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By I. A. Menshikh, S. A. Kotov, N. L. Shinkarkin

All the cycle for conversion of natural and reprocessed uranium of ROSATOM’s “TVEL” Fuel Company is concentrated at the Siberian Chemical Plant. Conversion capacities are located on two sites, i.e. the Radiochemical Plant, which refines feedstock, and the Conversion Plant, which produces uranium oxides and uranium hexafluoride. Liquid radioactive waste arising in the process, after pretreatment, is transferred to a dedicated national operator for underground disposal. Environmental strategies pursued by the Fuel Company involve the introduction of process solutions intended to eliminate liquid radioactive waste and convert it into a solid phase. In the 5–7 years coming, work will be performed to refurbish and upgrade conversion facilities of the Siberian Chemical Plant that will principally change its radioactive waste management scheme. This paper describes the current waste management scheme and sets out planned schemes for management of natural and reprocessed uranium waste, which will be implemented in the refurbishment of conversion facilities of the Siberian Chemical Plant. The new technologies for the management of liquid radioactive waste from uranium conversion described in the present paper have an undeniable advantage over the current technology mainly due to significantly less environmental harm.

Jan 1, 2020

By W. N. Hamilton

"Evaporites abound in the Western Canada sedimentary basin, recurring throughout the stratigraphic column and widely scattered over the basin region. Alberta, situated centrally over the basin, includes many of the evaporites within its borders, but only a few have the right geological conditions to form potential economic deposits of salt or gypsum. These include the Middle Devonian Elk Point Group and related evaporites, Upper Devonian Wabamun Group-Palliser Formation evaporites, and evaporites of the 'Triassic Charlie Lake and Whitehorse formations.Salt deposits underlie almost half of Alberta. The major deposits belong to the Elk Point Group, which includes thick salt units in the Lotsberg, Cold Lake and Prairie Evaporite formations. Another, younger salt deposit in the Wabamun Group has only local distribution. Elk Point salts have a maximum aggregate thickness of 430 m in east-central Alberta. The deposits deepen southwestward across the province, from minimum depths of210 m at Fort McMurray to 1820 m at Edmonton.The thickest, most extensive salt deposits are the upper Lotsberg and Prairie Evaporite salts. Both have excellent development potential. The upper Lotsberg is up to 150 m thick, consists of clear, very coarse crystalline halite with only minor impurities, and has a notable lack of non-salt strata in its succession. Analytical data for the Lotsberg Salt show extraordinary chemical purity. Prairie Evaporite Salt differs lithologically from the Lotsberg in having a significant non-salt component. The deposit is up to 200 m thick and consists of medium crystalline halite, brownish coloured and cloudy as a result of finely dispersed impurities. The main impurities-shale, anhydrite and dolomite-are most prevalent as interbeds in the salt succession, ranging from very thin laminae to beds several metres thick. Although of lesser purity, the Prairie Evaporite Salt is shallower, thicker and more extensive than the Lotsberg and the salt quality is quite acceptable for most industrial uses."

Jan 1, 1982

By Mario Giavani

"IntroductionBy the 1980s, the continuous casting process had almost replaced the ingot casting of steel in Japan, Europe and North America. While economic benefits were probably initially the prime motivator, the transition rapidly proved that continuous casting in conjunction with ladle metallurgy offered a much greater degree of process control and made possible routine steel specifications not previously available.This new technology demanded improved procedures for the quantitative addition of the required metallurgical reagents, especially as regards the more volatile or toxic elements such as calcium , boron, carbon, sulphur, lead and tellurium. The injection of a thin steel tube containing the additive into the metal bath of a ladle refining station offers the best procedure for this. In the industry this has been referred to as ""Cored Wire "".Operators using this technology find that they are faced with balancing the injection speed against the small cross section of the tube to feed the required amount of reagent within the short time span available to the operation. Large-ladle shops requiring major quantities usually resort to multiple machines and high speeds. Many machines approach a maximum feed rate of 400 m/min. Higher speeds exceed the melting rate of the system, and the ferro static buoyancy of the tube will cause it to coil up the ladle wall and possibly resurface into the slag layer, and even eject itself above the surface. Under these conditions, exact control of element recovery becomes difficult, especially with the commonest addition, calcium silicon alloy.Many experts are persuaded that the final melting position of the carrier tube has major importance in establishing consistent element yield to the bath.For instance, the vapour pressure of calcium at l500 °C is close to I bar. Reaching a melting depth sufficient to accommodate this value is considered to be critical to achieving an acceptable and reproducible yield.Many studies have elaborated semi-empirical formulae to establish the melt zone depth, connecting this value essentially to the diameter of the tube , the injection rate and the superheat of the steel. The author's experience in steelmaking could not confirm such formulae in many cases, and he set about to develop a mathematical model which would be useful in addressing this problem, taking into account the several parameters which will regulate the behaviour of a filled tube immersed in molten steel."

