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By Charles Dr. Li, John Dr. Box

Selective flotation and adsorption behavior of zircon and rutile under hot soap conditions have been examined. Conditioning temperature, pH and washing steps were shown to control the flotation selectivity. The adsorption of the sodium soap of oleic acid at zircon- water and rutile-water interfaces was investigated through micro- electrophoresis and adsorption density measurements. The soap adsorption on the zircon surface increased markedly with increasing temperature due to a strong chemisorption/surface reaction, and was almost independent of pH. In contrast, the soap adsorption on rutile decreased at high pH values. A simple physisorption plus hydrophobic interaction appeared to be the principal mechanism for the soap adsorption on rutile at moderate temperatures (below ~70(C), beyond which it may change to chemisorption through an activation process. Water wash, particularly under acidic conditions (pH 2-3), of the rutile particles treated with soap, will lead to a desorption of the soap from the rutile surface by forming an acid salt precipitate.

Jan 1, 1995

By Edward L. Mooney

In the, West, walking draglines often offer the least cost method of uncovering coal for surface mines. However, with each of these machines costing millions of dollars, a good deal of analysis can be justified by the potenial savings or, conversely, costs associated with the choice of a machine. This has resulted in the recent development of a number of computerized models for dragline selection and pit design. One of the earliest reported models for this purpose was developed by Dunlap and Jacobs (1). Later, Rumfeldt described the computer approach to sizing stripping draglines given the required production rate and mine site parameters (2). This basic approach is probably still the most widely used with models for more complicated mining methods reported by Stefanko, Tomica, Finch, as well as others (3,4,5). furthermore, detailed simulation models useful in this regard have been developed by McDonnell Douglas and Fluor, Utah (6,7)

Jan 1, 1982

By C. W. Schultz

The Mineral Resources Institute at The University of Alabama is engaged in a program whose objective is to develop a beneficiation system for Eastern oil shales. Prior experience (1,2) at The University had shown that the grind required for liberation of the oil rich kerogen was substantially below 20~m. Based on this fact and the rapidly emerging consensus that column flotation is the preferred method for ultrafine particle separation, efforts were focused on the column flotation of oil shale. This paper, which must be regarded as a progress report on a continuing MRI project, describes the observations made and the results achieved to date. The investigation is being conducted in two phases. The first phase has been completed and consisted of a factorially designed experiment conducted for the purpose of screening a set of primary flotation variables. The second phase, which is still in progress, is focused on optimization of the operating conditions and development of a flowsheet for specific shales.

Jan 1, 1989

By G. G. O. O. Uwadiale

Because mineral matter is finely distributed within the matrix, Nigerian Labia coal is nonresponsive to conventional processing techniques. However, testing has shown that Lafia coal can be upgraded by selective oil agglormation. The optimum oil concentration was found to be 10 mL of paraffin per 25 g of coal. A product containing 6% ash and 1.9% sulfur was obtained with a yield of 90%. Optimum results were achieved with a grinding; time of from 2.5 and 3 hrs, which produced a 98% -400 mesh product. However, further grinding wars found to be deleterious to the process. Also, high pH adversely affected concentrate yields. Utilizing kerosene as a bridging liquid, a product containing 4% ash and 0.33% sulfur was achieved at a natural pH of 6.3 with a yield of 85%. At pH 9 and 10, a product containing 4.5% ash was achieved with a yield of >90%.

Jan 1, 1997

By D. Harney

Accurate measurement, tracking, and planning are vital for efficient utilization of energy in any mining operation, the major focus of this paper. This can be done with a number of assessments: 1) accurately measure KWH usage and track peak demand periods first; 2) identify the electrical equipment that affects your usage and the conditions that require it to be running; 3) remotely monitor and control as much equipment as possible, especially larger pieces of equipment; 4) with your utility determine that you are on the most suitable rate for your usage profile, then understand how your utility company calculates your electrical bill; 5) recognize how production affects energy usage and utility costs; 6) keep historical records of everything you monitor; 7) make information, live and historical, available to everyone; and finally, with the knowledge of your equipment and energy needs, automate controls that you have identified to optimize your energy usage and time of usage.

