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By Jie Li, Shu Yang, Zhongliang Tian, Xun Hu, Yanqing Lai

The purity of the electrolyte has an important influence on the content of the impurities in electrodeposited silicon. In this paper, effects of electrolysis temperature, current density and the time on the concentrations of two important impurities: phosphorus and iron in the electrolyte were investigated during the purification of Na3AlF6-10%K2SiF6-AlF3 melt. It was observed that the concentrations of P and Fe in the electrolyte decreased with the electrolysis temperature, current density and the electrolysis time increasing. X-ray fluorescence (XRF) of the electrolyte shows that the concentrations of P and Fe decrease from 4.2ppmw to 1.3ppmw and 204.0ppmw to 42.6ppmw, respectively. The removal rates of P and Fe are 69.08% and 79.12% when the electrolysis was performed for the duration of 3 hours and at a current density of 20mA·cm-2 while the operating temperature was 1225K.

Jan 1, 2015

By Qingcai Liu

The effect of the TiC addition on corrosion resistance of the Al2O3-C refractories in smelting reduction melts has been studied by quasi-station immersion and rotary immersion. The corrosion rate of Al2O3-C refractories is decreased with the TiC addition. The corrosion mechanism of Al2O3-C refractories is oxidization of graphite carbon by the oxides of the melts and the formation of deteriorate layer.

Jan 1, 2006

By Xiangru Chen, Honggang Zhong, Qijie Zhai, Qingqing Sun

"A horizontal directional solidification equipment, with an in-situ pouring system, was employed to physically simulate the solidification behavior of continuous casting. In this paper, the 2304 duplex stainless steel (DSS 2304) was investigated using this equipment due to its microstructure produced by continuous casting process was usually not satisfied. The grain size combined with the position of columnar to equiaxed transition (CET) of DSS 2304 were observed and the results showed these microstructure characteristics were very close to those of the continuous casting slabs. In addition, the influences of pouring temperatures and cooling conditions on the CET behavior were investigated. The results revealed that the length of the columnar grains decreased with decreasing the pouring temperatures and flow rates of the cooling water. Besides, the content of austenite decreases with increasing the distance from the chilled sidewall.IntroductionDuplex Stainless Steels (DSSs) have been widely used in industry for their excellent mechanical strength and superior corrosion resistance in Cl- environments when compared with other stainless steels [1,2]. Their good performances are mostly on account of the duplex phase structure-ferrite (d) and austenite (?) and the high proportion of alloying elements. Although, DSSs have good ductility, but worse formability compared to the austenitics, and this is the key to restrict DSSs application [3]. This is due to the differences properties between the two phases. The hot workability of ferrite (d) is better than austenite (?) and exhibits a lower flow stress during hot rolling processing [4]. The early workers had revealed that coalescent force of phase interface, microstructure, difference of mechanical property between two phases and the precipitations are the main factors affecting the formability of DSSs [5,6]. Another important reason that affects the alloy’s mechanical properties is columnar to equiaxed transition (CET) [7]. It often occurs during continuous casting solidification process and induces inhomogeneous mechanical properties and the microstructure varies with different processing parameters, such as pouring temperatures, cooling conditions (water flow rates in the cooling zones) and casting speed [8]."

Jan 1, 2012

By KNona C. Liddell

The time and spatial dependence of component and species concentrations during in situ uraninite leaching have been modeled using a reactive transport model based on partial equilibrium between reactive minerals and the solution. The flow field is represented by mixing cells in series. The effects of the H2O2, (NH4)2CO3, and NH4HCO3 component concentrations have been simulated, and results are presented for a one-dimensional flow field.

Jan 1, 1995

By Michael K. Rhodes

A 120 tonne per day BacTech bacterial oxidation plant treating refractory gold concentrates for Gold Mines of Australia's Youanmi project in Western Australia commenced operation September 1994. This was the first commercial application of the BacTech process. A pilot plant trial on concentrates produced from Youanmi ore was carried out at BacTech's laboratory in Perth. Results and measurements from this trial were used by Signet Engineering Pty Ltd to design the commercial plant. This paper cover the results obtained from the piloting, their implementation in the plant design and the initial commissioning of the full scale plant.