Jan 1, 1991

By C. H. Stockwell

THE Eastern Townships of Quebec have been the chief Canadian source of chromite. Production, however, has never been large and, except for a period of steady but small output between 1894 and 1909, mining has been active only in war time. The known deposits are too small or too low grade to compete with overseas sources in normal times. During the last war, shipping difficulties and a greatly increased demand in the United States resulted in high prices and a ready market for low-.grade material. The Quebec chromite industry flourished and played an important part in relieving the wartime shortage. Shipments in 1918 .amounted to 15,600 tons of crude ore and 6,400 tons of concentrates. At the outbreak of the present war it was natural to turn again to the Quebec field as a possible source of this strategic mineral. Some of the old properties have since been opened by private and government money and some new deposits have been found. Total mill capacity is 750 tons per day, as compared with 200 to 300 tons in 1918. During 1940, 1941, and 1942, about 85 chromite deposits were examined by the Geological Survey in a belt 100 miles long and up to 7 miles wide. A part of this belt, about 35 miles long, in which the geological features ?were not well known, was mapped on a scale of 1/2; mile to an inch.? Small ..areas around some of the deposits were mapped in detail, on scales of 20 to 200 feet to an inch. Some geophysical work was done but did not result in the discovery of ore. Prospecting by stripping and trenching was then undertaken and chromite ore was uncovered at several localities. The above work was done by the writer and by J. W. Ambrose, who has kindly contributed his results for incorporation in this paper. Y. O. Fortier actd as assistant in the geological work and, in 1942, was in charge of a sub-party engaged in geological mapping. The author is indebted to H. C. Cooke and J. W. Ambrose for reading the original manuscript and for offering many helpful suggestions for its improvement.

Jan 1, 1944

By Gheorghe Marin, Franco Chiesa, David Levasseur, Bernard Duchesne

Over the past 20 years, pressure die casting has evolved to a point where structural parts can now be produced by this process. This has been made possible by the development of vacuum die casting and by the development of die-castable, low iron content alloys. This resulted in the production of low porosity, weldable die-cast parts on which heat treatment may be applied. In the present paper, the influence porosities on the tensile properties of as-cast A360 tensile test bars was evaluated. This was done by casting 24 clusters, comprising three 6mm diameter test bars each, in a 280T cold chamber pressure die casting machine after a steady dynamic equilibrium had been reached. Modeling of filling allowed to explain the differences in porosity observed in the 3 samples of a same cluster while the results of solidification modeling were related to the microstructure. Tensile samples were radiographed on a real time X-cube apparatus and separated into 2 lots: samples where no porosity defect were visible and samples with visible defects. By measuring the tensile properties of the 2 lots it was possible to quantify the drop in tensile properties brought about by porosity, which is the most common defect observed in pressure die-cast parts.

