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By G. T. Lapidus, R. Zárate-Gutiérrez

Selective leaching of lead from a Pb-Ag-Zn concentrate with hydrogen peroxide in citrate solutions was studied at room temperature. Leaching tests were performed, varying the H2O2 concentration and the solid-liquid ratio, holding the solution pH constant at 7, and the citrate concentration at 1 M. Lead extractions of 100 % were achieved with 4 and 5 times the stoichiometric quantity needed to form elemental sulfur, with only a small amount of metal impurities dissolved (Ag, Zn and Fe). The lead solubility limit at those conditions was found to be ~21 g L-1. X-ray diffraction analyses of the leach residues were free of galena (PbS), while other metal sulfides, such as sphalerite (ZnS), chalcopyrite (CuFeS2) and pyrite (FeS2), were basically unaffected.

Jan 1, 2014

High Pressure Grinding Rolls (HPGR) are said to be a good option in new grinding circuits. Due to their low energy consumption compared to other grinding systems such as SAG milling, there is a strong incentive to check their behaviour for certain ore types. With rising energy prices the operation will become even more beneficial in future. As published in the past, the HPGR is claimed to increase the liberation of the valuable mineral component within an ore. An investigation at the research centre of Polysius was conducted to substantiate the liberation behaviour in finish grinding operations. A pilot scale HPGR test unit (POLYCOM MAGRO) with a roll diameter of 950 mm and processing capacity of 80 t/h was used. Grinding tests were completed with a screen and a two stage drying air separation process (SEPOL). Analysis included standard screen analysis, fractional XRF and modern MLA technology. A technique was developed to oppose the amount of produced slimes (resuming bad flotation) against the positive effect of producing high mass fraction at flotation-easy sizes. The paper shows how effective the use of a dry grinding separation could be in terms of production of mass of liberated metal.

Jan 1, 2012

By Wm. F. Wuest

INTRODUCTION THE Western Canada sedimentary basin has one feature in common with the Precambrian Shield area: it also was a great chemical laboratory. The mining industry of Canada exploits the end products of chemical experiments that occurred on the Shield during periods of repeated disturbances in Precambrian times. The petroleum industry on the other band exploits what also appears to be the final results of chemical experiments that took place throughout all of post-Precambrian up to Tertiary times. Since the subject of this paper is a factual study of Alberta well waters, no attempt is made to answer significant questions pertaining to the probable role waters play in the generation of oil, or to the significance of the effects of structure and depth on waters. Data from several hundred well-water analyses were compiled by the writer in a series of charts and diagrams, of which those included in this paper are representative. Early studies indicated the possibility that outstanding anomalies in general concentration of waters and in greatly increased concentration of elements such as calcium, magnesium, bromine, and iodine for example, might be expected from wells that produced oil or were in the immediate vicinity of producers. The water analyses from wells which? were drilled at a later date did not confirm this possibility, and it is suggested that, aside from their initial value to the petroleum engineer or to. those interested in the commercial possibilities of brines, no definite significance as an aid in oil discovery can be attributed to water analyses.

Jan 1, 1951

By J. M. Hollicky

The economical processing of wet and sour natural gas presents a problem due to the seasonal demand for natural gas. The plants must be sized to handle the peak loads but may only operate at half capacity on the average, in which case the sales value of sulphur and hydro-carbon liquid by-products cannot support the operating and capital costs of the plant. This must result in an increased price for the gas. This problem was solved by Pacific Petroleums and Westcoast Transmission in the design of their pipeline and plant facilities now operating in the Peace River area, where there are both wet and dry gas fields. By .building a plant to process sufficient wet gas to pro-vide the base load requirement, and by drawing on the dry gas fields for peak loads, an optimum economic operation was ?possible. The sulphur, L.P.G., and gasoline produced not only are able to support the operating and capital costs of the pro-cessing plant, but were instrumental in the sharp drop in retail prices of these commodities in the area. The sour gas and condensate is gathered from the fields in the area and transmitted in a two-phase gathering system to the gas processing plant at Taylor, B.C. The condenrnte is knocked out in inlet scrubbers. Hydrogen sulphide and carbon dioxide are removed in an amine scrubbing unit. The hydrogen sulphide is stripped from the amine and is sent to the Jefferson Lake Sulphur Company's plant which produces sulphur by the partial oxidation of the hydrogen sulphide. The natural gas, now sweet, is processed in an absorption unit to recover additional liquids, before being de-hydrated to remove water. It is then sent to Westcoast's main c8mpression station. The condensate recovered in the inlet scrubbers and the liquid re-covered in the absorption unit are fractionated to remove fuel gas, used in the plant, and to produce pro-pane, butane, and naphtha. The pro-pane and butane are scrubbed with caustic soda to remove hydrogen sulphide. The naphtha is treated with hydrogen in a unifiner unit to re-move sulphur compounds completely, and is split into a light and heavy naphtha. The heavy naphtha is .catalytically reformed to produce a high-octane blending-component. These fractions are blended with components produced from crude oil at the Dawson Creek refinery to produce a high-quality balanced gasoline with special attention being paid to volatility for ease of starting, warm up, and engine cleanliness, and octane for power and ?performance.

