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By W A. Ducker, R-H Yoon, M Mao

Froth flotation relies on an attractive force between a particle and a bubble to selectively extract particles from a mixture. The range and magnitude of this attractive force is an area of ongoing investigation. We describe measurements of the effect of dissolved gases on the long-range attractive surface forces between a silica plate and a glass sphere in aqueous octadecyltrimethylammonium chloride (C18TACl) solutions. The measurements follow on the work of Sakamoto et al (2002) who have concluded that long-range interactions occur in air-equilibrated surfactant solutions but not in degassed solutions. In the present work, we have measured attractive forces that have a much larger in magnitude than the expected van der Waals force in solutions that were degassed by the same procedure used by Sakamoto et al (2002). We find that the forces are most attractive at 5 + 10-6 M C18TACl, which is close to the charge compensation point (ccp) of the glass sphere. At this concentration, the attractive force decays exponentially with distance and the decay length is 34 in air-saturated solution, and 38 nm in degassed solutions. In both air-equilibrated and degassed solution, the force is quite sensitive to the concentration of surfactant. The force is also sensitive to the pH. We note that our degassing procedure increases the pH of the solution from about 5.7 to 6.6 (presumably by removal of dissolved CO2). We find that the forces measured in degassed solution can be reproduced by using a solution that was equilibrated in air, then the pH was increased by addition of NaOH. Therefore, we conclude that the main effect of degassing in our experiments is to raise the pH. We show that the range and magnitude of the attractive force decreases in the presence of salt (NaCl). This suggests an electrostatic mechanism for the attraction. Possible mechanisms for the attractive force are examined, including the mechanisms that rely on a patchy coverage of surfactant on the silica surface.

Jan 1, 2005

By Reid T. W

This paper describes the results of investigations into the relationship between specific gravity and chemical composition in the Cockatoo Island orebody, In the early investigations the samples were classified into groups according to porosity. This resulted in high, medium and low porosity groups, the latter being further subdivided into ore and waste. Whole number tonnage factors were assigned to each group. In the later investigations the reciprocals of bulk specific gravity and true specific gravity were ex- pressed as linear combinations of iron, silica and alumina using stepwise regression. The efficiency of the models as predictors was tested by dividing the data into two sets; one of which was used to calculate the regression equation and the other to test the efficiency of the equation as

Jan 1, 1976

Copper entering a lead ,smelter in concentrate or from other sources is recoVered as matte and speiss which contain appreciable quantities of lead. The matte and speiss are usually sold to copper smelters to recover the copper content and also any gold and silver in these products, but the value of the lead is largely lost. Some copper plants pay for portion of the lead content, but regarded as a means of recovering lead it is more costly and less efficient than if the lead were recovered at the lead smelter.Because of the value of this lead loss, the metallurgy of copper recovery has assumed greater importance in recent years owing to the rise on the price of lead.Two processes are in use today to produce matte and speiss, namely the iron matte process and the soda matte process developed by the American Smelting and Refining Co. 1 in D.S.A. The latter process is characterised by a higher copper to lead ratio than the older iron matting process.The following analyses are typical of matte and speiss produced at Broken Hill Associated Smelters, by both processes, although the soda matte process is still in a developmental stage and experience indicates that matte and speiss of lower lead tenor can be produced under favourable conditions.

Jan 1, 1951

By M J. Sale

The Epithermal and Mesothermal Gold Prospectivity Modelling Projects recently completed by Crown Minerals provided explorers in New Zealand with a new compilation of historical exploration data combined with new geological information from the GNS QMap 1:250 000 scale mapping project. These data were used to produce predictive mineral potential maps for gold mineralisation in New Zealand. The aim of these projects, which was to stimulate mineral exploration and investment in exploration, has been successful with new companies acquiring new tenements and committing significant exploration expenditure to exploring in New Zealand in the coming years. The projects were undertaken at a national scale and consequently not all exploration data were compiled into the prospectivity models. HPD New Zealand Ltd recognised the value of the prospectivity modeling work and committed exploration funds to continue the modelling process started by the projects. They recognised the need to compile the remaining data and run the models again to allow detailed exploration targeting.