Jan 1, 2015

By V. Bazhko, V. Yahorava

The calcium sulphate waste stream of the wet phosphoric acid process, commonly called phosphogypsum (PG), contains the majority of rare earth elements (REE) initially present in the apatite feedstock. Mainly light and middle REE are present in PG and their total concentration ranges from 0.27% to 0.35% by mass. Worldwide, around 7 billion tonnes of PG have been produced to date at a current growth rate of 150-200 million tonnes per annum. In total, an estimated 21 million tonnes of REE are locked in PG waste dumps around the world. Due to the value of the REE contained in PG dumps a number of processes have been devised for their recovery. The majority of these processes applied complete or partial gypsum dissolution, but were deemed not viable due to high capital and operating costs. Mintek developed an alternative method for the recovery of REE from PG by applying Resin-in-Leach (RIL) technology. This technology was tested on PG sampled from dumps and current arisings from South African phosphoric acid production plants. The extensive testwork program included evaluation of various lixiviants and optimisation of lixiviant additions, optimisation of REE leach and adsorption conditions, batch equilibrium and kinetic adsorption tests, continuous RIL testwork and numerous variability tests. It was found that PG from different sources was highly variable, both in terms of REE recovery as well as physical properties of the material such as viscosity and filterability of the slurry. The recovery of REE varied from 15% to 80% depending on the origin of the samples. A high-level economic study indicated that at a price of >21 $/kg for mixed REE oxide product in conjunction with an overall REE recovery as low as 15% the economics of REE recovery from PG via RIL technology may already be favourable.

Jan 1, 2016

By David W. Mogk, Tamara Darsow, Macgregor L. Fogelsong, Robert M. Hunter, Frank M. Stewart, Edwin H. Abbott, Courtney A. Young

Abstract: Development of cost-effective techniques for recovering precious metals from their ores has been the goal of metallurgists for hundreds of years. Today, metallurgists are increasingly called upon to design processes for ores that are refractory to conventional recovery techniques. These challenges and the addition of environmental costs (including site remediation) to the total cost of mining have stimulated a search for alternatives to conventional processes, such as cyanidation. This paper describes the progress made to date in development of an innovative alternative to cyanidation, termed bisulfide leaching, for extracting gold, silver and platinum-group elements from refractory ores and concentrates. While bisulfide leaching can be implemented abiotically, significant benefits accrue from its practice as a bioprocess that integrates the steps of precious-metals liberation and extraction. In many applications, bisulfide leaching appears to offer significant advantages over the traditional cyanidation process. Dissolved bisulfide and hydrogen sulfide are much less toxic than dissolved cyanide and hydrogen cyanide. Recommended workspace exposure limits and harmful concentrations for hydrogen sulfide gas are higher than those for hydrogen cyanide gas. While the facilities required to practice the bioprocess on an industrial scale would be similar to that of cyanidation plants, chemical reagent costs could be 80 percent less. The bioprocess may also offer advantages in the leaching of ores and concentrates that are not amenable to cyanidation. For example, bisulfide leaching of ores containing carbonaceous material may produce higher gold recoveries if the "preg-robbing" characteristic of the material can be controlled biologically or with dissolved sulfide binding. Moreover, in that precious metals are much more soluble than base metals in bisulfide solutions, bisulfide leaching offers distinct advantages over cyanidation for selective dissolution of precious metals from base-metal concentrates. Thus, the bioprocess uses the natural sulfur cycle to mitigate pollutant production and to enhance precious-metals recovery.

Jan 1, 1998

Accountability for profit realized or lost, and responsibility for continued safe operation are the main impetus behind operator training. Efficiency in operation enables production at lower unit costs. An inefficient operation eats profitability of the operation, creating short term losses, and also affecting longer term viability particularly when commodity prices fluctuate and competition erodes market share. Safe operation and efficient operation are ultimately conjoined entities which may not be able to be sustained without dual effort. Training is a very valuable tool to engage operations in adopting more efficient and safe practices. Training requires time, facilities and trainers. One novel way of minimizing both the trainers and the facilities is through the use of Computer Based systems. Included amongst this are Computer based equipment simulators, following an identical philosophy as flight simulators used for pilot orientation and training for different aircraft types.

