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By M. O. Makwarela, M. W. Erwee, K. Bisaka

"Energy efficiency in mining and minerals processing forms part of Mintek’s long-term research strategy which includes a specific programme designed at overcoming the challenges faced by the South African pyrometallurgy industry.The electric smelting industry is currently severely constrained by the global economic downturn as well as by the availability and increasing cost of electricity. Efficient utilisation of electricity through energy recovery systems and improved smelting process flowsheets can significantly contribute towards creating sustainable operations.Apart from efficient engineering design and solid process control, smelting of either cold or hot pre-reduced ores has been shown to decrease furnace electricity consumption by more than 40%. Various methods of solid-state reduction tests have been carried out at Mintek in order to select the most appropriate process option in the context of the South African industry. This paper summarises a subset of the results obtained, specifically on pre-reduction tests done on South African chromite and manganese ore pellets.In this set of tests, it was found that the use of an organic binder, together with B2O3 as flux, promotes manganese ore pre-reduction, but retards the pre-reduction of chromite. By pre-reducing the manganese ore feed, significant cost savings can be achieved in subsequent smelting processes and there is potential to minimise manganese losses as a result of fuming, due to possible lower operating temperatures."

Jan 1, 2016

By W. D. Sinclair, R. J. Cathro, E. M. Jensen

"The Cash is one of the largest porphyry copper-molybdenum Deposits found in Yukon to date. It is 80 km northwest of Carmacks, within the unglaciated portion of the Dawson Range, and is associated with the Big Creek fault, an important tectonic feature. Part of the mineralized zone is blanketed by up to 70 m of alluvial drift . The remainder is covered by a relatively thin residual soil layer. The mineralized zone, however, was not detected by conventional stream-sediment sampling because pathfinder elements, such as Cu and Mo, have not been geochemically dispersed into the main drainage system. The deposit was discovered by a combination of soil analysis and inspection of rock fragments from small pits.Twenty widely spaced, shallow drill holes have outlined an areaover 2700 m long and 550 to over 1000m wide that grades more than 0.1% copper equivalent (% CuE = % Cu + (5 x % MoS2)). Two smaller zones grading over 0.4% copper equivalent occur within the larger area. The limits of the widest end of the deposit have not been delineated.The Cash deposit is fairly typical of high-level, calc-alkaline porphyry copper-molydenum occurrrences in the Canadian Cordillera {cf, CIM Special Volume 15) and is representative of most prospects in the Dawson Range. It is associated genetically with a subvolcanic complex of small, irregular stocks and dykes of feldspar porphyry and related breccias of Late Cretaceous age. Copper and molybdenum sulphides occur along fractures, in quartz veinlets and disseminated in feldspar porphyry and in older metasedimentary and intrusive rocks. Higher-grade zones of copper and molybdenum have associated potassic alteration. Phyllic alteration is, in part, superimposed on potassic alteration. Argillic alteration occurs locally.This paper describes the history of the discovery and the geochemical and geophysical characteristics, together .with the regional geology, and the nature and distribution of the host rocks, hypogene mineralization and hydrothermal alteration."

Jan 1, 1981

By P. H. Oliver

"The current theory of how explosives fracture rock offers no explanation for the improvements in fragmentation and the reduction of fly rock and back break which occurs when an adequate inter-row delay time is used. Nor does it explain why fragmentation improves with rectangular drill patterns where the hole spacing may be as much as four times the hole burden.A new theory of rock fragmentation is proposed which builds on the existing theory. It offers rational explanations for the many blast effects which the current theory does not address and the need for adequate timing delays between rows. It improves on the design of inter-row delay timing by defining the length of free-blasted face needed in front of a hole *Retired from Inco Ltd., Sudbury, Ontario when selecting the delay element which will provide an adequate inter-row delay time."

Jan 1, 2003

By M. Maley, S. Burling, R. Ring

ABSTRACT The numerous global uranium deposits vary significantly in mineralogy, grade, and textural characteristics; therefore, information from traditional (or conventional) sources on the fundamentals of leaching uranium and gangue minerals is not always applicable when studying particular ores. Empirical studies can be effective in understanding leach systems and can lead to improvements in process design but there remains a lack of fundamental understanding necessary for ongoing process optimization as ore bodies continue to vary. ANSTO Minerals has undertaken a work program to address several fundamental questions about uranium leaching, including the unexpected impact for some ore types of leaching at high oxidation potential.

