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By R. C. Bunge

The selective flotation of semi-soluble salts with fatty acids is often negatively affected by the interaction of the potential determining cation with the ionic surfactant in bulk solution. This problem can be avoided by floating at low pH which involves the emulsification of the collector. The research presented here focuses on the influence of the Ca2+ ion on the flotation of fluorite with palmitic acid at low pH. Our results show that the surfaces of collector emulsions are dominated by precipitation phenomena similar to those encountered in bulk. In turn, fluorite in palmitic solution at intermediate pH displays surface properties similar to those of the collector by itself. This may be due to two alternative mechanisms (i) adsorption of bulk precipitate on the fluorite surface or (ii) the formation of a bilayer of surfactant ions on fluorite. Possibly, both mechanisms occur simultaneously.

Jan 1, 1993

By D. Lynn, D. Arthur

Infrastructures continue to age and drinking water supplies are becoming scarce in the San Fernando Valley of Los Angeles, California. Frontier-Kemper Constructors, Inc. (FKCI) was engaged by the Los Angeles Department of Water and Power (LADWP) to complete the River Supply Conduit Improvement Upper Reach—Unit 7 Project (RSC7). Two tunnel sections were bored using a 2.64 meter diameter Microtunnel Boring Machine (MTBM) and a 4.12 meter diameter Earth Pressure Balance Tunnel Boring Machine (EPBTBM) to excavate approximately 3,733 meters (3.7 km) of tunnels through highly abrasive late-Pleistocene-age Quaternary alluvial deposits (Old Alluvium) and Holocene age Young Alluvium deposits above the water table. This paper discusses the challenges encountered managing the TBM’s equipment degradation, use of soil conditioners, cutterhead wear, torque and advance rates while maintaining the necessary face-pressures and parameters to limit over excavation and ground settlement.

Jun 13, 2021

By Thomas V. Durkin

About 1.41 kt (45.2 million oz) of gold have been ! produced in South Dakota since 1875. South Dakota's mining laws attempt to strike a balance between economic development and environmental protection. Mining is promoted as an industry while prevention of pollution is required along with reclamation of affected lands to a beneficial use. The South Dakota Department of Environment and Natural Resources' (DENR) system of "one-stop shop- ping" for environmental permits streamlines the permit process. It fosters quick resolutions to compliance problems and helps keep enforcement actions out of the courts. Paha Sapa means "Hills that are Black" in Dakota Sioux. Appearing dark from a distance due to a thick forest of Ponderosa pine, the Black Hills were gold to many people. The exact date that gold was discovered in the Black Hills remains debatable. An inscribed stone tablet found in 1887 near Spearfish recorded these words:

Jan 1, 1998

By A. Pratt, G. Deschênes

This paper quantifies the detrimental effects of pyrite and stibnite on gold leaching kinetics. Means to reduce the effect of these minerals by addition of lead nitrate and oxygen are presented. A significant retarding effect was observed when the pyrite concentration was 20%. A pretreatment with lead nitrate reduced the extent of gold surface coating by Ag, Fe and S. Stibnite, at a concentration as low as 20 ppm, significantly affected the gold leaching kinetics through forming a passivating film of Sb(V) oxide possibly Sb2O5. The most practical way to alleviate the effect of stibnite is to leach the materials at a moderate pH with addition of lead nitrate. A low temperature reduced the efficiency of lead nitrate to counteract the effect of stibnite. The increase of dissolved oxygen is not favourable to alleviate the coating of stibnite on gold.

Jan 1, 2004

By D. K. Grubbs

Anorthosite is an abundant, domestic source of alumina with reserves in individual deposits ranging from a few billion to hundreds of billions of tons. While anorthosite contains less alumina than does kaolinite, its CaO and Na20 contents are significantly higher (Figure 1). Alumina can be produced from anorthosite by alkaline, soda-lime sinter or acid processes. CaO and Na20 are advantageous because they are reactants consumed in alkaline processes. Acid processes require high calcium plagioclase feldspars (bytownite-anorthite) to obtain high alumina extraction because the lower calcium plagioclase feldspars (andesine-labradorite) are not as readily dissolved during digestion. The layered Raggedy Mountain Gabbro group in the Wichita complex in southwest Oklahoma is a high calcium anorthosite that could be processed by acid, sinter, or alkaline methods. Chemical grade limestone in the Arbuckle Group is located within 45 km of the anorthosite (Figure 2).

