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By Alexey Lozhko

The technical-and-economic furnace exploitation indices are considerably influenced by the system of heat utilization. In the situation of total output decrease works are forced to exploit furnaces at the partial loading, sometimes even at the idle running for the sake of steam production. The furnace exploitation in this regeme is known to cause the increase of the heat portion, taken away together with waste flue gases. The losses can be partially compensated at the expense of heat exchange efficiency development in the recuperator or heat-exchanger. One of the well-known methods, characterised by high efficiency and low expenditures is the intencification of the heat exchange process by the means of pulsation method.

Jan 1, 2006

By Adriana Gómez

White dross is a result of the aluminum oxidation during its primary production and is mainly composed of metallic aluminum, Al2O3, with minor amounts of AlN and some other oxides. Because of the great variety of phases, the quantitative characterization is complicated. This work shows a quantitative method to determine the main phases of white aluminum drosses by means of X-ray diffraction (the Rietveld method). Nowadays the Rietveld method is maybe the most useful method for obtaining quantitative phases information in multicomponent mixtures, this method permits relatively quick quantitative phase analysis by fitting the calculated X-ray diffraction profile with the observed one. The analysis were done using powder with a grain size less than 45 µm; to obtain the suitable material size the aluminum dross was grounded by ten minutes, several times. The grounded material was screened, and the material smaller than 45 µm was taken to quantitative XRD analysis. Keywords: Rietveld Method, Characterization, Aluminum dross.

Jan 1, 2005

By Vincent Menard

The purpose of the present work is to demonstrate the removal of manganese from a neutral leach zinc-rich solution ([Zn] =150 g/L) at 80°C by oxidative precipitation using a gas mixture of sulphur dioxide (SO2) and oxygen (O2). In order to determine the optimum conditions for manganese removal, several bench-scale semi-batch experiments were performed, where the effects of ORP and gas mixing were investigated. These tests showed that SO2/O2 is a fast and effective oxidant for removing manganese down to ppm level as long as the appropriate ORP is attained/maintained and gas transfer kinetics are optimized.

Jan 1, 2006

By Wenming Wang

Recycling of retired cadmium telluride (CdTe) photovoltaic (PV) modules has attracted attention due to new European environmental regulations. Recycling tellurium from CdTe PV modules is becoming more important because of the low availability of this metal. We investigated several treatment paths for reclaiming tellurium from solutions obtained from leaching fragments of CdTe PV modules. Our experiments showed that conventional soda ash neutralization/hydrolysis methods recovered only 50~60% of tellurium. However, by appropriately combining neutralization and sulfide precipitation, almost all the tellurium present in the leaching solution was precipitated and recovered; the concentration of tellurium in the processed solution was reduced from 900-1000 mg/L to less than 1 mg/L, yielding a tellurium recovery greater than 99%. This method can be incorporated in the scheme of recycling spent CdTe PV modules and manufacturing wastes. It may be also an alternative to the current operations for removing tellurium from copper anode slime leaching solutions.

Jan 1, 2006

By Xiaowen Liu

The thermal decomposition of diaspore was investigated by thermogravimetry (TG),differential scanning calorimetry (DSC), X-ray power diffraction(XRD),infrared (IR)spectrain this paper. The thermal decomposition mechanism of diaspore was discussed according to Coat-Redfer equation. It was found that the decomposition of diaspore was carried out at 500?,and the peak temperature was 530?. The electrovalent balance of diaspore was destroyed. The previous crystal structure was changed. a- Al2O3 was obtained after thermal decomposition. The activation energy is 287KJ/mol.

Jan 1, 2006

By Patricia Martínez Nicolás

Nickel and ferronickel are some of the major components in the production of special alloys; however, the energy consumption for their production greatly increases their price. A cheaper option could be to use NiO and a reducing agent. This work presents experimental and theoretical analysis to estimate the effect of slag basicity and amount of reducing agents on the NiO reduction from the slag which interacted with molten steel at 1600 °C in an EAF. The slag system contained CaO, SiO2, CaF2 and NiO together with a reducing agent, ferrosilicon or carbon. The NiO content in the slag was 25 mass%. The amounts of the reducing agents (Si and C) were 1 to 4 times the stoichiometric mass to reduce NiO. The CaO/SiO2 ratio was 1.5 and 2.5. The kinetics of the process was very fast since after few minutes the maximum nickel yield was obtained. The slag basicity had a negligible effect on the reduction of NiO.

