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By Hsu-Hui Hsing

In several previous studies from this laboratory (1-4) the autophobicity concept of Zisman and co-workers (5, 6) has been extended to gas phase adsorption processes. Low molecular weight alcohols adsorb on silica or alumina to yield novel isotherms in that monolayer adsorption occurs at low relative pressures indicative of strong bonding, but subsequently multilayer adsorption is quite sparse and diminishes with molecular weight of the alcohol. Such isotherms fit no standard classification scheme, however, in the vacinity of monolayer coverage alcohol isotherms give an excellent fit to the Langmuir or B. E. T. , Type I model (7). Monolayer adsorption is relatively irreversible and it is thus possible to prepare these chemisorbed layers and perform subsequent adsorption studies thereon. All indications are that the adsorptive properties on such films is radically different from that on the underlying alumina (4, 8) and in one study finite contact angles for hydrocarbon fluids were observed. One perennial conceptual difficulty is that there is no observed upper bound to the adsorption isotherm which would be necessary for autophobic adsorption to occur. The cause for this has been studied, and it is currently believed that adsorption is complicated by reversible capillary condensation at contact points between powder particles. The evidence for this is that large particle powders give less "apparent" adsorption at high relative pressures and in one very tedious study adsorption on planar sheets, oxidized aluminum displayed similar reduced uptake at high relative pressures when compared with high specific surface area powders (3).

Jan 1, 1974

By Wescomb R. Jones

The United States is the world's largest producer of hydrofluoric acid (HF), with its 1971 output of 317,000 short tons representing about 40 percent of the estimated Free World production. U. S. production has increased over five fold in the past 20 years, with a growth rate of about 7 percent per year between 1960 and 1970. However, the growth rate to 1977 is expected to be less than 5 percent per year, due primarily to a reduced rate of growth in requirements by the aluminum industry and an expected increase in imports from Canada and Mexico. This discussion will include our analyses of the consumption pattern for HF in 1972 and the factors influencing the demand forecast for 1977.

Jan 1, 1973

By Peter C. Ashbrook

The Regional Copper-Nickel Study was initiated in large part because of fears that copper-nickel development might cause adverse effects on the environment from air pollutants such as sulfur dioxide (SOZ) emissions from a smelter, and water pollutants such as acid mine drainage. The Study comprehensively examined the potential for ad- verse effects on the environment and possible mitigation measures on both a local and regional scale by first characterizing existing air and water quality, and existing sources of pollution, and then developing hypothetical development scenarios to model potential adverse effects. This paper gives a brief overview of the Study's findings concerning air and water resources.

Jan 1, 1980

By W. E. Benton

Diatomite or diatomaceous earth is a siliceous sedimentary rock principally made up of the skeletal remains of the diatom, a microscopic, single-cell aquatic plant related to algae. The unique structure, chemical stability and physical properties are the major attributes of diatomite not met by other forms of silica. The production of diatomite was down in 1982 vs. 1981, reflecting the worldwide recession. The principal markets for diatomite products continue to be basically filtration and fillers. The outlook is for small but steady growth into the 1990s.

Jan 1, 1983

By J. Harrison Daniel

More stringent dust standards, because of quartz in coal, have become a major compliance problem for the coal industry. Reducing quartz levels has become the major focus of the Bureau of Mines dust control research program. Results to date have identified hath the sources of quartz and prospective control technology. Control techniques are being developed for both room-and-pillar and longwall mining underground operations. Techniques include changes in face ventilation, mining cycle modifications, and better roof bolting dust control.

Jan 1, 1985

By L. Barry Phelps

Selective placement of toxic mine spoil has been advocated as a means of reducing environmental pollution at the source. However, methods of burial to control environmental damage are not well understood. Using the finite element method, this paper investigates the burial of toxic material within low permeability packages below the water table. The effects of differing package and spoil permeabilities, anisotropy, and infiltration are modeled to provide information about their effect on the flow system. Projection can then be made which will assist in the design of the toxic spoil packages to limit the amount of groundwater flowing through them.

Jan 1, 1983

By T. Hackett

Western underground coal reserves are tremendous, but recovery in western seams can be poor because of mining problems caused by deep cover, geologic anomalies, and thick seams. For instance, many seams contain a rock parting too thick to be extracted economically with the coal. This forces the operator to mine the coal above or below the parting. Subsequently, the rock pressures induced by mining make the part left difficult or impossible to extract by standard mining methods. Because upper and lower parts of the seam are frequently of minable thickness, the presence of rock partings can result in a significant loss of coal. Given a longwall recovery of 60 pct and equal thickness for the two parts of the seam, overall recovery is reduced to less than 30 pct if one part only is mined. The coal left in place is unavailable to meet the nation's energy needs, or to produce revenues for coal companies or government. [ ] Multi-slice longwall mining has the potential to recover the portion of split seams that are now left in the mine. Using superimposed standard longwalls with chain pillars, overall recovery could be doubled, depending on panel and pillar widths. Using a combination of advancing and retreating longwalls in descending slices, overall recovery could be improved to more than 80 pct. Because of the potential for improved recovery, the Bureau of Mines is analyzing the ground control factors affecting multi-slice longwall under western mining conditions and is conducting field trials at a planned multi-slice operation.