Jan 1, 1995

By S. I. Sobol

Completeness of cobalt recovery from slag requires decomposition of maggemite and non - ferrous metal desorption with polymerized silicon-acid. Cobalt losses are reduced in leaching tai1s up to 200 g/t of iron.

Jan 1, 1993

By K. Yamaguchi, Y. Takeda

"Partial pressure - temperature - composition correlation diagrams of the Ga-As, In-As, Ga-P and In-P systems were contracted based on the obtained experimental data of the phase diagram and thermodynamic properties for the III-V systems. The total vapor pressures of arsenic or phosphorus at melting point of GaAs, InAs, GaP and InP were determined as 101, 10.1, 1510 and 253 kPa, respectively, at the corresponding melting points of 1509, 1211, 1739 and. 1336K , These diagrams are applied to the analysis of the horizontal Bridgman method and the liquid phase epitaxial growth technique. On the other hand, the analysis of the equilibrium state of the. chloride-CVD process was carried out using the data of the Gibbs energy of the compounds obtained by· authors.IntroductionThe group III-V compound semiconductors ate important materials used in optoelectronic liquid high speed electronic device. The crystal growth of the III-V compounds can involve processes that require contact between the solid, liquid and vapour phases at near equilibrium condition. Examples of processes that involve contact between the solid, liquid and vapour phases include bulk crystal growth such as the horizontal Bridgman and the liquid encapsulated Czochralski method and liquid epitaxy, and between the solid and vapor include chemical vapour deposition and molecular beam epitaxy. Therefore, the knowledge of the phase diagram and thermodynamic properties for the III-V binary alloys is essential for the analyses of crystal growth techniques of III-V compounds.For these reasons, a series of different · types calorimetric measurements had been carried out: (1) The heat contents of alloys for the Ga-As, In-As, Ga-P and In-P systems by a drop calorimeter [1;2,3]; (2) the heats of formation of the GaAs, InAs, GaP and InP compounds by a twin solution calorimeter [4]; and (3) the standard entropy of these compounds by an adiabatic calorimeter [5]. Based on the third law method, the Gibbs energies of these compounds were derived from the heat capacity, standard heat of formation and standard entropy data obtained by authors. Integral molar thermodynamic quantities of the liquid III-V .alloys were also determined from combining the heat contents of alloys with standard heat of formation and standard entropy data of the compounds· by applying the thermodynamic analysis method developed by Oelsen [6]. In the present study, the thermodynamic calculations for the crystal growth processes of the III-V compound were carried out using newly experimental data of the phase diagram and thermodynamic .properties measured by authors"

Jan 1, 2000

By Daoxin Wu, Zhong Cao, Yan Shi, Yu Ding, Huanli Yang, Zhongliang Xiao

"2-substituted benzimidazole-zinc and 2-substituted benzimidazole-copper complexes were main components of organic solderability preservative (OSP) in PCB producing process and affect the thermal stability of OSP film. So these four complexes were prepared by 2-substitutedbenzimidazole reacting with zinc ion and copper ion, the complexes crystals were determined by IR, its thermal stabilities were studied by TG method. The results indicated that the thermal stability of 2-substituted benzimidazole-zinc is higher than the 2-substituted benzimidazole copper,and the thermal decomposition mechanism was presentedIntroductionImidazole compounds which is an important heterocyclic compound shows the important value and outstanding prospects[I-3l in field of biological engineering, medicine, and high-performance composites. It's said that imidazole compounds is an excellent new metal surface treatment[4] agent, because it has good reaction activity with metals and can form a chemical layer on the metal surface. The complexes of imidazole were main components of organic solderability preservative (OSP) in PCB producing process and affect the thermal stability of OSP film. The mechanism of imodazole combined with metal and film deposited has been reported, but the opinions about thermal stability of film have bifurcation, let alone the thermal decomposition mechanism of film at high temperature. The complexes were prepared by combining of 2- substituted-benzimidazole with zinc and copper iron, which were studied by IR and TG method, in order to get thermal stability of different complexes."

