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By T Takayama, M Matsumura, Y Konno

The steel industry accounts for 14 per cent of domestic CO2 emission in Japan, and iron ore sintering process occupies approximately three per cent. While Fe content in iron ore is gradually decreasing. So, the amount of concentrated iron ore will increase in the future. We have focused on magnetite concentrate as sinter materials, because magnetite can be easily magnetically beneficiated. However, it is experienced that blending magnetite ore resulted in increasing Fe2+ component in the iron ore sinter, which results in lower reducibility. Therefore, promoting the oxidation reaction from magnetite to hematite in the sintering process is countermeasure for reducibility. In addition, this promotion causes increase of oxidation heat, which results in high sinter strength and reduction of coke. It is assumed that the oxidation of magnetite tends to proceed in the cooling stage, where the oxygen partial pressure increases after the combustion of fine coke, but there are few studies on the effect of heat profile, especially cooling path. The purpose of this study is to design the effective sintering heat profile to promote oxidation of magnetite ore, especially, to investigate the effect of cooling path on sintered ore microstructure. In this study, magnetite ore and magnetite reagent were respectively mixed with calcium carbonate reagent. Then the mixed samples were pressed and formed into cylindrical tablets for simulating the adhesive layer of a pseudo particle. Through examining influence of maximum temperature and cooking rate on oxidation reaction of magnetite, we confirmed that the oxidation reaction of magnetite is suppressed at above 1350°C for maximum temperature, compared to 1300°C. Sintering at lower temperature is desirable because hematite is stable below 1350°C in the Fe2O3-CaO phase diagram.

Nov 8, 2021

By G Reynolds, L Lu

Queensland Pacific Metals (QPM) is developing its flagship Townsville Energy Chemicals Hub (TECH) facility to produce nickel and cobalt sulfates from imported high-grade nickel laterite ore for nickel-cobalt-aluminium and nickel-cobalt-manganese Li-ion batteries. The TECH facility is expected to use a patented leaching, recovery and recycling process called the DNi Process™. It uses the nitric acid leaching process for extracting nickel, cobalt and other valuable metals from laterite ore. Apart from the nickel and cobalt sulfates, the TECH Project will also produce high purity alumina, hematite (~640 ktpa) and other by-products. The hematite by-product precipitated from the DNi Process™ (hematite precipitate hereafter), is high in Fe and particularly low in impurities. QPM is working to identify potential applications for these high-purity by-products to generate additional revenue and to achieve its zero-waste ambition. As such, QPM has engaged CSIRO to evaluate various agglomeration options to produce low-cost, hematitic products suitable as ironmaking feed materials. This paper will first reveal the unique characteristics of the hematite precipitate arising from the TECH Project and then examine the sintering and pelletising processes for preparing the hematite precipitate as an ironmaking feed.

Sep 18, 2023

By G Reynolds, N A. Ware, L Lu

Queensland Pacific Metals (QPM) is progressing its Townsville Energy Chemicals Hub (TECH) project to produce nickel and cobalt sulfates for advanced battery materials. Apart from the nickel and cobalt sulfates, the process also generates a hematite by-product (~640 ktpa). The hematite byproduct precipitated from the process, hereafter ‘hematite precipitate’, is high in Fe and particularly low in impurities. However, it is a fine <20 μm crystalline, hydrometallurgical precipitate and is produced as a filter cake containing a high moisture content of about 15 per cent. This is considerably different from natural hematite ore and is expected to change its performance during sintering. In the present study, laboratory scale sintering tests were undertaken to evaluate the potential impacts of substitution of the hematite precipitate for traditional magnetite concentrates and further for Australian hematite-goethite ores in a simulated industry base blend. Substitution of hematite precipitate for magnetite concentrates was found to slightly increase the sintering temperature required to achieve the strength of laboratory sinters. However, further substitution of hematite precipitate for Australian hematite-goethite ores slightly reduced the sintering temperature required to achieve the laboratory sinter strength. These results reflect the reduction in Al2O3 contents of the blends and are consistent with the trend observed in industry and pilot scale facilities. The reduction in sintering temperature generally correlates to a reduction in fuel rate in the larger scale sintering process. The pore structure of selected laboratory sinters was further examined and discussed in conjunction with sinter strength. The pore structure images highlighted the relative difference between the blends with the most obvious difference being seen at 1290°C which correlates well with the laboratory tumble index (TI). The laboratory sinter samples showed an increase in porosity and irregularity of pore shape, as hematite substitution increased demonstrating the correlation between a more porous structure and a lower TI.