Jan 1, 1958

By J. B. Boniwell

The INPUT electromagnetic prospecting system was originally developed by Dr. A. R. Barringer in an effort to increase the sensitivity and penetration of airborne EM methods. Although brought to an operational state some several years ago, it is only through relatively re-cent modifications and testing that some of the potential of the system has been fully realised. This is brought into perspective by some recent results over known ore deposits and geologic environments.

Jan 1, 1967

By A. Klingberg, M. Svensson, N. Smolko Schwarzmayr

"Removal of silicates and carbonates from sedimentary phosphate ores by the use of new synthetic collector/formulations was investigated in a comparative study with traditionally used collector systems as references. In the direct carbonate flotation the new formulations showed higher efficiency, contributed to an improved balance of P2O5 recovery and P2O5 enrichment in the recovered material. Efficiency of the new formulations containing synthetic surfactants was 1.5–2 times better than potassium salt of fatty acid sulfonate based formulations that are traditionally used for that purpose. The new formulations also provided up to 7% increase in P2O5 recovery at the same P2O5 grade. The new synthetic collectors for removal of silicates showed extremely good selectivity towards silica bearing minerals. The selectivity factor for the flotation tests when new formulations were used was 32–52 and for the flotation tests with the traditional collectors: 20–32. The ratio between distribution of an amount of silicates (as SiO2) and distribution of phosphate in the froth (waste) is defined as the selectivity factor. The new formulations provided more than 2% decrease of the amount of SiO2 at the same P2O5 recovery.INTRODUCTIONPopulation growth and decrease of arable land are the main reasons for constant increase of consumption of apatite (phosphate ore) in the fertilization field (Lannefors, Gorochovceva, Klingberg, Lima, & Gustafsson, 2015). Fertilizers play a key role for farmers to produce more with less land. The phosphate component of the fertilizer is vital for producing healthy and large amount of crop. As a result the demand for phosphate rock is growing.The largest producers of phosphate rock are the Unites States, Morocco, Tunisia, China, Russia, and Brazil. The term “phosphate ore” includes all phosphate-bearing minerals and rocks, but only two of them are of industrial interest: apatite (igneous origin) and sedimentary phosphate (Peres, Araujo, El-Shall, Zhang, & Abdel-Khalek, 2007). The majority of the world’s phosphate deposits are of the sedimentary type. There are two different types of sedimentary phosphates: siliceous and carbonaceous which are categorized based on gangue minerals (such as quartz, carbonates, mica, and clay)."

Jan 1, 2016

By F. K. McKean

THE task of establishing a new corrosion testing laboratory is more difficult than it need be because there is very little information on the subject available in the literature. Many articles describing tests and results may be found, but a wide search will unearth only passing remarks on the different types of equipment that may be selected for accelerated corrosion tests. An article describing some of the apparatus needed in a corrosion laboratory should be of help to those interested in building a new unit or in making additions to an old one. In May of this year, the writer was given the assignment of equipping a laboratory for general corrosion testing, to form a part of the new Physical Metallurgy Research Laboratories of the Department of Mines and Resource~ at Ottawa. With the help of senior members of the staff, along with what could be gathered from other sources, a list of necessary equipment was compiled and a plan for arranging it in the rooms was decided upon. Where possible, the apparatus was constructed in the excellent machine shops at the disposal of this Department, while the rest was placed on order with the manufacturers.