Jan 1, 2006

By Pratheesh George

Solid state galvanic cell with CaF2 as the electrolyte was employed for determining the thermodynamic properties of Nb-Al binary alloys in the temperature range of 973-1073 K. The activities and activity coefficients of Al in NbAl3 were determined. The experimental procedure and the design and construction of the experimental setup have been also explained in detail. Aluminum activity in NbAl3 increased with increase in temperature and shows a strong negative deviation from ideality. The activities of aluminum in NbAl3 were determined to be 0.0165 and 0.0289 at 973 and 1073 K respectively. The stability of NbAl3 has been compared with other available intermetallic systems.

Jan 1, 2006

By D. Gu, R. G. Anthony, C. V. Philip, M. E. Huckman

"In this paper, we review the equations needed to construct an ion exchange column model. These models contain three major components: 1) a differential material balance around the column, 2) a differential material balance around an ion exchange particle, and 3) a constitutive equation for diffusive flux. We then examine the ability of a fairly simple mathematical model to predict ion exchange column experimental data. This model contains the traditional absorption theory equations and is used to predict the behavior of a column filled with a hydrous crystalline silico-titanate and which is removing trace amounts of Cs+ from a high pH, complex electrolyte solution. Finally, we propose replacing Fick's law with the Nemst-Planck equation as the constitutive equation for diffusive flux. We use a NemstPlanck type model to predict batch experimental data, then evaluate it by comparing it's ability to predict experimental data to that of a more traditional Fick's law type model. The data from this comparison suggests that the Nemst-Planck type model yields better results.IntroductionMillions of gallons of strongly basic, radioactive waste are currently stored in underground storage tanks at Hanford and Savannah River and several locations within the United States. Due to the limited life expectancy of the tanks, there is a pressing need to remediate these wastes. This need has prompted the recent development of new ion-exchange materials for removing radioactive elements from aqueous solutions. A novel material called TAM-5 has been developed jointly by Texas A&M University and Sandia National Laboratories. TAM- 5, a crystalline silico-titanate, is highly selective for Cs + in the complex electrolytic solutions typical of these wastes. It is stable in very basic solutions and in radioactive environments [1, 2 ,3]. In laboratory testing to determine the selectivity of various materials, TAM-5 was superior to other candidate ion exchangers [4, 5]. The selectivities were determined by measuring a distribution coefficient, Kd, which is defined as the concentration, gig or mmols/g of Cs in the solid phase divided by the concentration, mg/L or mmols/mL, of Cs in the liquid phase. The units of Kd are ml/g or L/kg. Table 1 shows Kd values for TAM-5 compared to 9 other candidate materials in a typical waste solution [6]."

Jan 1, 1996

By Markus A. Reuter, Robert Matusewicz

"Consumer products are a complex man-made mixture of sometimes in excess of 50 elements. In order to recover these complex mixtures of elements either as metals, compounds or energy requires versatile technology in physical separation but also smelting and energy recovery. This paper explores this by referring to the innovative application of Top Submerged Lance (TSL) technology and associated theoretical and environmental aspects to process (recycle) post consumer materials and industrial intermediate products and residues. A diversity of applications has been tested in Ausmelt’s pilot plant in Dandenong and many have gone to commercial scale globally. This paper reviews the varied applications ranging from e-waste recycling, lead and NiCd battery recycling, metals recovery from slags, zinc leach residue processing, electric arc furnace (EAF) dust, Municipal Waste Incinerator bottom ash processing, carbon containing residues such as retort ashes and spent pot liner from the aluminium production process as well as use of the technology for materials such as automotive shredder residue (ASR) and plastics. Introduction The modern resource cycle is a link between primary production of metals linked to the recycling of post-consumer goods. The sometimes complex combinations of materials and metals in consumer products such as televisions depicted by Figure 1, does require a range of technology to recover materials, metals and energy for reuse and/or recycling in an economically feasible as well as environmentally friendly manner."

Jan 1, 2008

By Denise Crocce Romano Espinosa

The recycling of waste of electric and electronic equipment (WEEE) is one of the main modern challenges. Among the variety of WEEE, batteries can be set apart due to their composition and their growing demand along with portable devices. The objective of this work is to characterize the thermal behavior of a sample of mixed types of batteries using a thermobalance (TGA). The results of tests showed that Cd evaporated up to 800ºC, Zn evaporation occurred mainly above 900ºC and manganese oxides were pre-reduced to MnO at temperatures above 900ºC.