Jan 1, 2012

By W. Graham

"IntroductionEFFLORESCENCE is herein considered to be any deposit of salts on the surface of a masonry structure that is brought from within or through the structure by capillarity and deposited by evaporation. Usually, efflorescence is white although green, yellow, and brown efflorescence is sometimes observed.The common white efflorescence almost always consists of sulphates of the alkali and alkaline earth metals and calcium carbonate, although sodium chloride is frequently present in structures erected near the sea shore.The first and most obvious result of the presence of soluble salts in masonry is the unsightly accumulation of these salts on the surface. This is particularly noticeable early in its life and is frequently fugitive ( 1), as much of the salt is soluble and is gradually washed away by rain. This removal can usually be facilitated by scrubbing; the structure with dilute hydrochloric acid.A more serious effect is the continuous accumulation of soluble salts as a result of ingress of sulphur acids in rain water or water from the ground. This may eventually cause spalling and disintegration by crystallization of salts in the pores of brick and mortar. An example of this type of failure, resulting from the crystallization of calcium sulphate, is discussed by Hardesty (2). Butterworth (3) describes similar failure resulting from •crystallization of magnesium sulphate."

Jan 1, 1954

By R. C. Gilmore, J. F. Brune

"Pulverized limestone rock dust used in United States underground coal mines to prevent and suppress coal dust explosions must easily disperse by forces of a methane or coal dust explosion. Moisture in the mine environment causes caking of the dust. Colorado School of Mines researchers performed dispersibility tests in a full-size explosion test drift. Tests included conventional, hydrophobized, and rock dust approved for German mines. Conventional and German standard rock dust products partially agglomerate, which may not be effective in suppressing a coal dust explosion, while hydrophobic rock dust retains better dispersibility.INTRODUCTIONA coal dust explosion devastated the Upper Big Branch mine in 2010 resulting in the death of 29 miners, the worst mining accident in the United States since 1972. The explosion propagated through approximately 65 km of active mine workings, but was extinguished in areas that had been properly rock dusted (Page, 2011). Researchers have long studied and established the ability of inert limestone rock dust to suppress coal dust explosions, see Richmond et al. (1975), Cybulski (1975), and Sapko et al. (2000).To be effective, rock dust must contribute to a total inert content of > 80% by weight and 100% of rock dust particles must pass through an 850 µm sieve, while 70% of the rock dust must be finer than 74 µm. This is established in US regulations 30 CFR §75.2. Dry rock dust is a nuisance that prevents mining work downwind from rock dusting activities. To overcome this problem, dust manufacturers have proposed applying the rock dust as a wet slurry or foam. After drying, manufacturers expected the slurry or foam-applied dust to have the same explosion suppression capabilities as dry-applied rock dust.Researchers at the Colorado School of Mines (CSM) designed and built a full-scale, underground Explosion Test Facility (ETF) at the CSM Edgar Experimental Mine in Idaho Springs, Colorado about 20 miles west of the CSM Golden, Colorado campus. To disperse the different rock dust products, researchers produced an air pressure pulse using a mesh array of PETN detonation cord. This method is simpler, more reproducible and safer than other methods considered, including methane-air explosions and a compressed air cannon. The detonation cord blasts produce a wind velocity of 30 to 50 m/s, the minimum velocity at which coal dust explosions can propagate, based on research by Nagy (1981) and Cybulski (1975)."

