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By William Skinner, Jim Pae Lem, Massimiano Zanin

It is well known that the specific density of minerals has adverse influence on the classification performance of a hydrocyclone, particularly when liberated high density minerals such as gold or uranium are present in sulphide ores. These liberated heavy minerals often misreport to the underflow and recirculate to the system. Such phenomena does result in serious issues in a closed-grinding circuit, such as overgrinding, leading to production of flaky particles (as in gold) or ultrafines, in addition to increased energy inefficiency. In plants which present gold liberated at coarser size, loss of gold due to cyclone inefficiency is sometimes prevented by incorporating gravity concentrators into the grinding circuit to recover the gold. The work reported in this paper looks at whether the effect of density will prevent successful rejection of liberated U-bearing minerals in the –10µm size range of a plant re-cleaner feed, which is necessary to minimize penalty U accumulation in a copper concentrator. The study was carried out using a cyclone rig with spigot diameter of 0.25 inches in combination with batch flotation. It was found that the density effect is almost negligible at particle sizes below 10µm. Consequently, the liberated U-bearing particles finer than 10 µm were successfully removed in the overflow stream as rejects and hence U grade in the copper concentrate remarkably reduced, by 16 ppm. Based on the results, de-sliming of the re-cleaner feed was recommended for plant trial and implementation.

Jan 1, 2016

By W G. Forbes

SOME 20 years ago, upon finishing second year at the University of Manitoba, I was faced with the choice of whether I wanted to be a geologist or a chemist. Accordingly, I sought out Professor Brownell, Head of the Department of Geology, to ask him what a geologist did. His reply contained the statement that following graduation one went out into the field in northern Canada for 5 to 15 years to reduce to practice what had been learned at university. To a young man, very socially conscious, even one year, let alone 5 to 10, in a small mining community sounded like being banished to a monastery in the Himalayas and thus I turned to chemistry. Moving to the present, last month I asked a geologist, and then a mining engineer, what does the fresh graduate in their field do these days? The reply was: usually serve an apprenticeship for an indeterminate period either underground or in the field learning the job.

Jan 1, 1965

By Rodrigo Madariaga, Tracy T. Morris

The practice of stripping copper starter sheets from titanium blanks to be used in a conventional electrolytic tankhouse has been around since the advent of Electrometallurgy. Historically it has been done manually, utilizing many people to produce in some cases thousands of starter sheets per day. Some other conventional tankhouses have successfully converted to using mechanical means to strip starter sheets or have made the switch to permanent cathodes and although robotics have been around for quite some time they have not been used to strip starter sheets until recently. The Amarillo Copper Refinery began using robotics to strip several years ago and the details to how this came about and how the robots work will be described. INTRODUCTION ASARCO LLC (Asarco) was organized in 1899 as the American Smelting and Refining Company. Originally a consolidation of several lead-silver smelting companies, it evolved over the years into an integrated producer of primary non-ferrous metals, including copper, lead and zinc and associated co- products (Marcosson, 1949). Grupo México, S.A.B. de C.V acquired Asarco in 1999. Today, Asarco is a vertically integrated producer of primary refined copper and associated co-products such as gold, silver, molybdenum, selenium and tellurium. Asarco operates three open-pit mines and mills and two solvent extraction-electrowinning (SX-EW) plants all in Arizona plus a copper smelter in Arizona and a copper refinery in Texas. Figure 1 illustrates how the copper metal comes out of the ground at the mine and ends up as a refined product at the refinery The copper refinery in Texas is known as the Amarillo Copper Refinery (ACR) and is located in Amarillo, Texas. It was built in 1975 to replace 3 other aging refineries and was designed to produce 550,000 tons (500,000 MT) of refined copper per year using conventional starter sheet technology. At the time it was commissioned it was the largest tankhouse in the world at just under 1/2 miles long under one roof.