Jan 1, 1987

By R. J. Caine

Like most major firms engaged in project management, Dravo Corporation faces a constant challenge to keep its management systems in tune with the ever-increasing demands imposed by larger and more complex projects. This paper suggests that one of the key elements in meeting this challenge is more effective organization of project data. It reveals some of the details of a program at Dravo's Minerals 6 Metals Division which seeks, through better organization of project data, to improve Dravo's capabilities in estimating, cost control, scheduling, performance reporting and material control. In particular, this paper discusses ideas Dravo is developing for improved job numbering, codes of accounts, requisition and purchase order numbering, inventory cataloging, and employee/badge numbering.

Jan 1, 1980

By Carlos Viramontes Aldana

Mining in Mexico is one of its post traditional activities, whose influence in the development of important cities and communications has been decisive. Precious metals and, to some extent, copper and tin were known and used before the Colonial period, but from the sixteenth century to tie end of the nineteenth century, mining and metallurgical industries were concentrated in the precious metals, mainly silver. This silver was exported to Spain and other countries under the Spanish. Rule, Mexican peso was known world wide since the end of the sixteenth century and Mexico ranked as the first silver producer since the eighteenth century.

Jan 1, 1985

By B. A. Kennedy

The instrumentation, monitoring, and prediction of a major slope failure at the Chuquicamata mine are described. In December 1967, pre-existing tension cracks on the south end of the east wall of the Chquicamata mine began to open. Various forms of instrumentation were installed for continuous monitoring. These systems included tension crack stakes, crack extensometers, linear extensometers, tape and transit lines, sliding wire contacts, and a seismograph. From the information obtained, the failure date was accurately predicted some five weeks before failure, enabling the mine to reroute truck and rail access; hence, causing a minimal mine shutdown of two and one-half days and preventing any injuries to persons or damage to equipment. The shape and form of the sliding mass are analyzed, as are the possible modes of failure.

Jan 1, 1970

By John C. Brower

Bolivia is nor a major gold producer but has produced continuously since pre Inca times. Production reached a peak in 1964 of about 4,000,000 grams and is currently about 1,000,000 grams. Production is mainly from the Tipuani River valley north of La Paz and is derived from Pleistocene basin fill: the Cangalli conglomerate and overlying terraces. Abandoned Pleistocene lake terraces south of La Paz in the Oruro area are another source of gold whose potential have not been realized. In both the Tipuani and Oruro areas, primitive hand methods are the principal means of production, with the exception of a single modern dredge. In spite of a long history of production, probably very little of the gold potential has been mined.

Jan 1, 1979

By J. P. Morgan

The Vesta Preparation Plant of the Jones & Laughlin Steel Corporation is located on the Monongahela River, eight miles south of Brownsville, Pennsylvania. This plant is capable of cleaning 2400 NT/hr of a mixture of Pittsburgh seam high volatile coals from the Vesta and Shannopin mines to produce a metallurgical coal of 6.75% ash and a steam coal containing 14% ash. Heavy media vessels are utilized to upgrade the coarse coal while launders and tables. handle the -1/4" fraction of the raw coal feed. Cleaned -coal goes to boot classifiers where the +48 mesh material settles and is removed by bucket elevators. This 1/4 x 48 mesh material is then sent to centrifugal driers for dewatering. As designed, the minus 48 mesh fraction overflows the boot as a 7 to 8% solids slurry and is recovered by cyclones and a thickener and dewatered by filtration. The-products of the heavy media circuit, the launder-table-boot-drier circuit and the cyclone-thickener-filter circuit are combined to constitute the shipped metallurgical coal. This Vesta-Shannopin mix is combined at J&L's Pittsburgh and Aliquippa Works with purchased low and medium volatile coals for the production of metallurgical coke.

Jan 1, 1962

By R. A. Matuszak

U.S. Government sponsored studies proclaim large reductions in surface mine productivity. Consulting studies place a large share of the blame on increased governmental regulatory activities and on inexperienced, improperly train people. Union rules, which allow indescriminate bidding for job openings, seem to be a major factor causing the lack of experience in spite of elaborate training programs.

