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By B. Kenney

For SOFCs, composite cathodes comprising an electronically conducting electro¬catalyst (e.g. LSM) and an conically conducting electrolyte material (e.g. YSZ) are considered to improve the electrochemical performance by extending the active reaction zone to regions beyond the electrolyte-electrode interface, as in the case of conventional cathodes. Interpretation of experimental data for composite cathodes, however, is complicated by the mixed conducting behaviour which results in local overpotential distributions throughout the composite cathode. These local overpotentials depend on many factors, such as the composition, particle size, porosity and thickness of the cathode. Reliable experimental data obtained from composite cathodes requires carefully crafted microstructural parameters in order to minimize the overpotential variations. A mathematical model of a composite cathode was developed using coupled differential equations describing transport and consumption of chemical species, oxygen ion and electrons. Simulations under various oxygen concentrations were used to obtain the reaction order of the oxygen reduction reaction. An apparent po2 dependency was then extracted from the predicted Rp vs P02 data. It was found that this p02 dependency can be significantly influenced by the micro-structural parameters of a composite cathode, primarily due to local overpotential distributions.

Jan 1, 2005

By T. R. Kostecki, K. V. Jessu

"Roof bolts are subjected to axial stresses, shear stresses, or both. Axial and shear stresses were compared between roof bolts machined with two and three slots. Shear stresses perpendicular to and at an angle to the shear planes were evaluated by analyzing a three-slot instrumented roof bolt, performing laboratory tests on two- and three-slot roof bolts, and conducting in-situ test analyses. Threeslot bolts appear to provide a complete bending strain profile, requiring no prior knowledge of the estimated shear-plane orientation. Minimum displacements occur in roof bolts installed perpendicular to rather than at an angle to the shear planes.RÉSUMÉ Les boulons d’ancrage dans le toit d’une mine sont sujets à des contraintes axiales, des contraintes de cisaillement ou les deux. On a comparé les contraintes axiales et de cisaillement de boulons d’ancrage usinés avec deux ou trois fentes. Les contraintes de cisaillement perpendiculaires et à angle aux plans de cisaillement ont été évaluées en analysant un boulon d’ancrage de toit à trois fentes, en effectuant des essais en laboratoire sur des boulons d’ancrage de toit à deux et à trois fentes et en effectuant des analyses de tests in situ. Les boulons à trois fentes semblent fournir un profil complet de résistance aux contraintes de flexion, sans avoir besoin de connaître l’orientation estimée du plan de cisaillement. Des déplacements minimums ont lieu dans les boulons d’ancrage de toit installés perpendiculairement, plutôt qu’à un angle, aux plans de cisaillement."

Jan 1, 2016

By J. Ji, A. Shi, B. Grcic

Floating copper minerals selectively against iron minerals such as pyrite has been challenging for most copper and copper/gold deposits, and many operations continuously strive to maximise copper recovery whilst meeting target concentrate grades. Maximising grade is achieved by selectively floating copper minerals and rejecting pyrite. This challenge is to minimise copper and gold losses in the roughers if this approach is used. A flotation testing program was conducted by Bureau Veritas Minerals on a high-level pyrite bearing copper/gold ore sample to establish the potential to reject pyrite in the rougher stage, but also maximise copper and gold recoveries, and ultimately final product grades. The test program included feed characterization, rougher and open-circuit cleaner flotation as well as locked cycle flotation tests. The main variables tested for achieving selective flotation of copper and gold were collector type and pH control, through lime addition. Grind sizes used in the rougher and cleaner tests had been established from previous test work. The collectors tested were SIPX, Aerophine® 3418A, Aerophine® 3421, Aerophine® 3422, Reagent S-11192 Promoter, Reagent S-11193 Promoter and FloMin C4150. The two best performing collectors were then tested in open-circuit cleaner tests, with the optimum conditions examined further in locked cycle tests. INTRODUCTION Bureau Veritas Minerals Metallurgical Division was retained by Eldorado Gold Corporation to perform a metallurgical testing program on a high-level pyrite bearing copper/gold ore sample from a gold- copper porphyry deposit to optimize flotation reagent scheme to improve gold and copper recoveries and copper content in the concentrate. The test program included feed characterization, rougher and open-circuit cleaner flotation as well as locked cycle flotation tests. Initially, various collectors were screened in kinetic rougher tests, and over a pH range of 8.5 (i.e the natural ore pH) up to 11.5, using a primary grind size of 80% passing 120 µm. The collectors tested were SIPX (sodium isopropyl xanthate), Aerophine® 3418A, Aerophine® 3421, Aerophine® 3422, Reagent S-11192 Promoter, Reagent S-11193 Promoter and FloMin C4150. The enrichment ratio, which is the ratio of copper to sulfur in the concentrate to that in the feed, was used as proxy for rating selectivity (i.e. degree of pyrite rejection or depression).