Jan 1, 1945

By A. Musschoot

"The paper will review general types and designs of vibratory feeders, describing briefly the design features and characteristics that apply to the application of specific types. Control considerations for selecting types will be dis• cussed, such as fixed or adjustable, manual or automatic, individual or multiple bank, and process requirements. Design parameters for hopper openings and installation geometry will be discussed, including consideration of material size distribution, segregation, moisture content and other characteristics, based on practical applications and experience as well as theory. Pan designs and the selection of pan materials will also be discussed with reference to wear, corrosion, impact and practical economic factors."

Jan 1, 1972

By A. E. Cameron

The theory of atomic distribution of the stranger atoms in the space lattice of the solvent metal has been well developed by Rosenhain. It has long been known that the addition of one metal to another to form a solid solution increases the strength and hardness of the solvent metal. This increase is practically proportional to the amount of added substance up to the limit of solid solubility. To account for this increase in hardness and strength, Rosenhain assumes that the stranger atoms occupy positions on the solvent metal space lattice. Atomic attractions about the stranger atoms will not be the same as in the case of the pure metal, and there will thus be a disturbance of the orderly arrangement of the atoms on the space lattice, or a distortion of the lattice. Such a disturbance would interfere with the ease of slip along the planes and would thus tend to promote strength and hardness. Rosenhain notes that not only may there be a local disturbance of the lattice about the stranger atom but there may well be also a measurable change in the dimensions of the lattice as a whole. The relative amounts of local and general distortion of the lattice will depend upon the nature of the lattice itself. As Rosenhain says, "If the lattice is comparatively soft and flexible the distortion is likely to be largely local. In a stiff lattice, however, local distortion will be resisted and there will be a correspondingly increased general distortion."

Jan 1, 1927

By G H. Reavely, The University of Western Ontario Department of Geology

The lower Middle Devonian Sylvania Sandstone occurs in the sub-surface in the western part of Mal-den township, Essex county, Ontario. The formation is composed of well rounded, frosted quartz grains with a silica content varying from 42 to 93 per cent and the grains are cemented by carbonate, constituting up to 57 per cent of the rock. This sand-stone is not a homogeneous bed but is divided by strata rich in carbon-ate cement. The thickness of the Sylvania in Malden township varies up to a known maximum thickness of 88 feet. The lower contact with the chert-bearing Bois Blanc formation is sharp but the upper contact with the Amherstburg formation (Detroit River group) exists as a transition by a gradual downward increase in quartz grains. The Sylvania would seem to outcrop in the lake bottom near the mouth of the Detroit River dipping to the north along a broad anticline the axis of which follows the Detroit River. Just south of Amherstburg, a local east-west trending

Jan 1, 1961

By J. G. Stevens, S. W. Colley

"Selective separations of metals and ions in mineral extraction and refining are becoming more challenging as ore bodies become more complex and environmental pressures increase. The separation and containment of mercury produced in gold mining are a factor in the profitability and operability of mines. This paper will discuss the development and implementation of the Johnson Matthey HgFree selective mercury removal process. The process is designed to selectively recover co-leached mercury from either heap leach pregnant solutions at ambient temperature and low mercury concentrations, or electrowinning pregnant solutions at elevated temperature and high mercury concentration, without affecting gold or silver recovery. The process utilizes a highly selective adsorption-desorption step in which mercury is removed quantitatively by the HgFree adsorbent without adsorption of gold, silver or other metals present. Development of the original HgFree adsorbent has resulted in a process whereby mercury can be recovered as an inert salt and is never present as the free metal. The HgFree adsorbent can be regenerated and recycled in situ, and is capable of being reused multiple times. The overall process is compatible with existing gold mining and recovery practices and offers significant environmental and sustainability benefits, including reduction or elimination of the need to retort mercury with a subsequent reduction in potential mercury air emissions. Development of the HgFree adsorbent and process will be discussed along with a pilot operation at two operating mines.INTRODUCTIONMany gold ore bodies contain high concentrations of mercury which when extracted with cyanide, co-extract with the gold and other metals. This mercury is carried through the process with the gold, posing environmental and technical issues when it is separated from the doré. This paper describes a method to selectively adsorb mercury from the gold recovery circuit while it is in a soluble form, leaving gold to be processed as normal. The removal of mercury from the circuit eliminates the need for mercury retorting of doré and so reduces the potential environmental impact of fugitive emissions of elemental mercury."

