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By İsmail İnce

The existence of water is one of the most effective factors in deterioration of natural building stones. In the process of deterioration, capillary water absorption is the most significant procedure of water penetration into the building stones. Pyroclastic rocks have been widely utilized as building stone especially in historical buildings and monuments since ancient times in the Central Anatolia in Turkey. Nowadays, this type of rocks is used in the restoration of historical buildings as well as in the construction of modern buildings. Pyroclastic rocks are highly susceptible to deterioration process. Capillary rise has a significant influence on water penetration into building stones. Therefore, it is quite important to identify the factors affecting the values of capillarity, capillary rising speed, and capillary rise that define capillary water absorption in these rocks. To this end, pyroclastic rock samples in different textures were compiled from the Cappadocia region, in Central Anatolia. First, petrographic, mineralogical, geochemical, physical, and pore diameter distribution properties of the samples were determined in the laboratory. Then, capillarity values with capillary rise and capillary rise speeds dependent on time were established. Based on the data obtained, correlation coefficients between matrix percentage and capillary water absorption rate and capillary rise values of pyroclastic rocks were calculated and found to be as 0.850 and 0.891, respectively. Thus, the article proposes a new empirical equation to practically calculate the capillary rise value depending on the matrix percentage (MP) and median pore diameter (MPD) values.

Nov 30, 2020

By S. D. Abbott

Mines are filled with a mixture of gases, some of which are toxic, flammable, or explosive. Others serve as early reporters of impending problems. Mines monitor these gases in order to ensure the safe, efficient operation of the facility and avoid losses or disasters. Two different approaches to monitor these gases have historically been taken. One kind of device measures the amount of each gas present by using selective detectors (e.g. handhelds and spectrometers). Another kind separates the mixture of gases into the individual constituents, then measures the amount of each gas present (e.g. gas chromatographs). Handheld units are the most widely used, but gas chromatographs are the most powerful yet underutilized units available to enhance mining operations. There are many misconceptions about the nature, applicability and proper use of each type of device, and little data is available. Up to this point, many people had only the manufacturers? claims to guide them. This study was undertaken to clarify the range of applicability, important characteristics, and value in use of these units in real-world situations. An additional goal of the study was to provide ways to evaluate comparative data, and thus aid mining operations in choosing the most beneficial and reasonable ways to use such devices in various situations and contexts.

Feb 23, 2014

By C. Cristoffanini

A real-time transient pipeline simulation was used to model the operational pressure response in the concentrate and tailings pipelines of the Minera Los Pelambres copper mine in Chile. A high-fidelity simulator was needed to train the operators on safe operation of the pipeline for different scenarios. A simulator that solves the transient equations was used to dynamically predict the pressure and flow throughout the pipeline to provide real-time responses to operational changes such as opening or closing a choke valve, or sending a water batch. Slurry rheological properties were incorporated into the model. This paper presents the technical background of the pipeline simulation model and the study of slurry properties. The paper shows the results of the transient simulation for different operating scenarios such as start-up, shutdown and leakage, by presenting the hydraulic gradient curves for each case. Finally, the paper briefly presents how the simulator was connected to an emulated control system and used to train the operator, it demonstrates the most effective tool available to learn to resolve undesirable conditions.

Feb 23, 2014

By M. S. Moats, W. C. Hartzell

The stable domestic supply of gallium, indium, and germanium has been identified as a critical need for the United States. Electric arc furnace dusts, processed to recover zinc, produce a residue that could be a potential source of these critical materials. An industrial zinc leach residue was characterized to determine its particle size, chemical composition, and predominant mineral phases. Heated, atmospheric, agitated leaching using sulfuric acid and hydrochloric acid was examined to determine the extractions of gallium, indium, and germanium as a function of concentration and temperature. Extractions of gallium were found to be similar to iron in all experiments. The maximum percentage of Ga, Ge, and In leached into solution were 71%, 63%, and 48%, respectively.

