and longitudinal barrel-weld seams. Recently an Australian Company, W.E. Smith Hudson (WESH) P/L, has developed a fully flush batten strip and is building autoclaves with this design. Significant research and development has been performed in the process. In this presentation, design aspects of these batten strips are presented that cover topics such as residual-stress magnitudes during fabrication, affect of preheat during batten-strip welding and residual stress in respect to fatigue life. There has been little research done regarding the affects of residual batten stress in relation to fatigue life. Considerations of this 'grey' area of design will be discussed based on the author's research data and finite element analysis.

Jan 1, 2005

By S. Dominguez, E. Gebrehiwot, S. Richardson, S. Sandoval

Copper electrowinning/electrorefining (EW/ER) is powered by direct current (DC) rectifiers that typically generate 30,000 to 70,000 amps and a bus-bus voltage of 200 to 500 volts DC. Tankhouses are designed so that DC current flows through “cell lines” which contain individual EW/ER cells electrically connected in series. Electrolyte composed of copper sulfate and sulfuric acid in water forms the “liquid conductor” that connects the metallic conductors in this circuit. In this setting, stray current is a DC current that strays from and therefore bypasses the tankhouse circuit by finding a path to ground, often through the electrolyte in pipelines that feed into and discharge from the cells, or through dried electrolyte (i.e. sulfate), which is also electrically conductive. Tankhouse workers can be exposed to shock hazards if they become part of a stray current path to ground. This presentation details examples of stray current shock hazards in electrolytic tankhouses and provides voltage and amperage measurements associated with stray current in these examples. A review of critical safety controls in EW/ER tankhouses that will mitigate the risk of employee shock from stray current is also provided. INTRODUCTION Electrolytic tankhouses are designed to deliver relatively large amperages of DC current to a series of electrolytic cells in which copper is plated out of solution using the classic anode-cathode pair geometry within each cell. Electrolyte is the “liquid conductor” that transfers current in between the metallic conductors of the cell. The metallic conductors include inter-cell copper bus bars and the anodes and cathodes themselves. It is sometimes forgotten that electrolyte as a conductor is capable of delivering DC current outside the designed circuit of a tankhouse. Stray current is a DC current that strays from the tankhouse electrical circuit by finding a path to follow other than the designed path. Safety becomes a concern when there is a risk of an employee becoming part of an accidental stray current path, thereby suffering an electrical shock. In 2016, Freeport-McMoRan (FMI) suffered a fatality at one of its copper electrowinning tankhouses. The forensic analysis concluded that stray current from the tankhouse rectifier contributed to the fatality. An employee accidentally fell into contact with a metal flange at the end of an HDPE pipe that was collecting cell overflow electrolyte from the tankhouse. DC current passed through the employee to ground, creating a shock that was judged to contribute to his death. The situation was exasperated because the employee was unconscious, and therefore was exposed to the stray current for several minutes before being found. In addition, the employee’s clothing was saturated with liquid, and the employee was found kneeling in puddled liquid on the ground. FMI immediately began an investigation into the root cause of the stray current that was measured at the scene. Sufficient electrolyte had accumulated in the HDPE pipe such that a continuous path was formed between it and electrolyte that was continuously overflowing from energized electrowinning cells. The metal flange on the pipe was the metallic conductor that carried the current to the employee from the electrolyte inside the pipe. Current then flowed through the employee to ground. Because of this incident, FMI undertook an extensive review of the hazards of stray current in EW/ER. FMI’s tankhouse workforce received a Tankhouse Electrical Safety training course developed in- house to insure worker understanding of stray current hazards. Tankhouse design changes were implemented to better insulate workers from stray current. Personal protective equipment (PPE) standards were also reviewed and changes made.

Jan 1, 2019

By D. Purdie

"This paper aims to remind researchers, designers, operators, and managers about the benefits of seeding in the design of precipitation stages in their flowsheet. Including a high density solids (HDS™) process encourages the precipitating solids to form on the surface of existing precipitated particles. This paper discusses the application of the HDS technology at Kennecott Smelter, where the authors have witnessed significant improvements in settling and filtration rates. The authors have also applied this technology at various smelter bleed treatment plants worldwide with similar improvements in precipitation and filtration rates. HDS is a registered trademark of De Nora Water Technologies. RÉSUMÉ Cet article a pour objectif de rappeler aux chercheurs, aux concepteurs, aux exploitants et aux administrateurs les avantages de l’ensemencement dans la conception des étapes de précipitation de leur schéma de traitement. L’introduction d’un procédé des boues haute densité (procédé HDS™, de l’anglais high density sludge) encourage la formation de substances solides précipitantes à la surface des particules précipitées existantes. Cet article porte sur l’application de la technologie HDS à la fonderie Kennecott, où les auteurs ont observé des améliorations importantes au niveau de la vitesse de sédimentation et de filtration. Ils ont également appliqué cette technologie à diverses usines de traitement des rejets liquides des fonderies dans le monde entier, et ont constaté des améliorations similaires en termes de vitesse de précipitation et de filtration. Le procédé HDS est une marque de commerce déposée du fabricant De Nora Water Technologies.INTRODUCTION In 1966, the lead author worked as an assistant smelting metallurgist for the Tsumeb Corporation Limited copper and lead smelter in Tsumeb, Namibia. The smelter produced copper and lead, as well as cadmium and arsenic trioxide as byproducts. The cadmium was concentrated in the lead blast furnace off gas dust, and was collected by a baghouse. The baghouse dust was leached with dilute sulfuric acid (H2SO4) in a batch process. The iron and arsenic in the solution were oxidized with potassium permanganate (KMnO4) and basic ferric arsenate (BFAS; Fe(AsO4)x(SO4)y(OH)z·wH2O) was precipitated using milk of lime. The cadmium was cemented from the purified solution using zinc dust."

