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By A. Zaidi

"The mining and metallurgy industry is highly energy intensive and one of the largest energy users in Canada. Energy costs are also a major component of total production costs in this industry as described in the 1990 Report of The Canadian Industry Program for Energy Conservation (CIPEC). For some plants, energy costs are reported to be up to 30% of total production costs. Therefore, a reduction in energy costs provides an opportunity to improve industry profitability. The specific energy intensity and production costs can be reduced by using modem energy efficient natural gas technologies. In addition, these technologies often improve product quality and increase productivity. Natural gas not only offers economic benefits, but is also environmentally benign as compared to other major energy sources. Emissions of NO"", CO2 particulates and SO2 are lower with natural gas than other fossil fuels.This paper provides a brief overview of some state-of-the-art gas technologies for the mining and metallurgy industry including cogeneration, oxy-air-fuel burners, ceramic immersion tube heaters, direct gas contact process, low NOx burners, and energy efficient liquid heating systems.CogenerationCogeneration is defined as the simultaneous production of electricity or mechanical power and useful process heat from a single fuel source. One of the primary considerations in selecting a cogeneration system is the relative quantities of electrical and thermal energy which are to be produced. Two types of systems are discussed below."

Jan 1, 1993

By T. Plikas, T. Porretta, M. Al-Dojayli, B. Pretorius, J. Woloshyn, H. Ghorbani

"Water-cooled ducts represent an integral part of high temperature off-gas systems in metallurgical processes. Typically, off-gas enters these ducts at significantly elevated temperatures; therefore, water cooling may be required to maintain the duct skin temperature within allowable design limits. These off-gases are typically of high mineral content that could lead to dust buildup, and there is a possibility of slag buildup / molten metal splashing. Therefore, dust cleaning provisions may be necessary in order to remove or minimize accretion on the duct wall, which could otherwise impact the water cooling and the system process efficiency. These ducts may have complex geometry and experience a wide range of loading, including gravity loads, water and gas pressures, cyclic thermal loading and dynamic impact forces. Consequently, the thermo-mechanical assessment of such water-cooled ducts is critical and requires consideration phenomena such as high temperature gradients, potential nucleate boiling, thermal ratcheting and fatigue failures. Such assessment is not comprehensively covered by design-by-rule design codes and guidelines due to its complexity. This paper presents a successful implementation example of design-by-analysis methodology to improve the design and extend the life of a water-cooled furnace transition duct using Computational Fluid Dynamics (CFD) and Finite Element Analysis (FEA).INTRODUCTION Water-cooling represents an important part of high temperature off-gas systems in metallurgical processes. Typical temperatures of the off-gas in the furnace uptake are in excess of 1400°C, and thus there is a need to maintain the water-cooled duct and jacket skin temperatures within their material allowable design limits. Water-cooled channels have been used effectively in arc furnace roof design (Sosonkin et al., 1972; Smolyarenko and Khainson, 1988) and other furnaces as well as in furnace fuming jackets (Scholey et al., 1994). The design of these systems was based on one-dimensional analysis to ensure sufficient cooling is available under extreme furnace conditions (Smolyarenko and Khainson, 1988; Scholey et al., 1994). With advancement in furnace and fuming system designs, water-cooled duct designs have become more complicated in geometry. Numerical techniques, such as three-dimensional fluid flow and heat transfer modeling, are therefore needed to more accurately calculate water velocity, temperature and convective heat transfer coefficients in the water-cooled channels (Haywood et al., 2002; Henning et al., 2010). This is of particular importance around geometric corners where stagnant water flow may lead to local nucleate boiling at the critical heat flux, causing hot spots (Bergman et al., 2011). High wall skin temperatures increase the risk of failures due to thermal stresses as well as increasing corrosion rates (Gelfi et al., 2012), leading to costly equipment downtime and potential safety risks."

