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By D. Moronkeji, R. Maharidge, D. A. Curry, B. J. Davis, U. Prasad, J. Franquet

"Proper shale characterization is crucial in shale gas drilling, exploration, completion and production. Unlike porous sandstone and carbonate reservoirs, the challenge with shales comes from their micro- to nano-darcy permeability ranges and the anisotropy of their mechanical and hydraulic properties. Most porosity-dependent logs are not sensitive enough to capture the true behavior of shales. Consequently, mineralogy and other strength and stiffness-related properties must be determined to characterize magnitudes and variances in shale mechanical and flow properties. In addition, these properties must pass quality assurance/quality control (QA/QC) practices to give confidence in their use in subsequent log calibrations, during geomechanical modeling, or in fracture design models. This paper presents a technique to integrate shale properties that are measured by various methods, and a methodology to perform QA/QC on the data before application.Shale properties originate from various sources, including downhole and laboratory measurements. Physical samples for laboratory testing are usually limited to a few depths. Lab tests are often costly, and replicating in-situ conditions can be difficult or impossible. In addition, results frequently show wide scatter, reflecting inherent depth variability and lateral heterogeneity. Wireline logs provide nearcontinuous data, but rarely yield direct measurements of rock strength properties. Although geomechanical and fracture models use log data, calibrating it with reliable and previously verified lab-measured properties is important. This paper presents a process to perform QA/QC on lab-measured data using various crossplots.Ten mechanical, microstructural and physical properties are graphically displayed to visually characterize shale strength behavior in ambient and in-situ conditions, whether measured or modeled statically or dynamically. These properties are often sourced from different departments. The properties are integrated but are individually subject to the previously mentioned uncertainties. Pairs of property values are crossplotted and compared with correlations from the literature or previously established with qualified data from related formations. Conformance with these correlations gives confidence in the data, whereas outliers are flagged as questionable. Repeating the process with questionable data crossplotted against other parameters for the same depth highlights the property with the greatest uncertainty. The determination of its value is investigated to locate the source of the inconsistency and establish a more reliable value. Where this is not possible, the user has a rational basis for rejecting that property value."

Jan 1, 2015

By S. Spigarelli

The creep response of the AE44 magnesium alloy was studied by means of constant load creep tests carried out at 125 and 150°C, obtaining that at the latter temperature the minimum creep rate observed under an applied stress of 100 MPa was two orders of magnitude lower in the investigated alloy than in AM50. The minimum creep rate dependence on applied stress was described by a conventional power-law, e = Aon , where A was a temperature dependent parameter and n was the stress exponent, resulting in a n value close to 30, i.e. by far larger than those observed in commercial alloys with similar Al content. This large difference in creep response was attributed to the precipitation of rare earths (RE) intermetallic phases distributed in the grain boundary zone in form of an almost continuous network of dispersoids that were observed by means of scanning electron microscopy.

Jan 1, 2006

By K. K. Dehn

This study focused on determining the stability of thin shotcrete fill fences at a hard rock mine in northwestern Ontario during increased pour rates of paste backfill. Determination of the stability of the fence is needed for both personnel safety and to avoid failure of a fence. Failure of a fill fence during backfill activities would have severe impacts on production and potential hazards to nearby workers. Approved fill fences at the mine are a slender design of 10.5 centimeters of shotcrete applied to a rebar framework with burlap lined ?bedspring? backing. Approved mine standards dictate that fill rates may not exceed 1.5 meters of paste depth per 10-hour shift when pouring behind a flat fill fence. To decrease the backfill cycle time the study looked at fence stability during increased pour rates of 2.5 meters paste depth poured within a 10-hour shift. An instrumentation design was developed including pressure cells, strain gauges, and tilt-meters that were built into experimental fences to observe the effects of increased pour rates on lateral wall pressures, strain development in the rebar and shotcrete reinforcement, and physical deformation patterns along the face of the fence. The data was analyzed for overall stability.

