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By Harry M. Castrantas, James L. Manganaro, Craig W. Rautiola, James Carmichael

Caro's acid (peroxymonosulfuric acid) was successfully field tested as a cyanide detoxification agent at a North American gold mine. An on-site FMC generator injected Caro's acid into a mill tailings slurry sump. The WAD cN-(weakly acid dissociable plus free cN-) was reduced from 40-108 ppm to below the target level of 20 ppm using a 1/1 mole ratio of CA (Caro's acid) /CN-. At an inlet CA/CN-mole ratio of 1.8/1, WAD CN­concentrations as low as 4 ppm cN-were achieved. Raw material costs for the cyanide detoxification were cut by 60% compared to using hydrogen peroxide (H202) alone. Detoxification time with Caro's acid was much faster compared to H202. This resulted in completion of detoxification before the treated slurry reached the tailings pond thereby substantially reducing the probability of wildlife fatalities.

Jan 1, 1993

By M. Stefanakis

Respect for the people is one of the main values of S&B. Such respect needs to be manifested by actions ensuring the bodily and spiritual integrity of personnel in pursuing their work. The ultimate target is to achieve zero accidents by developing the culture and infrastructure required to support it. Within this framework, the following proactive safety practices were introduced in 2004 and are implemented at S&B Greek sites: (a.) Management Safety Visits (MSVs) of shop floor operations to address safety attributes of work guidelines, (b.) Monitoring compliance with critical work guidelines, using a ?safety barometer? tool. The proactive nature of both above systems, facilitates communication with employees on safety behaviors and their adoption in our facilities at Milos and Fokis, has been successful. Above all, these practices corroborate the management?s concern for the people and its commitment to continuously improve the working environment.

Jan 1, 2007

By John A. Shuster, Joseph A. Sopko

Construction of two shafts, as well as associated deep concrete structures, for a major storm sewer project in Milwaukee, Wisconsin required ground water control and temporary ground support to depths ranging from 19.2m to 55.0m. Lowering of the site ground water table eras not possible because of potential consequences for existing nearby structures. Construction entailed completion of two shaft collars into bedrock. In addition to the shafts, several adjacent connected. structures were completed. Ground freezing was selected to provide temporary ground support and ground water control for all excavations. The first application of using reinforced frozen earth was successfully incorporated on the project. The procedure enabled the contractor to create openings in excess of 9.1m in height, without bracing, through highly stressed frozen earth walls. Design features and construction procedures for completion of ground freezing and related excavation are reported.

Jan 1, 1989

By Alfredo P. Vargas

Industrial flotation of sulfide ores is 80 years old. It has gone through many advances to date. However most flotation operations are still struggling to improve performance, which as a worldwide average is at the 90% level. What can be done to push the ceiling to 95% or better without performing finer primary grind, nor without duplicating flotation plant capacity? Such "unique task" can be performed by the low volume high capacity new flotation equipment known as the JAMESON CELL, when used as, "post-scavenger" of final plant tails. Improved efficiencies are obtained mainly from two cases: -Particles which never contacted a bubble. -Particles sheared-off by cell turbulence due to reduced number of hydrophobic sites. The application reverses conventional trend of using large volume mechanical cells by trade-in with smaller efficient equipment: resulting in reduced capital expenditures and operating costs. Outstanding "pre-rougher" applications are also presented.

Jan 1, 1993

By James E. Brewer

Procedure for approval by the U. S. Army Corps of Engineers of a new source of aggregate is in three phases. Phase 1 consists of an investigation of a quarry or proposed quarry by district geologist and laboratory geologist and/or petrographer. The quarry face or suitable outcrop is logged in detail or, if exposures are poor, cores may be taken to determine whether further investigations are warranted. Phase 2 consists of thorough laboratory testing. Cores and crushed material are subjected to a number of acceptance and quality tests for soundness, absorption, abrasion, reactivity, and other properties. Petrographic analysis is also made. Phase 3 is a physical and economic study of the site and involves determining quantity of stone avail- available, amount-and character of overburden, condition of haul roads and distance to rail shipping point, plant flow sheets and capacity, aggregate sizes produced, and approximate price of material at plant.

