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By Lar Liljeblad

"As demands upon the earth's natural resources continue to grow, exploration companies, mining organizations and others face the problem of the need to tackle increasingly more difficult strata to open up new reserves. Innovations in materials technology and tool design have steadily improved this capability, but none perhaps so drastically as a recently introduced cemented carbide in which tool wear resistance and/or toughness can be tailored precisely to the user's drilling needs.Introduction Until about forty years ago, the bulk of rock-drilling operations had to be carried out with hardened steels. Short life between re-grinds was common especially in abrasive rock formations. Shortly after World War II, Sandvik, Sweden, pioneered the development of sintered (cemented) carbide-tipped steel tools as a means of improving drill tool life. The new material was a composite of tungsten carbide and cobalt, the latter acting as a 'cement' to bind the wear-resistant carbide grains together, and the composite, in turn, was brazed to the steel. The immediate effect was a 100-fold increase in the service life of the tool.Intractable ProblemsWhile the carbide-tipped tools served the mining and quarrying industries admirably there were, nonetheless, some seemingly intractable limitations. The greater the wear resistance of the material - the quality for which it is selected - the more brittle it is. Also, rocks vary widely in hardness and abrasiveness and no single tool, either in terms of material or shape, meets every need. Specifically, for fast penetration of non-abrasive rock, toughness must be combined with a relatively sharp tool prome. Highly abrasive rock, on the other hand, demands a substantially broad area of extremely wear-resistant material on the tool if long bit life is to be assured. Between these extremes there are innumerable variations in rock"

Jan 1, 1991

By Umbreen Agha, Stephan L. Chryssoulis, A. Margaritis

"The deportment of gold in samples of the biooxidation feed and product from the Harbour Lights mine in Western Australia was determined using optical microscopy and microbeam techniques such as Secondary Ion Mass Spectrometry (SIMS), Time-of-Flight Laser Ionization Mass Spectrometry (TOF-LIMS), and Electron Probe Microanalysis (EPMA). The main objective was to determine the mechanisms by which acidophilic bacteria (Thiobacillus ferrooxidans) liberate refractory gold which is locked in a sulphide minerals host as visible gold inclusions (> 0.1 µm) and as submicroscopic or 'invisible' gold.Using the integrated mineralogical approach approximately 99% and 100% of the assayed gold in the biooxidation feed and biooxidation product was accounted for. The results were compared to and verified by chemical assays.The gold deportment study indicates that during biooxidation, locked visible and 'invisible' gold is rendered cyanidable by the direct action of Thiobacillus ferrooxidans as well as indirect chemical leaching. Visible gold which is enclosed in sulphide minerals is liberated or partially exposed and is therefore rendered cyanidable as the host mineral is oxidized and dissolved. 'Invisible' gold either coalesces on the surface of the host sulphide mineral as the particle is dissolved or is released into the liquid phase and immediately adsorbs onto the surface of other ore particles with a net negative charge.The shakeflask suspension indicates that direct bacterial oxidation pits and channels correspond to zones of 'invisible' gold and arsenic (in pyrite) enrichment in the host sulphide mineral."

Jan 1, 1996

By Qiling Zhang, Zengqian Hou, Xiaoming Qu

Abstract - The Okinawa trough is an active back-arc-spreading center in which submarine hydrothermal exhalation (black chimneys) and sulfide mineralization are forming. Fluid inclusion composition in minerals of the hydrothermal feeder zones in the JADE field shows that the hydrothermal systems are extremely gas-rich. There are two independent and co-existing fluids, CO2-hydrocarbon and saline fluids. Microthermometry and Laser Raman Microprobe (LRM) analyses on individual fluid inclusions of the CO2-hydrocarbon type, dominated by CO2 and containing minor CH4, C2H4, C2H6, N2 and H2S, are almost equivalent to the fluid inclusion composition of a natural gas field. The saline fluid is mainly composed of H2O and contains minor Na+ and K+. It is close to a H2O-NaCl, or H2O-NaCl-KCl system, with salinities from 3.7% to 7.5% NaCl eq. Before venting on the seafloor, the fluids experienced immiscible separation. One of the end-member fluids is downward circulating seawater that interacted with sub-seafloor rocks. The other was gas (volatile)-rich fluid derived from a shallow magma chamber. The immiscibility separation of fluids resulted from the decrease of temperature and pressure of the hydrothermal system and continuous input of magmatic volatiles. The saline fluids in this system are discharging to form sulfide chimneys and black smoke. Meanwhile, CO2-rich fluid discharges as CO2 bubbles through hydrate pipes. A large amount of CO2-CH4-H2S gas or fluid in the upper part of the hydrothermal system, and reaction of this gas or fluid with saline fluids, finally enables the accumulation of metal sulfides.