May 1, 2007

By K. S. Fraser, H. J. H. Pieterse

"A pressure oxidation plant to pretreat refractory sulphide ore at the Goldstrike plant in Nevada, was commissioned in early February 1990. The plant, with a nominal capacity of 1363 t/d, was commissioned over a one-week period and achieved design capacity and availability within ten weeks an unusually short period for a plant of this complexity.The pressure oxidation process is conducted under elevated temperature and pressure conditions, and in a corrosive environment. These conditions demand that the process and engineering design of the plant be carried out in a much more sophisticated and detailed manner than is normally required in a conventional gold plant.This paper provides an account of the process and engineering design of the Goldstrike pressure oxidation plant with special emphasis on the design of the vessels, slurry pumps, piping, valves, and control systems.BackgroundLocationThe Goldstrike property is located in Eureka County in northcentral Nevada on the Carlin geological trend. The mine is approximately 40 km northwest of the town of Carlin which is situated on Interstate Highway 80. The minesite is located 1700 m above sea level in the Tuscarora Mountains.Initial Goldstrike OperationsShallow, low-grade mineralization was discovered by diamond drilling in the Goldstrike area in the 1960s. A heap leach operation was established in the mid-I970s by the previous owners. The Post deposit was discovered in 1982. Gold production by mining and heap leaching reached I t/a (40 000 oz/a). American Barrick purchased the property in 1987 and started an aggressive program of deep drilling. This led to the discovery of the Betze and Deep Post deposits and established sufficient reserves to justify an initial 4100 t/d mill and a 5 500 000 t/a heap leach operation"

Jan 1, 1992

By G. E. Wood

THE INSTABILITY of copper prices and their low levels since late 1974 are of great concern to both producers and, to a lesser degree, consumers of copper. The price levels portrayed by the "neutral long-term" price trend are assumed to have been enough to encourage sufficient investment to provide adequate world production capacity and yet not so high as to encourage development of excessive over capacity. The identification of the present level of this trend has taken on special importance for governments and for corporations active in the world copper industry. One approach to the possible determination of such a price is through the use of moving averages. In this way, the effects of relatively short-term price movements can be dampened, as can those related to business cycles. From such averaged price data, long-term trends can be sought over a selected time period. The choice of the past time period for which a price trend is sought may have a major effect on the result'. For example, in the period 1885-1973, the long-term price trend for copper in constant dollars showed a decline, whereas in the period 1919-1973 it was rising. For the purposes of discussion, an appropriate choice of period might be a relatively short and recent one so that the majority of the present cost factors would be present throughout. It should also be long enough to cover a number of full business cycles.

Jan 1, 1977

By P. M. Dranchuk

"""PLANET EARTH seen from space appears as a fragile and limited life-supporting system in a vast emptiness. That such a view is, in fact, an accurate one is now more widely accepted than it was not long ago, before Earth's problems of over-population, overconsumption, limited resources and environmental degradation attained the limelight. The danger is that a government and public now deluged by doomsday prophecies and bemused by equally confident reiterations that technology will cure all may hesitate in coming to grips with the problem, in the hope that, given time, it will go away."" With these words, Preston Cloud begins a recent editorial, in Science(l), in which he presents a brief resume of some of the findings of the Committee on Resources and Man of the National Academy of Science-National Research Council(20.Their report, which is based on a two-year study by an extremely competent group and consists of some 250 pages of text, is even more far-reaching and sobering than the report on Energy Resources(3). It begins by quoting Sir Macfarlane Burnet as follows:""There are three imperatives: to reduce war to a minimum; to stabilize human population, and to pre-vent the progressive destruction of the earth's irreplaceable resources.(4)"