Jan 1, 2019

By G. Stafford Whitby

N ATURAL gas is found in several provinces of Canada, particularly Ontario, New Brunswick, and Alberta. The largest producer is Alberta, and there the most important field is the Turner Valley, where some low-gravity crude oil and naphtha are associated with the gas. Last year there was produced from the Turner Valley field an average of 3,462 barrels, or about 450 tons, of oil a day. The gas flow from the wells in this field bears such a high ratio to the oil which comes from them that, despite the enforcement of a measure of conservation, it amounted to the vast quantity of 6,000 tons a day, or more than 2,000,000 tons a year. Prior to the application of any conservation measures, the gas flow was at one time of the order of 12,000 tons a day. The heat content of one ton of the gas is almost equal to that of two tons of coal. A certain amount, say, 10 per cent," of the gas is used in Calgary and surrounding towns and in re-pressuring the Bow Island gas field, but the greater part of it goes to waste. What are the possibilities of making use of this waste gas, in whole or part? The possibilities of using it profitably as fuel for domestic and industrial purposes have undoubtedly been carefully considered by the Company which now distributes a part of the gas to cities and towns in Alberta. But the relative sparness of the population and the cost of pipe lines makes such possibilities strictly limited. There are, however, distinct possibilities of making use of at !east a part of the gas for the production of a variety of chemical products and of liquid motor fuel. The present paper is devoted to outlining some of these possibilities. About three-quarters (by weight) of the Turner Valley waste gas consists of methane, the lightest and, chemically speaking, the simplest of hydrocarbon gases. The remaining quarter consists of heavier hydrocarbon gases-ethane, propane, and butane. Formerly, naphtha was separated from the well gas by a simple process of self-refrigeration. The gas coming from the wells at a pressure of, say, 1,200 to 1,800 lb., was passed through simple cylindrical vessels fitted with baffles and known as 'separators'. The pressure was allowed to drop to, say, 300 lb. in the separators, and the cooling effect secured by this expansion brought about separation of the naphtha. The naphtha thus obtained was 'wild', that is, it had a high vapour pressure owing to the presence in it of dissolved and liquefied gas. In order to reduce the vapour pressure to a level at which the naphtha could be shipped, this gas was removed either by distilling it out through a 'stabilizing' column or, according to the practice at many wells, merely by allowing the naphtha to 'weather' in open tanks (heated by coils if necessary) until the gas had been driven off in to the air.

Jan 1, 1936

By D. L. Cluff

Ventilation Air Methane (VAM) is a high volume low concentration methane source. The capture or use of methane from VAM is challenging, which results in the routine discharge of methane into the atmosphere. Mitigating VAM has the benefits of providing an energy source and reducing the atmospheric Greenhouse Gas (GHG) burden. The GHG radiative forcing effect of methane is 17?23 times as potent as carbon dioxide on a 100-year time horizon. Thus, any reduction in atmospheric methane would be beneficial. The calorific value of methane is 55.5 MJ/Kg; therefore, a 100 m3/s flow with VAM concentrations from 0.1?1% can provide 3.8?38 MW of exploitable power. Strategies to mitigate VAM such as: Thermal Flow Reverse Reactors (TFRR), Catalytic Flow Reverse Reactors (CFRR), Lean Burn and Catalytic Gas Turbines, Biothermica Vamox®, Megtec VOCSIDIZER©, and Vamcat? are briefly reviewed. The review of VAM mitigation technologies reveals disadvantages such as the need to maintain a minimum internal heat capable of oxidizing the methane. This requirement uses all of the available methane up to the point of reaction sustainability and up to half at the highest methane concentration in VAM. Some systems may introduce a pressure drop to the ventilation system, which would impinge on the existing ventilation system design. These impediments necessitate the development of a more amenable technology. In the proposed system, gas turbines (GT), coupled to a combustion chamber with an external fuel supply, assist the combustion of the VAM. The combustion-chamber coupled system provides electricity, while the heat contained in the GT exhaust gases increases the temperature of the VAM, encouraging the development of a flame inside a combustion chamber. The flow from the combustion chamber streams through a primary air/fluid heat exchanger capable of producing steam of a high enough quality to generate electricity using conventional steam turbines. The residual heat after primary extraction, directed through other equipment, provides additional heat based products such as industrial scale dry air, chilling by an absorption chiller or hot water. The overall design of the system is scalable for low to high VAM flows or variations in concentrations and is capable of providing the company or community with heating, chilling, hot water, electricity or motive force as needed by the particular site or community. The Multi-generation system uses heat from three sources to provide clean efficient energy while mitigating the atmospheric emissions of methane. These sources are heat from the GT, often considered waste heat, heat from fuel injected into the igniters and heat from the VAM. The opportunity to collect carbon credits may improve the economics. In order to design a system with this capacity, a detailed analysis of the combustion characteristics of three separate flows is required. VAM is the main airflow, having the highest volumetric effect, while the GT exhaust and the additional fuel added to the hot exhaust flow of the gas turbine are lower flows, but have a higher velocity and temperature. The aim of the modeling undertaken in this work is to establish the combustion dynamics, degree of pre-heating required and the geometry essential to the design of combustion based VAM mitigation multi-generation systems.