Jan 1, 2019

By J. Bruce See

INTRODUCTION This symposium at Cu 2019 has been organised to honour and celebrate the career and achievements of Dr Phillip John Mackey, an internationally recognised expert in the production of non-ferrous metals, especially copper and nickel smelting and refining. Phillip was born in Epping, a suburb of Sydney, New South Wales, Australia on 19 April 1941 and is one of 4 children of Gilbert and Philomena (nee Bartlett) Mackey. After completing Primary School in Epping, he attended Marist Brothers High School in Eastwood, Sydney and graduated in 1957 as the Dux of the School. Phillip’s father, being on the staff of the Sydney Technical College, in Ultimo, Sydney had the opportunity in the early 1950s to meet the late Professor Sir Rupert Myers, Foundation Professor of the School of Metallurgy at the New South Wales University of Technology (later called the University of New South Wales or UNSW). Gilbert Mackey was impressed by the new young Professor of Metallurgy and encouraged his son to study metallurgy - at the time an expanding industry in post-war Australia. EDUCATION AT THE UNIVERSITY OF NEW SOUTH WALES Phillip commenced at UNSW in 1958, graduating with honours in 1963. His undergraduate education and training included a few years of part-time study while working at British Motor Corporation on sheet metal forming of car bodies. At University Phillip developed his talent for teamwork. He was a contributing writer to the University newspaper, Secretary of the UNSW Students’ Union and was active in the UNSW Metallurgical Society and co-editor in 1963 of “Metallurgical Review,” the annual journal of the UNSW Metallurgical Society. His diverse interests and curiosity about the world around him were likely nourished while at University. Upon completing his Bachelor’s degree, Phillip was awarded a Commonwealth of Australia Postgraduate Research Scholarship. He began his PhD in 1964 on the thesis topic “Studies in Heat Transfer between Dispersed Liquid Metals and Gaseous Atmospheres” working under the supervision of then Associate Professor Noel Warner, an outstanding Professor at the University. Professor Warner is now an Emeritus Professor at the University of Birmingham and is internationally respected for his pioneering theoretical and practical work on established and innovative smelting processes.

Jan 1, 2019

By Stephen L. Chryssoulis

"""Preg-robbing"" of gold by carbonaceous matter during the cyanidation of certain types of carbonaceous gold ores is well documented. Recent studies established that ""preg-robbing"" of gold is not limited to carbonaceous matter. Gold sorbed on the surface of pyrite grains was detected and quantified by TOF-LIMS (Time of Flight Laser Ionization Mass Spectrometry). Crystallites of pyrite from a number of ores from different geological environments have been shown to have gold on their surface apparently sorbed from the ore forming solutions. Surface gold accounts for significant fractions of the gold head assay. Preg-robbing of gold by pyrite from pregnant cyanide solutions was also documented, and accounts for significant losses to tailings. Preventative measures are discussed.1.0 IntroductionThe detection and subsequent quantification of gold sorbed on the surface of pyrite particulates came about during routine determinations of the deportment of gold employing the comprehensive mineralogical approach (Chryssoulis and Cabri, 1990). In some pyritic gold ores it was discovered that the sum of the various forms in which gold ""conventionally"" occurs, was short of the gold assay. The mineralogical procedure used involves the independent determination of each fraction of gold, in other words there is no form of gold which is calculated ""by difference"". The systematic shortfall after having added the forms of gold listed in Table 1 led to the inquiry for the 'missing' gold and its discovery on the surface of pyrite grains, such as crystal facets and fractured surfaces.Preg-robbing of gold by pyrite from pregnant solutions was first described by Lloyd. In his studies, preg-robbing was measured by changes in the solutions/solids gold assays. This paper describes the first application of a direct measurement method for surface gold on pyrite particles from untreated and processed samples, its impact on gold deportment and processing. The advantage of the direct measurement lies in the absence of interference from other forms of gold, leading to more accurate and precise determinations of this unconventional form of gold."

Jan 1, 1997

By M. E. D. Raymont

"During the history of the sulphur industry there have been three distinct phases of production. Factors controlling supplies during these periods have shifted from demand for sulphur to demand for energy and a cleaner environment. The pattern of brimstone production is t raced through these phases and includes estimates of future supply; these indicate an involuntary excess production of some 20 million plus tons per year by 1980 unless some large-scale new uses are found. Traditional uses for sulphur, including fertilizer, chemicals, fibers, etc., are generally expanding slowly; how• ever, supply in ""by-product"" form alone will soon outstrip demand. The predicted oversupply situation can be corrected by the development of novel potential markets. Promising areas include construction materials, insulation and plastics, among others."