Jan 1, 2017

By L. K. Sinclair

In situ leaching of copper has the potential to deliver low-cost recovery for soluble copper deposits of sufficient permeability. In order to provide key inputs for modeling of the in situ leaching process, bench scale test work can be used in conjunction with geochemical software to identify key leaching and precipitation reactions. A case study is presented in which a series of flow-through acid leaching tests were conducted on drill core sections from a porphyry copper deposit without crushing or grinding. Concentrations of copper and other key elements were monitored in the recirculating leach solution over several months. A geochemical model of each leaching test was prepared using Geochemist's Workbench using a combination of diffusion-controlled and reaction-controlled rate mechanisms. Key reactions included leaching of chrysocolla, iron oxides, and plagioclase. The model was able to simultaneously satisfy the evolving chemistry of the recirculating leach solution, mineralogy of the head and leach residue, measured acid consumption, and leaching rates for key minerals reported from previous laboratory studies. Opportunities and limitations for scaling up the model to simulate the commercial wellfield are discussed.

Jan 1, 2015

By W. D. Haley

The report of the Forestry Committee, presented to the recent Imperial Conference at London, is discouraging in its view of the future of timber resources and supplies. From a review of the forestry situation throughout the world, there is every likelihood that, thirty years from this, a shortage of the soft-woods will be severely felt. In the United States, only about one-third of the present forest area contains virgin timber. This will be cleared at the rate of five and a half million acres a year, so that in twenty-five years it will be about all gone. Canada has only about 27 per cent of her original forests left, and her virgin soft-wood will last but another half century. At the present time, the value of her lumber products is over $300,000,000 annually. During the summers of 1909 and 1910, the Government of Nova Scotia caused an examination to be made of the forest conditions in this Province. The reconnaissance, which was under the direction of Professor B. E. Fernow, of Toronto, involved an examination of the various soils, the rate of growth of the wood, and a general survey of the forest area. The importance to the Province of conserving its forest resources was clearly shown, and a number of recommendations were made, which; however, were never acted upon.

Jan 1, 1927

By A. J. Baer

"DEFINITION OF THE REGION AND ITS BOUNDARIESTHE EXPOSED PART OF THE GRENVILLE PROVINCE is the southeastern part of the Canadian Shield, characterized by crystalline rocks with K-Ar ages of about 1,000 million years. Its Canadian portion is bounded on the southwest by Georgian Bay •and by Paleozoic sediments south of a line passing through Orillia and Kingston, on the southeast by the St. Lawrence River valley and the north shore of the Gulf of the St. Lawrence, on the east by the coast of Labrador and on the northwest by the Grenville front, a linear tec-tonic feature that is a metamorphic transition zone and/or a fault. Rocks located to the southeast of the front have younger K-Ar radiom€tric ages than rocks located to the northwest of it.The region is formed of complexly deformed and highly metamorphosed crystalline rocks and in part differs from other areas of the Canadian Shield by the presence of large amounts of crystalline limestone and bodies of anorthosite."

Jan 1, 1970

By G. Deschenes

"This literature survey discusses the recovery of gold from thiourea solutions. An overview of techniques used and general comments on the basic cyanidation methods are presented. The chemistry and mechanisms of cementation, activated carbon, resins, electrowinning, solvent extraction and pressure reduction are examined. Conclusions and recommendations give orientation for future research and development activities in this field.RésuméCette revue littéraire traite de la récupération de I ‘or des solutions de thiourée. Elle fait un survol de I ‘ensemble des techniques utilisées tout en introduisant des commentaires généraux sur la méthode classique qu'est la cyanuration. La cémentation, Ie charbon active, les résines, l'électroextraction, I ‘extraction par solvant et la réduction sous pression sont les méthodes analysées tout en considérant leur caractère chimique respectif ainsi que les mécanismes qui y sont rattaches. Des conclusions sont tirées et différentes recommandations sont suggérées pour orienter la recherche dans ce domaine."