Aug 1, 2013

By I. C. Edwards, E. O. Lilge, H. H. Mccreedy

"Introductory and GeneralTHE DRIESSEN CONE bas been used fairly extensively commercially as a classifier. Its use as a concentrator in the upgrading of ores at a fairly high ratio of concentration with concomitant recoveries has been almost negligible. Certain known features about the cone, however, such as its high throughput capacity, cheapness of construction and operation, and simplicity of design have attracted the attention of mill men. An inadequate knowledge of the operating characteristics of the cone when used as a concentrator seems to have been the main reason for its lack of use. It was for this reason that the present investigations§ were undertaken to determine the operating characteristics of the cone and its application to the concentration of uranium ores, with particular emphasis being placed on the concentration of low-grade uranium ores.The investigations were started in December, 1951, and have continued uninterrupted to the present. The initial work was confined chiefly to investigating the operating characteristics of the cone in order to establish the trends that certain variables would exert on the general metallurgy of uranium concentration. Optimum metallurgy was therefore not the prime initial objective."

Jan 1, 1955

By Peter Chmara

The measurement of dust concentration in Ontario mines since 1926 has been accomplished by konimetry, based on South African experience and methods. The introduction of a voluntary program of semi-annual surveys of air conditions at all operations throughout Ontario mines created a need for an instrument that would assess konimeter spots rapidly and accurately. The development of the Electronic Scanner, it is felt, answers this need. A program whereby all konimeter spot samples taken at Ontario mines will be counted at the MAP AO field offices in North Bay is described.

Jan 1, 1969

By Ronald Molnar

"High demand for metals is driving the exploitation of lower grade and more complex orebodies. These projects are often the initiatives of junior mining companies with limited financial resources. In addition, existing operations seek to enhance revenue from their existing metal recovery operations, through the production of value-added by-product metals and chemicals. Typically, hydrometallurgical circuits, often with novel chemistry, are required to exploit these new ores, to produce the multiplicity of products that will make a marginal project economical, or to increase the product range of an existing operation. Often, the mineral processing engineer is given the task of coordinating the development of a back-end hydrometallurgical flowsheet for their mineral processing project. This paper discusses the objectives that companies have when they commission the operation of a hydrometallurgical pilot plant. The paper goes on to enumerate some of the principal differences between mineral processing and hydrometallurgical pilot plants and the effect these have on the design, operability and potential pilot plant outcomes. Important factors include working with chemically reactive solutions and pulps, elevated temperatures operation, changing rheological properties of slurries, the complexity of integrated circuit flowsheets with long hold-up times and multiple recycle streams, and the need in some cases for extreme attention to purity and cleanliness. Examples will be drawn from the extensive experience base of SGS Minerals Services at the Lakefield site, in piloting both mineral processing and hydrometallurgical process flowsheets.INTRODUCTIONWe are currently experiencing a period of strong growth in the demand for metals. This in turn is turning the spotlight on a great many smaller mining companies and mining promotion ventures trying to tap into the rising metal demand. Some of these companies want to develop their properties and recover metals while others want to develop to the point that a major company will take an interest, or in some cases buy them out completely.With the heightened interest in metals, many orebodies that have been known about for years are being reconsidered for exploitation. Often, the reason they have not been developed to date is because of difficult metallurgy and marginal grades leading to marginal economic viability. In both cases the key that unlocks the resources is often the application of a novel metallurgical flowsheet, often a hydrometallurgical flowsheet."