Jan 1, 1982

By E. H. Ahrens

This paper deals with the daily work of operating geologists and should be of interest to recent graduates. Working with development and production is quite different from exploration and many of the required skills and techniques must be learned on the job. Try to obtain your first position at a mine where good geological work is being done because it is important that you establish a solid foundation by learning valid techniques. Many do not! Those who desire to work in exploration are well advised to spend the initial two or three years at an operating mine where they will deal daily with an orebody during development and mining. Attempt to understand the controls of ore deposition and be interested in all phases of the operation. Learn something about factors which can adversely affect profitability and you will be a better explorationist.

Jan 1, 1983

By Michael Werner

A three-way research program, facilitated by the U.S. Bureau of Mines Generic Institute funding, conducted by Hecla Mining Co., Spokane Research Center of the Bureau and the University of Idaho, shows that a cooperative effort to solve difficult mining problems should be considered. A five-year plan to change an overhead cut-and-fill mining system to a longwall undercut-and-fill involves more than twenty people from three organizations. The investigations will eventually include, ground stress, stress analysis, fill selection placement and compaction, ground and fill support, underhand mining and materials handling, access, ventilation, equipment selection and synthesis and operations and cost simulation.

Jan 1, 1985

By D. W. Alberter

I consider it a great pleasure and distinction to be invited to appear before your organization to discuss our experiences with a comparatively new system of what is known as a "Full Dimension" extensible conveyor system. One of these systems has been operating in our Diamond Smokeless Mine, Boltz, Pennsylvania, since 1959 servicing a continuous mining machines For those of you who are not familiar with this method of transportation, I would like to offer an explanation.

Jan 1, 1962

By L. A. Clark

Although vein-, syenite-, and pegmatite-type deposits are known in Saskatchewan, recent intense exploration stems from discovery of several exceptionally high grade uranium and uranium-nickel deposits locallized near the basal unconformity of the 1.3-1.4 b.y. Athabasca Sandstone Formation. Graphitic basement rocks and post-Athabasca faulting or brecciation coincident with the unconformity are important in locallizing uranium deposits which form as tabular, shoe lace-like bodies with grades averaging over two percent and containing up to 50,000 tonnes U308. Some deposits have similar nickel contents. A few published sandstone analyses average 0.8 ppm uranium while basement granitoid and meta-sedimentary rocks vary from 0.5 to 20 ppm. In the proposed genetic model, traces of uranium are leached from these rocks by oxidized formation waters sweeping through the sandstone and along faults. Solutions are reduced and uranium is precipitated as basement graphitic meta-pelites are encountered along brecciated fault zones.

Jan 1, 1979

By Joseph S. Malesky

The discovery and development of explosives mark one of the most important findings in the history of civilization. Without explosives our vast economic enterprise concerning the mining of coal, copper, iron, aluminum, and various other ores could not function. Explosives are used in all kinds of construction works, in the razing of old buildings, blasting of trenches, driving of tunnels, and in many other instances common to our everyday life. For these reasons explosives are rightfully referred to as the forerunner of progress. An explosive may be defined as a substance (usually a mixture) that, when flame or shock is applied, yields readily to rapid combustion or oxidation, accompanied by the formation of such relatively large quantities of gases as to produce much violence and pressure which, in turn, react against their surroundings and cause what is termed an explosion. By their very nature the action of explosives is destructive and disruptive of adjacent materials. Decomposition of explosives can occur through deflagration, which is rapid burning or combustion, as in the case of black powder, or through detonation, which is an almost instantaneous disruption, as in the case of dynamites and blasting agents.

Jan 1, 1981

By Gene Mattila

Each installed rock bolt costs in excess of 520.00. High cost in conjunction with the primary purpose of safety makes it only logical to install the highest quality anchors possible. Each bolt has designed support capabilities in axial, shear and fluctuating ground condition, if installed to manufacturers recommendations. The quality of anchor is not; however, only affected by material specifications, but by transportation, handling storage, installation procedure, machine performance and geology. The quality is not only affected by many variables, but reliability should be assured. Non-destructive methods of testing reliability are only available for several types of bolts.

Jan 1, 1985

By Richard L. Ash

Less than optimum production in mining always results when poorly blasted material is provided at loading points. More often than not the cause is due to blasting founds that fail to fully control and utilize explosive energy. In many cases the problem exists because too few blasters understand how blastholes actually break rock and recognize that blasting is a three-dimensional process in designing their blasts. To better understand how blasts can be more effectively designed the two major rock breakage processes are described. In addition, the respective contributions of the borehole and detonation pressures are defined as are the specific roles of the several important blasting design variables. The concept of stiffness as an engineering principle and its significance in blasting design is introduced for explaining the breakup of rock. Basic guidelines for affecting control over fragmentation and side effects like over-break are offered.

Jan 1, 1975