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By R. Yang

This paper presents a kinematic approach for blast modeling with examples of blast models that were developed previously. A kinematic approach was applied successfully in developing blasting models that can simulate all blast design parameters for field applications. Several applied blasting models have been developed and applied widely in the world. A kinematic approach to blast modeling refers to using measurements of kinematic quantities such as the velocity, strain, or displacement and well-established assumptions to model blasting phenomena, rather than being restricted to use first principal of physics, such as, the stress- and material-constitutive relations. The kinematic quantities are easy to measure in the field. Due to the complexity and inhomogeneity of rock mass properties, using first principles of physics, many parameters of rock and explosive properties must be involved, which are hard or impossible to quantify. This creates a major impediment when trying to simulate the total process of blasting based upon first principles of physics. The 3D kinematic model for muckpile formation was developed and applied to open pit blasts. The multiple blasthole fragmentation model developed during recent years has been applied successfully to many mine sites around the globe. These models are typical examples of blast modeling using the kinematic approach, which enables the models to catch major trends of the blasting process and explicitly simulate full blast design parameters and complex geometries. Blast modeling using the kinematic approach results in easy model calibration and validation against field measurements and effective applications to practical problems. Using kinematic models of the muckpile formation and the multiple blasthole fragmentation model, this paper demonstrates the merits of the kinematic approach for blast modeling. New developments of the models were also presented in the paper, which illustrate the potential of the kinematic modelling approach.

Mar 2, 2022

By Lilly PA, Kavetsky AP

An empirical, kinematic model is developed which calculates the trajectory of individual blocks of rock in a blast, their point of impact in the muckpile and the final shape of the muckpile. The method is based on the determination of initial block velocity and requires input on stemming length, bench height, subdrill, burden, spacing, energy of explosive per unit length of blasthole, energy attenuation rate and resistance to movement. The model, which will form part of a comprehensive blast simulation package, has application in open cut mining in predicting muckpile geometry and the movement of grade blocks during blasting, which in turn impact on shovel productivity and grade control.

Jan 1, 1986

By R. R. Liebenberg, M. I. Brittan

The kinetics of the copper segregation process has been investigated. The experimental strategy used to isolate the rate-controlling reaction step is described. This step was found to be the chloridisation of the oxide copper minerals in the ore. The link between the rate of chloridisation and the overall rate of segregation is demonstrated experimentally. The influence on the kinetics of the various parameters in a TORCO system is examined and the implications are discussed

Dec 1, 1971

A kinetic model for leaching of various metals with different lixiviants in a batch system has been developed. Material balances for reactants and products at the solid/liquid interface were formulated and solutions to these balances were obtained in view of practical conditions. Special emphasis has been given to examine mixed controlled reaction systems where both heterogenous reaction and mass transfer play important role on the overall rate expression. The resulting kinetic expressions for either powder or rotating disc are discussed in light of experimental findings for various metals. Examples of the metal dissolution systems considered in this study include cobalt, nickel, copper and gold in acid, cyanide or ammoniacal solutions.

Jan 1, 1992

By J. J. Jonas, G. R. Stewart, A. M. Elwazri

Two important parameters for dynamic recrystallization can be derived from the changes in the strain hardening rate: the critical strain for initiation of dynamic recrystallization and the point of maximum softening. In this work, these values are determined from the flow stress-strain data obtained in continuous compression testing in the range 900-1100°C. The resulting strains are used to calculate a kinetic model of dynamic recrystallization for two materials: 304 austenitic stainless steel and a hypereutectoid plain carbon steel. The mechanical parameters used to define the proposed model are confirmed with quantitative metallographic analysis of the recrystallized microstructure.

