Search Documents

By Robert W. Metcalf

The feldspars are a series of related aluminum silicates containing varying proportions of potash, soda, rind lime; smaller amounts of other minerals arc likely to be present as impurities. They comprise three principal types: Potash spars, microline and orthoclase (KA12Si208); soda feldspar or albite (NaA1Si308); and soda-lime e (plagioclase) fellspars. The last-named is an intermediate group ranging from albite through oligoclase, andesine, labradorite, and bytownite to anorthite or line feldspar (CnA12Si2O8), Minor varieties are barium feldspar or celsian and a potash-barium feldspar. Perthite is a mixture of orthoclase end albite in alternate layers. Graphic granite or "corduroy spar" is an intergrowth of feldspar and quartz characteristically in the ratio of 3:1. Cornwall stone is a natural mixture of feldspar, quartz, end kaolinite imported in former years in sizable quantity from Cornwall, England. (A similar synthetic mixture, including some fluorspar, has been blended and marketed in the United States as "Carolina stone".)

Jan 1, 1941

By R. V. Rahfuse

Noncaking 0- by 2 -inch subbituminous coal from New Mexico was gasified with air and steam at 205 prig using a stirred-bed producer to determine coal losses by entrainment in the gas for this low-sulfur, high-ash coal which contained 20 percent particles smaller than 1/16-inch sieve size. The use of fine-sized coal has particular importance because most production from mechanized mines is smaller than 2-inch size. This initial attempt showed technical feasibility for gasifying New Mexico subbituminous coal containing small-sized particles in fixed-bed producers without excessive coal loss by entrainment. Dust loss averaged about 2 percent of moisture-free coal, most of which was recovered from the gas. Ash clinkering was controlled by adding 1,010 lb/hr steam to reduce tempera¬tures in the combustion zone. Yield of low-Btu fuel gas, 150 Btu per scf, dry, amounted to 69,800 scfh from 1,490 lb/hr coal (as received) and 3,450 lb/hr air (dry).

Jan 1, 1974

By Robert W. Freedman

In the Bureau of Mines study, a filter with a 20-by 20-inch-square cross section was inserted into the exhaust ducting of a 4-stroke-cycle, 90-hp diesel engine, and the efficiency of removal of total particulate was measured gravimetrically as a function of time. Removal efficiencies were close to 90 pct during the main portion of several extended runs employing several combinations of filter beds. Variations in engine load had little effect on collection efficiency. Particle size as measured by a Bureau-developed online instrument centered on 0.07 m based on number count. Removal efficiency increased rather sharply for both larger and smaller particles.

Jan 1, 1979

By D. E. Fogelson

In a factorial experiment, blasting caps were detonated in three sizes of shotholes in mortar with three types of stemming--dry sand, wet sand, and hydrostone. Free-surface displacement pulses were recorded with a capacitive-displacement gage at a distance of 15 inches. The effects of decoupling and the type of stemming on the amplitude and the duration of the displacement pulse were determined. Both the amplitude and the duration of the displacement pulse were significantly decreased by increasing the decoupling, but they were little affected by the type of stemming.

Jan 1, 1965

By N. S. Dalal, X. Shi

While it is known that vanadate and related compounds of pentavalent vanadium ( V (V)) exert potent toxic effects on a wide variety of biological systems, the underlying biochemical mechanism is still not fully understood ( 1- 3). One of the pathways is thought to involve the oxidation of NAD ( P) H. Thus, considerable effort has been devoted to finding the mechanism of NAD ( P) H oxidation by Vcvi (1-15). Erdmann et al. (5) first noted that vanadate stimulated the oxidation of NADH by plasma membranes and attributed this effect to a membrane containing NAD(P)H-dependent V(V) reductase. Later studies by Liochev and Fridovich indicated that endogenous superoxide ( 02 ) plays a central role in this reaction ( 4, 12, 13) . They proposed that NAD ( P) H dehydrogenases or oxidases produce 02, which causes VCV ) to stimulate NAD ( P) H oxidation via the following free radical chain mechanism ( 4, 12, 13) :

Mar 1, 1992

By Raymond W. Hiteshue, Henry H. Ginsberg, Paul S. Lewis

Coal was gasified in the presence of up to 3.57 million roentgens of gamma rays by the Bureau of Mines to determine whether the irradiation increased the gasification rate or yields of methane and hydrogen . High volatile A bituminous coal was gasified with steam at 500 and 1,500 psig and temperatures of 1,400 ° and 1,800 ° F ; five other coals ranging in rank from lignite to anthracite were gasified at 500 psig and 1,800 ° F. The average results of replicate experiments with and without radiation were compared for possible effects of radiation from 40,000 curies of radioactive cobalt . The irradiation had no gross effect on the gasification rate or on the yield and distribution of methane and hydrogen . It was concluded that gammaray irradiation produced no improvement in the technology or economics of coal gasification .