Jan 1, 2004

Botanical exploration has identified many plant species that naturally accumulate very high concentrations of elements, particularly heavy metals. The enormous potential applications of some of these species to remove metals from soil (phytoextraction) are slowly being realised. The discovery of hyperaccumulation has resulted in considerable research into applications for removing contaminants (phytoremediation) or more importantly, in the context of this discussion, for commercially æfarmingÆ metals (phytomining) from metal-bearing soils. Currently published phytoextraction models estimate Ni yields using Berkheya coddii (a South African nickelophyte) are approximately $US 750 ha-1, excluding the cost of processing. Research indicates that B. coddii will also accumulate significant amounts of Co, resulting in a considerable increase in the value of the crop. Modification of the substrate by acidification, fertilisation and/or chelation indicate fruitful avenues for improving this yield by increasing the extractability of the target element, elevating biomass production rates and/or rendering other contained heavy metals extractable. Plant uptake of more insoluble elements, such as Au, may be induced in many plant species using chemical compounds. These chelates applied to the soil, form soluble complexes with poorly soluble metals forcing them into the soil solution. Plants may then accumulate these metal complexes through transpiration. Research has achieved foliar Au concentrations of 78 mg kg-1 in Iberis intermedia, 56 mg kg-1 in Brassica juncea and 9 mg kg-1 in B. coddii (on a dry weight basis). Therefore in theory B. coddii could phytomine a soil containing modest concentrations of Ni, Co and Au to yield 116 kg Ni, 36 kg Co and over 6 oz Au ha-1 at a current value of $US 4000. Root crops have also shown promise in chelate assisted Au accumulation (eg 6.8 mg kg-1 in Beta vulgaris and 118.5 mg kg-1 in Raphanus sativus). Phytoextraction, in its varied applications, is rapidly coming of age as a technology having considerable potential for application in environmental science and the minerals industry. Phytotechnology employs unique plant biochemical behaviours in the rhizosphere, driven by the sunÆs energy, to seek out and concentrate low levels of heavy metals at very low cost.

Jan 1, 2002

By D Morris

This presentation discusses a water filtration technology termed Fabric Media that is somewhat novel to the Australian market place and reports several recent mining industry installations. Like many novel household cleaning products, the Fabric Media technology applies the science of active washable micro fibres as the means of capturing contaminant solid particles. The simple Fabric Media water filtration product offers several attractive attributes when compared to the more traditional media bed filtration processes such as sand filters, and barrier filters such as micro membranes. A micro fibre based filtration media enables both superior adsorption for the contaminant and wash ability. Stronger adsorption capture enables a much higher flux and greater solids loading density for the filtration task, meaning that lower cost and smaller footprint equipment is available. For Fabric Media water filters, a textile weave is selected that minimises the flow backpressure for a given particle size separation. Thus for an equivalent filtration performance this provides a much lower operating energy requirement, generally between 50 and 80 per cent less than for a sand filter. A Fabric Media is not abrasive to itself or to the filter tank. The filtration performance remains constant and predictable. The equipment life is much longer and the asset value of the new filtration equipment should maintain throughout the project life. Fibres are extremely mechanically robust and chemically inert. Fabric Media survives repetitive exposure to a rapid mechanical washing event providing high wash efficiency with minimum equipment off-line time for the backwash. Dislodging captured contaminants by a high-speed mechanical agitation enables a minimum off-line time during backwash events. The vigorous backwash destroys adhering flocculant and eliminates the formation of mud balls, which can permanently foul sand filters. The mechanical agitation wash of the Fabric Media water filter ensures complete removal of grease and biofilm, which can adhere and block a membrane surface. In comparison to sand filters and micro filtration membranes, the Fabric Media product is applicable to a significantly wider range of solids concentrations without permanent damage. The technology is very forgiving to excursion in plant control and is therefore considered a very operator-friendly concept.