Jan 1, 1966

By Frank T. Wheby, Edward M. Cikanek

A computer performs all logic and computations customarily done by hand in preparation of engineers' estimates or contractors' bids on tunnel-shaft systems. The program described is based on construction methods, work forces and equipment selections corresponding to the current state-of-the-art of rock, soft ground and cut-and-cover tunneling. The program contains logic to permit estimates of cost of complicated tunnel-shaft systems; it is not necessary to input quantities, as the program calculates those from the tunnel design that is internally generated. In any estimate, the program bases its cost computation on user-input requirements and site conditions, such as tunnel shape and size, shaft depth, ground characteristics, construction methods, and other factors. To provide great flexibility, the user of the program is provided with options for accepting designs built into the program or overriding these designs by his own inputs. An illustrative example is presented.

Jan 1, 1974

By Frank K. Mattson

The Minerals Processing Section of Surface Combustion is currently engineering and erecting a plant designed to produce 400,000 LTPY of 95% metalized pellets from raw magnetite concentrate, This venture is the first domestic commercial facility that will manufacture pre-reduced pellets as an integral part of a process to produce steel. Surface Combustion has developed the methods that will be used. Midrex, a division of Surface Combustion's parent company, Midland-Ross, will own and operate this plant. The site is adjacent to the City of Portland, Oregon on a 15 acre hydraulically-filled area on the east bank of the Willamette River. Either filter cake or concentrates in slurry form will be purchased from Marcona in Peru, delivered to the dock facility by ocean vessels and distributed to a pond for wet storage. Reclamation from the pond will be with a conventional dredge delivering concentrate to a thickener.

Jan 1, 1968

By James Veri, Andrew H. Stern, Gerald N. Torbert

When mining coal, the occurrence of high methane liberation rates can often overwhelm the existing ventilation capabilities of the working place and result in elevated levels of methane gas. These “gas-off/stand-by condition" events often limit the production of the section and increase the potential opportunity for the occurrence of an ignition. This paper investigates the potential effectiveness of using a continuous miner equipped with an integral dust scrubber which was modified to provide high flow rates to reduce these events during active coal mining. Work was undertaken to quantify various adaptations of the mining system, by simulating site parameters in the controlled environment of an instrumented "full-scale" test facility. Monitoring (in real-time) of velocities and gas concentrations at many fixed points was also undertaken in an attempt to learn the effective limits of the system at high release volumes of gas.

Jan 1, 1997

By Robert L. Runkel, Kenneth E. Bencala, Briant A. Kimball

Thousands of abandoned and inactive mines are located in environmentally sensitive mountain watersheds. Cost-effective remediation of mining sites in these watersheds requires knowledge of the most significant sources of metals to surface waters. The significance of a given source not only depends upon the concentrations of a toxic metal, but also on the total mass, or load of metal added to the stream. To determine loads, we combined tracer-injection methods, to provide reliable discharge measurements on a watershed scale, with synoptic sampling, to provide spatially detailed concentration data. The resulting load profiles indicate which sources have the greatest effect on streams, where natural attenuation of metal loads occurs, and where ground-water inflows are located. This is part of the information needed for planning remediation of mine-drainage effects. The approach is illustrated by comparing zinc loading curves from three watersheds affected by mine drainage.

Jan 1, 2000

By J. E. Rourke, O&apos

This paper describes the use of index testing to obtain rock properties that are useful in the design and construction planning of an underground development for civil engineering or mining projects. The index properties discussed include: point load; Schmidt hammer hardness; abrasion hardness; and total hardness. The first two index properties correlate to uniaxial compressive strength (UCS) and Young's modulus. Discussions are given on empirical, normalized relationships of UCS to rock mass properties and the integrated use with semi-empirical, geotechnical design methods. The hardness property indices correlate to construction performance parameters and some relevant experience is cited. Examples of data are presented from an index testing program carried out primarily on siltstone, sandstone and limestone rock core samples retrieved from depths up to 1005 m (3300 ft) in a borehole drilled in the Paradox Basin of eastern Utah. The borehole coring was done for a nuclear waste repository site investigation.