Jan 1, 2007

By Meliton M. Garcia, Satya Harpalani

This paper discusses the results of an investigation carried out in an underground mine to characterize the volatile by-products adsorbed on airborne particulates following the detonation of four common explosives including ANFO. The primary objective of this study was to determine if any organic amine compounds, particularly nitrosamines, and any polycyclic aromatic hydrocarbons were produced and trapped in the dust that a miner might inhale during the workday. The production of these substances is of great concern because of their suspected carcinogenic nature. The results of the study indicated that a large variety of the by-products are adsorbed on the particulates generated, and thus remain airborne following the detonation of explosives. The major by-products retained by the dust were bis(2-ethylhexyl) phthalate, and aliphatic hydrocarbons with carbon chains ranging from C12 to C28. One explosive, a water gel, produced the polycyclic aromatic compound, trimethylnaphthalene. No nitrosamine compounds were detected.

Jan 1, 1989

By V. McLemore

New Mexico ranks 2nd in uranium reserves in the U. S., which amounts to 15 million tons ore at 0.277% U3O8 (84 million lbs U3O8) at $30/lb (EIA, 2006). The most important deposit in the state is sandstone within the Morrison Formation (Jurassic) in the Grants district. More than 340 million pounds of U3O8 have been produced from these deposits from 1948-2002, accounting for 97% of the total production in New Mexico and more than 30% of the total production in the United States. Sandstone uranium deposits are defined as epigenetic concentrations of uranium in fluvial, lacustrine, and deltaic sandstones. Three types of sandstone uranium deposits are recognized: tabular (primary, trend, blanket, black-band), roll-front (redistributed, post-fault, secondary), and fault-related (redistributed, stack, post-fault). Several companies are planning to mine these deposits by in-situ leaching.

Jan 1, 2007

By John E. Litz, Charles W. Kenney, Wayne Carter

Refractory gold ore pretreatment processes continue to receive much attention. This paper compares the relative economics of treating ores by oxygen pressure oxidation, roasting and bacterial oxidation with or without preconcentration by froth flotation. Capital and operating cost estimates for each method of pretreatment were prepared and these estimated costs and ore sulfide grades then are used to compare the process economics. The study indicates that the most significant item affecting the economics is the amenability of the ore to flotation. The cost benefits of flotation are $10-13 per tonne ore processed (2%-4% s=, 10:1 ratio of concentration). In most cases bacterial oxidation has the lowest overall cost, especially if less than complete oxidation of the sulfides will give acceptable recovery, however bacterial oxidation has yet to be practiced on a large scale. In all situations pressure oxidation shows the highest cost. However, the cost differences between the treatments are small, less than $7 per tonne.

Jan 1, 1990

By P. J. Tarkoy

To successfully bid a tunneling contract by machine, a contractor must have a reliable estimate of expected penetration rates and cutter costs. Preferably, these predictions should be independent of those supplied by machine and cutter manufacturers. Therefore, a series of rock index tests have been developed and incorporated in routine Rock Mechanics testing for the purpose of predicting rock boreability. Index properties were evaluated empirically by using rock samples and pertinent construction records from recently machined tunnels. Samples were taken from the completed tunnel walls, tested parallel to machine penetration, and results were compared to localized rates of penetration. Indices are based on two measures of rebound hardness and two measures of abrasive properties. The Shore (C-2 type) Scleroscope and Schmidt (L-type) Hammer were utilized to measure rebound hardness and a Taber Abraser was modified to measure rock abrasiveness and abradeability. Results indicate that rock hardness index properties investigated in this study can be used successfully to predict TBM penetration rates.