Jan 1, 1999

By Alan G. Galley

"Advances in our knowledge of the petrochemical attributes of deposit environments and of the character and extent of hydrothermal systems associated with certain deposit types has resulted in increased application of lithogeochemistry to exploration programs. Lithogeochemistry can be used to vector an exploration program toward an area of high potential through the use of a series of collapsing scales of analysis from a tectonic subprovince down to a particular stratigraphic segment. In the case of volcanogenic massive sulphide (VMS) deposits this involves the recognition ofsuitable volcanic domains, and the identification of subvolcanic intrusions and cogenetic felsic extrusive complexes. The recognition of chemical vectors within regional-scale alteration zones and associated chemical sedimentary rocks allows the geologist to identify the stratigraphic units with the most potential for hosting a base metal deposit.An integrated lithogeochemical program requires the judicious use of major, trace and rare-earth element and isotopic analysis. Standard discriminant plots may be employed to identify suitable tectonic and lithologic environments. Analysis of the chemical and mineralogical variations in broad-scale, semi-comfortable alteration zones provides a useful set of vectors to VMS mineralization. These may include contouring raw data, element ratios on XY plots, normalizing data against known rock values, or calculating mass changes in alteration zones."

Jan 1, 1995

By Hung-wei Liu, Kevin Plucknett

Early attempts to manufacture titanium aluminides using blended elemental powders, through powder metallurgical processes, have been obstructed due to serious swelling during sintering. Although the use of pre-alloyed powder can avoid this undesired expansion problem, there are limited commercial powder sources available. Therefore, in the present research, fundamental studies on the synthesis of dual-phase (? plus a2) Ti48Al intermetallic materials is undertaken, in particular assessing powder manufacture. In order to produce pre-alloyed powders, highly porous Ti48Al pieces are initially sintered from elemental Ti and Al powder blends, and subsequently pulverised into powders. The powder size is then further reduced by use of either dry or wet milling processes (i.e. shatterbox grinding, attrition, or ball milling). Among these methods, shatterbox grinding has shown the highest efficiency, with a slight mechanical alloying effect observed. The manufactured powder morphologies and phases, as well the sintered material, will be discussed.

Jan 1, 2015

By Simon B. Blancher, Malo Rousseau, Renato Contessotto, Thomas Wallmach

The Manganese division of the ERAMET group extracts manganese ore in Gabon and produces manganese alloys for the steel industry. ERAMET has an economic interest to maximize the ore throughput without reducing the lifetime of its manganese mines. This can be achieved by means of research and development leading to innovative ore beneficiation processes. For this purpose, the ERAMET research center has designed and constructed a new pilot plant for ore beneficiation by physical separation processes. This pilot facility was erected within an infrastructural and synergetic framework, including competencies in hydrometallurgy, pyrometallurgy, numerical modelling, analyses and mineral characterization that provide ideal research conditions. After laboratory scale tests, a pilot operation of beneficiation of low grade Mn ore (around 35% Mn) was carried out by jigging of the 1-10 mm fraction. This gravity separation process exploits density differences between the various Mn-bearing minerals such as pyrolusite and lithiophorite as well as gangue minerals such as silicates and iron-hydroxides. Enrichment leads to the production of a marketable product associated with a high mass recovery (53% for the jigging step). However, 20% of pyrolusite and 30% of lithiophorite are lost in the waste. Mineral characterization has shown microtextural complexities, but grinding the ore to approach the liberation mesh was not an option due to commercially defined constraints given by the ferro-alloy industry. Recovery of the Mn-bearing minerals or adjustments of the feed grain size (6.3-10 mm) are two potential areas of process improvements identified by means of Qemscan® mineral characterization. This paper details the process tested on a pilot scale (0.5 t/h), which has led to a significant increase in the beneficiation of a low grade Mn ore.