Jan 1, 1964

By N. S. Dalal, A. H. Hoffman, X. Shi, D. E. Banks, J. K. H. Ma, Y. Rojanasakul

Excessive production of reactive oxygen radicals by alveolar macrophages is proposed to play an important role in oxidative lung injury. A major product of oxygen radical formation is the highly reactive hydroxyl radical (•OH) generated via a biologic Fenton reaction. In addition to its known ability to induce lipid peroxidation, recent studies have suggested that the •OH may exert its cytotoxic effect through the alteration of [Ca2+], homeostasis. To test this potential mechanism as well as to investigate the relationship between •OH and Ca" overloading in cytotoxic injury, isolated rat alveolar macrophages were exposed to externally generated radical system, H2O2 (0.01 to 1 mM) and Fe (1 mM) and their [Ca2+] levels and cell injury were monitored using quantitative fluorescence microscopy with the aid of the specific Ca" indicator, Fura-2, and membrane integrity indicator, propidium iodide. Electron spin resonance measurements using the spin trap 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) confirmed the production of the .OH radical by this system. Upon the addition of the radicals, the macrophages displayed a rapid initial rise in [Ca2+] which was followed by a slower but more pronounced [Ca2+], elevation that reached a level 3 to 5 times higher than the basal level. This process preceded cell death as evident by nuclear propidium iodide fluorescence. Depletion of extracellular Ca" inhibited both the [Ca2+], response and cell injury. Preincubation of the cells with the Ca" channel blocker verapamil or .0H radical scavenger mannitol similarly inhibited the [Ca2+], rise and loss of viability. Firefly luciferase assay of cellular ATP content demonstrated that the alterations in [Ca2+], following .0H treatment preceded the depletion of ATP. Changes in membrane potential caused by Na* substitution with K* had no significant effect on either the unstimulated or stimulated [Ca"], levels. Taken together, these measurements indicate that .OH-induced injury in alveolar macrophages is associated with the alteration in [Ca2+], homeostasis. The mechanism of •OH-induced [Ca2+] loading is not due to nonspecific membrane damage or energy depletion, but mainly due to an increase in Ca2+ influx through Ca2+ selective channels. This Ca2+ over-load state as well as energy depletion caused by the oxidant may activate certain cellular degradative processes leading to cell injury and death.

Nov 1, 1995

By L. C. Marchont

This Bureau of Mines report tabulates data on nitrogen-gas reservoirs and isolated occurrences of inert gases in several Williston basin oilfields. Recoverable reserves of nitrogen gas in the Minnelusa nitrogen interval within the areas of five oilfields on the Nesson anticline in North Dakota are estimated at about 1.27 trillion standard cubic feet, based on computer analyses of logs from over 300 wells. This volume of nitrogen represents a large source of high-pressure inert gas and warrants consideration of possible application in oil-production operations. Drill-stem tests made in two of the fields indicated that nitrogen can be produced at rates up to 28 million cubic feet per day.

Jan 1, 1966

By P. M. Sullivan

At its College Park Metallurgy Research Center in Maryland, the Bureau of Mines has installed and is operating a 5-ton-per-hour pilot plant for continuous mechanical separation of values contained in raw urban refuse. The entire sys tern was assembled using commercially available equipment. The process relies on multistage processing including shredding, air classification, screening, gravity concentration, and electrostatic separation. Compactor trucks deliver raw refuse collected along typical routes in metropolitan Washington, D.C., to the pilot plant. The loads are separated into concentrates of (1) light-gage iron, (2) massive metals, (3) glass, (4) putrescibles and waste combustibles, (5) paper, and (6) plastics. While some refinements remain to be made in the processing system flow-sheet, the data obtained to date have been highly encouraging, indicating favorable economics for commercial-size plants.