Sep 18, 2023

By L C. P J Fonteneau, B Godel, E R. Ramanaidou

The Hamersley Province in Western Australia hosts large iron ore deposits. Each deposit displays various iron ore types that were defined on their metallurgical properties, especially in terms of porosity and mineralogy. Conventional porosity and mineralogy information on iron ore types are provided on 2D thin sections using automated image analysis with scanning electron microscopy (SEM)-based techniques combined with chemical analyses. However these techniques cannot accurately quantify the 3D porosity. High-resolution X-ray computed tomography (HRXCT) is a non-destructive technique providing a 3D image of the sample with a resolution close to 0.5 - 0.7 ¦m for samples size of up to few centimetres in length. 3D image analysis using customised algorithms now provide accurate quantitative porosity and mineralogy of iron ore types.CITATION:Fonteneau, L C P J, Godel, B and Ramanaidou, E R, 2013. Application of high-resolution x-ray computed tomography to iron ore characterisation, in Proceedings Iron Ore 2013 , pp 243-250 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By P Aguilera, C Guerrero, M Tucker

With the advent of Electronic Detonator Systems in the global mining industry, as well as the development of high precision pyrotechnic delays, the measurement and analysis of delay performance (usually measured in terms of dispersion about a batch mean û precision, and the deviation of that mean from the nominal detonation time û accuracy), has become an important issue. Through the non-conventional use of existing Velocity of Detonation (VoD) measurement technology, it has been shown to be feasible to measure the precision and accuracy of delay detonator series connected in the same manner as a typical open pit bench hook up. This paper describes the work undertaken to compare and contrast performance results obtained using a range of instrumentation including High Speed Video (HSV) filming, digital counter timing using a Hewlett Packard Universal Counter and a digital VoD measurement device. The results obtained demonstrated the practical feasibility of using the latter technology in order to obtain relatively large amounts of data in a time-efficient manner, with a precision of better than 0.5 microseconds, if required. The results also confirmed the close statistical agreement obtained between the three forms of performance measurement, therefore permitting the substitution of the VoD measurement technique for the more capital cost intensive HSV technique and the slow, sample-by-sample HP Universal Counter method. This paper describes the methodology applied and the results obtained.

Jan 1, 2004

Reconciliation involves the collection of tonnage, grade (quality) and contained metal (product) data from disparate and hopefully independent sources. Examples are exploration data, production sampling data from blastholes or drawpoints, and process plant data. These data may be compared by means of ratios (factors). The F1 factor usually relates short-term (ore control) model tonnages, grades and metal content to ore reserves depleted. The F2 factor usually relates received-at-mill tonnages, grades and metal content to delivered-to-mill = production tonnages, grade and metal content. The F3 factor is F1 &#215; F2 and enables a comparison of a mineÆs ability to recover the tonnage, grade and metal content estimated in ore reserves. The F1 factor measures the accuracy of orebody knowledge in the ore reserves to the demarcation of ore and waste by ore control (short-term model). The F1 factor may be used to check and calibrate the selectivity of mineral resource models and/or planned dilution assumed in transfer from mineral resources to ore reserves. The F2 factor enables a check on unplanned dilution entering the ore stream between ore control and the mill. Using the factors it is possible to calculate a monetary value on improvements in the accuracy of orebody knowledge, selectivity and the effects of dilution and ore loss. Reconciliation should be an implicit part of the mining process, and reconciliation targets should be a key performance indicator for well-run mines.