Feb 1, 2023

By Y. Numata

2-Mercaptobenzothiazole (MBT) is a heterocyclic-mercaptan and belongs to a group of molecules containing nitrogen and sulfur as electron donor atoms. MBT has been employed as a collector in flotation under names of MBT, Captax, and Flotagen. It is a major constituent of reagents in the 400 series of the American Cyanamid Co. Current applications of the reagent include flotation of copper minerals, tarnished or oxidized lead, copper activated sphalerite, and nickel ores. It has been used successfully in the flotation of pyrite in acid circuits in the range of 4 to 5.

Jan 1, 1990

In the screening process, used to prepare particles for many applications, shape is known to have a significant effect. The degree of flakiness of construction aggregates has been considered particularly important. The objective of this research was to find values of operating parameters that optimize the separation of flaky from non-flaky particles by slotted screens. Thus an investigation was conducted to experimentally determine the influence of the particle size and thickness on the screening process. The Response surface method was employed for modelling and analysis of the data. Experiments employing a central composite design were performed on a pilot-scale, rectangular-aperture, vibrating screen to examine the effects of the screening variables the mass recovery of flaky and non-flaky particles to the oversize product. The SAS statistics package was used to fit a second-order model to each response and to analyze the fitted surface to determine the optimum levels. The optimization associated with a dual response system was then considered. The results of this study should provide a basis for optimizing screening conditions to obtain maximum recovery of non-flaky particles to the screen oversize while minimizing the recovery of flaky particles, which should be of interest to the aggregate industries.

Jan 1, 1999

By Martin G. Casto

Mixer-settler extractors, among the oldest forms of extraction equipment, have been used since the beginning of this century. Over the past years, a very large number of mixer-settler devices have been designed and operated. Both batch and continuous flow mixer-settlers have been used. The continuous flow mixer-settler extractor offers a great number of advantages over other extraction equipment. The main advantage of the continuous flow mixer-settler is that it is a compact device. A large number of stages can be assembled in a relatively small area, and more stages can be added fairly easily. Many improvements have been made in the design of mixer-settlers. These improvements occurred in almost every phase of mixer-settler' operation; interface control, mixer design, intrastage pumping, interstage flow of the two liquid phases, and stage construction. It is believed that Barstow1 used one of the first continuous mixer-settler extractors. This mixer-settler had concurrent flow within each stage and countercurrent flow overall. The flow for both phases took place by gravity. The Barstow device and other early mixer-settlers had no separate interface control for each stage, therefore, "tilting" of the stages was necessary. In 1934 Holley and Mott2 designed a mixer-settler in which the heavy phase was recirculated within each stage by the use of a valve controlled central line instead of by a pump. Gordon and Zeigler3 in 1939 were among the first to use an adjustable valve to control the interface levels in a mixer-settler, making tilting of the extractor unnecessary. In 1952 Coplan et al. 4 used a modification of the Holley-Mott idea to build a highly improved mixer-settler with flat common walls, and with the