Jan 1, 1973

By J. E. Zeilinger, John Nagy, Irving Hartman

"INTRODUCTION Experience and research have shown that an effective way to reduce structural damage from explosions is to provide adequate pressure-relief vents in the walls of equipment and buildings within which explosions might occur. In general, free or unrestricted openings represent the most efficient type of vent. However, in many manufacturing operations it is impractical to use free vents, and it becomes necessary to cover the openings with diaphragms or blow-out disks, hinged panels, or other devices, in order to give protection against weather changes, to prevent the efflux of dusts or vapors from equipment during normal operations, or for other reasons.A few data on the pressure-relieving capacities of hinged panels and a paper diaphragm were published in Bureau of Mines Report of Investigations 3924,4/ which covered the first phase of the dust-explosion venting study made by the Bureau. The present report describes recent experiments that were made to determine the relative effectiveness of an unrestricted vent and 22 types of closures, including various paper, cloth, and metal-foil diaphragms, hinged doors or panels, and several kinds of scored and unscored glass panes.The tests showed that many of the vent closures were effective in releasing the explosions rapidly during their incipient stage, so that the development of destructive pressures was prevented. Vents of this type should prove useful in safeguarding industrial equipment from severe explosion damage. The experiments disclosed that the venting capacities of the diaphragms are approximately inversely proportional to their static bursting strengths."

Jan 1, 1950

By Robert L. Rough, William E. Eckard

Laboratory data obtained from a Bureau of Mines rotary air core of a well near Sugar Grove , Warren County , Pa . , were instrumental in initiating hydraulic fracturing in the area to stimulate oil recovery from Glade sand oil reservoirs . This report outlines the general geology , lease development , reservoir- rock characteristics , and oil - production history of Glade and Clarendon sand reservoirs in Warren County . The methods of well completion for single- stage and multiple- stage hydraulic fracturing of old and new wells are discussed , and a range of hydraulic fracture treatment data from 29 Glade sand and 10 Clarendon sand wells is presented . A composite decline curve representing oil - production data from six wells shows probable results of hydraulic fracturing . Average cumulative oil production during the first 100 days after hydraulic fracturing with a sand - carrying liquid is compared with production after conventional shooting with liquid nitroglycerin .

Jan 1, 1964

By E. J. Schneider

In view of the current interest in the constituents of low-temperature tar, the Synthesis of three known xylenols and their hydroxyacetic acid derivatives has been undertaken by the U. S. Bureau of Mines. One of these xylenols, the 1,3,2 derivative first reported by Steinkopf and Höpner,4 has been described by Brown and Branting.5 The other two derivatives, the 1,3,5 first reported by Schütz6 and the 1,2,3 reported by Steinkopf and Höpner, have now been studied in greater detail. In the present work the synthesis of 1,2,3-xylenol and 1,3,5-xylenol was repeated, with some improvements in the former. The hydroxyacetic acid derivatives were also prepared, and it was found that while the melting point of the 1,2,3 derivative agreed with that of Steinkopf and Höpner. that of the 1,3,5 derivative was found to be 111° instead of 85 to 86° as reported by Schütz, by Steinkopf, and later by Bruckner. The discrepancy between the melting-point figures is doubtless due to differences in the purity of the xylenols used in the synthesis of the acids. Schütz obtained his 1,3,5 acid by recrystallizing an impure sample obtained from a mixture of xylenols. The difficulty of obtaining a pure acid by starting with a mixture is demonstrated by Bruckner, who despite painstaking efforts was unable to obtain the pure 162.5° melting 1,2,4 isomer from a mixture that persistently melted at 138° C. Steinkopf did not repeat Schütz's work but merely used the latter's figures in compiling a table. Bruckner, on the other hand. apparently also made the acid (by an improved method), and it is difficult to explain his checking Schütz's figure, unless it is that he, too used a symmetrical xylenol obtained from a tar and not prepared synthetically, as was the one reported in this paper.

Jan 1, 1929

By R. R. Brown

The solubility and the activity of aluminum chloride hexahydrate, A1C13?6H2O, in aqueous solutions were determined as a part of the Bureau of Mines, U.S. Department of the Interior, research to improve mineral processing technology for recovering alumina from low-grade domestic resources. The solubility of A1C13 in pure water was found to be 31.09 and 31.77 wt-pct at 25° and 85° C, respectively, and decreased drastically to 10 and 0.1 wt-pct when the respective amounts of 20.3 and 37 wt-pct hydrochloric acid (HCI) were added in solution. The equilibrium constant for the solubility of hexahydrate, activities, and activity coefficients of A1C13 and H2O were calculated and compared with the results from the available methods of estimation. The results were shown to be useful in leaching nonbauxitic ores for extraction of alumina by changing the solubilities of component salts upon addition of HC1. Simultaneous solubilities of A1C13, FeC13, KC1, and NaC1 in solutions of HC1-H2O were also determined and their effects on the purity of A1C13?6H20 crystallized from mixed salt solutions are briefly discussed.