Jan 1, 1986

By Lauri Pesonen

"Although electrical energy use at copper smelters is typically about 15-20% of operational costs, it is something which is not very often analyzed and discussed at a detail level in technical papers and presentations. This paper aims to list different equipment configurations per smelter area and estimate their electrical energy consumptions versus unit of material processed. In addition chosen smelting technology and oxygen enrichment rates affect the overall electricity consumption and therefore some overall guidance is provided for efficiency gains.INTRODUCTION In principle, processing plants, such as copper smelters, require electrical and chemical energy together with some degree of human input to process input materials into desirable output form like metallic copper. From the standpoint of metallurgical plant designers, the thermodynamics of smelting, when it comes to releasing and conserving thermal energy, is sufficiently understood and frequently discussed in the literature in detail, but judging from the quantity of publications, the way how we exactly utilize electrical energy is not. This article is meant to illustrate how electrical energy consumption is distributed among different process units and equipment types at copper smelters using various smelting technologies. In general, typically about 15-20% of operational costs are related to electricity and at locations with high electricity prices the potential savings can be quite significant for the overall profitability of the plant operations. In today’s tight profit margin environment any potential savings are more than welcome. The purpose here is not to promote any certain copper smelting technology, but to open a discussion on how and where we use electrical energy, and how the overall energy use could be lowered with the implementation of newest electric power saving designs and solutions. Using the principles outlined in this article, it should be fairly easy and straightforward to replicate the calculations and even improve them wherever it is seen necessary for the greater benefit for us all in this industry"

Jan 1, 2017

By Binbin Luo, Northeastern University, Chuanyao Sun, Jie Liu, Yimin Zhu, Yanjun Li

"A series of new type collectors a-bromo-saturated fatty acids, CH3(CH2)5CHBrCOOH (a-BHA), CH3(CH2)7CHBrCOOH (a-BDA), CH3(CH2)9CHBrCOOH (a-BLA), CH3(CH2)11CHBrCOOH (a-BMA) were synthesized from saturated fatty acids and bromine by solvent-free method (Hell-Volhard-Zelinski reaction) in laboratory. The micro-flotation tests of quartz mineral were conducted at a relatively low temperature of 15 °C. The adsorption mechanism of such collectors on quartz mineral surface were established by zeta potential measurements, in conjunction with the results of quartz micro-flotation tests. The flotation results showed that the collecting ability is in the order of a-BMA > a-BLA > a-BDA > a-BHA for the flotation of quartz mineral, which also demonstrating that the a-bromo-saturated fatty acids (a-BFAs) are new selective collectors for reverse flotation to remove quartz mineral from iron ores at a relatively low temperature.INTRODUCTIONThe requirement of higher pulp temperature to maintain the activity of fatty acid anionic collectors which have been widely applied in technological process of iron ores reverse flotation lead to a great deal of energy consumption.The purpose of this paper is to synthesize a new modified collector with carbon chains from eight to fourteen atoms, with strong electronegativity bromine atom introduced into a-carbon position to improve the activity and solubility of the reagent so that it can be adopted at a comparatively low pulp temperature. The collecting performances of these new collectors on quartz surface were studied, and the structure - properties were discussed in light of zeta potential measurements and quantum chemistry calculations."

Jan 1, 2016

By J. H. Morrish

"The delivered price of any mineral is the determining factor in converting untapped resources into economic resources. Transporting the minerals from the mine to the market plays a significant part in the total package. The expansion of the Western minerals industry in the last ten years has been paralleled by improved transportation systems to reduce cost, increase accessibility of resources and get the minerals to market in the shortest time possible. A review is made of developments, such as unit trains, complex multi-modal systems and containerized transport, over the last ten years, with specific movement outlined. The total transportation package of land transport, port and terminal facilities, and water transport, where needed, is stressed. As the volume of minerals movement expands, increasingly sophisticated and integrated transportation systems will have to be utilized. The development of solids pipelines and other possibilities is outlined."

Jan 1, 1973

By G. Shore

Radiation grafted structures my be fabricated to contain ion exchange groups selective to an ion complex. Proper choice of substrate and monomer will provide selective ion exchange with differing physico and chemical properties. Grafting a selected monomer to the proper polymer will provide selective ion exchange with assured chemical protection of the substrate. Ion exchange systems utilizing radiation grafted structures have been fabricated to ''capture'' gold, silver and palladium from dilute solutions. Other ion exchange systems can feasibly be produced to remove other precious metals. Rotating Cathode Technology is used to recover the metals from their regenerating solutions are pure metal foil.