Jan 1, 2016

By Kamran Esmaieli

Open Pit Mining Through Underground Voids: Challenges Main Challenges/Hazards: Unexpected collapse of the pit floor and/or pit walls; The loss of equipment and/or people into underground voids; Loss of explosives from blast holes that broken through into the underground voids. How to address these challenges? An important step that must be integrated into mine planning and design is the accurate detection and delineation of underground voids. (i.e. probe drilling, Geophysical techniques, laser scanning,?); Leaving a pillar of adequate thickness between the working bench and the underground voids; Backfilling the underground voids from surface using vertical or inclined raises; Monitoring the working locations (pit floor and pit slopes) to detect movements.

May 1, 2013

By A. B. Carino

Gulf Minerals (Canada) Limited's Rabbit Lake uranium operation is located in the northern portion of Saskatchewan, 198 miles southeast of Uranium City and /34 miles northwest of Lynn Lake, Manitoba. The paper follows the ore flow through crushing, grinding, sulphuric acid leaching, countercurrent decantation, solvent extraction, ammonium diuranate precipitation, thickening, drying and tailing neutralization.

Jan 1, 1979

By A. J. Smethurst, S. B. Hearn, S. Boskovic

"The problem of crud in solvent extraction is well known and can be a major handicap and operational issue. Colloidal silica can cause a number of problems including interfering with flocculation, initiating crud formation in solvent extraction (SX), decreasing SX extraction kinetics and increasing SX phase disengagement times. Flocculation can be utilized to remove some of the troublesome particulates but colloidal silica does not flocculate well and presents a different problem requiring innovative chemistry to solve. Coagulants can assist by facilitating the removal of this colloidal silica by promoting the agglomeration of the particles to a size which can be more readily settled or flocculated in solid/liquid separations. This is achieved when the coagulants bind to the surfaces, displacing water and destabilizing the colloids, whereupon they bind to each other which facilitate their amenability to conventional flocculation.INTRODUCTIONSilicate minerals are abundant in the upper layers of the Earth’s crust, and there are few mineral deposits without significant levels of gangue silicates. Silicate minerals include the pure silicas, such as quartz and other silicate containing minerals such as clays, chlorites, feldspars, as well a vast number of less common silicates.During the acid leaching of ores, two types of fine silica particles are released in solution from the dissolution of the host mineral. The first consists of partly depleted silicates, and the second is colloidal silica, which forms in solution. It is this second type which has the potential to cause crud formation as well as poor solution clarities, slow filter rates and excessive flocculant usage (Figure1)."

Jan 1, 2016

By M. L. Jeremic

"The syngenetic and epigenetic mechanics of sedimentation and deformation of coal seams resulted in various types of internal structure, as listed below:TYPE I-massive structure with evenly distributed coal constituencies of integrated mechanical properties.TYPE II-broad-banded structure, with bright and dull coal bands of differential mechanical properties.TYPE III-heterogeneous structure, with sheared coal bands and partings of sectional mechanical properties.TYPE IV-contortional structure, with refolded coal layers and deteriorated mechanical properties.TYPE V-porous structure of orogenically crushed and pulverized coal, with disintegrated mechanical properties.The study suggests criteria for the estimation of coal seam internal structure (gamma-gamma density log and cracks density log), which might be related to the evaluation of strata stability and coal mineability.IntroductionIt is common knowledge that coal seams have various internal structures due to different syngenetic and epigenetic events. Investigations of the internal structure of coal seams have been carried out in the coal fields of Western Canada, as follows: geological field studies of coal-bearing strata;?,geophysical borehole surveying studies;?,geological borehole logging and crack density;?,underground phenomenological studies of mine structure;?,chemical coal analysis; and?,mechanical testing of coal samples.These investigations eliminated a large number of criteria previously established for the estimation of coal seam internal structure and indicated that, from an engineering point of view, only two of them are sufficient:(I) density of seam profile (inferred from gamma-gamma log);(2) density of crack s (inferred from geological log).On the basis of these criteria, five main structural types of coal seams have been classified, which might be related to mechanics of deformation and ' failure of mine structures."

