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APPROXIMATELY 90 per cent of the steel that is melted and refined in the United States and poured into ingots is made in basic open-hearth furnaces, as shown in Table 1-1. The annual ingot capacity of the steel industry reported January 1,1950, by the American Iron and Steel Institute8* was 99,040,160 tons, of which the basic open-hearth process accounted for 85,896,580 tons, 86.7 per cent of the total. The capacity of the individual furnaces varies over a wide range, a large majority falling within limits of 50 to 200 tons (Fig 1-1). Most of the units constructed [ ] since 1942 are in the larger size groups, between 175 and 225 tons capacity.

Jan 1, 1951

By Donald E. Cummings

Certain dusts are dangerous when inhaled, but most hazardous of all dusts are quartz or other forms of pure crystalline silica. The inhalation of dusts containing silica in combination with other elements gives rise to changes in the lung which differ from those produced by pure silica. As a generality, silicates are less dangerous than pure crystalline silica and vary greatly among themselves in harmfulness. Repeated analyses have shown that approximately 70 per cent of the total number of particles involved in any dust-producing operation are below 1 to 2 microns in diameter. (A micron is approximately 1/25,000 in.) Similar studies of dusts recovered from silicotic lungs post mortem have demonstrated essentially the same size frequency distribution, except that the upper limit of size retained in the air sacs is approximately 10 microns. Experiments carried on by Gardner and the author have further demonstrated that greater changes were produced by a fixed weight of very fine quartz particles (2 to 3 microns and smaller) than by the same weight of slightly larger particles (8 to 10 microns). Any attempt to control a dust hazard should therefore be directed toward the removal from the working atmosphere of particles less than 10 microns in size, and particularly those below 3 microns. All industrial hygienists agree on this matter, but there remains considerable dispute as to the lower limit of particle size capable of causing injury. It has been generally conceded, however, that particles of harmful dusts smaller than 1/4 to 1/2, micron are not essentially concerned in the development of pulmonary fibrosis. This opinion is partly substantiated by the existence of large numbers of these small particles in practically all atmospheres that are not associated with any known hazard. Such particles are so small that they have very little mass, fail to settle even in quiet air, and probably are not easily retained in the lung. Until further research proves that they are involved in the dangers provoked by the inhalation of certain dusts, engineers will generally agree that it is better to disregard them.

Jan 1, 1937

The Maas patent drill-hole compass, for determining the direction and dip of drill holes, is successfully used to a depth of 3,000 ft. APPARATUS FOR SURVEYING DEEP DRILL HOLES. The compass is placed in a thermos bottle or glass tube with hot liquid gelatine and lowered in a water-tight phosphor-bronze case, with a tube containing hydrofluoric acid. When the gelatine is cold the rods are pulled, the direction of the needle is marked on the tube which contained the acid, and the direction and inclination of the hole determined from this tube in a goniometer. There is nothing to get out of order and the compass can be used by any drill foreman, the mark and etching on the tube making a permanent record of direction and inclination. (See Fig. 1.)

Jan 1, 1916

By Earl Oliver

CONTENTS PAGE A.I.M.E. Stabilization Committee Activity 3 Definition of Capture Rule: Robert E. Hardwicke 4 Westmoreland Natural Gas Co. vs. DeWitt 5 Kelly vs. Ohio Oil Co 5 Bernard vs. Monongahela Gas Co 6 Definition of Ownership in Place 7 Prospective Stabilization Remedies 7 Dean Roscoe Pound's Four Tests of Practicability 7 I: Mechanically Feasible 8 Capture Rule 8 Ownership in Place 10 Mechanical Separation Method 10 Engineering Appraisal Method. 11 II. Economically Advisable. ., . 13 Capture Rule 14 Ownership in Place 14 III. Politically Wise 14 Capture Rule 14 Ownership in Place 17 IV. Legally Sound 18 Capture Rule 18 Ownership in Place 19 Dean Henry M. Bates' Analysis 19 Resume 22 THE A.I.M.E. Stabilization Committee was named in 1932 to ascer-tain whether some practical substitute could be devised for the Rule of Capture, which was generally credited with being the major cause of instability in the Petroleum Industry. After considerable intercommittee correspondence a letter was received from. E. DeGolyer under date of Jan. 25, 1935, in which he discussed the possibility of modifying rather than discarding the Rule of Capture. He summarized his proposal as follows:

Jan 1, 1937

By C. W. Wahsburne

Former studies of sedimentatry strata have been based upon the mineralogical and mechanical characters of the solid components, rather than upon the open spaces between them.