Jan 1, 2006

Today the application of computer programs for planning of mine-ventilation and for safety- analysis of ventilation systems is widespread practice in German mining. The computer program for network calculat- ion, developed at the "Mine Ventilation Testing Centre of the Westfalische Berggewerkschaft- skasse" allows the distribution of airflow and pressure in mines to be calculated. In a physically well founded manner it takes into account the natural ventilation as well as changes of volume-flow in the mine, which both are dependent on pressure and temperature. Compared to an incompressible treatment of the mine air these circumstances are of increasing importance with the increase of depth, air temperatures and fan-pressures'. This especial- ly holds for the calculation of airflows during failures of fans or for assessing the influence of open mine-fires on ventilation. The application of the program is very easy and its structure is made to fit the requirements of practice. For instance it takes into account the fan characteristics of all fans. For each planning calculated air- flows in all mine workings are compared to those of an eligible basic calculation or to measured airflows. In addition for the

Jan 1, 1983

The Agnew Mine No. 1 Ventilation Shaft is the largest diameter shaft blind drilled in a hard rock mining environment. The selection of this method of shaft development was based on achieving an accelerated mine development and exploration programme. Drilling the shaft from a pre-sink depth of 73m commenced on March 22, 1982 and the shaft was stopped due to rig structural problems at a depth of 750m, 280m from the designed depth, on February 12, 1983, 137 days behind schedule. While problems with rig mechanical availability, cutter life and lost drilling tools in the hole hindered progress and escalated costs, penetration rates above prediction were achieved and both the speed and safety aspects of the method were well demonstrated.

Jan 1, 1983

Difficult ground conditions in the area planned for placement of vent rises to the surface at the Porgera Goldmine led engineers directing the project to chose blind shaft boring methods of shaft construction from the available alternatives. Zeni Drilling Pty Ltd was first contracted in 1988 to install a group of three closely-spaced, steel lined shafts. The success of these led to an order for a fourth hole in the same group followed by two more, less than a kilometre. away, under a separate contract in 1992. All of the shafts were completed on.schedule to within one day. The only significant difficulty arose during commencement of the last shaft when the strata collapsed trapping the drilling tools and jeopardising the stability of the surface collar pad. The situation was corrected by innovative lining techniques and the project went on to finish on schedule. This paper discusses the application of various technologies associated with the project including aspects of geotechnical input, drilling fluid chemistry, mining engineering and logistics.

Jan 1, 1993

By Wheatley MR

Answers to the questions "which rocks contain diamonds?" and "which indicator minerals should diamond explorers look for?" are no longer so easily obtained, now that diamonds are known to occur in lamproites and various types of lamprophyres, as well as their traditional source of kimberlites. One way of isolating those factors (host-rock"geochemistry, geographical or tectonic location, xenolith minerals, etc.) which are most critical in determining the diamond potential of a given pipe, is a detailed and critical re-examination of the huge volumes of accumulated data on kimberlites, lamproites and related rocks. A large analytical database to this end has been set up on an Apple Macintosh II microcomputer using the quasi-relational database management system 4th Dimension. Currently, it contains data for up to 90 major and trace elements, isotopic ratios and contained mineral compositions for some 4,000 rock specimens from all over the world. Many experiences in setting up this database are probably relevant to other geologists setting up their own systems: they include determining the relationships between data items; the advantages of codes over free text in representing categorical variables such as rock types; the need for rigorous error trapping and data validation; and the problem of missing data values and ambiguities thereof. The working system is now being used in a rigorous statistical assessment of the criteria which distinguish diamondiferous from non-diamondiferous rocks.

Jan 1, 1989

Here, in what is partly a review and partly a personal viewpoint, I take stock of changes in emphasis and comprehension on the subject of basaltic volcanism in the decade that has passed since the completion of the landmark Basaltic Volcanism Study Project (1981). I concentrate attention on the relatively neglected physical-volcanology aspects (in 1988 it was still possible to publish a 340-page book on flood basalts with barely any mention of physical mechanisms).I adopt the useful unifying concept of "volcanic system" to embrace the invariably-present intrusions as well as the volcano; I consider controls exercised by magma-supply rate and modulator-mechanisms on the nature of the system;I emphasize that sheeted-intrusion complexes, consisting either of dikes or inclined sheets (depending on the ability of the system to expand laterally) occur in all eroded major systems and fuel geothermal systems; I show how constraints set by cooling of narrow intrusions cause such complexes to be wedge-like and produce considerable rotations; I consider the role of the level of neutral buoyancy in making magma chambers possible, causing lateral subsurface magma flow and localizing intrusions, while the LNB itself can be accentuated by intrusions; and I examine the possibility that underwater systems could have very different internal structures from systems on land.