Jan 1, 2019

By Walter Nelson

Considerable thought and discussion had been devoted toward provision for increased milling capacity at the Allenby concentrator of The Granby Consolidated Mining, Smelting and Power Company operations as early as 1940. During the war, plans for the installation of an additional grindi.ng unit were formulated but were not carried out. It took considerable time after the war to prepare the mine again for its highest rate of production since, with the scarcity of men, development work had been sacrificed in favour of maximum ore shipments. In order to prepare for the expected competitive market in copper, the matter of increasing the capacity of the concentrator was again given serious attention. As ore became available in the mine and the output of the mill was increased, limitations for a satisfactory recovery were observed, due to the overloaded condition of the classifier units at the higher tonnages. From a metallurgical standpoint, the ore from the Copper Mountain mine had always been difficult to treat on account of the finely disseminated character of much of the mineralization and the difficulty of grinding to the desired fineness. This trouble has become aggravated with time as an increasing amount of wall-rock has diluted the ore and lower grade orebodies have been mined. It therefore has been, and is, the practice at the concentrator to maintain the maximum amount of reduction in size of material fed to the flotation units as is possible for the daily tonnage to be milled. This means that all the grinding units are operated for the maximum possible time, and that the classifiers are regulated to return as much feed ?as possible to the mills. The number of tons to be milled for ?the day is determined by the concentrator superintendent after ascertaining the availability of ore from the mine, the condition of the concentrator ore bins, and the need for repairs in the rolls plant. In order to maintain the tonnage des1red, hourly estimates are made of the rate of grinding by weighing the amount of ore contained on one foot of each of the belts conveying the feed to the various ball-mills, and adjustments are made accordingly.

Jan 1, 1950

By Martha Gellner, Lutz Wuschke, Hans-Georg Jackel, Urs A. Peuker

"Electric vehicles are an alternative to the existing combustion engine driven cars. According to the EU Battery Directive a substantial recycling rate of at least 50 wt.-% has to be met for aged batteries since 2006. Existing recycling techniques are based on energy intensive pyro- and hydrometallurgical process, which are not able to recover all components. Aluminum and lithium for instance are slagged. The EU-Project “ABattReLife” investigated possibilities for a mechanical processing in order to create a sustainable process and a closed material loop from grave to cradle. After a sufficient liberation of the Li-ion batteries, components like the doped carbon black fraction (mainly lamination of electrode foils), the separator foil and the housing material can comparatively easily be separated from the other components by screening and air sifting. The remaining mixture consists of anode and cathode foils which have a similar free-settling ratio and are more difficult to separate from each other. A second comminution and compaction step modifies the particle size and shape as well as the degree of delamination. These changes influence the density of the electrode foils in order to improve the separation efficiency. Yield and purity of the generated metal concentrates were parameters to show if the separation was successful. The specific energy consumption for the different methods of processing was estimated in order to benchmark the cost-benefit ratio for each one.The studies have been accomplished with a zig zag sifter (model TUBAF), a hammer mill (model HM 340 Jehmlich) and with a Petkus-Sifter. Finally a process flow sheet was developed for a Li-ion battery recycling plant in pilot scale."