Jan 1, 1985

By K. Barbetti

"The carbon-in-pulp (CIP) process has been the dominant gold recovery process since the early 1980s. CIP has proven to be very adaptable for a wide range of ores and circuit configurations. The key performance indicator for CIP circuits is the minimisation of soluble gold losses to tailings, however, it is also important to operate the circuit efficiently (maximising gold loadings on carbon and minimising carbon inventory). Over the last 30 years the Curtin Gold Technology Group has studied CIP circuits as part of an on-going collaborative industry funded project (the AMIRA Gold Processing Technology Project). In the early years the project undertook basic research into understanding activated carbon, and its management in the circuit. More recently the development of process models and instrumentation has provided additional tools to assist operators. The results show that while most CIP circuits operate well, there are still significant opportunities for further cost savings, or additional revenue. This paper reviews the observations arising from this work, including key requirements for good carbon management, the results of benchmarking and industry surveys of carbon circuit over 20 years, the value of process modelling of CIP circuits to establish operating parameters, and the use of automated instrumentation to better optimise carbon control in the circuit.INTRODUCTION The introduction of activated carbon to recover gold from cyanide leach solutions in the last quarter of the 20th century was the most significant development in gold ore processing since the advent of cyanidation seventy years before. Replacing the Merrill–Crowe zinc cementation step with carbon-in-pulp (CIP) or carbon-in-leach (CIL) circuits provided a process that allowed the treatment of lower grade and problematic ores (e.g. high-clay ores), at lower capital and operating costs, and higher metal recoveries. The CIP circuit was first developed in the 1950s at the Carlton Mill, Cripple Creek, Colorado. All the components of the modern CIP process came to fruition at the Homestake Mine in South Dakota in 1973 (Fast, 1988). From the late 1970s onward a variation of CIP, carbon-in-leach (CIL) which combined the leach and adsorption stages, became the preferred circuit design in most parts of the word."

Jan 1, 2017

By D. L. Cluff

Ventilation Air Methane (VAM) is a high volume low concentration methane source. The capture or use of methane from VAM is challenging, which results in the routine discharge of methane into the atmosphere. Mitigating VAM has the benefits of providing an energy source and reducing the atmospheric Greenhouse Gas (GHG) burden. The GHG radiative forcing effect of methane is 17?23 times as potent as carbon dioxide on a 100-year time horizon. Thus, any reduction in atmospheric methane would be beneficial. The calorific value of methane is 55.5 MJ/Kg; therefore, a 100 m3/s flow with VAM concentrations from 0.1?1% can provide 3.8?38 MW of exploitable power. Strategies to mitigate VAM such as: Thermal Flow Reverse Reactors (TFRR), Catalytic Flow Reverse Reactors (CFRR), Lean Burn and Catalytic Gas Turbines, Biothermica Vamox®, Megtec VOCSIDIZER©, and Vamcat? are briefly reviewed. The review of VAM mitigation technologies reveals disadvantages such as the need to maintain a minimum internal heat capable of oxidizing the methane. This requirement uses all of the available methane up to the point of reaction sustainability and up to half at the highest methane concentration in VAM. Some systems may introduce a pressure drop to the ventilation system, which would impinge on the existing ventilation system design. These impediments necessitate the development of a more amenable technology. In the proposed system, gas turbines (GT), coupled to a combustion chamber with an external fuel supply, assist the combustion of the VAM. The combustion-chamber coupled system provides electricity, while the heat contained in the GT exhaust gases increases the temperature of the VAM, encouraging the development of a flame inside a combustion chamber. The flow from the combustion chamber streams through a primary air/fluid heat exchanger capable of producing steam of a high enough quality to generate electricity using conventional steam turbines. The residual heat after primary extraction, directed through other equipment, provides additional heat based products such as industrial scale dry air, chilling by an absorption chiller or hot water. The overall design of the system is scalable for low to high VAM flows or variations in concentrations and is capable of providing the company or community with heating, chilling, hot water, electricity or motive force as needed by the particular site or community. The Multi-generation system uses heat from three sources to provide clean efficient energy while mitigating the atmospheric emissions of methane. These sources are heat from the GT, often considered waste heat, heat from fuel injected into the igniters and heat from the VAM. The opportunity to collect carbon credits may improve the economics. In order to design a system with this capacity, a detailed analysis of the combustion characteristics of three separate flows is required. VAM is the main airflow, having the highest volumetric effect, while the GT exhaust and the additional fuel added to the hot exhaust flow of the gas turbine are lower flows, but have a higher velocity and temperature. The aim of the modeling undertaken in this work is to establish the combustion dynamics, degree of pre-heating required and the geometry essential to the design of combustion based VAM mitigation multi-generation systems.