Jan 1, 1990

By D A. Kepert, D Clark

During early 2004, Fortescue Metals Group (FMG) began an aggressive exploration and drilling program in the Chichester Range, targeting iron enrichment developed in the Nammuldi Member at the base of the Marra Mamba Iron Formation. The timely recognition by FMG of distinct zones of (hypogene) microplaty hematite (mplH) enrichment overprinted by extensive supergene mineralisation led to an early reappraisal of the geological history of the area and characterisation of the possible structural and stratigraphic controls on mineralisation. Regionally, the Chichester Range dips gently at less than 5¦ to the south, however, detailed mapping shows that this regional limb is overprinted by low amplitude, long wavelength, north/south to northeast/southwest trending folds. The locations of major structures in the Marra Mamba Iron Formation, combined with spectral analysis of known mineralisation, allowed extrapolation and prioritisation of exploration target areas. The delineation under cover and understanding of these structures was enhanced by detailed airborne magnetic data. Recognition that supergene mineralisation was associated with a palaeotopography that continued significantly under cover to the south under sediments of the Fortescue River valley led to the discovery of extensive supergene mineralisation together with additional mplH mineralisation. A model for the landscape evolution and preservation of enriched Nammuldi Member was generated in order to help communicate both the complexities involved with targeting drill holes beneath cover and the potential limits to the lateral extents of mineralisation.

Jan 1, 2005

Previous methods for the assessment of the explosive potential of gas mixtures have required the plotting of apeexplosibility diagram. These became cumbersome if a large -number of assessments of various sampling locations over a period of time wererequired. This may make the approach of a dangerous situation more difficult to predict. With the aid of a programmable calculator, a new method for the rapid assessment of the explosibility of coal mine sample gases has been developed. This method does not require that an explosibility diagram be drawn to indicate the explosive status of a gas mixture. Simple Cartesian co-ordinates representing the explosive potential of,mixtures are obtained, which may readily be plotted to show changes with time.

Jan 1, 1981

By Khosia NK, Ravishankar SA, Sankar TAP

Alumina reduction in Rajhara iron ore slimes essentially involves separation of hematite from gibbsite in relatively coarser fraction and from kaolinite in the finer fraction. Selective dispersion flocculation studies on synthetic mixtures clearly indicated that while it was possible to achieve almost perfect separation of hematite from kaolinite using starch and PAMX (modified polyacrylamide containing hydroxamate functional groups) flocculants, no selectivity was observed in iron oxide-alumina system. A schematic flowsheet suggested on the basis of this work for the beneficiation of Indian ore slimes thus consists of classification in a hydrocyclone, followed by selective dispersion of coarse fraction (underflow) and selective flocculation of the overflow fraction. Starting with a feed assaying 46 per cent Fe and 11.6 per cent A1203, a concentrate assaying 60 per cent Fe and 4.7 per cent A1203 could be produced at an overall iron recovery of 60 per cent using conventional Reagents.