Jan 1, 1980

By Catherine T. Aimone

A computerized cost model has been developed to simulate the technical and economic effects of strip mine blasting in the vicinity of structures. Current surface mining regulations restrict the allowable level of production blasting as a function of this distance. Blast design modifications,' therefore must be employed when blasting in the vicinity of homes to ensure compliance with federal and state regulations specifying limits to the seismic effects generated from a blast. The blasting level allowed. is computed by the charge weight of explosives per delay from the following scaled distance formula: [ ] where W is the charge weight per delay, in kilograms (pounds), D is the distance factor corresponding to the regulatory limit of peak particle velocity to which a structure may be subjected to. Current regulations specify 2.54 cm (1.0 in.) per second corresponding to a SD factor of 27 (60) (Federal Register, 1977).

Jan 1, 1982

By Ralph D. Daley, Kevin E. Redinger

The production of coal/water fuel (CWF), a highly loaded mixture of finely ground coal, water, and chemical additives, presents a unique opportunity for significant ash and sulfur reduction through physical coal cleaning. Froth flotation can be integrated with the staged, wet, fine grinding inherent in the CWF production process. A laboratory scale research program was conducted to demonstrate the feasibility of a flexible, integrated coal cleaning/CWF process flowsheet. Performance of the conceptual flowsheet was examined for two coals of CWF commercial interest, Upper Freeport and Pittsburgh seam coals, from central and southwestern Pennsylvania, respectively. Several multi-stage coal flotation and reverse flotation circuits were evaluated. CWF was produced from the cleaned coal in each case at similar solids loadings and viscosities as observed for the raw coal. However, the ash loading and SO2 emission potential for each CWF had been significantly reduced.

Jan 1, 1988

By William E. Foreman

The results of the electrokinetic study of the activation of quartz by divalent cations showed that the charge reversal was related to the point at which the cation hydrolyzed. The reversal was not due to the presence of solid hydroxide at the surface of the quartz but due to the charged ions in the solutions. The charge reversal for beryllium at a log molar concentration of 1x10-4 was observed at pH 5 and 9. The quartz was positively charged between a pH reading of 5 to 10. Magnesium at the same log molar concentration did not show a charge reversal from pH 2 to 12. The probable cause of the charge reversal was due to the ionized Be3 (OH)3+3 or Mg (OH)+ . Variations in the electrokinetics of quartz were minimized by heating the sample to 300° C.

Jan 1, 1968

By J. Mersch Ward

Homestake Mining Company has identified a significant native sulfur resource at its Cinnabar Canyon prospect in Mono County, California. Elemental sulfur occurs as replacements, fracture coatings and breccia fillings in a thick sequence of Miocene-Pliocene intermediate volcanic rocks. The deposit extends along a northwest trending regional fault and measures approximately 900' in width, at least 1800' in length, and has a thickness in excess of 200'. The deposit lies approximately 150' below the surface and is covered by a silicified cap of volcaniclastic strata. The deposit has been delineated by rotary and core drilling. Utilizing a grade cutoff of 5% elemental sulfur, the delineated deposit has a probablelpossible resource of 16.1 million tons of ore averaging 17.9% elemental sulfur containing 2.57 million long tons sulfur. Assay grades within the resource area range up to 40% sulfur over a 40-foot intercept.

Jan 1, 1992

By V. Prabhu, D. Mantha, R. Reddy

Secondary copper blast furnace slag was treated with carbon to derive the conditions for maximum recovery of copper with a minimum simultaneous reduction of iron oxide. Experiments were carried out to study the effect of temperature, carbon and CaO additions to the slag on the efficient recovery of copper. A two-stage reduction process was also employed to study the efficiency of copper recovery and the results were compared with those of single-stage reduction. The maximum recovery of copper in alloy phase was obtained with 5 % initial carbon in the slag, 2% CaO addition to the slag and at a reducing temperature of 1573 K. Higher grade of the alloy phase with respect to copper was obtained by employing a two-stage reduction process. The results obtained in this study are comparable to those of the earlier research on the recovery of copper from reverberatory furnace discard slags.