Jan 1, 1974

By P Simpson, P Bundo

The Eureka Mine is situated in the Guruve district of Zimbabwe, some 150 km north of Harare. The mine was first worked in 1895 and until recently was operated as a typical Zimbabwean "smallworking" with a single owner­operator and small labour force mining at up to 50m depth and processing 50 tonnes per day of ore via grind, gravity recovery and CIP. The gravity circuit comprised a Knelson 12" Centre discharge Concentrator from which a significant but variable portion of production was recovered. In 1996 exploration was commenced by Delta Gold Zimbabwe (Pvt) Ltd (DGZ), a wholly owned subsidiary of Delta Gold NL of Australia, with the aim of testing mineralisation and establishing a large-scale open pit operation. A feasibility study was completed in April 1998. Construction began in August 1998 and first gold was poured in June 1999. The mine is designed to produce 65 000 oz/annum of gold from 1.5 million tonnes of opencast ore grading 2 git Au.

Jan 1, 2000

By S. K. Kawatra, S. J. Ripke

Finely disseminated iron ores compose much of today's reserves. After removing the silicate gangue, the resulting fine iron oxide concentrates require pelletization with a binder to enable transportation and reduction. Binders can be used more efficiently if their binding mechanisms can be completely understood. Typically, bentonite clay is needed as a binder to improve the strength of the pellets. Bentonite is an effective binder at a relatively low cost, but costs could be reduced further by replacing bentonite with even lower-cost binders, such as high-carbon Fly-Ash Based Binder (FBB). In this study, it was found that bentonite binds by a physical mechanism, while FBB binds by a chemical mechanism. These mechanisms were determined to be incompatible. Partial replacement of either binder with the other reduced dry magnetite pellet compressive strengths below the industrially acceptable value of 22.2 newtons (5 lbf). Activators and accelerators that activated the fly-ash deactivated the bentonite. The incompatibility of these two binders is explained.

Jan 1, 2000

By Robert M. Cox

The principal factor that must be determined for the effective design of a coal mine roof bolt support system is the maximum stable tension that can be developed with a given bolt assembly in a particular roof rock. There are four basic types of roof bolt anchorage techniques available: (I) the splitwedge; (2) mechanical expansion units; (3) resin point anchors or grouted expansion units; and (4) the cone shell which is placed in a reamed hole. A study of this problem has been made which includes theoretical analyses, laboratory experiments and field tests. A static free-body analysis of each of the anchorage techniques has provided formulas for predicting the anchorage capacity for a particular rock from the results of standard pull tests. The formulas also provide an insight into the anchorage mechanism of technique and allow for a comparative evaluation of the methods for design purposes. The theoretical analyses also indicate clearly the pertinent variables affecting the anchorage mechanism of each method.

Jan 1, 1977

By S. Constantinescu

The alloys mainly used for short (or segmented) chip material cutting (cast iron, porcelain, etc) are alloys of the WC-Co type; in some cases with small additions of other carbons. The same alloys but of different granulometric classes are also used for pieces exposed to wear (wire drawing, moulds) The higher performance of the WC-Co alloys in chip machining applications is accounted for by their very good heat conductivity, which is 2-3 times higher than that of fast steels. The hard-alloys producers can resort to a wide range of possibilities to achieve variation of properties of a WC-Co composition and thus they can adapt their products to the particular type of tools they may choose to manufacture. The present metallography technique allows for a correct identification and evaluation of hard sintered carbons structures. The metallography approach is an indispensable method of investigation and control in the industry.

Jan 1, 2008

By Ken Takahashi, Yuuich Umeki, Masahiko Arakawa, Dr. Tominaga. Yuusaku

Macroscopic characteristics of a complicated mine ventilation is remarked to build an expert system for mine safety in the Taiheiyo coal mine, Hokkaido, Japan. To gain the characteristics a large number of simulation were performed with varying aerodynamic resistance of the branches with regulator in mine ventilation network. The principal results of the study are as follows, (1) Pressure loss diagram for ventilation network with main and auxiliary fans enables capability of air circulation in the network. (2) H-Q (pressure-quantity) diagram gives capacity of air quantity In a network with main and auxiliary fans. (3) When airflow rate, [] through branch qi is changed by opening/closing regulator set in the branch, air flow rate, [], through branch p can be represented by the empirical formula. [ ] where Api and Qp,o are the constant coefficients. (4) Macroscopic characteristics mentioned above are available to make rules in an expert system for escaping route at emergency.