Jan 1, 1972

By M. Kalin

"Ecological Engineering and Biological Polishing technology is a decommissioning approach for inactive coal, uranium and base metal operations. To improve acid mine drainage water some fundamental aspects of wetland ecology and sediment microbiology are combined, to provide conditions to allow for biomineralization of the contaminants.This paper summarizes the first records of microbial alkalinity generation in acid mine drainage through the utilisation of the ARUM process. The process requires that the seepage is at pH 4.5 where sulphate reducers utilize sulphate to produce hydrogen sulphide, which in turn precipitates with metals. The pH increase is brought about by alkalinity generating microbes.The ARUM process has been successful in increasing the pH from 2.5 to 7.0. Flow through reactors operated in the laboratory continuously for more than 60 days have removed Ni from 13 mg/L to < 0.01 mg/L. Design parameters are being developed for low flow rates of 5 L/min in a test system receiving seepage from a tailings.1.0 INTRODUCTIONAcid mine drainage associated with mining wastes poses a significant environmental problem. Conventional means to treat acid mine drainage (AMD) use chemical treatment system. Ecological Engineering technology uses natural biological means to curtail and ameliorate AMD during mine operations and at the time of decommissioning. The premise underlying Ecological Engineering technology is that AMD is the result of a natural process enhanced by mining activities. Therefore, in nature, a process providing a natural balance to AMD has to exist, which, when assisted through appropriate means, can counteract the detrimental effects of AMD on the environment. This process is microbial alkalinity generation which is known to occur in wetlands, lake and ocean sediments (Baas Becling et al, 1960)."

Jan 1, 1991

By Ian Bruce

Tailings and water management facilities are essential and integral components of mine and mill operations. They must be managed for the long term in order to ensure that safe and environmentally responsible stewardship is achieved. Toward this end, in 1998, The Mining Association of Canada (MAC) published A Guide to the Management of Tailings Facilities, which recommended the implementation of a tailings management framework (Figure 1) to integrate environmental and safety considerations into each stage of the life cycle of a tailings facility, from initial site selection and design, through construction and operation, to eventual decommissioning and closure. By February 2000 it was becoming apparent that while mining companies were making significant progress toward implementing and documenting tailings management systems, and integrating them with overall environmental management systems, further effort was warranted in their application at the operational level. In particular, a need was identified for further guidance in preparing manuals that outline procedures for the safe operation, maintenance and surveillance (OMS) of tailings and water management facilities.

May 1, 2002

By Gordon R. Harris, Raymond Chalk

Descriptions of typical pulp and paper manufacturing processes are presented, with particular emphasis on the use of minerals and derived products. Some consideration is given to the future demand for these minerals by the pulp and paper industry. Possible influences of techno-logical change and social legislation are suggested and their effect on saltcake demand by the pulp industry is discussed. Predictions are made regarding trends for new and existing paper products.

Jan 1, 1968

By W. L. Nelson

The orebodies at Copper Mounta1n lie along and within a few hundred feet of the contact of an intrusive stock of gabbro with a series of bedded volcanic rocks of the Nicola formation. These. orebodies are all entirely within the volcanic series but in many cases the centre line of the orebody at depth is directly under the gabbro contact at the surface, due to a slight overhang of the gabbro. The gabbro and volcanic rocks are cut by a number of faults and fault zones which did not materially affect early mining operations, but, as undeground openings increased in size, the faults became more important factors in determining mining methods and procedure. Caving methods were adopted to take advantage of ground weakness in fault zones, and the effect of ground subsidence which resulted from the division of the ground 1nto large, independent blocks by faulting had to be considered in planning the sequence of mining of certain ore blocks. The faults have been divided into two classes: the longitudinal system and the cross faults, or &apos;breaks&apos; as they are termed locally. In addition to the two classes of faults, the zones of parallel ore fracture also control mining procedure, but to a lesser degree, in regard to caving or ground subsidence. A third structural feature which influences mining procedure is the mine dyke system. The longitudinal or main fault system roughly parallels the gab? bro contact and is made up of a number of branches and auxiliary fractures. The main fault itself is essentially vertical, but there are a number of branches and fractures on each side of it which, though parallel m strike, may dip as flat as 50 degrees toward or away from the main fault. The full width of the main fault system has not been determined, but it is known to extend beyond the zone of mine workings. A marked schistosity follows the main fault and both schistosity and chloritic alteration have been noticed along the secondary faults of this system. Several prominent orebodies lie along the main fault and its branches. The influence of the main fault system on mining is probably related more to subsidence than to actual cavi.ng, although it is effective in both.