Feb 1, 2008

By T. Krumins, L. Zunti, R. Frischmuth

Mercury is known to occur in sulphide-bearing refractory gold deposits in the form of sulphide minerals or elemental inclusions. These deposits typically require an oxidative pre-treatment process, such as pressure oxidation or roasting, to achieve economic gold recovery. However, these processes also have the potential to liberate mercury, a portion of which may then be released to the environment through gaseous emissions. Mercury emissions from mine processing operations have been of particular interest in recent years, as governments impose lower emission targets and organizations adopt better industry practices to reduce the environmental and health aspects of releasing mercury into the environment. This paper describes various mercury removal technologies with respect to pressure oxidation gas handling circuits, with a focus on key design variables and technology selection criteria.

Jan 1, 2014

By Atsushi Sainoki

Blast vibration induced by mining activities, such as stope production blasts, could lead to the initiation of seismic events that inflict damage to mine openings. In this paper, the effect of stope production blasts on nearby fault is examined. First, validation of blast vibration attenuation is performed with a numerical model representing a single blast hole through comparison with that calculated from charge-weight scaling law derived from in-situ data. Subsequently, a mine-wide scale model with a fault parallel to a steeply dipping, tabular ore deposit that is mined out with sublevel stoping method is generated, and the stopes are extracted and backfilled with static analysis to simulate burst-prone conditions on the fault. Based on the stress states, dynamic analysis is performed, in which blast vibration is applied to grid points on a stope wall on the hanging wall side. This assumes 9 blast holes located close to the wall, and blast-induced particle velocities that consider the positional relationships between the assumed blast holes and the stope wall are applied. During the dynamic analysis, blast sequence is considered, and stress states and shear displacement on the faults are examined. It is found from results that, after a rise in normal stress on the fault due to compressive waves induced by the blasts, the normal stress decreases because of the reflection of the compressive waves on the fault. The reduction in the normal stress due to the reflected waves is found to be large enough to cause the fault to slip. The results also show that the level of normal stress eventually keeps decreasing with time as the blast sequence proceeds and that an increase in shear displacement on the fault is accompanied by a decrease in normal stress. This study clarifies the mechanism by which blast vibration causes the fault to slip. In addition, the simulation technique to apply blast vibration that takes into account blast sequence and the locations of blast holes to a stope wall is developed.

Aug 1, 2013

?Founded in 1969 by the Ruia family ?Diversified global business corporation with a balanced portfolio of assets in the manufacturing and service sectors; $15 Billion revenue in FY 2009-2010 ?Employs 70,000 people worldwide with offices in Asia, Africa, Europe and North America

May 1, 2011

By D. S. Conochie

The world is poised for rapid growth in consumption as large, less developed economies acquire greater wealth. It might be expected that there would be a corresponding growth in waste generation, but this might not necessarily be the case. The metallurgical industry has an excellent record of process development which has allowed it to provide a high tonnage supply of low cost, high quality metals. Environmental challenges have been faced and indeed the recycling of scrap iron through the electric arc furnace has made a massive contribution to cleaning up obsolete structures and equipment of past generations. Issues in waste generation and processing still remain, and the expectation for cleaner processing and environmental performance continues to rise. The waste impact of key process developments of the last century and the recent developments in metallurgical waste processing in Canada will be outlined. The potential to use state of the art design tools to produce the next generation of zero waste processes will then be explored.