Jan 1, 1990

By R. C. Ford, J. Kelsey, S. A. Pierce, M. D. Ankeny

Evaluation of acid drainage risk from spent (leached) ore in arid climatic zones consists of two components: (1) whether residual and secondary minerals will release acid and metals when exposed to rainfall, and (2) whether ambient rainfall is likely to infiltrate, and eventually impact surface or ground water resources. The risk of acid drainage from spent ore at the El Abra on-off copper leach pad operation was evaluated using conventional geochemical methods and unsaturated flow models. Although geochemical testing indicated poor quality water would result from any seepage, unsaturated flow modeling demonstrated that infiltration and seepage were unlikely given the arid climatic conditions. Modeling further demonstrated that the residual moisture content of the spent ore when it is removed from the leach pad controls the risk of seepage. To further reduce the risk of seepage, operational controls were developed and implemented at the El Abra site.

Jan 1, 2000

By A. K. Sheik, W. G. Pariseau

A small underground mine in northern Idaho was used as an experimental facility for studying the role of water in the analysis of mine-opening stability. Laboratory test data, borehole measurements and geological mapping assisted in the construction of a coupled finite element model of the rock mass. The model was used to make quantitative estimates of rock stress, strain and displacement changes and to make estimates of the water pressure and flow velocity changes that occurred during historical mining. Stope cuts and wet fills were included in the analysis. The stability of the crown pillars between stopes was of particular interest. The relatively low effective stress and high rock-mass strength showed that water pressure changes were of no great consequence, which is in agreement with experience. The computational tools used in the analysis may be applied to other wet mines with appropriate changes to site-specific data.

Jan 1, 2002

By Liuming Wu, Willis Forsling

The complexation of Alizarin Red S (ARS) at the surface of hydrous fluorapatite particles has been investigated at 25.0 C by means of potentiometric titrations, adsorption experiments in 0.1 M NaCI ionic medium, and Diffuse Reflectance Infrared Fourier Transform spectroscopy (DRIFT) studies. A chemical model describing the reaction at the aqueous mineral surface has been established under equilibrium conditions according to the reaction [== -CaOH2 + HA2 - « _ =PO CaA2 - z + H30&apos;; to (int.) = -5.61 ± 0.02 3 a =PO- logBs-1110(int.) ( ) within the range 8.40 <_ -log[H ] <_ 9.80.] Experimental data were evaluated using the computer program FITEQL on the basis of a constant capacitance model for the electric double layer. The surface complex structure, has been proposed to involve the quinoid and alpha phenolic oxygens of ARS coordinated to the calcium sites on the fluorapatite surface.

Jan 1, 1993

By Wilbur I. Duvall

This paper discusses general principles of underground opening design based on the concept that with the necessary input data regarding the geology of a site, the physical properties of the rocks, the in situ stress field in the rock and the general geometry of the underground openings, the rock formation can be classified into six major categories which are useful for design purposes. Using simple theories for the criteria of failure for rock In compression and tension, general elastic theory for stress concentration around openings and In structures, beam theory for stability of roof rock, and elementary inelastic theory for creep phenomena, basic design techniques are outlined for the various rock classifications. The need for field evaluation of the theoretical design is stressed and some general techniques that should be used in these field evaluations are discussed. Where appropriate, the need for additional studies and research is noted.