Jan 1, 1971

To produce high quality castings, one must monitor the melt quality by evaluating such parameters as the grain refinement and silicon inoculation and modification during the production of the commercial casting. Thermal analysis is a tool one can use for both monitoring and providing input to the process control of the operation. The current technique of performing thermal analysis in commercial foundries is to pour a relatively small quantity of the molten aluminum alloy into a sampling cup and to then acquire the cooling curve. This approach is somewhat simplistic in that one has limited control of the cooling rate and hence the solidification rate of the sample. Moreover, this process requires a fair amount of user intervention and effort. In the past, studies have been conducted in an attempt to develop a system for conducting thermal analysis in-situ. In a study at McGill University, an alkali based heat pipe system was developed for conducting thermal analysis in-situ. While the concept was deemed as very desirable, the complexity of the equipment and procedure was a substantial negative component. In order to improve the technique of accomplishing real-time thermal analysis with an in-situ probe, a new method that is based on McGill heat pipe technology was developed. In the new system, a controllable and flexible water based heat pipe probe is used to solidify a small quantity of metal while residing in the melt. The solidified aluminum is remelted after completing the thermal analysis. This is a key feature of the probe. It resides permanently in the melt yet it is able to both solidify a sample of the melt and then to subsequently remelt it. Various solidification rates encountered in commercial castings are attainable by adjusting the heat extraction rate of the unit.

Jan 1, 2004

By H. P. Kang, Y. J. Feng

The hard roof in underground coal mines is generally considered as a main cause that induces disasters in working faces and entries, such as rock burst and windblast. Hydraulic fracturing technology is an effective approach to weaken hard roof to reduce ground pressure and control rock burst. The state and achievements associated with hydraulic fracturing technology applied in Chinese coal mines are summarized in this paper. Theories related to hydraulic fracturing are of the essence in fracture design to determine the fracture initiation and propagation pressure and predict the geometry and the characteristics of hydraulically induced fractures. Initially, theory of elasticity was employed to determine the breakdown pressure for a vertical borehole where the rock medium is assumed to be elastic. However, porosity and pore fluid have an influence on the borehole breakdown pressure, and then the poroelasticity theory was applied. Arbitrary deviated boreholes in practice are rather common and the maximum tensile stress criterion was employed to determine borehole breakdown pressure. The effect of natural crack in the rock medium on the initiation pressure has been taken into consideration through fracture mechanics. Meanwhile, considerable achievements have been made on hydraulic fracturing tools and equipment, and a set of mature hydraulic fracturing technologies for hard roof control are available. Some comprehensive investigations on the hydraulic fracturing for hard roof weakening are presented, and successful field applications in the Jincheng and Luan coal mining districts are introduced. Finally, the unsolved problems related to hydraulic fracturing are also put forward.

Jan 1, 2015

By A. Dahi Taleghani, Amir Shojaei

A continuum damage mechanics (CDM) based constitutive model has been developed to describe elastic, plastic and damage behavior of rock during drilling. In addition to inelastic deformations, this model incorporates rock anisotropies like toughness anisotropy due to the bedding planes orientation that is a common observation in soft Shales. The pressure sensitive inelastic deformation of porous rocks together with their damage mechanisms are studied for drained and undrained conditions. Fracture mechanics of microcrack and micro-void nucleation and their coalescence are incorporated into the formulation of the CDM models to accurately capture different rock failure modes. The performance of the developed elastoplastic and CDM models are compared with the available single cutter test data of a specific shale play and then the models are introduced into a commercial finite element package through user-defined subroutines. A workflow to derive the required model parameters is presented through inverse modelling of the single cutter test data. The developed CDM model outperforms the traditional discrete element and fracture mechanics approaches by removing stress singularities at the fracture tips and simulation of progressive fractures like formation of the cuttings ribbon without any essential need for remeshing. This model would provide a robust tool for modeling bit performance and rate of penetration using conventional elements of FEA with a reliable results and a computational cost less than similar computational techniques like discrete element methods.