Sep 26, 2011

The purpose of this study was to investigate the effectiveness of froth fl otation for the recovery of gold from the gravity tailing stream of the former Lihir Gold Limited (LGL) operation in Ballarat. The P80 of the tailings was determined by screen analysis as 1 mm, with test work conducted on as received material along with samples ground to P80 sizes of 47, 78 and 134 microns. Laboratory scale batch flotation tests were conducted at both natural and elevated pH to investigate the impact of pyrite depression on gold recovery. Results indicated that although an increase in grade from approximately 0.7 g/t to 3 g/t was achievable at a natural pH and a P80 of 134 micron, gold recovery was low at just 35 per cent. Finer grind sizes were found to have an adverse effect on both grade and recovery. Future efforts will be focused on the sub 310 micron size fraction of the tailings, which was revealed to contain approximately 85 per cent of the available gold and may be amenable to cyanidation or ultra-fine gravity treatment.

Aug 1, 2010

By V Sanmartfn, J Torracchi

The broad biodiversity of our country is manifested through several different biological forms. From the villages of Portovelo and San Gerardo in the southern part of Ecuador, some samples of water and rocks were taken in order to identify the native micro-organisms which take part in the natural processes of leaching of sulfurous minerals. The presence of Spp Thiobacillus ferrooxidans was determined together with a fungi sample which has not yet been characterised by the current workers. These have been isolated, grown, experimented and conserved in appropriate cryogenic environments. The present research intends to study the individual and group adaptation of the bacteria and the fungi upon suitable systems of agitation and ventilation, in combination with several different concentrations of refractory auriferous samples. These refractory samples were derived from old mine workings and the experiments were performed to test the effectiveness of the isolated species in bioleaching as pre-treatments upon the cyaniding processes. The capability of these bacteria to develop in environments with high concentrations of cyanide has also been studied, to investigate the possible use of bacteria in the biodegradation of cyanide. The presence of Thiobacillus ferrooxidans in acid conditions has already been tested in advance, however, the presence of fungi species in these conditions are studied to prove their efficiency as another alternative for the bioleaching of refractory auriferous minerals and Baptista, 1998).

Jan 1, 2004

By H Wang, D Wang

Mine dust is the most serious occupation hazard in coalmines. And many coal workers suffer from pneumoconiosis because of long-term inhalation of respirable dust. Reducing the dust concentration of workplaces by effective technical means is an important way to prevent coal worker’s pneumoconiosis (CWP). In order to overcome deficiencies in existing dust control technology for underground mining, especially the disadvantage of water spray technology mounted on roadheaders or continuous miners, the authors developed an integrated dust suppression technology utilising foam for fully mechanised heading faces. This paper presents an overview of the principles, materials, equipment and application of this technology. Among these, a jet type foaming device and a green foaming agent were developed, which can realise the goal of efficient preparation of foam. In addition, an arc fan nozzle used for foam spraying was invented, which can effectively cover and enwrap the dust produced by the roadheader at the cutting point and achieve the goal of efficient utilisation of foam. This dust suppression application of the proposed foam technology was investigated on fully mechanised heading faces. The results show that the dust concentration was cut down significantly with a dust suppression efficiency of greater than 85 per cent, an increase of over 30 percentage points compared to the water spray system. This study demonstrates that this foam technology can play an important role in dust suppression on fully mechanised heading faces, which provides an important method to improve the working environment and protect coal workers’ health.CITATION:Wang, D and Wang, H, 2015. Technology of dust suppression by foam for fully mechanised heading face, in Proceedings The Australian Mine Ventilation Conference, pp 177–182 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By V A. Chanturia, T N. Matveeva, V V. Getman, A Yu Karkeshkina