Jan 1, 1971

By M. A. Reyes, J. Bickson, J. R. Srednicki

Federal laws mandate the presence of refuge alternatives (RAs) in underground coal mines and provide guidelines for harmful gas removal. After an explosion, harmful gases can follow survivors into an RA and can reach a deadly concentration. Investigators from the National Institute for Occupational Safety and Health (NIOSH) tested 12 ventilation system configurations (VSCs) to purge sulfur hexafluoride (SF6) tracer gas from a built-in-place (BIP) RA in the Experimental Mine in Bruceton, PA. Using a borehole air supply, tests were conducted with airflows of 750 and 1,000 standard cubic feet per minute (SCFM). Excluding a VSC where the air inlet was 1.98 m (78 in) from the air outlet, the results show that the time to purge the SF6 concentration from 1,000 parts per million (ppm) to 25 ppm ranged from 26 to 29 minutes for an airflow of 750 SCFM and ranged from 18 to 23 minutes for an airflow 1,000 SCFM. Mines can use this information to reduce purge time in case of a mine disaster and determine which VSC to avoid. INTRODUCTION After a fire or an explosion in an underground mine, the concentration of carbon monoxide can reach a fatal level. In a mine disaster, the main goal is to escape. However, if miners cannot escape, they have to migrate to a location to find refuge and, if possible, communication, and a borehole source for a fresh air supply. To ensure survival of the miners, Federal laws mandate the presence of a refuge alternative (RA) within 304.5 m (1,000 ft) of the nearest mining face. In addition, Code of Federal Regulations Title 30 CFR Section 7 sets the guidelines for personnel tracking, RAs, and the removal of noxious gases in underground coal mines (Mineral Resources, 30 CFR, 2014). Federal regulations define an RA as a protected, secure space with an isolated atmosphere and integrated components (Mineral Resources, 30 CFR, 2014). There are three types of RAs: portable metal RAs, portable tent-type RAs, and built-in-place (BIP) RAs. A BIP RA is constructed using masonry or other stoppings to create an isolated space in a mined-out area. Blast doors are installed in one or both of the stoppings for the miners to enter the RA. Furthermore, RAs must provide the following components: breathable air, food, water, air monitoring, and harmful gas removal. Federal regulations have emphasized the mandate for breathable air and harmful gas removal in the following words: “Purging or other effective procedures shall be provided for the airlock to dilute the carbon monoxide concentration to 25 ppm” (Mineral Resources, 30 CFR, 2014). The purpose of the mine ventilation system is to provide a sufficient quantity of air to the underground mine workings, to dilute methane and other contaminants, to maintain a suitable working environment, and to prevent accidents from happening (Cheng and Wei, 2014). In addition, the organic nature of coal amplifies risks from poisonous gases, explosions, and fires (Engström et al., 2018). If an underground coal mine ventilation system fails after an explosion, the concentration of toxic gases, most notably carbon monoxide, will increase. Carbon monoxide is dangerous because it creates tissue hypoxia by binding to hemoglobin (Özmen and Aksoy, 2015).

Jan 1, 2019

By James R. Hindman

Vermiculite is the mineralogical name generally applied to a group of hydrated, trioctahedral ferromagnesian aluminum platty or micaceous silicate minerals. In microscopic particles the mineral as mineral is differentiated from montmorillonite by a higher Si:AI ratio of approximately 3:l and a higher layer charge and higher cation exchange capacities. Commercial vermiculite, the vermiculite which is mined, beneficiated, and discussed in this chapter, is an important industrial mineral which is formed by the alteration of macroscopic particles of biotite and iron-bearing phlogopite. In natural form it has the size and shape of mica, while possessing the ion exchangeable properties of zeolites and some clays. Within the internal structure of vermiculite lie water molecules, which when rapidly heated to high temperature, transform into steam causing the vermiculite particles to increase in volume. This process of thermal exfoliation produces a lightweight product which finds use in various construction products, agriculture, horticulture, and other industrial applications. In exfoliated form it has the low density and biological inertness of expanded perlite, while maintaining a chemically active surface. Most of the uses of vermiculite are for the thermally exfoliated material. In addition, the cation exchange potential of vermiculite and its layer-silicate structure are properties which can be used as the basis for numerous products including intumescent coatings and gaskets, inorganic films, and the treatment of nuclear and other toxic waste. When chemically and physically modified, it possesses some properties common to organoclays and synthetic compounds. In high purity concentrates and manufactured products, these properties can be altered and optimized in applications to produce superior performance. GEOLOGY Mineralogy Vermiculite was first described as a mineral by Thomas H. Webb in 1824. Webb believed vermiculite to be a variety of talc and described its diagnostic property of thermal exfoliation thusly: "If subjected to the flame of a blowpipe, or that of a common lamp, it expands and shoots out into a variety of fanciful forms, resembling most generally small worms having the vermicular motion exact." Observing that with one exception, all commercial vermiculite has formed by the alteration of iron-bearing phlogopite, a simple definition of vermiculite might be the alteration product of trioctahedral micas, macroscopic particles of which display marked exfoliation when heated rapidly to temperatures above 374°C (the critical temperature of water). The first vermiculite described was found near Worcester, MA, but it was later pointed out by Brush (1866) that vermiculite had been known for some time in Japan as a children's novelty. Because the techniques for mineral analysis were somewhat primitive com- pared to those routinely available today, and because the structure and crystal chemistry of the micas and related minerals were not widely understood, the early literature generated at least 20 "new" minerals which were nothing more than variations in the color and chemistry displayed by vermiculite. Trade names such as Dugarlite, Mandolitem, Strong-LiteTM, and Zonolitem are sometimes used to denote commercial vermiculite, thermally exfoliated vermiculite and their products. Vermiculite particles resemble mica and vary in color from colorless through tan and green to black, depending on the chemical composition. Most physical and optical properties are close to those of biotite, with perfect basal cleavage, hardness between 1.5 and 2.5 Mohs, and specific gravity between 2.2 to 2.8. Fine-sized particles will feel talcose, especially when wet. However, for commercial vermiculite the diagnostic test is that of thermal exfoliation. Vermiculite can display a wide range of compositions, depending on the composition of the original mica and the change of chemistry during weathering and ion exchange. Chemical data for some commercial vermiculites are given in [Table 1]. There are numerous analyses for vermiculite given in the literature, and the analyses of vermiculites from commercial deposits will fall within the range indicated by the average analysis in the table. Many analyses separate the adsorbed water (H2OP) from crystalline water and water as hydroxyl (H20+). The basis of separation of adsorbed water is generally considered to be 100°C. However, hydrate water within the vermiculite interlayer begins to be lost at 75°C and lower. Therefore, measured water content and loss on ignition are combined in the table as H20[total].

