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By B N. Morrison

In all metallurgical plants metallurgists require analyses of the various intermediate products, eg flotation feeds, flotation concentrates, tailings, mattes, slags, etc to monitor the efficiency of the plant processes and for plant control purposes. Traditionally these samples have gone to off-site laboratories and there can be some considerable delay before analytical data are received. On-line monitors have to be used for plant control purposes and these are difficult to maintain and can give poor quality data. Recent technological advances in automation in analytical laboratories now allow a far quicker turn-around time for analytical data so they can be of more use to the metallurgist. Automation, which involves the use of robots and fewer people in laboratories, has the added benefit of providing higher quality data as the possibility of human error and bias is minimised. Differences between conventional manual laboratories and automated laboratories are described. Automated analytical laboratories are now becoming the laboratories of choice for mining companies which require large numbers of samples to be analysed on a 24/7 basis on similar sample types using the same sample preparation methods and analytical procedures. Automated laboratories have now been installed in platinum, iron ore, copper and aluminium producing mining companies. A further advantage to metallurgical plants is now the possibility of siting automated analytical laboratories in-plant and designing the plant around the laboratory. Concentrator streams, slags, etc can be sampled by automated samplers, the samples transferred by automation to the in-plant laboratories and all sample preparation and analyses carried out by automated processes. These laboratories require a minimum of staff. Such automated in-plant laboratories have been installed on a platinum mine flotation plant, a platinum mine smelter and steel plants. One is in process of being installed on an iron-ore mine with the sampling being carried out by an automated sampling tower. The procedures followed in planning an automated analytical laboratory for a metallurgical plant are described in detail in the paper. The platinum plant smelter automated system which includes rapid transport of samples by air-tube to the laboratory for the analysis of the samples by XRFS is also described in the paper. It is concluded that automated analytical laboratories can be retro-fitted to most metallurgical plants but they are best suited to greenfield sites.

Jan 1, 2008

By Abraham B. K, Jensen B, Gillies A. D S

The aim of the research was to investigate the feasibility of using an impedance cell and ratio-transformer bridge to measure solids content in coal slurry pipelines. It appeared that this technique could be developed to measure variations in conductance which correlate with solids content. Successful implementation of the measurement technique would have a variety of applications in existing coal wash plants and the potential for automatic process control. A small pilot plant was designed for a feasibility study. This was a closed loop system in which the coal was uniformly dispersed in a tank with a variable speed agitator and then circulated through an external pipe returning to the top of the tank. The impedance cell was located near the end of the external pipe. Slurry concentrations were varied from clean tap water to 50 per cent solids by weight with the addition of weighed quantities of dry coal dust. Ratio-transformer bridge measurements showed that variations in individual observations were equivalent to measurement errors of about two per cent. These probably reflect variations in concentration of the mixture in the pipe. Data for increments in concentration of one per cent indicate that this is about the limit of resolution of the current system. The paper discusses the principles of operation of the impedance cell and measurement system. Results from the pilot study and proposed improvements in the impedance cell design are examined.

Jan 1, 1995

By Bailey S, Avraamides J, Jayasekera S

The anodic dissolution of iron from three different Western Australian reduced ilmenites was investigated using the carbon paste electrode technique. A characteristic current-potential diagram, called a cyclic voltammogram (CV), was obtained for each of the reduced ilmenites. The shape of the CV measured for all three reduced ilmenites was strongly time dependent. The effect of electrolyte composition and temperature on the CV of one reduced ilmenite was also investigated. The results suggest that the initial surface of iron in reduced ilmenite is slow to dissolve and that chloride ions and higher temperatures accelerate the dissolution of this initial surface layer. However, after removal of this layer, the dissolution rate was essentially independent of the electrolyte composition and the temperature.

Jan 1, 1996

Direct seeding or regeneration of vegetation in Australia has been occurring in nature for about 400 million years! From the 1870's till the 1930's, direct seeding by man was used in the south-west of Victoria as a method of re-establishing native vegetation on broadacre farmland. The introduction of improved exotic pasture grasses and the wide-spread use of superphosphate from the 1930's lead to its demise as a farmland revegetation technique.