Jan 1, 2016

By V. ?. Chanturiya, G. P. Dvoychenkova, ?. Ye. Kovalchuk

"Several mineralogical investigations have revealed the composition of modified kimberlites and the mud generated during treatment of diamonds, which contains up to 50% clay minerals (e.g., talc, talcsaponite, chlorite-saponite, Na-saponite) and X-ray amorphous phase. We investigated the composition of the natural diamond surface in relation to the diagnosed minerals and established the sequence and conditions for mineral formation on the crystal surface under kimberlite processing conditions. This article suggests a method to destroy and further dissolve minerals on the crystal surfaces using water system electrolysis products, which makes it possible to restore the diamond hydrophobic properties. The application of chemically treated water in the foam separation cycle under the conditions of high recovery of diamonds made it possible to increase the content of the factory concentrate by 8.0%.INTRODUCTIONThe high content of the modified minerals in the kimberlite ore results in the formation of hydrophilic slicks on the surface of the crystals which decreases the diamond’s hydrophobic properties and increases the losses thereof in the process of grease and foam separation to 20-30% (Kurenkov, 1957; Chanturiya et al., 1998, 1999, 2005; Duikarev et al., 2000).The previous researches have revealed the fact that the prospective way of solving the problem of intensity of mineral impurities formation on the surface of the crystals and the increase of concentration parameters is reached due to application of physical and chemical stimulation techniques on the solid and liquid pulp (Stricland-Constable, 1971; “Improvement of the technology…”, 2006; Makarskii, Adodin & Tarasova, 2011; Chanturiya, Dvoychenkova & Trofimova, 2012). However, the main task of investigations to stipulate the objective achievement is the studying and justification of the reasons of the diamond surfaces covering by the mineral slicks"

Jan 1, 2016

By B. K. Gorain

Barrick' s Buzwagi copper-gold deposit in Tanzania comprises oxide, saprock and sulphide mineralized zones averaging approximately 0.058oz/t gold, 0.13% total copper and 0.03% cyanide-soluble copper. A comparative evaluation of the project based on two potential flowsheet alternatives is presented. The first flowsheet included a gravityconcentration and carbon-in-leach (CIL) plant. The second flowsheet was based on a Gravity-Flotation-CIL plant, which proved to be more economically robust. Selective flotation of copper minerals to produce a saleable copper concentrate proved to be challenging. Detailed characterization of the Buzwagi deposit was carried out through understanding of ore mineralogy, mineral liberation, floatability and selectivity, reagent chemistry and regrinding issues. With this insight, a flotation concentrate of greater than 25% Cu was achieved, recovering a significant amount of copper minerals and tellurides. The overall economics of the project improved significantly with the addition of flotation. Leach tests on gravity and flotation tailings showed an overall increase in gold recovery of approximately 6% for a Gravity-Flotation-CIL plant compared to that for a Gravity-CIL plant.

Jan 1, 2007

By William D. Swank, Prabhat K. Tripathy, Tedd E. Lister, Eric S. Peterson, Delon C. Haggerd

More than half of the primary neodymium, produced directly from ores, is being used to manufacture neo magnets. Neodymium, being a critical element in supply, has attracted considerable interest worldwide to recover this metal from a variety of waste streams. From among different recycling processes, hydriding-dehydriding can prove to be highly effective in recycling discarded neo magnets present in consumer electronics. In the present study, manually removed magnets from discarded Hard Disk Drives (HDDs) were subjected to the hydriding-dehydriding process in order to evaluate the resultant products for the re-fabrication of the magnets. The paper describes the effect of experimental parameters on both the hydriding and dehydriding processes as applied to different magnet chemistries.

Jan 1, 2014

By G. Vibert Douglas

It often happens that the field geologist encounters a fault in ground where there is little to guide him with regard to the throw, or vertical displacement, and the heave, or horizontal displacement. The following construction gives both of these components of the fault, and the writers hope that it may prove a help to others. The construction is applicable to both normal and reversed faults. Briefly the procedure is as follows: Take a point which is common to the faulted geological feature and to the fault plane and on the downthrow side of the fault. Move this point in the horizontal plane in the direction indicated by the fault striæ. Rebat the point down to the plane of the fault and obtain its throw. Next consider the other side of the fault and truncate it down by the amount of the throw just determined. Then project the line of the geological feature through to the trace of the fault-plane at the lower horizon. The result is the relative positions of the two parts of the original geological feature as severed by the fault. In Figure r, let us consider a typical normal fault, that is, a fault in which the hanging-wall has gone down relative to the footwall. This characteristic, or its alternative, the reversed fault, is determined by observation on the ground. Let AB be the line of any geological feature such as the edge of a dyke, vein, or bedded sediment. The plane of which AB is the trace may have any dip; in the present case let us say 70° right. Let FF be the trace of a fault-plane which may have any dip; let us say 35° left in this case.

