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By D. J. Wesolowski, D. A. Palmer, P. Bénézeth, S. Hilic

The equilibrium solubilities of gibbsite, Al(OH)3, and boehmite, A1OOH, have been extensively studied in our laboratory from 30 to 90°C, and 100 to 300°C, respectively, to ionic strengths of 5 mol.kg-1 (NaC1) over a wide range of pH. The resulting solubility constants have been treated with consistent empirical models that incorporate appropriate experimental data taken from the literature. These studies were initiated in part to understand and quantify scale formation in geothermal fields as a result of fluid re-injection from electric power generating plants. Most of the experimental results were obtained through application of a unique potentiometric method that allows for rapid, precise measurement of the in situ pH and allows the approach to equilibrium to be monitored from under- and super-saturation. The experimental program was extended to deal with more basic solutions (e.g., five molal NaOH), in which the dissolution of boehmite was measured for application to the refining of bauxite by the Bayer process. More recent results in strong caustic solutions at temperatures below 90°C were obtained to investigate the dissolution of aluminum-containing sludge from holding tanks at the Savannah River waste reprocessing site. In this case the solubility enhancing effects (kinetic and equilibrium) of triethanolamine were also established and quantified. Finally, potentiometric solubility experiments were conducted (50°C in 0.l mol-kg-1, NaCl) on aluminum alloy sheets to identify mainly the nature of the aluminum oxide/hydroxide surface layer formed under these conditions.

Jan 1, 2004

By J. Ipinza, J. P. Ibáñez, Casas J., S. Cortés

Copper powder generated during the treatment of electro-metallurgical bleeds by reactive electro- dialysis (RED) had totally reduced the content of ferric ions in acidic synthetic electrolytes (Cu (II)- Fe (III) – H2SO4). In batch and columnar experiments 100% of the ferric ions were reduced to ferrous ions with an extremely high kinetics. A preliminary conceptual design for reducing ferric ions based on an integrate RED- Column for treatment of electro-winning bleed system is discussed. This system is able to recover simultaneously sulfuric acid and copper powder, which will reduce ferric ions. INTRODUCTION It is well known the negative effect of ferric ions in the copper electro-winning process. The increase of ferric content in the electrolyte reduces the current efficiency, i.e., there is an increase in the energy consumption, and changes the surface morphology of the copper deposit (Das, Gopala & Krishna, 1996; Vargas & Parra, 2013). The increase of the specific energy consumption due to the loss of current efficiency occurs by the reduction reaction of ferric to ferrous ions in the cathode, at the anode the ferrous ions are slowly oxidized to ferric ions (Shaw, Dreisinger, Lancaster, Richmond & Tomlinson, 2004). To control the level of iron in the electrolyte, bleeds are needed; this bleed electrolyte containing copper, sulfuric acid, cobalt, iron and other impurities normally is waster, which increased the production cost of the plant (Milbourne, 2002; Mckevitt & Dreisinger, 2009). Then, permanent efforts oriented to treat those bleeds to avoid losses of valuables components are made; among them are use ion exchange resins (Shaw et al., 2004; Mackevitt et al., 2009), chemical precipitation (Izadi, Mohebbi, Amiri & Izadi, 2017) and electrodialysis (Cortés, Ipinza & Ibáñez, 2013). The last one allows to the simultaneous recovery of sulfuric acid and copper powder. If one of the valuables obtained by treating the bleed can be used to reduce ferric ion concentration in the electrolyte could be an important asset. This issue at laboratory scale is reported in this work, the use of copper powder, generated by reactive electro-dialysis when treating synthetic acidic electro-metallurgical bleeds, for reducing ferric ions in acidic electrolytes.

Jan 1, 2019

By S. Ando

The fatigue crack growth behavior of magnesium single crystal has been investigated, CT (compact tension) type specimens with different notch orientations were prepared. In the case of notch plane and direction are (1-210) and [10-10], fatigue crack propagates parallel to notch, From TEM observation, it is found that pyramial slips occures at the crack tip. When notch is normal to basal plane, a fatigue crack propagates [0001] and parallel to basal plane depending on stress intensity factor range, In the case of notch parallel to basal plane, a fatigue crack propagates through straight route with some {10-12} twin, Fatigue crack growth rate, da/dN of A- and B- specimen is lower than F-specimen with crack parallel to basal plane.