Jan 1, 1950

By Pizhi Zhao, Yingdong Li, Hailong Cao, Yingjuan Feng

"Three types of anodic films (unsealed, hot water sealed and agent sealed) were prepared to study the effects of anodizing pores structure on the adhesive bonding performance of AA5754 automotive sheets. The morphology of the anodic films was examined by using scanning electron microscope (SEM) and the composition was examined by glow discharge optical emission spectroscopy (GDOES). The adhesive bonding strength and durability in corrosive environment were investigated by using single lap shear test and salt spray corrosion test (SST), respectively. The results showed that the pores structure could significantly influence the adhesive bonding performance. The unsealed sample showed porous structure and provided high bonding strength, however, the durability was poor in corrosive environment. The hot water sealed sample showed fine and loose hydrated alumin a structure on the surface and provided high durability in corrosive environment, but the bonding strength was low. In contrast, the agent sealed sample provided both high bonding strength and durability in corrosive environment.INTRODUCTIONAdhesively bonded aluminum joints by using adhesives have been widely used for the realization of lightweight design in industrial applications like automotive and aerospace industry[1, 2]. Durable bonds which are capable of taking structural loads can be created due to a careful consideration of the way in which the joint is formed, the type of adhesive and the appropriate treatment of the adherend surfaces prior to bonding[3-6]. Experiences demonstrate that the surface treatment is the most critical step which could not be disregarded, since it is essential to achieve long-term service capability [7].In structural applications, a bonded assembly is expected to maintain a significant load and may be combined with exposure to harsh environmental conditions in its service life. For this purpose, the pretreatment for structural bonding of aluminum alloy must provide not only strong tensile strength and durability but also good corrosion resistance. Chromic acid anodizing (CAA) process provides an anodized layer which has good corrosion resistance while also exhibiting useful adhesion characteristics as well as lacquer coating retaining characteristics[8].However, the use of Cr (VI) is unadvised from a health and environmental point of view since it is toxic and carcinogenic, and this process is gradually limited even prohibited. Boeing's phosphoric acid anodizing(PAA) process provides a more open pore structure allowing penetration of high molecular primers/adhesives[8]and PAA process is the most widely used pre-surface treatment suitable for adhesive bonding between aluminum alloy components. Rahimi et al. demonstrated that nanostructure can be produced by PAA process and is affected by the time of pretreatment and anodizing parameters [9]. Xu et al.investigated the influence of surface energy and roughness on adhesive bonding through PAAprocess and provided improved adhesion performance under certain anodizing parameter[10]. However, PAA process is normally not recommended for a major concern of deterioration of the mechanical performance of the joints as a result of exposure to a wet and corrosive environment. Sulfuric acid anodizing(SAA)process, recently, has been widely used for corrosion protection and good base coating for the adhesion of lacquers in aerospace manufacturing[11]. The good performance is explained by properties such as the porous morphology and high adsorptive power of the oxide film, the chemical and electrical inertness of the anodized layer. Moreover, modified sulfuric acid could also used for adhesive bonding. Lunder et al. found that anodizing in hot sulfuric acid is promising as a simple, very rapid and environmentally friendly pre-treatment for adhesive bonding[12].Saeedikhani et al. studied the process of phosphoric/boric/sulfuric acids anodizing and found it was is a promising pre-treatment for adhesive bon"

Jan 1, 2018

By Nick D. Rose

Outline ?Background ?History of inverse-velocity for failure prediction ?Methodolog ?Case Histories ?Three case examples of predicted slopefailure to actual date of occurrence ?One case example of mitigated slope failure using inverse-velocity to forecast failure time and schedule remedial measures ?Conclusions