Jan 1, 1994

By E. S. Forbus

A process for producing reductive bleach in-situ in kaolin slurries has been developed. The bleach is formed by mixing an iron sponge powder (-325M) with slurry treated with SO2. The process has been successfully demonstrated in production, and applied to several grades. The color, brightness, and viscosity of the bleached product is equivalent to or better than that of product bleached with commercial sodium hydrosulfite . The tested products can be bleached at a cost, which is 38-54% of those associated with the use of commercial bleach.

Jan 1, 1993

By Yu-ren Jiang

Novel compounds of hydroxycarbamoyl carboxylic acids, including 2-hydroxycarbamoyl -3-methlcyclohexane carboxylic acid (HCMC), 2-hydroxycarbamoylmethyl decylen-4-yl carboxylic acid (HCDC) and 2-hydroxycar-bamoylmethyl tridecylen-4-yl carboxylic acid (HCTC) were synthesized. The flotation behaviors of diaspore, kaolinite and illite using these compounds as collectors were investigated. The flotation results revealed that the floatability of the minerals was, in descending order, diaspore and kaolinite, followed by illite, and the ability to collect the minerals was, in ascending order, HCMC and HCDC, followed by HCTC. At a dosage of 2×10-4 mol/L, both HCDC and HCTC show a strong ability to collect diaspore and a weak ability to float kaolinite and illite. The flotation recovery of diaspore is over 90% and that of kaolinite and illite less than 30%. Moreover, Fourier transform infrared spectroscopy (FTIR) spectrum and zeta potential, as well as the adsorption amount, indicated that the adsorption interaction between HCTC and diaspore was primarily a kind of chemisorption in the form of chelate rings, while the interaction between the collector and aluminosilicate mineral was dominated by physisorption. It was concluded that the novel hydroxycarbamoyl carboxylic acid compounds are highly selective collectors for the flotation of diaspore vs. aluminosilicate minerals.

Jan 1, 2011

Placing a detonating explosive inside a volume of rock is an efficient method of rock fragmentation. The explosion generates internal tensile stresses in the rock, and because rock is a brittle material, this brings about crack propagation and fragmentation far more efficiently than does application of explosive on the surface. To get the explosive inside, we drill a pattern of boreholes and charge the explosive into the holes. This is really the one and only purpose of making blastholes in mining: to give access for the explosive to the interior of the rock. No matter how big and expensive a drilling jumbo we stand up in front of a rock face, and no matter how many boreholes we let it drill, the rock does not fall apart by itself without blasting. It is the action of the explosive in the boreholes that does it. When we consider that we need a pound or two of explosive for every cubic yard of rock to be fragmented, and a pint of borehole volume for each pound of explosive, we see that the process of blasthole charging is an important element in the whole process of rock blasting.