Jan 1, 1915

By Stephen E. Merritt, T. Carl Shelton

Surveying and mapping are used to locate and visually portray objects, lines, or areas in relation to a reference point or line. The actual making of the measurements to locate the objects and points falls under surveying while mapping is concerned with putting the survey information into a graphical form. Generally, the type or class of proposed survey depends on the precision required. Some surveys may need only approximate measurements which can be obtained by simply pacing or by using an ordinary measuring tape; others may require much accuracy, thus calling for the use of an engineer's transit or theodolite along with a graduated steel tape for horizontal measurements, or a level and a graduated rod for measuring vertical distances. Mapping is likewise dependent on accuracy requirements. For example, a general layout showing the relative position of surface facilities may not call for a large scale of dimension or great precision whereas for detailed work, a large scale plus care in plotting points and drawing lines and curves are important factors. SURVEYING METHODS There are many kinds or types of surveying methods. Some examples include: land surveying for determining boundaries of land areas ; route surveying for locating roads, highways, right-of-ways, and haulways; city surveying for laying out lots, streets, and alleys ; and mining surveying for projecting mine openings and locating mining operations. There are other types of surveying than those named, but in general, the type of method to be used will depend on the purpose for which the survey is to be made.

Jan 1, 1973

By Herbert Clark Hoover, Lou Henry Hoover

GEORGIUS AGRICOLA was born at Glauchau, in Saxony, on March 24th, 1494, and therefore entered the world when it was still upon the threshold of the Renaissance ; Gutenberg's first book had been printed but forty years before ; the Humanists had but begun that stimulating criticism which awoke the Reformation; Erasmus, of Rotterdam, who was subsequently to become Agricola's friend and patron, was just completing his student days. The Reformation itself was yet to come, but it was not long delayed, for Luther was born the year before Agricola, and through him Agricola's homeland became the cradle of the great movement ; nor did Agricola escape being drawn into the conflict. Italy, already awake with the new classical revival, was still a . busy workshop of antiquarian research, translation, study, and publication, and through her the Greek and Latin Classics were only now available for wide distribution. Students from the rest of Europe, among them at a later, time Agricola himself, flocked to the Italian Universities, and on their return infected their native cities with the newly-awakened learning. At Agricola's birth Columbus had just returned from his great discovery, and it was only three years later that Vasco Da Gama rounded Cape Good. Hope. Thus these two foremost explorers had only initiated that greatest period of geographical expansion in the world's history. A' few dates will recall. how far this exploration extended; during Agricola's lifetime. Balboa first saw the Pacific in 1513 ; Cortes entered the City of Mexico in 1520; Magellan entered the Pacific in the same year ; Pizarro penetrated into Peru in 1528 ; De Soto landed in Florida in 1539, and Potosi was discovered in 1546. Omitting the sporadic settlement on the St. Lawrence by Cartier in 1541, the settlement of North America did not begin for a quarter of a century after Agricola's death. Thus the revival of learning, with its train of Humanism, the Reformation, its stimulation of exploration and the re-awakening of the arts and sciences, was still in its infancy with Agricola. We know practically nothing of Agricola's antecedents or his youth. His real name was Georg Bauer (" peasant "), and it was probably Latinized by his teachers, as was the custom of the time. His own brother, in receipts

Jan 1, 1950

By S. S. Rumsey

Introduction IN order to realize the economies which would result in operating the mine pumps at the Chapin mine with electricity. generated by water power, the Oliver Iron Mining Co. recently installed a hydro-electric plant at the upper Quinnesee, falls on the Menominee river, and constructed a transmission line to the mine. On account of the large flow of water in the Chapin mine, and the great depth from which it has to be handled, it was necessary to make a thorough investigation of the merits of both the motor-driven centrifugal and motor-driven plunger pumps, in order that the most economical results as regards power, cost of installation, maintenance, and operation, be obtained. This investigation resulted in the selection of motor-driven centrifugal pumps, as the cost of the pumps and motors, installation, and maintenance was considerably lower, and the space required in the underground workings very much smaller, than for the plunger pumps. The overall efficiencies guaranteed by several of the centrifugal-pump manufacturers were so nearly those guaranteed by plunger-pump manufacturers that the saving in power which would result from the installation of plunger pumps did not justify their increased first cost and the increased cost of installation under the conditions prevailing at the Chapin nine. In order to substantiate the representations of the centrifugal-pump builders it was deemed necessary to insist upon a factory test of the completed units before shipment, the test to be conducted under conditions of head and capacity approximating as nearly as possible those under which the pumps would operate in service. Furthermore, it was considered necessary to demonstrate, by test, that there were no deficiencies in design or capacity of the pumps or motors before their final installation in the mine, as it would be extremely difficult to make alterations in the pumps or motors after they were installed.