Jan 1, 1928

By A. S. Dawson

"IntroductionTHE PURPOSE of this paper is to describe the results of a preliminary investigation of a method thought to be useful in interpreting geological structures in un-metamorphosed sedimentary rocks. The writer is not aware of the method having been described or investigated previously, although no thorough search of the literature has been made.The method to •be described is based on the assumption that, in argillaceous sedimentary rocks, certain ceramic properties are diagnostic for certain beds within areas of variable limits.Two ceramic properties• have been investigated: pyrometric cone equivalent (P.C.E.), and bloating characteristics of shales. The enquiry has been directed toward testing the usefulness of these properties in determining the following:A -The correlation of shale beds and, by inference, of coal seams, sandstone beds, or other such structures associated with them.B.-The location of contacts between marine and non-marine shales where lithological, palaeontological, or other evidence is lacking.Limitations of time and facilities have prevented a thorough investigation of this problem. The results given in the present paper are preliminary only. It is hoped, however, that they will occasion discussion or even lead to more thorough investigation of the method by individuals or organizations.There are, admittedly, various limitations to the proposed method. It is thought to show some promise when used in conjunction with the well-known and established methods used in stratigraphic correlation and, more particularly, when the conventional methods are not applicable."

Jan 1, 1952

By Xu Wang, Yizhe Zhang, Yangge Zhu, Xiao’ou Xia, Fangming Liu

"The progress of lean magnetite preconcentration in China was introduced in this paper, such as using coarse crushing to reject tailings, and multistage grinding, multistage magnetic separation. The applications of “more crushing and less grinding” process and equipment in lean magnetite preconcentration could reduce production costs effectively. The related analysis and study on concrete cases were carried out in this paper.INTRODUCTIONIn the case of the slowdown and weak recovery in the global economy, bulk commodity prices fell sharply in 2015. Take iron ore's prices for example, about 60% grade iron ore's import prices in China from about $65 per ton at the beginning of 2015 fell to about $42 per ton in the end of the year, down by about 35%. But iron ore resources are non-renewable resources, with the continuous development and utilization of mineral resources, high grade iron ore resources will be exhausted gradually. Accompanying with the economic recovery iron ore prices after this fall is bound to return to its value to maintain a high level.The development and utilization of resources is gradually turning to the low grade iron ore. Restricted by technical development level and disadvantages of lean iron ore resources, the cost of utilization lean iron ore resources is relatively high. Making full use of their rich lean ore resources has become many countries' important strategy to get rid of dependence on foreign countries' ore. Over the years with the development and progress of lean magnetite mineral processing technology in China, the production number of concentrator has been greatly improved.As the world's largest steel producer and consumer countries, ensuring a stable and continuous supply of iron ore is particularly important for the healthy development of China's iron and steel industry. Chinese iron ore production and import data in recent years are showed in Table 1.With the expansion of iron and steel production, iron ore demand has also been a phenomenal growth. Taking 2013 for example, China's crude steel production is about 780 million tons in 2013, accounting for about half of the world's total output of crude steel. At the same time, China is also the first major iron ore import countries whose iron ore imports in 2013 was about 820 million tons, an increase of about 10%. The degree of external dependence is very high. In some years, the cost of China's iron ore imports was even more than $100 billion, and second only to oil’s import cost in all bulk commodities."

Jan 1, 2016

By G. Avramovic-Cingara

Grain boundary characteristics and microstructural evolution are analyzed in a comparative study using orientation imaging microscopy (OIM/SEM) and transmission electron microscopy (TEM/SAD). The subgrain sizes and misorientations were determined by the OIM for aluminum deformed in torsion to equivalent strains between 0.2 and 4 over the temperature ranges of300-600°C and strain rates 0.01-1 s". The OIM gives clearer evidence of boundaries with high misorientation than does TEM, but it overestimates their frequency b y missing boundaries less than 1 0. T EM more clearly reveals low-angle arrays of widely spaced dislocations resulting in finer subgrain sizes than those indicated by OIM. The evidence supports a mechanism combining dynamic recovery (DRY), deformation band formation with permanent boundaries and geometric dynamic recrystallization (gDRX) in contrast to the hypothesis known as continuous dynamic recrystallization (cDRX).

Jan 1, 2004

By Scott Beer

What New Technologies Will Drive Economic Improvements? ??Historical ?1060?s: Mainframe Technologies ?1970?s: Mini Computing ?1980?s: Workstation Computing ?1990?s: Personal Computing ?2000?s: Network Computing Internet PDAs Cellular phones ??What?s the next technology improvement? ??What?s next for Mining?