Jan 1, 2011

By Fumio Hashiuchi, Yushiro Hirai, Masatoshi Maeda, Toshihiro Nagata

"Increase in the copper smelting capacity at Saganoseki Smelter & Refinery was attained through various improvements in the PSconverters and the flash furnace. Two of the major innovations in the converting process were: a new operational technology which avoids increase in the copper content in the converter slag even when higher copper grade matte (65%) are treated in the slag making stage and a technology which shortens the operational interruption time which is caused by coolant charging. The latter was realized by introducing a new automated coolant charging system with which it was made possible to charge the coolant without stopping the blowing into the converter. These improvements brought about a remarkable increase in · the production capacity per converter and an annual production of 450,000 tons of copper without adding new furnaces was made possible. In addition, good results have been obtained of the tests with modified tuyeres to further increase the production.IntroductionIn a bid to renovate its Saganoseki Smelter & Refinery and to establish a leading production unit in terms of global competitiveness, Nippon Mining & Metals undertook major restructuring efforts since 1994. One of its themes was the shift from· a two-flash furnaces operation to a single-flash furnace operation. The shift was successfully completed in 1996 while maintaining the production at the same level (330,000 tons per annum of copper). Then, the productivity was enhanced to 450,000 mtpy without adding new furnaces through technological and operational improvements. It is now planned to increase the smelting capacity further to 470,000 mtpy this year.Some technological and operational improvements in the matte converting process and the new plan resulted from the tests with modified tuyeres are presented in this paper."

Jan 1, 2000

By M. A. Halim, V. I. Lakshmanan, T. Sheikhzeinoddin, R. Roy

"Chloride metallurgy is emerging as an alternative process for the production of base metals. Process Research ORTECH Inc. (PRO) has been at the forefront of technological development of chloride metallurgy. PRO has developed an innovative technology for the production of high purity titanium dioxide, iron oxide and vanadium pentoxide from ilmenite ores and concentrates. PRO is also developing its proprietary mixed chloride technology for the extraction of vanadium from other sources such as oil shales. In this paper, results from the test work conducted at PRO for the extraction of Ti and V using a mixed chloride lixiviant are presented.IntroductionTitanium and vanadium alloys and compounds have numerous industrial applications. Titanium dioxide is used in paints, plastics, rubber, paper, inks, textiles and a number of other miscellaneous applications. Currently nanosize T1O2 is being investigated for application in the cosmetics industry. Inorganic sunscreens mainly use T1O2 or ZnO particles, which reflect and scatter ultra-violet light. T1O2 nanomaterial is also finding application in smart construction materials and coatings, as a photo-catalytic converter. Nano TiO2 can catalyze the dissociation of NOX gases and other automotive emissions, thereby reducing the smog in urban centers. After the construction material is exposed to sunlight or ultra-violet light, the T1O2 is photo-activated and degrades the pollutants.Titanium metal and titanium dioxide are produced from ilmenite (FeTiOs) or rutile (naturally occurring T1O2) ore. Only about 6% of the titanium resources are used to produce titanium metal and the rest is used to produce T1O2. Many of the titanium ore deposits currently have unacceptable levels of transition metals which limits their processing by conventional routes."

Jan 1, 2012

By C. Acuna

The standard procedure of fire refining consists of sulphur removal via air injected through tuyeres, arsenic slagging via soda-lime flux and oxygen reduction by air or oxygen deficient air or a steam fuel mixtures. The use of porous plugs to stir with an inert gas has been mainly considered as a surface renewing agent that increases the product quality and shorten the refining cycle. In the present study the effect of the bottom stirring by nitrogen gas injection through porous plugs for the treatment of the crude copper in the range of 400-150 ppm sulphur, 3,000?2,000 ppm arsenic and 14,000-7,000 ppm oxygen content was investigated. The combined effect stirring-reducing, by the use of air or a steam fuel mixtures through tuyeres for oxygen removal, follows a kinetics of first order where the constant, K, can be represented by the following polynomial expression: K = A .* R2 + B * R + C Where A, Band C are constants that depend on the nitrogen flow rate and R is the air-fuel ratio or the steam-fuel used in the reducing step. Depending on the optimization of the flow of nitrogen and the air-fuel or steam-fuel mixture and only if just the oxidation, complexing and reducing steps are considered, the process cycle might be shortened by 45%.