Jan 1, 1975

By R. K. Singhal

In an underground coal mining environment, a frictional ignition may be defined as the ignition of an explosive air/ methane/coal dust mixture by mining machinery. As the use of power loading equipment has become more widespread, frictional ignition incidents have increased. There have been many fatalities and injuries from this cause including the death of eleven miners in Sydney coalfield of Nova Scotia, Canada in 1979. This paper reports on the findings of a preliminary study carried out under the auspices of the Coal Research Laboratories, Department of Energy, Mines and Resources Canada. The objective of this study has been to identify a Longwall face cutting system that is inherently safer than the conventional shearer loaders used in Nova Scotia.

Jan 1, 1985

By B. A. Carbon

Western Australia is the largest state in Australia with an area one and three quarter times the size of Texas. Most of the State is desert or semi-desert, and only the southwest corner is heavily populated. The State has a population of one and a half million people, and one million of these live in and around the city of Perth. Perth is located on the narrow Swan Coastal Plain and is flanked by the Indian Ocean and the Darling Plateau. The Darling Plateau is an ancient peneplain rising some 300 metres above sea level, and forms an important resource base for the population.

Jan 1, 1984

By Sam H. Patterson

Fuller's earth and bentonite are two clay commodities that are interrelated either by mineral composition or use. Because of this interrelation and the sale of both for many different uses, some ambiguity in their classification has resulted. The term "fuller's earth" has no compositional or mineralogical meaning, and it is used more or less as a catchall for any clay or earthy material suitable for certain uses. Most, but not all, of these uses require absorbent properties. Bentonite by geologic definition must have formed from volcanic ash or tuff or the glassy material in volcanic rock; most bentonites consist chiefly of montmorillonite but other clay minerals may be present. In industrial usage the term "bentonite" is applied to any clay consisting chiefly of montmorillonite, irrespective of origin. Georgia and Florida have historically been the leading States in the production of fuller's earth; bentonite has been produced in Alabama on a small scale. The first major use of fuller's earth was in refining of oils. Other materials have replaced fuller's earth for this purpose to a major extent, but many new uses for fuller's earth have been found, and production has increased in recent years. The new uses include absorbent products, insecticide and pesticide carriers, drilling mud, and many others. The bentonite now produced in Alabama is of the "southern," "low selling," or "calcium" type and is used mainly as foundry-sand bond. Most of the fuller's earth mined now is in the Hawthorn Formation of Miocene age; a lesser amount is produced from the Twiggs Clay Member and other beds in the Barnwell Formation of Eocene age. Inactive pits from which fuller's-earth was produced from other formations occur at several localities. The bentonite now mined in Alabama is in beds of Cretaceous age; several years ago bentonite was produced from Eocene beds in this State.

Jan 1, 1972

By X. Li, J. C. Stankus, J. Ma, H. Chen

Accurate evaluation of stress and geological conditions is critical to ground control design in underground openings. For a slope entry, the problem is more difficult, because a slope will transverse through many types of strata. Over the last few years, Keystone Mining Services LLC, an affiliate company of the Jennmar Corporation, has developed a new methodology designated the “Stress, geologic and support design system (SGS).” The method analyzes the stress, geology and support design for a mine slope. The method has been successfully applied in various new slopes across the United States, and ground control plans developed using SGS methodology has helped coal companies successfully pass review and/or hearings by state and federal regulatory agencies. With a case application in the U.S. Midwest, this paper details and demonstrates the main concepts of the methodology, including (1) analysis of stress and geology and identification of strong, fair and weak zones along the slope; (2) primary and supplemental support design; (3) long-term support design in the form of steel square sets or arches and (4) validation of the support design utilizing advanced finite element computer modeling.