The development and application of new effective environmentally friendly reagents for the flotation of thin and ultrathin mineral components is an urgent task. The analysis of the nomenclature of chemicals, including flotation reagents and flocculants, showed that water-soluble polymers (WSP) might be used in flotation separation of fine grinding products containing non-ferrous and precious metals. Water-soluble polymers that are responsive to temperature changes are the most attractive as reagents during flotation. These are the thermo-responsive polymers or thermomorphic polymers. The presence of nitrogen and oxygen atoms in the polymer molecule contributes to the formation of a coordination bond with non-ferrous and precious metals. A research conducted at the ICEMR RAS within the framework of the scientific school of Academician of the Russian Academy of Sciences Chanturia helped to develop a method of flotation of finely ground mineral particles containing valuable components using modified thermomorphic polymers. The paper focuses on the experimental study of poly (vinyl caprolactam) (PVC) as a flotation reagent for gold recovery from finely ground mineral products. PVC is a ready-made water-soluble thermosensitive polymer that does not require complex synthesis. PVC has a high ability to form complexes in an aqueous environment when heated. According to experimental data, the polymer interacts with gold nanoparticles, contributing to the extraction of gold from fine mineral products and the tailings that makes it perspective as an additional flotation agent for the processing of gold-containing ores.

Aug 24, 2022

By R A. Pakhomov, L V. Krupnov, P V. Malakhov, I M. Dymov

The article presents results of thermodynamic calculations and laboratory studies, focusing on the cobalt behaviour during oxidative smelting of copper-nickel mattes. The compositions of the studied solutions are related to the products formed during the second stage of the converting process of copper-nickel matte at the Nadezhdinsky Metallurgical Plant (NMP) of MMC Norilsk Nickel company. These sulfide products typically contain from 1.5 to 12 wt per cent of iron. The obtained experimental results and thermodynamic calculations indicate that adjusting the CaO ratio to increase the proportion of CaO or complete replacement of SiO2 with fluxes containing CaO leads to a significant increase in cobalt recovery rates in the matte phase (with an iron concentration of 2.5 wt per cent) raising them from 30 per cent to 45 per cent. Meanwhile, the recovery rates of copper and nickel remain constant.

Aug 21, 2024

By N J Welham

A commercial enargite concentrate was mechanically milled in inert and oxidising atmospheres for 10 hours. No substantial effect was observed in either an inert atmosphere or in air other than a broadening and weakening of the diffraction peaks. Milling dry in oxygen or wet in air was dramatic with a significant reaction occurring which formed arsenolite, As2O3 and CuSO4.5H2O, both of which are readily soluble.A small amount of SO2 was also formed. Dissolution in acid left CuS as the major phase implying incomplete oxidation. The small fraction of tennantite in the sample was comparatively resistant to oxidation.

Jan 1, 2001

By J G. Shellnutt, Y Iizuka, T W-Y Hsia, T-C Liu

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The formation of magmatic oxide ore deposits hosted in chemically-evolved layered gabbroic intrusions is attributed to a variety of petrological processes, but there is little to no consensus on the general applicability of each model. Complicating the matter further is that many layered gabbroic intrusions are spatially and temporally associated with alkaline A-type granites, suggesting that there is a petrogenetic relationship between the two types of chemically different rocks. Our experimental results show that petrological modelling using a starting composition of high-Ti basalt from the Emeishan large igneous province can produce evolved silicic liquids that resemble the compositions of microgranular enclaves from the syenitic unit of the bimodal, oxide ore-bearing Baima igneous complex. The experimental results confirm that bimodal gabbro-granitoid complexes can form from a common parental magma and that early crystallisation of Ti-rich magnetite can explain the formation of the oxide ore deposits in the lower parts of the layered gabbroic intrusions. We conclude that crystallisation of a typical high-Ti basaltic parental magma can produce world-class giant magmatic oxide ore deposits and that the occurrence of some alkaline granites may be an indicator of their presence.CITATION:Shellnutt, J G, Hsia, T W-Y, Liu, T-C and Iizuka, Y, 2015. Cogenetic formation of the peralkaline syenite and oxide ore-bearing layered gabbroic intrusion of the Baima igneous complex, Emeishan large igneous province, south-west China , in Proceedings PACRIM 2015 Congress, pp 317–324 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By R Jia, J T. Waldram