Jan 1, 1977

By Peter C. Busse, Henry M. Giegerich, Ronald K. Netolitzky

Zimbabwe The Republic of Zimbabwe is situated in south central Africa and north of the Tropic of Capricorn. The country is land-locked, bounded on the north by Zambia, on the south by the Republic of South Africa, on the east by Mozambique and on the southwest by Botswana. Nearly 400,000 sq km in area, Zimbabwe is bigger than both France and Spain and nearly three times the size of England. The outstanding physical feature is the central plateau, known as the highveld, which is about 650 km long and 80 km wide at an elevation of +1,200 m, and on which the Jena Mines is located. Because of its elevation and inland position, Zimbabwe&apos;s climate is temperate, generally drier and cooler than is normally expected in the tropics. Zimbabwe&apos;s population is in excess of 10 million. English is the official language, with Ndebele and Shona being the main ethnic languages. About one million people live in Greater Harare, the capital city. The basic unit of currency is the Zimbabwe dollar, which has depreciated substantially over the past few years. Currently (November, 1995), the exchange rate is $US 1.00 = $Zim 9.00, compared with $US 1 .OO = $Zim 2.50 in 1991. Project Area The Jena Mines Complex is situated in central Zimbabwe (Figure 1), in the Silobela area of the lower Gweru River valley. The mine site is 270 km from Harare by paved and gravel road. The Jena Mines property consists of a single rectangular (8 km by 5 km) shaped mining lease with an area of approximately 40 sq km (Figure 2). Annual average precipitation is 720 mm falling in the summer months between October and April. Mean daily maximum temperature is 24°C in October and mean minimum is 14°C in July. The southern parts of Zimbabwe have experienced drought conditions over the past four years which has affected water and power supplies. The countryside in the Jena area is generally low relief with a gentle slope to the northwest. The mine site topography is flat with an average elevation of 1,210 m. Zimbabwe Mining Industry Zimbabwe has a long mining tradition, particularly for gold. In the 1,200 years preceding European colonization, it is estimated that about 4,000 ancient mines produced between 600 and 800 tonnes of gold. Since the turn of the century more than 1,700 tonnes of gold have been produced. An excellent infrastructure has developed to support the mining industry. This includes a well- maintained system of paved roads, railway links to major mining areas, an electricity grid covering most of the country, and numerous industries manufacturing a wide range of mining supplies. Jena History The claims in the Jena Mines area are among the earliest registered in Zimbabwe. The gold potential was easily recognized because of extensive ancient (pre-European) workings. European trading beads from the 14th Century have been recovered from anthills in the mine area. Development of the Jena Mines commenced in 1898 and several mines have operated intermittently over the past 90 years. The recorded cumulative historical production from the significant producers of Jena is tabulated in the following:

Jan 1, 1996

By H. Wesley Peirce

Arizona, in 1966, has continued to be the site of an extensive and intensive search for metallic mineral deposits. Over fifty separate entities--companies and individuals--have been actively engaged in mineral exploration programs, both large and small, in the Basin-and-Range portion of the State. Certainly, copper has been primarily responsible for the major efforts, although associated gold, silver, and molybdenum mineralization also has been important in the economic evaluation of potential copper deposits. It is not difficult to explain why the Basin-Range portion of Arizona is receiving such attention. Part of the story, undoubtedly familiar to most, can be illustrated by reference to three graphical presentations. For example, Figure 1 shows Arizona&apos;s annual copper production for the period 1955-1965, inclusive, and it demonstrates that new records of production have been accomplished in each of the past 6 years and in 9 of the last 11 years.