Jan 1, 2003

By Masayoshi Matswnoto

The Kosaka Smelter and Refinery produces copper and lead, and has a history of more than 100 years as a metallurgical department of Dowa?s Kosaka Mine. The Smelter treats complex sulfide concentrates which are difficult to smelt. Valuable metals are recovered using various processes developed by Kosaka Smelter and Refinery. Effluent waters from the smelter contain large quantities of heavy metals. This paper describes how Kosaka Smelter and Refinery recovers valuable metals from various effluent waters and handles overall waste waters in order to meet strict environmental standards.

Jan 1, 1993

By Rolando Campos

In August 1993, the operation of Refimet Chile's copper custom smelter commenced at La Negra, near Antofagasta in northern Chile. Design smelter throughput corresponded to 235 000 tonnes of concentrate, calcines and copper cements arising from suppliers in the north of the country to produce 90 000 t/y of blister copper. Refimet had initially gained experienced in building and operating leaching, roasting and a blast furnace facility at Rungue, near Santiago, followed by Roasting at La Negra. The initial smelter project was based on conventional reverb- smelting and Peirce-Smith converting and the majority of equipment was 'purchased second-hand and rehabilitated or modified. After only 3 years in production, the treatment capacity was significantly improved by introduction of technical improvements to the original plant operating scheme. Recently, the plant was further expanded to an annual smelting capacity in excess of 400 000 t/y feed, corresponding to around 160 000 t/y copper production. This expansion, referred to as Phase 2, was achieved by modification of the reverb to oxy-fuel firing, addition of a further (second-hand) acid plant, fire refining and anode casting facilities. Parallel development of concentrate injection into enlarged converters-also took place. Following successful commissioning of Phase 2 expansion, initial engineering studies for a third expansion phase have been completed. This aims to use leading technology based on bath smelting of bone-dry concentrates in a Continuous Reactor. This paper provides an overview of the relatively short plant history, its development and improvements together with operating indices achieved.

Jan 1, 1998

By Byung-Su Kim

The recovery of elemental sulfur from sulfur dioxide has important implications for coal- burning power plants and nonferrous metal smelters. The thermodynamic analyses showed calcium sulfide to be suitable for recovering elemental sulfur from sulfur dioxide. At the temperatures of 1023 to 1153 K under the sulfur dioxide partial pressures of 5.0 - 60.1 kPa, elemental sulfur from sulfur dioxide was recovered by its reaction with calcium sulfide. The kinetics of this reaction were measured at the same conditions using a thermogravimetric analysis technique. This reaction scheme would be attractive if the coproduct calcium sulfate can be reduced to regenerate calcium sulfide. This is the topic of another paper. At 1073 K under the sulfur dioxide partial pressure of 25.8 kPa, 48 % of the original calcium sulfide was converted to calcium sulfate in an hour. Under the same conditions, 55 % of the regenerated calcium sulfide were converted to calcium sulfate in an hour even after third regeneration.

Jan 1, 1999

By William E. Torres

The Southern Peru Limited smelter, in Ilo, operates two reverberatory furnaces, seven Peirce-Smith converters, one Teniente Converter, two casting wheels and a single contact acid plant. The Teniente Converter was commissioned in August 1995 and was designed to smelt 744 dry metric tons (820 dry short tons) of concentrate per day. The process off-gas is collected in a water-cooled hood, cooled in a spray chamber, and cleaned in a Joy electrostatic precipitator for further treatment in the Acid Plant. This paper presents the current Teniente Converter operating practices and control philosophy. Relevant improvements and modifications to achieve a 379 day campaign without tuyere replacement and a daily average smelting rate of 862 dry metric tons (940 dry short tons) of concentrate are discussed.