Jan 1, 2004

By D. J. Simbi, T. R. C. Fernandes, M. Nyamhunga

The recovery of P2O5 from a 90-95% minus 45 microns phosphate slimes sample was carried out in a 5.08-cm internal diameter and 549-cm high flotation column cell. The influence of the feed rate, feed percent (%) solids, and frother dosage on the recovery was investigated following a truncated cubic 3 level by 3 variables experimental design. Two three-variable interactions of feed rate (-l)/feed percent solids (+l)/frother dosage (-1) and feed rate (-l)/feed percent solids (-1)/ frother dosage (+I) gave the region of optimum column performance: recovery (52.60-74.50%), mass yield (15.68-18.80%), and concentrate grade (22.87-31.2196). The collector dosage also showed a significant influence on the column performance. The high reagent consumption relative to the current plant levels points to the need for the removal of ultrafine particles (<10 µm).

Jan 1, 1999

By R. C. Ford, J. Kelsey, S. A. Pierce, M. D. Ankeny

Evaluation of acid drainage risk from spent (leached) ore in arid climatic zones consists of two components: (1) whether residual and secondary minerals will release acid and metals when exposed to rainfall, and (2) whether ambient rainfall is likely to infiltrate, and eventually impact surface or ground water resources. The risk of acid drainage from spent ore at the El Abra on-off copper leach pad operation was evaluated using conventional geochemical methods and unsaturated flow models. Although geochemical testing indicated poor quality water would result from any seepage, unsaturated flow modeling demonstrated that infiltration and seepage were unlikely given the arid climatic conditions. Modeling further demonstrated that the residual moisture content of the spent ore when it is removed from the leach pad controls the risk of seepage. To further reduce the risk of seepage, operational controls were developed and implemented at the El Abra site.

Jan 1, 2000

By Jue Kou, Fazhao Sun, Jiang Liu, Cuili Gui, Baoqiang Yu, Chunbao Sun

A novel special magnetic separator was developed based on the special properties of precious metal-bearing alloy in highgrade nickel matte. The recovery of Au, Pt, and Pd was 77.79%, 84.79%, and 81.79% respectively at optimum operation conditions of magnetic separator feed of 2.5t/h, pulp density of 45%, and flush water of 1.5t/h, and the recovery significantly improved comparing with normal magnetic separator. Magnetic field simulation of the special magnetic separator indicates that magnetic intensity of 0.6 T can be generated on the surface of magnetic drum, which can strengthen the recovery of heavy alloy that contains precious metals. The alternate strong and weak magnetic field can also make magnetic particles rolling on the surface of drum, which will reduce the generation of magnetic agglomeration to a large extent and decrease the content of impurities in magnetic concentrate.

Jun 16, 2022

By Christopher P. White, John R. Wagner

This paper will discuss the complex and difficult soil conditions encountered in the sinking of 15 shafts of 18m to 27m depth and the excavation and lining of 6700m of 2.74m dia. interceptor sewer on Staten Island, New York. The complex soil profile consists of dense glacial till and sand outwash strata overlying the much older cretaceous sand, silt and clay strata. The tunnel varies from 8m to 14m below the nearby sea level. A significant amount of boulders were anticipated in the till. therefore, a decision was made to excavate the tunnel with a digger shield installing bolted, gasketed concrete segments. The bid documents stated the soils were dewaterable. Several conditions occured in this complex soils matrix which required modifying the planned means and methods including the necessity to use compressed air. The conditions encountered and the equipment used will be described.

Jan 1, 1991

By C. J. Webb

Abandoned uranium mines in the southern Black Hills of South Dakota were sampled for uranium, radium, and rare earth elements during 1992 and 1993. Analyses of water samples from several shallow ponds in the mine pits showed pH values between 3 and 4 with uranium concentrations between 1600 and 2600 ppb. Rare earth elements and their respective isotopes were analyzed with an inductively coupled plasma mass spectrometer and were referenced to a shale normalization pattern. All samples showed an enrichment in the middle rare earth elements. Rare earth levels often were greater than 0.2 ppm. At one site, the concentrations of lanthanides were 150,000 times above background levels. While the southern Black Hills have long been known for rich uranium ore deposits, these analyses show that significant levels of rare earth elements also are present, indicating that the potential exist for future development.