Jan 1, 1967

Disposal of solid and liquid wastes from mining and milling operations has become a focus of attention in recent years. Consequently, the geotechnical engineer is more frequently associated with design of disposal facilities. Jack Wulff, a representative of one consulting firm with experience in this field, talks with ME about the geotechnical engineer&apos;s contribution. Mr. Wulff, mine and mill waste disposal today is receiving more attention-and many more dollars-than in the past. Regulatory agencies have promulgated demanding requirements concerning mill waste (especially uranium mill waste) and specialist consultants are frequently being called in to design disposal systems. What can the experienced geotechnical engineer add to the development of waste disposal facilities? It&apos;s true that geotechnical engineers have recently become more visible in the minerals sector, but we&apos;ve been around mining for a long time-as foundation engineers for mills and mine support buildings, and for geotechnical aspects of open pits, pipelines, railroads, roads, and so forth. We&apos;ve also designed water supply dams, which could be considered recursors of tailings dams and other forms of disposal systems. Let me show by example what geotechnical engineering can contribute to waste disposal facility design. I recently was asked to look at several small wastewater impoundments which had failed. The design of the earth embankments appeared, at first glance, to be rather conservative. They were only about 3.4 m high, the slopes were 3 to 1 (horizontal to vertical), with about 24 m of bottom contact with the earth foundation. But there had been three episodes of dike failure in a few months, all upon initial filling. The problem was the nature of some material in the foundation that was also used as structural fill-a dispersive clay that readily deflocculated and eroded on contact with water, especially with seeping or flowing water. The design did not include the defensive measures required to use such materials confidently in water retention structures. Apparently, the designer did not recognize the potential problem posed by the unusual soil characteristics. That&apos;s the sort of engineering information fundamental to geotechnical engineering, but not necessarily a part of the civil, structural, or mining engineer&apos;s professional training or experience. This difference in expertise is not simply a matter of factual knowledge-it also affects the design process. The structural engineer can design a structure to fit the client&apos;s functional needs and can specify the materials (grade of steel, PVC, concrete, etc.) to meet the demands of the design. The geotechnical engineer&apos;s design process is somewhat different, since we work with natural materials, not man-made materials produced according to specification. We first have to establish what kinds of materials are available (usually directly from the chosen site, since importation of materials becomes expensive). Then we determine the engineering properties and characteristics and, finally, design the structure to fulfill the client&apos;s requirements within parameters dictated by available materials. In brief, the geotechnical engineer works with naturally-evolved, not man-made, materials and uses design techniques developed to accommodate that fact. Because no two sites are exactly alike in configuration, structural (geologic) characteristics, or available materials, there will be unique design and judgmental questions to be resolved on virtually every project. You said that water retention dams could be considered the precursors of tailings dams-you probably had a specific technical relationship in mind. There&apos;s a very strong carryover of methodology from earth dam design, where the technology developed and where it has become very refined. In designing a tailings impoundment or similar facility, essentially the same procedures of field sampling are involved (with a geotechnical engineer or an engineering geologist directing the program since representative

Jan 7, 1980

By Scott G. Britton

Until now, only the range of typical construction projects which are repeated over and over during the life of a coal mine have been discussed. This chapter looks at underground construction projects which occur only once or twice during the life of any given mine and are major construction projects in both time and cost. These projects usually require the services of an outside engineering and construction firm with hands- on experience in design installation. Because of this involvement with engineering and construction firms (EIC), the role of the construction engineer will change from one of actively de- signing and directing tasks to one of planning, inspection, and quality control. To reflect this role change in the discussions, the focus of this chapter will be changed to a broad overview of project participation. Of course, the projects under consideration in this chapter could easily fill more than one book on their design and installation. In addition, major construction projects are extremely site specific, requiring months of data collection about site geology, physical conditions, and potential excavation and construction requirements. Therefore, no attempt shall be made to discuss any detailed construction aspects as was done in earlier chapters. The purpose of this chapter is to present the fundamental concerns of a staff engineer or supervisor. This engineer does not make the decisions on choosing the EIC firm, but assists and interacts with their project team to accomplish the goals set forth by higher management. The construction topics to be reviewed fall into three main categories. The first category is highlighted by the installation of a main surge bin; the second is typified by the construction of an underground shop; and the third category encompasses special projects such as rotary dumps, crusher stations, and foremen&apos;s offices. These categories highlight the differences between degrees of mine responsibilities for project completion. The first topic is usually a turnkey project by an E/C firm for a given mine. The second topic represents the leading role of the mine in the project with a contractor as a support service or equipment supplier only. The third topic, special projects, is an example of a joint venture-between a contractor (leading partner) and mine management. These roles can change with any given project, but the changes in management responsibilities for the construction engineer can be nicely illustrated for the purposes of this text. The first step toward constructing major mine projects is to analyze the mine which influence their design. From the mine management standpoint, these parameters should reflect the role the mine will play in the project construction. In other words, what is the nature of the proposed mine environment and what are the material, labor, and time requirements needed to assist or direct the chosen engineering and construction firm? Answering these questions requires some basic project planning and cost estimation work. Here, only a general treatment is necessary, since detailed discussions of these topics will follow in Chapters 8 and 10. For those persons interested in the role of the EIC contractor, I suggest beginning by reviewing the article by Beall, "The Role of an Engineering and Construction Contractor," presented in the October 1980 issue of Mining Engineering magazine.