Jan 1, 1993

By J Player

Big Bell Mine started experiencing relatively large mining related seismic events, and accompanying rockbursts, from February 1999. Twelve rockbursts damaged access development from February 1999 to June 2000, with severe damage extending for up to 100 m along footwall drives. Five seismic events associated with the rockbursts were recorded by the AGSO, measuring 1.9, 2.2, 1.7, 2.4 and 2.2 on the Richter scale. These events affected 485 and 460 footwall drives in August and November 1999 and 535 footwall drive in June 2000 (drive level nomenclature is equivalent to the depth below surface and RL). After the third event (July 1999) it was apparent that the seismicity was not a once-off phenomenon. This (sudden) onset of seismicity required management to implement a series of precautionary measures:to ensure the safety of the workforce, to maintain continuity of production, and to reduce rockburst damage rehabilitation. The measures included extended re-entry periods and exclusion zones in high-risk areas, improved rockburst resistant support systems in areas prone to damaging seismic activity and improved support systems in areas prone to shakedown damage. A full-scale minewide ISS seismic system was ordered in October 1999 and commissioned in February 2000. A portable eight-channel CSIR-Miningtek system was installed at short notice as an interim measure in August 1999. This CSIR system covered the northern producing stopes, where the majority of the rockbursts had occurred. The objective of the seismic monitoring was to monitor relative activity and to determine trends with regards to time and location. MAP3D numerical modelling was used to investigate the relationship between seismicity and various combinations of stress components to assess the relative seismic risk in both current and proposed working areas. This information is used to determine where and at what stage in the mining cycle the rockburst resistant support is required. Analysis of the seismicity has determined two distinct modes of seismicity û small-scale localised, high frequency events in high stress areas and larger events related to shear along previously intact foliation surfaces. This paper includes a summary of the seismic history, seismic data analysis, support system design, mine design adjustments and management action to minimise the effects of seismic activity at Big Bell Mine.

Jan 1, 2000

By Kokubu H, Moro-Oka A

Gaseous desulphurization from hot metal- lurgical slags containing sulphur mainly as sulphide and(or) sulphate was measured under `low at four different oxygen pressures. The total gas rate was from 1.7 to 2,8 litre/min. Crushed slag samples weighing 2 to 12 g were used for the experiments. The amount of SO2 gas evolved from samples kept at 15500 was rieasured over tires ranging from 20 to 300 min. The gaseous desulphurization rate of sul- phide sulphur becomes high as the oxygen part- ial pressure is increased, while that of sul- phate sulphur is high under low oxygen pressure. The effect of basicity on the desulphurization rate of sulphide sulphur in oxygen atmospheres is not obvious in the range of basicity from one to three. Changes in the ratio of sulphide to sulphate sulphur during the run in oxygen axe analysed. Desulphurization reactions and the rate controlling steps are discussed. De- sulphurization phenomena can be explained by inte.-¦ucia.l chemical reaction rate control.

Jan 1, 1980

By R Piper

The Yabulu Nickel Refinery commissioned in 1974, processes lateritic ore via a modified Caron process to produce high quality nickel and cobalt products. The Greenvale orebody provided the sole source of feed to the plant until 1990 and with well-blended mineralogy, it resulted in stable and predictable plant performance, allowing the operating focus to be on reducing energy consumption and increasing ore throughput. This approach provided better economics than pursuing increased reduction efficiency. From 1990, increasing quantities of lateritic ore were imported from Indonesia, Philippines and New Caledonia. This introduced considerable variation in ore blends and instability in plant operation but also provided the opportunity to treat higher grade ore blends which yielded higher reduction efficiencies. Ore reduction is conducted using 12 Herreshoff multiple hearth reduction furnaces, using heavy fuel oil as reductant. The æROASTERÆ Project was approved in November 2000 with the primary objective of improving Nickel reduction efficiency by: Stabilising Roaster Operation via a structured program including focused maintenance efforts, capital equipment upgrades, new process measurements, process re-design and improvements to operating skills and process troubleshooting. A structured technical program including laboratory and plant studies using one plant furnace as a pilot unit to develop improved knowledge of how the reduction process proceeds in the Herreshoff furnace. Armed with this knowledge, optimised process conditions and a reduction process model were developed contributing to a significant demonstrated reduction efficiency improvement. Technical input to the project was provided by QNI with Hatch providing the engineering and project management for the $8.5 M capital work. Execution of the work included extensive consultation with the plant operators and close cooperation between the Hatch project team and QNI operations personnel ensuring installations were completed with minimal production disruption. A strong focus on safety management resulted in a number of brownfields project relevant safety initiatives being implemented resulting in project completion without a serious injury.