Jan 1, 2015

By Elhachmi Es-Sadiqi

"For over 40 years, CANMET has focused its research on value-added products and energy efficiency in the metals industry. The Efficient Metal Production Program is currently managed by Dr. Elhachmi Es-Sadiqi, and the Canadian steel industry is its main client — both directly and through international organizations such as the American Iron and Steel Institute (AISI) and the International Lead and Zinc Research Organization. AISI membership includes Canadian steel companies IPSCO, Dofasco, Stelco, Algoma Steel and Sidbec Dosco.Canada’s steel industry makes important contributions to the economy. The industry comprises 14 companies and employs 33 600 people in locations such as Sydney, Nova Scotia; Tracy, Quebec; Selkirk, Manitoba; Saskatoon, Saskatchewan; and Sault Ste. Marie, Ontario. With annual production at about 16 million tonnes, sales in 1995 totalled $11 billion, $3.8 billion of which was exported.Canada’s steel industry supplies the transportation, oil and gas, appliance, packaging and construction industries. It is at the forefront of new technology use and has a substantial support network to provide raw materials, equipment and service. Three main segments of the industry include flat-rolled products (e.g., plate and sheet steels), long products (e.g., concrete reinforcing bar and structural steel), and specialty and alloy steels (e.g., stainless steel and tool steels, in both long and flat products)."

Jan 1, 1998

By J. P. Jylhä, A. Jokilaakso

The Outotec Flash Smelting process is widely used in primary copper production. A layer of slag on top of matte (copper–iron sulphide melt) creates a barrier through which matte droplets descend. Droplets of different sizes settle through the layer at different rates, which increases possibility of copper losses as smaller matte droplets may be removed with the slag. In this work CFD-DEM (computational fluid dynamics – discrete element method) coupling was used to simulate matte droplets settling through the slag during slag tapping. Discrete droplets and slag flow were simulated with DEM and CFD, respectively. This new approach enables tracking and solving movement and interactions of individual droplets. User-defined models were created to take coalescence and reaction kinetics into account. Coalescence created larger droplets, while the reactions decreased droplet size and increased its density. Drag caused funnelling effect, which pulled droplets towards the centre line of the descending cluster. This research is the only study known by the present authors in modelling liquid-liquid systems with the CFD-DEM coupling. Simulating coalescence and chemical reactions for discrete droplets enables more realistic simulations. However, CFD- DEM simulations are computationally resource intensive already without additional models, so a full scale industrial settler modelling still waits for further increase in computer performance. INTRODUCTION Flash smelting is a method used in copper and nickel production. In the flash smelting process, oxidation of sulphides in a concentrate is used to release energy needed to smelt the feed. In the process, copper matte is formed. Matte has copper content in the range of 55 – 70% (Sridhar, Toguri, & Simeonov, 1997), the rest is mainly sulphur and iron but has still many other impurities (Taskinen, Seppälä, Laulumaa, & Poijärvi, 2001). Oxidized iron forms iron-silicate slag while SO2 is collected for acid production (Davenport & Partelpoeg, 2015). The Outotec flash smelting furnace (FSF) can be divided in four major component: concentrate burner, reaction shaft, settler and uptake. Concentrate, flux and oxygen enriched air are injected into the reactor through the concentrate burner. The mixture then reacts in the reaction shaft forming matte and slag, which are collected in the settler, while off-gases flow out of the reactor through uptake for heat and dust recovery, and SO2 collection for H2SO4 production. The matte and slag form separate layers due to immiscibility and density difference. Raw material feed is continuous, but the matte and the slag are tapped periodically. A flash smelting furnace is depicted in Figure 1.