Jan 1, 2006

By H. C. Gunning

Introduction Considerable attention has of late been attracted to the area surrounding Nimpkish lake, on northern Vancouver island, by the discovery of important rich copper deposits. In less than two years some 200 mineral claims have been staked in a small area, and at least two groups have very promising surface showings. During the summer of 1929, the writer spent one month investigating the general geology and mineral deposits of the region, and, although no detailed work has as yet been done in the field or in the laboratory, the importance of the mineral discoveries and the lack of geological information available to the public warrants a preliminary paper on the district. The district is, from a mining viewpoint, very accessible. Boats from Vancouver call at Englewood, in Beaver cove, four times a week. From Englewood, a first-class logging railway, operated by the Wood, .English Company, extends to the northeast corner of Nimpkish lake. The fifteen-mile trip from the north to the south end of the lake is made by boat, two tugs being maintained by the logging company. The whole trip from Englewood can easily be made in one day. The known mineral deposits lie immediately east of the southern part of the lake, four miles or less from the shore. A fair trail, four miles ? long, leads from the lake to the Nimpkish Copper group. Apart from this trail and an old logging railway grade which follows the east side of Klaanch river for several miles, no trails exist on the southeast side of the lake.

Jan 1, 1930

By G. G. Richards, D. J. Rioux, R. L. Stephens

Teck Cominco Metals Ltd. operates an integrated zinc-lead complex at Trail, British Columbia, Canada. The year 2007 marks ten years of operation of KIVCETTM flash smelting technology for the treatment of zinc plant residues and lead concentrates. Since start-up in 1997, the furnace throughput has been increased to exceed its design rate and other metallurgical performance targets while continuing to meet its environmental objectives. This was achieved through resolution of key mechanical issues, improved understanding to stabilize the reaction shaft operation and control furnace accretions, significantly reduced boiler corrosion by molten chloride salts through the extensive application of weld overlay, a suite of projects to improve furnace integrity, and some debottlenecking of the surrounding unit operations in the lead smelter. The combination of increased feed rate and improved on-line time allowed the KIVCETTM furnace to set a new quarterly feed throughput record of 129,300 tonnes in the first quarter of 2008.

Jan 1, 2008

By Bob Robinson

In 1990, the European Space Agency (ESA) initiated a technology transfer program to stimulate the wider use of technology developed by the European and Canadian space communities. This paper focuses on the method of technology transfer from the space industry to terrestrial industries, with a focus on the mining resource sector within a program called the Harsh Environments Initiative (HEI) created in 1997. Other resource sector applications include forestry and oil & gas. C-CORE in partnership with the Mining Innovation, Rehabilitation and Applied Research Corporation (MIRARCO) supported by ESA, Canadian Space Agency (CSA) and European R&D organizations conduct projects to promote and demonstrate the transfer of innovative technologies from space to non-space industries. Space programs have and continue to develop new knowledge for extra-terrestrial application, e.g., satellite earth observation, manned missions and unmanned planetary exploration. Many of which hold the potential for application on land and ocean. Currently, space technologies of interest to the mine sector range from robotics and image analysis to sensors, software and advanced materials. The HEI works to identify and apply these types of technologies in the areas of automated/tele-controlled mine operations and mine monitoring.