Jan 1, 2004

By A. Warczok

Metal losses in discard slag are the main factor determining overall recovery. The metals are present both in dissolved form and as matte or metallic inclusions, varying in size from 2 to 1000 µm. Pyrometallurgical slag cleaning usually consists of heating the slag, reduction of oxides and settling of matte/metal droplets. Heating the slag decreases viscosity and accelerates reactions. Reduction of magnetite liberates inclusions and facilitates co-reduction of dissolved metal oxides. A significant amount of the matte and metal is present as very fine metallic inclusions, too small for settling. The coalescence of these matte or metal inclusions is required to remove them from the slag. The developed new concept of slag cleaning combines DC furnace technology with an extra magnetic field for vigorous slag stirring, enhancing mass transfer to the reductant surface, accelerating the rate of reduction, and destabilizing the emulsion of matte or metal inclusions. Intensive slag stirring increases the probability of collision of inclusions, will accelerate their growth and will therefore improve settling. The process is carried out in a patented DC channel furnace, where the liquid metal or matte layer acts as a cathode and the floating coke bed on the slag surface is the anode. In the first part of the furnace, a superimposed magnetic field induces a Lorentz's force causing the slag to start an intensive circular motion. The next furnace zone does not experience any stirring and is dedicated for quiet sedimentation of the inclusions. A mathematical model of gravitational coalescence combined with forced slag motion showed the possibilities of effective removal of copper matte inclusions. The results of laboratory pilot scale tests of continuous slag cleaning showed fast slag reduction and confirmed the improved matte removal from the slag. Conceptual analysis shows the potential use of the technology in various other non-ferrous industries, like for example nickel plants. It is also possible to use this technique batch wise.

Jan 1, 2007

By W. W. Rudolph, L. N. Trevani, P. R. Tremaine

UV-visible spectroscopy, Raman spectroscopy, and vibrating tube densimetry have been used in our laboratory to determine equilibrium constants of aqueous species at temperatures as high as 325 °C. The UV-visible and Raman spectra of solutions containing metal complexes and ionized acids or bases can be used to yield formation constants by applying curve fitting methods to resolve the contribution of each species. Colorimetric pH indicators identified by Johnston and coworkers at the University of Texas (Austin) provide an alternative means of determining ionization constants and the pH of complex mixtures. High precision density measurements over the same range yield standard partial molar volumes, which are key parameters for "equations of state" for aqueous species. Examples are given for the copper-ammonia system, simple carboxylic acids, and the iron-sulphate system.

Jan 1, 2004

By Xiang Yu

Hong Kong has a dense distribution of utility services laid under its road network. Utility undertakers frequently demand road openings to install new services and/or maintain existing ones. Road openings can cause troubles to the road network and negatively impact the public interest. Highways Department is responsible for managing road openings in Hong Kong under the Land (Miscellaneous Provisions) Ordinance. Highways Department has spent a lot of efforts to computerize excavation permit processing and utility management. The computerized system has gone through several generations and the current one is called the excavation permit management system (XPMS). On the one hand, the XPMS handles various excavation permit processing functions including permit application/approval/refusal/issuance/extension/termination, fees/costs, permit conditions, and permit period assessment; on the other hand, the XPMS accounts for some important utility management issues such as spatial check, coordination of multiple openings, traffic management, audit inspection, and defect liability. This paper discusses how the application, coordination, and other administrations of an excavation permit are eased by using the XPMS in Hong Kong. Background information such as the governing legal and regulatory framework, and Highways Department?s administrative structure is introduced. The system architecture and advantages of the XPMS are presented. The work procedures and various functions of the XPMS are studied in detail.

Aug 1, 2013

By N. Saracoglu, J. P. Golightly, R. H. Wallis, J. J. Brummer

"The McClean uranium deposits are located 11 km west northwest of the Rabbit Lake Mine. Their average grade is 1.8 % U3O8 , and they contain 6. 350 tonnes of uranium oxide in seven pods of variable grade and mineral assemblage. They are hosted by both basal Athabasca Group and the regolith developed on the underlying crystalline basement. The major mineral facies are: sulphide, arsenide, 'bleached', and hematite, with the important uranium minerals being coffinite, uraninite and pitchblende. Abundances of carbon and sulphur isotopes are consistent with their derivation from pyritic graphite in basement gneisses. Isotopes of oxygen and hydrogen suggest equilibration at temperatures of about 200°C. Ar39/ Ar40 age determination of illite associated with ore suggest mineralization began about 1300 m.y. ago and that significant alteration had ceased by about 1170 m.y. ago though Pb/ U data suggest the deposits continued to evolve into the Mesozoic.IntroductionThe McClean deposits lie on the eastern side of the Athabasca Basin of northern Saskatchewan where they are part of a cluster of uranium deposits lying west of Wollaston Lake (Fig. 1). The general stratigraphy is schematically portrayed in Figure 2 which emphasizes that mineralization is hosted by both the Athabasca Group and the underlying regolith and also that the deposits are preserved at depth and have not suffered from preand post-Pleistocene weathering and erosion. This circumstance, combined with their simple shape and the presence of seven separate zones of mineralization (pods) allows a description, based on over 450 fully cored drill holes, to be made of the wide variation in chemistry, grade, alteration patterns and position relative to the sub-Athabasca Group unconformity. Ar39 / Ar40 age determinations have been made of illites associated with regolith, Athabasca Group and mineralization and studies are in progress on C, S, 0 and H isotopes of mineralized material and host rocks. Only some of these data have been published; Brummer et al., (1981); Golightly et al., (1982); Bray et al., (1982); and Saracoglu et al., (1983). The only other published data on McClean geology are by Tremblay (1982, 1983)."