"The Caijiaying lead zinc mine is located in China, north-west of Beijing, in Hebei Province. The region experiences severe winters, below -35&deg;C, and warm summers, up to 30&deg;C. The mine and concentrator commenced operations in the second half of 2005 with a conventional tailings disposal system consisting of a tailings dam with peripheral ring main discharge and central water recovery. A second similar dam sharing one common wall was added later. In view of the extreme winter conditions tailings lines and ring mains plus spigots, together with return water lines, require insulation and electrical trace heating. The volume of process water trapped as ice in the tailings dam ponds each winter is significant. This seasonal variation presents a major difficulty in the management of process water availability. Although Caijiaying is an underground mine there was no backfill plant at the start of operations. As plant throughput increased more quickly than originally anticipated, tailings storage capacity became a prime concern. The construction of a backfill plant in 2007 reduced the pressure on surface tailings storage area requirements, but as suitable land on which to construct further tailings storage was both expensive and difficult to acquire, a more efficient use of the available area was required. Dry tailings storage, where flotation tailings are filtered to provide an immediate return of process water plus ‘dry’ tailings filter cake for stacking, provided an answer to both the land area required, and the water management difficulties. The paper details the reasoning behind the change and the benefits obtained at Caijiaying by moving from ‘wet’ tailings storage to ‘dry’ tailings storage.Citation:Waldram, J T and Jia, R, 2016. Caijiaying Dry Tailings Storage, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 379&ndash;382 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By M Parcell

"Ventilation risks in an underground mine have essentially remained the same for centuries, yet theevidence suggests that there are many coal mines that have failed to adequately control these risks.The conduit for the knowledge learned by previous generations exists in the mining legislation. In an ideal world, mines would not need legislation to tell them what to do; they would resolve the risks to an acceptable level so as to protect the safety of persons in the mines based on the acquired knowledge. There will be some who have been personally aff ected by a mining disaster but for the majority they will be remembered as a vague recollection of an event from long ago. The mining legislation is the repository for the knowledge and outcomes from inquiries of past disasters. The challenge for the current generation, and the generations to come is to appreciate the legislation that exists, so as to not ælearn the hard wayÆ. In reviewing most disasters there is comment or discussion on the adequacy of the legislation, which ultimately results in some amendment to the law. For each person, there is an increasing responsibility to ensure that the same mistakes are not repeated. Understanding the legislation, its history and its purpose is the fi rst step in ensuring thatventilation risks are eff ectively managed. Failing to do this will be disastrous. This paper discussesthe relevance, importance and potential pitfalls of coal mine ventilation regulation."

Jun 1, 2012

The tangible effects of leakage are presented graphically, and a technique for quantifying the leakage characteristics of a ventilation column using the æSolveÆ capabilities of a common spreadsheet is demonstrated. A case study of a working decline in Western Australia is used to demonstrate the potential for more realistic design of development ventilating systems, and for more cost effective management of the condition of the duct.

Jan 1, 2002

Sheaves are a critical safety component in a winding system and are expected to survive such extreme loading events as rope break. Sheave designs have often been developed and evolved empirically, consequently many existing sheaves are not necessarily subjected to the detailed analyses that are possible using todayÆs design tools. The design philosophy for sheaves is that the rope should be the weakest link in the system so that associated equipment can function safely for any load up to rope break. A number of failure mechanisms must be considered, but buckling is often prominent. During the course of investigating the feasibility of upgrading the hoisting capacity of a winding system, the capacity of all critical components was reviewed. The sheaves in the system were found to have insufficient spoke buckling capacity for the specified rope. A proposal to increase the spoke buckling capacity by connecting spokes together using a simple tie arrangement was evaluated and found ineffective. An alternative tie arrangement concept was developed and evaluated and shown to be adequate. This paper describes the finite element model, analysis approach and results for the original sheave and the two modifications. The contribution of the sheave rim to the total buckling capacity is evaluated. Some practical issues for spoke tie modifications are discussed.