Jan 1, 1982

By Noel G. Thomas

"This paper will identify where the industry is heading with iron· ore in the next ten years. From a customer's point of view, an indication of the changing, yet expanding, market will be made. This will progress further into the most likely changes in chemical and physical requirements of the ore products. No definite target can be set for 1990, but the logic from the direction of the changes will be established.IntroductionThe tonnage and quality of iron ore produced in the eighties will be heavily influenced by energy and investment considerations. That's not a great pronouncement, but this paper will explain how these two factors are :(I) influencing a disproportionate growth of electric furnace capacity and a greater use of scrap for iron units, in place of Iron ore;(2) influencing chemistry specifications; and(3) causing extensive examination of ore agglomerate form. Inflating investment costs are emphasizing the need for more productive blast furnaces, and the iron ore burden is under heavy examination as to how it affects productivity and coke rate."

Jan 1, 1981

By Robert B. Parsons

"A joint federal/provincial/industry subcommittee of the Intergovernmental Working Group on the Mineral Industry (IOWG) has published an informative and readable report on taxation matters concerning Canada's mining industry. The report, which was presented to the federal and provincial mines ministers in September 1986, identifies and discusses key tax issues relating to this industry. The report is mandatory reading for anybody with an interest in mineral exploration or production in Canada.IntroductionIn 1986, Canada's federal and provincial mines ministers were presented with an important report concerning the taxation of this country's mining industry. This document is important for a number of reasons, two of the reasons being: first, the report contains an objective analysis of the key mineral taxation issues of the day; and, second, the report is the product of a cooperative exercise involving representatives of various facets of the industry and government. The report should be regarded as compulsory reading for anybody who has an interest in fiscal matters affecting mineral exploration and production.The ""Report on Fiscal Proposals"" was prepared by a subcommittee of the Intergovernmental Working Group on the Mineral Industry (IOWO). IOWO is a group of senior federal, provincial, and territorial government officials concerned with the analysis of mineral policy issues in Canada."

Jan 1, 1986

By Peter A. Bevan

"In massive and semi-massive deposits, it is essential to take samples continuously for specific gravity determination as well as for assays of the various metals of interest. Failure to use specific gravity in mixed deposits of high density contrast will result in incorrect determinations of the average grade.Graphs and linear equations of specific gravity against the grade of one metal are not considered accurate enough in a multi-mineral deposit, but appear to be very satisfactory in a theoretical one-sulphide/gangue mix. Specific gravities based on base-metal values only in massive sulphide deposits will result in underestimating the effect of low grade areas on the average grade and also cause a reduction in the calculated tonnage.IntroductionBy definition, a base-metal assay is the percentage of metal by weight contained in a sample, whether it be a soil or silt sample, a grab, chip or channel sample, or a section of diamond drill core.In those cases where there is a series of contiguous samples, say in diamond-drill core, the average grade may be required of the various assays that are above a desired or required cutoff grade.Internal low grade or waste can be included if the assays one side or the other are used to ""carry"" the lower grade material and the resulting average grade is above the cut-off grade. To determine the average grade, the individual assays are ""weighted"" by multiplying these values by their respective lengths, adding up the cumulative assay times length and dividing by the total length. This method is essentially a weighting by volume, because the core diameter is constant and is common to all the samples being considered for estimating the average grade . If some of the core samples have much higher specific gravities than others, and the specific gravities are not used in the weighting process, the resultant average grade will be over-estimated or underestimated, depending on the grade of the heavier sections. When core assays of approximately the same specific gravity or weight are averaged by length, the error in the weighted estimation of the average grade is negligible."