Jan 1, 2004

By Neng-Wen Yu, Shau-Jun Zhu, Ji-He Wei

The desulfurization process by powder injection and blowing in the RH refining of molten steel and its mechanism have been considered and analyzed. Based on the two-resistance mass transfer theory and the mass balance of sulfur in the system, a kinetic model for the process has been developed. The related parameters of the model, including the mass transfer coefficients and the effective amount of powder in the molten steel being treated for desulfurization, have been more reasonably determined. Modeling and predictions of the process of injecting and blowing the lime-based powder flux under assumed operating modes with the different initial contents of sulfur and amounts of powder injected and blown in a RH degasser of 300 t capacity have been carried out using the model. The relevant circulation rate of the liquid steel and the powder injection and blowing rate were taken to be 100 t/min and 150 kg/min, respectively. The initial contents of sulfur in the liquid steel to be treated and the amounts of powder injection and blowing were respectively assumed to be 0.007, 0.006, 0.005, 0.004, 0.003, 0.002 mass-% and 10, 8, 6, 5, 4, 3 kg/t-steel. The total treatment time for desulfurization under each mode was set up at 24 min, equivalent to eight circulation cycles of the liquid steel to be treated. The results indicated that the predictions made with this model are in good agreement with some data of the industrial experiments and practice. Injecting and blowing the lime-based powder flux with the composition of 85 mass-% lime (CaO) + 15 mass-% fluorspar (CaF2) of 3-5 kg/t-steel, it is possible to decrease the sulfur content in the molten steel to ultralow level below (5-10)x10·4 mass-% from (60-80)x 10·4 mass-%. The total treatment time needed will appropriately be 12-20 min. Intensifying the powder injection and blowing operation and increasing the circulation rate of the liquid steel may effectively' raise the rate of the process in RH refining. The model may be expected to offer some useful information and a reliable basis for determining the reasonable process parameters and help in optimizing the technology of desulfurization by powder injection and blowing in the RH refining of molten steel.

Jan 1, 2000

By E. V. Cilento, K. A. DiGregorio, R. C. Lantz

"DIGREGORIO, K. A., E. V. CILENTO, AND R. C. LANTZ. A kinetic model of superoxide production from single pulmonary alueolar macrophages. Am. J. Physiol. 256 (Cell Physiol. 25): C405-C412, 1989.-A kinetic model was developed to describe the production of superoxide (02) by single pulmonary alveolar macrophages (PAM). Model predictions were compared with experimental results obtained from single rat PAM. The 02 was quantified by measuring the reduction of nitro blue tetrazolium (NBT) to a diformazan precipitate (NBTH,) from video-recorded images of individual cells. The kinetic model considered three reactions: 1 ) the production of extracellular 02 from the reduction of oxygen by NADPH oxidase using intracellular NADPH as the substrate, 2) the subsequent dismutation of 02 to form H,O,, and 3) the reaction of 02 and NBT to form diformazan. NBT specificity for 02 was analyzed by comparing results in the presence and absence of superoxide dismutase (SOD) that catalyzes the dismutation of 02 to H,O,. Measured PAM heterogeneity was accounted for by varying the concentration of intracellular NADPH, its rate of depletion, and the concentration of intracellular NADPH oxidase in the kinetic model. Model predictions compared favorably with experimental results except when SOD was present. This discrepancy may be due to diffusional limitations because NBT is a relatively small molecule (818 mo! wt) compared with SOD (34,000 mol wt). In addition, the cell surface is both ruffled and negatively charged, which may introduce steric hindrances and/ or electrostatic effects, since SOD is also negatively charged, whereas NBT is positively charged.PULMONARY ALVEOLAR MACROPHAGES (PAM) protect the lungs by phagocytizing foreign debris and bacteria. This process is accompanied by the production of superoxide anion (02) at the surface of the plasma membrane (3, 31). Superoxide readily dismutates to form H20 2 and subsequently, other oxygen metabolites which have been shown to be both antibacterial and cytotoxic (21, 25, 35).Superoxide is produced from the reduction of extracellular O, at the surface of the cell membrane by NADPH oxidase by the following reaction (3, 4)"

Jan 1, 1989

By F. A. Olson, S. L. Pohlman

A unique method of measuring weight loss as a function 3 of time, with a sensitivity of 10-5 grams, while leaching copper minerals with a flowing acid leach solution has been developed. Kinetic results obtained coupled with visual and microprobe analyses show topochemical reaction for the leaching of chrysocolla with sulfuric acid. The kinetics follow a shrinking core model and show ion diffusion through a product layer, chemical reaction at the unreacted core interface and mass transfer through the boundary layer as being important.

Jan 1, 1974

By F. -Z. Ji, A. G. Irons, M. Barati, K. Coley

In order to optimize carbon injection into oxidizing slags, in terms of carbon and iron yield, we must have a detailed understanding of the kinetics of the reactions involved. The current study measures the rate of carbon oxidation during injection at steelmaking temperature by means of injections of coal into EAF slags. The compositions of analysed outgoing gas were used to calculate gas flow rate and hence the gasification rate of carbon. A fundamental equation to predict residual carbon in slags was developed. The predictions using this model at moderate injection rates are in good agreement with experimental data. The reaction rate of EAF slag with carbon is under mixed control by the slag gas and the gas carbon reactions. The relative importance of each step depends mainly on the v-ratio of slags. A relative reactivity parameter ? has been defined and it is found to be important to carbon-slag reaction kinetics and slag foaming. Key words: carbon-slag reaction, kinetics, slag foaming.