May 1, 2001

By L. H. McKay

Tailing Dams Three types of dam have been structed to impound tailings from the Allenby mill: 1.- By classifier unit 2.- By earth dam 3.- By direct deposition of tailings The first type, which includes two dams, was built across a shallow valley which sloped down to Similkameen river, just below the mill site. Two earth embankments, one below the other, were built across the valley. Tailings were then piped to Akins classifiers mounted on wooden wheels. The classifiers were set up at one side of the valley and gradually moved ahead on the sand embankment created by the sand discharge from these classifiers, the slime overflow going to settli.ng ponds formed by the dams. Decanting wells were built in the settling ponds by placing four six-by-six timbers vertically in the ground, two feet apart, to which two-by-six tongue-and-groove boards were nailed. The elevations of the ponds were raised, as required, by nailing additional two-by-six boards on the well and bolting on more six-by-six timbers when required. The bottoms of the wells were attached to a covered launder made of three-inch lumber laid on a one per cent grade. This launder carried the overflow through the dam. The second type of dam was built across a long, narrow valley, known as Hitchen's Flat, the upper ~n d of which was about 2½ miles north of the mill. This valley, an ideal tailings site, was 4,000 feet long and from 600 to 800 feet wide. An earth embankment with a concrete spillway through the top was built approximately 28 feet high across the lower end of this valley. Tailings were then dumped into the upper end of valley, with no further expense until the basin was filled up to the level of the flume where this entered the valley. When the upper end of the valley was filled to this point there was still room for more tailings at the lower end. Therefore, a pump was installed to elevate the tailings to build a wall around the upper end of the valley by depositing sands from a launder built up on 20 foot supports and sloping both ways from the pumping station around the upper end of the basin.

Jan 1, 1950

By Mike Johnson, Greg Andrews, Niels Verbaan, David Dreisinger

"The Search Minerals Foxtrot project in Labrador represents a significant Canadian resource of rare earth elements rich in the sought after heavy rare earth elements (19.8% HREE/TREE). A preliminary economic assessment of the project indicated that the project is technically feasible and economically attractive. A variety of metallurgical test programs have been undertaken which have led to significant streamlining and simplification of the process flowsheet. The improved flowsheet should allow Search to reach production earlier and will use conventional processing equipment. The results of these test programs are presented and discussed in this paper INTRODUCTIONSearch Minerals Inc. (Search) is exploring and developing a number of deposits for rare earth element (REE) recovery in Labrador, Canada. The Port Hope Simpson District is in the southeast of Labrador and is highly prospective for heavy and light rare earth elements. The Foxtrot deposit sits within the Port Hope Simpson REE District (Figure 1), which is 70 km long by up to 10 km wide. The infrastructure available at Foxtrot is excellent; a deep-water port, air strip, and road and power infrastructure are pre-existing at St. Lewis. The three communities of Port Hope Simpson, St. Lewis and Mary’s Harbour are in close proximity to the site."

Jan 1, 2016

By Seong-Taek Lim

Recently, 7xxx aluminum alloys have been evolved into new variants for thick semiproducts which have low amount of 2nd phases and low quench sensitivity. Commercial 7xxx alloys, especially in the thick forgings made of big ingots, often entail microstructural inhomogeneities and concurrent poor mechanical properties due to limited heating ranges and slower quench cooling. In this study, high strength aluminum alloy 7175 and 7050 are adjusted as an attempt to control the equilibrium phases (M-, T- and S-phase) to have optimum microstructure for the thick forging applications. The effects of the relative content of (Zn, Mg, Cu) on the evolutions of the coarse equilibrium phases, hardening response and resultant mechanical properties are investigated. Equilibrium phases (M,T,S) are evolved depending on the constitutional effect, primarily the change of Zn:Mg ratio, and cooling rate following solutionizing. The formation of the T- and S-phases is effectively controlled, and M-phases are homogeneously precipitated in the adjusted (dilute and high Zn:Mg ratio) alloys. It provides extended heating range and lower quench sensitivity than conventional alloys. The attempts ensure the microstructural homogeneity and improved properties, and is expected to be uniquely applicable in 7xxx thick forgings.

Jan 1, 2004

By G. Griffiths

"P. WitteWitteck DevelopmentThe implications of using a tower mill for fine grainding in the ore processing of tailings are significant. What can those of us who are in a research and development situation do when we recommend this equipment to a client? When this prototype is placed on stream next to a conventional grinding mill as you suggest how do we estimate the power requirements and the grind which will be achieved?ReplyLet me explain the Macassa circuit. The tower mill here was running in parallel with one of the ball mills. The feed entering the tertiary system is scalped in a primary cyclone. The finial cut is made in a secondary cyclone. The actual feed to the tower mill is the underflow from the two cyclones and was split to the ball mill and tower mill. During the testing we were unable to isolate the tower mill to determine its contribution to the overall system. We then started to look at the amount of material produced across the mill. We entered the mill at between 17% and 20% finished material and exiting at between 36% and 40% finished material. We were able to project, with a high efficiency classification system, and arrived at 6 Kwh/ton or better."