Jan 1, 1993

By J. H. Shillabeer

"Rational exploration requires the prior selection of areas possessing excellent geological potential and minimum hazards to commercial development . Within an over-all strategy of grass-roots exploration, two procedures for selecting areas for (i) coal and (ii) metals exploration are described. The procedures explicitly balance infrastructure requirements and environmental concerns for areas of geological merit not alienated in parks and reserves. Through consensus, priorities are attached to those areas meriting closer scrutiny and field reconnaissance.IntroductionMining companies need to know that having made a potentially economic discovery, they will be allowed to develop it with minimum delay and at reasonable cost. The environment for exploration in British Columbia is complex and recent experience suggests that conditions are not becoming any easier. Conflicts over land use issues, preservation and economic development are common. The high cost of exploration requires that the risks should be offset where possible by: (i) carefully selecting the areas in which to work (ii) conducting operations in a responsible manner, and (iii) working cooperatively with the community of interests. This paper concerns the first action: prior selection of areas.To aid exploration planning at Suncor, a procedure was developed to grade those areas of the province possessing favourable geology according to the ease with which a mine might be developed . This had to be done within the constraints of the company's over-all approach to exploration. This emphasizes ""grass-roots"" exploration of self-generated projects in British Columbia. In addition, having selected a favourable belt of rocks, it is intended to persevere there while steadily adding to the accumulated data base and local experience. Hence, it is intended to concentrate on an area. This implies a long-term commitment to an area which in turn increases the importance of the original selection.Suncor's search is directed to finding base and precious metals in intrusive and volcanic environments, and export quality coal."

Jan 1, 1985

By S. L. Gula

"Effective and timely communication during routine operations, and especially during emergency situations, is no easy task in any underground mine. At Cominco Fertilizers, Potash Operations, where 150people are employed underground to produce 3.1 million tonnes of potash per annum at a depth of 1100 m (3600ft), this is no exception. The over-all mine workings underlie an area of approximately 20 km 2 with average travel time to the active mining areas being approximately 30 to 40 minutes by light vehicle, and significantly longer than this for heavy equipment.In a mine of this size, the deployment and management of personnel and materials on a day-to-day basis, and during mine emergencies, is an important exercise. The Personal Emergency Device (PED) system has provided the Potash Division a means to achieve improvements in this area and reduce the communications bottleneck.The MineAt Cominco Fertilizers Potash Operations, approximately 30 km southwest of Saskatoon, the orebody is the same horizon being mined by other potash producers in the Saskatoon area and extends over 300 km in an east-west direction, and approximately 150 km in a north-south direction. Mining operations are carried out with approximately 150 employees operating on a continuous-shift basis, seven days a week.Mining is presently being done from Block 6 which takes the mine to its northernmost boundary and contains reserves of approximately 50 million tonnes. Production is from one level by five twin rotor continuous mining machines, each capable of cutting a face up to 5.5 m wide and 3.3 m high . All ore is transported to the shaft via approximately 20 km of conveyor where it is removed to surface by two 24 tonne skips.After the ore is conveyed to the mill for processing, the finished product is shipped by rail car or trucks to other parts of Canada, the United States or through Vancouver to other parts of the world."

Jan 1, 1993

By K. D. Eng, W. T. Tierney

"During the past century, the development of vehicular transportation has benefitted tremendously from the performance improvement in engines in a situation where low-cost, plentiful fuel supplies were the order of the day. Engine advances were enhanced by and also dictated fuel modification to better adapt the energy source to the power plant.In discussing the several aspects of the change in approach from ""an engine and its fuel to a fuel and its engine"", the authors touch on the following areas:1. Description of an engine concept that provides the needed flexibility in fuel appetite at good efficiency to cope with future requirement s.2. The constraints placed on liquid fuel resource energy utilization efficiency by special engine-required fuel properties and the fuel efficiency of the various engine types available.3. Future vehicle engine fuel sources. This review will put into perspective the problem associated with the net energy available from future fuel sources under extensive research and development at present.4. A brief review of test data to show that fuel-tolerant and fuel-efficient engines are viable and that, in a fuel-resource-limited future, they can be a ""light at the end of the tunnel.""The Texaco Controlled Combustion System (TCCS)The TCCS is a unique means for stratified charge operation of an internal combustion engine in such a manner as to eliminate the requirement for octane or cetane number specification for the fuel. Octane rating is an empirical engine test method that evaluates a gasoline's resistance to spontaneous ignition or ""knock."" Cetane is based on a different engine test, which determines a diesel fuel's ease of spontaneous ignition . High cetane number enhances cold starting and permits high-speed diesel engine operation. As one would expect, the fuels in current use cover a band when the two values, octane and cetane, are plotted against each other."