Jan 10, 1914

OFFICERS AND COMMITTEES OF LOCAL SECTIONS AIME Committee on Local Section Affairs Roger Pierce, Chairman Carleton C Long Thomas C Frick AIME Committee on Student Chapter Affairs John P Nielson, Chairman John C Calhoun, Jr J R Van Pelt, Jr Council of Section Delegates A A Burr, Chairman (Hudson-Mohawk) Ralph A Watson, Vice-Chairman (North Pacific) L G Neely, Secretary (West Central Texas) INTERIM COMMITTEE M O Langham (East Texas), Fulton J Olivier (Delta), L W Smith (Niagara Frontier), G R Spindler (Central Appalachian) LOCAL SECTIONS (There are 78 Local Sections in the United States, 9 Foreign) ADIRONDACK Established June 18, 1952 Official year begins in April Meets fourth Saturday monthly, April through October Seven meetings annually Local Section Dues AIME Members $2, Nonmembers $3 Charles F Dievendorf, Chairman Severn P Brown, Vice-Chairman George E Erdman, Secretary-Treasurer Gouverneur Talc Co , Inc Gouverneur, N Y Malcolm V Lowry, '60, Section Delegate Committees Membership David J Crawford, Chairman Program Brower Dellinger, Chairman Student Affairs Eugene A Eastman, Chairman

Jan 1, 1959

A BLAST can be "full of sound and fury," signifying nothing but a poorly confined charge, or it can be a muffled, well controlled explosion which moves the rock efficiently and places it in the desired location with the least amount of fuss and bother. Why one method will do the job and another proves to be almost useless is shown by the machine-gun camera studies of quarry blasting made by the Atlas Powder Co. staff. The sequence, or machine-gun, camera is the latest scientific device for the study of cause and effect factors in blasting. Movie cameras, previously used, although of some use, were limited because slow shutter speeds and small negatives failed to give clear, sharp prints. During World War II, the AAF developed the sequence camera, which figuratively stops the blast at regular intervals, making study and evaluation feasible. The camera is simple and inexpensive and offers material for accurate examination of blasting techniques. The machine-gun camera takes three 5x5 in. exposures per sec at a 1/450 sec shutter speed, four times faster than a movie camera. Negatives are 30 times larger than those of movie cameras, giving large, sharp prints. The rock movement is frozen on the picture as the sequence of the blast takes place. Pictures on this page show the advantage of individual machine gun photographs. But the sequences made possible by this camera give graphic, dramatic and conclusive support to recently developed detonation theories.

Jan 1, 1952

By Victor Lenher

The interest shown recently in selenium and tellurium has brought many requests for an assembling of the analytical chemistry of these two elements. The intention of this paper is to discuss all of the chemical principles utilized in the detection and quantitative determination of these elements, as well as to describe the works methods actually followed by producers of tellurium and selenium in the United States. These methods have been furnished by S. Skowronski of the Raritan Copper Works, H. D. Greenwood of the United States Metals Refining Co., F. F. Colcord of the U. S. S. Lead Refinery, and E. W. Rouse and A. E. Hall of the American Smelting and Refining Company. Occurrence Selenium is found associated with sulfur, to which in many respects it is quite similar. Occasionally deposits of native sulfur, notably those in the Lipari Islands, Kilauea, and Japan, show a red-brown coloration, I which is readily distinguished from that of other sulfur; this red-brown * sulfur contains a small amount of selenium. Not infrequently, the , sulfides of the heavy metals are accompanied by selenium and tellurium, • presumably as selenides and tellurides. The Scandinavian pyrite, which is one of the large sources of European sulfuric acid, when roasted has fur- - nished a large part of the selenium that has come to the United States; it I was in flue dust from the roasting of Scandinavian pyrites that the element was discovered by Berzelius in 1817. Greek and Spanish pyrites also