May 1, 2006

By P. Kobylin, K. Haavanlammi, K. Valkama

"Base metals and precious metals can be recovered from a nickel matte or nickel concentrate using the Outotec nickel chloride leaching process. The raw material is leached with hydrochloric acid and the metals are recovered by solvent extraction, where ammonia is used to control the pH. Ammonium chloride is regenerated to ammonia and the side product of this step is calcium chloride solution. The regeneration utilizes either calcium oxide or calcium hydroxide. The calcium chloride solution is used to convert sulfuric acid into a hydrochloric acid solution while producing pure gypsum as a side product. The regeneration and reuse of ammonia and hydrochloric acid in this process will have a positive impact, from the point of view of both operating costs and environmental sustainability. This paper concentrates on the test work and technical concept development performed by Outotec to implement and develop chemical regeneration and recycling into a vital part of the nickel chloride leaching process.INTRODUCTION According to a nickel market analysis, the nickel market is expected to grow in the future. Main driver for this growth is the increase in stainless steel consumption as the living standards are equalizing globally. The expected increase in the amount of electrical cars and the need for nickel in the batteries of electrical cars also gives potential for the increased need for nickel in near future. At the moment the use of nickel in nickel-cobalt-manganese (NCM) and nickel-cobalt-aluminium (NCA) Li-ion batteries is in the range of 14 ktpa. It is estimated to increase to the level of 90 ktpa by 2025. In every era of the nickel industry, Outotec has been constantly developing new processes to create environmentally sustainable and economically viable processing routes. The Outotec® Nickel Matte Chloride Leaching process is a great example of a process that is flexible regarding raw material and could also treat nickel raw materials that are difficult for smelters. Outotec’s main options for pyrometallurgical nickel treatment include the Outotec® Direct Nickel Flash Smelting process (DON) and the Outotec® Ausmelt TSL process. The DON process is operated in Boliden Harjavalta Nickel Smelter in Finland. Ausmelt process is in use for example in Daye nonferrous plant in China. In the Outotec® Direct Nickel Flash Smelting Process, a sulphide nickel concentrate is processed in an Outotec Flash Smelting Furnace (FSF). Producing concentrates and processing them by Outotec Direct Nickel Flash Smelting to matte followed by hydrometallurgical refining offers a reliable route from concentrate to product. In the DON process, high-grade matte with low Fe content is produced in the FSF and the valuable metals in the slag are recovered in an electric furnace (EF). The Outotec® Ausmelt TSL process can use a large variety of raw materials (concentrates, secondary material and scrap metal) as feed. Fuel and oxygen are injected into the furnace through TSL (Top Submerged Lance) and this enables efficient smelting. Both Flash Smelting and TSL plants produce nickel mattes, which can be refined with Outotec hydrometallurgical processes."

Jan 1, 2017

By J. R. D. Gravel, D. A. Poland

"The induration of iron ore pellets has always utilized prefired pellets to protect the pallet cars from the environment of the induration furnace. This paper presents the process used to obtain superior upper sidewalls. These heat resistant castings are used on induration pallet cars, and their life improvements by as much as 400% is a significant step towards the reduction of the prefired (or hearth layer pellets.) The benefit to the industry in the removal of the hearth layer is improved overall productivity. IntroductionThe Iron Ore Company of Canada (IOC) operates with production facilities located in Labrador City, Newfoundland and Sept Iles, Quebec. It has recently been acquired by North Limited, an Australian based resource oriented company. Prior to its acquisition, IOC has examined several methods of operational cost reductions. One of these was an examination of indurrating pallets. Pallets are composed of numerous assemblies and sub-assemblies. The examination of the upper sidewalls began as an intent to increase the operational life of the component. The anticipated net effect was to be a reduction in the overall pallet maintenance cost. All of the components and assemblies have undergone a severe scrutiny. IOC has found that the success of the project has depended upon not only the technical competency of all parties involved, but also upon the ability to share risk, to be innovative, and to find a partner with whom the development can proceed without fear and yet with accountability. IOC has found in Cast Steel Products (CSP) such a partner in the field of pallet development. This paper will undertake to explore the progression into the arena of partnering between IOC and CSP. CSP and IOC met in the fall of 1994. The work of re-engineering the pallets began with an initial order for 36 pallets in March, 1995. The work on the upper sidewalls involved segregation of the effect of alloy development versus physical geometry development. The nature of partnering between the two companies allocated alloy development to IOC and physical geometry development to CSP, yet no advancements were made in either area without the close co-operation or the involvement of both partners."