Jan 1, 1998

By Minh H. Pham

This paper presents a technique for imaging the extent of solidification of molten metal flowing in a cooled pipe based on the concept of eddy currents. A 3D mathematical model, which relates the geometry of solidification to the scattered field induced in a solenoid external to the pipe, is derived. The model is described by a set of integral equations which are solved numerically using the moments method. An iterative algorithm is developed to reconstruct the solidification distribution image. Experimental measurements have shown that the eddy current technique is sufficiently sensitive for practical purposes.

Jan 1, 2001

By Luísa Maria Abrantes

Environmental control is becoming more and more stringent. As conventional processes for zinc production are pollutant routes, alternative methods have become an important subject of research. In this regard, the leaching processes have aroused a considerable interest, namely the electrochemically induced approach. The behaviour of zinc concentrate ore in the leaching processesses is influenced by several parameters. Chloride concentration and leaching solution pH, time and temperature of reaction were studied in order to evaluate their influence on the zinc recovery. The efficiency of the leaching process for zinc extraction is performed by factorial design. The experiments were carried out by 23 and 22 factorial designs of the factors. Results show that all factors, except for the time of reaction have a significant influence on the optimisation process, within each experimental region.

Jan 1, 2001

By Garrett May

We present a periodic technique for measuring the thermal conductivity of thin, disk-shaped samples. In samples of this type, temperature measurements must be made across the sample faces and are therefore subject to large error due to the interface resistance between the temperature sensor and the sample. The technique uses measurements of the amplitude and phase of the periodic temperature across both a reference sample and the unknown material at several different frequencies. Modeling of the heat flow in the sample allows the simultaneous determination of the thermal parameters of the sample as well as the interface resistance. The technique is demonstrated on nanocomposite samples less than 1.0 mm thick.

Jan 1, 2008

By Hector Henao

To provide thermodynamic data for converting the nickel matte to liquid nickel, an experimental study was conducted in the phase equilibrium between the Ni-S alloy and the CaO-Ah03 based slag melted in a MgO crucible at 1873 K under controlled Pso2 of 10.1 kPa and pO;, in a range between 2.5x,IO,2 and 10.1 Pa by using CO-C02-S0Z gas mixtures. The content of nickel in the slag at POz of 10.1 Pa, above which solid NiO is expected to precipitate in the equilibrium state, was found to be 4.1 mass% and the contents of sulfur and oxygen in the nickel melt were 0.4 and 0.2 mass%, respectively. It was clarified that increase in the temperature reduces the solubility of nickel in the slag and the contents of sulfur and oxygen in the alloy. The distribution of minor elements such as gold, silver, copper, cobalt, iron, arsenic and antimony between the Ni-S alloy and the CaO-AI20) based slag was also studied. The distribution ratios of iron and cobalt, defined by (%X in slag)/[%X in alloy] where X is the minor element, are larger values than that of nickel, while those of copper, silver and antimony are similar to that of nickel. The distribution ratios of arsenic and gold are lower than that of nickel in the higher range of oxygen partial' pressure.

Jan 1, 2003

By Susumu Imashuku

A pseudoternary phase diagram of the BaO?ZrO2?ScO1.5 system is established and the conductivities of the scandium-doped barium zirconate are measured in wet conditions. According to the phase diagram, the molar fraction of scandia in the barium zirconate phase that equilibrates with the cubic zirconia (ZrO2) and scandia (Sc2O3) phase is 0.03. On the composition line, where the molar fraction of barium oxide (BaO) is 0.50, the solubility of scandia into barium zirconate is 0.27 as a molar fraction of scandia. At around 500 °C, the conductivities of scandium-doped barium zirconate are estimated to be almost same as that of yttrium-doped barium zirconateThe activation energies for bulk proton conduction in scandium-doped barium zirconate (0.57 eV for BaZr0.90Sc0.10O3-d) are higher than that of yttrium-doped barium zirconate (0.44 eV for BaZr0.90Y0.10O3-d). In addition, the bulk conductivity of scandium-doped barium zirconate in this study is 10 times higher than the reported conductivities in the temperature range of 75 °C to 300 °C.

Jan 1, 2006