Jan 1, 1982

By Robert B. Parsons

"Considering the traumatic events of Canadian mining taxation of the 1970s, one wonders at the sanity of anybody who tries to predict what the 1980s might hold for the tax structure of the mining industry. Yet, the author agreed to tackle this task when called upon to do so at the annual meeting of the Quebec Metal Mining Association in June. The text of this ""daring"" speech follows.IntroductionI have been asked to play the part of the oracle at Delphi, and to predict what the 1980s might hold for the Canadian mining industry in terms of taxation. To appreciate the challenge of this difficult assignment, try to imagine someone in my position back in 1972 attempting to forecast the balance of the 1970s. I daresay that ten years ago nobody could possibly have conceived of the devastating and casualty-ridden rollercoaster ride that mining taxation actually took in the 70s. Nevertheless, I shall examine the entrails and try to shed some light on what might happen during the balance of this decade as far as mineral taxation is concerned.If one were to retreat deep into history, one would find that taxation generally served one purpose-namely, to raise revenues for the government. More recently, an important second function has emerged: taxation is increasingly being used as a fiscal tool-a tool intended to mould and shape future events in order to accomplish certain economic, social and political objectives. It is these two main forces-the need (or desire) for revenues and the perceived convenience of using taxation as a fiscal tool-which will continue to shape the tax structure of the future.In our assessment of where taxation of the mining industry may be headed, we should be able to learn something by looking at where we have been."

Jan 1, 1982

By J. G. Whellock, J. W. Matousek

"In spite of their importance to the economics of many metallurgical projects, the values and technical aspects of precious metals losses in smelting operations are relatively undeveloped subjects. This paper attempts to provide a condensed overview of precious metals losses in pyrometallurgy, using some of the limited production and experimental data available. It is intended for three general groups of metallurgists - operators attempting to improve recoveries, cost-accounting engineers making estimates of metal losses in new or modified smelting plants, and research engineers and students.Distribution coefficients of precious metals, the ratios of metal or matte assays to slag assays, are convenient means of comparing smelting processes and the tendencies of the different metals to enter the slag. For silver in lead blast furnaces this ratio is approximately 250;for gold and the platinum group metals in submerged-arc, electric furnaces it is 900. The ratio for gold and PGMs in converters varies with the degree of oxidation of the charge. The over-all cycle-average for industrial installations is tentatively estimated to be 35.IntroductionThe magnitude of precious metal s losses in pyrometallurgical operation s is difficult to assess. The primary producers are generally reluctant to discuss the subject. The by-product producers (the large sulphide smelters o f copper , nickel, and lead) might be more willing to disclose information, but these have precious metals in their feeds in such dilute quantities that accurate accounting is extremely difficult. It is not until numerous processing steps have been taken t hat the precious metals become sufficiently concentrated to permit acceptably accurate sampling and analytical procedures to be followed. Thus, knowledge of the precious metals contents o f the intermediate mattes and slags may simply be unavailable."

Jan 1, 1990

By Richard J. Kolada, Ian R. Muirhead

"This paper reports on a CANMET-funded examination of less conventional underground coal mining methods. These methods are documented and those that show the most promise for application to western Canadian conditions are discussed in detail.IntroductionIn recent years, mining considerations and economics have encouraged a transition from underground mining to surface mining. However, a change in market conditions or the development of superior underground mining methods may reverse this trend . Should this happen, the industry must be quick to respond and have information available on the latest developments of underground mining technology. In time, deposits of high-quality coal, which are easily accessible to surface mining, will be depleted and a change to underground mining methods will require consideration. The economic transition point between surface to underground will be a major determinant in maintaining a competitive edge. For these reasons, it is important to keep abreast of improvements in underground mining methods. To meet this objective, CANMET awarded a research contract to Monenco Consultants Limited, to investigate unconventional underground mining methods that show a potential for western Canadaoi. This paper presents the results of this investigation."