Jan 1, 1923

By L. S. Darken

In the study of reactions occurring in liquid iron, alone or in contact with a liquid oxide or slag phase, it has been found that the experimental data over a limited range of concentration can in some cases be represented satisfactorily by the simple equilibrium expression where (P) denotes the concentration of a product and (R) the concentration of a reactant in the reaction r1R1 + r2R2 + • • • D P lP1 + P 2P2 + • • • Some of the reactions for which it holds are listed in Table 1. For others, however, the simple equation apparently does not hold. This has been attributed to an improper method of expressing concentration (for instance, weight per cent instead of mol fraction); or it has been supposed that the solutions are not ideal in the sense that the activity of a component is not proportional to its true mol fraction. But it may be that the problem has been oversimplified by neglecting some molecular species actually present; that is, by considering only the ostensible simple components and thus leaving out of account possible compound formation. It is the purpose of the present paper to point out how, in a group of related cases, a reasonable consistent assumption relative to the presence of a compound makes it possible to express the experimental data satisfactorily by the simple equilibrium expression when this compound is taken into account, and to bring into harmony data referring to different reactions in liquid iron. There are several a priori reasons for believing that solutions in liquid iron should not deviate far from ideality, provided that the concentration of solute is not too great and is expressed in proper terms. The factors that commonly lead to nonideality in systems at ordinary temperature— as ionization or the occurrence of polar and nonpolar molecules—are presumably less effective in inetal and in slag systems at high temperature. Again, the type of equation commonly used to express the value of

Jan 1, 1940

By Benjamin N. Webber

Many of the auriferous placers of the arid Southwest differ widely from the standard types of stream and eluvial deposits of more humid regions, although exhibiting some of the features of each. This divergence in characteristics is of geological and economic importance and appears sufficient to warrant the consideration of these placers as a class distinct from both stream and eluvial deposits. It is hoped that the consideration of these auriferous gravels as a distinct type of deposit will facilitate recognition of morphological and economic features that might remain obscure if these deposits were viewed in the light of stream or eluvial placers whose type locality is a more humid environment. "Bajada placer" is proposed as the designation for this type of placer deposit. Bajada is the Spanish term for slope and is used locally in the Southwest to indicate the lower slope of a mountain range, the portion consisting of rock debris and standing at a much lower angle than the rock slope of the range proper. It has been used in a geologic sense by Schraderl and others. The type locality of bajada placers is the Sonoran Desert,2 where they occur on the bajada or rock debris slope of desert ranges. Stream placers are represented in the Southwest, but most of them lie within the mountain topographic province, the Mexican Highlands2 section of the Basin and Range physiographic province. Eluvial placers may occur in the mountainous semiarid Mexican Highlands but are almost unknown in the extremely arid Sonoran Desert, as mountain slopes are generally too steep to permit the accumulation of any considerable mantle of residual debris. Since their salient distinctions are almost wholly the result of formation under conditions of extreme aridity, bajada placers are largely confined to the Sonoran Desert, although a few occur in the adjacent Mexican Highlands. They may be modified by the action of ephemeral streams, in which case the placer gravels of these arroyos approach stream placers in type and habit of occurrence, but their relation to an arid environment and the bajada type is usually apparent.