Jan 1, 1986

By A. Banerjee, J. P. Weiler, J. Jekl, J. T. Wood, R. Berkmortel

"The work presented here is part of an ongoing project designed to develop predictive capabilities of the local mechanical properties, and thus, structural behaviour of a thin-walled high-pressure die-cast AM60B magnesium alloy component. This work focuses on developing correlations between process parameters and local microstructure. Numerical simulations of the die filling and solidification behaviour of the AM60B component were used to estimate local process parameters such as solidification rate, temperature gradient, filling velocity, etc. These estimated parameters were used to establish semiempirical correlations with measured VALUES (of the local microstructure measured in regions throughout the component of different solidification conditions. INTRODUCTIONHigh-pressure die-cast magnesium alloys are experiencing increasing use in structural automotive components. A strength-to-weight ratio comparable to steels and its ease of castability allow for these alloys to be utilized in such capacities as instrument panel beams, seat and door frames, and engine cradles, among others (Gjestland and Westengen, 2007). However, the current use of these alloys is limited due to variations in local mechanical properties. These local property variations restrict part designers to assume lower than actual properties, resulting in larger sections, thus diminishing the light-weighting advantages of magnesium alloys. If these local property variations could be predicted, part designers would be able to optimize die-cast magnesium alloy components and fully take advantage of the light-weighting capacity of these materials.The work presented here is part of an ongoing project aimed at developing predictive capabilities of the local mechanical properties, and bulk mechanical performance, from variations in local microstructure, and ultimately from local process parameters in die-cast magnesium alloys. This project, unique in its nature, is based upon the results determined from fifty sequentially cast AM60B magnesium alloy instrument panel beams provided by Meridian Lightweight Technologies (shown in Figure 1)."

Jan 1, 2012

By M A. Notte

Sand casting of steel is a process that offers the greatest design flexibility and highest metallurgical versatility. However, competition from other methods of fabrication is quite keen, constantly forcing the steel casting industry to the production of better quality castings at lower costs. New methods and materials have been put to use in the last ten years by foundries everywhere. This paper, in the form of a progress report, deals with new methods, processes and materials used by Canadian steel foundries for regular production, as well as with developments still in the initial but promising stages. T HE casting of steel to shape is the most direct method of producing steel parts in their final form. It is a basically economical process both as to cost and production time; it is also a process that offers design engineers the greatest flexibility and highest metallurgical versatility. In North America, the steel casting market has a normal yearly sales volume of 1,500,000 tons. In decreasing order, the largest customers are the railroads, construction machinery and earth-moving

Jan 1, 1965

By E. Lovera

ABSTRACT: The current study analyzes the feasibility of an odd operation: to obtain, using a properly tailored drilling and blasting scheme, blocks suitable for the production of dimension stone from tunnel driving. Clearly, a compromise must be found between the rate of progression and the achievement of workable blocks. As a case study, a civil work under consideration in northern Italy was examined. The work was planned to cross a conglomerate that has traditionally been locally exploited for the production of highly prized paving and lining stones with excellent strength and aesthetic features. Natural exposures and mined-out quarries were available for tests. The relevant rock data are given, blast designs are shown (within the limitations of contour accuracy), and the test program is described.

Jan 1, 2011

By Mark B. Thorpe

Golden Star Resources started gold mining operations in Africa in 1999 after 15 years of exploration in South America. At the time, the approach to local assistance was through "alternative livelihood" programs and the donation of infrastructure to local communities. This was initially successful with local community support. However, with time and on reviewing the implemented projects, it became evident that the success was limited and many if the projects were either poorly used or in disrepair. Through a review of the options, we decided to develop a community assistance model driven by the communities themselves, while keeping control of the finances and the actual construction of the projects. Through the formation of the Golden Star Development Foundation, we began to support community driven projects for local economic development. The evolution of economic development projects continued over the next several years with the addition of project requirements for partnerships with government, and finally an evolution to a partnered turn-key piece of infrastructure that we hand over to an agency for operation and ongoing maintenance. We are currently working with outside partners to further our economic development activities in Ghana to the benefit of our stakeholders.