Jan 1, 2018

By P. Leo

The hot deformation behavior of a Mg-9A1-1Zn alloy produced by high pressure die casting has been investigated by means of compression tests in the temperature and strain rate ranges of 125-300°C and 10-5-10-1 s-1 and torsion tests over 150-450°C and 5, 0.5, 0.05 5-1 . The compression samples were deformed in the die-cast state or after homogenization at 415°C for 2 h to evaluate improvements. A premature fracture at 45° with respect to the compression axis was observed in samples strained at low temperatures and high strain rates. The torsion specimens were tested as received or after a predeformation-homogenization treatment. In addition to constitutive analyses suitable for modeling previously published, the results are fitted to a relationship between strain rate normalized by diffusion coefficient and flow stress normalized by modulus. The results fit well with a set of published creep experiments that were conducted in the range of 70-150°C.

Jan 1, 2006

By Y. Champoux, N. Atalla, R. Oddo, C. Lesage

"Percussion drills are the source of the most serious noise problems in mining activities, due to their extremely high noise levels(114-122 dB(A)) and widespread use(Bartholomae and Stein, 1988). Percussion drills will continue to be widely used to drill small diameter holes in hard rock because no other method seems to be economically avail-able to replace them (Boillat et al., 1993).Many studies (Danière, 1991; Hawkes etal., 1977a; Jensen and Visnapuu, 1972;Leblond et al., 1976; Milette, 1989) were con-ducted to determine the major noise sources of percussion drills. The exhaust air of pneumatic drills, the hammer, the bit in contact with the rock and the drill rod have been identified as the major noise sources. A muffer can be used to reduce the exhaust noise and the hammer can be enclosed. The bit noise is considered to be of concern only at the beginning of holes. When all the available methods are used to reduce the noise of a percussion drill, the drill rod vibrations become the dominant noise source (Hawkes and Burks, 1979). However, the noise levels generated by this source remain high and future efforts should concentrate on reducing its radiation.Works by Hawkes and Burks (1979) and Hawkes et al. (1977b) for the U.S. Bureau of Mines provide the most complete description on the noise and vibration of percussion drill rods.The longitudinal and bending waves are the two most important types of elastic waves generated in drill rods. Among these, only the longitudinal waves contribute to the drilling rate. The bending waves are caused by non-centralized impacts, drill rod curvature and non-uniform bit/rock interface. Drill rod noise is generated by Poisson’s ratio expansions and contractions of the rod as the longitudinal waves travel up and down it and by transverse rod motions induced by bending waves. The radiation efficiency is much higher for bending waves than for longitudinal waves. Most of the impact energy is transformed into longitudinal waves, as expected for axial impacts. The evaluation of the relative contribution of longitudinal and bending waves to noise generation poses a very difficult problem for experimental, analytical and numerical approaches. It is, however, an important issue because the relative contribution of these two waves will guide future noise reduction efforts. It seems that very little can be done to reduce the noise radiation of the axial waves without affecting the drilling rate. The main difficulty that analytical and numerical approach-es face, in the evaluation of the relative contribution of the two waves, is that there is no adequate theory for predicting the bending vibrations from the factors that cause them. The experimental approach has, thus, been limited to test fixtures that do not adequately represent the boundary conditions, as well as by measurements obtained under real operating conditions from which it is difficult to establish the relative contribution of the two types of waves. For example, Hawkes and Burks (1979) and Hawkes et al. (1977b) used a test fixture with free-free boundary conditions and made no clear link with measurement under real operating conditions. Rather, they have based their discussion on a simple model. Many authors assume that fexural waves are the main noise source on drill rods. However, measurements have been somewhat contradictory and researchers are still unable to state with certainty that this is indeed the case (Lednik et al., 1988)."

Jan 1, 1997

By J-F. Béland, N. Parson

Aluminum extrusions are widely used for automotive crash management systems due to their superior specific energy absorption capabilities, as compared to steel. The Al-Mg-Si alloy series can be readily extruded into complex multi-hollow profiles, as required in crash systems, and can be used to target a range of desired strength levels. This paper focuses on the development of an axial crush test protocol and evaluation of the crush performance of common 6XXX series alloys for a variety of tempers. The observed crush behaviour is then compared to tensile test results.