Jan 1, 2019

By Les F. Sawatsky

Surface drainage, particularly mine closure drainage, must be properly considered during all stages of mine planning because it presents constraints that are critical to economic mine operation, minimizing environmental impacts and ensuring compliance with government regulations. Deficient mine site drainage increases costs of operation, causes unnecessary environmental impacts and may result in regulatory violations. The scope of this paper includes stream diversions around mine areas, drainage systems within the mine disturbed footprint, and closure drainage works to control surface water, ground water, erosion, sedimentation, and seepage discharges following mine operations. Developing selfsustaining drainage facilities upon mine closure, requires a mine plan that develops appropriate topography and constructed drainage courses that replace the function of pre-disturbance drainage systems without aggravated erosion and deterioration. Drainage criteria, particularly closure drainage criteria, represent important constraints on mine planning and are best considered by integrating drainage features into the mine plan well in advance of mining activities. Integrated mine planning by a multi-disciplinary team is recommended to achieve closure objectives at minimum cost and maximum effectiveness The geomorphic approach to channel design is an effective means of providing a drainage system that has the appearance, function and longevity of natural systems. By incorporating this technique into closure drainage planning, mine operators can construct sustainable (walk-away) drainage systems that require little or no maintenance in the long-term. This paper presents a process by which drainage criteria and associated mine plan constraints can be integrated into the mine planning process. This paper outlines the process for detailed design of drainage facilities, particularly closure drainage systems that are designed by the geomorphic approach.

May 1, 2009

By X. Shi

Magnesium, the lightest structural metal, has not yet been considered as a serious contestant for automotive use due to its weaknesses in corrosion. Electroless nickel-boron alloys are well known for their corrosion resistance and hardness. An electroless nickel-boron layer was successfully deposited first on the chemical conversion pre-treated AZ31 alloy and also on the Ni-P coating which was deposited on the conversion coating. The electroless bath contained nickel sulphate and dimethylamine borane (DMAB) as main salts and the samples were activated by a 5 g/L AgNO3 solution before the electroless plating process. The presence of the conversion coating between the nickel coating and the AZ31 substrate acted as a barrier and prevented corrosion of the alloy. The morphology of the nickel-boron layer was studied using SEM. The crystal structure and the composition were examined by EDS and the hardness was measured. The corrosion behaviour of the nickel-boron layer deposited on the conversion coating and on the Ni-P coating was studied using potentiodynamic polarization in a 0.5M NaC1 solution. A saturated standard calomel electrode was used as a reference electrode. The results show that the nickel-boron coatings had a significantly better corrosion resistance than the AZ31.

Jan 1, 2006

By E. Gervais

"In today's marketplace, heavy competition between materials is the norm. This is particularly true f or the base metals, which are being increasingly challenged by new or improved materials in all traditional applications. Current usage of base metals results from a combination of a metal's intrinsic properties, and technology. The future of the base metal industry rests with innovative, high-quality product development, its ability to take advantage of the results of worldwide, massive material R&D investments, and with the dynamism and effectiveness of its market development programs.The ZA casting alloys program is an illustration of the zinc industry’s efforts to protect and expand its market position in the casting field through state-of -the-art technological developments. The market potential f or these advanced engineering alloys is substantial, and their impact on traditional zinc die casting alloy consumption is particuarly important. The ZA alloys, in offering increased performance through zinc castings produced at low cost and by a wide range of moulding processes, have unlocked a multitude of new end-use applications.Following a review of the development of ZA alloys, of their key properties and of their performance characteristics, the numerous challenges that the alloys present to the zinc industry and to the R&D community are discussed.IntroductionZinc is anodic to steel and has a low, uniform rat e of corrosion; it has a low melting point, can be cast with precision , and is readily finished. In addition to its use in protecting steel and in the production of a wide range of castings, zinc is employed : (1) to produce brass, high-strength aluminum alloys and magnesium die casting alloys, (2) in the wrought state for coinage and in building products, particularly as roofing materials , and (3) as an oxide, in the rubber industry, in ceramics, glass, cosmetics, pharmaceutical products and as the starting materials for many chemicals.Zinc die castings are produced with accuracy at high speed, at low cost, are easily finished and have excel1ent mechnical properties . Car fuel economy, changes in automobile styling, competition from other materials, increased sophistication of design and miniaturization have all led to a dramatic change in the volume of zinc consumed for die-casting applications. This has been particularly notable in the United States. Throughout the 19505 and the I960s, casting was the fastest growing major use of zinc; it was firmly established, accounting for 35% of the total zinc consumption(1), By 1983, the volume of zinc being purchased for casting applications had dropped to less than 20% of all zinc consumed in the United States. In the western world(2), consumption for zinc casting application s is currently at about 15%; being nearly equal to the zinc consumed by the brass industry. Coating applications dominate with a consumption of more than 40% of the total market."