Jan 1, 1989

By James M. Barker, George S. Austin

Stone, one of the oldest building materials, today remains a well-established material throughout the construction industry. The use of natural stone is much less prevalent now than in the past. It is still widely considered to be the most aesthetically pleasing, prestigious, and durable building material. New and re-opened quarries are coming onstream to meet increased demand related to new building technology and increased residential use of stone. CLASSIFICATION No classification can completely eliminate overlap between dimension stone, aggregate, and decorative stone because most stone is multi-purpose. Many used for decorative purposes are not produced specifically for that end use. Rock otherwise considered waste in dimension stone or aggregate quarries can be decorative stone coproducts (Fig. 1). Many uses require a compromise between decorative and structural qualities (Bowles, 1992, written commu¬nication). Shipley (1945) used decorative stone interchangeably with or¬namental stone. Gary et al. (1972) defined decorative stone as that used for architectural decoration, such as mantels, columns, and store fronts, but added that it is sometimes set with silver or gold in jewelry as curio stones. Bates and Jackson (1987) also restricted decorative stone to that used for architectural decoration. Meanings of otherwise identical terms used in the stone industry differ be¬tween geologists, engineers, and quarriers. They often carry a much broader meaning for quarriers and engineers compared to their very specific use by geologists (Makens et al., 1972). Decorative stone, including ornamental stone, is more broadly defined by geologists as any stone used primarily for its color, texture, and general appearance. It is not used primarily for its strength or durability, such as construction stone, or in specific sizes, such as dimension stone. The decorative stone industry uses a much wider range of stone types compared to stone that is dimensioned. Decorative stone usually serves some structural pur¬pose, but is not load-bearing to any great extent. Weak or costly stones serve in decorative, not structural, applications. STATISTICS AND END USES Decorative and dimension stone data are difficult to separate because the US Bureau of Mines keeps statistics only on dimension stone and crushed stone. The value of domestic dimension stone production in 1990, which includes some decorative stone, was about $210 million compared to imports of about $524 million and exports of about $35 million. Production was 1 080 t of which at least one-third was for decorative uses (Taylor, 1992). The principal uses are rough blocks in building construction (23%) and monu¬ments (18%); the remainder is used as ashlar (18%), curbing (12%), and miscellaneous (29%). Major rock types are granite (50%), limestone (30%), sandstone (10%), slate (3%), marble (2%), and other (5%) (Harben, 1990). Crushed stone valued at $5.6 billion was produced in the United States in 1990 by 1700 companies operating 3400 active quarries in 48 states (Tepordei, 1991). About 52% is used in con¬struction, 9% in cement and lime manufacturing, 2% in agricul¬ture, 2% in industrial uses, and 35% for unspecified uses including decorative aggregate. Limestone and dolomite comprise about 71%, granite 14%, and traprock 8% of the stone crushed in the United States. The remaining 7% are, in descending quantity, sandstone, quartzite, miscellaneous rock, marble, shell, calcareous marl, volcanic cinder and scoria, and slate. The basic types of decorative stone are: rough stone, aggregate, cut or dressed stone, and manmade stone [(Table 1)]. Rough Stone Rough stone is used as it is found in nature with very limited processing such as minor hand shaping, edge fitting, and size or quality sorting (Perath, 1992, written communication). This stone type is often marketed locally in relatively small tonnages and includes fieldstone and flagstone. The primary end uses of rough stone are landscaping, edging, paving, or large individual stone landscape or interior accents [(Fig. 2)]. Fieldstone: Fieldstone is picked up or pried out of the ground (gleaned) without extensive quarrying and includes garden or large landscaping boulders (Austin et al., 1990, Hansen, 1969). Boulders and cobbles may be split or roughly trimmed for use in rubble walls and veneers, both interior and exterior. Popular fieldstone rock types include sandstone, basalt, limestone, gneiss, schist, quartzite, and granite, but many others are suitable. Much fieldstone is col¬lected by individuals or small companies because the industry is labor intensive and markets are small. The stone may be sold locally in small quantities from the back of vehicles (Austin et al., 1990). Fieldstone includes many rock types, sizes, and shapes with the only common denominator that it must be set by hand and be durable (Power, 1992, written communication). Moss Rock. Moss rock is fieldstone partially covered by algae, mosses, lichens, and fungi that give the rock an aged and variegated patina (Austin et al., 1990). The plants are supported by moisture and nutrients in the stone. Moss rock is used for landscaping, walls, and fireplaces. Although almost any durable rock can be a moss rock, most are slabby or rounded sandstone and limestone (Fig. 3). Flagstone: Flagstone or flagging consist of thin irregular slabs used for paving, walkways, and wall veneers. Random-shaped flagging is produced widely in the United States. Suitable stone