Jan 1, 1984

By H. C. Gunnings, C. O. Swanson

"The Sullivan mine; at Kimberley in southeastern British Columbia; is the largest silver-lead-zinc mine in the Empire and one of the largest in the world.The original discovery was made in 1892 by four prospectors. Until 1899, when the branch line of the Canadian Pacific railway from Cranbrook to Kimberley was completed, little work was done on the property. In 1900, systematic development was started, and during the next 3 years 5,000 tons of ore was shipped to the smelters at Nelson and Trail. By 1903, some 300,000 tons of ore was developed, and a smelter was started at Marysville, about 5 miles from the mine. However, this smelter closed down in 1907 because of metallurgical difficulties after treating 75,000 tons, and the property came under the control of the American Smelting and Refining Company. An option on the property was taken in 1909 by the Consolidated Mining and Smelting Company of Canada, who exercised their option in the following year. During the next 5 years by selective mining and sorting 188,000 tons of high-grade ore was produced and shipped to Trail. This tonnage came from the upper levels, about 4,600 to 4,800 feet in elevation. At the same time, deep drilling down to the 3,900-foot level showed the presence of an immense body of complex ore. In 1915, the main adit-the 3,900-foot level-was started, and by 1919 this had been driven a distance of 2 miles to develop the ore above this level. Meanwhile, progress was being made in overcoming the milling problems. An interesting account of this work was written by the staff ( 4). In 1923, the first unit of the present concentrator was erected, with a capacity of 2,500 tons a day, and thereafter the rate of production increased rapidly. In 1934 it was around 8,000 tons a day, and to date a total of about 30,000,000 tons of ore has been sent to the mill. In recent years, a considerable part of the production has come from levels between the 3,900-and 3,350-foot, which were opened by an internal incline shaft started in, 1930. In 1942, tin was added to the products separated at the concentrator."

Jan 1, 1954

By Marko Lampi, Ross Andrews, Jouni Pihlasalo, Robert Matusewicz

With widespread discussion on reducing carbon, sulphur and other emissions, use of sustainable energy sources and the pivotal circular economy theme, consideration needs to be given to pyrometallurgical operations broadly and more specifically, non-ferrous metallurgy. These themes present a number of challenges in terms of current operations and the view of processing the metals which are largely taken for granted in day to day living. This paper considers how these themes will impact pyrometallurgical flowsheets using the non-ferrous base metals as an example. It will examine the flowsheet chain to offer views on the boundaries of flowsheet optimization and the application of available tools to meet these future goals and challenges. INTRODUCTION The themes of reducing footprint through lowered CO2, S and other emissions, together with process sustainability (e.g. lowered energy) and links to the circular economy are well known to everyone in the metals industries. Whether it is reducing greenhouse gas emissions or analysing the importance of metals recycling in the circular economy, all these themes carry with them the fundamental premise of any change being considered; how can you best optimize a system to meet your aims? Of course, this depends on the available tools and the approach used for optimisation.

Jan 1, 2019

By W. H. Zieman

NORMAN WEISS, Milling Engineer, American Smelting• and Refining Company: The subject of the Forum on Rod and Ball Mill Liners is very fascinating, and there is no end of discussion when operators get together on grinding. However, the hypotheses and suppositions easily outrun the facts, especially when we •consider the inaccuracy of many reported observations. Still surprisingly small is the number of concentrators even reasonably well equipped to measure power consumption of each grinding mill, together with running time, so that data on this tangible factor, at least, can be obtained with precision. While the more elaborate devices of this nature, producing for each 24-hour period the total power consumption, average kilowatt hours per hour, short-term demand chart, instantaneous demand, and print-out, may cost in the neighbourhood of $2,500 per mill and may be difficult to justify, the combination of an ammeter, watthour meter, and running-time meter will cost only a few hundred dollars, so there appears to be little reason not to in-stall them in view of their numerous advantages.