Jan 1, 1992

Australia has a long and successful record in mineral processing technology extending over 100 years. This has included the development of new processes and equipment and new analytical techniques. These developments have added greatly to the efficiency of mineral processing and thereby to Australia's national wealth. Demands on mineral processing engineers in the future show no signs of diminishing, in fact they will increase considerably as more difficult areas must be treated and the requirements for quality control become more stringent. These demands must be met successfully since mineral processing must continue to be one of the most important technologies in Australia's economic future.

Jan 1, 1989

By Bourgeois F

The population balance concept has provided a useful framework for the description of the operating behavior of the ball mill. This approach finds expression in the so-called selection breakage function model for batch and continuous mills. This model produces very good descriptions of the size distribution of the products from ball milling operations and the model is very useful for the description of batch and continuous mills and, when combined with models for classifiers and other unit operations, provides a solid basis for flowsheet simulation procedures. The breakage and selection function model is essentially descriptive and not predictive because the parameters in the model cannot as yet be related to the fundamental material properties of the material that is broken and to the fracture mechanics that govern the comminution of brittle particulate material during the rapid impact and compression events that occur with high frequency in a ball mill. The population balance approach smears over the individual processes and regards the ball mill as a continuum with breakage occurring continuously in time and space. New experimental techniques, particularly the adaptation of the Hopkinson bar as the ultrafast load cell (UFLC) to the problem of observing the extremely rapid impact fracture of particulate solids, have made it possible to make accurate and consistent measurements of particle strength, particle fracture energy and the single-impact breakage function. These quantitative measurements have been incorporated into a new conceptual model for the description of the ball mill. The model is based on identifying all events that give rise to particle breakage, and using the fundamental experimental data obtained on the UFLC and other single-particle fracture tests, the probabilities of these events can be independently determined. The distribution of impact energies that occur in the ball mill has been established by discrete element simulation of the media motion. The probabilistic description of the individual fracture events and the distribution of impact energies are combined to make a priori predictions of ball mill performance under a variety of operating conditions. The new model is used to calculate the selection and breakage functions for quartz in a small batch mill.

Jan 1, 1993

By Warren L. J

In the mineral processing industry solid-liquid separation within a thickener usually requires the addition of a synthetic flocculant to enhance the settling rate of fine particles. The characteristics of the resulting flocculated suspensions may vary considerably depending upon the physical and chemical conditions which prevail during the flocculation process. For example, parameters such as flocculant type, dosage and solution concentration, surface chemical characteristics of particles and the suspension agitation conditions can influence the degree to which the particles aggregate. Aggregated suspensions exhibit various structures, and range from those composed of small, dense aggregates to those containing large, voluminous aggregates. The size distribution and structural type of the aggregates which form within the feed-well of a thickener can have a dramatic effect upon overall thickener performance. Thickener performance cannot be optimized without optimization of the aggregate structure produced in the feed by synthetic flocculant addition. This has required the development of new techniques to quantify the nature of aggregated suspensions, details of which are presented in this paper.

Jan 1, 1989

By Field R. V, Graieg O, George T. J

The design, construction and operation ofa laboratory scale rotary pot kiln are outlined. Charges ofup to 3 kg can be heated to temperatures up to 1200°C in a controlled atmosphere. Some examples of pyrometallurgical investigations carried out using the kiln are briefly described, including thermal reactivation ofcarbon using steam at 550-850°C, high temperature testing ofkiln liners for corrosion resistance to fluoride, and calcination oflimestone. Results obtained from these trials allow either direct scale-up to the Engineering Chemistry Laboratory's pilot-scale (50-100 kg/hr) rotary kiln or modifications to be made to commercial scale processes and/or equipment.

Jan 1, 1986

By F Cappuccitti

A colourimetric technique, originally developed for methyl iso butyl carbinol (MIBC) based on the Komarowsky reaction, has been extended to a wide range of common mineral flotation frothers. The procedure, which is briefly described, is shown suited to on-site determinations in a campaign at Kennecott Utah Copper Copperton Concentrator (Rio Tinto). Some observations are described, including: frother (MIBC) concentration evolution down a bank, frother distribution between pulp and froth phases, and loss of frother over time due to adsorption on certain minerals. A possible interference with a fuel oil addition was overcome. MIBC in recycle water was also measured. The ability to monitor frother easily will help interpret gas dispersion behaviour and should permit further optimisation of flotation cell hydrodynamics and chemistry. The capability to directly measure should help optimise the type, amount and location of frother addition, and to assess frother recycled with reclaim process water.