Jan 1, 2015

By R. F. Baxter, C. M. Read, R. I. McCulloch

"Globalization of the aluminium industry continues to increase the pace of change and the intensity of competition, while simultaneously, society demands better products, cleaner technologies and sustainable industries. Bechtel, a global engineering, construction and project management company, is not immune to either the opportunities or the challenges created by globalization. However, and not withstanding the challenges, for aluminium industry ""players"" with a true global perspective, globalization presents very real opportunities that may be leveraged to deliver value creating goods and services. The following paper will focus on the exploitation of one of the opportunities created by globalization in the Knowledge Management domain - the application of high level tools and methodologies to improve global delivery of greenfield and brownfield aluminium smelter construction projects. Specific examples will be presented of value driven solutions that were delivered at the early stages of project engineering."

Jan 1, 2006

"Real-time, on belt analysis of minerals is becoming increasingly important and critical in modern operations, especially in the mine-to-mill. Prompt gamma neutron activation analysis has long been utilised for real-time elemental analysis in bulk materials, with Scantech's GEOSCAN being the instrument of choice in the minerals sector. Working in the minerals space for 15 years, the GEOSCAN has been successfully implemented in a wide range of minerals applications including iron, copper, lead-zinc, manganese, phosphate and more, and it caters for the very high demands and increasing requirements of a contemporary processing facility. An area of focus has been on increasing the analysis frequency to allow for rapid analysis results with the same high degree of accuracy typically expected of the GEOSCAN. This paper discusses the underlying research and technology that has enabled such rapid analysis and presents a range of examples using a thorough statistical approach on real production material, demonstrating achievable accuracy over a short analysis time, and dispelling common myths about the speed of the technique. Potential applications are discussed to conclude the paper.INTRODUCTION Technology and the information it can provide plays a critical role in the evolving modern mineral processing landscape. The importance of technology to analyse various features of ores and concentrates being processed is obvious, and recent years has seen the advance of numerous technologies to provide a variety of real-time measurements on conveyed material flows. From sampling apparatus to particle size analysis to weight and density meters to full elemental analysis, the availability of information enables a variety of improvements in the process leading to improved efficiency and increased revenue. To maximise the potential benefits, access to real-time information is imperative, and rapid updates of information become necessary to make appropriate process control decisions based on the most relevant and up-to-date information."

Jan 1, 2017

By W. S. Szolga, M. Moser, M. D. Soderstrom, L. Cohen

"CYANEX® 272 is a phosphinic acid-based solvent extraction reagent used commercially since the early 80’s to recover and purify cobalt from sulfate solutions. Historically, the design of CYANEX 272 circuits has involved the selection of an optimal pH profile during pilot-scale testing using mixbox pH control. The desired pH profile is required to be carefully controlled in the same manner during commercial operation. To assist operators in the design and optimization of their circuits, Solvay developed CYANEX 272-specific solvent extraction modeling software, which has enabled determination of the ideal pH profile and staging configuration. Solvay’s recent advances in modeling capabilities have allowed the simulation of circuits without direct mixbox pH control. Modeling has indicated that circuits operated without direct pH control can achieve the desired metal separation while simplifying the commercial operation significantly. This paper reviews a number of potential circuit configurations for the use of CYANEX 272 and demonstrates the separations achievable under the right design and operational conditions, some of which have historically been considered too difficult.INTRODUCTION CYANEX® 272 is a phosphinic-acid based reagent designed specifically for the separation of cobalt from nickel by solvent extraction from weakly acidic sulfate solutions (Rickelton, Robertson, & Burley, 1982; Rickelton, Flett, & West, 1984; Rickelton & Nucciarone, 1997). Following commercial introduction in the 1980’s, CYANEX 272 has been used in a number of hydrometallurgical flowsheets for cobalt purification and/or recovery. CYANEX 272 metal extraction occurs by means of a cation exchange mechanism. Extraction of a divalent metal ion M2+ is represented by the following equation where RH represents the CYANEX 272 ligand and MR2 represents the ligand-metal complex."

Jan 1, 2017

By A. B. Barlow, D. H. Pitcher

"The Geophysics/Geochemistry Section of the Ontario Geological Survey initiated an aerial geophysical survey in the James Bay Lowlands, Cretaceous Basin area, District of Cochrane, Ontario. The survey was contracted to Scintrex Limited and was carried out in 1978. Approximately 8000 line kilometres of airborne electromagnetic and magnetic data were recorded. The Tridem airborne electromagnetic system was employed, mounted in a twin-engined PB Y Canso aircraft. This specific Tridem system uses a vertical coaxial coil configuration and measures in-phase and quadrature components of the secondary field at 500, 2000 and 8000 Hz.The primary purpose of this survey was to map subsurface conductivities and, in particular, to search for lignite deposits. Physical property measurements show that electrical methods should detect differen ces in conductivity between the moderately conducting clay-lignite horizons and the less conducting clay, soil, muskeg and gravel horizons. A preliminary Tridem test survey, as well as surface DC resistivity soundings, confirmed this approach. The interpretation of the present survey data indicates that Tridem is a suitable electrical method to aid lignite exploration in the James Bay Lowlands."

Jan 1, 1980