Jan 1, 2004

By J. A. du Plessis, C. Dorfling

Selenium, tellurium and other precious metals (OPMs, namely Rh, Ru and Ir) dissolve in the final leaching stage of base metal refineries. Se and Te are typically removed from the copper sulphate leach solution by precipitation with sulphurous acid. Recovery of dissolved OPMs is desirable because it will reduce OPM inventory and losses. Thiourea is an effective OPM precipitation reagent, but yields insufficient Te removal. Copper is known to enhance Te precipitation when using sulphurous acid as precipitation reagent. The primary objective of this project was to evaluate whether simultaneous precipitation of Se, Te and OPMs using thiourea with metallic copper as precipitation reagents is possible. Batch precipitation tests were performed to evaluate the effect of temperature (50 – 70°C), thiourea addition (160 – 430% excess) and copper addition (2 – 8 g/L) on Se, Te and OPM precipitation. Increasing the temperature from 50°C to 70°C resulted in an average increase of 55.6 percentage points for Se precipitation and 13.5 – 23.5 percentage points for OPM precipitation. The copper addition did not have a significant impact on the precipitation behaviour. Increasing the thiourea addition increased the precipitation of Se and Te, especially when the copper addition was low; Rh and Ru precipitation also increased with up to 10 and 12 percentage points, respectively. Despite these observations, the precipitation of Se was significantly faster when no thiourea was added. It is not currently clear why thiourea appears to inhibit the Se precipitation by reaction with metallic copper. In general, Te precipitation was low (less than 30%) at the conditions investigated. Simultaneous precipitation of Se, Te and OPMs at temperatures below 80°C does not appear to be a viable option; a multiple stage operation for sequential removal of Se and Te with copper followed by OPM precipitation with thiourea would be required.

Jan 1, 2016

The rate of liquid copper deoxidation during top blowing of reducing flames has been investigated using a high capacity thermogravimetric unit at 1200 °C. For 1 kg copper samples, it was observed that the rate of deoxidation was proportional to the flow rate of the reducing reagent (H2 or CO). Under similar experimental conditions, it was found that H2 is more effective than CO even though both have similar thermodynamic potential to deoxidize liquid copper. The rate of deoxidation of liquid copper with reducing 0 2/CH4 flames was measured for 0 2/CH4 molar ratios of 1.5 to 2. The deoxidation rate depends on the 0 2/CH4 ratio and decreases as it approaches the stoichiometric ratio (02/CH4 = 2). Estimation of the rate of deoxidation of liquid copper with top blowing flames based on the thermodynamic composition ofH2 and CO in the product gases, agrees well with measured values.

Jan 1, 2007

By Magnus Evertsson, Johannes Quist

HPGRs have since introduced in the 1980s (Kellerwessel, 1993; Schönert, 1988), now become integral comminution units at several minerals processing plants around the world. Even though a lot of the initial issues concerning performance, availability and wear have been addressed and solved there are still phenomena and aspects which can be improved and understood further. Schönert and Sander (2002) presented experimental results and a mechanistic model including the internal force dynamics between the rollers and the compacted bed. They derived expressions for the pressure distribution involving most of the influencing terms and effects. However, in order to solve the differential equations several of the terms vanish by assumptions. The Schönert and Sander model reflects the experimental data in many aspects but the predicted shear force distinctly deviates from the experimental results at the angular position of the peak pressure level. This finding suggests that the particle to particle interaction and breakage process in the different zones seen in Figure 1 are complex and difficult to model using analytical models. A numerical modelling approach using DEM does not require the same amount of assumptions and simplifications of boundary conditions. Hence such modelling may provide further knowledge and vital understanding. In this paper the breakage process is simulated in order to investigate the shear slip behaviour and how it relates to different operating variables. A laboratory scale HPGR corresponding to the experimental setup used by Schönert (2002) have been modelled in EDEM (DEM-Solutions). The bonded particle model (BPM) is used for modelling quartz particles (Potyondy, 2004). The breakage model strength parameters are calibrated against interparticle breakage experiments in an Instron 400RD compression device. The contact model parameters are calibrated using calibration methods developed by Quist (2015). The floating roller dynamics are modelled using a spring-damper system. Results present insights regarding the interparticle slip behaviour as well as the frictional tangential force distribution on the rollers. The simulated roller pressure distribution shows good correspondence with previously reported findings in the literature.