Jan 1, 1935

By Gerhard Derge, Arthur H. Grobe, Harold Markus

The high corrosion resistance possessed by tin under most circumstances, combined with its generally satisfactory appearance and useful physical properties, has led to many and varied uses for the metal. These uses have been partly limited by the fact that tin is an expensive metal, therefore many applications have been developed in which tin has been employed in combination with lead, either by coating, as in tin-lined collapsible tubes, or by the formation of alloys containing various proportions of tin-rich and lead-rich phases, as tcrne plate. A detailed knowledge of the corrosion characteristics of the tin-lead couple therefore is of general interest and has become specially important at the present time, when every effort is being made to conserve tin as much as possible. The present study has been limited to carbonate solutions with a pH range from 8.4 to 11.2 so that the results may be related to earlier work on the corrosion of tin and its alloys. 1-3,6 In these papers, the effects of a number of anion and cation additions to these solutions have been observed. Apparatus and Method The electrodes for the corrosion cell were cut from rolled sheet about 1/16 in. thick. The length of all specimens was held constant at 7 in., while the width was varied from M to 2 in. These electrodes were fastened to brass electrode supports, which were attached to rubber stoppers fitting into tall-type one-liter Pyrex beakers that contained the electrolyte. The lead electrodes were prepared from Omaha pig* and the tin was rolled from a slab of Chempur.† After cutting to size, the sheets were polished with No. I emery paper and cleaned with carbon tetrachloride. The edges, back and upper parts of the specimen were coated with a synthetic lacquer, which was supplemented with beeswax for the lead electrodes. The binding posts were coated with beeswax after the electrodes had been clamped. The pH of the electrolyte was controlled by adjusting the ratio of carbonate to bicarbonate. Approximately 600 ml. of electrolyte was used in each beaker. The entire assembly was placed in an oil bath thermostatically adjusted to operate at 30°C. + 0.1". Potentials were measured against a saturated calomel electrode connected to the cell by an agar-agar salt bridge. The carbonate solution used in the salt bridge was the same as that used in the corrosion cell. Currents were measured with a milliam-

Jan 1, 1942

By W. M. Rust, W. D, D. W. Mounce

The almost universal acceptance of electrical logging by the petroleum industry calls for a critical examination of the physical bases of the common methods. This is particularly needed for the natural potential log. The conventional explanations are based on the phenomena of electrofiltration and electro-osmosis. However, experimental data show that they fail to give a basis that is quantitatively sound. Moreover, they lead to interpretations of details of electrical logs that are erroneous. It was found experimentally that when a plug of shale is placed in a chain of dissimilar electrolytes, a current flow results. Experiments on oil-well cores and fluids similar to those existing in wells show that potentials are set up which are in reasonable agreement with those encountered in electrical logging. Doubtless other sources of potential are important but this explanation not only accounts for much of the potential but also clarifies some fairly familiar examples of misinterpretations. Introduction The extraordinary value of electrical well logging as a tool for petroleum engineers and geologists is now so uni- versally recognized that it is not necessary to point out the ways in which it can be useful. It is sufficient to mention only the saving that has resulted from the elimination of much coring that would have been necessary under former practices and the considerable additions to reserves resulting from the discovery of sands missed in coring. Paradoxically, the very remarkable success that has resulted from the application of electrical logging to correlation and completion problems has cost some of its most consistent users dearly.' The fact that some operators have placed unwarranted faith in erroneous interpretations of electrical logs does not reduce the value of the logs. It should, however, make one pause long enough to ask why experienced users should be misled. The answer to this question is not hard to find. In nearly every case, the fault has been oversimplification. This is illustrated very aptly by the familiar interpretation and theory of the natural potential log. Recording and Interpreting Logs The natural potential log is extremely simple to record precisely enough for all present-day uses. One needs only an electrode, a cable to lower the electrode through the drilling mud, a recording meter and a surface ground connection. The electrode can be elaborate but need not be. A simple brass rod 2 in, in diameter and 2 or 3 in. long is quite satisfactory. The cable need not be particularly well insulated, nor need it have a very low resistance. The recorder can be a vacuum-tube 1 References are at the end of the paper.

Jan 1, 1944

By Nicholas Kowall, K. L. Clark

Maximum furnace efficiency and close control of final steel composition demand that the steel melter be able to follow closely the variations in the carbon content of the bath. For many years, the fracture test has been used by melters for estimating carbon, because it requires only a very short time to pour a sample into a chill mold, cool it in water, break it with a sledge hammer, and observe the fracture. After long experience gained from the observation of such fractures, most melters are able to estimate the carbon content of steel with amazing accuracy, particularly in the lower carbon ranges. Notwithstanding the utility of the fracture test, there has been widespread interest in other methods for rapid carbon determination to supplement it and to ensure against possible errors in human judgment. Several methods, based upon measurement of magnetic properties as functions of carbon content, have been described in the literature1-6 and have been found to give reasonably reliable results in plant practice when scrap composition is known and controlled. A difficulty encountered in the use of analyzers of the magnetic type is that alloying elements do change the relationship between carbon content and magnetic properties and it becomes necessary to establish calibration curves for all the expected combinations of alloy residuals that are not oxidized in the bath. The work reported here is of an investigation of a method that is independent of alloying elements normally present in constructional steels, being based upon the relatively well-known fact that in plain carbon and low-alloy steels martensitic hardness is a function of carbon content alone. Work oF Other Investigators In I938, Burns, Moore and Archer published & curve? that showed that the hardness of martensite is a function of carbon from 0.10 to 0.50 per cent and is independent of grain size or alloy content, at least within the rallge found in construc-tional S.A.E. compositions. Some of the deeper hardening types investigated, however, contained carbon to a maximum of only o.2o per cent. Using this principle, Kern8 developed a method of rapid carbon determination for S.A.E 43xx steels, His procedure consisted of chill-casting a test bar that was large enough to give a a that could be prepared for Brinell indentations. The test piece was quenched immediately after solidi fication was complete and hardness readings were taken, so that the carbon content could he read from an experimentally determined curve giving the relationship between as-quenched hardness and carbon. Experimental Work Although Kern's work had been done with a relatively deep-hardening steel, it