Jan 1, 1987

By S. Koppalkar

ABSTRACT: The development and evolution of the gravity recoverable gold (GRG) test procedure at McGill University is reviewed in this paper. Since the late 1980s, the research group led by the late Professor André Robert Laplante at McGill University has undertaken fundamental studies and applied research of the Knelson concentrator to develop a sustainable method of estimating GRG. Historically, a concept of “free gold” was used, and it was de?ned as the gold that could be separated and recovered from gold ore by amalgamation. Due to health and safety hazards, the practical use of amalgamation has declined. Around 1994, a methodology using a 3-in Knelson concentrator to measure gravity recoverable gold was established at McGill University. As a result of more than 10 years of improvement and optimization, this technique has become a standard method of evaluating GRG for gold ores, gold plant streams and platinum group metals. By 2006, about 200 GRG tests were carried out at McGill University on ores from all over the world. Recently, a modi?ed version of the GRG test (a simpli?ed test) was developed to provide a quick and rough estimate of the GRG in a sample; this simpli?ed test has the advantage of reduced mass, processing time and cost. To recognize and honour the contributions made by the late Professor Laplante towards the establishment of a standard test procedure for assessing gravity recovery potential, the authors propose that the GRG test be named after Laplante.

Jan 1, 2010

By S. Koppalkar

ABSTRACT: The development and evolution of the gravity recoverable gold (GrG) test procedure at McGill university is reviewed in this paper. Since the late 1980s, the research group led by the late Professor André Robert Laplante at McGill university has undertaken fundamental studies and applied research of the Knelson concentrator to develop a sustainable method of estimating GrG. Historically, a concept of “free gold” was used, and it was de?ned as the gold that could be separated and recovered from gold ore by amalgamation. Due to health and safety hazards, the practical use of amalgamation has declined. around 1994, a methodology using a 3-in Knelson concentrator to measure gravity recoverable gold was established at McGill university. as a result of more than 10 years of improvement and optimization, this technique has become a standard method of evaluating GrG for gold ores, gold plant streams and platinum group metals. By 2006, about 200 GrG tests were carried out at McGill universityon ores from all over the world. recently, a modi?ed version of the GrG test (a simpli?ed test) was developed to provide a quick and rough estimate of the GrG in a sample; this simpli?ed test has theadvantage of reduced mass, processing time and cost. to recognize and honour the contributions madeby the late Professor Laplante towards the establishment of a standard test procedure for assessing gravity recovery potential, the authors propose that the GrG test be named after Laplante.

Jan 1, 2010

By W. O. Karvinen

"In the Timmins area, a close spatial and chronological association exists between gold deposits and two major stratabound carbonate-rich members and related quartz-feldspar porphyries. Synvo/canic and metamorphogenic are the two main types of mineralization recognized. Synvolcanic ores include the stratiform quartz-ankerite ""veins"", pyritic carbonates and chert-carbonate-tuff sedimentary rocks and epigenetic ventrelated breccias and stringer zones. Metamorphogenic ores consist of quartz-carbonate fracture fillings in dilatant zones developed during various phases of regional deformation and metamorphism. They are classically epigenetic in character.The evidence suggests a primary syngenetic enrichment of gold on the ocean floor and in vent areas during submarine felsic volcanism and related exhalative-hydrothermal activity followed by further enrichment into quartz-carbonate stockworks during regional deformation and greenschist metamorphism.Although normally thin (a few hundred metres), carbonate members in Archean volcanic terrain represent intense hydrothermal activity which could have transported and enriched gold. They should be used to locate fossil vents and structurally favourable zones where economic concentrations of gold may be found."