Jan 1, 2011

By W. G. Pariseau

"BACKGROUND The Crandall Canyon Mine (CCM) is located in the Wasatch coal field in central Utah. Extensive longwall mining at CCM preceded a decision to recover coal left in barrier pillars on each side of a set of main entries extending far into the mine. During mining in March, 2007, a major bump occurred that led to cessation of mining in the barrier pillar on the north side of the mains and to begin mining in the south barrier pillar. Subsequent loss of ground control in August, 2007, through coal pillar bursts had tragic consequences with loss of six miners and shortly afterwards three rescue team members. An MSHA report describes the events in detail (MSHA, 2008). An important lesson to be learned from CCM is the need to select a computer program suitable for pillar design. Computer programs are engineering tools; selecting the right tool for the job is essential. In this regard, a minimum program requirement is capability for computing stress distribution within a pillar and adjacent roof and floor strata. The reason is simple: strength of rock is stress dependent; both vary from point to point in pillars and adjacent strata. Preferably, one should follow the evolution of stress as the mining plan is executed from start to finish to assure safety or to warn of a potentially hazardous situation developing as mining progresses. The approach to the problem posed by barrier pillar mining at CCM is conventional in the sense of applying well known finite element modeling techniques to analysis of a proposed mining plan. The engineering purpose is to evaluate the mining plan with respect to ground control questions including roof, floor and pillar safety. Results of previous two dimensional finite element analysis indicated pillar safety was by no means assured (1, 2, 3). Geometry of barrier pillar mining is limited in two-dimensions, for example, crosscuts are not seen in vertical cross sections. While three dimensional analyses are preferred, even moderately sized regions often lead to very large problem sizes that exceed computer capabilities. However, a recent development in finite element modeling of tabular deposits allows for whole mine analysis in three-dimensions. This technique involves a dual node – dual mesh concept. Both have been used separately in much earlier work, but are only now are used in combination. Estimation of subsidence at a kilometer scale and details of stress, strain and displacement about barrier pillars, main entries and pillars, and so on at a meter scale are possible (4). No compromise involving empirical formulas or similar guess work is required. Indeed, all calculations are based on first principles: physical laws, kinematics, and material laws. Effects of joints and in situ variability or uncertainty in strata properties, elastic moduli and strengths, may be included for greater realism. An important objective of the present study is to assess the role of three-dimensional pillar geometry in arriving at conclusions regarding barrier pillar mining versus two-dimensional results."

Jan 1, 2015

By Harry Leslie Bullock

With silica making up more than 27% of the earth's crust, its oxides amounting to more than 59% of the igneous rocks and quartz the most prevalent of the main free oxides, it follows that the mining engineer' is in constant contact with quartz, mainly as a gangue material to be removed as completely and economically as possible and sometimes as a valuable mineral to be purified' for the chemical,, ceramic or glass industries. Water scarcity under desert or semi-arid conditions, dwindling water supplies and difficulties of wet waste disposal in many locations and trouble from freezing in arctic locations make dry benefication more and more desirable. Advances made during the last few years in apparatus and methods and a steadily increasing knowledge of solid state physics are widening the field open to the economical application of electrostatic separation.

Jan 1, 1967

The Putnam Coal Mine, at design capacity, will be the third largest underground bituminous coal mine in the world and will feature the world's longest single flight belt conveyor. Construction is now in process; initial mining will commence in early 1969 and design capacity will be reached in 1971. I'm Jerry Workman, Assistant Mining Manager for the Coal Group of the Mining and Metals Division of Union Carbide Corporation, and I am acting as Project Manager for installation and start-up of the Putnam Mine. The Putnam Coal Mine reserves are located in south-central West Virginia and contain approximately 27,000 acres of prime Pittsburgh No. 8 coal; reserves are sufficient to support a 3.5 MM tons per year operation for over 30 years. The mine portal area is located some six miles inland from the Kanawha River. The river loading facility is located approximately 156 miles by way of river from the market.

Jan 1, 1968

By E. Farrokh

CSM and NTNU models are among the most commonly used models in TBM performance evaluation. Due to increasing application of TBM in different tunneling conditions, modification became necessary for these models. Sensitivity analyses on these two models indicate that both models are very sensitive to machine characteristics. Analyses performed on CSM database for cutter load and penetration rate prediction indicate while the r-square of the CSM model is reasonably high for the predicted cutterload, the r-square value for the penetration is low. In order to increase prediction capability of CSM model for penetration rate the model was reevaluated using non-dimensional analysis and the original database of Colorado school of mines. NTNU model is evaluated using Monte Carlo simulation and regression analysis. The results of analyses indicate that the majority of the variation of the penetration in NTNU model can be explained by only three parameters. This might indicate that the effects of other factors are overshadowed and it is worthy to reevaluate NTNU model using original database and more updated statistical methods to avoid overlapping of different parameters correlations.

Feb 23, 2014