Jan 1, 1994

By Jiang Su, Alan Bloodworth

"Composite sprayed concrete lining (SCL), consisting of two layers of permanent sprayed concrete separated by a layer of spray-applied waterproofing membrane, represents the latest development in SCL tunneling, but presents several challenges to designers. This paper aims to address the following issues: (1) how to simulate composite action, (2) behavior of a composite SCL tunnel, and (3) how to utilize composite action to achieve lining thickness efficiency. It firstly sets out the background to the composite SCL concept, and then presents a strategy for numerical investigation. The main part of the paper is the presentation and discussion of the simulation results, focusing on the lining deformation, load sharing and the safety margin of both linings. Interface stresses are also examined. It is found that significant secondary lining thickness reduction may be achieved by utilizing composite action. Challenges for the design of composite SCL tunnels are briefly discussed at the end. INTRODUCTION Sprayed concrete lined (SCL) tunnelling has seen rapid development over the last twenty years in the UK (Su 2013). One of these developments has been the replacement of traditional sheet membrane and cast in situ secondary lining with innovative spray applied waterproofing membrane and sprayed secondary lining system, which has been adopted in recent major projects, such as Crossrail (Pickett 2013), and brings many benefits to the construction (Dimmock et al. 2013). The combination of sprayed primary lining, spray applied waterproofing membrane and sprayed secondary lining is perceived to provide a structurally efficient lining system that outperforms the traditional lining system, which consists of sacrificial primary lining, sheet waterproofing membrane and cast in situ secondary lining. The claimed benefits in structural performance arises from the composite action between the sprayed primary and secondary linings via the spray applied waterproofing membrane, which produces a much stiffer cross-section and therefore a more efficient use of materials. Early investigations on the design of composite SCL tunnels were carried out without (1) definite and reliable long-term interface parameters, (2) a verified numerical modelling technique, or (3) consideration of different stress histories between primary and secondary linings (Thomas and Pickett 2011, Marcher et al. 2011). This paper reports the findings from a numerical parametric study on a typical composite SCL tunnel with varied secondary lining thickness. The results show that the true benefit of composite lining arises from the optimisation of the lining thickness (stiffness) ratio between the primary and secondary linings to achieve secondary lining safety and thickness efficiency at the same time."

Jan 1, 2016

By Jun Ho Lee, Dae Young Kim, Ebrahim Farrokh, Ki Chang Hyun

"The Jinhae Geoje gas pipeline tunnel project is the largest (7.8 km) and the deepest (90 m) subsea tunnel in South Korea. This tunnel will house a pipeline to carry natural gas from the mainland to Geoje Island southeast of the country to alleviate the increased demands for natural gas, especially in the winter season. Tunneling is currently underway using two slurry shield TBMs of 3.5 m diameter. This paper describes the major design elements of the tunneling machines and their performance evaluation. For this purpose, a thorough analysis of geotechnical information was performed to evaluate the tunnel elevation to reduce the risk of tunneling under high water pressure in unstable and permeable rock mass under 9 bar water pressure. TBM specification and TBM performance were also analyzed using different methods, including well-known models as well as a rotary cutting machine test developed in house in Hyundai Engineering and Construction Company. INTRODUCTION High demand for natural gas, especially in winter season was the primary driving factor for the design of the Jinhae Geoje gas pipeline project. This project is located southeast of South Korea between Jinhae district and Geoje Island and runs for over 50 km length. The mid part of this project includes a 3.5 m diameter subsea tunnel consisting of two sections of Geoje to Jiri Island (4.3 km) and Jinhae to Jiri Island (3.5 km). Figure 1 shows the tunnel project location and its layout. Figure 2 shows the geological profile along the tunnel. As can be seen, the tunnel passes mainly through three rock types: granite, tuff breccia, and andesite tuff. This tunnel was planned to be constructed by two face pressurized shielded TBMs and to be lined with a segmental lining of 2.8 m internal diameter. The major challenge for this tunnel is its maximum expected water pressure at the tunnel invert (8.83 bar). At such a high water pressure, the TBMs required special design to ensure they can handle unexpected water pressure and to ensure the risks for the TBM maintenance intervention are minimal. In this regard, a thorough analysis was conducted on the TBM design parameters and geotechnical information to define required TBMs’ design parameters and to identify the safest tunnel elevation. This paper provides a brief overview of the project geotechnical information, TBM selection and its design specification, tunnel elevation selection, and TBM penetration rate evaluation. In this regard, a rotary cutting machine testing equipment was used to perform trial tests on a similar rock type encountered along the tunnel for performance evaluation and optimization."