Jan 1, 1999

By Yihan Liu, Jintao Zhang, Chen Xiao, Xiaomeng Zhao, Guanglei Song

To estimate the performance of the inert anode materials based on NiFe2O4 spinel ceramic during it used for aluminum electrolysis, we investigated the wetting process of cryolite molten salt which is in composition of industrial aluminum electrolysis with carbon anode and NiFe2O4 based cermet materials, by means of determination the interface wetting angle between the molten cryolite electrolyte and the solid anodes interface. The results show that the wetting angle between the electrolyte and carbon anode is larger than 90 angulation, this means that they basically can not wetting; however the nickel ferrate spinel ceramics behaves much better. In regard to the NiFe2O4 matrix materials, their initial wetting angles is 76.9. The initial wetting angles for 1.0wt%MnO2, 2.5wt%TiO2 and 0.5wt%V2O5-doped samples are respectively 56.86°, 52.98° and 51.93°. However, after 50s later, all the wetting angles came down below 15°.

Jan 1, 2015

By S. Fahland, P. Vogel

"The Gorleben salt dome has been investigated since 1979 for its suitability as a repository for the disposal of high-level radioactive wastes. The geoscientific surface exploration was followed by underground exploration of the site beginning in 1983: underground excavation work included the sinking of two shafts from 1986 to 1994, the excavation of the infrastructure area and of drifts located in the first exploration area EB1 within the following years. The exploration was interrupted for ten years from 2000 to 2010 as part of a moratorium. After the expiry of the moratorium in March 2010, the geoscientific underground exploration at the Gorleben site was resumed. The investigations were interrupted again in autumn 2012 due to a political decision. The exploration programme included extensive geoscientific investigations: geological exploration, geophysical investigations, mining exploration and mining observation, laboratory tests, in-situ geotechnical measurements, geological modelling and numerical model calculations. To analyse and interpret the results of the in-situ measurements and mining observation geomechanical, thermal and thermo-mechanical model calculations were carried out. One of the main elements of the in-situ geotechnical investigations were high-resolution geothermal measurements performed in boreholes used for geological exploration and geotechnical tests.The geothermal measurements are used to evaluate several geotechnical findings, e. g. drift closure, rock deformation, stress change, and are completed by thermal model calculations to analyse and interpret the results of in-situ measurements and mining observation. The model calculations have been carried out using the special purpose JIFE code. To consider the whole exploration mine with the adjoining host rock as well as the successive excavation of drifts and boreholes in detail a three-dimensional finite-element model was developed. The model calculations are used to analyse the cooling-off of the surrounding rock of the drifts caused by ventilation. The cooling-off of the surrounding rock is an ongoing process affecting the results of further geotechnical measurements in the near field of the drifts. To predict a realistic time and space dependent distribution of the temperature field of the host rock within the exploration area which is influenced by ventilation thermal model calculations are necessary. Comparing the calculated temperature field with the in-situ determined rock mass temperature field within the exploration area EB 1 the results show a sufficient agreement. Furthermore there is very good correspondence, both qualitatively and quantitatively, between the experimental and the calculated findings regarding the temperature profiles including the effects of excavation and ventilation of the drifts."

Jan 1, 2015

By J. W. Coetzee, H. E. Deist

Carbon-in-pulp (CIP) and Carbon-in-leach (CIL) processes are used extensively in the gold mining sector to recover aurocyanide from solution. This paper discusses the modelling of these operations, using various simplifying assumptions, in order to simulate the effect of changing operating conditions on the dynamics of the system. It is assumed that the adsorption and leaching rates are a function of concentration difference between the source phase and recipient phase. The simulation was set up using Matlab&apos;s Simulink interface. Plant variables are solved using a medium scale Newtonian search algorithm in Matlab, where the differences between the actual and predicted plant outputs are minimized on a continuous time-line.

Jan 1, 2005