May 1, 2009

By John B. Riddell

"AN EXCELLENT review of the status of applied geochemistry was given by Warren (1959) at last year's General Meeting of the C.I.M. The purpose of this paper is to present recent developments and trends. Several important books were announced during 1958: Ginzburg, I. I. Principles of geo-chemical prospecting. (In process of translation from the Russian by V. Sokoloff).Vinogradov, A. P. The geochemistry of rare and zvidely scattered chemical elements in soils. Consultants Bureau, N.Y. Korzhinskii, D. S. Physicochemical basis of the analysis of the paragenesis of minerals. Consultants Bureau, N.Y.In addition to these translations Mason's Geochemistry' has been revised, and Hawkes and Webb (personal communication) are publishing a book on geochemical exploration. A Symposium on Geochemistry was head in Paris in July, 1957, in conjunction with the XVIth International Congress of Pure and Al-lied Geochemistry. The abstracts of the papers presented at this Symposium were published in Geochimica et Cosmocl1imica Acta, 1958, Vol. 14, pp. 150-167."

Jan 1, 1960

By W. R. Lindsay

Considerable attention has of late been given to the blasting of large amounts of ore in one operation, on account of the saving in labour and explosives and consequent low cost per ton, and also on account of the additional safety to employees. The blast here described, at the Hidden Creek mine. at Anyox, B.C., is not necessarily unique either in size or methods employed, but some interesting p10blems were encountered and the solutions of these may be of interest to others engaged in similar work. The ore consisted mainly of old scope-bottoms and sill pillars, although there also were some braces and parts of vertical pillars included. Some of the stope-bottoms were overlain by caved waste, and one of the problems was to break them in such a manner that the maximum amount of ore could be recovered without serious dilution with waste. The ore blocks, designated as the 385 silt and the 7 A-103 blocks, were under preparation for blasting for over a year, as conditions permitted. This work consisted in drilling long machine drill holes, varying in length from 14 to 20 feet. These holes were drilled with the Numa detachable bit, made locally, starting at 2~-inch diameter and bottoming at 2 inches for the longest length. The long hole drilling was used in the thinner sections of the area. For the stronger, thicker portions, powder drifts (3 ft. by 4 ft. in section) were driven for the powder charges. Reference to the plan and sections (Figures 2 co 8 inclusive) show the relative location of these, as well as the long drilling. The amount of explosives used in the powder drift charges averaged 0.25 pounds per ton of estimated burden, varying from 0.2 to 0.3 pounds per ton.

Jan 1, 1934

By G. M. Proudfoot

IN June, 1940, a .Longyear 3420 blast-hole drill rig was purchased by the Hudson Bay Mining and Smelting Company for the purpose of experimental blast-hole drilling. The early work showed that the diamond drill could compete successfully with the Leyners then in use and by January 1st, 1941, the diamond drills were placed on contract. They may be considered to have gone into production at that date. Prior to the introduction of the diamond drill, our bench drilling was clone with Ingersoll-Rand S-70 and S-83 Leyner drills. Holes up to 40 feet were drilled, using coupled 1 1/4-inch round steel. Bits with a gauge of 3 inches were used in starting these holes, with a drop of 1/8-inch gauge for each 2-foot run. The holes normally ended with 1 1/2 or 1 5/8-inch gauge, though bits down to 1 1/8 inches were available for holes longer than normal or for holes drilled in abnormally abrasive ground. This method of drilling was very satisfactory and was a distinct improvement on the three-bench method of drilling used previously (1). During 1937 and 1938, when experienced miners were available, Leyner long-hole drilling was carried on with great efficiency. However, in 1939 and 1940, labour turnover in-creased and experienced long-hole drillers became scarcer. This resulted in a marked decline in the efficiency of the drilling operations, with increased costs and less tonnage drilled per shift. EXPERIMENTAL WORK The initial diamond drilling test work was carried on with a Longyear 3420 air-driven blast-hole drill rig, drilling a 1 3/16-inch hole. Tests indicated that diamond drilling could be successfully adapted to local conditions and that overall costs compared favourably with costs obtained with the Leyner long-hole method. Leyner long holes on stope benches usually bottomed at a larger diameter than the 1 3/16 -inch diamond-drill holes. More powder could therefore be introduced into the Leyner holes than could be placed in the diamond-drill holes. To achieve the same fragmentation, additional footage was required when diamond drilling. Diamond-drill holes of larger diameter were indicated.