May 1, 2011

By B. Westin, G. Voicu, C. Daoust

Orogenic gold deposits represent a major class of deposits that are found in various rock types of various ages. Those deposits show a strong structural control that usually complicates their interpretation at the regional and deposit scales. The Rosebel Gold district located in Surinam (South America) is hosted in a Paleoproterozoic greenstone belt of the Guiana Shield, and has been recently classified as one of those orogenic gold deposits. The gold district comprises eight distinct deposits located along three different structural trends and within different rock types. The mineralization is undefonned and shows a strong structural control characteristic of orogenic gold deposits. All the deposits of the Rosebel Gold district have been subject to a detailed structural analysis that has led to the elaboration of a new structural model for the whole gold district, which is now differing considerably from the previous models. This characterization had direct implications at three different scales. 1- While the older models were considering some areas of the property as gold-barren, the new structural model has led to recent exploration campaigns which have revealed positive results. 2- At the deposit scale, the comprehension of the various vein systems and of the folding of the host rocks has helped the establishment of optimized drilling campaigns. 3- At the mining scale, the comprehension of the architecture of the veins helps for the elaboration of optimized mining method. This study thus shows that the structural analysis of orogenic gold deposits is critical, and should be a priority for exploration and production in any mine.

Jan 1, 2011

By S. Theobald

Semi-finished copper and copper-alloy products are typically produced by casting, subsequent hot rolling or extruding and further cold working by rolling and drawing. The technological properties of the products depend not only on the chemical composition of the alloys but also on process parameters such as annealing conditions and degree of deformation. In each production step, measuring and control technology is an important tool for optimizing processes and ensuring constant high quality. This paper follows the product all the way from testing incoming scrap packages, chemical analysis of melts, mould level control in casting, non-destructive testing technologies in cold forming processes, controlling geometrical properties in the production process, to the final tests of technological properties. All test methods are focused on the applications and requirements of our customers, as the examples show.

Jan 1, 2007

By Marc Symbaluk

Core Programs Current ? Aboriginal Involvement Program ? Adaptive Forest Management / Forest History Program ? Grizzly Bear Research Program ? Natural Disturbance Program ? Foothills Growth and Yield Association ? Foothills Stream Crossing Program ? Fish and Watershed Program ? Caribou Landscape Management Association ? Social Science Program ? Local Level Indicators Program ? Communications and Extension Program ? Geographic Information Systems Program ? Mountain Pine Beetle Ecology Program In Development ? Climate Change Program ? Forest Community Program ? Water, Quantity and Quality Program (Water for Life) ? Circumboreal Initiative ? Yellowhead Ecosystem Management Group

May 1, 2008

By M. Uszko

The paper presents the conditions for determining the selection of methods for methane drainage in Polish hard coal mines. Various factors for the evaluation of methane drainage performance are used, including the methane drainage effectiveness ratio. However, as will be discussed there are limitations to the methane drainage ratio approach resulting from the characteristics of the deposits extracted in Kompania Weglowa S.A. coal mines.

Aug 1, 2013

By R. R. Dickson

Princess colliery, the largest mine operated by the Old Sydney Collieries, Limited, commenced operations in 1877. It was the first mine sunk in the Sydney coal field with the primary object of working submarine coal. Until 1925, coal was won by the room-and-pillar system. By that year, the depth of cover over the workings was 1,300 feet, and physical conditions had become such that it was impossible to extract completely the pillars formed by the working of the rooms. Because of this, the system of work was changed to longwall in the early part of that year. At first, an orthodox hand-pick method was used, with gate roads laid off at 50-foot centres and the mine cars loaded by hand directly on the longwall faces. Later in the year, the first machine-cut conveyor longwall faces were started.