Jan 1, 1988

By Michael L. Free, Zongliang Zhang, Joshua M. Werner

In the copper electrowinning process, short-circuiting between the anodes and the cathodes is a critical problem that changes the current allocation among local electrodes and reduces the current efficiency significantly. Possible reasons for the short-circuiting include the improper alignment of the electrode, bent electrode, and nodules on the cathode surface. In typical tankhouses, there is often a time between shorting and harvesting as well as between shorting and clearing. Therefore, it is inevitable to have short-circuiting affect the operation performance in practical electrowinning operations. However, one key piece of missing data is the actual measurements of the current efficiency as short-circuiting is approached and allowed to continue. Consequently, short-circuiting tests that allow tracking of electrowinning parameters before and after short-circuiting were performed in a laboratory scale Cu electrowinning cell. In the tests, the electrode spacing change, the mass of electrodeposited Cu, the deposition morphology, and the current allocation as well as the current efficiency before and after short-circuiting were studied. Results show that the short- circuiting affects the current allocation and the current efficiency significantly. Moreover, it changes the Cu deposition on the short-circuited cathode and therefore causes problems for Cu electrowinning. INTRODUCTION Electrowinning (EW) is commonly used for copper production around the world, with a rated production from 120,000 to 200,000 tons per year per operation (Wiechmann, Aqueveque, Henríquez, Muñoz, & Morales, 2014). In Cu electrowinning, Cu ions in the electrolyte are reduced on the cathode surface as metallic copper with a DC current, while on the anode, a counter anodic reaction occurs with oxygen gas generation (Werner, Zeng, Free, Zhang, & Cho, 2018; Zhang, Werner, & Free, 2018; Zhang, Werner, & Free, 2018). In copper electrowinning, an average current density of 200 to 400 A/m2 is applied to the electrowinning cell (Wiechmann et al., 2014). As the Cu deposits on the cathode, the distance between anode and cathode reduces and most of the time, short-circuiting forms between some anodes and cathodes in a large tankhouse containing thousands of electrodes, reducing the current efficiency and increasing the energy consumption significantly. The current efficiency in well-run copper EW operations is typically above 90 %. Most of the unused current is wasted through short circuits, stray currents, and by-byproduct formation (Davenport, King, Schlesinger, & Biswas, 2002; Wiechmann, Vidal, Pagliero, & Gonzalez, 2002; Wiechmann, Morales, & Aqueveque, 2010). Usually, in the tankhouse, the short-circuiting increases the current in the involved cathode by up to 1500 A (Wiechmann et al., 2010). Multiple reasons can cause the short-circuiting in the cell, and the most common reasons include the uneven current distribution among cathodes, tilted electrodes, bent electrodes, and nodules formed due to the large deposition roughness. Recognition of this challenge in the Cu electrowinning process has led researchers to perform many investigations on approaches to avoid and reduce the short-circuiting in the cell. A series of research investigations have been conducted to develop and improve a new type of intercell bar for Cu electrowinning (Wiechmann et al., 2002; Wiechmann, Morales, Aqueveque, & Burgos, 2007; Wiechmann, Morales, & Aqueveque, 2009; Wiechmann et al., 2010; Wiechmann et al., 2014). The associated test results show that this new design limits the occurrence and magnitude of short circuits and allows operation at higher current densities. Sandoval, Clayton, Dominguez, Unger, and Robinson (2010) stated several keys to control short circuits, such as maintaining the straightness of the cathode, removing “edge hair” from the cathode starter, and maintaining electrode alignment in the cell. Prengaman and Siegmund (1999) from RSR technologies developed a new Pb-Ca-Sn anode to prevent the anode deformation, thereby reducing the short-circuiting in the Cu electrowinning cell. Although the negative effects of short-circuiting on the Cu electrowinning have been recognized, and various investigations have been conducted to address this issue, the actual measurements of the electrowinning behavior and performance as short-circuiting is approached and allowed to continue are seldom reported. However, in typical tankhouses, there is a time between when shorting occurs and harvesting/clearing are performed. One key factor in determining the harvest time is the frequency of shorting. Consequently, we have performed short-circuiting tests that allow us to track electrowinning parameters before and after short-circuiting.

Jan 1, 2019