Jan 1, 1943

By M. Li, T. H. Dubaniewicz, H. N. Dougherty

"INTRODUCTION Underground mines have the risk of accumulation of gases if not ventilated properly or during and after emergency situations when ventilation controls become damaged or stop working. Common gases that are monitored in underground coal are carbon monoxide (CO), oxygen (O2), and methane (CH4). Methane is a gas found in coal and released through mining; its explosive range is between 5% and 15%. Methane is commonly monitored on all mining equipment and with handheld gas sensors carried by most underground coal miners. Fiber optics (FO) is a popular technology applied in underground mining, particularly for its electric isolation. Many miners are familiar with FO cables hung throughout the mine, which are primarily used in the communication of voice and data (Taylor et al. 2010). Advancements in laser and fiber optics have made this technology well suited for gas sensing the harsh environment of mining applications. The work of the U.S. Bureau of Mines on the use of fiber optic monitoring of gases in mines started in 1992. Dubaniewicz et al. (1992, 1993, 1995, 1999, 2003) developed prototype gas sensors, including methane gas sensors, for research purposes. Previous research (Dubaniewicz & Chilton 1992) identified potential fiber optic gas detection cross-sensitivities associated with the index of refraction of various gases. Index of refraction effects was noted for carbon dioxide (CO2), which is produced in significant quantities by mine fires or explosions. NIOSH released a broad agency announcement (BAA) for the development and demonstration of mine safety and health technology (CDC NIOSH 2017). The objective of this announcement was to validate a sensor, specifically fiber optic, for the mine environment and test it in an actual working mine. The RSL FO sensor “OptoSniff” provided from this work is capable of hundreds of sensing points over distances of up to 20 km, has a measurement range of 0.05% to 100%, senses in an oxygen- deficient environment, and has no gas cross-sensitivity (RSL, 2014). The RSL system is totally electrically passive outside the central control unit (CCU), which can be housed in an MSHA-approved explosion-proof (XP) enclosure or in a control room outside of the permissive area. The sensor was tested in dusty and signal loss situations, showing it is tolerant of dust, has functioned at signal losses up to 90%, and was successfully tested in a mine environment for a five-month period (Walsh et al. 2014). This paper describes how the RSL FO sensor is used for testing using smoke and its contaminants for applicability in emergency situations. The testing investigates individual contaminants such as CO2, temperature, and smoke. Each test was performed separately and methane concentration, laser power, and response time data were collected."

Jan 1, 2019

By D. J. MacKinnon, Kazi E. Haque

Ammonia present in a variety of mine/mill waste waters was almost completely oxidized to nitrogen by chloride mediated electro-oxidation. A closed circuit operation of preconcentration of ammonia on a suitable adsorbent (e.g. zeolite or a resin) followed by brine stripping of ammonia and electrolysis of the strip liquor seems to have sound technical, economic and environmental merits. The removal of ammonia, cyanide, cyanate or thiocyanate from a mine/mill waste water (e.g. gold mill), either individually or collectively, is also feasible by chloride mediated electro-oxidation technique. Further R&D investigations are necessary for the development of a closed circuit operation for the removal of ammonia, cyanide and thiocyanate; and also to obtain technical data for process cost estimates