Jan 1, 2004

By V. Annamalai, J. B. Hiskey

Abstract-The kinetics of copper cementation on a rotating disc of pure aluminum were studied as a function of chloride ion concentration, rotational speed of the aluminum disc, hydrogen ion concentration, copper ion concentration, and temperature. The optimum experimental conditions for all the parameters were determined. Chloride ion was found to destroy the naturally existing aluminum oxide film, and enabled the cementation reaction to proceed. A two-step rate, observed in most of the experiments, was attributed to the attainment of a roughened surface. An Evans diagram for the copper-pure aluminum system was constructed and utilized in predicting the controlling mechanism of the system. At low temperatures (<33°C), the rate with an experimental activation energy of 20.36 kcal mol-1 was controlled by the presence of an oxide layer. While at higher temperatures presence of an oxide layer. While at higher temperatures (>33° mol-1 was controlled by ionic diffusion. The deposits obtained were pure copper and not a copper-aluminum alloy. The amount of aluminum dissolved was determined for each experiment, and the maximum excess consumption was found to be only 40%. The structural characteristics of the copper deposits were studied using a scanning electron microscope. These observations indicated that the deposits were either bulbous, massive crystalline, or dendrites of different degrees of fineness depending on the experimental variables. The reaction rates seemed to depend on the deposit structures in a predictable way when a particular experimental parameter was varied.

Jan 6, 1978

By Hu Long

Pyrite, as the host mineral in refractory gold ores and concentrates, has been treated by pressure oxidation in sulfuric acid solutions at temperatures above 180°C to liberate gold prior to cyanidation since the 1980&apos;s. However, no data is available on the kinetics of pyrite during acid pressure oxidation over the temperature range of 180 to 230°C which is the range employed by most commercial plants. The dissolution of pyrite (FeS,) in sulfuric acid solution under oxygen pressure was investigated at temperatures ranging from 170 to 230°C. The effects of temperature, particle size, agitation speed, oxygen partial pressure, and pulp density were evaluated. The effects of foreign ion addition and the concentration of sulfuric acid were also examined. The apparent activation energy was estimated to be 42.6 kJ/mol in the temperature range 170 to 230°C. The reaction orders with respect to particle size and oxygen partial pressure were found to be -1.5 and 0.5 at 210°C, respectively. Experimental evidence suggests that the kinetics are limited by the surface chemical reaction initially, and then also to some extent by the diffusion of ferrous ions away from the particle surface.

Jan 1, 1999

By G. Gabra

The kinetics of acidified thiourea leaching of pyrite concentrate was investigated at temperature ranging form 20 °C to a 60 °C. The effect of various parameters on the dissolution rates are discussed. The gold extraction was found to be zero and first orders with respect to Fe (111) and thiourea concentration, respectively. The order of the reaction with respect to sulfuric acid was found to be zero. The activation energy was determined from the Arrhenius plot as 2,039 kcal mole -1 (for a freshly prepared acidic solution containing Fe (111) as the oxidant and at 800 rpm stirring speed. This relatively low activation energy value suggests that the gold extraction is controlled by a-physical phenomenon. Under optimum conditions, more than 90% of gold has been dissolved in about 30 min. and 95% in 60 min. Attempt to recover gold from thiourea solution using active carbon is also discussed.

Jan 1, 1984

By Raul A. Deju

This paper shows how one can relate the chemical reactions between water and a silicate bed to the equations of flow. First the reaction mechanism is studied both theoretically and experimentally. Once the reaction mechanism is established, the equations of flow are solved and a solution (under physically reasonable side conditions) is obtained. Experiments to substantiate the solution are also presented.