Jan 1, 1944

By D. B. Masson

THE martensitic transformations occurring in ,B AgCd as a result of cold working at room temp.. a-ture and cooling below room ten1erature have been reported by Masson and Barrett.1 These authors found that simple cooling to 127°K caused body-cen-tered-cubic AgCd containing 53.0 at. pct Ag to transform to an orthorhombic structure, while mechanical deformation at room temperature was found to induce a hexagonal structure. Furthermore, they observed that the temperature at which martensite first appeared on cooling, Ms, and that at which the transformation was complete, MI, as well as the corresponding temperatures for the reversion on heating, As and Af, could be ascertained to ± 1°K, although they report these temperatures only for the alloy containing 53.0 at. pct Ag (51.96 wt pct). In the work reported here the temperature range of the transformation on cooling was studied as a function of composition, and further consideration was given to the relationship between the original bcc structure and the transformation-induced hexagonal and orthorhomic structures. EXPERIMENTAL PROCEDURE All samples studied were in the form of annealed 300-mesh powder and were prepared from the constituent metals in the manner described previously.1 The compositions in weight and atomic pct are listed in Columns 1 and 2 of Table I. Method of determination of transformation temperature was the same as utilized previously1—measurement of the intensity of X-rays diffracted by the transformation product. A diagram of the low-temperature sample mount is shown in Fig. 1. This mount was made to fit a GE model XRD-3 X-ray diffraction unit. The powder sample was varnished to a flat surface on a copper sample holder at A. This sample holder was soldered to a brass rod, B, which was in turn soldered to a second copper rod, C. Rod C could be cooled to 78°K by inserting it into a reservoir of liquid nitrogen, D. A heater coil of nichrome wire was wound at E on the sample holder, and by varying the current through the heater a thermal gradient could be maintained along brass rod B. Sample temperatures from 78°K up could be attained and held as long as needed. The sample holder and nitrogen reservoir were insulated by Styrofoam, F, and the sample itself was protected by two radiation shields, G. The X-ray beam entered and left the sample chamber through windoys in the supporting container at H and I. Sample temperatures were measured by a calibrated copper-constantan thermocouple varnished to the sample holder just out of the beam at A. The low-temperature structure had been found to possess orthorhombic symmetry1 and the expected positions of the diffraction maxima were known. Therefore the sample was aligned in the X-ray beam and the Geiger counter of the spectrometer set to receive the most intense orthorhombic reflection without an adjacent interfering cubic reflection. This

Jan 1, 1961

By Max Heberlein, R. P. E. Hermsdorf

The electrolytic refining of metals for the removal of undesirable impurities has become a recognized necessity in the nonferrous field. Copper, lead, zinc, nickel, silver and gold have been produced in this manner for years. The United States Metals Refining Co., realizing that considerable quantities of lead and tin could be made available to the trade if a satisfactory method of purification of these metals could be established, decided to investigate the possibilities of electrolytic solder. In cooperation with Dr. Edward F. Kern, of the School of Mines at Columbia University, the company developed a process of electrolytic refining of lead-tin alloys using a tin-lead fluosilicate electrolyte. A pilot plant was installed in November 1927, and the commercial unit was put in October 1929. Since that time thousands of tons of electrolytic solder have been produced in this plant and consumed by all branches of industry that use solder. Older Methods of Producing Solder In the early days practically all solder was made by melting together virgin lead and tin in the proper proportions to meet specifications; then the solder was cast into the commercial shapes required. Today the base of most solders comes from scrap or secondary materials. Ordinarily solder is produced from secondary materials either by sweating solder-bearing scrap or by smelting lead and tin-bearing drosses, residues and similar materials. When solder is produced from scrap by sweating, clear solder is collected directly. It is then given some kind of kettle refining and usually blended to specification with virgin metals before it is cast into finished shapes. In producing solder from drosses and residues, the materials are usually first given a reducing smelting treatment from which a crude solder is obtained. This crude solder may be refined in several ways, but usually the first step is a furnace liquation to remove the bulk of the copper, which is followed by one of the more or less complicated methods for the removal of antimony and other impurities.