Jan 1, 2016

By J. Groppo, W. Zhang, R. Honaker

"Rare earth elements (REEs) found in coal are in the form of minerals, ion-adsorbed onto clay surfaces or inner layers, or organically bound. Rare earth minerals such as monazite exist in coal and have grain sizes smaller than 5 µm. In this study, froth flotation was successful in concentrating rare earth minerals existing in a thickener underflow material derived from Fire Clay seam coal that contained around 431 ppm of total rare earth elements (TREE) on a dry ash basis. Conditioning with fatty acid followed by processing using multiple stages of conventional flotation produced a final concentrate containing 2,300 ppm TREE. Using a laboratory flotation column to limit hydraulic entrainment, the TREE content was further enriched to around 4,700 ppm, which equated to an enrichment ratio of 10:1.IntroductionRare earth elements (REEs) are becoming increasingly important and have been widely used as raw materials for the production of phosphor, metal catalysts, magnets and batteries (Binnemans et al., 2013; Zhang et al., 2015). REE recovery from alternative sources such as coal and coal byproducts has the potential to stabilize the economic viability of coal mining operations while providing a dependable supply of critical materials.The average REE content of the world’s coal resources is around 60 to 70 ppm (Zhang et al., 2015). There are many well-known coal beds with high contents of REEs such as those in the Far East coalfields in Russia with contents of 300 to 1,000 ppm, the Fire Clay coal seam in eastern Kentucky in the United States with contents around 500 ppm and the Sydney Basin in Nova Scotia, Canada, with contents of 72 to 483 ppm (Birk and White, 1991; Seredin, 1996; Hower, Ruppert and Eble, 1999; Blissett, Smalley and Rowson, 2014). The occurrence of REEs in coal and coal byproducts can be classified into three types: (1) rare earth minerals, such as monazite and xenotime, (2) ion-adsorbed REEs on clays and (3) REEs associated with organic matrices. The rare earth minerals in coal and coal byproducts are very small in particle size, generally on the micrometer and/or nanometer scales (Honaker et al., 2014). Froth flotation, which concentrates minerals based on surface chemistry differences, has been widely used to treat fine rare earth industrial minerals such as monazite, xenotime and bastnaesite (Abeidu, 1972; Cheng, Holtham and Tran, 1993; Pavez and Peres, 1994; Pavez, Brandao and Peres, 1996; Jordens et al., 2014). As such, flotation is a promising method for the concentration of rare earth minerals from coal and coal byproducts."