Jan 1, 2016

By Minghui Li

China is the largest coal producer in the world. In 2012, the coal production in China is 3.65billion tonnes, accounting for approximately 49% of global coal production. The raw coal production in 2012 was 3.8% more than the year 2011. 56% of total raw coal has been washed. The increase in raw coal production also promotes technology to be developed and brings separation capacity become larger and larger in coal processing in China. At present, over 40 extra-large scale coal preparation plants (each plant has capacity of more than 10 Mtpa) are in operation in China, the largest one is 32.5 Mtpa. Heavy medium separation are widely used in new built coal preparation, the washing limit for thermal coal feed lower and lower, the equipment selection tends larger which brings the whole washing system simplified, the local equipment developed and manufactured are more and more used. By discussing designs of several typical thermal coal preparation plants and coking coal preparation plants in China, this thesis introduces the current design of China?s extra-large coal preparation plants, and sums up the prevailing design features and trends of extra-large coal preparation plants.

Aug 1, 2013

By D. Sharma, A. K. Singh, R. Singh, P. K. Mandal, M. Sarkar

"This paper deals with the stability investigations carried out at the XIVth seam of Jitpur colliery. The study was conducted to investigate the possible causes of roof cavity formation and face spalling at the middle slice face of block-3 longwall panel and to suggest remedial measures. The instrumentation and monitoring work was carried out in the panel over a period of nine months. On the basis of observations, it was found that if the maximum face span was reduced from the existing 4.8 m to 3.6 m, and if the face time schedule cycle was reduced from a maximum of 37 days to about 18 days, this problem could be eliminated. The recommendations of CMRI have been implemented in the middle slice face of block-4 panel with success. IntroductionModerate to steeply dipping, undisturbed seams of uniform thickness are worked by way of inclined slicing parallel to walls. In this method, the seams are treated as a combination of several moderately thick seams dipping parallel to roof and floor. Numerous variations of multislice mining have been used worldwide to get high coal recovery under local conditions of geology, subsidence control, proness to spontaneous combustion, statutes and economics. Multislice mining can proceed either downward descending from the roof or upward ascending from the floor. Ascending methods require backfill behind the working face to provide a base for the next slice. It is also adopted for surface protection against subsidence or mining under a massive roof. This paper presents a scientific study conducted in Jitpur colliery, IISCO where a 9 m thick seam is mined in three slices in ascending order with stowing."

Jan 1, 2002

By Oakley B. Gwillam

The study of leached outcrops as an aid in determining the character of mineralization beneath the surface is in its infancy. Practically all the work on this subject up to the present has been applied to the 'porphyry' copper deposits of the southwestern United States. Some work has been done also on the zinc-lead solid sulphide deposits of the western United States. The question has been asked, "Can this study be applied, and would it have any practical application, in northern Manitoba?" When one realizes the size of the unprospected territory in this Province and the consequent need for a cheap and rapid method of interpreting the countless outcrops which occur in order to discriminate between valueless iron sulphides and valuable sulphides of the base metals, it is readily seen that the study is of great value if it can be applied with a reasonable degree of surety. Augustus Locke, well known economic geologist of the southwestern United States and a pioneer in the study of leached outcrops of disseminated copper ore, has written much on the subject. Messrs. Blanchard and Boswell in a series of articles have dealt with the leached outcrops derived from lead and zinc sulphides in the western United States. Since this paper is essentially a comparison between the leached outcrops of the southwestern United States and those of northern Manitoba with the purpose of testing the adaptability of the study in this Province, an outline of the criteria used in the southwest will be of value to the reader.