Jan 1, 1995

By H. L. Ford

Flocculant testing should be initiated for economic or performance reasons. When the decision has been made to test, the laboratory can provide valuable information concerning the various products under consideration. Properly conducted laboratory tests can determine: 1. If two flocculants are needed to achieve clarity or density. 2. Ease of mixing. 3. How quickly the material goes into solution. 4. Stability of prepared f locculant solution. 5. Stability of the floc formed. 6. Amount of mixing required for proper floe formation. 7. Optimum flocculant concentration. 8. Optimum pulp density. 9. Approximate location of the point of addition. 10. Single or multiple addition points. When a flocculant shows promise in the laboratory, a plant test should be scheduled. During the plant trial, arrange for normal conditions and start testing with a crew that is most familiar with the unit operation where the flocculant will be applied.

Jan 1, 1986

By A. I. Kogut

Impurity minerals in fluorspar ores and concentrates from a deposit in Southern Africa have been studied by reflected light, transmitted light, and cathodoluminescence microscopy. The principal impurities are quartz, calcite, aegirine, apatite, ankerite, magnetite, goethite, and synchysite [Ca(La,Ce,Nd)(CO3)2F]. Cathodoluminescence microscopy was found to be very useful in studying the character of the fluorite and especially for recognizing the presence of apatite and calcite impurities. Fluorite exhibits blue, calcite shows yellow, and apatite has white, light purple, and pink cathodoluminescence. The cathodoluminescent character of apatite varies with its geological environment and position in the orebody. The results of this microscopic study show that phosphorus present in fluorite concentrates occurs principally in binary locked apatite-fluorite particles. Successive fluorite cleaner concentrates contain progressively smaller amounts of locked apatite-fluorite particles. Free apatite has been effectively partitioned to the final tailings.

Jan 1, 1995

By Eugene R. Palowitch

From the late 1880s to the present, the Appalachian region continues to be a dominant supplier of premium-quality coals. The region contains an estimated 93.4 Gt (102.7 billion st) of demonstrated reserves in Alabama, eastern Kentucky, Maryland, Ohio, Pennsylvania, Tennessee, Virginia and West Virginia. Therefore, Appalachia will remain a source of quality coals for the metallurgical, export and utility markets. Figure 1 shows the annual production of coal in Appalachia and nationally from 1970 through 1993 (Energy Information Administration, 1994). During that 23-year period, annual domestic coal production almost doubled. Coal production from Appalachia increased at an average annual rate of only 0.7%. Coal production remained essentially constant at about 409 Mt/a (450 million stpy). Thus, Appalachia&apos;s market share decreased from 69.8% in 1970 to 47.2% in 1993 - a drop of almost one-third (Energy Information Administration, 1994).

Jan 1, 1995

By John A. Shuster, Joseph A. Sopko

Construction of two shafts, as well as associated deep concrete structures, for a major storm sewer project in Milwaukee, Wisconsin required ground water control and temporary ground support to depths ranging from 19.2m to 55.0m. Lowering of the site ground water table eras not possible because of potential consequences for existing nearby structures. Construction entailed completion of two shaft collars into bedrock. In addition to the shafts, several adjacent connected. structures were completed. Ground freezing was selected to provide temporary ground support and ground water control for all excavations. The first application of using reinforced frozen earth was successfully incorporated on the project. The procedure enabled the contractor to create openings in excess of 9.1m in height, without bracing, through highly stressed frozen earth walls. Design features and construction procedures for completion of ground freezing and related excavation are reported.

Jan 1, 1989

By Timothy N. Dunne, Joseph M. Gonzalez

This paper presents the case history of a comprehensive geotechnical investigation for the Crosstown Transport Facility, a 10,880 m long, 3.2 m diameter pressure tunnel proposed for construction in San Francisco, California. The proposed tunnel would be part of the City and County of San Francisco&apos;s Clean Water Program, and its purpose would be to convey stormwater and sewage from the east side of the City to the Pacific Ocean. Tunneling conditions were defined by surface geologic mapping, 94 exploratory borings, surface and borehole geophysics, aquifer testing, Goodman Jack testing, pressuremeter testing, and laboratory testing. Through the use of advanced coring techniques and a strictly controlled drilling fluid system, core recovery averaged 90 percent in the sheared and fractured rock of the Franciscan Formation. As a result, over 1,400 linear meters of rock core was recovered and is available for examination.

Jan 1, 1983