Aug 1, 2013

By Guojun Wang, Zejun Chen, Wenchang Liu

Al/Mg/Ti laminated metal composite sheet (LMCS) can combine the merits of each of metal components, and obtain excellent performances. It incorporates the advantages of high strength, light weight, easy melt and atomization, and good space adaptability to substitute for the bumper Al sheet of Whipple shield structure for space debris shield. The Al/Mg/Ti LMCS was fabricated by hot roll bonding technology in a certain sequence. The manufacturing process and parameters were analyzed and studied, including the first rolling reduction, roll boding temperature and stacking structure of each metal. The microstructure of dissimilar metals and bonding interface were characterized and analyzed. The optimized manufacturing procedures and parameters were presented based on the microstructure and mechanical properties of LMCS. The research results offer some guides and references for controlling the shape of bonding interface, optimizing the annealing process, improving the mechanical properties of Al/Mg/Ti LMCS.

Jan 1, 2015

By A. H. Harvey, M. Delangen, A. D. Fernie

"A large-scale expansion to Pacific Coast Bulk Terminals Ltd. has now been completed and placed in operation. The original plant, built approximately eight years ago, consists of the direct rail-car to ship transfer of bulk commodities. The extension includes additional rail-car unloading, a transfer house system for directing commodities to storage or ship, major storage and reclaim facilities, a second shiploader and a second deep-sea berth. In addition to the facilities for overseas shipments, a wood-chip loader and a barge berth have been installed for domestic shipments of wood chips and, occasionally, for other local commodities. The design considerations imposed by the nature of the products to be handled are covered in this paper."

Jan 1, 1969

By J. L. Llanca

The New Level Mine project (NLMP), the planned underground expansion of the El Teniente mine in Rancagua, Chile, is expected to reach a daily extraction rate of 137 to 180 ktpd upon achieving full capacity. Production is planned to start in the year 2017 and the current plan is to meet that target through two development phases, from the year 2012 to 2014 and from the year 2015 to 2017. To achieve the 2012 to 2014 underground development schedule, the ventilation requirements have been estimated in the range of 189 m3/s (400 kcfm), and cannot be made available without significant modifications to the current system of El Teniente. As a result, a certain number of alternatives were explored to find a solution to this shortfall, for example, adding raises to generate parallel airways and installing fans to reinforce the current ventilation system. From the alternatives studied, the installation of a second main fan (system) in parallel to an existing one was identified as the best solution, and selected for implementation, however the location was not ideal and there were concerns as to the operation of both fans once the second fan was installed. This paper presents the study used to estimate the operational points of both the current and the new fan, and to justify the parallel installation of the additional main fan. An additional computational fluid dynamics study was undertaken to validate the operational point, given the particular geometry of the fan?s location and placement, to guarantee a stable operation of the fans. Finally, the protocols arising out of this work for starting the fans, and operating them in parallel to avoid generating a stall condition and damaging the investment are discussed.