Jan 1, 1937

By John D. Meahin

THE use of digital methods for generating crystallo-graphic data is well-established and many programs are now available. Transmission electron microscopy usually requires a knowledge of the electron diffraction pattern which is obtained by plotting a planar section through reciprocal space. With cubic symmetry these sections are very easily produced, but with hexagonal and lower symmetry systems considerably more labor is involved. Johari and Buchanan1 have written a Fortran program for generating standard projections and along similar lines we have produced a short but completely general program for generating any section through reciprocal space. The required inputs are the lattice parameters and angles for the real crystal. The Miller indices of the direction [U, V, W] parallel to the electron beam are then specified and the program will generate the Miller indices of the plane normals perpendicular to [U, V,, W] up to some specified integer. A subroutine can be inserted to test for forbidden reflections if desired. We have used such routines for fct and hcp crystals. As each permitted index is generated it is printed or punched out and no storage arrays are utilized in the computer. The normal diffraction pattern corresponds to the zero-order Laue zone, but with thin crystals or crystals of large lattice parameters the higher-order Laue zones may contribute to the diffraction pattern. Accordingly the program will generate successive Laue zones and project them onto the zero-order zone. The output of the program first lists the zone axis [C, V, W] and the Laue zone, and then gives a list of permitted reflections and the corresponding XP and YP coordinates of the reciprocal lattice point in angstroms-'. In addition, ZP, the perpendicular distance of the reciprocal lattice point from the (U, V, Ur) plane in reciprocal space is given, as is the reciprocal interplanar spacing. In the case of the zero-order Laue zone ZP is zero. A diffraction spot from the higher-order Laue zones will be very slightly displaced from the computed coordinates as its position in an actual pattern is given by projection along the diffracted beam2 and not along [u, V, w]. For any given electron wavelength this correction could be readily incorporated into the program, but as it only amounts to -1 pct it was decided to leave the program in its most general form, i.e ., a computation of points

Jan 1, 1970

By S. K. Nowak

The lithium solubility limit in solid aluminum was determined by the use of micro-graphic techniques. The solubility limit thus established was shown to be a true equilibrium by checking the reversibility of AlLi phase precipitation and dissolution around the equilibrium temperature. The experimental results fit a straight line by plotting log N(LI) against 1/T. The metallurgical reasons explaining the lack of agreement among previous investigations are discussed. THE solubility limit of lithium in solid aluminum was determined by Shamray and Saldau1 by micrography and by Grube et al.' and also Voss-Kiihler- by measurement of electrical resistivity. Since the addition of lithium induces extremely small changes in the aluminum lattice, X-ray techniques could not be employed for this purpose; in fact, the addition of lithium does not cause an expansion of the lattice as might be expected from a consideration of atomic radii, but causes a small contraction from 4.040 to 4.037A3, 4 when the solvent aluminum is saturated with this element. An analysis of the results from previous investiga-tions'" shows that with improvement of investigation techniques the solubility limit tends toward a lower lithium content. Again, some of the author's own experimental results on the action of atomic hydrogen on A1-Li alloys seemed to indicate that the solubility of lithium should be much lower, i.e., about 0.3 pet at 300°C: instead of 1.15 pet, the lowest published value.4 For the foregoing reasons it was decided to investigate this problem. The aluminum and the lithium used for this purpose were of the highest purity. The lithium solubility limit was determined by metallographic techniques, in particular by the use of a reagent especially developed for the purpose of revealing the AlLi phase. The solubility limit thus determined was shown to be a true equilibrium by checking the reversibility of AlLi phase dissolution and precipitation around the equilibrium temperature. All of the experimental work was carried out in 1951 at the Centre d'Etudes de Chimie Metallur-gique at Vitry, France, under the direction of Georges Chaudron.

Jan 1, 1957