Jan 1, 1979

By C. E. Hennig

On January 1, 1959, the United States had 313 petroleum refineries with a total installed crude-oil throughput capacity of 9,819,846 barrels per day, according to the Bureau of Mines annual survey. Compared with a year ago, this represents a net decreased of five in the number of slants mild a net increase in capacity of 412,139 barrels per day. The continued increase in total capacity and decrease in number of plants raised the average capacity of a refinery to a new high of 31,373 barrels per day. During 1958 total capacity increased in every refining district except the Louisiana Gulf district, which showed a 2-percent decrease due mainly to the retirement of the American Oil Company's plant at Destrehan, La. The largest increase, 14 percent, occurred in the Texas Inland district followed by a 12-percent increase in the Arkansas-Louisiana Inland district. At the beginning of 1959 the industry was building facilities that would add 108,400 barrels per day to crude-oil capacity. It also had under construction a capacity of 226,100 barrels per day as replacement. On January 1, 1959, no new refineries were under construction.

Jan 1, 1959

By Robert Roby

The Mouat copper-nickel deposit in Stillwater County, south-central Montana, was examined by Paul T. Allsman, an engineer of the Bureau of Mines, in 1939. Because of the strategic importance of nickel, a project was executed by John East, Jr., J. J. Naughton, and E. W. Newman, engineers of the Bureau, to further delimit some of the copper-nickel sulfide-bearing bodies that had been discovered by the Anaconda Copper Mining. Co. in 1937 and to investigate the central part of the deposit, which had not been drilled previously. This report is based largely upon the results of the. Bureau of Mines investigation and the results of exploration by the Anaconda Copper Mining Co. In addition, a brief description is given of some other copper-nickel sulfide-bearing deposits along tho Stillwater Complex.

Jan 1, 1949

By Oliver Q. Leone

Three electrorefining cells were designed to investigate various factors associated with the electrorefining of reject - grade titanium sponge . Operation of the cells provided information on cell design as well as on how design and operating variables affected the quality of the titanium product . A sodium chloride - titanium chloride electrolyte was used , and the electrolyte chambers had capacities ranging from 400 to 3,500 pounds of molten salt . Major factors investigated were electrolyte composition , temperature and useful life , effect of various cathode shapes and materials of construction , methods for removing cathode deposits , effect of current density and cell potential , and the mechanics of deposit growth and crystal morphology . One of the cells was in intermittent operation over a 4 - year period and produced 2 tons of refined titanium . A product with a hardness of 80 or less Bhn (Brinell hardness number ) was consistently and easily obtained . Some metal with a hardness of less than 60 Bhn was produced . In one of the cells in which the electrolyte was held at operating temperature with an internal heater an ac input of 25 kw maintained 3,500 pounds of electrolyte at 850 ° C , but with an external heater 35 kw was required to maintain 400 pounds at 850° C.

Jan 1, 1964

By R. Van A. Mills

Crude oils are capable of dissolving quantities of gas under pressure. This fact has been known for some time, but questions have arisen as to the effects of gas in solution upon the characteristics of the oil. Previous investigations4 show that gas in solution in an oil affects the viscosity and surface tension of the oil, but the effect's on the volume and A. P. I. gravity of the oil have not been known. The results given in this report show that there is a decided change both in volume and in the A. P. I. gravity of the oil due to the solution of the gas in the oil under pressure. As gas is dissolved, the volume of the oil and the A. P. I. gravity increase. The converse of this phenomenon is also true: if the gas is released from a saturated oil, there is a shrinkage in volume and a decrease in A.P.I. gravity due to the release of gas from solution. However, various oils show marked tendencies to retain a portion of the dissolved gas upon releasing the pressure to that of the atmosphere. This retained gas has an appreciable effect on the volume and A. P. I. gravity of the oil because the oil does not resume its initial volume or gravity while it retains dissolved gas. In a sense the oil has been "Freshened" and will not return to its original or weathered volume until it loses some of the lighter fractions. Wiggins5 has shown that a fresh oil decreases both in volume and in gravity because of the weathering of the lighter fractions while the oil is standing in storage tanks.