Jan 1, 1930

By C. Allen

In 2004, Boliden Odda underwent an extensive modernisation project targeting mainly the leaching section of the plant. Direct leach technology was introduced as part of this project. The Direct Leach process, developed by Outokumpu, is an atmospheric oxidative leach of zinc sulphide concentrate. The effects of this new processing operation on behaviour of iron in the plant are discussed. As well, the filterability of the new residue on belt filters prior to its deposition in mountain caverns is also discussed. The solids from the direct leach process have been analysed by scanning electron microscopy, and the results of these analyses are presented.

Jan 1, 2006

By T. E. Warren, K. W. Bowles

"IntroductionTHE PROBLEM of producing synthetic liquid fuels from coal and other raw materials is of increasing importance in Canada as well as in the United States. This is due, to a large extent, to the continually increasing demand for gasoline and other liquid products which are now obtained solely from petroleum. The United States has reached a position where domestic supplies of crude petroleum must be augmented by imports and Canada is still a long way from self-sufficiency. In the event of war, there might well be an immediate need to find supplementary sources of liquid fuels. It is, therefore, expedient to consider alternative sources of production now -well in advance of the time when supplies of petroleum may prove inadequate to meet requirements.The purpose of the present paper is to give a short review of the history of liquid fuel production from coal, to describe briefly the research sponsored by the Federal Government on the coal hydrogenation process, and finally to evaluate the present status and future trend of the synthetic fuel industry, with special reference to necessary research work.History of the Oil-From-Coal IndustryThe history -of coal liquefaction began in 1913, in Germany, with the work of Frederick Bergius. His first approach to the subject was not deliberately planned."

Jan 1, 1952

By G. Avramovic-Cingara

Grain boundary characteristics and microstructural evolution are analyzed in a comparative study using orientation imaging microscopy (OIM/SEM) and transmission electron microscopy (TEM/SAD). The subgrain sizes and misorientations were determined by the OIM for aluminum deformed in torsion to equivalent strains between 0.2 and 4 over the temperature ranges of300-600°C and strain rates 0.01-1 s". The OIM gives clearer evidence of boundaries with high misorientation than does TEM, but it overestimates their frequency b y missing boundaries less than 1 0. T EM more clearly reveals low-angle arrays of widely spaced dislocations resulting in finer subgrain sizes than those indicated by OIM. The evidence supports a mechanism combining dynamic recovery (DRY), deformation band formation with permanent boundaries and geometric dynamic recrystallization (gDRX) in contrast to the hypothesis known as continuous dynamic recrystallization (cDRX).

Jan 1, 2004

By S. Steinlechner, S. Wegscheider

"In the past, the metallurgical industry was most of the time dedicated on their main commodity, recovering base metals like zinc, copper or lead but leaving other valuable side elements in the generated residues. As a result, these accompanying minor elements, like gold, silver, indium or also PGMs can be found in the dumps of the corresponding industry. Because of political unrest, strikes, economic reasons or decreasing primary resources leading to a high supply risk, also those mentioned minor elements moved into the focus of the recycling industry. Therefore, beside the base metals, first of all the recovery of those minor metals would be of high interest contributing to the economic viability of recycling processes, although they occur in much smaller quantities in materials. In this context, residues from zinc industry, like leaching residues or precipitation residues show high potential to carry silver as well as indium next to lead and zinc. Therefore, the paper summarizes carried out thermochemical calculations investigating a possible recovery of silver as well as indium by volatilization and the influence of zinc and lead on this process. Based on these theoretical investigations with HSC, trials in lab scale were done verifying the obtained results.INTRODUCTIONHuge amounts of iron precipitate, mainly jarosite get landfilled every year although there is a high content of valuable metals in this residue beside iron. Nevertheless, jarosite has to be dumped due to the presence of contaminating heavy metals. The accumulation of these residues takes up massive land on the one hand but also causes a series of environmental problems in ecosystems on the other. Moreover, some toxic ingredients such as arsenic and cadmium can be dissolved in rain water and are therefore harmful to the health of the aquatic systems. (Erdem & Özverdi, 2011; ÖzverdI & Erdem, 2010) Approximately 0.5 t of dry jarosite accumulate in the production of 1 t of zinc by the hydrometallurgical zinc-winning route (Svens, 2010). Jarosite is a precipitation residue formed during the iron removal. In general, the iron already exists in the zinc ore which is why zinc ferrite builds up during the roasting step of the zinc ore. Zinc ferrite is only soluble in strongly acidic solutions and during the hot acid leaching step it gets dissolved while zinc and iron enter the solution. It is necessary to get rid of the iron because otherwise it would deposit on the cathode first due to its precious character which would be harmful in the zinc-winning electrolysis. Nevertheless successful investigations were done by adding chlorine to the jarosite to recover silver. These findings leads to another residue which occurs in huge amounts – electric arc furnace dust (abbreviated with EAFD) from the iron and steel industry. In 2013 the annual electric steel production reached about 451 million tons. Around 15-20 kg of EAFD is produced per ton of steel in an electric arc furnace (EAF), creating approximately up to 9 million tons of dust per year. (Grabda, Oleszek, Shibata, & Nakamura, 2014; World Steel Association) Next to elements like zinc, lead and iron, chlorine and fluorine are present in this dust. While galvanized steel plates in the scrap act as a source for zinc, casting powders, flame retardants and synthetic coatings are responsible for the chlorine and fluorine contents in the dust."