Jan 1, 2009

By Slobodan Radosavljevic

The polymetallic W-Pb-Bi-Ag ore from the ?Nova jama? ore zone of the Rudnik ore field have been investigated. Contact-pneumatolytic (skarn), pneumatolytic-hydrothermal, and hydrothermal mineralization phases are defined in this ore zone. The most significant mineralization phase that gave compact ore bodies is pneumatolytic-hydrothermal phase. A relatively pure Mo-free scheelite is the only tungsten-bearing mineral. Lead minerals are mostly presented by Pb-Bi sulphosalts and much less with galena. The image analysis coupled with Energy Dispersive Spectrometry (EDS) analysis on a Scanning Electron Microscope (SEM) was applied to the characterization of a W-Pb-Bi-Ag ore as an efficient tool for mineral quantification. Results of EDS (Energy Dispersive Spectrometry) analyses gave the empirical formulae: Pb1.91Ag0.05Cu0.08Bi1.93S5 for cosalite, Pb0.98Ag0.03Cu0.05Bi1.99S4 for galenobismutite and galena Pb0.99Ag0.03S.

Jan 1, 2006

By Gabriella Tranell

In the manganese ferroalloys industry, there is increasing focus on the performance of different carbonaceous materials within the smelting processes. With a developing scarcity of traditional raw materials, new carbon sources are being identified for potential use in the processes. For this purpose, it is important to be able to predict the suitability of different materials in the process. Hence, the effects of both the physical and chemical properties of the carbon material on the reduction kinetics of manganese and silicon from slag to metal, have been investigated using an advanced sessile drop technique. Using this technique, the reaction patterns of SiO2-MnO containing slag droplets in contact with various solid carbon materials (graphites with different properties as well as cokes and charcoals) at 1400 to 1600\\176;C were studied in-situ. In addition, slag and metal reaction products from kinetic experimental series were analysed. From these results, differences in reactivity between various carbon materials and slags were demonstrated and explained. Mechanisms for both manganese and silicon reduction were proposed.

Jan 1, 2006

By Yunnen Chen

The test and use of natural materials as biosorbents for the removal of heavy metals from industrial wastewater is under constant development. In the present study, the biosorption capacity of waste microzyme was studied for cadmium The cadmium removal study has been carried out batchwise where the influence of physico-chemical key parameters such as pH value of solution, contacting time and initial cadmium ions concentration have been considered. The influence of metal ion concentration was evaluated and the results were fitted using adsorption isotherm models. The kinetic of cadmium biosorption was also investigated. The maximum percent removal was attained at the pH 7.0 after about 30 min. Waste microzyme was a potential biosorbent for the removal of Cd(II) from the effluent of electroplating industry.

Jan 1, 2009

By Yuanbo Zhang

Zinc leach residues produced by hydrometallurgical zinc plants contain many valuable elements (zinc, iron, lead, gallium, indium silver, etc), while they have not been utilized effectively hitherto. In this paper, a new process of flotation-reduction roasting-magnetic separation to recover these valuable elements from zinc leach residues is developed on a basis of mineralogy investigations of them. The results show that silver concentrate with grade of 4321.6 g/t and recovery of 80.69% have been obtained, using 1750 g/t Na2S as conditioner, 750 g/t ammonium dibutyl dithiophosphate and SN-9 (assistant collector) as combined collector and 100 g/t terpenic oil as frother, if zinc leach residues with 523 g/t silver are floated at pH = 5.0. When the flotation tailings are subjected to reduction roasting at 1100? for 2 h, the volatilizations of zinc, lead and indium are over 96%. After roasted products are treated by wet-grinding and magnetic separation, the grade of gallium and gallium in the concentrates achieved respectively reaches 1805 g/t and 1536g/t, and the recovery of them is high to 94.67% and 93.20%, respectively.