Jan 1, 1959

By J. W. Austin

"Introduction The Brenda dust collection system was originally designed to handle air at the 5000 ft. elevation with less than 1 grain of dust per cubic feet of air handled. The temperature variation is from 32°C in the summer to -20°C in the winter.DUST COLLECTIONOriginal Equipment 1. Primary Crusher 2 compartment baghouse, shaker type design capacity - 17,000 cfm2. Primary Screening 3 compartment baghouse, shaker type design capacity - 30,000 cfm3. Secondary Crusher 4 compartment baghouse, shaker type design capacity - 45,000 cfm4. Secondary Screening 4 compartment baghouse, shaker typedesign capacity - 60,000 cfmThe original dust collecting equipment was designed using a napped terylene fabric at an air to cloth ratio of 5:1. The ducting was designed to handle the dust laden air at 3200 ft. per minute with all elbows and blast gate sections rubber lined. The hoods and the pickup velocities were designed to handle the anticipated low dust counts."

Jan 1, 1976

By Lang Tao, Jun Wang, Wei Xiao, Wenqing Qin, Pan Cao, Guanzhou Qiu, Key Lab of Biohydrometallurgy of Ministry of Education, Central South University

"The effect of metal cations on the rutile flotation using styryl phosphoric acid (SPA) as the collector was investigated by micro-flotation test, bench scale flotation test, zeta-potential measurements and adsorption measurements. The micro-flotation results indicated that Fe (?) and Al (?) ions in low concentrations had obvious activation on the rutile flotation, and Pb (?) ions in low concentrations had smaller activation of rutile, but Fe (?), Al (?), Pb (?), Ca (?) and Mg (?) have strong inhibition of rutile flotation in high concentrations. The bench scale flotation results indicated ethylene diamine tetraacetic acid (EDTA), boracic acid, and sodium hexametaphospate can decrease the metal ions concentrations, and increase the recovery of rutile flotation. Adsorption measurements and zeta-potential measurements revealed that Fe (?), Al (?) and Pb (?) ions were adsorbed on the rutile surface, and had interaction with SPA. But when these ions concentration were over the largest adsorption capacity, residual metal ions could occur chemical reaction with SPA.INTRODUCTIONRutile is one of the favored minerals for production of titanium dioxide white pigment, primarily through the chloride manufacturing process (Stanaway 1994; Hou et al., 2013) However, the majority of rutile ores belong to refractory ores, while flotation is one of the most efficient methods to separate fine rutile from gangue (Dolbear et al., 1937). With the flotation development, many effective collectors were successfully applied in the oxide ore. Many reviews have indicated that organic phosphonic acid collectors showed good selectivity on oxide ores such as ilmenite and rutile (Bulatovic & Wyslouzil 1999; Liu & Peng 1999).It is inevitable that many types of metal cations are present in ore pulp. These metal cations significantly influence the flotation of minerals. Liu et al. (2015) showed that Ca2+ and Mg2+ could improve the floatability of spodumene at pH 12.5 and 10.0, respectively. The authors proposed that Ca2+ and Mg2+ ions readily form hydroxy complexes (CaOH(l) and MgOH(l)) and precipitates as (Ca(OH)2 and Mg(OH)2) in strongly alkaline solutions. Fan and Rowson (2000) investigated the effect of Pb(NO3)2 addition as an activator on ilmenite flotation and showed that it could improve ilmenite floatability. The addition of Pb(NO3)2 resulted in an increase of ilmenite zeta potential in both weakly alkaline and acidic aqueous solutions. Mehdilo, Irannajad, and Rezai (2015) studied three kinds of ilmenite of different origins and discovered that both Mg and V had a negative correlation with ilmenite flotation, while the Mn content seemed to correlate positively with flotation efficiency. A number of studies have also showed that Fe3+ can improve the floatability of ilmenite (Fan et al., 2009; Nuri, Mehdilo, & Irannajad, 2014)."

Jan 1, 2016