Jan 1, 1946

By S. Litke

Elemental sulfur was stockpiled at the Mount Polley Mine for use as a source of sulfuric acid as part of research into leaching copper from oxide ores, but the project did not proceed beyond an initial pilot- scale evaluation. Since placement, the sulfur has oxidized and some sulfuric acid leached into the underlying rock. The reaction of the acid with these underlying materials has been studied as part of an evaluation of the effects of leachate from the pile. The rock underneath the sulfur pile is composed dominantly of primary and secondary alumino-silicates with less than 1% carbonate (calcite) and iron sulfide (pyrite). In its unaltered condition, the rock is classified as non-acid generating. Conceptually, it was expected the sulfuric acid would be neutralized by the rock to varying degrees resulting in a series of pH-controlled weathering fronts progressing from leached near the contact with the sulfur pile (pH <3), to active neutralization by silicates (pH 4–5), to active neutralization by carbonates (pH >7). The rocks underneath the pile were sampled to determine the extent to which the rocks had reacted and their long-term stability after removal of the acid source. INTRODUCTION When rock is blasted and excavated to facilitate mining ore, it is typically placed and stored on the surface in piles. The resulting drainage may have a neutral to basic pH (i.e., non-acidic drainage) or a low pH (i.e., acid rock drainage, ARD) depending on the mineralogy of the rock being stored in the piles. Acid- base accounting (ABA) can be used to characterise the two types of rock: potentially acidic drainage generating (PAG) and not potentially acidic drainage generating (NAG) (Price, 2009). According to Price (2009), NAG is defined as having an excess of neutralization potential (NP) in the rock in the form of calcium carbonate-like minerals when compared to acid potential (AP), i.e., a Neutralization Potential Ratio (NP/AP = NPR) greater than 2.0, whereas PAG is classified as having an excess of AP (i.e., an NPR less than 1.0). This is a conservative estimate and may be slightly modified depending on the mineralogy at specific mine sites. Rock with an NPR of 1–2 is also capable of generating acid (Price, 2009) and, depending on the mineralogy, may also be classified as PAG. Drainage from PAG material can generate acid immediately, or many years after it has been exposed to surface conditions. Disposal techniques depend on the category (i.e., NAG or PAG) and reactivity of the rock stored in the piles.

Jan 1, 2019

By V. G. Papangelakis, S. Peters

Pressure oxidation of refractory gold ores can be conducted on ores with high carbonate content using just water or water with alkaline reagents to promote fast kinetics, and suppress the formation of elemental sulphur and CO2. In this work, a fundamental study was conducted to explore the silica-pyrite interaction in the presence of calcium and sodium carbonate. It was found that an alkaline environment increases the pyrite decomposition kinetics on one hand, but on the other dissolves silica, which encapsulates the dissolving pyrite thus hindering ultimately its complete decomposition.

Jan 1, 2011

By D. Roy Eccles

A multi-element geochemical response, with contrasts of up to 29 times background, was obtained in soil above the Mountain Lake Diatreme, northwestern Alberta. The overall geochemical signature is indicative of an ultramafic source; geochemical responses contain elevated concentrations of Co, Cr,O, Cu and Ni with the presence of high Ba, Ga, HI, PO,, Rb, Ta, Ti and light rare earth elements suggestive ofa kimberlite or lamproite body. The shape, or morphology, of the enzyme leach-based geochemical signature over the Mountain Lake Diatreme combines moderately strong to strong oxidation halos, or a rabbit's- ear geochemical profile, with a sharply-defined apical geochemical profile. Because some Alberta diatremes discovered to date form positive topographic highs, the resultant geochemical signature may express the soil development profile that forms directly on top of kimberlitic and lamproitic bodies. The enzyme leach technique, which has proven to be a useful tool in base metal, precious metal and petroleum exploration, may have a significant impact on exploration for kimberlite, lamproite and related rocks in Alberta by providing industry with a useful and cost effective tool to probe blind and/or buried anomalies identified by airborne and ground magnetic surveys in areas of glacial overburden.

Jan 1, 2001

By Fr. -W. Bach

In the past years the enormous weight saving potential of magnesium sheet has been demonstrated by various research projects all over the world. It has been shown magnesium flat products can benefit automotive, aviation, machine tool and consumer electronics industries. Major material problems such as poor formability, corrosion resistance and high production cost still inhibit the application of magnesium sheets in large scale production. The present contribution outlines achievements in casting and rolling technology. The authors developed an adapted strip casting process in which near-net-shape rolling feedstock of several wrought alloys has been produced. During the rolling process, various parameters were varied in order to modify the microstructure and surface quality of sheet. Several temperature cycles, strains, lubricants, roll surface structures and roll coatings have been analyzed. The sheets were examined and tested in deep-drawing experiments. Suitable rolling schedules have been developed for standard and modified wrought alloys. The study concludes with an overview of current industrial solutions and an estimation of the potential cost savings that might result from the adaptation of the process that has been developed.

Jan 1, 2006