Jan 1, 1969

By Sukumar Bandopadhyay

In recent years, research in the field of artificial intelligence (AI) has had many important successes. Among the most significant of these has been the development of powerful new computer software known as the "expert systems". Expert system programs designed to provide expert-level consultative advice in mineral exploration (Duda et al, 1981), scientific (Feigenbaum, Buchanan and Lederburg, 1971) and medical (Shortliffe, 1976) problem solving are generally acknowledged to be among the forerunners of this research. As the decision makers virtually in all fields face a more complex and involved world within which to operate, the need for some decision support is also becoming urgent. Thus applications of expert systems continue to spread out reaching problems that, because of their dimensions or particular aspects, set more demand on the decision methodologies. To meet these new requirements, many activities which were performed in the past by the domain expert or engineer must become automated. Furthermore, previous research (Dawes and Corrigan, 1974; Dawes, 1979) has shown that automating an expert&apos;s decision rules often provide better decision than the expert does. For large systems it would be very useful (or even necessary) to have formal tools, allowing one for example, to automatically discover inconsistencies, contradictions or redundancies, or to identify the possibilities of wrong lines of reasoning in the decision process.

Jan 1, 1990

By JOSEPH MACDONALD

STRIPPED of its romantic possibilities, mining is a commercial business, carried on for the profit there is in it, and the business of the manager, in its ultimate analysis, is to make the profit as large as possible. The general manager of a mining company should keep himself personally familiar with all the details of its operations. If be fails to do so, chaos results, labor becomes inefficient, costs go up, and profits go down. Nowhere is this emphasized more than in Mexico. If the mining operations are extensive and complex, involving, besides the work of mining the ore, its transportation and treatment by various milling operations, and the marketing of the products, the business, to be carried on properly, must be divided into a number of main departments, which are subdivided into minor departments. Each main department should be under the immediate charge of a superintendent, or a foreman, and each minor department under a shift-boss. Organized in this way, and with all the principal centers of activity connected by telephone, the manager can keep in touch at all times with the details of every branch of the business, and be in a position to perform effectively the full duty of manager. The ?total cost of mining operations may be broadly divided under the heads of Labor, Supplies, and Marketing. Of these, it will be found, on averaging a number of cases, that the cost of labor will be about two-thirds of the total cost. The importance, therefore, of an efficient labor-department will be apparent. This department must be sub-divided and organized differently, according to the peculiar conditions at each mine, and no one system, however well suited for one particu-

Jan 1, 1909

By T. I. Martinovic

A major investigative&apos; program was conducted on the development of an acceptable substitute organic binder for bentonite for the pelletizing of the Iron Ore Company of Canada&apos;s Carol concentrate. The first phase of the program covered an evaluation of several organic binders in laboratory tire balling in order to identify the most promising potential organic binders. Based on the green ball quality obtained, Peridur C-10, Alchem 8C26 and peat moss were selected for full scale pot-grate testwork. The selected binders were tested with various pelletizing mixes (acid, dolomite, limestone and fully fluxed). The pot-grate test results showed that an acceptable pellet quality can be produced with the use of Peridur C-10.

Jan 1, 1989

By Geoff W. Seward, Charles J. Maes

INTRODUCTION The work of the metallurgical engineer engaged in developing a leach, solvent extraction electro- winning process usually begins in the laboratory and generally proceeds via pilot plant testing before finally resulting in a commercial operation. The path leading to the development of the eventual process will involve a test program on leaching in order to derive information on the amenability of the copper-bearing material to acid dissolution, under various conditions. Commonly in North America the leach process of choice is either dump or heap leaching but it may also be in-situ leaching or the treatment of mine waste- waters and bleed streams. In the past, agitation and vat leaching have also been included in the list of options. Currently the economics of copper production dictate that only material of mineralogy and grade, capable of being leached without prior milling, will lead to a viable process. This is not necessarily true in other parts of the world where grades are higher and milling costs lower and therefore this paper con- fronts all the techniques available to the metallurgical engineer in terms of the evaluation of the solvent extraction process. Understanding the objectives of a laboratory and pilot plant evaluation of a solvent extraction route is important and these are described in some detail in this paper. Of at least equal importance is understanding limitations of such a test program and this aspect of process development is also discussed with reference to the kind of equipment and experimental practices that have been shown to produce results consistent with the objectives. WHERE TO BEGIN? At the inception of a project much information is developed on the variables of the leach process and indeed in some instances the type of leach that best suits the ore to be treated is the subject of intense investigation (Wadsworth 1983). The decision to treat the leach solution by solvent extraction focuses attention on the selection of the extractant most suited to the nature of the chemical composition of the solution. A laboratory screening program will probably need to be arranged in order to assist in narrowing the options and the following is suggested for this initial screening. Selection of a Representative Leach Solution This is preferably obtained from leaching a representative sample of the ore under conditions likely to pertain in the commercial leach circuit. As the conceptualized circuit flow sheet will undoubtedly involve the recycle of aqueous solutions via the leach, then it is desirable to know the nature of and the likely level of the impurity ions in the solution as well as the concentration of copper. The other most important parameter that is required is the free acid (Anon, Acorga Analytical Method) content of the solution. As a rule of thumb, it is always true that recovery across SX is maximized as the pH of the leach solution rises. Whilst a high pH may be desirable for SX recovery, it is not always desirable for the pH (or more correctly, the free acid) of the leach to rise too high. The working range, therefore, tends to be between 1.5-2.5 pH. At an early stage in process development it is likely that a number of ill-defined conditions will exist, making it difficult to decide on typical leach conditions in which case the screening tests should be carried out using a synthetic leach solution prepared from laboratory chemicals. In doing this the copper and free content should be carefully controlled along with the appropriate addition of major impurity ions as their sulphate salts. Preparation of Suitable Organic Solutions Manufacturers information sheets on the reagents to be tested are required at this stage The information necessary to make an informed judgment on reagent performance is: Copper Uptake Value. This will indicate the amount of copper that can be extracted by a reagent as a function of its operating concentration in a