Jan 1, 2005

By Virtanen M

Grinding has been one of the areas of major development at Outokumpu's concentrators. During its early years the company used entirely rod and hall mills, but due to the high costs of metallic grinding it began the testing of autogenous grinding as early as the 1950s. In the late-1970s, the company's own modification for two stage autogenous grinding was ready for industrial use. Surprisingly late, in the 80s - 90s, an interest rose to check also the effects of grinding methods on flotation results. This paper firstly gives a short history of the development work of Outokumpu type autogenous grinding, called 'Outogenius'. The effects of some grinding methods on the process results of two nickel ores are then reviewed. The tests to date show notable effects of grinding methods on flotation.

Jan 1, 1996

By Granholm S

The current emphasis within the mining industry to reduce the cost of production has stimulated interest in the fields of maintenance and operational reliability of capital intensive mining equipment. From an economic point of view, high reliability is desirable to reduce the maintenance costs of the systems. Two graphical methods consider reliability analysis. The first one, the method of Total Time on Test (177)-plotting deals with the reliability data which are free from trend and serial correlation. The second method which is based on time dependent modelling approach deals with the data which are not free from trends and serial correlation. The examples show how these graphical methods can be used to calculate the optimal maintenance intervals for components or systems.

Jan 1, 1991

By Gresham J. J

The rapid and successful development by Western Mining Corporation Limited (WMC) of a gold mining industry based on the deposits of the Kambalda-St Ives group, was the final chapter in a story that started some 85 years earlier. Although the exploration work that led to the development of the current mining operation took place in the 1970s and 1980s, the successes had their roots in the 1890s and it took three gold rushes, and separate uranium and nickel exploration booms to make the discoveries Possible.

Jan 1, 1991

Mathematical modelling of continuous rotary vacuum filtration has been limited by the wide range of variables and the absence of connecting equations linking the variables. The filter type and size, mechanical design and predicted performance are generally determined by laboratory leaf tests on representative samples of slurry, or plant samples from an operating filter. A model has been developed which includes the major process variables such as slurry feed rate and concentration, cake thickness, wash water and air flow rates, to predict the filter production throughput, cake moisture and residual solubles. Where possible the model incorporates well established equations relating form filtration, washing and drying rates of the filter cake. Where an equation has not been formulated, standard curve fitting programs have been used to establish an algorithm. The theoretical equations and the derived algorithms are defined in the text. A major feature of the model is that operators, metallurgists, process, mechanical and instrumentation engineers become more aware of the interaction of process variables, the principles of the equipment design and its limitations when operating at peak performance. The model has specific application in the alumina industry where a high moisture content of the filter cake can increase chemical losses and energy costs, and in the coal industry where overseas companies are insisting on lower export coal moistures.

Jan 1, 1989

By Kyle J. H, Misra V. N

The recovery of copper from a flotation concentrate using ferric chloride leaching has been investigated. The concentrate from the Horseshoe Lights Mine near Meekatharra, Western Australia, contained mainly digenite, pyrite and talc minerals. Over 95 per cent of the copper was dissolved in an acidified ferric chloride solution in one hour at 70¦C and ambient pressure. The pyrite and gangue minerals did not react. The leaching process was found to consist of four separate reactions and the shrinking core model was used to describe the process. The effects of particle size, temperature, concentration of FeCls, stirring speed and leaching time on metal dissolution were investigated. The apparent activation energies in the second, third and fourth reactions of leaching of copper concentrate were 28.8, 11.9 and 53.9 kJ/mol, respectively. The optimum conditions for the leaching of copper from the concentrate, within the range of conditions studied were: particle size 63 per cent minus 38 ¦m, a ferric chloride concentration of 1.48 M, a temperature of 70¦C, and a stirring speed of 800 rpm.

Jan 1, 1991

In Situ Bioremediation of a Heavily Polluted Alkaline Soil in a Uranium Deposit

Sep 13, 2010

A pilot plant has been constructed for the low temperature carboni-zation of Wallarah (N,S,W6) coal at the rate of 300 pounds per hour. The plant was built and tested at Australian Mineral Development Laboratories for Broken Hill Pty, Ltd. Char product was required within the specifi-cation 15.5 `S' 1 per cent volatile matter. The design was based c atz an entrained state carbonizer developed by Parry and U.S. Bureau of Mines co-workers at Denver, U.S.A. The method involved the carbonizatioan of fine coal by entrainment with air in an externally heated reactor.. The heat required for carbonization of tits coal was supplied to the be, both through the reactor walls and also by internal cambustion of products .