Jan 1, 2006

By Tiebao Yang

In high pressure die casting processes, a die plays a critical role in removing heat from the molten metal during the cavity filling and solidification stages. Proper control of die temperature is essential for producing superior quality components and yielding high production rates. This paper proposes a local temperature control scheme for die thermal management based on a computerized intelligent real-time monitoring and control system (IRMCS). In this scheme, cooling water lines are controlled by a pump and solenoid valves. A controller is designed according to the law of die temperature fluctuations. The results obtained from the experiments carried out on a laboratory die casting process simulator indicate that the controller can limit the local die insert temperatures in a given band. Hence, the desired thermal pattern of the die insert becomes achievable.

Jan 1, 2006

By Eun-young Kim

Electrogenerated chlorine leaching of waste printed circuit boards was investigated in hydrochloric acid solutions. The pulverized printed circuit board contained about 37.6% of metal component, in which copper was about 83.6%. The leaching rate of copper was greatly affected by current density and agitation speed. The leaching of copper up to 98% was achieved at 20 mA/cm2, 50?, 180 minutes, and 600 rpm in 1M HCl solution. Increasing agitation and lowering current density enhanced utilization efficiency of electrogenerated chlorine. Leaching of copper was suppressed at initial stage, while the minor metal elements, such as aluminum, lead, and tin, were dominantly leached out.

Jan 1, 2006

By Zhao-feng Xie

A new process of recycling valuable metals containing in the slag of jamesonite smelting in the blast furnace was studied. In this process, the valuable metals such as Pb, Sb, Zn and In etc. were fumed and volatilized and enriched in the dust firstly and then the dust was leached by sulfuric acid. In the leaching procedure, Zn and In in the dust entered into the leaching solution and were separated from Pb and Sb which remained in the residue.The optimal operation conditions of the fuming procedure are as follows: the mass ratio of the blast furnace slag, coal powder and lime are 100:22:10 respectively and the fuming time are 1.5~2.5 h, the fuming temperature is not below 1200C and the volatilization rates of Pb, Sb, Zn and In are 95%, 92%, 86% and 75% respectively. The optimal conditions for the leaching procedure are also presented: the consumption of sulfuric acid is 1.15 times of the theoretical consumption, the ratio of liquid to solid is 4:1 and the leaching temperature, leaching -1time and stirring speed are 90, 1.5h and 300 r?min separately. The leaching rates of Zn and In are 98.5% and 95.2% respectively. The experimental results shows that the valuable metals in the dust can be recovered and separated effectively by this process and the?ir recovery efficiencies are as follows: Pb94%,Sb91%, Zn84% and In69%.

Jan 1, 2009

By Yunnen Chen

This work concerns the removal of zinc(II) and COD by means of sawdust obtained as a by-product from locally used wood. The zinc(II) and COD removal study has been carried out batchwise where the influence of physico-chemical key parameters such as tree species, pH value of solution, temperature and contacting time and dosage of adsorbent have been considered. The maximum percent removal was attained at pH 9 all for Zn(II) and COD after about 60 min. The adsorbent can be effectively desorption using 0.1 M HCl. The experimental results showed that ion exchange maybe the major adsorption mechanisms for binding the divalent metal ions to the sawdust. Sawdust was a potential adsorbent for the removal of Zn(II) from the effluent of electroplating industry.

Jan 1, 2009

By Jesús Contreras

Within its programme for continuous improvement and cultural change, Atlantic Copper has installed the Six Sigma methodology as a basic tool for the improvement of management techniques in all its production centres. Following an implementation period, the methodology is widely used for analysis and improvement, not only in the fields of production and maintenance, but also in other areas of the business such as supplies or energy management. The present paper describes, phase-by-phase, the project that was developed to improve the quality of converter slag through the application of Six Sigma techniques, from the initial set up to the final results obtained.

Jan 1, 2005

By Wolfgang Van Hooff

Encouraged by a strongly growing and evolving market for granulated products, Paul Wurth continuously improves its granulation and dewatering technologies to provide customers with state of the art installations. Continuously developed know-how about the granulation process of iron blast furnace slag enabled application to non-ferrous materials such as Ni-Slag, Pb-Slag, Blister Copper, Cu-Matte and even TiO2-Slag, which rank among the most difficult materials to granulate. This paper identifies how critical objectives in granulation and dewatering technologies applied to different molten materials with respect to various product quality objectives can be addressed. The differences between hot and cold water granulation systems are explained, including the step from cold runner to granulation water tank. Development of a flow and pressure controlled blowing box is the latest step to optimize the granulation process in order to meet the latest standards in terms of quality, power consumption and environmental protection.

Jan 1, 2006