Jan 1, 1986

By Danqing Xu, A. W. Khair

"This paper presents a laboratory simulation of regrinding and resulting dust generation. An Automated Rotary Coal Cutting Simulator (ARCCS) was modified to conduct regrinding experiment. In order to estimate the effects of coal properties and operating parameters on regrinding and dust generation, an orthogonal fractional factorial experimental design was implemented in regrinding experiment. Marple personal cascade impactors, Series 290, were used to measure dust concentration during experiment. Three types of coal seams, namely, Waynesburg, Pittsburgh, and Lower Kittanning, were used to represent different coal properties. Experimental results and complete parametric analysis were presented.In a rotary cutting system, all the broken coal and part of the remaining coal from previous cutting cycles must be transported through part or entire circumference of the cutting drum. This transportation of already recovered coal through the cutting zone of rotary head makes it a rotary grinder. Some of the coal particles will be subjected to secondary fragmentation or regrinding in the process. The potential effect on dust generation by regrinding is significant because the cutting head utilizes kinetic energy to comminute recov¬ered coal material. The moving bits and bit blocks on the cutting head impact coal particles and transfer some of their kinetic energy to the particles. After obtaining kinetic energy, coal particles are free to impact one another and they also impact the coal seam or cutting head. During impact, high impact force and high internal stress concentration are created in the particles. Kinetic energy is transformed into strain energy. When stored strain energy exceeds allowable strain energy, the particles will break. A great amount of respirable dust will be generated due to impact failure. In reality, regrinding occurs at the same time as primary cutting. The particles to be ground are the result of primary cutting. Both primary cutting and regrinding produce dust. Therefore, it is impossible to separate regrinding from primary cutting. In order to study respirable dust generation by regrinding and analyze the influencing parameters, a laboratory approach was adopted. In this approach, it is possible to study the regrinding separating from primary cutting."

Mar 1, 1992

By Tooley S. M

An experimental investigation of the hydraulic cuttability of coal from the Theiss Dampier Mitsui mine near Moura, Central Queen land illustrated the ability of established cutting equations to describe the behaviour of the coal during cutting. The experimental equipment developed for the work proved reliable. The results of the experimental programme are consistent with accumulated experience from overseas.

Jan 1, 1985

This case study describes various aspects of establishing a laboratory facility for testing chemically-cemented fill materials. The applicability of data obtained from such a facility related to mine conditions depends on many factors: kind of data, type of testing facility, sample parameters (composition, geometry, size, etc.). The equipment employed must be adaptable, to accommodate variations in sample size and properties. The design, construction and operation of the testing facility is described, and its application to fill samples prepared from sulphides and oxides both chemically and naturally cemented. The present system was selected following an extensive study of equipment available for testing materials in the fields of rock mechanics and construction materials. The strength testing&apos; facility incorporates Linear Variable Differential Transformers for monitoring both lateral and axial displacements during sample compression. The output from these and from other related instrumentation can be recorded or fed direct to a computer, enabling stress-strain data to be printed out while the test is in progress. Also described are controlled environment curing facilities which allow samples to be cured or weathered under different temperature or humidity conditions to simulate long-term ageing and in place conditions.

Jan 1, 1973