Jan 1, 1963

The type of population encountered in the sampling of coal, ores and other products of natural phenomena is one in which the variance within a cluster of elements generally increases steadily as the size of the cluster increases. To enable estimation of variances of stratified random or systematic sampling for such populations one must model the serial correlation function or alternatively, the variogram function. The author has postulated a specific symmetry of the serial correlation function which leads to expressions with rich theoretical and practical implications. These expressions provide a spatial correlation function which explains power law relationships often observed in studies of dispersion variances. They also enable straightforward calculations of sampling variances. The importance of the role of finite population size in the equations leads one to examine previously held concepts of ælargeÆ and æsmallÆ sample populations. The model based on the symmetry postulate is a fractal model with the serial correlation function of a hypothetically infinite population being of the same form as that developed by Mandelbrot for discrete fractional noise. Techniques used in fractal mathematics apply, including box counting and fitting of a dimension function. The paper establishes a framework for the understanding of this fractal theory and demonstrates how to calculate sampling variances from the model variogram using simulated data fitting the model.

Jan 1, 2008

The investment worth of a mineral deposit can only be realistically evaluated in relation to specific engineering design criteria, which fully details the proposed method of exploitation. These criteria have not in general been taken into serious consideration when leaseholders have reported reserves in the past. In fact, many "reserve" figures quoted are probably more correctly classified as geological resources. The industry now recognises that it is necessary to take into consideration not only grade and mill recovery factors, but also likely mining and processing costs as well as the current market price for the commodity. Once having estimated those costs which are applicable to the resource under study, they can be deducted from the gross inherent worth of the orebody to result in an estimate of the potential net revenue. Through a process of interactive trial mine designs and evaluation, reserves can be quantified to provide an estimate of the available recoverable economic reserves given a set of assumed cost and operational parameters. It follows then, that the available economic reserve recoverable from a given resource will vary from time-to-time as cost and price factors vary in response to changing technology and economic factors. A methodology is described which may be used to derive economic recoverable reserves based on a computerised model of the geological resource data and appropriate economic and operational cost algorithms. Examples are provided from both coal and gold studies to illustrate the impact of economic criteria on the magnitude of the reserve figure reported for each project.

Jan 1, 1987

By T A. Helms, P Gottlieb, S E, R Bateman

In response to the ever-increasing challenges facing the modern gold mining industry and the need for improved gold recoveries within all processing streams, CSIRO has upgraded its latest automated mineralogical analysis system, QemSCAN (formerly QEM*SEM), with special purpose hardware that speeds up the location and measurement of precious metal-bearing phases. By rapidly scanning the surface of polished blocks, and accepting only fields that contain the minerals of interest, QemSCAN is able to find, map, and quantify target minerals in extreme detail. Phase identification and quantification is achieved by placing a grid of points over the target particle and collecting X-ray information at each analysis point. The resulting mineral maps provide the metallurgist with a complete textural description of all gold-bearing phases within the product measured, together with quantification of the gold phases in terms of their modal abundance, particle size, mineral associations, relative contributions to gold deportment and liberation characteristics. Examples are presented which illustrate how QemSCAN is able to find and quantify gold-bearing phases within low-grade ores from the Super Pit, Kalgoorlie. This work is the result of a collaborative project between Kalgoorlie Consolidated Gold Mines (KCGM), CSIRO Minerals, and the University of Queensland, and is on-going.

Jan 1, 2000

By S R. Grano, J Duan, T A, D Fornasiero

We have determined the experimental rate constants for chalcopyrite particles floated from a complex sulfide ore and compared them with those calculated using a recently developed flotation model. The model incorporates contributions from the efficiencies of collision, attachment and stability between particles and bubbles, as well as their frequency of collision. For these calculations, the contact angle of the chalcopyrite particles in the ore was obtained independently using a surface spectroscopic approach. The calculated flotation rate constants were in good agreement with the experimental data and able to reproduce the characteristic maximum in flotation rate constant for particles of intermediate size. The values of bubble velocity and turbulent dissipation energy derived from these calculations are relatively low and may well correspond to mean values of these parameters inside the flotation cell. We have extended this approach through the application of a property based model to an operating plant, with a satisfactory outcome.

Jan 1, 2005