Jan 1, 2016

By V. Bondarenko

The importance and necessity of gas hydrates deposits development followed by natural gas extraction is considered in the present paper. Analysis is given to world sources focused on methane hydrates formation conditions. Information covering the most perspective gas hydrate deposit of the Black Sea is presented in the article. Two most common methods of gas hydrates development ? thermo stimulation and inhibitor injection are analyzed presenting their comparative characteristics. Basic scientific trends and developments of underground mining department in the field of gas methane extraction from gas hydrates are scrutinized. Schemes and methods of natural gas hydrates development are shown together with formulas, parameters and factors influencing the extraction process. Also the analysis is given to the possibility of gas hydrates formation from methane-air mixtures of degassing wells from coal mines of Ukraine. Improved experimental unit for gas hydrates formation under laboratorial conditions is presented with its basic characteristics. General conclusions and basic tasks requiring further research are given in the end.

Aug 1, 2013

By L. Dorador

"In block caving projects, the rock mass fragmentation process plays a controlling role in the design and success of the operation. Poorly understood, however, is the secondary fragmentation that occurs as blocks of caved ore move through the draw column and interact with one another. The initial size of these blocks can be considerable, as can their strength and stiffness as the presence of non-persistent joints and veining will be variable. Intuitively, more planes of weakness within the blocks should facilitate early fragmentation, but this assumption could depend on additional factors such as contact type between adjacent blocks and loads imposed through varying heights of the draw column. This paper reports the findings from a laboratory investigation examining the role of block strength and planes of weakness on secondary fragmentation. Testing was carried out on small-scale concrete cubes of uniform size, with and without embedded planes of weakness. The results obtained demonstrate the significance of veining and other planes of weakness on secondary fragmentation under one-dimensional compression, and allow for the development and constraint of empirical guidelines.INTRODUCTIONThe fragmentation process during block caving involves the initial (primary) fragmentation of rock in the cave back through stress-induced fracturing, release and fall of individual blocks onto the broken ore muck pile. This is followed by secondary fragmentation involving splitting and rounding of blocks as they move downwards through the draw column towards the draw point. The degree of secondary fragmentation achieved involves many variables related to the mechanical properties of the rock blocks as well as different operational factors. With respect to the block properties, the presence of planes of weakness in the form of veining and non-persistent joints is a topic of special interest given the significant influence it potentially has on the overall fragmentation process. However, the inherent heterogeneity and variable size of individual blocks generated from the cave back makes it difficult to develop any empirical relationships relating secondary fragmentation to compressive loading based on insitu observations and mine data. More preferable would be to keep constant block parameters, such as shape (aspect ratio and angularity) and size, through controlled laboratory testing. This work presents an efficient technique to fabricate concrete cubes in order to keep constant different block properties. These are then tested under one-dimensional compressive loading. The objective of these tests is to emulate a tight packing condition of single blocks such as that which would occur when the air gap between the cave back and broken ore in the draw column is small. When the air gap is small, detached blocks are unable to fall and rotate but instead maintain a very tidy arrangement with minimal voids left between adjacent blocks."

Jan 1, 2015