Jan 1, 1983

By Peter W. Willcocks

The Cyanide Regeneration Process (CRP) was developed by Golconda Engineering and Mining Services and installed at Golconda's Beaconsfield Gold Tailings Retreatment Project situated in Tasmania, Australia. The Tailings Project is a 1000 ton per day carbon-in-pulp treatment plant, feed for which consists of tailings material which is dredged from the Tamar River. The pulp is screened to remove debris, then cycloned to form two products. Underflow pulp is stored in a 350 ton bin and cyclone overflow passes to a thickener. The coarse pulp material is fed to the grinding circuit then rejoins the thickened slimes in the cyanide leach circuit. Gold is extracted by carbon-in-pulp techniques. The plant is sited in rolling, hilly country approximately 200 meters from the Tamar River. The residue disposal area is quite small consisting of four dams, totalling 42 acres. The regional climate is cool and wet with little evaporation; therefore, we anticipated a net increase in contained liquor, and subsequent storage problems. Our plan was to remove cyanide from the liquor prior to returning the detoxified solution to the river system. Such treatment was not required until midway through the second year of the project. Initial testwork on sample material indicated that destruction of cyanide by chlorine was the simple solution. Subsequent follow-up on actual plant liquor indicated a huge chlorine requirement due, we believe, to the substantial degradation of vegetable matter plus organic content from the marine environment. The cost of cyanide destruction could not be justified.

Jan 1, 1998

By K. Vanbroekhoven

An industrial site near the centre of a historical town in Flanders is characterized by chromium(VI) contamination of the groundwater. Since the potential for natural attenuation was not sufficient to control the groundwater plume as observed from different analyses like pH, Eh, soil oxidation and reduction capacity, the feasibility of site remediation based on in-situ bioprecipitation of chromium was examined in lab microcosm studies. By creating reducing conditions by addition of a carbon source in the groundwater, chromium(VI) can be biologically reduced to chromium(III), which can form an insoluble precipitate of chromium(III) hydroxide. Microcosms contained contaminated groundwater and aquifer samples that were collected and manipulated under anaerobic conditions. Three different carbon sources were screened for their effectiveness: molasses from sugar beet production, molasses form starch production (protamylasses) based on potato juice and lactate. The different concentrations of sugar molasses were used to determine the optimal conditions. A range of parameters was monitored at regular time intervals for a period of six months such as chromium(VI) and chromium(III), DOC, methane, pH, Eh. A rapid conversion of chromium(VI) to chromium(III) was observed for all conditions tested. However, extensive removal of chromium from the groundwater by precipitation was only achieved for a limited number of conditions. In general, lactate was found to be the most effective carbon source, slightly better than the lowest concentration of sugar molasses that was tested, which itself was more effective than molasses based on potato. Higher concentrations of molasses, although causing a steeper decline in redox potential, resulted in less effective Cr removal. Typically, the fermentation of molasses results in acidification and this drop in pH may hinder the formation of insoluble chromium(III)hydroxides. It may also be possible that certain components of the molasses form soluble complexes with chromium(III). For lactate, no significant drop in pH was observed. Following the laboratory microcosm tests, the stability of the chromium precipitates was examined by performing a sequential extraction on the microcosm materials. These were performed under redox conditions which were similar to the ones observed in the field. Since the outcome of these tests was positive, a pilot scale test was implemented in the field in April 2005. Two different substrates, the cheap waste product sugar molasses and lactate are being injected creating two different impact zones and typical parameters are monitored. Frequent re-injections were important to maintain reduced conditions and are carried out three-weekly up to now. To study the stability of precipitates formed, mesocosm socks containing aquifer material were installed in the monitoring wells and harvested at regular intervals. Results of this pilot test will be presented and compared to the laboratory results. Based on the success of this field test, a full scale process will be designed and implemented as remediation strategy.

Jan 1, 2006