Jan 1, 1928

By R. W. METCALF, A. G. Charles, F. M. SHORE

To furnish the information frequently requested by producers and suppliers as to the fuel requirements of the Federal Government , the Bureau of Mines , with the cooperation of the consuming departments and establishments , has collected the data herein , showing the Government's fuel consumption during the fiscal year ended June 30 , 1930. The following tables show the quantities and kinds of fuels consumed by the Federal Government in each of its departments and their principal branches , in each State , and in Alaska , Hawaii , Panama Canal Zone , Porto Rico , and the Virgin Islands . The separate departments and establishments were asked to supply information for each Federal building or other plant and , as to vessel fuel , the amount loaded at each port of supply . Fuels consumed in internal combustion engines are not included . The report does not include fuels used by Post Offices of the fourth class , since their fuels are not purchased by the Federal Government but are covered by an allowance in each case for light and heat . In some cases the data supplied represent receipts , which are approximately equivalent to consumption . The present study is believed to be the first effort to bring together the data representing the Government's requirements for the various fuels which it consumes . Figures showing the coal consumed by the Federal Government were gathered for the year 1922. These data are shown in an article by O. P. Hood and R. H. Kudlich of the Bureau of Mines , contributed as a chapter to " Industrial Coal ; Purchase , Delivery and Storage , " published by the American Engineering Council . The figures of coal consumption presented herewith are approximately comparable with those published for 1922 , a relatively small difference being due to the fact that the 1922 figures include the Philippine Islands and all other territory in which any coal was consumed by the Government . At the present time , the only data on Government fuel consumption that are published regularly are those compiled by E. B. Swanson , chief economist of the petroleum economics division of the Bureau of Mines . These are published annually by the Bureau of Mines in " Sources and Distribution of Major Petroleum Products , Atlantic Coast States , " and by the bureau in cooperation with the American Petroleum Institute in the annual " National Survey of Fuel Oil Distribution . " It is believed that the data herewith will prove of interest and value to the fuel industries as well as to Government consumers and that it will also afford a basis for measuring future trends in the use of the various fuels by the Federal Government . Figures showing the quantities of the various kinds of fuels consumed by each of the executive departments and independent establishments , are given in Table 1. It should be noted that when one organization procures and delivers fuel to be consumed by other branches

Apr 1, 1932

By E. C. Pattee

A mobile spectroscopic laboratory was completed by the Bureau of Mines in 195 to provide a rapid, inexpensive means of field testing samples for beryl¬lium and other associated metals of possible commercial importance. Spectro-copes have been used in laboratories for many years in various types of research and routine analyses, but this spectroscope is probably the first mobile unit. The laboratory provides for spectroscopic, radioactivity, fluorescent, and limited chemical tests of samples. The unit has been a valuable reconnaissance tool. It has been used to search for beryllium, cesium, columbium, tantalum, rubidium, and lithium in Idaho, Washington, and Montana. Several very low grade deposits of these elements were found, and occurrences of other important elements were identified; however, none are of economic importance. The spectroscope permits the detection of elements by analysis of visible light produced when elements in a small powdered sample are volatilized in an electric arc., A total of 70 elements can be detected; 29 can be detected at or below 0.01 percent, Electric power for the arc is supplied by a gasoline motor-driven generator, Equipment is housed in an aluminum van, mounted on a 4-wheel-drive vehicle for easy maneuverability on mountain roads, A trailer with crushing, pulverizing, and splitting equipment permits the reduction of samples to a small representative pulp.

Jan 1, 1963

As part of its regular program to provide timely information on domestic mineral commodities, the Bureau of Mines conducted an engineering appraisal of more than 1,300 lode and placer gold deposits in the United States to deter-mine their gold production potential. While these deposits were estimated to contain over 400 million ounces of gold, only 9 million ounces, or slightly more than 2 percent, was found to be producible at $35 per ounce under prevailing mining and metallurgical technologies. The study revealed that any significant increase in available gold in the United States is most likely to come from the discovery of new sources, intensive exploration and development of the more promising known mineralized areas, and development of new or improved mining and metallurgical techniques.

Jan 1, 1967