Jan 1, 2005

The cloud transform simulation is a technique used to generate realisations of correlated attributes. The principle of this technique is to partition the scatter diagram between the input attributes into several interval classes and derive for each class a cumulative distribution function (CDF) using only the data pairs of the scatter diagram in that class. The simulation then proceeds like a traditional Monte Carlo simulation but using the derived CDF in each class.The cloud transform simulation has the advantage of being a simple and fast technique that is able to reproduce the uncertainty in the relationship between the two input attributes regardless of whether the relationship is linear or not. However, the technique has three major drawbacks. First, the number of classes has an impact on final simulated results and there is not a robust approach to define such number. Second, simulated results exhibit some saw tooth variations that are unrealistic and third the reproduction of the spatial continuity of the simulated attribute is not guaranteed.This paper presents the use of the quantile regression approach in order to overcome the first two disadvantages of the cloud transform simulation. Details of the technique and how it can be coupled with the cloud transform simulation are presented along with a real case study.

Sep 26, 2011

By Y Chung, B Choi, H Lee

Numerous studies have explored refractory corrosion in the presence of slag and/or metal, utilising the Finger Rotating Test (FRT). Recent experimental results revealed that corrosion initially increased with rising rotation velocity but was then suppressed above a critical rotating speed, under conditions involving a two-liquid solution of slag and molten steel. This phenomenon indicated that the liquid/liquid interface movement occurred during spindle rotor. However, understanding of the phenomenon, known as the rod climbing effect, remains inadequate in the case involving slag, molten steel and refractories. To gain deeper insights, a simulation experiment was conducted on the phenomenon using silicon oil/water and the phenomenon was analysed using computerised simulation software (Ansys Fluent). Experimental modelling demonstrated that interfacial movement occurs even at low rotation velocity, as low as 200 rev/min, when the viscosity of silicone oil is at 100 cP. Computational analysis utilising the Volume of Fluid (VOF) method and a realisable k-ε turbulence model elucidated that interface elevation during rotor rotation arises due to viscosity disparities between the two fluids. Furthermore, this movement is more pronounced when the viscosity difference is lower. Additionally, the study findings suggest that higher density differences between two liquids suppress the phenomenon of interface movement.

Jun 19, 2024

By J Webb

"It is vitally important in projects where the cut-off grade is low that there is no contamination during the sampling and sample preparation process, both in the ore and the waste zones. Failure to identify contamination could have devastating financial consequences for a project. The use of a variety of blank types is essential for ensuring that contamination is identified and eliminated at every stage of the sampling and sample preparation process. This paper examines an instance where an effective assay quality assurance and quality control (QA/QC) program was able to identify and eliminate a source of significant multi-element contamination in the prefeasibility stages of an open pit project. This examination includes the: evidence for contamination findings of the investigation process of resolving the problem and correcting the data evidence for both addition of metal and dilution through contamination potential impact on the project had this issue not been dealt with. It was through the use of a combination of blank types that the QA/QC process at Mount Isa Mines (MIM) identified a contamination issue at the first crushing phase of sample preparation. Identification of the contamination allowed MIM to stop assaying activities and work with the laboratory to correct the problem. The sampling program could then be continued with no further doubts about the sample preparation process. Contaminated samples were resampled from retained core. With the continuous monitoring provided by the blanks program, it was possible to ensure that only clean results went into the resource modelling data set. CITATION:Webb, J, 2014. When nothing is what you need – the importance of using blanks at all stages of sample preparation, in Proceedings Sampling 2014 , pp 49–54 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 29, 2014