Jan 1, 2017

By Duane B. Jorgensen

The two calcium sulfate minerals, gypsum and anhydrite, occur in many parts of the world, and gypsum has long been of economic importance in the family of industrial minerals. Gypsum, the dihydrate form of calcium sulfate (CaSO, . 2H20) and anhydrite, the anhydrous form (CaSO,) are frequently found in close association, and it is seldom that a calcium sulfate deposit will consist exclusively of one mineral or the other. Although known gypsum deposits are extensive, anhydrite makes up the larger part of total calcium sulfate resources. Although it has very minor economic use, it is important to the understanding of gypsum deposits and is referred to frequently in the following discussion. Calcium sulfate is one of the principal constituents of evaporite deposits, and when pure, has the following composition: [ ] Deposits of pure gypsum or of pure anhydrite which are large enough to be considered commercial have not yet been found because of both the metastable relationship between the two minerals, and the presence of impurities such as calcium or magnesium carbonates, chlorides, other sulfate minerals, clay minerals, or silica. Most gypsum produced ranges from 80 to 95% pure and beneficiation is normally limited to selective mining or quarrying or upgrading by crushing and screening during mill processing. END USES The largest use for gypsum is based upon the unique property which calcium sulfate has of readily giving up, or taking on, water of crystallization. With the application of a moderate amount of heat in a process known as calcining, gypsum is converted to plaster of paris, the hemihydrate of calcium sulfate (CaSO4 ½ H2O), which when mixed with water will set or harden as the calcium sulfate returns to the stable dihydrate form. This semifinished product, usually called stucco, is then manufactured into a large variety of plasters, wallboard, and block for construction use, or into plasters for industrial applications. About 75% of the gypsum used in the United States is calcined for these purposes. Uses of uncalcined gypsum are principally as a retarder for portland cement, as a soil conditioner, as a mineral filler, and other minor industrial applications. About 25% of the gypsum mined in the United States goes into these markets; however, in other countries with building practices different from those in the United States and Canada, relative usage varies widely. Calcium sulfate deposits are the world's largest sulfur resources; minor quantities of gypsum and anhydrite have been used to produce sulfur or sulfur compounds. This use is accompanied by a unique site-specific set of economics because sulfur is generally available from non-gypsum sources at lower cost.

Jan 1, 1994

By A. Wahab Khair, Negendra P. Reddy

INTRODUCTION The continuous mining machines which were introduced in the 1950's now account for more than half the production of coal from underground mines. Unfortunately, these continuous miners which were designed for increased productivity have also increased the concentration of respirable dust in mines. Inhalation of this respirable dust by miners causes the Coal Worker's Pneumoconiosis (CWP). Concern for CWP increased in the United States following a 1963-65 survey that showed definite x-ray evidence of CWP in 9.8 percent of working miners and in 18.2 percent of nonworking miners in the Appalachian bituminous coal region (Breslin and Niewiadomski, 1982). One of the major objectives of the Federal Coal Mine Health and Safety Act of 1969 was the prevention of CUP. This law initially limited the daily average exposure of coal miners to 3 mg/m3 of respirable dust. However, following the results of a probabilistic model developed by Jacobsen, et. al. in 1971, the limit was reduced to a mass concentration of 2 mg/m3 unless quartz content exceeds 5 percent, a rare occurrence in mines. Based on x-ray categorization prior to death it is believed that the mass concentration in the respirable fraction is a parameter of primary interest for hygenic evaluation of dust exposure. Elorgan, Burgess and Jacobson (1973) suggested that the quantity of inhaled dust, although influential is not the only aspect of exposure which is significant in producing CWP. Miners working in higher rank coal (anthracite) mines are more susceptible to CWP (Morgan, Burgess and Jacobson, 1973). This also confirms the findings of the British (Bennett, Dick and Kaplan, 1979 and Hurley, et. al., 1979) and Germany (Reisner and Rubock, 1977). Based on the cy to toxicological evidence Reisner and Rubock (1979) suggested that when coal properties are similar, increasing quartz and mineral content increases toxicity. David, Ottery and Le ?oux (1975) examined that as the severity of the CWP increased the retention of the coal dust content in the pulmonary region remained the same, while that of quartz content increased significantly . Leiteritz, Baur and Bruckman (1971) studied the various components of coal dust and showed that coal particles comprised a smaller fraction of the mass of fine dust than did particles , of quartz and minerals. It is ironic that quartz and mineral matter both comprise smaller fractions of the higher rank coal dust (Dodgson, et. al., 1971 and Dwiggins, 1981). Results of a recent research revealed that quartz or any other mineral examined had no strong or consistent effect on the incidence or progress of CWP (Attfield,

Jan 1, 1986