Jan 1, 2002

By A Robertson

Australia has been slow in adopting the use of underground space as a part of our urban planning process. Australia has one of the highest levels of tunnel advance per capita per annum in the world, yet the use of underground space in our cities appears difficult for our planners and politicians to comprehend, not withstanding the general availability of good quality rock and contractor expertise in Australia. However, the lack of space in our urban areas is being highlighted as our major cities expand outwards and people and businesses gravitate towards city centres. Typical potential underground space uses include car parking, self-storage and archiving facilities, water storage, underground quarrying, small industrial facilities and another layer of traffic (electric and fuel cell) and services network. Historically, blasting in high density population areas has resulted in blast vibrations and blast overpressures exceeding the limits, which in some case have been set extremely low in terms of peak particle velocity (PPV). This makes conventional blasting difficult, often requiring low charge weights per delay and associated small blast sizes and slow advance rates. However, the introduction of new technologies, such as computer aided drilling, electronic delays and low-energy explosives has made this task considerably easier. Although more expensive than conventional blasting, excavation by blasting using these products and technologies in relatively good quality ground is believed, in most cases, to be less than the cost of mechanical excavation. In this paper, the authors look at innovative trends in underground quarrying, underground commercial space and tunnelling and put forward their concept of future excavation demand, future product requirements and technical specifications to the drill and blast community.

Jan 1, 2007

By R Hindstr÷m

The demand for iron ore has increased dramatically in the last years and is forecast to remain on a stable high production level for years to come. ItÆs expected that the world economy is facing a stable continuous growth of iron ore to two billion tonnes and more over the next decades (Beddows, 2007). Furthermore it is expected that the existing and known high-grade ore resources will decline, and the iron ore industry will be forced to implement more and more advanced beneficiation plants. As a consequence of the more complex beneficiation requirements, there will be a need for modern solutions for iron ore dewatering that are reliable mechanically as well as cost effective and with high capacity per unit at the same time. Conventional vacuum filtration methods have been the most prevalent in fine iron ore dewatering. Product quality needs, lower ore grades, complex mineralogy and energy costs have resulted in iron ore producers seeking better solutions for dewatering, in particular pelletising feed. New advanced filtration methods have been introduced to the market. This paper describes how these modern methods are answering the needs of the industry. Performance of advanced dewatering technologies (pressure filtration and ceramic capillary action filtration) for iron ore applications has been studied, and the findings are based on both industrial and pilot scale experiences on different materials. For example, the results show that the cake moisture content of iron ore pelletising feed can be optimised more effectively by using modern filtration technologies. By selecting the most suitable and adjustable equipment, the effects of variations of feed material on downstream processes can be minimised and the possibilities of processing more difficult raw materials to high-quality pellets are better. The Larox Corporation develops, designs and manufactures industrial filters and is a leading technology company in its field. Larox is a full service solution provider in filtration for separating solids from liquids. As such, this paper compares the new developments in this market area with the prevailing known vacuum filtration technology, but focuses on a comparison between capillary action filters and rotary vacuum disc filters (RVDF). The trade name CeramecG is used to differentiate the Larox filter from the generic term.

Jan 1, 2007

The South Ghorveh Batholith (SGB) and the Almoughlagh Batholith (AB) intruded the volcanosedimentary sequence of Songhor Series (Triassic-Jurassic), during the Oligo-Miocene orogenic phase. The granitoids of the AB belong chiefly to the quartz-syenite and syenogranite clans while those constituting the SGB can be generally characterised as quartz monzonite varying towards quartz monzodiorite, and diorite. Granitoids constituting both the batholiths are low in free quartz, and possess characteristics of the æmagnetite seriesÆ, mostly of I-type, metaluminous to marginally peraluminous and calk-alkaline type. Adjacent to them are located the magnetite skarn deposits of Baba Ali and Gelali. In the light of petrography, geochemistry, mineralogy and field geology investigations they could be classified as Fe-skarn and mainly bear characteristics of calcic skarn deposits.

Jan 1, 2005