Jan 1, 1982

By Rob Boom, Yasuyuki Tozaki, Frank M. Wheeler

Selection of a suitable site for a metallurgical plant is crucial for the success of the business case. For a brownfield project, with the decision to locate the project on a site with existing production facilities and activities, the selection of the site has been made. For a greenfield project, important economic and logistical considerations include proximity to primary and secondary resources and/or to the market, infrastructure, and access to energy and water. National and regional aspects, including the social license to operate, can be decisive in final site selection. Key to recruiting and retaining a labour force are proximity to urban areas, along with weather and health conditions at the site. Risk factors include site geotechnical parameters and topography, contamination, as well as probability and types of potential natural disasters.

Jan 1, 2015

By John E. Callahan

"A stream sediment geochemical survey covering an area of 13.000 sq. km near Churchill Falls. Labrador. was conducted for Brinex (British Newfoundland Explorations Ltd.) prior to partial flooding by the Churchill Falls power project. Stream sediments (minus 80-mesh) were analyzed for Cu, Pb, Zn, Ni, Ag, Mo. U and Mn, and the heavy mineral, nonmagnetic fraction (minus 60-mesh) for Cu, Pb, Zn, Ni, Ag, Mo, Ba and Mn. A binocular examination of the concentrates for sulphides and pyrope garnet was done on the heavy mineral concentrates. The concentrates were also examined for fluorescent minerals.Two distinct areas with high trace-element values indicate the need for follow-up studies. The first is in an area of gabbro erratics containing massive and disseminated sulphides (pyrrhotite, pyrite and minor chalcopyrite) on the western edge of the survey area along the Esker Road. The second, largest area (several hundred square kilometres) is anomalous in U and Mo and associated with felsic intrusives (Red Wine Complex?), syenites. granite gneiss and sedimentary rocks (Seal Lake Group?).The binocular study showed that almost 15% of the heavy mineral concentrates contained pyrite and no other sulphides. This indicates that this technique may be worthwhile in determining the presence of sulphide minerals in stream sediments from glaciated environments. The only fluorescent mineral observed in the study was zircon."

Jan 1, 1981

By B. Haneman, J. A. Gorst, W. Slabbert

"The Bayer process involves the digestion of bauxite in caustic liquors at high temperature and pressure. Typically the digestion section of the plant involves the heating of liquors up to the digestion temperature followed by flashing of the digestion product to atmospheric pressure with the flashed steam used to pre-heat the incoming cold slurry. Despite the heat recovery, the digestion process is a high consumer of energy. The application of tube digestion technology in such plants has resulted in significant improvements in refinery energy efficiency with associated benefits of process simplification and refinery flow sheet capital cost reduction. This paper reviews the potential application of this technology to other metals within the non-ferrous industry.THE BAYER PROCESSA typical Bayer flow sheet is shown in Figure 1. The raw feed material bauxite (containing aluminium hydroxide as gibbsite Al(OH)3 and boehmite AlO(OH)) is digested in caustic liquors (caustic soda is the solvent) at high temperature and pressure. This process extracts the alumina and silica and any carbon present on the ore. The slurry is then flashed down to atmospheric condition allowing for heat recovery from the flashed vapour and producing slurry supersaturated in alumina.Following the digestion process the mud is removed via thickening and then pressure filtration to remove fine particulate and produce a clarified liquor with dissolved alumina in solution. The resulting pregnant liquor is then cooled allowing the alumina in solution to precipitate as aluminium trihydrate Al(OH)3. The precipitated hydrate is then filtered and washed and classified into fine and coarse fractions. The fine material is returned to the precipitation process as seed while the coarse fraction is calcined at high temperature to produce alumina. The filtrate from the filtration process (spent liquor) is then heated by the incoming pregnant liquor before being fed to an evaporation process which produced the strong caustic liquor required in the digestion process. Finally, the mud from the thickening process is washed to recover caustic and then fed to tailings ponds. The washer overflow is then mixed with the digester product to increase super-saturation."

Jan 1, 2012