Jan 1, 2016

By A. E. Moss

"IntroductionTHE WORLD-WIDE search for iron ore has been vastly accelerated during the past fifteen years .and Canada is playing a most prominent role in this prospecting boom. During this period, the search for .and development of iron ore deposits in Canada bas proven eminently successful and there is every indication that exploration will continue to be active for many years.This paper has been prepared primarily for the information of those who have bad little or no experience in iron ore exploration. For convenience, it is divided into three parts: ( 1) a brief discussion of the marketing of iron ores, with special reference to Canadian production; (2) a summary of the main features to be considered when prospecting for or evaluating a potential iron ore deposit; and (3) an outline of the methods and procedures used in the search for the direct-shipping iron ores in the Quebec•-Labrador iron ore field.The Iron Ore MarketDue to the tremendous tonnages of high-grade direct-shipping iron ore indicated in the iron ore fields of the Quebec-Labrador and Steep •Rock areas, it might be assumed that there would have been a sharp decline in iron ore prospecting in this country. On the contrary, the development of these two major fields, which must be classed among the world's greatest, has been responsible for much of the current activity. The search for high and medium grade magnetite deposits is being• conducted in many parts of the country and a number of these have reached the development stage. Production is being expanded from the known fields, such as Wabana in Newfoundland and Michipicoten in Ontario."

Jan 1, 1955

By M. I. Kalashnikova, Y. M. Shneerson, M. V. Keskinova

Interaction between mattes having various compositions and solutions with a wide range of free acid and non-ferrous metals concentration have been studied in terms of chemistry, mechanism and kinetics. The solution acidity and oxidizers to reducers ratio in the matte-solution-gas phase system have been demonstrated to be the major factors determining the process behaviour. It was found that the types of copper and nickel secondary sulphides resulted from nonferrous metals precipitation from solution, depend on of the solution and initial matte composition. Based on these studies, technologies of matte leaching and nonferrous metal precipitation in the form of rich sulphide concentrates are developed.

Jan 1, 2004

By Philippe Caudal

This paper presents a case study in which a slope failure was observed on the west wall of the LAB Chrysotile mine in the vicinity of the main ramp in January 2010. Airborne LiDAR results were used to evaluate slope geometry before and after the failure occurred. Back analysis of the failure was performed to assess rock mass properties at the slope scale using various numerical techniques: limit equilibrium, finite elements and fracture networks. The various approaches correlated well with field observations.

Aug 1, 2013

By José L. Carvalho

"Time-dependent swelling deformation of several shaley rock formations in Ontario is a wellknown phenomenon. In shales and mudstones with a higher salt concentration in the pore fluid than the ambient fluid, the outward gradient generates an osmotic pressure which acts as the driving force for swelling. The swelling phenomenon appears to be related to ion exchange between the rock porewater and the surrounding water.The swelling potential is expressed as the percent swelling strain that occurs per log cycle of time, in either the vertical (perpendicular to bedding) or horizontal (parallel to bedding) directions. In addition, the swelling potential is also noted to be stress dependent. In practice, therefore, the conditions required for swelling are (i) the accessibility to water, and (ii) an outward salt concentration gradient from pore fluid of the rock to the ambient fluid. The relief of in-situ rock stress during excavation serves an initiating mechanism (Lo and Micic, 2010).INTRODUCTIONTime-dependent swelling deformation of several shaley rock formations in Ontario is a well-known phenomenon. In shales and mudstones with a higher salt concentration in the pore fluid than the ambient fluid, the outward gradient generates an osmotic pressure which acts as the driving force for swelling. Swelling is also controlled by the inter-particle bonding; if the bond strength exceeds the osmotic pressure, swelling will not occur, and vice-versa. The bond strength can be reflected by the calcite content which forms cementation bond between rock particles."

Jan 1, 2015

By J. Bouchard, A. Desbiens, M. Maldonado, R. del Villar

ABSTRACT: Despite many years of practical applications in mineral processing plants, the potential of column flotation has still not been fully exploited. The challenge in measuring some key variables is certainly an important contributing factor to this situation. Reliable online measurement of variables, such as the froth depth, bias, gas hold-up, frother concentration, bubble surface area flux, and bubble size distribution, provides opportunities for the application of various advanced control strategies and real-time optimization based on an economic criterion. For several years, Université Laval’sLaboratoire d’observation et d’optimisation des procédés researchers have been working on these opportunities. This paper describes the most recent advances and current research trends.

Jan 1, 2011