Aug 1, 2013

By R. Lodha, C. Oprea, G. Oprea, H. Zargar, T. Troczynski

"The basic refractories used in non-ferrous industry contain chrome ore for improving the thermal shock resistance, thus reducing the penetration of molten metal and fayalite-type slags into the lining. The current study aims to replace chrome ore with Me4+ ions along with Fe3+ ions in order to form MgO-Al2O3- FeOx-Me4+O2 based complex spinel systems that could perform similar to the complex chromia-bearing spinel in the magnesia-chrome refractories. This system allows for lower temperatures of synthesis and sintering. In our study, compositions with 60% MgO were fired below 1500°C and resulted in complete formation of complex spinel, and open porosity less than 5%. The in-situ formation of the complex spinel from the fine mix of oxides in the MgO-Al2O3-FeOx-Me4+O2 system offers a suitable alternative of binding system to produce basic refractories at lower temperatures and of similar physical and mechanical properties with magnesia-chrome bricks fired above 1750ºC. INTRODUCTIONThe synthesis of magnesium aluminate spinel (MgAl2O4) (Maschio, Fabbri, & Fiori, 1988) or magnesium chromate spinel (MgCr2O4) from their respective oxides is diffusion controlled resulting in a sluggish reaction even at high temperatures. For instance, the diffusion of Mg2+ and Al3+ ions in the intermediate spinel layer during reaction is slower than the diffusion of Mg2+ in corundum and Al3+ in periclase. The interfacial layer of spinel formed during the reaction increases the diffusion path for the spinel forming cations. This accompanied by ~8% volume expansion retards further reaction resulting in incomplete spinel forming reaction during sintering and hence densification during the reaction cannot be achieved. In order to assess sintering studies with fine particulate oxides that would result in a lower diffusion path, a mechanical mixture of the hydroxides of aluminium and magnesium calcined at 1400ºC to 1600ºC for 1 hour does not result in complete spinel formation (Sarkar, Das, & Banerjee, 2003), which indicates that reaction sintering of stoichiometric magnesium aluminate spinel is retarded by initial reaction forming the interfacial spinel layer. The basic bricks used as linings in non-ferrous pyro-metallurgical convertors are manufactured using magnesia and chrome ore, the sintering of which produce spinel solid solution. This solid solution is a mix of both normal and inverse spinel structures that sinters at temperatures in excess of 1800ºC in air."

Jan 1, 2012

By Jason Berenyi

Presentation Overview ? What is Potash? ? Where are the potash deposits? ? Current potash mines ? production, capacity and planned upgrades ? Saskatchewan Saskatchewan?s Potash Production Potential s ? Current Status of Potash Exploration ? Increasing Demand for Potash ? Saskatchewan global role

May 1, 2009

By Gurinder Kaur

Selenium (Se) based materials find wide applications in rectifiers, solar cells, photographic exposure meters, data storage devices, xerography and anticancer agents. They are also used in the glass industry to eliminate bubbles and remove undesirable tints produced by iron. In addition, Se is highly reactive towards a wealth of chemicals that can be potentially exploited to convert Se into other functional materials such as CdSe, ZnSe, Ag2Se. Here, we report a review of structural investigations of Se based materials in glassy and nanostructured forms. Glasses having varying amounts of Se and Tellurium (Te) were doped with group IV and V elements such as antimony and tin. Structural changes accompanying the composition variation were characterized with x-ray photoelectron spectroscopy, differential scanning calorimetry and x-ray absorption near edge spectroscopy. At the same time Se-Te nanoalloys were synthesized in aqueous micellar phase using Na2SeO3/Na2TeO3 as the Se/Te source. Morphology change from nanoparticles to nanoribbons was investigated using Scanning and Transmission Electron Microscopy (SEM/TEM) techniques. Structural investigations were also done for well defined morphologies of Se based nano-biomaterials obtained in the presence of water soluble protein bovine serum albumin (BSA).

Aug 1, 2013

By D. C. Fraser

Copper occurs invisibly in a geo-logical environment characterized by swampy conditions and an accumulation of forest peat. This swamp, located in southeastern New Brunswick, contains up to ten per cent cop-per (dry weight), in the organic sediments. This occurrence appears unique in that the metal is apparently organically combined in a chelate compound. Unlike the acidic nature of most peat bogs, the pH of the cup-riferous peat is nearly neutral. Analyses of the peat and associated soils have indicated that the bulk of the copper is contained in the organic sediments. It appears that the cop-per distribution is affected by capillarity, evaporation and the growth of frost crystals, and that the copper fixation is effected by organic sequestration resulting in the metal being bound to the nitrogen or oxygen components of the forest peat. While such a fixation mechanism is not definitely established as responsible for the immobilization of the metal, the facts at hand are compatible with

Jan 1, 1961

By A. M. Esteves

This paper offers an overview of local content policies and practice in the mining sector. Specifically, the paper aims to answer the question of how national and regional governments, industry and civil society can work together to seek an optimal outcome while pursuing their diverse objectives. The paper begins by defining local content and its scope at the subnational level. Specific recommendations for the design of local content policies to mitigate social, economic and governance risks are developed. The document then offers some recommendations regarding the role of partners in design, implementation, monitoring, and enforcement of local content policies.

Aug 1, 2013