Jan 1, 1996

By Zhan Zhang, Hiromi Nagaumi, Zhen Li

"Recently, the remarkable strengthening effect of ??-Al(Mn, Fe) Si dispersoids at both ambient temperature and elevated temperature were found by several researches. A large amount of dispersoids can be formed by applying special heat treatments and within a suitable range of chemical composition of AA3xxx alloys. In the present work, the influences of Cr addition on the mechanical properties and microstructures of the Al-Mn-Mg-Si alloys were investigated. The mechanical properties at ambient and elevated temperatures were evaluated by micro-hardness and yield strength. Moreover, the microstructures in as-cast and heat-treated conditions were quantitatively analyzed by optical and electron microscopes. Results revealed that Cr also had effect on the number density and volume fraction of dispersoids. Micro-hardness and yield strength at ambient temperature increased with the increasing content of Cr, and the Cr addition increased the yield strength at elevated temperature as well. Moreover, the creep resistance at 300°C improved dramatically with the increasing content of Cr.INTRODUCTION Traditionally, AA3xxx aluminum alloys were widely used in packaging, automobile and architecture industries, because of its good formability, excellent corrosion resistance and weldability. And AA3xxx alloys were considered as non-heat-treatable alloys. However, the strengthening effect of dispersoids in AA3xxx alloys was discovered recently (Li & Arnberg, 2003;Li, Muggerud, Olsen, & Furu, 2012; Li, Zhang, & Chen, 2016; Liu & Chen, 2015).Alarge amount of dispersoids could precipitate by a proper heat treatment.In order to further improve AA3xxxalloys, the composition of the alloys should be optimized. A few previous studies were reported to investigate the influence of compositions on AA3xxx alloys. Adding Mn element could enhance the precipitation of ??-Al(Mn, Fe)Si dispersoids and improve the yield strength(Muggerud, Mørtsell, Li, & Holmestad, 2013), as long as the concentration of Mn was under the solid solution limit. Fe decreased the solubility of Mn and accelerated the precipitation rate of ??-Al(Mn, Fe)Sidispersoids(Li & Arnberg, 2003), the yield strength and creep resistance at elevated temperature could increase with an optimized content of Fe(Liu & Chen, 2016). Mg element would affect the nucleation process of ??-Al(Mn, Fe)Sidispersoids by forming metastable Mg2Si(Hirasawa, 1975; Li, Zhang, & Chen, 2017a; Lodgaard & Ryum, 2000), metastable Mg2Si precipitated during heating process and promoted the precipitation of ??-Al(Mn, Fe)Sidispersoids, moreover, Mg provided solid solution strength for AA3004 alloys(Li et al., 2016). Si increased the volume fractionof ??-Al(Mn, Fe)Sidispersoids(Muggerud et al., 2013)and decreased the size of ??-Al(Mn, Fe)Sidispersoids(Li, Zhang, & Chen, 2017b). With the addition of Mo, the size of dispersoids became finer with a higher volume fraction, the volume percentage of dispersoid free zones was reduced. Elevated temperature yield strength and creep resistance improved due to Mo addition (Liu, Ma, & Chen, 2017).However, the effect of Crelements on microstructure and mechanical properties of AA3xxx alloys were rarely reported."

Jan 1, 2018

By R. S. James, S. P. Goff, A. E. Armitage

"Abstract - Oxide-facies banded iron formation in the Third Portage Lake area is hosted by ultramafic and calc-alkaline volcanic rocks and related sedimentary rocks of the Archean (2.8 Ga) Woodburn Lake Group, 80 km north of Baker Lake. These rocks record at least two phases of metamorphism/ metasomatism. Greenschist facies metamorphism, in the temperature range of 370°C to 520°C and at pressures above 2.3 kbar, has affected all rocks on a regional scale. Later mineralization and alteration of banded iron formation (BIF) and associated volcanic rocks resulted from metasomatic fluids which carried Mg, K, Ca, S, As, Cu and Au. These fluids were confined to ductile to brittle, cross-cutting and layer-parallel micro-shears developed in the thickened hinge region of a shallow plunging recumbent fold. Metasomatic reactions yielded cummingtonite + biotite-bearing assemblages which are associated with strongly mineralized iron formation. Pyrrhotite is the dominant sulfide phase and occurs within ductily deformed iron formation where it pervasively replaces magnetite. Minor fine-grained chalcopyrite and arsenopyrite generally occur as inclusions within pyrrhotite and recrystallized magnetite, and rarely as individual grains. Pyrite is restricted to brittlely deformed iron formation, and to the contact between iron formation and altered ultramafic rocks, where it is associated with quartz veins. Pyrite typically replaces pyrrhotite. Native gold is associated with both pyrrhotite and pyrite, but higher gold concentrations are associated with pyrite. Grunerite/Ca-amphibole + stilpnomelane and sparse pyrrhotite and pyrite characterize weakly mineralized iron formation. Within adjacent ultramafic rocks, metasomatic reactions yielded assemblages of interlayered Ca-amphibole + biotite, and talc + Ca-amphibole + carbonate + biotite. K-Ar geochronology on metasomatic biotite from mineralized BIF yielded a 1791 ± 32 Ma age.An epigenetic model is favored for the emplacement of gold. The age of the gold mineralization in the Third Portage Lake area is uncertain, but may be Proterozoic based on the preliminary isotopic age and by analogy with Proterozoic gold deposits elsewhere in this part of the Churchill Structural Province."

Jan 1, 1996